EP2598324A1 - Mehrlagige karte mit einer äusseren faserschicht - Google Patents

Mehrlagige karte mit einer äusseren faserschicht

Info

Publication number
EP2598324A1
EP2598324A1 EP11748739.7A EP11748739A EP2598324A1 EP 2598324 A1 EP2598324 A1 EP 2598324A1 EP 11748739 A EP11748739 A EP 11748739A EP 2598324 A1 EP2598324 A1 EP 2598324A1
Authority
EP
European Patent Office
Prior art keywords
outer layer
card
fibrous outer
fibrous
relative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11748739.7A
Other languages
English (en)
French (fr)
Inventor
Thibaut Le Loarer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArjoWiggins Security SAS
Original Assignee
ArjoWiggins Security SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ArjoWiggins Security SAS filed Critical ArjoWiggins Security SAS
Publication of EP2598324A1 publication Critical patent/EP2598324A1/de
Withdrawn legal-status Critical Current

Links

Classifications

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    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40Manufacture
    • B42D25/45Associating two or more layers
    • B42D25/455Associating two or more layers using heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/005Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/02Layered products comprising a layer of paper or cardboard next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/18Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
    • B32B37/182Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only one or more of the layers being plastic
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
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    • B42D25/30Identification or security features, e.g. for preventing forgery
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    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40Manufacture
    • B42D25/45Associating two or more layers
    • B42D25/465Associating two or more layers using chemicals or adhesives
    • B42D25/47Associating two or more layers using chemicals or adhesives using adhesives
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26Polyamides; Polyimides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/385Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • D21H21/44Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
    • D21H21/48Elements suited for physical verification, e.g. by irradiation
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    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/2481Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Definitions

  • Multilayer card having a fibrous outer layer
  • the present invention relates to the field of multilayer cards and more particularly to multilayer cards of the credit card, social security card or identity card type, comprising one or more security elements.
  • multilayer structures comprising a layer of paper are known from the following documents.
  • WO 2009/007659 describes an insert comprising a chip module and a wire antenna.
  • the module opens on the outer surface of the insert.
  • Said insert being intended to be integrated in a passport or an identity card, it constitutes an inner layer which is therefore not intended to be printed.
  • WO 2006/101493 discloses a multilayer structure comprising a printable layer including synthetic paper type Teslin ® .
  • the multilayer structure further comprises an intermediate layer comprising a thermosetting polymer and a base layer on the surface of which electronic components are deposited.
  • Teslin ® is a plastic material that is neither fibrous nor cellulosic. This multilayer structure may be printable inkjet but its resistance to successive bends may not be entirely satisfactory.
  • WO 2006/077339 discloses paper layers loaded with synthetic fibers to enhance their internal cohesion.
  • the present invention aims to meet all or part of the aforementioned needs.
  • the invention relates to a multilayer card comprising a fibrous outer layer, the fibrous outer layer comprising at least:
  • mineral fillers in a mass content of between 9 and 20%, preferably between 12 and 16%, relative to the total weight of the fibrous outer layer,
  • a binder especially a mixture of PVA and of starch or a latex, preferably chosen from acrylic, styrene-butadiene or butadiene latexes, and
  • a softening agent in particular glycerol, urea, sodium nitrate or a mixture thereof,
  • the outer fibrous layer being printed and / or comprising a security element, in particular a luminescent element.
  • the chip advantageously does not open onto the outer surface of the fibrous outer layer.
  • the triple combination of synthetic fibers, a binder as well as a softening agent advantageously makes it possible to give the outer fibrous layer improved elasticity, flexibility and double-fold resistance properties.
  • the presence of mineral fillers advantageously makes it possible to give the fibrous outer layer printability properties, in particular offset and inkjet printability.
  • the printing of the fibrous outer layer may consist of a variable mention, for example the name or the photograph of the holder of the multilayer card according to the invention.
  • All or part of the printing and / or the security element of the outer fibrous layer may be visible.
  • at least part of the printing and / or the security element of the fibrous outer layer of a multilayer card according to the invention may be visible to a user of said multilayer card.
  • the resolution of the printing of the fibrous outer layer may be greater than 600 dpi.
  • the natural fibers may be present in the fibrous outer layer in the form of a mixture of long natural fibers (derived from softwood) and short natural fibers (from hardwood).
  • Long natural fibers may, for example, be used to improve mechanical strength and short natural fibers may, for example, be used to impart opacity.
