EP2503031A2 - Method for coating, pole tube and device for executing the method - Google Patents

Abstract

The method involves forming a corrosion protection layer on a workpiece. A metallic bonding layer is applied electrolytically on boundary surface of workpiece, before formation of corrosion protection layer. The metallic bonding layer is made of electrolytic nickel strike. The corrosion protection layer is made of zinc material. Independent claims are included for the following: (1) pipe pile; (2) apparatus for coating two different metallic materials on surface regions of workpiece; and (3) clamping leg.

Description

The invention relates to a method for coating a workpiece consisting of two different metallic materials, a pole tube with two pole tube sections consisting of different materials, and a device for carrying out the method.

Switching or proportional solenoids of hydraulic solenoid valves usually have a pole tube with an armature space for receiving a magnet armature whose armature plunger passes through a Polbasis, via which a valve spool of the solenoid valve is adjustable. Since the structure of the pole tubes from the prior art, for example from the DE 199 52 800 A1 is known, is dispensed with a detailed description.

The pole tube consists of a mix of materials, usually made of stainless and acid-resistant stainless steel and unalloyed steel, such as structural steel St35 or St37. In order to avoid corrosion of the non-rust-resistant areas of the pole tube, this is conventionally provided with a galvanically applied zinc layer. This coating of the pole tube is problematic in practice due to the different materials, since they basically behave differently in the usual manner in galvanic processes performed pretreatments (degreasing, activating, etc.). Thus, it may happen, for example, that the pole tube regions made of stainless steel are polarized during the pretreatment differently to those regions which consist of structural steel - this different polarization then leads to problems in the adhesion of the later applied zinc layer. These adhesion problems can then lead to tinsel formation due to delamination of the tin layer in the region of the stainless steel. Around To avoid this, one uses specially adapted pre-treatment process, on the one hand require a considerable procedural effort and on the other hand can not completely eliminate the liability problems described.

On the other hand, the object of the invention is to provide a method for coating a workpiece consisting of two different metallic materials, a pole tube with two pole tube sections consisting of different materials, and a device for carrying out the method by which or improved adhesion a corrosion protection layer is ensured.

This object is achieved with regard to the method by the features of claim 1, with regard to the pole tube by the features of claim 7 and with respect to the device by the combination of features of claim 8.

Advantageous developments of the invention are the subject of the dependent claims.

The inventive method is basically applicable to all workpieces, which consist of two different metallic materials which form a material interface in the surface region of the workpiece, wherein the workpiece is to be provided with a corrosion protection layer. At least in the region of the material interface, the workpiece is provided with an electrolytically applied metallic adhesive layer before the application of the corrosion layer, which forms a primer for the corrosion protection layer. This electrolytically applied adhesive layer is preferably applied continuously. In principle, however, it may also be sufficient to apply this adhesive layer only in the region of the workpiece sections, which are made of a material with poor adhesive properties (stainless steel), wherein the material boundary area should also be covered.

The pole tube according to the invention is provided in a corresponding manner with an electrolytically applied adhesive layer for the subsequent corrosion protection layer.

The inventive device for carrying out the method has a holder which dips into an interior of the workpiece, wherein the holder has at least two, preferably resilient, clamping legs which are diametrically on an inner peripheral wall of the Abut workpiece, wherein a clamping leg along an approximately axially parallel clamping line and the other clamping leg diametrically engages approximately punctiform on the inner circumferential wall. These clamping legs make it possible to position the workpiece, in particular the pole tube in a predetermined relative to the galvanic coating relative position in the electrolyte bath, wherein the electrical contact can be made via the clamping legs.

In a particularly preferred embodiment, the adhesive layer is formed by a nickel-strike electrolyte. This process, which is known per se from the prior art, has the purpose of dissolving (activating) the natural oxide skin of the rust- and acid-resistant steel and at the same time producing a thin layer as a primer for subsequent galvanizing. It has surprisingly been found that can be almost completely eliminated by such a nickel-strike electrolyte, the problem described above, so that even under unfavorable operating conditions flaking of the corrosion protection layer can be avoided.

In one embodiment of the invention, the surface of the workpiece is dekapiert before forming the nickel layer, wherein the decapping a degreasing step may be upstream.

The adhesion of the corrosion layer can be further improved if such a decorating step is performed even after the formation of the adhesive layer. Of course, the individual steps of the pretreatment are followed by the rinsing operations customary in galvanic processes, which are preferably carried out in multiple stages or as a rinsing cascade.

The corrosion protection layer is preferably a zinc layer.

The clamping legs of the holder for fixing the position of the workpieces within the electrolyte are preferably formed in pairs symmetrical, so that the workpiece from the inner circumference and the outer circumference is clamped and / or contacted.

• Figur 1 eine Vorderansicht eines Gestells, an dem eine Vielzahl von Polrohren gehalten wird,
• wenn dies die einzigen Schritte eines galvanischen Prozesses durchläuft;
• Figur 2 eine Seitenansicht des Gestells gemäß Figur 1;
• Figuren 3a, 3b Detaildarstellungen des Gestells gemäß den Figuren 1 und 2;
• Figur 4 eine schematische Darstellung zur Erläuterung des erfindungsgemäßen Verfahrens und
• Figur 5 Verfahrensschritte einer Nachbehandlung gemäß dem erfindungsgemäßen Verfahren.

