EP2746428B1 - Revêtement de composants de turbine - Google Patents
Revêtement de composants de turbine Download PDFInfo
- Publication number
- EP2746428B1 EP2746428B1 EP13196979.2A EP13196979A EP2746428B1 EP 2746428 B1 EP2746428 B1 EP 2746428B1 EP 13196979 A EP13196979 A EP 13196979A EP 2746428 B1 EP2746428 B1 EP 2746428B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- filler
- turbine
- steam
- blades
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000576 coating method Methods 0.000 title claims description 59
- 239000011248 coating agent Substances 0.000 title claims description 49
- 239000000945 filler Substances 0.000 claims description 31
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- -1 polysiloxane Polymers 0.000 claims description 17
- 229920001296 polysiloxane Polymers 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 230000003628 erosive effect Effects 0.000 claims description 13
- 239000011159 matrix material Substances 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 238000007747 plating Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000002209 hydrophobic effect Effects 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 239000002131 composite material Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 102220043159 rs587780996 Human genes 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910003828 SiH3 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- SKKMWRVAJNPLFY-UHFFFAOYSA-N azanylidynevanadium Chemical compound [V]#N SKKMWRVAJNPLFY-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/54—Contact plating, i.e. electroless electrochemical plating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1655—Process features
- C23C18/1662—Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1689—After-treatment
- C23C18/1692—Heat-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/027—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal matrix material comprising a mixture of at least two metals or metal phases or metal matrix composites, e.g. metal matrix with embedded inorganic hard particles, CERMET, MMC.
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
- C25D5/50—After-treatment of electroplated surfaces by heat-treatment
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/30—Manufacture with deposition of material
- F05D2230/31—Layer deposition
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/80—Repairing, retrofitting or upgrading methods
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Definitions
- the invention relates to the coating of turbine parts, particularly the blades of a low-pressure steam turbine, and to a long-lasting coating with hydrophobic properties for such parts.
- turbine is used to refer to rotary engines having a stator and a rotating part force coupled by a fluid medium such as water or gas.
- a fluid medium such as water or gas.
- axial turbines comprising radially arranged fixed stator blades or vanes alternating with radially arrangements of moving rotor blades. Movements are generally registered as movements relative to a casing or housing.
- the pressurized steam is typically expanded across several stages of the turbine, respectively referred to as high pressure, intermediate pressure and low pressure stage of the turbine.
- the steam In the low pressure stage the steam is expanded and cooled close to a point of condensation and exhausted into a condenser.
- the relative wetness of the steam at the last stage of the low pressure stage may result in droplet erosion and other potential sources of performance losses as well as material degradation due to water droplet impact, requiring a need for additional spare parts to be exchanged.
- the expansion of the turbine steam in a low-pressure turbine to condenser pressure usually results in a range for wet steam.
- the mass content of the condensation water in the wet waste steam can be up to 14%.
- the impulse of the entire mass stream of the turbine steam is preserved, independently from the condensation water content.
- the presence of a liquid phase in the rotating and stationary elements of the turbines may result in increased dissipative losses.
- about 12-14% of the mass stream can be generated in the form of water.
- This moisture loss can result in a loss of efficiency of the low-pressure turbine of approximately 6-7%, which corresponds to a loss of efficiency of approximately 1-2% of an entire steam power plant.
- the contribution of power of the low-pressure turbine in relation to the overall plant power is slightly higher by comparison, so that the loss in overall efficiency due to moisture losses may be between 2-2.3% or 3-3.5% overall.
- protective layers are described for example in the published United States patent application US 2008/0152506 A1 and the published international patent applications WO 2011/039075 A1 and WO 2010/066648 .
- coatings and methods are described including the use of hydrophobically activated particles incorporated into a polymeric coating material wherein the coating servers as a matrix to bind the particles to an underlying substrate.
- a method according to claim 1 forms a coating with hydrophobic filler whose properties can be adjusted to withstand the working temperature.