  • the mass proportion of short natural fibers within the fibrous outer layer may be less than or equal to the mass proportion of long natural fibers.
  • at least 50% by weight of the natural fibers can be long natural fibers.
  • at least 80% by weight of the natural fibers are long natural fibers.
  • the natural fibers may be formed in whole or in part of cellulosic fibers, in particular all of them being cellulosic fibers.
  • the synthetic fibers may, for example, be chosen from rayon fibers, in particular fibran or viscose, or from a thermoplastic material, in particular a polyamide, a polyester, a polyolefin and / or a mixture of such fibers.
  • the mass content of synthetic fibers in the fibrous outer layer can be evaluated, for example, by three-dimensional measurement by two-dimensional cross-section stereology using a scanning electron microscope.
  • the number of synthetic fibers intercepted by the cut for each image is counted for each paper direction, namely N st and N sm .
  • the total length L of counted paper is given by the sum of the lengths of the counted images.
  • N ml -.
  • the weight of synthetic fibers per square meter, w is calculated using the titration (or linear density) T of the synthetic fibers expressed in decitex (weight in grams of 10,000 m of fibers) and Nmi using the following formula :
  • the rate of synthetic fibers is obtained by dividing this weight by the weight of the fibrous outer layer.
  • the number of images is sufficient to count at least 400 synthetic fibers, in order to reduce the imprecision of the method.
  • At least 50% by weight of the synthetic fibers may be polyamide fibers.
  • the synthetic fibers may, for example, have an average length greater than 4 mm, for example 6 mm.
  • synthetic fibers may have an average length of
  • the average diameter of the synthetic fibers may be between 0.9 and 4.2 dtex, for example between 0.9 and 3.3 dtex, better still between 1.2 and 1.7 dtex.
  • the mineral fillers may be chosen from silica, sodium silicates and aluminosilicates, carbonates, in particular calcium, talc, kaolin, alumina hydrate, titanium dioxide and mixtures thereof.
  • the fibrous outer layer may, for example, comprise silica, sodium aluminosilicate and titanium dioxide as mineral fillers.
  • Silica and sodium aluminosilicate may, for example, be used for printability, and titanium dioxide for opacity and whiteness.
  • the fibrous outer layer may comprise silica in a mass content of between 1 and 10%, preferably between 6 and 8%, relative to the total weight of the outer fibrous layer.
  • the fibrous outer layer may comprise sodium aluminosilicate in a mass content of between 1 and 9%, preferably between 5 and 7%, relative to the total weight of the fibrous outer layer.
  • the fibrous outer layer may comprise titanium dioxide in a mass content of between 2 and 9%, preferably between 4 and 7%, relative to the total weight of the outer fibrous layer.
  • the binder may advantageously be chosen from thermoplastic polymers having a glass transition temperature Tg of less than or equal to +20.degree. C., better still 10.degree. C., to provide flexibility.
  • the fibers of the fibrous base are bonded with a binder precipitated in bulk, the binder of the fibrous base being for example chosen from polymers with a Tg of less than or equal to -10 ° C., for example being selected from styrene butadiene copolymers, acrylic polymers and vinyl acetates and copolymers thereof.
  • the binder is, for example, introduced into the fiber base by surfacing, the binder of the fibrous base being chosen for example from polymers with a Tg of less than or equal to + 10 ° C.
  • binder of the fibrous base comprising for example a natural binder, in particular starch, or synthetic, in particular polyvinyl alcohol or a styrene acrylic polymer, for example with a Tg close to 7 ° C.
  • the coating binder advantageously comprises a thermoplastic material, the quantity of thermoplastic material being adjusted, for example, to give the coating a concentration of between 10 and 20 g / m 2 sec in order to obtain good printability (a too high concentration of binding agent may degrade F printability) while maintaining the "non-crease marking" of the fibrous base, the coating binder of the surface layer may for example comprise a polymer or copolymer styrene butadiene nature, acrylic, styrene acrylic or vinyl.
  • the binder may, for example, be selected from latex.
  • the binder is chosen from acrylic latices, styrene butadiene or butadiene and more preferably for reasons of durability, in particular UV resistance and aging resistance, among acrylic latices.
  • the binder may be selected from PVA, starch and mixtures thereof, preferably a mixture of PVA and starch.
