EP2638993A4 - Oberflächenbeschichtetes schneidwerkzeug - Google Patents

Oberflächenbeschichtetes schneidwerkzeug Download PDF

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Publication number
EP2638993A4
EP2638993A4 EP11818965.3A EP11818965A EP2638993A4 EP 2638993 A4 EP2638993 A4 EP 2638993A4 EP 11818965 A EP11818965 A EP 11818965A EP 2638993 A4 EP2638993 A4 EP 2638993A4
Authority
EP
European Patent Office
Prior art keywords
cutting tool
coated cutting
coated
tool
cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11818965.3A
Other languages
English (en)
French (fr)
Other versions
EP2638993B1 (de
EP2638993A1 (de
Inventor
Yoshio Okada
Minoru Itoh
Hideaki Kanaoka
Chie Suzuki
Anongsack Paseuth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Hardmetal Corp
Original Assignee
Sumitomo Electric Hardmetal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Hardmetal Corp filed Critical Sumitomo Electric Hardmetal Corp
Publication of EP2638993A1 publication Critical patent/EP2638993A1/de
Publication of EP2638993A4 publication Critical patent/EP2638993A4/de
Application granted granted Critical
Publication of EP2638993B1 publication Critical patent/EP2638993B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/148—Composition of the cutting inserts
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C23C14/5886—Mechanical treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/02—Pretreatment of the material to be coated
    • C23C16/0272—Deposition of sub-layers, e.g. to promote the adhesion of the main coating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/34—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/56—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/042—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material including a refractory ceramic layer, e.g. refractory metal oxides, ZrO2, rare earth oxides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/044—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2200/00—Details of cutting inserts
    • B23B2200/24—Cross section of the cutting edge
    • B23B2200/245—Cross section of the cutting edge rounded
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B2228/00—Properties of materials of tools or workpieces, materials of tools or workpieces applied in a specific manner
    • B23B2228/10—Coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00—Cutters, for shaping
    • Y10T407/24—Cutters, for shaping with chip breaker, guide or deflector
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00—Cutters, for shaping
    • Y10T407/27—Cutters, for shaping comprising tool of specific chemical composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12458—All metal or with adjacent metals having composition, density, or hardness gradient

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Drilling Tools (AREA)
  • Chemical Vapour Deposition (AREA)
EP11818965.3A 2010-11-10 2011-06-10 Oberflächenbeschichtetes schneidwerkzeug Active EP2638993B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2010251705 2010-11-10
PCT/JP2011/063351 WO2012063515A1 (ja) 2010-11-10 2011-06-10 表面被覆切削工具

Publications (3)

Publication Number Publication Date
EP2638993A1 EP2638993A1 (de) 2013-09-18
EP2638993A4 true EP2638993A4 (de) 2017-12-20
EP2638993B1 EP2638993B1 (de) 2019-07-24

Family

ID=46050674

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11818965.3A Active EP2638993B1 (de) 2010-11-10 2011-06-10 Oberflächenbeschichtetes schneidwerkzeug

Country Status (6)

Country Link
US (1) US8715838B2 (de)
EP (1) EP2638993B1 (de)
JP (1) JP5866650B2 (de)
KR (1) KR101386856B1 (de)
CN (1) CN102625737B (de)
WO (1) WO2012063515A1 (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5831708B2 (ja) * 2012-03-14 2015-12-09 三菱マテリアル株式会社 表面被覆切削工具
JP5568649B1 (ja) * 2013-01-22 2014-08-06 日本航空電子工業株式会社 刃物工具
CN103506640B (zh) * 2013-07-17 2016-04-13 厦门金鹭特种合金有限公司 一种具有涂层的切削工具及其制作方法
JP6084996B2 (ja) * 2015-02-04 2017-02-22 株式会社不二機販 低温セラミックスコーティングの密着力強化方法
KR102027028B1 (ko) * 2015-08-28 2019-09-30 스미또모 덴꼬오 하드메탈 가부시끼가이샤 표면 피복 절삭 공구
JP6507457B2 (ja) * 2016-01-08 2019-05-08 住友電工ハードメタル株式会社 表面被覆切削工具の製造方法
JP6507456B2 (ja) * 2016-01-08 2019-05-08 住友電工ハードメタル株式会社 表面被覆切削工具の製造方法
JP6604553B2 (ja) * 2016-03-30 2019-11-13 三菱マテリアル株式会社 表面被覆切削工具
JP2018030206A (ja) * 2016-08-25 2018-03-01 住友電工ハードメタル株式会社 表面被覆切削工具およびその製造方法
JP2018030205A (ja) * 2016-08-25 2018-03-01 住友電工ハードメタル株式会社 切削工具およびその製造方法
JP6521127B2 (ja) * 2017-04-21 2019-05-29 株式会社タンガロイ 被覆切削工具
JP6521130B2 (ja) * 2017-04-21 2019-05-29 株式会社タンガロイ 被覆切削工具
JP6635347B2 (ja) * 2017-06-27 2020-01-22 株式会社タンガロイ 被覆切削工具
WO2019152936A1 (en) 2018-02-02 2019-08-08 Lockheed Martin Corporation Tribological optimized cutter tool for milling titanium or titanium alloys
JP7054473B2 (ja) * 2018-03-14 2022-04-14 三菱マテリアル株式会社 表面被覆切削工具
US12109625B2 (en) * 2018-09-28 2024-10-08 Mitsubishi Materials Corporation Surface-coated TiN-based cermet cutting tool in which hard coating layer exhibits excellent chipping resistance
JP7256947B2 (ja) * 2018-10-11 2023-04-13 株式会社不二越 硬質皮膜被覆ドリル
WO2020079952A1 (ja) * 2018-10-15 2020-04-23 住友電工ハードメタル株式会社 切削工具
KR102495052B1 (ko) * 2018-10-15 2023-02-06 스미또모 덴꼬오 하드메탈 가부시끼가이샤 절삭 공구
EP3868502A4 (de) * 2018-10-15 2022-04-27 Sumitomo Electric Hardmetal Corp. Schneidwerkzeug
JP6641661B1 (ja) * 2018-10-15 2020-02-05 住友電工ハードメタル株式会社 切削工具
WO2020079953A1 (ja) * 2018-10-15 2020-04-23 住友電工ハードメタル株式会社 切削工具
CN112839760B (zh) * 2018-10-15 2023-06-06 住友电工硬质合金株式会社 切削工具
JP7411312B2 (ja) * 2019-12-16 2024-01-11 株式会社Subaru 転削加工方法
CN112410515A (zh) * 2020-11-02 2021-02-26 桃江富硕精密机械有限公司 一种高强度耐磨导轨钢的加工工艺
US12109628B2 (en) * 2022-08-10 2024-10-08 Iscar, Ltd. Cutting tool with a TiAlN coating having rake and relief surfaces with different residual stresses
CN116372206B (zh) * 2023-03-09 2024-03-19 株洲肯特硬质合金股份有限公司 一种刀具用纳米涂层及涂层刀具