- hydrophobic filler being a polysiloxane that is stoveable to achieve a required temperature resistance/ hydrophobicity balance.
- An aspect provides a coating for axially rotating machine part that in use is subject to water laden gas, the coating having a metal matrix with polysiloxane filler.
- the coating is a metal matrix material comprising Nickel or alloys thereof.
- filler include fibrous, platelets, spheres or other particle shapes.
- the filler comprises preferably between 5 to 50 volume % of the coating, more preferably between 25 to 45 volume % and most preferably between 35 to 45 volume percent of the coating.
- the coating has a corrosion resistant inner layer free of filler and the metal matrix of other aspects forms an outer layer of coating.
- the part is an airfoil of a steam turbine.
- the part is an airfoil of a gas compressor of a gas turbine.
- the method of coating includes the process of electrolytic nickel plating.
- the thickness of a layer of the metal matrix on a substrate is typically in the range of 10- 300 microns.
- the substrate or base material to which the coating is applied can include carbon steels, chromium nickel steels, titanium based materials and composite materials. These materials are used for example in static and rotating vanes or blades for turbines, which can be larger in height than 1m.
- the coating of various embodiments of this invention allows local restoration of the coating following in service erosion without removal in either a mounted or a dismounted state and thus provides a simple and cost effective solution.
- Hydrophilic is defined as a material with a contact angle, as measured by the static sessile drop method, between a solid surface of the material and a water droplet of greater than 90 degrees.
- Siloxanes are defined as a functional group in organic silicon chemistry that has a Si-O-Si linkage.
- Siloxanes include polymeric hydrides, referred to as silicones or polysiloxanes that have the formulae H3-Si-[O-SiH2]n-O-SiH3 wherein hydrogen atoms may be substituted by halogens or organic groups.
- the temperature resistance of specific polysiloxanes can be varied by varying the degree of cross linking and pyrolysis/ hydrolysis in which there is a successive replacement of carbon containing end groups with oxygen to form SiO2.
- the result is an increase in the ceramic (SiO2) to organic ratio of the polysiloxane which increases the temperature resistance but typically has a detrimental effect on hydrophobicity.
- Fig. 1 shows a coating 10 of an exemplary embodiment a of coating 10 that at least partially coats an axially rotating machine part 20 and is subject to water droplet impact, wherein the coating 10 comprises a metal matrix 12 having polysiloxane distributed filler 14.
- Such plants include steam turbine plants and axial flow compressors that are part of a gas turbine plant, in particular gas turbine plants that are configured with water injection means upstream of the compressor.
- the suitability of the coating 10 for axial rotating machines is a result of the coating's 10 erosion resistance, temperature resilience and pH tolerance. For this reason exemplary embodiment are particular suitable for use in either steam turbines or compressors.
- the invention is not however limited to these machines and may alternatively be used in any high temperature moist environments where the coating 10 is required to provide erosion protection through hardness and temperature resistance and hydrophobic properties by the incorporation of hydrophobic filler.
- An effect of the filler 14 being homogenously distributed in the coating 10 is that this ensures that during the inevitable erosion of the coating, which occur in the aggressive environments of steam turbines and compressors in regions where moisture is present despite materials, such as like Titanium and Nickel alloys, the problem of erosion still exists.
- the filler 14 may be fibrous, have a platelet, spherical or other shape.
- the loading of the metal matrix 12 is in the range of 5 to 50 vol%, preferably in the range of 25 to 45 vol%, most preferably in the range of 35 to 45 vol%.
- the coating includes more than one type of filler 14, wherein the definition of type includes shape, size, material and degree of crosslinking/pyrolysis/hydrolysis.
- the coating 10 includes an erosion resistant inner layer 16 and an outer layer 12, wherein the inner layer 16 is sandwiched between the outer layer 12 and the machine part 20.
