EP2546067A1 - Méthode pour la fabrication d'un matériau pour l'enregistrement sensible à la pression - Google Patents
Méthode pour la fabrication d'un matériau pour l'enregistrement sensible à la pression Download PDFInfo
- Publication number
- EP2546067A1 EP2546067A1 EP12155798A EP12155798A EP2546067A1 EP 2546067 A1 EP2546067 A1 EP 2546067A1 EP 12155798 A EP12155798 A EP 12155798A EP 12155798 A EP12155798 A EP 12155798A EP 2546067 A1 EP2546067 A1 EP 2546067A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- coating composition
- recording material
- producing
- material according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims description 27
- 239000008199 coating composition Substances 0.000 claims abstract description 55
- 239000000758 substrate Substances 0.000 claims abstract description 41
- 238000000576 coating method Methods 0.000 claims abstract description 29
- 239000011248 coating agent Substances 0.000 claims abstract description 28
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 25
- 239000011230 binding agent Substances 0.000 claims abstract description 16
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 7
- 238000005096 rolling process Methods 0.000 claims abstract description 7
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims description 27
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 25
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 25
- MFGZXPGKKJMZIY-UHFFFAOYSA-N ethyl 5-amino-1-(4-sulfamoylphenyl)pyrazole-4-carboxylate Chemical compound NC1=C(C(=O)OCC)C=NN1C1=CC=C(S(N)(=O)=O)C=C1 MFGZXPGKKJMZIY-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 14
- 239000005995 Aluminium silicate Substances 0.000 claims description 13
- 235000012211 aluminium silicate Nutrition 0.000 claims description 13
- 229920000126 latex Polymers 0.000 claims description 13
- 239000004816 latex Substances 0.000 claims description 13
- 229920002472 Starch Polymers 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 239000008107 starch Substances 0.000 claims description 12
- 235000019698 starch Nutrition 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000002174 Styrene-butadiene Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 7
- 239000011115 styrene butadiene Substances 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 238000010345 tape casting Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 11
- 239000000370 acceptor Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000002243 precursor Substances 0.000 description 7
- 206010013786 Dry skin Diseases 0.000 description 6
- 239000003094 microcapsule Substances 0.000 description 6
- 238000013461 design Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000011265 semifinished product Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000007645 offset printing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical class [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 2
- IAUKWGFWINVWKS-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene Chemical compound C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 IAUKWGFWINVWKS-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 101100453960 Drosophila melanogaster klar gene Proteins 0.000 description 1
- 239000004890 Hydrophobing Agent Substances 0.000 description 1
- 241000294754 Macroptilium atropurpureum Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- -1 for example Polymers 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- JFTNAXDYYMQUHC-UHFFFAOYSA-L zinc;4-nitrobenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=C([N+]([O-])=O)C=C1.[O-]C(=O)C1=CC=C([N+]([O-])=O)C=C1 JFTNAXDYYMQUHC-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
- B41M5/155—Colour-developing components, e.g. acidic compounds; Additives or binders therefor; Layers containing such colour-developing components, additives or binders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
Definitions
- zinc benzoates are generally known as color acceptors in color-reactive recording materials.
- the non-generic EP 1 375 182 A1 the zinc 4-nitrobenzoate, which is not identical to zinc salicylate, as a developer component in heat-sensitive recording materials.
- zinc benzoates and also those color developers, which include the zinc salicylate proposed here are disclosed as components of color-reactive recording materials, without mentioning the possible embodiments of such color reaction layers or even production processes for forming recording materials with such color reaction layers received.
- Subject of the US 4,257,935 A is a color-developing coating composition which, according to introductory passages, is to be used preferably for pressure-sensitive recording systems.
- a coating composition will contain, in addition to zinc salicylate as a color acceptor, and starch and Latex as a binder, a clay pigment, the possible involvement in which there proposes coating composition composition explanatory description is not mentioned.
- a SC (selfcontained) coating composition for forming a carbonless paper are disclosed for the zinc-salicylate as a color acceptor, a variety of possible components such as starch and polyvinyl alcohol as a binder and optionally also various pigments as possible fillers.
- CB layers (coated back), as understood in the present specification, contain microcapsules in which dye precursors are present in a suitable solvent.
