US20140178699A1 - Coatings for turbine parts - Google Patents

Coatings for turbine parts Download PDF

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Publication number
US20140178699A1
US20140178699A1 US14/135,764 US201314135764A US2014178699A1 US 20140178699 A1 US20140178699 A1 US 20140178699A1 US 201314135764 A US201314135764 A US 201314135764A US 2014178699 A1 US2014178699 A1 US 2014178699A1
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US
United States
Prior art keywords
coating
filler
metal matrix
particles
turbine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/135,764
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English (en)
Inventor
Thomas Widmer
Sven Olliges
Alexander Stankowski
Piero-Daniele Grasso
Mauro MELAS
Thomas Baumann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Technology GmbH
Original Assignee
Alstom Technology AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alstom Technology AG filed Critical Alstom Technology AG
Assigned to ALSTOM TECHNOLOGY LTD reassignment ALSTOM TECHNOLOGY LTD ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: Melas, Mauro, BAUMANN, THOMAS, GRASSO, PIERO-DANIELE, Olliges, Sven, STANKOWSKI, ALEXANDER, WIDMER, THOMAS
Publication of US20140178699A1 publication Critical patent/US20140178699A1/en
Priority to US15/046,533 priority Critical patent/US10865481B2/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/54—Contact plating, i.e. electroless electrochemical plating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1655—Process features
    • C23C18/1662—Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1689—After-treatment
    • C23C18/1692—Heat-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/027—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal matrix material comprising a mixture of at least two metals or metal phases or metal matrix composites, e.g. metal matrix with embedded inorganic hard particles, CERMET, MMC.
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48—After-treatment of electroplated surfaces
    • C25D5/50—After-treatment of electroplated surfaces by heat-treatment
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12—Blades
    • F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • F01D5/288—Protective coatings for blades
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
    • C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00—Manufacture
    • F05D2230/30—Manufacture with deposition of material
    • F05D2230/31—Layer deposition
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00—Manufacture
    • F05D2230/80—Repairing, retrofitting or upgrading methods
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00—Aeronautics or air transport
    • Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

