EP2570517B1 - Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse - Google Patents
Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse Download PDFInfo
- Publication number
- EP2570517B1 EP2570517B1 EP12008314.2A EP12008314A EP2570517B1 EP 2570517 B1 EP2570517 B1 EP 2570517B1 EP 12008314 A EP12008314 A EP 12008314A EP 2570517 B1 EP2570517 B1 EP 2570517B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrolysis
- anode
- electrode
- substrate
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 65
- 238000000034 method Methods 0.000 title claims description 34
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims description 29
- 229910052731 fluorine Inorganic materials 0.000 title claims description 29
- 239000011737 fluorine Substances 0.000 title claims description 29
- 239000000126 substance Substances 0.000 title claims description 12
- 230000002194 synthesizing effect Effects 0.000 title claims description 10
- 239000000758 substrate Substances 0.000 claims description 52
- 229910003460 diamond Inorganic materials 0.000 claims description 45
- 239000010432 diamond Substances 0.000 claims description 45
- 239000007789 gas Substances 0.000 claims description 23
- 229910021397 glassy carbon Inorganic materials 0.000 claims description 19
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 230000035699 permeability Effects 0.000 claims description 6
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 38
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 36
- 229910052799 carbon Inorganic materials 0.000 description 20
- 229910052759 nickel Inorganic materials 0.000 description 18
- 230000000694 effects Effects 0.000 description 17
- 230000000977 initiatory effect Effects 0.000 description 12
- 229910002804 graphite Inorganic materials 0.000 description 10
- 239000010439 graphite Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 239000002019 doping agent Substances 0.000 description 5
- 150000002222 fluorine compounds Chemical class 0.000 description 5
- 238000004050 hot filament vapor deposition Methods 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 150000004812 organic fluorine compounds Chemical class 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- 238000001764 infiltration Methods 0.000 description 4
- 230000008595 infiltration Effects 0.000 description 4
- 150000002484 inorganic compounds Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000001069 Raman spectroscopy Methods 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- -1 perfluoro compound Chemical class 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 229910021587 Nickel(II) fluoride Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910003481 amorphous carbon Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- DBJLJFTWODWSOF-UHFFFAOYSA-L nickel(ii) fluoride Chemical compound F[Ni]F DBJLJFTWODWSOF-UHFFFAOYSA-L 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229960001730 nitrous oxide Drugs 0.000 description 2
- 235000013842 nitrous oxide Nutrition 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 239000011698 potassium fluoride Substances 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- YPJHKJFGSWJFTM-UHFFFAOYSA-N 1,1,1-trifluoro-n,n-bis(trifluoromethyl)methanamine Chemical compound FC(F)(F)N(C(F)(F)F)C(F)(F)F YPJHKJFGSWJFTM-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910021594 Copper(II) fluoride Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910018499 Ni—F Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004769 chrono-potentiometry Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- GWFAVIIMQDUCRA-UHFFFAOYSA-L copper(ii) fluoride Chemical compound [F-].[F-].[Cu+2] GWFAVIIMQDUCRA-UHFFFAOYSA-L 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000012025 fluorinating agent Substances 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000013076 target substance Substances 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/245—Fluorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
Definitions
- fluorine or a fluorine-containing compound is synthesized by an electrolytical synthesis method.
- the method comprising conducting electrolysis using the electrode for electrolysis according to the present invention in an electrolytic bath comprising hydrofluoric acid and, added thereto, a substance to be fluorinated, is preferable.
- the electrolysis was stopped and the anode was taken out. As a result, the anode was found to have broken into powder in the electrolyzer.
- This electrode was attached to a (CH 3 ) 4 NF ⁇ 5HF electrolytic bath immediately after preparation of the bath.
- a nickel plate and Cu/CuF 2 were used as a cathode and a reference electrode, respectively, and constant-current electrolysis was conducted at a current density of 100 mA/cm 2 .
- the anode potential was measured and was found to be 4.6 V.
- the anode potential was 4.8 V.
