EP2767601A1 - Produit plat en acier laminé à froid pour applications d'emboutissage profond et son procédé de fabrication - Google Patents

Produit plat en acier laminé à froid pour applications d'emboutissage profond et son procédé de fabrication Download PDF

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Publication number
EP2767601A1
EP2767601A1 EP13155225.9A EP13155225A EP2767601A1 EP 2767601 A1 EP2767601 A1 EP 2767601A1 EP 13155225 A EP13155225 A EP 13155225A EP 2767601 A1 EP2767601 A1 EP 2767601A1
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Prior art keywords
cold
annealing
content
steel
flat steel
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EP13155225.9A
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German (de)
English (en)
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EP2767601B1 (fr
Inventor
Evgeny BALICHEV
Harald Hofmann
Jose Jimenez
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ThyssenKrupp Steel Europe AG
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ThyssenKrupp Steel Europe AG
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Priority to EP13155225.9A priority Critical patent/EP2767601B1/fr
Application filed by ThyssenKrupp Steel Europe AG filed Critical ThyssenKrupp Steel Europe AG
Priority to KR1020157024979A priority patent/KR102193066B1/ko
Priority to PCT/EP2014/052810 priority patent/WO2014125016A1/fr
Priority to JP2015557422A priority patent/JP6383368B2/ja
Priority to US14/767,741 priority patent/US10513762B2/en
Priority to CN201910355506.7A priority patent/CN110295317A/zh
Priority to BR112015019413A priority patent/BR112015019413A2/pt
Priority to CN201480021223.4A priority patent/CN105121673A/zh
Publication of EP2767601A1 publication Critical patent/EP2767601A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0405—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26—Methods of annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/004—Dispersions; Precipitations
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling

