EP2600980B1 - Assembly and method for aerosol spraying a liquid product contained in a container - Google Patents

Assembly and method for aerosol spraying a liquid product contained in a container Download PDF

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Publication number
EP2600980B1
EP2600980B1 EP11755120.0A EP11755120A EP2600980B1 EP 2600980 B1 EP2600980 B1 EP 2600980B1 EP 11755120 A EP11755120 A EP 11755120A EP 2600980 B1 EP2600980 B1 EP 2600980B1
Authority
EP
European Patent Office
Prior art keywords
container
pressurised air
liquid product
assembly
feeding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP11755120.0A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2600980A1 (en
Inventor
Sergio Raffaghello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MARHVEL Srl
Original Assignee
MARHVEL Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MARHVEL Srl filed Critical MARHVEL Srl
Publication of EP2600980A1 publication Critical patent/EP2600980A1/en
Application granted granted Critical
Publication of EP2600980B1 publication Critical patent/EP2600980B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
    • B65B31/003—Adding propellants in fluid form to aerosol containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
    • B05B7/2405—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle
    • B05B7/2416—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device using an atomising fluid as carrying fluid for feeding, e.g. by suction or pressure, a carried liquid from the container to the nozzle characterised by the means for producing or supplying the atomising fluid, e.g. air hoses, air pumps, gas containers, compressors, fans, ventilators, their drives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2402—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device
    • B05B7/2475—Apparatus to be carried on or by a person, e.g. by hand; Apparatus comprising containers fixed to the discharge device comprising a container carried on the back of the user