Definitions

  • the invention relates to the coating of turbine parts, particularly the blades of a low-pressure steam turbine, and to a long-lasting coating with hydrophobic properties for such parts.
  • turbine is used to refer to rotary engines having a stator and a rotating part force coupled by a fluid medium such as water or gas.
  • a fluid medium such as water or gas.
  • axial turbines comprising radially arranged fixed stator blades or vanes alternating with radially arrangements of moving rotor blades. Movements are generally registered as movements relative to a casing or housing.
  • the pressurized steam is typically expanded across several stages of the turbine, respectively referred to as high pressure, intermediate pressure and low pressure stage of the turbine.
  • the steam In the low pressure stage the steam is expanded and cooled close to a point of condensation and exhausted into a condenser.
  • the relative wetness of the steam at the last stage of the low pressure stage may result in droplet erosion and other potential sources of performance losses as well as material degradation due to water droplet impact, requiring a need for additional spare parts to be exchanged.
  • the expansion of the turbine steam in a low-pressure turbine to condenser pressure usually results in a range for wet steam.
  • the mass content of the condensation water in the wet waste steam can be up to 14%.
  • the impulse of the entire mass stream of the turbine steam is preserved, independently from the condensation water content.
  • the presence of a liquid phase in the rotating and stationary elements of the turbines may result in increased dissipative losses.
  • about 12-14% of the mass stream can be generated in the form of water.
  • This moisture loss can result in a loss of efficiency of the low-pressure turbine of approximately 6-7%, which corresponds to a loss of efficiency of approximately 1-2% of an entire steam power plant.
  • the contribution of power of the low-pressure turbine in relation to the overall plant power is slightly higher by comparison, so that the loss in overall efficiency due to moisture losses may be between 2-2.3% or 3-3.5% overall.
  • protective layers are described for example in the published United States patent application US 2008/0152506 A1 and the published international patent applications WO 2011/039075 A1 and WO 2010/066648.
  • a coating with hydrophobic filler whose properties can be adjusted to withstand the working temperature. This is general achieved by the hydrophobic filler being a polysiloxane that is stoveable to achieve a required temperature resistance/hydrophobicity balance.
  • An aspect provides a coating for axially rotating machine part that in use is subject to water laden gas, the coating having a metal matrix with poly-siloxane filler.
  • the coating is a metal matrix material comprising Nickel or alloys thereof.
  • filler 14 include fibrous, platelets, spheres or other particle shapes.
  • the filler comprises preferably between 5 to 50 volume % of the coating, more preferably between 25 to 45 volume % and most preferably between 35 to 45 volume percent of the coating.
  • the coating has a corrosion resistant inner layer free of filler and the metal matrix of other aspects forms an outer layer of coating.
  • the part is an airfoil of a steam turbine.
  • the part is an airfoil of a gas compressor of a gas turbine.
  • An aspect provides a method for coating a part for an axially rotating machine a coating with erosion resilience and hydrophobic properties, the method including the steps of:
  • the method of coating includes the process of electrolytic nickel plating.
  • the thickness of a layer of the metal matrix on a substrate is typically in the range of 10-300 microns.
  • the substrate or base material to which the coating is applied can include carbon steels, chromium nickel steels, titanium based materials and composite materials. These materials are used for example in static and rotating vanes or blades for turbines, which can be larger in height than 1 m.
  • the coating of various embodiments of this invention allows local restoration of the coating following in service erosion without removal in either a mounted or a dismounted state and thus provides a simple and cost effective solution.
  • FIG. 1 presents a cut view of a steam turbine part showing a coating of an exemplary embodiment of the invention
  • FIG. 2 is a cut view of the part and coating of FIG. 1 further including an inner and an outer coating layer;
  • FIG. 3 Is a cut view of the part and coating of FIG. 2 further including a filler.
  • “Hydrophobic” is defined as a material with a contact angle, as measured by the static sessile drop method, between a solid surface of the material and a water droplet of greater than 90 degrees.
  • Siloxanes are defined as a functional group in organic silicon chemistry that has a Si—O—Si linkage.
  • Siloxanes include polymeric hydrides, referred to as silicones or polysiloxanes that have the formulae H3—Si—[O—SiH2]n—O—SiH3 wherein hydrogen atoms may be substituted by halogens or organic groups.
  • the temperature resistance of specific polysiloxanes can be varied by varying the degree of cross linking and pyrolysis/hydrolysis in which there is a successive replacement of carbon containing end groups with oxygen to form SiO2.
  • the result is an increase in the ceramic (SiO2) to organic ratio of the polysiloxane which increases the temperature resistance but typically has a detrimental effect on hydrophobicity.
  • FIG. 1 shows a coating 10 of an exemplary embodiment a of coating 10 that at least partially coats an axially rotating machine part 20 subject to water droplet impact, wherein the coating 10 comprises a metal matrix 12 having polysiloxane distributed filler 14 .
  • Such plants include steam turbine plants and axial flow compressors that are part of a gas turbine plant, in particular gas turbine plants that are configured with water injection means upstream of the compressor.
  • the suitability of the coating 10 for axial rotating machines is a result of the coating's 10 erosion resistance, temperature resilience and pH tolerance. For this reason exemplary embodiment are particular suitable for use in either steam turbines or compressors.
  • the invention is not however limited to these machines and may alternatively be used in any high temperature moist environments where the coating 10 is required to provide erosion protection through hardness and temperature resistance and hydrophobic properties by the incorporation of hydrophobic filler particles.
  • An effect of the filler 14 being homogenously distributed in the coating 10 is that this ensures that during the inevitable erosion of the coating, which occur in the aggressive environments of steam turbines and compressors in regions where moisture is present despite materials, such as like Titanium and Nickel alloys, the problem of erosion still exists.
  • the filler 14 may be fibrous, have a platelet, spherical or other shape.
  • the loading of the metal matrix 12 is in the range of 5 to 50 vol %, preferably in the range of 25 to 45 vol %, most preferably in the range of 35 to 45 vol %.
  • the coating includes more than one type of filler 14 , wherein the definition of type includes shape, size, material and degree of crosslinking/pyrolysis/hydrolysis.
  • the coating 10 includes an erosion resistant inner layer 16 and an outer layer 12 , wherein the inner layer 16 is sandwiched between the outer layer 12 and the machine part 20 .
  • a purpose of the inner layer 16 is to protect the machine part 20 in the case of erosion of the outer layer 12 .
  • the particles may be spherical particles, flake shaped particles, a combination of spherical and flaked shaped particles.
  • the coating 10 may be applied to the machine part 20 , or alternatively the inner layer 16 , using a Electrolytic Nickel-Phosphorus coating method using a method adapted from the known electrolytic Ni—P-PTFE coating method described, for example, in “Chemisches Vernickeln”, author: N. Kanani, E. G. Leuze Verlag 2007 (ISBN 978-3-87480-229-1) pg. 510-513.
  • the method includes the process steps of chemically reducing Nickel in a reducing agent in which filler 14 particles are homogenously suspended with the assistance of a wetting agent. In this way, filler 14 particles are homogenously distributed within the Nickel coating 10 as it is deposited on the machine part 20 .
  • the coating 10 is be applied my means of chemical electroless Nickel plating, as is known in the art.
  • the coating 10 is applied using a multi-layer principle in which layers are applied by different methods, for example either chemical electroless Nickel plating and Electrolytic Nickel coating.
  • a coating containing poly-siloxane filler 14 controlled stoving is used to tailor the filler temperature resistance/hydrophobic properties.
  • the actual stoving temperature required is not uniform but instead needs to be matched to the required end use of the coating in consideration of the presence of catalytic substances such as acids, tin and titanium compounds that affect he degree of crosslinking/pyrolysis/hydrolysis and the actual composition and form of the polysiloxane.
  • a particular advantage of the tailoring of polysiloxanes compared to alternative polymeric hydrophobic filler 14 is that the tailoring makes it possible to produce coatings with polymeric hydrophobic fillers particles that are suitable for application where temperatures exceed 400° C. or even 500° C.
  • the method entails stoving a component have a coating containing a filler of polysiloxane particles such that the temperature resistance of the filler is increased.
  • this is done after the filler 14 is embedded into the metal matrix 12 , for example, during heat treatment of the machine part 20 , carried out, for example, for the purpose of improving the adhesion properties of the coating to the machine part 20 .
  • the stoving step is completed before embedding the filler 14 into the metal matrix 12 . This may be done, for example when the staving step significantly changes the density of the filler 14 . In this way, any shrinkage of the filler 14 as a result of pyrolysis occurs before it is embedded in the metal matrix 12 .
  • Such coatings and method can advantageously be used in steam turbine coatings, in particularly low pressure steam turbines as a fog rejecting coating in order to lower/avoid losses caused by condensation of steam.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
US14/135,764 2012-12-20 2013-12-20 Coatings for turbine parts Abandoned US20140178699A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US15/046,533 US10865481B2 (en) 2012-12-20 2016-02-18 Coatings for turbine parts