Definitions

  • the invention relates to a cold-rolled steel flat product for thermoforming applications, which has a reduced weight as a result of a density reduction with optimized mechanical properties and an optimized deformability. Likewise, the invention relates to a method for producing such a flat steel product.
  • Al-containing deep-drawing steels may contain a maximum of 6.5% by weight of A1 (cf. U. Brüx "Thermoformable iron-aluminum lightweight steels", construction April 4, 2002 ).
  • the object of the invention was to provide a flat steel product which, with a significant reduction in weight, has optimized deformation suitability and likewise optimized mechanical properties.
  • this object is achieved with regard to the cold-rolled flat steel product by providing a product having the features specified in claim 1.
  • a cold-rolled flat steel product according to the invention for deep-drawing applications consists of a steel which, in addition to iron and unavoidable impurities (in% by weight) C: 0.008-0.1%, Al: 6.5-12%, Nb: 0.1-0, 2%, Ti: 0.15-0.5%, P: up to 0.1%, S: up to 0.03%, N: up to 0.1%, and optionally one or more elements from the group " Mn, Si, rare earth metals, Mo, Cr, Zr, V, W, Co, Ni, B, Cu, Ca, N "with the proviso contains, Mn: up to 1%, rare earth metals: up to 0.2%, Si : up to 2%, Zr: up to 1%, V: up to 1%, W: up to 1%, Mo: up to 1%, Cr: up to 3%, Co: up to 1%, Ni: up to 2%, B: up to 0 , 1%, Cu: up to 3%, Ca: up to 0.015%.
  • the cold-rolled steel strip according to the invention is distinguished by r values of at least 1.3, with flat steel products according to the invention regularly achieving r values of greater than 1.3.
  • the high r-value stands for a good deep drawability of the cold-rolled steel flat product according to the invention, since with increasing r-value the tendency to thinning during deep-drawing is reduced and consequently stronger deep-drawing degrees are made possible. Otherwise there would be a risk of component failure at the thinned area.
  • a cold-rolled flat steel product according to the invention not only has high r values, but also reaches an elongation A50 of more than 18% on a regular basis. Steel flat products produced under optimum processing conditions have elongations A50 of 25% or more.
  • the ⁇ -carbide content of a flat steel product according to the invention is from 0% by volume (completely ⁇ -carbide-free state) to at most 0.1% by volume. Due to the minimized ⁇ -carbide content, the processability of the flat steel product according to the invention is reliably ensured.
  • a composite steel flat product according to the invention is further distinguished by the fact that the grains are globulitically pronounced in their microstructure.
  • the ratio of the grain length in the rolling direction to the grain width in the transverse direction of the band is generally less than 1.5, in particular less than 1.2. That is, the length of the grains is at most 50%, in particular at most 20%, greater than their width.
  • the steel according to the invention may contain a large number of further alloying elements in order to set certain properties.
  • the relevant elements are summarized in the group "Mn, Si, rare earth metal, Mo, Cr, Zr, V, W, Co, Ni, B, Cu, Ca, N".
  • Each of these optionally added alloying elements may be present in the steel according to the invention or completely absent, the respective element is also considered “not present” when it is present in the flat steel product according to the invention in an amount in which it is ineffective and therefore the production unavoidable impurities attributable to.
  • Aluminum is present in the steel of the present invention at levels of 6.5-12 wt%, with Al contents greater than 6.8 wt% being advantageous in view of the desired density reduction.
  • Typical Al contents of flat steel products according to the invention are in the range from 6.5 to 10% by weight, in particular from 6.8 to 9% by weight.
  • the presence of high Al contents reduces the density of the steel and significantly improves its corrosion and oxidation resistance.
  • A1 increases the tensile strength in these contents. Excessive contents of A1, however, can lead to a deterioration of the forming behavior, which is expressed in a decrease in the r value.
  • the Al content is limited to a maximum of 12 wt .-%.
  • An optimally balanced ratio of reduced density and processability arises when 6.5 to 10% by weight of Al, in particular at least 6.8% by weight of Al, are present in the steel according to the invention.
  • the C content is limited to at most 0.1% by weight in steel according to the invention, with C contents of 0.015-0.05% by weight, in particular 0.008-0.05% by weight, being particularly favorable.
  • C contents above 0.1 wt.% Can cause the formation of undesirable brittle kappa carbides ("K carbides”) at the grain boundaries and consequent reduction in hot and cold workability.
  • ⁇ -carbides Fe-Al-C compounds
  • ⁇ -carbides are formed in the Processing of generic steels early during hot processing at high temperatures on the grain boundaries and cause embrittlement of the material.
  • carbide-forming alloying elements in accordance with the invention, the lowest possible free C content is set, thus largely preventing the formation of ⁇ carbides.
  • 0.15-0.5% by weight of Ti and 0.1-0.2% by weight of Nb are present in the first place for this purpose.
  • the effect of titanium can then be used particularly reliably if the Ti content is 0.15-0.3% by weight.
  • niobium when Nb is present in amounts of 0.1-0.15% by weight in the steel according to the invention.
  • the respective contents of Ti and Nb must be adjusted in such a way that they fulfill the condition prescribed according to the invention for the ratio of these contents.
  • Ti and Nb contents which fulfill these requirements cause the formation of finely dispersed Ti and Nb carbides in the steel according to the invention, which promote the formation of a fine structure which supports the deformability of the flat steel product.
  • V, Zr and W are also effective carbide formers and In amounts of up to 1% by weight each can supplement the effect of the Nb and Ti required contents provided according to the invention.
  • the effect of V, Zr and W can be used particularly purposefully if their content is limited to in each case up to 0.5% by weight, in particular 0.3% by weight.
  • Mn By adding Mn in amounts of up to 1% by weight, in particular up to 0.5% by weight, the hot workability and weldability of the steel according to the invention can be improved.
  • Mn aids in deoxidation during melting and contributes to increasing the strength of the steel.
  • Mo can be present in amounts of up to 1% by weight in the steel according to the invention. Mo also forms carbides and contributes to increasing the tensile strength, creep resistance and fatigue strength of a flat steel product of the present invention.
  • the carbides formed by Mo with C are particularly fine and thus improve the fineness of the structure of the flat steel product according to the invention. High levels of Mo, however, degrade the hot and cold workability. In order to avoid this particularly reliably, the optionally present Mo content of a steel according to the invention can be limited to 0.5% by weight.
  • the S content to a maximum of 0.03 wt .-%, preferably at most 0.01 wt .-%, and the P content to a maximum 0.1 wt .-%, preferably at most 0.05 wt .-%, limited.
  • the N content of the flat steel product according to the invention is limited to at most 0.1% by weight, in particular at most 0.02% by weight, preferably at most 0.001% by weight, in order to avoid the formation of relatively large amounts of Al nitrides. These would degrade the mechanical properties.
  • the presence of rare earth metals in amounts of up to 0.2% by weight contributes to improved resistance to oxidation and increased strength of a flat steel product of the present invention.
  • contents of rare earth metals are desulfurizing and deoxidizing.
  • the oxides formed by the respective rare earth metals also have a fine grain and promote positive texture selection for improved technological properties.