- a purpose of the inner layer 16 is to protect the machine part 20 in the case of erosion of the outer layer 12.
- the filler 14 are spherical particles, flake shaped particles, a combination of spherical and flaked shaped particles.
- the coating 10 may be applied to the machine part 20, or alternatively the inner layer 16, using a Electrolytic Nickel- Phosphorus coating method using a method adapted from the known electrolytic Ni-P- PTFE coating method described, for example, in " Chemisches Vernickeln", author: N. Kanani, E.G. Leuze Verlag 2007 (ISBN 978-3-87480-229-1) pg. 510-513 .
- the method includes the process steps of chemically reducing Nickel in a reducing agent in which filler 14 particles are homogenously suspended with the assistance of a wetting agent. In this way, filler 14 particles are homogenously distributed within the Nickel coating 10 as it is deposited on the machine part 20.
- the coating 10 is be applied my means of chemical electroless Nickel plating, as is known in the art.
- the coating 10 is applied using a multi- layer principle in which layers are applied by different methods, for example either chemical electroless Nickel plating and Electrolytic Nickel coating.
- a coating containing polysiloxane filler 14 controlled stoving is used to tailor the filler temperature resistance/ hydrophobic properties.
- the actual stoving temperature required is not uniform but instead needs to be matched to the required end use of the coating in consideration of the presence of catalytic substances such as acids, tin and titanium compounds that affect he degree of crosslinking/ pyrolysis/hydrolysis and the actual composition and form of the polysiloxane.
- a particular advantage of the tailoring of polysiloxanes compared to alternative polymeric hydrophobic filler 14 is that the tailoring makes it possible to produce coatings with polymeric hydrophobic fillers particles that are suitable for application where temperatures exceed 400°C or even 500°C.
- the method entails stoving a component have a coating containing a filler 14 of polysiloxane particles such that the temperature resistance of the filler 14 is increased.
- this is done after the filler 14 is embedded into the metal matrix 12, for example, during heat treatment of the machine part 20, carried out, for example, for the purpose of improving the adhesion properties of the coating to the machine part 20.
- the stoving step is completed before embedding the filler 14 into the metal matrix 12. This may be done, for example when the stoving step significantly changes the density of the filler 14. In this way, any shrinkage of the filler 14 as a result of pyrolysis occurs before it is embedded in the metal matrix 12.
- Such coatings 10 and method can advantageously be used in steam turbine coatings, in particularly low pressure steam turbines as a fog rejecting coating 10 in order to lower/ avoid losses caused by condensation of steam.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Claims (4)
- Procédé de revêtement d'une pièce (20) pour une machine à rotation axiale avec un revêtement (10) de résistance à l'érosion et, le procédé comprenant les étapes suivantes :- prévoir une pièce (20) d'une machine à rotation axiale ;- revêtir la pièce (20) avec un revêtement (10) comprenant une matrice métallique (12) avec une charge de polysiloxane (14) répartie dans l'ensemble d'une épaisseur de la matrice métallique (12) ; et- étuver la charge (14) de façon à modifier la résistance thermique de la charge de polysiloxane (14) .
- Procédé selon la revendication 1, dans lequel l'étuvage avant l'étape de revêtement de la pièce (20) .
- Procédé selon la revendication 1, dans lequel l'étape d'étuvage est effectuée après l'étape de revêtement.