- the electrolysis was stopped, and the anode was taken out and examined for contact angle between a surface of the electrode and water. As a result, the contact angle was found to be 150 degrees. It was hence ascertained that the so-called anode effect had occurred.
- Electrolysis was conducted in a (CH 3 ) 4 NF ⁇ 5HF electrolytic bath immediately after preparation of the bath, in the same manner as in Example 2 except that the electrode produced was used as an anode.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Claims (2)
- Procédé de synthèse électrolytique de fluor ou d'un composé contenant du fluor, dans lequel le procédé comprend la réalisation d'une électrolyse utilisant une électrode pour électrolyse dans un bain électrolytique comprenant du fluorure d'hydrogène anhydre avec ou sans substance à fluorer, caractérisé en ce que l'électrode pour électrolyse comprend :un substrat constitué de carbone vitreux ; etun film de diamant électriquement conducteur avec lequel au moins une partie du substrat est revêtue.
- Procédé de synthèse électrolytique de fluor ou d'un composé contenant du fluor selon la revendication 1, dans lequel la perméabilité au gaz du substrat est de 10-7 cm2/s ou inférieure.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009021157A JP2010174358A (ja) | 2009-02-02 | 2009-02-02 | 電解用陽極および該電解用陽極を使用するフッ素含有物質の電解合成方法 |
| EP10152341A EP2213770A1 (fr) | 2009-02-02 | 2010-02-02 | Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse |
Related Parent Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP10152341.3 Division | 2010-02-02 | ||
| EP10152341A Division EP2213770A1 (fr) | 2009-02-02 | 2010-02-02 | Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2570517A1 EP2570517A1 (fr) | 2013-03-20 |
| EP2570517B1 true EP2570517B1 (fr) | 2017-04-05 |
Family
ID=41716349
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12008314.2A Active EP2570517B1 (fr) | 2009-02-02 | 2010-02-02 | Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse |
| EP10152341A Withdrawn EP2213770A1 (fr) | 2009-02-02 | 2010-02-02 | Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP10152341A Withdrawn EP2213770A1 (fr) | 2009-02-02 | 2010-02-02 | Anode pour électrolyse et procédé de synthèse électrolytique d'une substance contenant du fluor à l'aide de l'anode pour électrolyse |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20100193371A1 (fr) |
| EP (2) | EP2570517B1 (fr) |
| JP (1) | JP2010174358A (fr) |
| KR (1) | KR101625010B1 (fr) |
| CN (2) | CN103014756A (fr) |
| TW (1) | TWI496953B (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009038192A1 (fr) * | 2007-09-20 | 2009-03-26 | Toyo Tanso Co., Ltd. | Substrat carboné et électrode permettant une production électrolytique du fluor |
| CN102560530A (zh) * | 2012-03-15 | 2012-07-11 | 中南大学 | 纳米镍质点增强的非石墨化导电碳阳极材料及其制备方法 |
| CN107604378A (zh) * | 2017-10-19 | 2018-01-19 | 浙江巨圣氟化学有限公司 | 一种全氟已烷的制备方法 |
| JP7310824B2 (ja) * | 2018-08-23 | 2023-07-19 | 株式会社レゾナック | 電解合成用陽極、及びフッ素ガスの製造方法 |
| CN112226783B (zh) * | 2020-10-27 | 2022-03-08 | 浙江诺亚氟化工有限公司 | 一种电化学联合氟化工艺 |