  • Particularly suitable rare earth metals are Ce and La.
  • the positive influences of rare earth metals in the steel according to the invention can be used particularly purposefully if the contents of rare earth metals are in the range of up to 0.05% by weight.
  • the carbides formed by the presence of one or more of the elements Ti, Nb, V, Zr, W, Mo contribute to increasing the strength of the steel of the present invention.
  • Si in amounts of up to 2 wt .-%, in particular up to 0.5 wt .-%, supported in the melting also the deoxidation and increases the strength and corrosion resistance of the steel according to the invention. Too high levels are due to the presence of Si however, reduces the ductility of the steel and its weldability.
  • Typical Si contents of steels according to the invention are in the range of 0.1-0.5% by weight, in particular 0.1-0.2% by weight.
  • the Co content of the steel according to the invention is limited to max. 1 wt .-%, in particular max. 0.5% by weight, preferably max. 0.3% by weight, limited.
  • Ni improves the corrosion resistance and reduces the proportion of primary ferrite in the structure of the steel according to the invention.
  • Ni can be used in the steel according to the invention at levels of up to 0.5% by weight in a particularly practical manner.
  • the addition of B can also lead to the formation of a fine, the deformability of the steel according to the invention favoring structure. Too high levels of B, however, the cold workability and the Impair oxidation resistance. Therefore, the B content of the steel according to the invention is limited to 0.1% by weight, in particular up to 0.01% by weight, preferably 0.005% by weight.
  • Cu in amounts of up to 3% by weight improves corrosion resistance in the steel of the present invention, but at higher levels may also deteriorate hot workability and weldability. If present, therefore, the Cu content in a practical embodiment of the invention to at most 1 wt .-%, in particular 0.5 wt .-%, limited.
  • a waiting time of at least about 15 minutes should elapse between the last addition of alloy and the casting, in order to ensure thorough mixing of the molten steel.
  • Typical effluent temperatures are in the range of about 1590 ° C.
  • the hot strip is cold rolled to a degree of cold rolling of at least 65%, or a cold rolling degree of at least 65% is also achieved in the two- and multi-stage cold rolling after the intermediate annealing.
  • the two-stage cold rolling can be carried out in such a way that the degree of cold rolling in the first stage is at least 40% and the last stage at least 65%, in particular more than 70%, for example at least 80%.
  • the molten steels E1 and E2 have been cast into precursors in the form of blocks.
  • the blocks were then heated through a preheating of two hours in each case to a preheat temperature VWT and vorgeblockt to slabs.
  • the reheated slabs are hot rolled at a hot rolling end temperature WET to a hot strip and the resulting hot strip was wound at a reel temperature HT each to form a coil.
  • a cast strip was produced as a precursor via a two-roll strip caster, which was then also hot-rolled into a hot strip with a hot rolling end temperature WET.
  • the processing to the hot strip was carried out in a continuous process sequence without interruption following the strip casting, so that the precursor already had a temperature lying in the range of inventively predetermined preheating temperatures when entering the hot rolling device and the preheating could be omitted.
  • the hot strip produced from the steel E3 has been coiled after hot rolling at a reel temperature HT to form a coil.
  • the so annealed hot strips were cold rolled in one or two stages with cold rolling degrees KWG1 (cold rolling degree of the first cold rolling stage) and KWG2 (cold rolling degree of the respective second cold rolling stage) each to a cold rolled steel strip. If two-stage cold rolling has been used, an intermediate annealing at an intermediate annealing temperature ZGT is in each case between the cold rolling stages Have been carried out. After cold rolling, the cold-rolled steel flat products have undergone a final annealing at an annealing temperature SGT. The intermediate annealing and the final annealing have each been completed in continuous operation.
  • the respective preheat temperature VWT, hot rolling end temperature WET, coiler temperature HT, annealing temperature GT, the respective cold rolling degree KWG1, KWG2, and the respective intermediate annealing temperature ZGT and final annealing temperature SGT, are given in Table 2.
  • the cold-rolled steel strips produced from the steels E1 and E2 produced according to the invention in accordance with the invention have yield strengths which are regularly greater than 300 MPa, in particular greater than 320 MPa and thereby reach values of 380 MPa and more, and tensile strengths which are regularly greater 460 MPa, in particular greater than 480 MPa, while achieving values of 530 MPa and more, and having elongation values A50 of at least 18%, which regularly exceed 21%, in particular greater than 25%, and always have r values of 1 , 3 or greater.
  • Cold-rolled steel strips not assembled according to the invention do not achieve such r-values even if these steel strips have been produced taking into account production parameters that are closely related to the parameters set in the production of the cold-rolled steel flat products according to the invention. Also according to the invention composite, but not according to the invention processed flat steel products do not reach the properties of steel flat products produced according to the invention or can not even be cold-rolled.
  • the steel strips produced according to the invention have, despite their high Al contents, a superior deep-drawing capability, without the need for expensive alloying or process-engineering measures.
  • a flat steel product with optimum deformation properties (r ⁇ 2, n ⁇ 0.2, A50 ⁇ 30%) is achieved by a combination of alloy according to the invention, high degree of cold deformation and low hot rolling temperature (about 850 ° C).
  • the cold-rolled steel strips produced from the steels according to the invention in accordance with the invention contain, in addition to a Fe (Al) mixed-crystal matrix, locally occurring hardening precursor phase.
  • a Fe (Al) mixed-crystal matrix in standard hot rolling parameters, rolling is carried out in the full-ferrite phase region and hot strip with typical three-layer structure is obtained, which in turn is characterized by recrystallized globulitic margins and the only recovered core area with stem crystals is marked.
  • the hot strip annealing performed according to the invention reduces the dislocation density in the recovered area and facilitates subsequent cold rolling processing. Without the hot strip annealing, the alpha fiber texture component is strong but weak with hot strip annealing.
  • a low maximum cold rolling degree of up to 50% results in weak gamma fiber texture components
  • one-stage cold rolling with a high cold rolling degree of at least 65%, especially at least 80%, or two-stage cold rolling with correspondingly high deformation in the last rolling stage results in one strong gamma fiber component.
  • These dependencies are more pronounced at lower hot rolling end temperatures, which are in the range of 830-960 ° C, especially 840-880 ° C.
  • the deformation behavior of the resulting cold-rolled steel flat product is significantly influenced by the texture.
  • High r and n values as well as a high elongation at break A50 are particularly noticeable when the gamma fast texture component dominates over the alpha fiber texture component.
  • the inventively predetermined hot strip annealing and the inventively provided parameters of cold rolling ensure that this goal is achieved.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)
EP13155225.9A 2013-02-14 2013-02-14 Produit plat en acier laminé à froid pour applications d'emboutissage profond et son procédé de fabrication Active EP2767601B1 (fr)