  • the binder may be present within the fibrous outer layer in a mass content of between 3 and 15%, preferably between 7 and 12%.
  • the binder of the fibrous base may, for example, be combined with a softening agent.
  • a softening agent may be selected from glycerin, the urea / sodium nitrate mixture, or mixtures thereof.
  • the softening agent is a compound for lubricating the individual fibers in the fibrous network constituted by the paper, it may be a surfactant product.
  • Such an agent used in papermaking may have the effect of providing the paper with a soft feel and high elasticity.
  • the softening agent may be present within the fibrous outer layer in a mass content of between 2 and 12%, preferably between 3 and 7%.
  • softening agent preferably with a weight ratio
  • sodium nitrate of between 1 and 5, for example between 1.5 and 3.
  • Glycerin can also be used.
  • the ratio between the binder mass content and the mineral filler content in the fibrous outer layer is between 0.25 and 1.5, preferably between 0.5 and 1.
  • the fibrous outer layer may have a basis weight of between 90 and 175 g / m 2 , for example between 100 and 150 g / m 2 .
  • the outer fibrous layer according to the invention may comprise any type of security elements known to those skilled in the art, chosen in particular from the security elements described below.
  • the present invention relates, in another of its aspects, to a multilayer card comprising a fibrous outer layer, the fibrous outer layer comprising:
  • mineral fillers in a mass content of between 9 and 20%, preferably between 12 and 16%, relative to the total weight of the fibrous outer layer,
  • a binder especially a mixture of PVA and of starch or a latex, preferably chosen from acrylic, styrene-butadiene or butadiene latexes, and
  • a softening agent in particular glycerine, urea, sodium nitrate or a mixture thereof,
  • the fibrous outer layer being intended to be printed especially in offset and / or ink jet on its outer surface.
  • the present invention relates, in another of its aspects, to a multilayer card comprising a fibrous outer layer, the fibrous outer layer comprising:
  • mineral fillers in a mass content of between 9 and 20%, preferably between 12 and 16%, relative to the total weight of the fibrous outer layer,
  • a binder especially a mixture of PVA and of starch or a latex, preferably chosen from acrylic, styrene-butadiene or butadiene latexes, and a softening agent, in particular glycerine, urea, sodium nitrate or a mixture thereof,
  • the outer fibrous layer being printed, in particular in offset or inkjet, on its outer surface.
  • the printing can be a pre-print and the card can be provided to the user already printed, for example in offset.
  • the user can then, if he wishes, customize the card, for example by inkjet printing, to enter his name, address, photograph or other information about him.
  • the present invention relates, in another of its aspects, to a multilayer card comprising a fibrous outer layer, the fibrous outer layer comprising:
  • mineral fillers in a mass content of between 9 and 20%, preferably between 12 and 16%, relative to the total weight of the fibrous outer layer,
  • a binder especially a mixture of PVA and of starch or a latex, preferably chosen from acrylic, styrene-butadiene or butadiene latexes, and
  • a softening agent in particular glycerine, urea, sodium nitrate or a mixture thereof,
  • the thickness of the card at least is in accordance with ISO 7813.
  • the card has a thickness of 760 ⁇ +/- 80 ⁇ .
  • the present invention relates to a method of manufacturing a multilayer card as described above comprising at least the steps of:
  • the fibrous outer layer and said card body may comprise an adhesive coating on at least one face.
  • a heat-activatable adhesive or a pressure-sensitive adhesive may be used.
  • the adhesive will be chosen from hot-activated adhesives comprising, for example, a polymer chosen from polyurethane, polyethylene, acrylic or vinyl polymers, for example polyvinyl acetate and mixtures thereof.
  • the assembly of the card body and said at least one fibrous outer layer may for example be by hot lamination techniques known to those skilled in the art.
  • the card body may itself comprise one or more layers of paper and / or plastic.
  • the present invention relates to a method of manufacturing a fibrous outer layer, for example as described above, comprising at least the steps of:
  • the fibrous suspension prefferably refined before step b).
  • the method described above may further comprise the addition of a composition comprising at least one binder, for example by mass precipitation.
  • the method described above may further comprise, after addition of the synthetic fibers, the addition of a composition comprising at least one binder, for example by impregnation, surfacing, coating and / or coating.
  • the mineral fillers can be included in said composition and thus be added during impregnation, surfacing, coating and / or coating.