- the application of a localized pressure to the CB coating causes the microcapsules to break up, resulting in a release of the previously encapsulated dye precursors.
- the dye precursor from the microcapsules with the zinc salicylate as at least one color acceptor within the CF layer together it comes to forming a color reaction, which takes place exactly where the microcapsules were previously broken by the pressure exerted: usually this happens along a script line, which is formed by inscription by means of pen or typewriter.
- an SC coating includes both encapsulated dye precursors and dye acceptors that react with these dye precursors upon release.
- CF recording materials produced by the method proposed herein color-forming to be bonded CB recording materials having microcapsules which largely not in terms of size and the leuco dyes preferably used therein are restricted.
- those microcapsules which have a wall material of melamine-formaldehyde resin with a preferred average capsule size in a range in particular of 4 to 6 ⁇ m are particularly well-proven.
- Diisopropylnaphthalene oil KMC oil from Rütgers Novares GmbH, Duisburg, Germany
- dye precursor leuco dyes in a range from 4 to 7.5% by weight.
- the formation of the web-like substrate in its execution as paper is done for example on a paper machine, in which at least one upstream Mischbütte a paper pulp of different pulps, optionally groundwood, fillers and water is applied and where preferred to this paper pulp before being fed to the paper machine other ingredients such as resin size for engine sizing and other conventional additives such as pigments, Nuancierfarbstoffe and / or optical brighteners are added.
- a paper machine in which at least one upstream Mischbütte a paper pulp of different pulps, optionally groundwood, fillers and water is applied and where preferred to this paper pulp before being fed to the paper machine other ingredients such as resin size for engine sizing and other conventional additives such as pigments, Nuancierfarbstoffe and / or optical brighteners are added.
- the first coating composition for forming a CF layer in addition to the zinc salicylate comprises at least one inorganic pigment selected from the list comprising: natural kaolin, calcined kaolin, silica, talc, natural calcium carbonate, precipitated calcium carbonate and aluminum (hydr). oxide.
- the CF layer it is possible for the CF layer to contain a pigment mixture, wherein the pigment mixture contains at least one inorganic pigment, more preferably at least two inorganic pigments, selected from the list respectively, comprising: natural kaolin, calcined kaolin, silicic acid, talc , natural Calcium carbonate, precipitated calcium carbonate and aluminum (hydr) oxide.
- the CF layer comprises a pigment mixture of exactly two materially different inorganic pigments, each selected from the list, comprising: natural kaolin, calcined kaolin, silicic acid, talc, natural calcium carbonate, precipitated calcium carbonate and aluminum (hydr) oxide ,
- the CF layer contains a pigment mixture exclusively of natural kaolin and precipitated calcium carbonate.
- the CF layer preferably contains at least a binder selected from the list comprising: styrene-butadiene latex, styrene-acrylate latex, starch, polyvinyl alcohol.
- styrene-butadiene latex which is used in particular together with starch.
- the zinc salicylate in a range of 4 to 14 wt .-%, most preferably in a range of 5.5 to 11.0 wt .-% - based on the Total weight of the CF layer - integrated in this layer.
- Silica, kaolin, aluminum (hydr) oxide and, in particular, natural and also precipitated calcium carbonate may be used as the inorganic pigment within this backside coating, and it is also conceivable to use a mixture of said inorganic pigments with one another or else with other inorganic pigments. If, in addition to the previously disclosed pigments, other pigments are to be used within the backside coating, it is preferred if these other inorganic pigments in a mixing ratio based on wt .-% to silica, aluminum (hydr) oxide or in particular natural or also precipitated calcium carbonate between 1: 4 and 1:25 are included within the second coating composition.
- Styrene-acrylate latex, starch, polyvinyl alcohol and very particularly preferably styrene-butadiene latex are suitable as binders within this backside coating.
- Wax and / or AKD glue are used in particular as a means of hydrophobing the pigmented coating.
- the application of the second coating composition to form a pigmented and preferably hydrophobic coating on the back side of the substrate is preferably accomplished by means of a coater selected from the list comprising: roller coater, curtain coater, doctor blade and doctor blade coater.
- the second coating composition used to form this pigmented backside coating is also preferably aqueous.