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP12198707.7 2012-12-20
EP12198707 2012-12-20
EP13196979.2 2013-12-12
EP13196979.2A EP2746428B1 (fr) 2012-12-20 2013-12-12 Revêtement de composants de turbine

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US15/046,533 Division US10865481B2 (en) 2012-12-20 2016-02-18 Coatings for turbine parts

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EP (1) EP2746428B1 (fr)
CN (1) CN103879084B (fr)
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10865481B2 (en) * 2012-12-20 2020-12-15 General Electric Technology Gmbh Coatings for turbine parts
EP3839096A1 (fr) * 2019-12-19 2021-06-23 Raytheon Technologies Corporation Barrière de diffusion pour empêcher la déplétion du super alliage dans le revêtement des pointes de lame en nickel-cbn

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014215082A1 (de) * 2014-07-31 2016-02-04 Siemens Aktiengesellschaft Laufschaufel für eine Dampfturbine
DE112017006146T5 (de) 2016-12-05 2019-08-22 Cummins Filtration Ip, Inc. Trennbaugruppe mit einer einteiligen impulsturbine
WO2018129438A1 (fr) 2017-01-09 2018-07-12 Cummins Filtration Ip, Inc. Turbine à impulsions avec surface non mouillante pour une efficacité hydraulique améliorée
US11261762B2 (en) 2017-11-21 2022-03-01 Bl Technologies, Inc. Improving steam power plant efficiency with novel steam cycle treatments
EP3781289A4 (fr) 2018-04-17 2021-12-29 Cummins Filtration IP, Inc. Ensemble de séparation comprenant une turbine à impulsion à deux pièces
IT201900003463A1 (it) * 2019-03-11 2020-09-11 Nuovo Pignone Tecnologie Srl Componente di turbomacchine avente un rivestimento metallico
FR3095969B1 (fr) * 2019-05-17 2021-04-23 Renault Sas Couche de protection comprenant du nitrure de phosphore et du polytétrafluoroéthylène, procédé de fabrication associée et roue de compresseur munie d’une telle couche.