  • Any known method or device can be used for this purpose, in particular an impregnator, an enco lieuse press (also called “size press”), a "press film”, an air knife or doctor blade coater, a curtain coater, a Champion coater, a gravure coater or a film transfer coater, for example such as a Twin-HSM coater from BTG.
  • Said composition comprising at least one binder is preferably added by means of an impregnator or a gluing press.
  • the fibrous composition obtained after one of the steps b) or c) can be drained, pressed and dried according to the current papermaking process, for example before the addition of the binder.
  • the present invention relates to an article comprising, in particular consisting of, a multilayer card as described above in which at least a part of the printing and / or the security element of the layer. external fibrous is visible.
  • the multilayer card may be embedded within said article by one or more transparent layers, for example thermoplastic material.
  • the present invention relates to a method of manufacturing a printed document in which a multilayer card is printed comprising a fibrous outer layer, the fibrous outer layer comprising:
  • mineral fillers in a mass content of between 9 and 20%, preferably between 12 and 16%, relative to the total weight of the fibrous outer layer,
  • a binder especially a mixture of PVA and of starch or a latex, preferably chosen from acrylic, styrene-butadiene or butadiene latexes, and
  • a softening agent in particular glycerine, urea, sodium nitrate or a mixture thereof.
  • the printing may, for example, be offset, inkjet or gravure printing.
  • the ink used for printing may, for example, comprise a coloring agent such as a dye and / or pigments, especially luminescent pigments.
  • the fibrous outer layer according to the invention may not have a crease marking. Indeed, when the two edges according to the length of an ID-1 card comprising at least one fibrous outer layer according to the invention, in accordance with the standards ISO 7810 and 7813 (for example described in the examples below), are brought into contact by folding, the outer fibrous layer has neither mark nor fold, neither irreversible deformation. Such a property is not verified by a fully plastic ID-1 card that will break or be irreversibly marked even before its two edges are in contact.
  • the Applicant has therefore sought to define the mechanical characteristics of the fibrous outer layer which make it possible to obtain a product having no mark, no fold or irreversible deformation under the conditions described above. After several attempts, the Applicant has demonstrated that the composition according to the invention makes it possible to obtain an outer fibrous layer having the following characteristics and having no mark, no crease or irreversible deformation during folding, in particular as described herein. -before. In particular at least two of the mechanical characteristics presented hereinafter, preferably all three, are verified by the outer fibrous layer according to the invention.
  • the Young's modulus is determined according to ISO 1924 "Paper and board - Determination of tensile properties” ("Part 2: Constant elongation gradient method”).
  • the fibrous outer layer may, for example, have a Young's modulus of less than 2000 MPa, preferably less than 900 MPa.
  • the double fold resistance is determined according to ISO 5626 "Paper - Determination of bending strength”.
  • the outer fibrous layer according to the invention may, for example, have a double fold resistance (Lhommargy measurement) greater than 5000, preferably greater than 7000 and more preferably greater than 10,000.
  • the elongation is determined according to ISO 1924 "Paper and board -
  • the fibrous outer layer according to the invention may, for example, have a running direction elongation (in the production direction on the paper machine) greater than 5%, preferably greater than 6%.
  • security elements that can be incorporated in the fibrous outer layer, some are detectable to the eye, daylight or artificial light, without the use of a particular device.
  • These security elements comprise for example colored fibers or boards, fully or partially printed or metallized wires. These security elements are called first level.
  • Additional security elements are detectable only with a relatively simple apparatus, such as a lamp emitting in the ultraviolet (UV) or infrared (IR).
  • UV ultraviolet
  • IR infrared
  • These security elements comprise, for example, fibers, boards, strips, wires or particles. These security elements may be visible to the naked eye or not, being for example luminescent under a lighting of a Wood lamp emitting in a wavelength of 365 nm. These security elements are said to be second level.
  • security elements require for their detection a more sophisticated detection device. These security elements are for example capable of generating a specific signal when they are subjected, simultaneously or not, to one or more external excitation sources. The automatic detection of the signal makes it possible to authenticate, if necessary, the document.
  • These security elements comprise, for example, tracers in the form of active materials, particles or fibers capable of generating a specific signal when these tracers are subjected to optronic, electrical, magnetic or electromagnetic excitation. These security elements are said to be third level.
  • Reagents may also be incorporated into the outer fibrous layer, for example chemical or biochemical reagents for tampering and / or authentication and / or identification which may react with at least one counterfeiting agent and / or authentication and / or identification.