- the subsequent drying of the second coating composition after the application is again usually carried out by a method in which heat is supplied, as is done by hot-air floatation dryer or contact dryer. Proven is also a combination of the listed dry processes.
- the areal mass of the pigmented backcoat of the second coating composition is preferably between 2.5 and 4.2 g / m 2, and more preferably between 2.7 and 3.7 g / m 2 .
- a paper web of bleached and ground deciduous and softwood pulps with a basis weight of 47 g / m 2 is prepared as standard additives in conventional amounts and in particular with the addition of resin size for engine sizing and at the end of the paper machine as a semi-finished product rolled up on a spool.
- a first coating composition to form a CF film and a second curtain coater using a second curtain coater in its slot die design become a second coating composition Formed a pigmented and hydrophobic coating and dried each.
- the second coating composition contains as main constituents natural calcium carbonate as pigment, styrene-acrylate latex and starch as binder mixture and AKD glue as a means for hydrophobizing the pigmented backcoat. While the back coating is applied with a basis weight of 3.0 g / m 2 , the basis weight for the CF layer is 4.0 g / m 2 .
- the CF layer is alternatively formed from seven different first coating compositions, these coating compositions differing as shown in Table 2 below.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
- Color Printing (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12155798.7A EP2546067B1 (fr) | 2011-07-14 | 2012-02-16 | Méthode pour la fabrication d'un matériau pour l'enregistrement sensible à la pression |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11173923.1A EP2546066B2 (fr) | 2011-07-14 | 2011-07-14 | Matériel d'enregistrement sensible à la pression et procédé pour sa fabrication |
| EP12155798.7A EP2546067B1 (fr) | 2011-07-14 | 2012-02-16 | Méthode pour la fabrication d'un matériau pour l'enregistrement sensible à la pression |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2546067A1 true EP2546067A1 (fr) | 2013-01-16 |
| EP2546067B1 EP2546067B1 (fr) | 2014-04-09 |
Family
ID=44971135
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11173923.1A Active EP2546066B2 (fr) | 2011-07-14 | 2011-07-14 | Matériel d'enregistrement sensible à la pression et procédé pour sa fabrication |
| EP12155798.7A Active EP2546067B1 (fr) | 2011-07-14 | 2012-02-16 | Méthode pour la fabrication d'un matériau pour l'enregistrement sensible à la pression |
| EP12175324.8A Active EP2546068B1 (fr) | 2011-07-14 | 2012-07-06 | Matériel d'enregistrement pour formation induite par pression d'un sigle et procédé de fabrication d'un tel matériel d'enregistrement |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11173923.1A Active EP2546066B2 (fr) | 2011-07-14 | 2011-07-14 | Matériel d'enregistrement sensible à la pression et procédé pour sa fabrication |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12175324.8A Active EP2546068B1 (fr) | 2011-07-14 | 2012-07-06 | Matériel d'enregistrement pour formation induite par pression d'un sigle et procédé de fabrication d'un tel matériel d'enregistrement |
Country Status (3)
| Country | Link |
|---|---|
| EP (3) | EP2546066B2 (fr) |
| ES (2) | ES2525570T5 (fr) |
| PL (1) | PL2546066T5 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102014108341A1 (de) * | 2014-06-13 | 2015-12-17 | Papierfabrik August Koehler Se | CF-Papier |
| ES2623811T3 (es) | 2014-07-29 | 2017-07-12 | Mitsubishi Hitec Paper Europe Gmbh | Material de registro termosensible con un derivado del ácido salicílico como revelador (del color) capaz de reaccionar con un precursor de colorante |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4257935A (en) | 1975-11-28 | 1981-03-24 | Sumitomo Naugatuck Co., Ltd. | Color developing sheet for pressure-sensitive recording systems |
| EP0360522A2 (fr) | 1988-09-16 | 1990-03-28 | The Mead Corporation | Composition révélatrice |