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EP13155225.9A EP2767601B1 (fr) 2013-02-14 2013-02-14 Produit plat en acier laminé à froid pour applications d'emboutissage profond et son procédé de fabrication
PCT/EP2014/052810 WO2014125016A1 (fr) 2013-02-14 2014-02-13 Produit plat en acier laminé à froid pour emboutissage et son procédé de fabrication
JP2015557422A JP6383368B2 (ja) 2013-02-14 2014-02-13 深絞りを適用するための冷間圧延された平鋼製品及びそれを製造するための方法
US14/767,741 US10513762B2 (en) 2013-02-14 2014-02-13 Cold-rolled flat steel product for deep drawing applications and method for production thereof
KR1020157024979A KR102193066B1 (ko) 2013-02-14 2014-02-13 딥드로잉 적용을 위한 냉간압연 평강 제품 및 그 제조 방법
CN201910355506.7A CN110295317A (zh) 2013-02-14 2014-02-13 用于深冲应用的冷轧扁钢产品及其制造方法
BR112015019413A BR112015019413A2 (pt) 2013-02-14 2014-02-13 produto plano de aço laminado a frio para aplicações de estampagem e método para a sua produção
CN201480021223.4A CN105121673A (zh) 2013-02-14 2014-02-13 用于深冲应用的冷轧扁钢产品及其制造方法

