EP2501818B1 - Procédé optimisé au plan énergétique pour l'exploitation d'une installation de production de bioéthanol - Google Patents

Procédé optimisé au plan énergétique pour l'exploitation d'une installation de production de bioéthanol Download PDF

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Publication number
EP2501818B1
EP2501818B1 EP10721517.0A EP10721517A EP2501818B1 EP 2501818 B1 EP2501818 B1 EP 2501818B1 EP 10721517 A EP10721517 A EP 10721517A EP 2501818 B1 EP2501818 B1 EP 2501818B1
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EP
European Patent Office
Prior art keywords
plant
biogas
bioethanol production
production plant
bioethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP10721517.0A
Other languages
German (de)
English (en)
Other versions
EP2501818A2 (fr
Inventor
Georg Pollert
Oliver Lüdtke
Enrico Fichter
Klaus-Dieter Bettien
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Verbio Vereinigte Bioenergie AG
Original Assignee
Verbio Vereinigte Bioenergie AG
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Publication date
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Priority to PL10721517T priority Critical patent/PL2501818T3/pl
Publication of EP2501818A2 publication Critical patent/EP2501818A2/fr
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Publication of EP2501818B1 publication Critical patent/EP2501818B1/fr
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Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00Preparation of oxygen-containing organic compounds
    • C12P7/02Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06Ethanol, i.e. non-beverage
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the invention relates to an energetically optimized method for operating a bioethanol production plant, wherein the resulting vinasse is introduced into a biogas plant to convert contained organic substances into biogas, for carrying out a combined operation of bioethanol and biogas production according to the preamble of patent claim 1.
  • the problem to be solved is to develop a thermal power plant by the steam turbine is a process application downstream, in which a portion of the energy contained in the process steam is consumed and for the residual steam a bioethanol plant for the production of bioethanol is followed, for the energetic processes, part of the energy contained in the residual steam can be used.
  • the energy contained in the effluent from the turbine process steam energy is partially used in the downstream application, wherein the energy contained in the residual steam from the process application in the downstream bioethanol plant for the production of bioethanol is used.
  • biogas production can also utilize suitable biological residues, such as, in particular, so-called 'bioethanol production' sludge.
  • This vinasse has a high content of organic matter. Therefore, it is very suitable for biogas production.
  • the utilization of the stillage for biogas production reduces the otherwise necessary disposal logistics. So it should be increased by the processing of the vinasse to biogas, the energy efficiency of a corresponding system and the utilization of the theoretically usable plant potential total.
  • the DE 10 2006 040 567 A1 in the local process for the production of bioethanol from biomass especially cereals and especially rye is that in the production of ethanol from rye quite high conversion costs. These higher costs result from the application of viscosity-lowering enzymes to counteract the congealing in the conversion process and the higher steam demand in DDGS (Distiller's Dried Grains with Solubles) drying.
  • DDGS Disistiller's Dried Grains with Solubles
  • the bottoms product obtained as Schlempewasser should also be at least partially used for the production of process water by a vacuum circulation evaporation plant, a microfiltration, ultrafiltration, nanofiltration and reverse osmosis and / or membrane techniques to obtain low-salt process water and high-salt concentrate from the Schlempewasser be used.
  • the current production has made the production of ethanol as a substitute for automotive fuel a major factor in agriculture.
  • the motive of state support lies mainly in the reduction of CO 2 emissions to the atmosphere in the transport sector.
  • the vinasse can be applied as NPK fertilizer to the fields in the vicinity of the production facility. But this also has several serious disadvantages.
  • the method of fertilizer application is not very economical, since agriculture hardly compensates the value of the fertilizer and the organic components of the added value are lost.
  • the application is also associated with a high energy expenditure, since very large amounts of water must be transported over sometimes considerable distances.
  • the application is limited in time by a core retention period in winter.
  • the biogas plant effluent in one embodiment may be partially subjected to a solids separation step.
  • the thus treated, purified effluent is then fed to the bioethanol recovery plant.
  • the separation step may include filtration and / or decantation.
  • the hydrogen sulfide contained in the return can be removed. This removal may be e.g. done by degassing and / or cases.
  • the necessary rejection can in principle be carried out at each, but also at several process stations in the system.
  • An important step according to the embodiment is the separation of the ammonia by stripping in a corresponding process step.