| EP0485064A1 (fr) | 1990-11-07 | 1992-05-13 | The Standard Register Company | Encre auto-chromogène pour l'impression contenant un pourcentage élevé de solides |
| EP1375182A1 (fr) | 2001-04-04 | 2004-01-02 | Nippon Soda Co., Ltd. | Mat riau et feuille d'enregistrement |
| EP2161255A1 (fr) | 2002-03-14 | 2010-03-10 | Nippon Soda Co., Ltd. | Composés phénoliques et matériaux d'enregistrement les contenant |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4360548A (en) † | 1980-10-24 | 1982-11-23 | The Standard Register Company | Self-contained covert image |
| JPS6013839B2 (ja) † | 1980-11-12 | 1985-04-09 | 十條製紙株式会社 | 感圧複写用顕色シ−ト |
| GB2106529B (en) * | 1981-08-05 | 1985-06-12 | Monsanto Co | Solvent systems containing a high proportion of diluent for pressure-sensitive copying systems |
| JP2828634B2 (ja) † | 1988-07-18 | 1998-11-25 | 王子製紙株式会社 | 感圧複写用呈色紙 |
| JP2786510B2 (ja) † | 1989-11-22 | 1998-08-13 | 株式会社三光開発科学研究所 | 顕色剤水分散液の製造方法及びそれを用いた感圧記録紙 |
| DE4224719C3 (de) † | 1992-07-27 | 2002-03-07 | Mitsubishi Hitec Paper Bielefe | Verfahren zur Herstellung einer eine CF-Schicht aufweisenden Papierbahn für druckempfindliches Durchschreibepapier |
| DE4342140C2 (de) † | 1993-12-10 | 1997-03-06 | Zanders Feinpapiere Ag | Aufzeichnendes Blatt für druckempfindliche Aufzeichnungssysteme |
| JP2002347339A (ja) † | 2001-05-30 | 2002-12-04 | Oji Paper Co Ltd | 感圧記録紙およびその製造方法 |
| JP2005111695A (ja) † | 2003-10-03 | 2005-04-28 | Nippon Paper Industries Co Ltd | 感圧複写用顕色シート |
| CN101373183B (zh) † | 2008-08-01 | 2012-04-18 | 东莞市天盛特种纸制品有限公司 | 用基准纸检测无碳复写纸cb面和cf面显色方法 |
-
2011
- 2011-07-14 EP EP11173923.1A patent/EP2546066B2/fr active Active
- 2011-07-14 PL PL11173923T patent/PL2546066T5/pl unknown
- 2011-07-14 ES ES11173923.1T patent/ES2525570T5/es active Active
-
2012
- 2012-02-16 ES ES12155798.7T patent/ES2477553T3/es active Active
- 2012-02-16 EP EP12155798.7A patent/EP2546067B1/fr active Active
- 2012-07-06 EP EP12175324.8A patent/EP2546068B1/fr active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4257935A (en) | 1975-11-28 | 1981-03-24 | Sumitomo Naugatuck Co., Ltd. | Color developing sheet for pressure-sensitive recording systems |
| EP0360522A2 (fr) | 1988-09-16 | 1990-03-28 | The Mead Corporation | Composition révélatrice |
| EP0485064A1 (fr) | 1990-11-07 | 1992-05-13 | The Standard Register Company | Encre auto-chromogène pour l'impression contenant un pourcentage élevé de solides |
| EP1375182A1 (fr) | 2001-04-04 | 2004-01-02 | Nippon Soda Co., Ltd. | Mat riau et feuille d'enregistrement |
| EP2161255A1 (fr) | 2002-03-14 | 2010-03-10 | Nippon Soda Co., Ltd. | Composés phénoliques et matériaux d'enregistrement les contenant |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2525570T5 (es) | 2018-11-07 |
| EP2546067B1 (fr) | 2014-04-09 |
| PL2546066T3 (pl) | 2015-02-27 |
| EP2546066B1 (fr) | 2014-09-10 |
| EP2546066A1 (fr) | 2013-01-16 |
| EP2546068A1 (fr) | 2013-01-16 |
| PL2546066T5 (pl) | 2018-10-31 |
| EP2546068B1 (fr) | 2014-09-10 |
| ES2477553T3 (es) | 2014-07-17 |
| EP2546066B2 (fr) | 2018-06-27 |
| ES2525570T3 (es) | 2014-12-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3221153B1 (fr) | Materiel d'enregistrement sensible a la chaleur | |
| DE3024205C2 (de) | Aufzeichnungspapier für Tintenspritzaufzeichnungsverfahren | |
| DE3787449T2 (de) | Thermisches aufzeichnungsblatt hoher qualität und herstellungsverfahren. | |
| DE1275550B (de) | Druckempfindliches Aufzeichnungsmaterial | |
| DE1671561B2 (de) | Aufzeichnungspapier | |
| EP3098085A1 (fr) | Matériau de transfert pour l'impression par sublimation | |
| EP0387893B1 (fr) | Papier d'enregistrement par jet d'encre | |
| WO2011067004A1 (fr) | Matière d'enregistrement thermosensible comprenant un revêtement barrière | |
| DE60127424T2 (de) | Aufzeichnungsmaterial mit einem eingebetteten bild | |
| EP2546067B1 (fr) | Méthode pour la fabrication d'un matériau pour l'enregistrement sensible à la pression | |
| DE60312134T2 (de) | Tintenstrahlaufzeichnungsmedium und herstellungsverfahren dafür | |
| DE19604907A1 (de) | Verfahren zur Herstellung von hoch-abriebfesten Auftragsschichten | |