| KR20230172306A (ko) | 2022-06-15 | 2023-12-22 | (주) 테크윈 | 전기화학적 특성과 밀착력이 향상된 다이아몬드 전극 및 그 제조 방법 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2210968A1 (fr) * | 2007-09-20 | 2010-07-28 | Toyo Tanso Co., Ltd. | Substrat carboné et électrode permettant une production électrolytique du fluor |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3486268T2 (de) * | 1983-06-22 | 1994-07-07 | Atochem Elf Sa | Werkstoff auf Basis von stromleitfähigen Fasern, seine Herstellung und seine Anwendung, insbesondere zur Herstellung von katodischen Elementen. |
| US4753717A (en) * | 1985-03-25 | 1988-06-28 | Kanebo Ltd. | Porous article having open pores prepared from aromatic condensation polymer and use thereof |
| GB9221102D0 (en) * | 1992-10-07 | 1992-11-18 | British Nuclear Fuels Plc | An electrode |
| JPH091151A (ja) * | 1995-06-23 | 1997-01-07 | Showa Denko Kk | 水処理用炭素電極 |
| US6241956B1 (en) * | 1997-08-27 | 2001-06-05 | Nisshinbo Industries, Inc. | Glassy carbon and process for production thereof |
| JP3416066B2 (ja) | 1999-01-11 | 2003-06-16 | 科学技術振興事業団 | 電解フッ素化反応用電極と有機電解フッ素化方法 |
| FR2790268B1 (fr) * | 1999-02-25 | 2001-05-11 | Suisse Electronique Microtech | Cellule d'electrolyse a electrode bipolaire comportant du diamant |
| JP4535822B2 (ja) | 2004-09-28 | 2010-09-01 | ペルメレック電極株式会社 | 導電性ダイヤモンド電極及びその製造方法 |
| JP3893397B2 (ja) * | 2005-03-14 | 2007-03-14 | ペルメレック電極株式会社 | 電解用陽極および該電解用陽極を使用するフッ素含有物質の電解合成方法 |
| KR101030940B1 (ko) * | 2006-01-20 | 2011-04-28 | 토요 탄소 가부시키가이샤 | 불소 또는 삼불화 질소를 제조하는 전기 분해 장치 |
| JP4460590B2 (ja) * | 2007-06-22 | 2010-05-12 | ペルメレック電極株式会社 | 導電性ダイヤモンド電極構造体及びフッ素含有物質の電解合成方法 |
| JP4951429B2 (ja) | 2007-07-13 | 2012-06-13 | 第一電子工業株式会社 | コネクタ |
-
2009
- 2009-02-02 JP JP2009021157A patent/JP2010174358A/ja active Pending
-
2010
- 2010-02-01 US US12/697,593 patent/US20100193371A1/en not_active Abandoned
- 2010-02-01 CN CN2012104009951A patent/CN103014756A/zh active Pending
- 2010-02-01 CN CN2010101066614A patent/CN101928956A/zh active Pending
- 2010-02-02 EP EP12008314.2A patent/EP2570517B1/fr active Active
- 2010-02-02 EP EP10152341A patent/EP2213770A1/fr not_active Withdrawn
- 2010-02-02 KR KR1020100009597A patent/KR101625010B1/ko active IP Right Grant
- 2010-02-02 TW TW099102983A patent/TWI496953B/zh active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2210968A1 (fr) * | 2007-09-20 | 2010-07-28 | Toyo Tanso Co., Ltd. | Substrat carboné et électrode permettant une production électrolytique du fluor |
Non-Patent Citations (1)
| Title |
|---|
| NODA T ET AL: "Glass-like carbons", JOURNAL OF NON-CRYSTALLINE SOLIDS, NORTH-HOLLAND PHYSICS PUBLISHING. AMSTERDAM, NL, vol. 1, no. 4, 1 June 1969 (1969-06-01), pages 285 - 302, XP024060632, ISSN: 0022-3093, [retrieved on 19690601], DOI: 10.1016/0022-3093(69)90026-X * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2213770A1 (fr) | 2010-08-04 |
| TW201035384A (en) | 2010-10-01 |
| KR101625010B1 (ko) | 2016-05-27 |
| CN101928956A (zh) | 2010-12-29 |
| KR20100089037A (ko) | 2010-08-11 |
| US20100193371A1 (en) | 2010-08-05 |
| CN103014756A (zh) | 2013-04-03 |
| TWI496953B (zh) | 2015-08-21 |
| EP2570517A1 (fr) | 2013-03-20 |
| JP2010174358A (ja) | 2010-08-12 |
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