A preferred embodiment of the invention will be explained in more detail with reference to schematic drawings. Show it:

• FIG. 1 a front view of a frame on which a plurality of pile tubes is held,
• if this goes through the only steps of a galvanic process;
• FIG. 2 a side view of the frame according to FIG. 1 ;
• FIGS. 3a, 3b Detailed representations of the frame according to the Figures 1 and 2 ;
• FIG. 4 a schematic representation for explaining the method according to the invention and
• FIG. 5 Process steps of a post-treatment according to the inventive method.

The invention will be explained below with reference to the galvanic coating of a pole tube. In principle, the method according to the invention and the device according to the invention can also be used for applying a corrosion protection layer to other components which are manufactured from different metallic materials.

The basic structure of a pole tube is known from the prior art, for example from the cited document, so that explanations are unnecessary in this regard. For the following description of the invention is only essential that the pole tube areas of stainless steel corrosion and areas of conventional structural steel, which can lead to adhesion problems in the corrosion protection layer when using the conventional electroplating later use of the pole tube.

In the method steps of the galvanic process for applying a corrosion protection layer described below, a plurality of pile tubes 1 are held on a frame 2. This is attached via a suspension 4 to a conveyor 6 indicated by dashed lines, so that the frame 2 can be conveyed to the individual electroplating baths of the galvanic process and immersed in the respective process fluid.

As in FIG. 1 indicated, each pole tube 1 is held on the frame 2 via paired clamping legs 8, 10, wherein each pair of clamping legs 8a, 8b, 10a, 10b clamped against a peripheral wall of the pole tube 1. In the illustrated embodiment, a total of 64 clamping leg pairs 8, 10 are provided, so that in a corresponding manner 64 pile tubes 1 are held on the frame 2. How the particular Side view according to FIG. 2 can be removed, in particular four levels of clamping leg pairs 8, 10 are provided, wherein in each plane two, approximately V-shaped mutually arranged clamping leg pairs 8, 10 are provided, which in accordance with a common base 12 in one FIG. 1 horizontally extending frame strut 14 are attached. In the illustration according to FIG. 2 are the clamping leg pairs 8, 10 perpendicular to the plane behind the other, with the clamping leg profile perpendicular to the plane, so that the clamping arm pairs 8, 10 appear in the side view as a straight line.

As usual in galvanic processes, the pole tube 1 forms the anode, wherein the electrical contact via the clamping legs 8, 10 takes place. These are provided with an insulation which is interrupted in the contacting area, so that the power supply takes place to optimize the layer structure only along intended areas. The inclination of the pile tubes 1 on the frame 2 and thus the relative positioning of the pile tubes in the electrolyte of the respective galvanic process is chosen so that an optimal layer thickness distribution of the electrodeposited layer is achieved, the coating still by a movement and thus mixing of the electrolyte via suitable measures , such as Venturi nozzles, stirrers, etc. can be improved.

The FIGS. 3a, 3b show individual representations of the inner clamping legs 8a, 10a of the above-described clamping leg pairs 8, 10 which dive into a receiving space 16 of the pole tube 1 and abut the inner peripheral wall 20, so that a mechanical and / or electrical contact takes place.

Here, the clamping leg 8a has a projecting in the radial direction crank 18, which abuts approximately punctiform on the inner circumferential wall 20. The other clamping leg 10a has a retaining portion 22, which is likewise bulged in the radial direction toward the inner circumferential wall 20, but which is designed with a flat base which rests approximately linearly on the inner circumferential wall 20 and runs approximately parallel to a polar axis 24. The other two, in the presentation according to the FIGS. 3a, 3b not shown clamping legs 8b and 10b are formed accordingly and are each as shown in FIG FIG. 1 on the outer peripheral wall of the pole tube 1 at.

In the illustration according to FIG. 3a a comparatively small pole tube 1 is held over the clamping legs 8a, 10a. In the illustration according to FIG. 3b a pole tube 1 is shown with a larger axial length and larger diameter, which is also held on the clamping legs 8a, 10a. It can be seen that when clamping the smaller pole tube 1 (FIG. FIG. 3a ) of the clamping leg 8a is deflected with the crank 18 in the radial direction inwards, wherein the crank 18 but with its V-shaped apex in this deflected position ensures an approximately point-like contact with the inner circumferential wall 20. When clamping the larger pole tube 1 ( FIG. 3b In particular, the clamping leg 8a springs outward in the radial direction in order to rest clampingly against the inner circumferential wall 20. The crank 18 ensures - as mentioned - always a roughly point-like investment, while the spring-elastic running clamping leg 10a in both pole tubes 1 with its holding portion 22 linearly abuts the inner peripheral wall 20. The geometry of the clamping legs 8, 10 thus makes it possible to keep different pole tube sizes on the frame 2.