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US20170002436A1 (en) * 2015-07-01 2017-01-05 Posco Ferritic lightweight steel sheet having excellent strength and ductility and method for manufacturing the same
WO2017021464A1 (fr) * 2015-08-05 2017-02-09 Salzgitter Flachstahl Gmbh Acier hautement résistant contenant du manganèse, utilisation de l'acier pour des produits plats en acier laminés flexibles et procédé de fabrication et produit plat en acier le concernant
DE102015116186A1 (de) 2015-09-24 2017-03-30 Thyssenkrupp Ag Halbzeug und Verfahren zur Herstellung einer Fahrzeugkomponente, Verwendung eines Halbzeugs und Fahrzeugkomponente
EP3225702A1 (fr) 2016-03-29 2017-10-04 Deutsche Edelstahlwerke GmbH Acier a epaisseur reduite et procede de fabrication d'un produit allonge ou plat en acier a partir d'un tel acier
WO2020078529A1 (fr) * 2018-10-15 2020-04-23 Thyssenkrupp Steel Europe Ag Procédé de fabrication d'une bande en acier électrique à grains non orientés dotée d'une épaisseur intermédiaire
US11970757B2 (en) 2018-11-08 2024-04-30 Thyssenkrupp Steel Europe Ag Electric steel strip or sheet for higher frequency electric motor applications, with improved polarization and low magnetic losses

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DE102014017274A1 (de) * 2014-11-18 2016-05-19 Salzgitter Flachstahl Gmbh Höchstfester lufthärtender Mehrphasenstahl mit hervorragenden Verarbeitungseigenschaften und Verfahren zur Herstellung eines Bandes aus diesem Stahl
CN107254636B (zh) * 2017-05-02 2019-02-22 嘉禾福顺机械实业有限公司 一种泵用合金钢材料及其制备方法
CN113584406A (zh) * 2021-07-14 2021-11-02 武汉钢铁有限公司 一种csp工艺生产的防火门板用钢及其制造方法

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Publication number Priority date Publication date Assignee Title
US20170002436A1 (en) * 2015-07-01 2017-01-05 Posco Ferritic lightweight steel sheet having excellent strength and ductility and method for manufacturing the same
WO2017021464A1 (fr) * 2015-08-05 2017-02-09 Salzgitter Flachstahl Gmbh Acier hautement résistant contenant du manganèse, utilisation de l'acier pour des produits plats en acier laminés flexibles et procédé de fabrication et produit plat en acier le concernant
DE102015116186A1 (de) 2015-09-24 2017-03-30 Thyssenkrupp Ag Halbzeug und Verfahren zur Herstellung einer Fahrzeugkomponente, Verwendung eines Halbzeugs und Fahrzeugkomponente
WO2017050558A1 (fr) 2015-09-24 2017-03-30 Thyssenkrupp Steel Europe Ag Produit semi-fini et procédé de fabrication d'un élément de véhicule, utilisation d'un produit semi-fini et élément de véhicule
EP3225702A1 (fr) 2016-03-29 2017-10-04 Deutsche Edelstahlwerke GmbH Acier a epaisseur reduite et procede de fabrication d'un produit allonge ou plat en acier a partir d'un tel acier
WO2017167778A1 (fr) 2016-03-29 2017-10-05 Deutsche Edelstahlwerke Specialty Steel Gmbh & Co. Kg Acier de masse volumique réduite et procédé de fabrication d'un produit acier plat ou d'un produit acier allongé réalisé dans un acier de ce type
WO2020078529A1 (fr) * 2018-10-15 2020-04-23 Thyssenkrupp Steel Europe Ag Procédé de fabrication d'une bande en acier électrique à grains non orientés dotée d'une épaisseur intermédiaire
US11970757B2 (en) 2018-11-08 2024-04-30 Thyssenkrupp Steel Europe Ag Electric steel strip or sheet for higher frequency electric motor applications, with improved polarization and low magnetic losses

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BR112015019413A2 (pt) 2017-07-18
CN105121673A (zh) 2015-12-02
KR102193066B1 (ko) 2020-12-21
WO2014125016A1 (fr) 2014-08-21
US10513762B2 (en) 2019-12-24
JP2016511795A (ja) 2016-04-21
US20160017467A1 (en) 2016-01-21
EP2767601B1 (fr) 2018-10-10
JP6383368B2 (ja) 2018-08-29
CN110295317A (zh) 2019-10-01
KR20150119230A (ko) 2015-10-23

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