  • the additional security element (s) present within the fibrous outer layer may have first, second or third level security features.
  • FIG. 1 represents an exemplary embodiment of a multilayer card according to the invention
  • FIG. 2 represents a cross-section along II-II of the map of FIG. 1,
  • FIG. 3 represents an alternative embodiment of a card body used within a multilayer card according to the invention.
  • FIG. 4 represents an alternative embodiment of a multilayer card according to the invention.
  • FIG. 1 shows a multilayer card 1 comprising two fibrous outer layers 2A and 2B disposed on either side of a card body 3.
  • Adhesive layers can extend between the card body 3 and the fibrous outer layers 2A and 2B so as to ensure the cohesion of the multilayer card 1.
  • the outer fibrous layers 2A and 2B may, for example, have respective thicknesses 1 and / 3 each of between 50 and 500 ⁇ , for example between 50 and 200 ⁇ .
  • I 1 and / 3 are substantially identical.
  • the card body 3 may, for example, have a monolayer structure as shown in FIG.
  • FIG. 3 shows an alternative embodiment in which the card body 3 has a multilayer structure, which comprises two plastic layers 10 A and 10 B disposed on either side of two paper layers 20 and 30.
  • Adhesive layers can extend between the different layers so as to ensure the cohesion of the card body 3.
  • the two plastic layers 10A and 10B comprise, for example, PVC or PET and have, for example, respective / 4 and / 5 thicknesses between 50 and 200 ⁇ .
  • the thicknesses / 4 and / 5 may be represented as being substantially equal or, alternatively, of different values.
  • the card body 3 may have a multilayer structure composed solely of paper layers or only layers of plastic material.
  • FIG. 2 shows a cross section of the multilayer card 1 of FIG. 1.
  • An RFID chip 40 and an antenna 50 may, for example, be included in the card body 3 and not lead to the surface.
  • FIG. 4 shows a variant embodiment in which the multilayer card 1 according to the invention comprises only a single fibrous outer layer 2.
  • a card is for example intended to receive an impression, preferably an inkjet on said single fibrous outer layer.
  • Example 1 Process for preparing a fibrous outer layer according to the invention
  • a fibrous suspension having the composition A below is available.
  • composition A Composition A
  • the natural fiber mixture has previously undergone a refining step according to the current papermaking process.
  • composition B is then mixed with the fibrous suspension of composition A.
  • a fibrous layer having a basis weight of 125 g / m 2 is obtained.
  • a fibrous outer layer according to the invention could be prepared by a process identical to that described above, except that composition B additionally comprises 12 kg per ton of fiber composition A fluorescent.
  • Example 2 Multilayer card according to the invention having a PVC card body without RFID
  • the card body is composed of six layers of PVC, supplied by the company Galazzi, each having a thickness of 100 ⁇ .
  • Two fibrous outer layers are disposed on either side of the card body.
  • the fibrous outer layers consist of a fibrous base of composition according to Example 1, except that in composition B, the synthetic fibers of polyamide of 1, 2 dtex and 4 mm in length are replaced by synthetic fibers of polyamide of 1.7 dtex and 6 mm in length, the dry weight introduced remaining the same.
  • a safety wire having an optically variable effect has been introduced into the window in said fibrous base.
  • the entire structure is hot rolled on a platen press at 140 ° C and 100 bar for 15 minutes.
  • the resulting card has the same properties as a traditional PVC card and does not mark when folded.
  • the resulting card has a thickness of 760 ⁇ +/- 80 ⁇ , that is to say in accordance with the ISO 7813 standard.
  • the card body is composed of three fibrous layers of composition according to Example 1 except that in the composition C, the latex styrene butadiene is replaced by an acrylic latex, the dry weight introduced remaining the same.
  • Each of the fibrous layers has a basis weight of 150 g / m 2 for a total thickness of 420 ⁇ .
  • Each of the layers is coated with Micryl 210 HP (pressure sensitive adhesive) sold by the company Planatol ®, on one of its faces.
  • Two fibrous outer layers are disposed on either side of the card body.
  • the fibrous outer layers with a basis weight of 175 g / m 2 consist of a fibrous base of composition according to Example 1 to which were added agglomerates of red fluorescent particles and a marker (or "taggant") in bulk.
  • the assembly is hot rolled at temperatures of the order of 130 ° C. and a pressure of 100 N / cm 2 for 15 minutes.