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6638572B1 (en) * 2001-06-27 2003-10-28 Charles F. Inglefield Heat resistant material for molds and other articles
US20100247321A1 (en) * 2008-01-08 2010-09-30 General Electric Company Anti-fouling coatings and articles coated therewith

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1027181A1 (ru) * 1982-04-09 1983-07-07 Ленинградский Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета Состав дл покрыти по металлу
DE19644692A1 (de) 1996-10-28 1998-04-30 Abb Patent Gmbh Beschichtung sowie ein Verfahren zu deren Herstellung
DE10056241B4 (de) * 2000-11-14 2010-12-09 Alstom Technology Ltd. Niederdruckdampfturbine
US6905730B2 (en) * 2003-07-08 2005-06-14 General Electric Company Aluminide coating of turbine engine component
EA009506B1 (ru) 2004-02-13 2008-02-28 Тотал Петрокемикалс Рисерч Фелюй Катализатор
US7150904B2 (en) 2004-07-27 2006-12-19 Ut-Battelle, Llc Composite, ordered material having sharp surface features
US8088440B2 (en) 2004-11-24 2012-01-03 Guardian Industries Corp. Hydrophobic coating including underlayer(s) deposited via flame pyrolysis
WO2006059719A1 (fr) * 2004-12-03 2006-06-08 Kaneka Corporation Particule polymere a la silicone et composition de silicone la contenant
JP4886271B2 (ja) 2005-10-31 2012-02-29 株式会社東芝 蒸気タービンおよびその親水性コーティング材料
EP1870485A1 (fr) * 2006-06-22 2007-12-26 Siemens Aktiengesellschaft Composition et méthode de métallisation d'un composant
US8202614B2 (en) 2006-08-09 2012-06-19 Luna Innovations Incorporated Additive particles having superhydrophobic characteristics and coatings and methods of making and using the same
DE102006044956A1 (de) 2006-09-22 2008-04-03 Reiss, Harald, Prof. Dr. Dr. habil. Oberflächenbeschichtung gegen Tropfenschlagerosion
DE102006052303B4 (de) * 2006-11-03 2012-07-12 Eads Deutschland Gmbh Schutz von erosionsbelasteten Luftfahrtstrukturen durch nanopartikelverstärkte anorganisch-organische Hybridbeschichtungen
DE102006061916A1 (de) 2006-12-21 2008-06-26 Rolls-Royce Deutschland Ltd & Co Kg Fanschaufel für ein Gasturbinentriebwerk
DE102008054596B4 (de) 2008-12-12 2011-04-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Offenzellige Keramik- und/oder Metallschaumkörper mit rauer umhüllender Oberfläche und Verfahren zu ihrer Herstellung
IT1393140B1 (it) * 2009-03-17 2012-04-11 Nuovo Pignone Spa Metodo di produzione di un rivestimento protettivo per un componente di una turbomacchina, il componente stesso e la relativa macchina
IT1397705B1 (it) * 2009-07-15 2013-01-24 Nuovo Pignone Spa Metodo di produzione di uno strato di rivestimento per un componente di una turbomacchina, il componente stesso e la relativa macchina
DE102009047798A1 (de) 2009-09-30 2011-04-14 Siemens Aktiengesellschaft Turbinenschaufel, insbesondere Endstufenlaufschaufel für eine Dampfturbine
US20110165433A1 (en) * 2010-01-06 2011-07-07 General Electric Company Erosion and corrosion resistant coating system for compressor
EP2746428B1 (fr) * 2012-12-20 2017-09-13 General Electric Technology GmbH Revêtement de composants de turbine

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6638572B1 (en) * 2001-06-27 2003-10-28 Charles F. Inglefield Heat resistant material for molds and other articles
US20100247321A1 (en) * 2008-01-08 2010-09-30 General Electric Company Anti-fouling coatings and articles coated therewith

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
G. Mallory and J. Hajdu: Electroless Plating: Fundamentals And Applications, (Noyes Publications William Andrew Publishing, LLC, New York 1990) pp. 276 and 277. *
Merriam Webster definition of "disperse", Internet Retrieval date of June 4, 2015, http://www.merriam-webster.com/dictionary/disperse. *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10865481B2 (en) * 2012-12-20 2020-12-15 General Electric Technology Gmbh Coatings for turbine parts
EP3839096A1 (fr) * 2019-12-19 2021-06-23 Raytheon Technologies Corporation Barrière de diffusion pour empêcher la déplétion du super alliage dans le revêtement des pointes de lame en nickel-cbn
US11225876B2 (en) 2019-12-19 2022-01-18 Raytheon Technologies Corporation Diffusion barrier to prevent super alloy depletion into nickel-CBN blade tip coating

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CN103879084B (zh) 2016-03-09
US20160160354A1 (en) 2016-06-09
US10865481B2 (en) 2020-12-15
EP2746428B1 (fr) 2017-09-13
RU2605872C2 (ru) 2016-12-27
CN103879084A (zh) 2014-06-25
EP2746428A1 (fr) 2014-06-25

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