Classifications

• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F24—HEATING; RANGES; VENTILATING
  • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
  • F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
  • F24S23/70—Arrangements for concentrating solar-rays for solar heat collectors with reflectors
  • F24S23/71—Arrangements for concentrating solar-rays for solar heat collectors with reflectors with parabolic reflective surfaces
  • F24S23/715—Arrangements for concentrating solar-rays for solar heat collectors with reflectors with parabolic reflective surfaces flexible
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F24—HEATING; RANGES; VENTILATING
  • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
  • F24S23/00—Arrangements for concentrating solar-rays for solar heat collectors
  • F24S23/70—Arrangements for concentrating solar-rays for solar heat collectors with reflectors
  • F24S23/81—Arrangements for concentrating solar-rays for solar heat collectors with reflectors flexible
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F24—HEATING; RANGES; VENTILATING
  • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
  • F24S25/00—Arrangement of stationary mountings or supports for solar heat collector modules
  • F24S25/10—Arrangement of stationary mountings or supports for solar heat collector modules extending in directions away from a supporting surface
  • F24S25/13—Profile arrangements, e.g. trusses
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F24—HEATING; RANGES; VENTILATING
  • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
  • F24S30/00—Arrangements for moving or orienting solar heat collector modules
  • F24S30/40—Arrangements for moving or orienting solar heat collector modules for rotary movement
  • F24S30/42—Arrangements for moving or orienting solar heat collector modules for rotary movement with only one rotation axis
  • F24S30/425—Horizontal axis
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E10/00—Energy generation through renewable energy sources
  • Y02E10/40—Solar thermal energy, e.g. solar towers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E10/00—Energy generation through renewable energy sources
  • Y02E10/40—Solar thermal energy, e.g. solar towers
  • Y02E10/47—Mountings or tracking
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T29/00—Metal working
  • Y10T29/49—Method of mechanical manufacture
  • Y10T29/49826—Assembling or joining

Definitions

• the present invention relates to a parabolic collector for the concentration of solar radiation according to the preamble of claim 1, a single collector according to claim 11 and a method for producing the parabolic collector according to claim 13.
• parabolic collectors whose reflective surface has a number of individual collectors are known.
• parabolic collectors have a diameter of 5 to 10 meters, with individual mirrors attached to a scaffold so that an ideal (i.e., geometrically correct) paraboloid approximates as closely as possible.
• an ideal parabolic mirror approximates as closely as possible.
• the individual mirrors are often curved only spherically or not at all, in the framework, however, aligned with the focal point of the (ideal) paraboloid, so that the overall result is an acceptable concentration of sunlight at a reasonable cost.
• An industrial use of such parabolic mirrors is despite the construction of different larger solar power plants not or hardly available today.
• the temperatures generated in the solar tower are 1000 ° C.
• Parabolic trough power plants are in operation today in large numbers and already operate comparatively economically.
• Parabolic trough power plants have (like the solar tower systems) collectors in large numbers, with parabolic trough power plants long concentrators are provided with a small transverse dimension, which thus have not a focal point, but a focal line.
• These line concentrators today have a length of 20 m to 150 m.
• An absorber tube for the concentrated heat (up to around 500 ° C) runs along the focal line and transports it to the power plant.
• Transport medium z.Bsp. Thermal oil or superheated steam in question.
• thermolysis is also environmentally neutral, ie for the production of hydrogen from water, although temperatures above 2200 ° C. are required.
• a widely applicable technology is not available today.
• Lower temperatures, but still temperatures in the range of 1500 ° C to 2000 ° C, require two-step water splitting cycles based on so-called metal oxide redox systems.
• metal oxide redox systems for example, in a first step at a temperature of about 2000 ° C zinc oxide decomposed into metallic zinc and oxygen, wherein the oxygen can be released into the atmosphere or further utilized.
• the second step involves the reaction of zinc with water, releasing hydrogen and transforming the zinc back into zinc oxide.
• the hydrogen can then be burned as an energy source, as mentioned above: environmentally neutral.
• environmentally neutral please refer to the article "Hydrogen from Water and Solar Energy” by Anton Meier, Christian Wieckert and Aldo Steinfels in: Alternative Energy Technology, Bulletin SEV / VSE 24/25 05. It is obvious that the cycle of renewable fuels is completely environmentally neutral can be kept if the production of renewable fuels is carried out by energy generated in solar power plants. However, the required high temperatures presuppose a high concentration of sunlight, whose upper limit in turn depends on the geometry of the earth-sun, ie on the opening angle of the solar disk observed from the earth.