Definitions

  • the present invention relates to an assembly for aerosol spraying a liquid product contained in a container.
  • the invention further relates to a method for aerosol spraying a liquid product contained in a container.
  • aerosol spraying is used to indicate the creation and the supply of a mixture of micro particles of liquid product dispersed into the air.
  • Containers for aerosol spraying liquid products such as paints, perfumes, insecticides, detergents, etc. are well known.
  • the so-called “spray cans” of the disposable type are common and widely used. These are cylindrical containers, made from tinplate or aluminium, which are filled with a mixture of a liquid product (for example paint) and with a liquid propellant consisting of a liquefied gas (for example propane, butane or isobutane). As an example, in a paint spray can of 400 ml, the aforementioned mixture can be formed by 200 ml of paint and 200 ml of liquid propellant.
  • a liquid product for example paint
  • a liquid propellant for example propane, butane or isobutane
  • the liquid propellant has the purpose of diffusing the liquid product in the form of aerosol.
  • Aerosol spraying of the liquid product by effect of the liquid propellant occurs at a mixing valve that is purposely provided in the spray can.
  • the liquid propellant Due to the pressure exerted on the aforementioned mixing valve, the liquid propellant returns to the gas state and violently comes out from a supplying nozzle which is purposely provided in the spray can, bringing therewith also the liquid product which it was mixed with.
  • the gas part of the mixture dissolves in the air separating from the liquid part, thus obtaining the aerosol spraying of the liquid product.
  • a dispensing gun is coupled, through a connection hose, with a group for generating pressurised air which is typically arranged at a remote position with respect to the gun.
  • a gun is moreover connected to a hose that draws from the container in which there is the liquid product to be aerosol sprayed.
  • a depression which draws the liquid product towards a supplying nozzle is created in the body of the gun, substantially due to the Venturi effect, by the supply of pressurised air.
  • the pressurised air thus expels the liquid product through the supplying nozzle, without any mixing being created upstream of the nozzle itself.
  • US 4,972,975 discloses a device for spraying a liquid product contained in a container made of plastic material. Such a container can be recharged many times with new liquid product.
  • the supplying device comprises a group for generating pressurised air that is suitably connected to the aforementioned container.
  • a group comprises a vane pump and a motor for actuating the aforementioned pump.
  • the pressurised air is introduced in the container through a hose that is connected to a properly designed supplying nozzle.
  • the supply occurs, upon actuating the motor of the vane pump, due to the pressure exerted by the user on the supplying nozzle.
  • the pressurised air introduced in the container pushes the liquid product to go up through a suction hose until it reaches the nozzle, which causes it to be nebulised in the air.
  • the interruption of the supply occurs by turning off the motor of the pump or, in a particular embodiment, by opening a vent hole properly created in the upper portion of the container.
  • the Applicant has found a number of drawbacks in the device described above, the first of which is the need to provide nozzles that are properly designed to obtain the nebulisation of the liquid product. Moreover, in the embodiment in which the interruption of the supply occurs by turning off the motor of the pump, when the motor is turned off there is a gradual and not instantaneous reduction of the supplied product, with negative consequences on the quality of the spraying. On the other hand, in the embodiment in which the interruption of the supply occurs by opening the vent hole, every time the vent hole is closed it is necessary to wait for the container to return to the desired pressure so as to be able to have an optimal spray. Moreover, the provision of the vent hole in the upper portion of the container actually prevents the device from being able to be used in positions that are different from the vertical one.
  • US 5,046,667 discloses a spraying device that differs from that described in US 4,972,975 in that it uses a slide valve which, in the position in which the button is pressed, allows the compressed air both to press on top of the free surface of the liquid product so as to allow the liquid product to go up into the suction hose and reach the supplying nozzle, and to reach itself the supplying nozzle, where the nebulisation between air and liquid product is created.
  • the Applicant has found that also in the abovementioned device it is necessary to provide nozzles that are properly designed so as to obtain the nebulisation of the liquid product. Moreover, the motor for actuating the pump is actuated only when the nozzle is open. This means that the container is never pressurised.
  • the Applicant has found that, differently from conventional spray cans, in the devices described in US 4,972,975 and US 5,046,667 there is no mixing valve upstream of the supplying nozzle and the supply of the liquid product in the form of aerosol occurs with dynamics which are comparable to those of aerographs.
  • the feeding of the pressurised air into the container occurs only during the supply of the product contained in the container.
  • US 5,411,183 discloses a device for spraying a liquid or foam, that is provided with a pump that can be actuated manually and that is suitable for feeding pressurised air into a container.
  • a dosing valve through which the supply of liquid or foam occurs, is associated to the container.
  • a one-way valve is placed between the pump and the container so as to avoid a flow of air from the container towards the pump.
  • the feeding of the pressurised air into the container occurs by effect of a thrust action exerted by a motorised pump.
  • the feeding of the pressurised air into the container occurs by arranging the container in a suitable loading station and, therefore, before the supply of liquid or foam.
  • Analogous devices from this point of view are described in CH 632423 , DE 3022913 and DE 8813 633U .
  • the Applicant has focused its attention on those aerosol spraying systems in which disposable containers provided with mixing valves, like for example conventional spray cans, are used.
  • the Applicant has indeed verified that these systems of aerosol spraying ensure a constant pressure inside the container and, consequently, a spray that is almost instantaneous with optimal characteristics, without suffering from the drawbacks mentioned above with respect to the devices described in the aforementioned prior art documents.
  • the technical problem at the basis of the present invention is that of aerosol spraying a liquid product contained in a container in an almost instantaneous manner, with a constant pressure and having optimal spray characteristics, without moreover using liquid propellants, so as to avoid the aforementioned drawbacks.
  • the present invention therefore, in a first aspect thereof, relates to an assembly for aerosol spraying a liquid product contained in a container as recited in claim 1.
  • the term "container” is used to indicate any kind of container for containing a liquid product. It can therefore be a can, a jar, a cartridge, etc..
  • the liquid product can be of any kind, like for example paint, oil, chemical products of various kind, etc..