  • the resulting map is a map consisting essentially of paper.
  • This card is more flexible than a traditional plastic card and has no irreversible deformation after bending or folding tests as described above to characterize the mechanical characteristics of the fibrous outer layer.
  • This card is secured, on the one hand, by the agglomerates of red fluorescent particles and can be detected using the taggant specific detector integrated in the mass of the paper.
  • This card is delivered blank to the customer who can fully customize it by inkjet printing.
  • the resulting card has a thickness in accordance with the ISO 7813 standard.
  • the card body consists of a PAPERLAM ® structure, ie a stack of two layers of paper of respectively 220 and 155 g / m 2 , manufactured according to the method which follows. Each layer is coated with a heat-reactive adhesive, then an integrated microcircuit device is integrated between the two layers before bonding. Said integrated microcircuit device is adapted to the contactless communication technology described in the ISO 14443 standard, it is for example a module chip and an antenna made of wire depositing ("wire embedding").
  • a fibrous support is made on the paper machine so that the support comprises a fibrous base composed of about 15% by weight dry relative to the finished paper of synthetic polyamide fibers, about 6 mm in length, d. a linear density of about 1.7 dtex, and about 56% of cellulosic fibers.
  • the cellulosic fibers are composed of 80% by weight of long fibers and 20% by weight of short fibers.
  • the support also comprises about 13% by weight relative to the finished paper of at least one inorganic filler, introduced either at the refining or later in a mixer.
  • the mineral filler is, for example, kaolin.
  • the fibrous base after sheeting is surfaced on the paper machine by a size press system.
  • the size press contains a binder, for example polyvinyl alcohol, at a level of 4% by dry weight relative to the bath, a softening agent, for example glycerol, at 15% by dry weight relative to the bath, and pigments, for example kaolin, at a level of 4% by dry weight relative to the bath, ie a final solids content of 23%.
  • the paper When impregnating in a size press, the paper is impregnated with about 40 g / m 2 of wet bath, ie a dry recovery of about 9 g / m 2 sec.
  • the fibrous base is then coated on both sides by means of an air knife coater, with a coating color comprising 30 parts of acrylic styrene-type binder and 100 parts of a mixture of pigment-based pigments.
  • a coating color comprising 30 parts of acrylic styrene-type binder and 100 parts of a mixture of pigment-based pigments.
  • the layer removal on the support is of the order of 10 g / m 2 sec per side, for example.
  • This coated support offers good tear resistance thanks to the presence of synthetic fibers of 6 mm. It also offers flexibility due to the presence of synthetic fibers, bulk and surface fillers, as well as glycerine.
  • the surface layer comprising at least one thermoplastic binder
  • it offers a good aptitude for the insertion of an antenna by ultrasound as well as, because of the presence of so-called absorbent fillers such as silicate and alumina hydrate, absorption capacity and surface energy favorable for subsequent lamination.
  • Two fibrous outer layers each coated with a heat reactivatable adhesive on one side, are arranged on both sides of the preceding structure and sandwich the PAPERLAM ® structure.
  • the fibrous outer layers consist of a fibrous base of composition according to Example 1, with the difference that in the composition C, the 60 kg of titanium dioxide are replaced by 40 kg of titanium dioxide and 20 kg of kaolin.
  • the assembly is laminated on a platen press at temperatures of the order of 130 ° C., a pressure of 100 N / cm 2 for 15 minutes.
  • the resulting card is an electronic card (ID card, driver's license, resident card ”) secured by the RFID system and identifiable with fluorescent security fibers and boards.
  • ID card driver's license, resident card
  • These cards are supplied pre-printed in offset and are customized by inkjet printing, for example the name of the card holder and / or his photograph.
  • the resulting card has a thickness in accordance with the ISO 7813 standard.
  • Example 5 "Mixed" secure multilayer card, for example 80% paper and
  • Radio Frequency Identification Device RFID
  • contact module such a card is commonly referred to as “Dual Interface Card” “Dual Interface Card”.
  • the card body consists of a PAPERLAM ® structure with a module chip and an antenna made of wire embedding as well as a 100 ⁇ PVC layer on both sides of the structure. PAPERLAM ® .
  • Two fibrous outer layers each coated on one side with a heat activatable adhesive composed of an acrylic-based polymer are arranged on either side of the PVC layers sandwiching the PAPERLAM ® structure.