• a parabolic collector having the characterizing features of claim 1, a single collector according to claim 11 and a method for producing a parabolic collector according to claim 13.
• the curvature in one direction must be the parabolic and the curvature in the other direction must be the circular arc of the collector at least approximate.
• the geometry of the individual collectors can be determined in a simple manner for perfect fitting in the geometrically complicated paraboloid-shaped reflecting surface of the collector.
• Fig. 2 shows schematically a single collector, as in the parabolic collector according to FIG.
• FIG. 3 shows a cross section through an embodiment of the collector of Fig. 2nd
• Fig. 4 shows schematically how a single collector according to FIG. 2 can be determined in its dimensions, so that it can be fitted operatively in the parabolic collector, and
• FIG. 5 shows a pattern for the arrangement of individual collectors in a parabolic collector according to FIG. 1 6 a shows schematically a first exemplary embodiment of the parabolic collector according to the invention, the individual collectors of which are integrated in a concrete framework,
• FIG. 6b shows the parabolic collector of FIG. 6a from above, FIG.
• FIG. 6c is a section along the line AA of Fig. 6a
• Fig. 6d is a section along the line BB of Fig. 6a
• Fig. 7 shows another embodiment with smaller dimensions, suitable for a concentration of 4000.
• Fig. 1 shows a parabolic collector 1, wherein on its outer side a surface line la and a circumferential line lb are shown as auxiliary lines.
• the collector 1 is pivotably mounted on a bearing 2 shown schematically so that it can be continuously aligned with the migratory sun.
• Sun rays 3 fall on the interior of the collector skeleton 4, also shown only schematically, in which individual collectors 5 are arranged.
• the individual collectors 5 are designed such that they reflect the incident on them sun rays 3 against an absorber element 6, in which by the high concentration of the radiation 3 temperatures in the desired amount of about 1000 ° C, up to 2000 ° C or 2500 ° C. and more can be achieved.
• the individual collectors 5 together form the reflecting surface 7 of the parabolic collector 1, which approximates an ideal paraboloid as well as possible, but not completely. Accordingly, the reflected beams 3 'are not concentrated in a focal point but in a focal point area.
• the extent of the focal point region depends on the design of the particular parabolic collector, which is determined by the person skilled in the art according to local requirements, and is entirely intentional to a minimum extent, since temperature peaks would occur if the focal region is too small, which are even higher than the above-mentioned desired temperatures and therefore could destroy the absorber element 6.
• the absorber element 6 is suspended on a carrier 8 shown schematically, in which also the lines for the heat-transporting medium are arranged.
• a reactor may be provided at the location of the absorber element in which, for example, the first stage of a water splitting cycle takes place. It is understood, however, that the present invention by no means limited to such processes, but is applicable anywhere where 6 high temperatures are desired at the location of the absorber element.
• FIG 2 shows schematically a particular embodiment of a single collector 10, as it can be used in a parabolic collector 1 ( Figure 1).
• the single collector 10 has a frame 11 in which a pressure cell 12 is stretched from flexible films.
• the top sheet 13 is transparent to incoming beams 3 (and, of course, for outgoing beams 3 ').
• the lower film is formed as a concentrator 14 and covered with a reflective layer of preferably vapor-deposited aluminum, which generates the reflected beams 3 '.
• these films are Mylar® which is a widely known trade name for a biaxially oriented polyester film, for example, polyenthylene terephthalate.
• these films are also possible to use other films or membranes of any type known to the person skilled in the art.
• the upper, transparent film 13 ETFE (Ethylene TetrafluoroEthylene) with 20 to 200 microns thickness while in particular for the lower film 14, as mentioned, an aluminum-coated Mylar or a PVC, PU or silicone-coated Textiles Tissue such as polyester fabric or fiberglass fabric or other suitable material having a reflective layer in question.
• the above components can also be suitably combined.
• Textile fabrics of the type mentioned are z.Bsp. known under the name Precontraint® 1002/1202/1302 by FERRARI or ATEX 3000 by Interglass.
• Pressure cells for use in trough collectors are known in the art, for example from the above-mentioned WO 2008/037108.
• auxiliary lines 15, 15 "and 16, 16 ' shown in the figure illustrate the Curvature of the concentrator 14 and show the curvature of the upper film 13 and the concentrator 14 under operating pressure conditions of the pressure cell 12th
• auxiliary lines 15, 15 'running in a first direction have a greater curvature than the auxiliary lines 16, 16' extending in a second direction.