  • the assembly of the present invention it is possible to aerosol spray the liquid product contained in the container in a manner that is completely similar to what occurs in a conventional disposable spray can, without however using any propellant. Therefore the risks related to the inflammability of the propellant are advantageously avoided.
  • the container of the invention can be filled substantially entirely with the liquid product to be aerosol sprayed.
  • the Applicant has found that keeping an almost constant level of pressure inside the container while aerosol spraying, and therefore obtaining a spray having the desired characteristics of uniformity, is ensured by the fact that the container continues to be supplied with pressurised air even while aerosol spraying the liquid product.
  • This moreover makes it possible to be able to provide levels of pressure that are lower with respect to those required in devices in which the supply of the pressurised air occurs only before the step of aerosol spraying, with a consequent advantageous reduction of the size and of the weight of the means especially provided for supplying the pressurised air, which can thus be transported more easily during the aerosol spraying step.
  • the cost of the aforementioned means is advantageously low.
  • the Applicant has further observed that in the assembly of the present invention the characteristics of spray quality are independent from the temperature at which it happens, contrarily to the case of the conventional spray in which the optimal characteristics are obtained at temperatures of 20°C and the variations of this parameter, affecting the physical characteristics of the expansion of the propellant gas adapted to create aerosol spraying, radically influence the quality of the result.
  • the aforementioned aperture is formed at said top portion of said case in a position so that, when the container is in a substantially vertical supplying position, it is above the free surface of the liquid product.
  • the position of the aperture for feeding air is such that part of the air introduced in the container directly reaches the mixing valve and another part of the aforementioned air acts by pushing onto the free surface of the liquid product, which is thus forced to go up through a special suction hose until it reaches the mixing valve.
  • a one-way valve is further provided, which can be coupled to said aperture and to said means for feeding the pressurised air.
  • the one-way valve prevents the liquid product from being able to flow out from the container through the aforementioned aperture. Therefore, the container of the invention can be used in any position, even with the axis of the container inclined with respect to the vertical or it can even be upside down.
  • the aforementioned means for feeding the pressurised air comprise a hose which can be coupled, at a first free end thereof, to said one-way valve and, at an opposite free end thereof, to a group for generating pressurised air which is provided at a remote position with respect to said container.
  • said group for generating pressurised air is associated with a belt which can be put on by a user.
  • the aforementioned means for feeding the pressurised air comprise a device for generating pressurised air which can be removably coupled to the container and a hose which can be coupled, at a first free end thereof, to said one-way valve and, at an opposite free end thereof, to said device for generating pressurised air, so that, when the device for generating pressurised air is coupled to the container and the hose is coupled to the one-way valve and to the device for generating pressurised air, the assembly forms a self-governing operative unit which can be gripped and moved by the user.
  • the same device for generating pressurised air can be used by the user each time associating thereto a plurality of different containers containing possibly different liquid products, such containers always being of the "disposable" type.
  • the containers with the liquid products can be sold separately from the device for generating pressurised air, which the user needs to buy only once.
  • said device for generating pressurised air is coupled with said container at a bottom surface of said case.
  • said device for generating pressurised air is coupled with said container at a bottom surface of said case.
  • the group or device for generating pressurised air comprises a diaphragm pump.
  • a diaphragm pump ensures that the pressure values required by the mixing valve are reached so as to achieve the desired aerosol spraying.
  • the present invention relates to a method for aerosol spraying a liquid product contained in a container as recited in claim 10.
  • such a method can be actuated by using the assembly of the present invention described above.
  • Figures 1-3 show an assembly for aerosol spraying a liquid product contained in a container, in accordance with the present invention.
  • the assembly is wholly indicated with reference numeral 10, whereas the container is indicated with reference numeral 20.
  • the liquid product is indicated with L, and it has a free surface P.
  • said liquid product L is a paint. It is however obvious that in the present invention any other type of liquid product can be used.
  • the container 20 comprises a case 20a that is preferably made of a metal material, more preferably carbon steel.
  • the container 20 is equipped with a mixing valve 22 which is fluid-dynamically and mechanically coupled with a supplying nozzle 24.
  • the latter is in fluid communication with the liquid product L through a suction hose 26.
  • an aperture 28 is formed on the top portion of the case 20a of the container 20. Such an aperture 28 is located at a portion of container 20 that is spatially separate from that in which the valve 22 and the nozzle 24 are provided.
  • the aperture 28 is placed above the free surface P of the liquid product L contained in the container 20, when the longitudinal axis X of the container 20 is in a vertical supplying position, i.e. it is arranged as illustrated in figures 1 and 2 .
  • the container 20 illustrated in the non limiting example of figures 1 and 2 substantially has the shape of a conventional spray can, i.e. it has a cylindrical body 30 that is closed at the bottom by a bottom surface 32 and at the top by a dome-shaped surface 34.
  • the bottom surface 32 is concave, i.e. it bulges inwards with respect to the container 20, and the dome-shaped surface 34 is convex, i.e. it bulges outwards with respect to the container 20.
  • a seat 38 in which the valve 22 and the nozzle 24 are arranged, both absolutely identical to those used in conventional spray cans.
  • the valve 22 can be opened by pressing a button 36 located above it. By releasing the button 36, on which a return spring (not illustrated for the sake of simplicity) acts, the valve 22 closes, just like what occurs in conventional spray cans.
  • the container 20 of the present invention differs from that of a conventional spray can only for the fact that there is the aforementioned aperture 28.
  • Such an aperture 28 is located at the dome-shaped surface 34 alongside the housing seat 38 of the valve 22 and of the nozzle 24.
  • the provision of the aperture 28 in a position that is separate from that in which the nozzle 24 is provided makes it possible to obtain the desired aerosol spraying effect in the spray, differently from what occurs in devices that operate similarly to the aerographs.
  • the aperture 28 is closed by a special lid (not illustrated).
  • a lid is screwed onto a threaded surface formed in the aperture 28.
  • a one-way valve 40 is coupled to the aperture 28, preferably through respective portions of threaded surfaces.