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Claims (6)

  1. Procédé pour mettre en oeuvre une exploitation combinée d'une installation de production de bioéthanol et d'une installation de biogaz,
    caractérisé en ce que
    - les drêches produites dans l'installation de production de bioéthanol sont introduites dans une installation de biogaz pour transformer les substances organiques contenues en biogaz, et
    - il est prévu un retour direct d'une partie de l'effluent de l'installation de biogaz à des fins de macération dans le fermenteur de l'installation de production de bioéthanol.
  2. Procédé selon la revendication 1,
    caractérisé en ce que
    l'effluent de l'installation de biogaz est soumis, avant le retour direct, partiellement à une étape de séparation de solides.
  3. Procédé selon la revendication 2,
    caractérisé en ce que
    l'étape de séparation comprend une filtration et/ou une décantation.
  4. Procédé selon l'une des revendications précédentes,
    caractérisé en ce que
    un flux partiel est enlevé par éclusage hors de l'effluent de l'installation de biogaz, qui est purifié au moyen d'un procédé à membrane, et de plus le perméat obtenu parvient complètement ou partiellement dans l'installation de production de bioéthanol pour la macération.
  5. Procédé selon l'une des revendications précédentes,
    caractérisé en ce que
    un flux partiel est enlevé par éclusage hors de l'effluent de l'installation de biogaz, il est évaporé et donc concentré, et le condensat parvient au moins partiellement dans l'installation de production de bioéthanol pour la macération.
  6. Procédé selon l'une des revendications précédentes,
    caractérisé en ce que
    l'ammoniac formé dans l'installation de biogaz est enlevé par stripage jusqu'à une concentration inoffensive pour le processus dans son ensemble.
EP10721517.0A 2009-06-02 2010-06-01 Procédé optimisé au plan énergétique pour l'exploitation d'une installation de production de bioéthanol Active EP2501818B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10721517T PL2501818T3 (pl) 2009-06-02 2010-06-01 Zoptymalizowany energetycznie sposób eksploatacji instalacji do pozyskania bioetanolu

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009023573 2009-06-02
DE102010005818A DE102010005818A1 (de) 2009-06-02 2010-01-27 Energetisch optimiertes Verfahren zum Betreiben einer Bioethanolgewinnungsanlage
PCT/EP2010/057657 WO2010139699A2 (fr) 2009-06-02 2010-06-01 Procédé optimisé au plan énergétique pour l'exploitation d'une installation de production de bioéthanol

Publications (2)

Publication Number Publication Date
EP2501818A2 EP2501818A2 (fr) 2012-09-26
EP2501818B1 true EP2501818B1 (fr) 2018-12-26

Family

ID=43049433

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10721517.0A Active EP2501818B1 (fr) 2009-06-02 2010-06-01 Procédé optimisé au plan énergétique pour l'exploitation d'une installation de production de bioéthanol

Country Status (6)

Country Link
EP (1) EP2501818B1 (fr)
DE (1) DE102010005818A1 (fr)
ES (1) ES2717202T3 (fr)
HU (1) HUE044218T2 (fr)
PL (1) PL2501818T3 (fr)
WO (1) WO2010139699A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3950914A1 (fr) 2020-08-03 2022-02-09 Verbio Vereinigte Bioenergie AG Procédé de mise en uvre d'un fonctionnement combiné d'une installation de production de bioéthanol et d'une installation de biogaz
WO2023159251A1 (fr) 2022-02-21 2023-08-24 Novozymes A/S Procédé de mise en œuvre du fonctionnement combiné d'une unité de production de bioéthanol et d'une unité de biogaz
WO2023164436A1 (fr) 2022-02-23 2023-08-31 Novozymes A/S Procédé pour produire des produits de fermentation et du biogaz à partir de matériaux contenant de l'amidon

Families Citing this family (8)