• These predetermined different curvatures as described below are each approximately spherical and determined by the contour of the frame 11 in which they are clamped (of course, for the length of the radii of curvature and the operating pressure in the pressure cell 12 and the extensibility of the concentrator membrane or concentrator membrane relevant).
• auxiliary lines 15 ' are essentially the same but smaller than the radii of curvature of the frame 11 (in the direction of the main axis of the frame 11) extending) auxiliary lines 16,16 '.
• radii of curvature for the sake of clarity, reference is made to radii of curvature, although, as mentioned, a spherical or parabolic curvature is formed only approximately.
• the concentrator 14 forms the parabolic-shaped wall portion of the parabolic collector 1 with good accuracy.
• the installation position is such that the main axis of the frame 11 is aligned along a surface line la, so that the auxiliary line 16 'substantially coincide with a surface line la and the auxiliary lines 15' substantially with circumferential lines lb.
• the real curvature of the concentrator 14 follows very well on the one hand in the first direction (auxiliary line 16 ') which is parabolic towards the outside widening shape of the reflecting surface 7 and on the other hand in the second direction (auxiliary lines 15 ') also the outwardly flared circular periphery of the reflecting surface 7 ( Figure 1).
• the real curvature of a respective concentrator 14 (with proper sizing and positioning of the frame 11, see below) is sufficiently well approximated to the ideal parabolic area to concentrate the reflected rays 3 'to a focal region having the required high temperatures in the absorber element 6 allowed.
• films known by the name Mylar are orthotropic, ie that their modulus of elasticity is higher in one direction, for example by 10 to 15%, than in the other direction.
• This property can be used advantageously: preferably, the film is arranged in the elliptical frame 10, 22 so that the direction with the higher modulus of elasticity coincides with the main axis. This improves the curvature in the second direction (auxiliary line 16 ') and leads to a measurably increased concentration or a focal point area reduced in the corresponding direction.
• Fig. 3 shows a preferred embodiment of a single collector 20, the frame 21 is also formed elliptical.
• the single collector 20 has a double pressure cell 22, formed of an outer, transparent film or membrane 23, a rear side or membrane 24 and the concentrator 25, the space between the transparent film 23 and the rear foil 24 into a front pressure zone 26 and a rear pressure zone 27 divides.
• This configuration allows a small pressure difference ⁇ between the pressure zones 26 and 27 at a sufficiently high total pressure to operably stabilize the dual pressure cell 22 for use.
• the front pressure zone 26 of the double-pressure cell 22 is set under the pressure p + ⁇ of preferably ambient air, with air passing from the front pressure zone 26 into the rear pressure zone 27 via an overflow channel 31.
• Another, preferably designed as a fan 32 pump maintains the necessary, small pressure difference .DELTA. ⁇ , which is required to bend the concentrator 25 in the double pressure cell 22 operable, such that rays 3 predetermined in a Brennticianbe- be richly concentrated.
• This arrangement has the advantage that ⁇ can be kept low and, accordingly, a very thin concentrator membrane or concentrator membrane with a smooth surface can be used, which supports a high concentration of the radiation 3.
• a single collector having a flexible film concentrator is much less expensive to manufacture than a conventional concentrator of the same quality.
• the pressure cell via which the concentrator is acted upon by the operating pressure, for example, as a simple pressure cell 12, as a double pressure cell 22 or (not shown) vacuum cell may be formed, wherein in the case of the vacuum cell one of its outer walls is designed as a flexible concentrator, the is forced by the atmospheric pressure in the vacuum cell and thus forms its curvature.
• the person skilled in the art can determine any suitable construction of a pressure cell for the specific case.
• FIG. 4 shows a method for producing a parabolic collector whose reflective surface has individual collectors with a concentrator pressurized during operation, wherein the concentrator of the individual collectors is designed as a film or membrane curved differently in different directions.
• a single collector with elliptical clamping of the concentrator foil (shown on the elliptical frame 11, 21 of the individual collectors 10, 20) satisfies these basic conditions particularly well, so that such an elliptically mounted concentrator foil has a corresponding elliptical shape Wall section from a paraboloid (ie, from the reflective surface 7 of the parabolic collector 1 of Figure 1) sufficiently well approaches to allow the desired concentration of the radiation 3.
• the prerequisite for this is that the geometry of the elliptical clamping of the concentrator foil is matched to the location of the installation in the paraboloid.
• the parabolic collector is designed in accordance with the desired properties in the specific case, and thus the paraboloid 40 representing reflecting surface 7 of the parabolic collector 1 (Figure 1) determined.