  • the assembly 10 comprises a device 50 for generating pressurised air A.
  • a device 50 is in fluid communication with the container 20 through a hose 52 for feeding pressurised air.
  • a free end 53a of the hose 52 is coupled to the one-way valve 40 mounted on the aperture 28, whereas the opposite free end 53b of the hose 52 is associated to the device 50.
  • the container 20 and the device 50 comprise respective means 42 for removably associating the device 50 to the container 20 so that the assembly 10 comprising the container 20 and the device 50 for generating pressurised air constitutes a self-governing operative unit that can be gripped and moved by a user.
  • the aforementioned means 42 preferably allow a mechanical coupling of the generating device 50 to the container 20.
  • the means 42 comprise a circumferential groove 44 ( figure 2 ) provided on a lower end portion of the cylindrical body 30 of the container 20, therefore at the bottom surface 32, and that snap-couples on an upper surface of the device 50 for generating pressurised air ( figure 3 ).
  • the aforementioned means 42 are defined by elastic hooks.
  • the device 50 comprises a case 56, closed at the bottom by a bottom 58 and on top by a cover 60.
  • the cover 60 comprises a circular recess 62 in which the lower end portion of the cylindrical body 30 of the container 20 is snap-coupled.
  • the cover comprises a convex portion, i.e. that bulges outwards from the device for generating pressurised air, and is shaped to match the concave bottom of the container.
  • a convex portion can contain magnets that ensure a sufficiently stable coupling with the bottom of the container.
  • the case 56 of the device 50 contains an air pump 64, an electric motor 66 which actuates the pump 64 and a group 68 for supplying power to the motor 66.
  • the pump 64 is of the diaphragm type.
  • diaphragm pumps currently on the market, which have technical characteristics so as to ensure the use in devices for generating pressurised air according to the present invention.
  • 2.3 - 2.5 bar diaphragm pumps are for example used, which satisfy the requirements of constancy and regularity of aerosol spraying.
  • the diaphragm pump rapidly brings the air in the container 20 to the optimal pressure for aerosol spraying (about 3 seconds).
  • the diaphragm pump is equipped with a system of valves on the delivery and suction sections which make it possible to not exceed the predetermined maximum pressure level, even in a condition of continuous use with the nozzle pushed.
  • the electric motor 66 can be actuated through a switch (not shown) preferably provided on the case 56.
  • the power supplying group 68 preferably comprises batteries of the rechargeable type. Recharging occurs through a conventional recharging device. Preferably, on the device 50 for generating pressurised air an indicator is provided which indicates the level of the battery charge, or rather, it signals when the batteries are almost flat.
  • the case 56 (or at least one of the bottom 58 and the cover 60), comprises at least one hole 70 so as to allow the pump 64 to suck in air from the environment.
  • a hose 72 for emitting pressurised air A which passes through the case 56 via a special hole 74, is associated to the pump 64.
  • the hose 72 is in fluid communication with the hose 52 for feeding pressurised air, or alternatively the hose 72 is nothing but an end portion of the hose 52.
  • the device for generating pressurised air instead of being associated to the aforementioned container 20, can be a conventional group for generating pressurised air provided at a remote position with respect to the container 20 and connected thereto through a hose for feeding pressurised air.
  • a hose for feeding pressurised air for example, an air compressor, or the compressed air line provided in an industrial factory, can be used.
  • Aerosol spraying of the liquid product L occurs in a manner that is substantially identical to what occurs in conventional disposable spray cans. The only difference is that while conventional spray cans also contain a propellant, the container 20 can be filled entirely with the liquid product L only, and pressurised air, which is supplied later on, is used as a vector.
  • Aerosol spraying the liquid product L thus initially provides for filling the container 20 with only the liquid product L.
  • pressurised air A is fed into the container through the aperture 28.
  • pressurised air A acts upon the free surface P of the liquid product L, whereas a different part directly reaches the mixing valve 22.
  • the liquid product L goes up towards the mixing valve 22 through the suction hose 26.
  • the mixing of the liquid product L with the pressurised air and therefore the aerosol spraying of the liquid product L occurs.
  • the liquid product L can thus be supplied into the outside environment in the form of an aerosol through the nozzle 24.
  • the feeding of pressurised air occurs by associating the device 50 for generating pressurised air to the container 20 beforehand (as described above and as illustrated in figure 3 ).
  • the pressurised air can be made to come from a group for generating pressurised air provided at a remote position with respect to the container 20.
  • the user during operation will grip and move the assembly consisting of a container 20 and a device 50 as if it were a conventional spray can. He will simply have to activate the device 50 for supplying the pressurised air before actuating the supplying button 36.
  • the device 50 can be bought only once by the user, who will then be able to find the relative container on the market with the desired liquid product therein.
  • a liquid product will be suitably studied and made so as to give it the best and most suitable chemical-physical characteristics to achieve the desired aerosol spraying.
  • the choice of the mixing valve 22 (and possibly of the supplying nozzle 24) will be made bearing in mind the chemical-physical characteristics of the liquid product L of interest, being able in any case to limit the choice to components already available on the market, since they are used in conventional spray cans.
  • Figure 4 illustrates a part of an alternative embodiment of the assembly of the present invention.
  • the container (not illustrated) is completely identical to the container 20 of figures 1 and 2 with the sole exception that on the lower end portion of the cylindrical body 30 of the container 20, i.e. at the bottom surface 32, there are no means 42 for coupling to the device 50 for generating pressurised air.
  • the generating device 50 is provided, at the bottom 58 thereof, with loops 90 that are suitable for allowing the insertion of a belt 100 which can be put on by the user. In such a way, during use, the user only grips the container, whereas the device 50 for generating pressurised air remains anchored to the waist of the user.
  • the device 50 is otherwise absolutely identical to that of figures 1 and 3 (although having a different shape and a different arrangement of the components provided therein), with the single further exception that on the cover thereof (not illustrated) there are no means for coupling to the container 20.
  • the switch for actuating the electric motor 66 is however visible (indicated with reference numeral 67).
  • the switch for actuating the electric motor 66 is however visible (indicated with reference numeral 67).
  • the switch there are also lights 67a, 67b that are suitable for indicating the actuation of the electric motor 66 and the charge level of the batteries (that is to indicate when the batteries are almost flat).