- Procédé selon la revendication 1, dans lequel le procédé de revêtement comprend l'électroplacage au nickel et/ou le revêtement par dépôt autocatalytique.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13196979.2A EP2746428B1 (fr) | 2012-12-20 | 2013-12-12 | Revêtement de composants de turbine |
US14/135,764 US20140178699A1 (en) | 2012-12-20 | 2013-12-20 | Coatings for turbine parts |
US15/046,533 US10865481B2 (en) | 2012-12-20 | 2016-02-18 | Coatings for turbine parts |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12198707 | 2012-12-20 | ||
EP13196979.2A EP2746428B1 (fr) | 2012-12-20 | 2013-12-12 | Revêtement de composants de turbine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2746428A1 EP2746428A1 (fr) | 2014-06-25 |
EP2746428B1 true EP2746428B1 (fr) | 2017-09-13 |
Family
ID=47561187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13196979.2A Active EP2746428B1 (fr) | 2012-12-20 | 2013-12-12 | Revêtement de composants de turbine |
Country Status (4)
Country | Link |
---|---|
US (2) | US20140178699A1 (fr) |
EP (1) | EP2746428B1 (fr) |
CN (1) | CN103879084B (fr) |
RU (1) | RU2605872C2 (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2746428B1 (fr) * | 2012-12-20 | 2017-09-13 | General Electric Technology GmbH | Revêtement de composants de turbine |
DE102014215082A1 (de) * | 2014-07-31 | 2016-02-04 | Siemens Aktiengesellschaft | Laufschaufel für eine Dampfturbine |
WO2018106539A1 (fr) | 2016-12-05 | 2018-06-14 | Cummins Filtration Ip, Inc. | Ensemble de séparation comprenant une turbine à impulsion en une seule pièce |
WO2018129438A1 (fr) | 2017-01-09 | 2018-07-12 | Cummins Filtration Ip, Inc. | Turbine à impulsions avec surface non mouillante pour une efficacité hydraulique améliorée |
WO2019103799A1 (fr) * | 2017-11-21 | 2019-05-31 | Bl Technologies, Inc. | Amélioration du rendement d'une centrale à vapeur avec de nouveaux traitements de cycle de vapeur |
US12030063B2 (en) | 2018-02-02 | 2024-07-09 | Cummins Filtration Ip, Inc. | Separation assembly with a single-piece impulse turbine |
WO2019204265A1 (fr) | 2018-04-17 | 2019-10-24 | Cummins Filtration Ip, Inc. | Ensemble de séparation comprenant une turbine à impulsion à deux pièces |
IT201900003463A1 (it) * | 2019-03-11 | 2020-09-11 | Nuovo Pignone Tecnologie Srl | Componente di turbomacchine avente un rivestimento metallico |
FR3095969B1 (fr) * | 2019-05-17 | 2021-04-23 | Renault Sas | Couche de protection comprenant du nitrure de phosphore et du polytétrafluoroéthylène, procédé de fabrication associée et roue de compresseur munie d’une telle couche. |
US11225876B2 (en) | 2019-12-19 | 2022-01-18 | Raytheon Technologies Corporation | Diffusion barrier to prevent super alloy depletion into nickel-CBN blade tip coating |
Citations (1)
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US20100247321A1 (en) * | 2008-01-08 | 2010-09-30 | General Electric Company | Anti-fouling coatings and articles coated therewith |
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SU1027181A1 (ru) * | 1982-04-09 | 1983-07-07 | Ленинградский Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета | Состав дл покрыти по металлу |
DE19644692A1 (de) | 1996-10-28 | 1998-04-30 | Abb Patent Gmbh | Beschichtung sowie ein Verfahren zu deren Herstellung |
DE10056241B4 (de) * | 2000-11-14 | 2010-12-09 | Alstom Technology Ltd. | Niederdruckdampfturbine |
US6638572B1 (en) * | 2001-06-27 | 2003-10-28 | Charles F. Inglefield | Heat resistant material for molds and other articles |