• the paraboloid 40 is shown in an xyz coordinate system, as well as its dashed lines indicated plan 41 in the xy plane.
• the z-axis coincides with the axis of symmetry of the polyaroid 40, which is thus perpendicular to the ground plane formed by the xy plane.
• a cylinder 43 On a floor plan 42, which is located within the plan view 41 of the paraboloid, a cylinder 43 is provided, whose longitudinal axis is parallel to the z-axis of the coordinate system. Shown in the figure are generatrices 44 of the cylinder 43.
• the cylinder 43 pierces it, the section of the two bodies being an ellipse 46.
• the ellipse 46 in turn has the desired geometry of the clamping of a concentrator so that it approaches the corresponding, bounded by the ellipse 46 wall portion of the paraboloid 40 sufficiently: the ratio of the major axis of the obtained ellipse 46 to the minor axis is such that the consequent Curvature of the concentrator foil in the direction of the circumference and fits in the direction of the generatrix of the paraboloid.
• the ellipse 46 thus defines the (ideal) paraboloid of the corresponding collector lying frame 11,21 ( Figures 2 and 3) and the clamping for a one cell collector 10,20 ( Figures 2 and 3). It also defines the associated with their geometry installation location of a single collector 5 in the parabolic collector 1 ( Figure 1).
• the ellipse 46 has the following properties: on the one hand, its main axis, and thus the main axis of a corresponding concentrator, lies in a plane passing through the symmetry axis of the parabolic collector 1.
• the minor axis perpendicular to the main axis lies in a plane perpendicular to the symmetry axis of the collector.
• FIG. 5 shows a method with which the arrangement of all individual collectors to be arranged in a parabolic collector can be determined. Shown is a top view of the floor plan xy with the plan view 41 of the paraboloid 40. Lines 50, 51 and 52 form a pattern of equilateral triangles and intersect at nodes 53 which lie in the corners of these triangles.
• One of the nodes 53 is preferably at the origin of the coordinate system xy.
• the nodes 53 are centers of the ground plan circles 55, the radii of which are preferably chosen such that the circles adjoin one another. For all floor plans completely within the plan 41 of the paraboloid 40, the section of the cylinders standing thereon can be determined with the paraboloid and thus the geometry of an associated individual collector.
• the distance of the individual collectors from the origin can be selected such that only the location of the shadow is provided by the absorber element 6 ( Figure 1) without a single collector.
• the radii of the ground plan circles 55 are preferably determined so that the circles 55 adjoin one another, whereby the surface portion of the ground plan circles 55 and the total area of the floor plan 41 becomes as large as possible. This then also applies to the individual collectors installed in the parabolic collector, whose surface portion on the surface of the paraboloid 40 formed by the parabolic collector (FIG. 4) is also as large as possible.
• the skilled person can not provide the arrangement of the ground plans 55 on the corners of an (equilateral) triangle, but choose another (symmetrical or non-symmetrical) pattern, which serves to optimize a determining parameter in the design of the parabolic collector, as in concrete case appears appears.
• the radii of the floor plans are of different sizes to fill gaps between adjacent Grundrissniken optimally or to occupy the areas on the edge of the parabolic collector 1 nor with individual collectors.
• the grid is selected such that a first group of individual collectors are equidistantly spaced from one another and from the origin of the ideal paraboloid, ie, annular around it.
• a second group is in turn arranged in the same way, but with a greater distance from the origin, and such that the individual collectors of the second group are placed with their inwardly extending ends between the individual collectors of the first group, and so the parabolic collector with Single collectors is tightly packed.
• FIG. 6 a shows a view of a first exemplary embodiment of a parabolic collector 60 according to the invention, the individual collectors 61 of which are integrated in a support structure 62 made of concrete.
• a support structure for large parabolic collectors with the above-mentioned diameters up to 30 m, 50 m or more, while at the same time individual panels 61 can be used in a according to the specific case by a person of skill considered suitable size , It is expected that a diameter of 15 to 20m will already be sufficient to provide both the required high temperatures and a power of 100 kW (15 m) or 200 kW (20 m).
• the width of the concentrators may be determined by the available film. Suitable foils today are essentially available up to a width of 2 m, which (today) limits the width of the concentrators to 2 m, unless a welding of several foil webs is provided. Welding is demanding in terms of production technology if no deterioration in the concentration of the concentrator produced in this way can be accepted.
• the concept according to the invention allows individual concentrators 61 of very different sizes. At the same time high power can be achieved by large parabolic collectors 60 at the high temperatures achievable according to the invention.