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1772216A1 (de) * 2004-07-23 2007-04-11 Sumitomo Electric Hardmetal Corp. Oberflächenbeschichtungsschneidwerkzeug mit überzugsfilm mit intensitätsverteilung von druckspannungen
EP1806193A1 (de) * 2004-10-29 2007-07-11 Sumitomo Electric Hardmetal Corp. Oberflächenbeschichtetes schneidwerkzeug

Family Cites Families (12)

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JP3661503B2 (ja) 1999-06-23 2005-06-15 三菱マテリアル株式会社 断続重切削で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆炭化タングステン基超硬合金製切削工具
JP4029529B2 (ja) 1999-07-23 2008-01-09 三菱マテリアル株式会社 断続重切削で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆炭化タングステン基超硬合金製切削工具
JP2002062603A (ja) 2000-08-18 2002-02-28 Fuji Photo Film Co Ltd 画像読み取り装置
US7087295B2 (en) 2002-01-18 2006-08-08 Sumitomo Electric Industries, Ltd. Surface-coated cutting tool
CN100479955C (zh) 2003-12-05 2009-04-22 住友电工硬质合金株式会社 表面被覆切削工具
JP2005271190A (ja) 2003-12-05 2005-10-06 Sumitomo Electric Hardmetal Corp 表面被覆切削工具
JP4593996B2 (ja) 2004-07-28 2010-12-08 住友電工ハードメタル株式会社 表面被覆切削工具
US7972714B2 (en) 2004-12-14 2011-07-05 Sumitomo Electric Hardmetal Corp. Coated cutting tool
JPWO2007111301A1 (ja) 2006-03-28 2009-08-13 京セラ株式会社 表面被覆工具
JP5013261B2 (ja) 2007-09-25 2012-08-29 三菱マテリアル株式会社 表面被覆切削工具
FR2925378B1 (fr) 2007-12-20 2012-06-15 Saint Gobain Ct Recherches Particules de grenaillage.
JP2010137315A (ja) 2008-12-10 2010-06-24 Sumitomo Electric Hardmetal Corp 表面被覆切削工具

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1772216A1 (de) * 2004-07-23 2007-04-11 Sumitomo Electric Hardmetal Corp. Oberflächenbeschichtungsschneidwerkzeug mit überzugsfilm mit intensitätsverteilung von druckspannungen
EP1806193A1 (de) * 2004-10-29 2007-07-11 Sumitomo Electric Hardmetal Corp. Oberflächenbeschichtetes schneidwerkzeug

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2012063515A1 *

Also Published As

Publication number Publication date
US20120282049A1 (en) 2012-11-08
JPWO2012063515A1 (ja) 2014-05-12
US8715838B2 (en) 2014-05-06
KR101386856B1 (ko) 2014-04-17
EP2638993B1 (de) 2019-07-24
KR20120094467A (ko) 2012-08-24
JP5866650B2 (ja) 2016-02-17
WO2012063515A1 (ja) 2012-05-18
CN102625737A (zh) 2012-08-01
CN102625737B (zh) 2014-12-17
EP2638993A1 (de) 2013-09-18

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