  • the fibrous outer layers consist of a fibrous base of composition according to Example 1 on which a holographic film has been applied.
  • the assembly is laminated on a platen press at temperatures of the order of 130 ° C., a pressure of 100 N / cm 2 for 15 minutes.
  • a contact module similar to those used in bank cards is inserted on the surface of the card by punching ("punchage") a fibrous outer layer and a PVC layer.
  • the resulting card is an electronic card (bank card, social security card ”) secured by the radio frequency identification system (“RFID”) and the contact module and identifiable by the holographic film.
  • RFID radio frequency identification system
  • the card body is composed of a PET layer with an "etched” aluminum antenna (that is to say made by ablation of metal) and a chip deposited by a gripper-depositor tool ("flip chip"), and than a fibrous layer of 130 g / m 2 according to the "method of manufacturing one of the paper layers constituting the PAPERLAM ® structure". Said fibrous layer is coated with a heat-activatable adhesive to compensate for the thickness of the chip.
  • the support thus obtained has an opening cavity in which the "flip chip” chip has been housed.
  • Two fibrous outer layers are disposed on both sides of the card body.
  • the fibrous outer layers consist of a fibrous base of composition according to Example 1 to which safety fluorescent fibers have been added.
  • the assembly is rolled on a roller press at a temperature of about 130 ° C.
  • the resulting structure is printed in offset then cut to the desired format.
  • the thickness of the structure is of the order of 350 to 400 ⁇ , this structure can for example be used as a loyalty card, ski pass or event ticket.
  • the event's personalization can be added ticket by ticket by inkjet printing.
  • a cell marked with a cross indicates that the ingredient indicated at the top of the column is present in the composition of the corresponding line
  • a cell marked with a minus sign ("-") indicates that the ingredient indicated at the top of the column is present in the composition but at a quantity less than the minimum value of this ingredient in a fibrous outer layer according to the invention.
  • Example Fibers Fibers Fillers Binder Comparative softener synthetic mineral cellulosic
  • the value 0 indicates that the outer fibrous layer is not printable, in particular layers which do not allow the ink to dry or whose printing has burrs,
  • the value 1 indicates an average printability, it is in particular an impression whose resolution can be estimated at a value between 180 and
  • the value 2 indicates good printability, it is particularly a print whose resolution can be estimated at a value greater than 600 dpi.
  • a multilayer card according to the invention may, for example, be a bank card, a social security card, a loyalty card, a ski pass, an event ticket or an electronic card (identity card, driving license. ..).
  • bearing (s) must be understood as "containing at least one”.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Credit Cards Or The Like (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
EP11748739.7A 2010-07-30 2011-07-13 Mehrlagige karte mit einer äusseren faserschicht Withdrawn EP2598324A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1056348A FR2963275B1 (fr) 2010-07-30 2010-07-30 Carte multicouche comportant une couche externe fibreuse
PCT/IB2011/053137 WO2012014112A1 (fr) 2010-07-30 2011-07-13 Carte multicouche comportant une couche externe fibreuse

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EP2598324A1 true EP2598324A1 (de) 2013-06-05

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US (1) US20140242356A1 (de)
EP (1) EP2598324A1 (de)
AR (1) AR082400A1 (de)
BR (1) BR112013002002A2 (de)
CA (1) CA2807239A1 (de)
FR (1) FR2963275B1 (de)
WO (1) WO2012014112A1 (de)

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WO2015049610A1 (fr) 2013-10-04 2015-04-09 Arjowiggins Security Structure multicouche de sécurité et procédé de fabrication associé

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FR2987577B1 (fr) * 2012-03-05 2014-10-24 Fasver Procede et dispositif de protection securitaire de documents officiels a l'aide d'un film transparent a couche continue unique thermoplastique
FR2992256A1 (fr) 2012-06-26 2013-12-27 Arjowiggins Security Element en feuille engravable par laser.
FR2997343B1 (fr) 2012-10-31 2015-04-24 Arjowiggins Security Carte securisee personnalisable par impression par transfert thermique.
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WO2012014112A1 (fr) 2012-02-02
AR082400A1 (es) 2012-12-05
CA2807239A1 (fr) 2012-02-02
FR2963275B1 (fr) 2012-08-17
BR112013002002A2 (pt) 2016-05-31
FR2963275A1 (fr) 2012-02-03

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