• FIG. 6b shows the parabolic collector 60 from above, so that the figure simultaneously corresponds to its ground plan.
• Various individual collectors are designated 61, 61 'to 61 "" and 61 *.
• FIG. 6c shows the parabolic collector 60 in section AA of Figure 6b.
• the concrete structure 62 consisting of concrete is shown hatched.
• negative pressure chambers 63 and 64 formed by the concrete structure 62 are closed by the concentrators 61 'and 61 "Suitable means for producing underpressure, such as hose connections to a central vacuum pump (again selected and dimensioned by a person skilled in the art in a concrete case Due to the negative pressure in the vacuum chambers 63, 64, the respective concentrator 61 ', 61 "is pressure-loaded above the atmospheric pressure, so that the predetermined curvature of the concentrators 61', 61" is formed.
• FIG. 6d shows the parabolic collector 60 in section BB of FIG. 6b.
• FIG. 7 shows a further exemplary embodiment of a parabolic commutator 70 according to the invention with individual collectors 71, 72 which have a length of the main axis in the region of 500 mm.
• the individual collectors 71, 72 are arranged on a simple metal frame 75.
• Another frame 76 carries an unillustrated to relieve the figure absorber element.
• the structure of the individual concentrators 71, 72 used in the parabolic collector 70 is shown as follows:
• a Konzentratorfolie 76 is clamped in a frame 77, which consists of an upper ring 78 and an unrecognizable lower ring, the rings between the concentrator film 76 pinch between them and are screwed together.
• the lower ring in turn carries a likewise not apparent bottom plate, which forms a vacuum chamber together with the lower ring.
• Suitable means for producing the negative pressure such as vacuum hoses and a central vacuum pump are also omitted to relieve the figure.
• the concentrator film 76 and the bottom plate are shown translucently, so that the attachment of the single collector 71 on the metal frame 75 can be seen: on a support 79 of the metal frame 75 vertically projecting support members 80 are arranged, which in turn about an axis 81 pivotally a T-shaped Attachment 82 is hinged, which in turn carries the bottom plate of the single collector 71.
• the individual collectors 71,72 can be easily aligned, for example with a gauge.
• the extremely simple construction allows a favorable production under simple conditions.
• the frames 77 of the individual collectors 71, 72 are elliptical, as described above in connection with the production method, in particular with reference to FIG.
• the deviation of the length of the major axis of the minor axis in the scale executed figure is not apparent.
• the minor axis becomes shorter relative to the major axis the farther the affected concentrator is from the origin of the paraboloid.
• the parabolic collector 70 has a ratio of focal length to diameter of about 1 (due to the individual collectors 71, 72 arranged on a grid, a fixed diameter in the sense of a circular diameter is not given). As a result, the concentration factor in the present arrangement is about 4000.
• the ratio of focal length to diameter is chosen to be about 0.5, the concentration recorded at the time of registration is about 6000, with an expected temperature of 2200 to 2700 ° C.

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• Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Life Sciences & Earth Sciences (AREA)
• Sustainable Development (AREA)
• Sustainable Energy (AREA)
• Thermal Sciences (AREA)
• Chemical & Material Sciences (AREA)
• Combustion & Propulsion (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Optical Elements Other Than Lenses (AREA)
• Photovoltaic Devices (AREA)

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• 2009
  • 2009-12-17 CH CH01942/09A patent/CH702469A1/de not_active Application Discontinuation
• 2010
  • 2010-12-16 US US13/511,026 patent/US9146043B2/en not_active Expired - Fee Related
  • 2010-12-16 MX MX2012006783A patent/MX2012006783A/es active IP Right Grant
  • 2010-12-16 AU AU2010333645A patent/AU2010333645A1/en not_active Abandoned
  • 2010-12-16 WO PCT/CH2010/000313 patent/WO2011072410A1/de active Application Filing
  • 2010-12-16 EP EP10805377A patent/EP2513572A1/de not_active Ceased
  • 2010-12-16 CN CN2010800572918A patent/CN102695926A/zh active Pending
• 2012
  • 2012-05-15 ZA ZA2012/03543A patent/ZA201203543B/en unknown
  • 2012-05-30 IL IL220073A patent/IL220073A0/en unknown
  • 2012-06-07 IN IN5026DEN2012 patent/IN2012DN05026A/en unknown
  • 2012-06-08 TN TNP2012000293A patent/TN2012000293A1/en unknown
  • 2012-06-14 CL CL2012001603A patent/CL2012001603A1/es unknown

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