Like that FIGS. 3a, 3b is removable, an end portion 26 of the holding portion 22 is bent radially inwardly and abuts an end wall 28 of the pole piece 1, so that it is also supported in the axial direction. The contact surfaces between the pole tube 1 and the clamping legs 8, 10 are minimal, so that a largely full-surface galvanic coating is possible.

The actual galvanic process is based on the flowcharts according to the FIGS. 4 and 5 explained.

In a first method step, the pole tubes 1 held on the frame 2 are degreased to remove oil and fat layers, it being possible to use aqueous methods, organic solvents or other methods, for example a plasma cleaning in a first bath. In order to avoid introducing the fluid used for degreasing in the subsequent process step, the degreasing is followed by a rinsing process, wherein preferably a multiple or cascade rinsing takes place. This multiple flush has the advantage that the flushing water consumption is optimized and by concentrating and recycling of flushing water from the individual steps a partial circulation is possible.

In the case of the method specifically shown, this flushing step is followed by picking or activation, by means of which the oxide process removes disruptive oxide layers in order to produce an active surface. In this pickling, dilute mineral acids or activating acidic solutions are used.

The decapping is followed by a rinsing step again in order to avoid an entry of the media used during picking in the subsequent process step.

After activation of the surface of the pole tube 1, they are immersed in the so-called nickel-strike electrolyte in order to effect a further activation of the surface with simultaneous deposition of a metal precipitate. Such a nickel-strike electrolyte contains a proportion of nickel chloride and hydrochloric acid dissolved in deionized water. The galvanic bath also contains a nickel anode, which has a relatively high degree of purity. The current density may be, for example, 3 to 5 A / dm ² , wherein the treatment time in the nickel-strike electrolyte is, for example, about 3 to 10 minutes to form the mentioned nickel fine layer on the pole tube 1.

This nickel-strike process step, also called Schlagnickel process, is followed by another rinsing step (multiple rinsing) and another decaping to prepare the actual galvanizing. The galvanizing then takes place in a conventional manner.

The galvanizing is followed by a post-treatment, which serves to improve the corrosion protection and the visual appearance. According to FIG. 5 For example, this post-treatment may involve further multi-stage rinsing and lightening of the zinc layer. After lightening, a rinse takes place, wherein this rinsing can be done in one stage.

In the described galvanic process then follows this flushing passivation, preferably a thick-film passivation. Such a thick-film passivation is a surface refinement by coating based on chromium-containing compounds, through which the corrosion resistance continues is improved. After this passivation, a further multi-stage rinsing step and then a drying of the pole tube 1 takes place.

According to the method described above, this pole tube 1 is provided with a corrosion-resistant coating, which adheres even under unfavorable operating conditions and thus is superior to conventional coatings.

Described is a method for coating workpieces, which consist of two different metallic materials. According to the invention, the workpieces are provided with a nickel layer as a primer before the application of a corrosion protection layer in a nickel-strike electrolyte.

LIST OF REFERENCE NUMBERS

1

pole tube

2

frame

4

suspension

6

Conveyor

8th

Terminal pair of legs

10

Terminal pair of legs

12

Base

14

frame strut

16

accommodation space

18

cranking

20

inner circumferential wall

22

holding section

24

Polrohrachse

26

end

28

end wall

Claims (11)

Method for coating a workpiece consisting of two different metallic materials, which form a material interface in surface regions of the workpiece, wherein the workpiece is provided with a corrosion protection layer, characterized in that on the workpiece before the application of the corrosion protection layer at least in the region of the material interface a metallic adhesive layer is applied electrolytically. The method of claim 1, wherein the adhesive layer is formed by applying a nickel-strike electrolyte, so that an activation of the surface and the formation of a nickel layer takes place. The method of claim 1 or 2, wherein the surface is decapitated prior to forming the adhesive layer. Method according to claim 3, wherein a degreasing step is carried out before picking. Method according to one of the preceding claims, wherein the forming of the adhesive layer followed by a Dekapierschritt. Method according to one of the preceding claims, wherein the corrosion protection layer is a zinc layer. Polrohr with at least two of different materials Polrohrabschnitten which are joined together along a material interface and which is provided with a corrosion protection layer, which is applied to a trained according to a method according to one of the preceding claims adhesive layer. Device for carrying out the method according to one of the claims 1 to 6, with a holder which dips into an interior of the workpiece, wherein the holder has at least two clamping legs (8a, 8b, 10a, 10b), the abut diametrically on an inner circumferential wall (20), wherein a clamping leg (10a, 10b) along an approximately axially parallel clamping line and the other clamping leg (8a, 8b) acts diametrically about punctiform. Apparatus according to claim 8, wherein the clamping legs (8a, 8b, 10a, 10b) are each formed symmetrically in pairs, wherein in each case a clamping leg (8b, 10b) engages about point or line on the outer circumference of the workpiece. Device according to claim 8 or 9, wherein the clamping legs (8a, 8b, 10a, 10b) are resilient. Clamping leg according to one of the claims 8 to 10, wherein the clamping legs (8a, 8b; 10a, 10b) are designed as contact elements for electrical contacting.

Images