| EP0652808B1 (fr) | Procede de fabrication de bandes de papier a couches de reception ou d'emission utiles comme papiers d'enregistrement sensibles a la pression | |
| DE3328064C2 (fr) | ||
| DE102005050418A1 (de) | Wärmeempfindliches Aufzeichnungsmaterial | |
| EP1543984B1 (fr) | Matériau d'enregistrement sensible à la chaleur pour l'impression recto-verso | |
| EP2505374B1 (fr) | Matériel d'enregistrement sensible à la chaleur, son utilisation et son procédé de fabrication | |
| DE4224719C3 (de) | Verfahren zur Herstellung einer eine CF-Schicht aufweisenden Papierbahn für druckempfindliches Durchschreibepapier | |
| DE2012129A1 (de) | Blattförmiges Aufzeichnungsmaterial | |
| DE3923586A1 (de) | Akzeptor-beschichtetes blatt fuer ein druckempfindliches kopiersystem | |
| EP2636532B1 (fr) | Procédé de fabrication d'un matériel d'enregistrement doté d'une marque d'authentification | |
| DE2018998A1 (de) | Aufzeichnungsblatt | |
| EP2487044A1 (fr) | Procédé de fabrication d'un matériel d'enregistrement sensible à la chaleur | |
| EP2517889A1 (fr) | Matériel d'enregistrement sensible à la chaleur avec une marque d'authentification | |
| EP1527900A1 (fr) | Matériau pour l'enregistrement par la chaleur, son utilisation et méthode pour sa fabrication |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| AX | Request for extension of the european patent |
Extension state: BA ME |
|
| 17P | Request for examination filed |
Effective date: 20130716 |
|
| RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| RIC1 | Information provided on ipc code assigned before grant |
Ipc: B41M 5/124 20060101ALI20130916BHEP Ipc: B41M 5/155 20060101AFI20130916BHEP |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| INTG | Intention to grant announced |
Effective date: 20131029 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP Ref country code: AT Ref legal event code: REF Ref document number: 661130 Country of ref document: AT Kind code of ref document: T Effective date: 20140415 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502012000565 Country of ref document: DE Effective date: 20140522 |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: T3 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2477553 Country of ref document: ES Kind code of ref document: T3 Effective date: 20140717 |
|
| REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140709 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140809 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140709 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140710 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140811 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502012000565 Country of ref document: DE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed |
Effective date: 20150112 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502012000565 Country of ref document: DE Effective date: 20150112 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150228 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150216 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150228 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150228 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150216 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 5 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 6 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20120216 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 7 |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 661130 Country of ref document: AT Kind code of ref document: T Effective date: 20170216 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170216 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140409 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20240301 Year of fee payment: 13 Ref country code: NL Payment date: 20240222 Year of fee payment: 13 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240228 Year of fee payment: 13 Ref country code: GB Payment date: 20240221 Year of fee payment: 13 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20240227 Year of fee payment: 13 Ref country code: FR Payment date: 20240227 Year of fee payment: 13 |