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Nozzles (AREA)
EP11755120.0A 2010-08-02 2011-07-29 Assembly and method for aerosol spraying a liquid product contained in a container Not-in-force EP2600980B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2010A001460A IT1401505B1 (it) 2010-08-02 2010-08-02 Assieme e metodo per aerosolizzare un prodotto liquido contenuto in un contenitore, e relativo contenitore
PCT/IB2011/001794 WO2012017293A1 (en) 2010-08-02 2011-07-29 Assembly and method for aerosol spraying a liquid product contained in a container and related container

Publications (2)

Publication Number Publication Date
EP2600980A1 EP2600980A1 (en) 2013-06-12
EP2600980B1 true EP2600980B1 (en) 2016-04-27

Family

ID=43733266

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11755120.0A Not-in-force EP2600980B1 (en) 2010-08-02 2011-07-29 Assembly and method for aerosol spraying a liquid product contained in a container

Country Status (6)

Country Link
US (1) US20130126560A1 (pt)
EP (1) EP2600980B1 (pt)
CN (1) CN103118799A (pt)
BR (1) BR112013002546A2 (pt)
IT (1) IT1401505B1 (pt)
WO (1) WO2012017293A1 (pt)

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AU2013330959A1 (en) * 2012-10-19 2015-05-07 Rust-Oleum Corporation Propellantless aerosol system
FR3030462B1 (fr) * 2014-12-19 2018-02-02 Aptar France Sas Distributeur de produit fluide.
US10179690B2 (en) 2016-05-26 2019-01-15 Rai Strategic Holdings, Inc. Aerosol precursor composition mixing system for an aerosol delivery device
US10421086B1 (en) * 2018-06-19 2019-09-24 Christine Kuligowski Reusable dry erase spray paint can
CN112705373A (zh) * 2019-10-25 2021-04-27 苏州宝时得电动工具有限公司 喷雾器

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Publication number Priority date Publication date Assignee Title
FR1002297A (fr) * 1946-09-04 1952-03-04 Appareillage de projection par air comprimé de liquides ou poudres, particulièrement pour traitement médical, chirurgical, dentaire, esthétique

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ITMI20101460A1 (it) 2012-02-03
CN103118799A (zh) 2013-05-22
BR112013002546A2 (pt) 2017-09-26
WO2012017293A1 (en) 2012-02-09
IT1401505B1 (it) 2013-07-26
EP2600980A1 (en) 2013-06-12
US20130126560A1 (en) 2013-05-23

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