US6905730B2 (en) * | 2003-07-08 | 2005-06-14 | General Electric Company | Aluminide coating of turbine engine component |
DK1611175T3 (da) | 2004-02-13 | 2006-07-31 | Total Petrochemicals Res Feluy | Katalysatorkornstörrelse |
US7150904B2 (en) | 2004-07-27 | 2006-12-19 | Ut-Battelle, Llc | Composite, ordered material having sharp surface features |
US8088440B2 (en) | 2004-11-24 | 2012-01-03 | Guardian Industries Corp. | Hydrophobic coating including underlayer(s) deposited via flame pyrolysis |
JPWO2006059719A1 (ja) * | 2004-12-03 | 2008-06-05 | 株式会社カネカ | シリコーン系重合体粒子およびそれを含有するシリコーン系組成物 |
JP4886271B2 (ja) | 2005-10-31 | 2012-02-29 | 株式会社東芝 | 蒸気タービンおよびその親水性コーティング材料 |
EP1870485A1 (fr) * | 2006-06-22 | 2007-12-26 | Siemens Aktiengesellschaft | Composition et méthode de métallisation d'un composant |
US8202614B2 (en) | 2006-08-09 | 2012-06-19 | Luna Innovations Incorporated | Additive particles having superhydrophobic characteristics and coatings and methods of making and using the same |
DE102006044956A1 (de) | 2006-09-22 | 2008-04-03 | Reiss, Harald, Prof. Dr. Dr. habil. | Oberflächenbeschichtung gegen Tropfenschlagerosion |
DE102006052303B4 (de) * | 2006-11-03 | 2012-07-12 | Eads Deutschland Gmbh | Schutz von erosionsbelasteten Luftfahrtstrukturen durch nanopartikelverstärkte anorganisch-organische Hybridbeschichtungen |
DE102006061916A1 (de) | 2006-12-21 | 2008-06-26 | Rolls-Royce Deutschland Ltd & Co Kg | Fanschaufel für ein Gasturbinentriebwerk |
DE102008054596B4 (de) | 2008-12-12 | 2011-04-14 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Offenzellige Keramik- und/oder Metallschaumkörper mit rauer umhüllender Oberfläche und Verfahren zu ihrer Herstellung |
IT1393140B1 (it) * | 2009-03-17 | 2012-04-11 | Nuovo Pignone Spa | Metodo di produzione di un rivestimento protettivo per un componente di una turbomacchina, il componente stesso e la relativa macchina |
IT1397705B1 (it) * | 2009-07-15 | 2013-01-24 | Nuovo Pignone Spa | Metodo di produzione di uno strato di rivestimento per un componente di una turbomacchina, il componente stesso e la relativa macchina |
DE102009047798A1 (de) | 2009-09-30 | 2011-04-14 | Siemens Aktiengesellschaft | Turbinenschaufel, insbesondere Endstufenlaufschaufel für eine Dampfturbine |
US20110165433A1 (en) * | 2010-01-06 | 2011-07-07 | General Electric Company | Erosion and corrosion resistant coating system for compressor |
EP2746428B1 (fr) * | 2012-12-20 | 2017-09-13 | General Electric Technology GmbH | Revêtement de composants de turbine |
-
2013
- 2013-12-12 EP EP13196979.2A patent/EP2746428B1/fr active Active
- 2013-12-19 RU RU2013156624/02A patent/RU2605872C2/ru not_active Application Discontinuation
- 2013-12-20 US US14/135,764 patent/US20140178699A1/en not_active Abandoned
- 2013-12-20 CN CN201310707883.5A patent/CN103879084B/zh active Active
-
2016
- 2016-02-18 US US15/046,533 patent/US10865481B2/en active Active
Patent Citations (1)
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US20100247321A1 (en) * | 2008-01-08 | 2010-09-30 | General Electric Company | Anti-fouling coatings and articles coated therewith |
Also Published As
Publication number | Publication date |
---|---|
CN103879084A (zh) | 2014-06-25 |
US20140178699A1 (en) | 2014-06-26 |
CN103879084B (zh) | 2016-03-09 |
US20160160354A1 (en) | 2016-06-09 |
EP2746428A1 (fr) | 2014-06-25 |
US10865481B2 (en) | 2020-12-15 |
RU2605872C2 (ru) | 2016-12-27 |
RU2013156624A (ru) | 2015-06-27 |
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