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DE102012104764B4 (de) 2012-06-01 2018-08-02 Technologie Manufaktur Weissinger UG (haftungsbeschränkt) Verfahren zur Verwertung von Altbackwaren
DE202013102153U1 (de) 2013-05-16 2013-06-06 Robert Hensel System zur Erzeugung von aliphatischen Alkoholen
DK2803654T3 (en) 2013-05-16 2017-02-27 Christian Schweitzer SYSTEM AND PROCEDURE FOR PRODUCING ALIFATIC ALCOHOLS
DE102013226991A1 (de) 2013-12-20 2015-06-25 Verbio Vereinigte Bioenergie Ag Verfahren zur Entfernung von Störstoffen aus wässrigen Medien
DE102014001909A1 (de) 2014-02-15 2015-09-03 Christine Apelt Verfahren zur stofflichen und energetischen Verwertung biogener Reststoffe von Anlagen zur Stärkeproduktion und Anordnung zur Durchführung des Verfahrens
DE102014001910A1 (de) 2014-02-15 2015-08-20 Christine Apelt Verfahren zur stofflichen und energetischen Verwertung biogener Reststoffe der Kartoffelverarbeitung und Anordnung zur Durchführung des Verfahrens
DE102014001907A1 (de) 2014-02-15 2015-08-20 Christine Apelt Verfahren zur stofflichen und energetischen Verwendung biogener Reststoffe von Braustätten und Anordnung zur Durchführung des Verfahrens
DE102014001912A1 (de) 2014-02-18 2015-09-03 Christine Apelt Verfahren zur stofflichen und energetischen Verwertung biogener Reststoffe von Anlagen zur Bioethanolgewinnung und Anordnung zur Durchführung des Verfahrens

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US7381550B2 (en) * 2004-01-08 2008-06-03 Prime Bioshield, Llc. Integrated process for producing “clean beef” (or milk), ethanol, cattle feed and bio-gas/bio-fertilizer
FR2903119B1 (fr) * 2006-07-03 2010-05-28 John Mahler Procede de production de bioethanol et d'energie a partir d'une matiere premiere vegetale saccharifere ou amylacee
DE102006040567A1 (de) 2006-08-30 2008-03-06 Bayer Technology Services Gmbh Verfahren zur Herstellung von Bioethanol
DE102007001614A1 (de) 2007-01-04 2008-07-10 Lrz Landhandels- Und Recycling-Zentrum Gmbh Energieautarkes Verfahren zur Herstellung von Bioethanol aus lignocellulose-, protein- und stärke- und/oder zuckerhaltigen Einsatzstoffen
DE102007015623A1 (de) 2007-03-29 2008-10-02 Be Bioenergie Gmbh & Co. Kg Heizkraftwerk und Verfahren zur energetischen Nutzung von landwirtschaftlich erzeugten Rohstoffen
DE102007033988A1 (de) 2007-07-19 2009-01-22 Acs Agrochemische Systeme Gmbh Verbesserte Verfahren zur Herstellung von Ethanol, Gluten und Kleie aus Getreide
EP2060635A1 (fr) * 2007-11-16 2009-05-20 Syngenta Participations AG Procédé amélioré pour la production d'éthanol à partir d'une matière végétale
DE102007061137B4 (de) * 2007-12-19 2011-12-15 Agraferm Technologies Ag Vorrichtung und Verfahren zur Umwandlung von bei der Ethanolproduktion als Abfallprodukt anfallender Fermentationsbrühe in Biogas
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3950914A1 (fr) 2020-08-03 2022-02-09 Verbio Vereinigte Bioenergie AG Procédé de mise en uvre d'un fonctionnement combiné d'une installation de production de bioéthanol et d'une installation de biogaz
WO2023159251A1 (fr) 2022-02-21 2023-08-24 Novozymes A/S Procédé de mise en œuvre du fonctionnement combiné d'une unité de production de bioéthanol et d'une unité de biogaz
WO2023164436A1 (fr) 2022-02-23 2023-08-31 Novozymes A/S Procédé pour produire des produits de fermentation et du biogaz à partir de matériaux contenant de l'amidon

Also Published As

Publication number Publication date
ES2717202T3 (es) 2019-06-19
WO2010139699A2 (fr) 2010-12-09
EP2501818A2 (fr) 2012-09-26
HUE044218T2 (hu) 2019-10-28
WO2010139699A3 (fr) 2011-02-24
PL2501818T3 (pl) 2020-03-31
DE102010005818A1 (de) 2010-12-09

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