WO2007012328A1 - Procede et installation d'hydrolyse en plusieurs etapes de matieres premieres biogenes solides - Google Patents

Procede et installation d'hydrolyse en plusieurs etapes de matieres premieres biogenes solides Download PDF

Info

Publication number
WO2007012328A1
WO2007012328A1 PCT/DE2006/001325 DE2006001325W WO2007012328A1 WO 2007012328 A1 WO2007012328 A1 WO 2007012328A1 DE 2006001325 W DE2006001325 W DE 2006001325W WO 2007012328 A1 WO2007012328 A1 WO 2007012328A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrolysis
raw materials
hydrolyzate
percolators
methane
Prior art date
Application number
PCT/DE2006/001325
Other languages
German (de)
English (en)
Inventor
Günter Busch
Jochen Grossmann
Original Assignee
Gicon Grossmann Ingenieur Consult Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gicon Grossmann Ingenieur Consult Gmbh filed Critical Gicon Grossmann Ingenieur Consult Gmbh
Priority to EP06761833A priority Critical patent/EP1907139A1/fr
Priority to DE200611001877 priority patent/DE112006001877A5/de
Publication of WO2007012328A1 publication Critical patent/WO2007012328A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/50—Treatments combining two or more different biological or biochemical treatments, e.g. anaerobic and aerobic treatment or vermicomposting and aerobic treatment
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/90—Apparatus therefor
    • C05F17/964—Constructional parts, e.g. floors, covers or doors
    • C05F17/971—Constructional parts, e.g. floors, covers or doors for feeding or discharging materials to be treated; for feeding or discharging other material
    • C05F17/979—Constructional parts, e.g. floors, covers or doors for feeding or discharging materials to be treated; for feeding or discharging other material the other material being gaseous
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/90—Apparatus therefor
    • C05F17/964—Constructional parts, e.g. floors, covers or doors
    • C05F17/971—Constructional parts, e.g. floors, covers or doors for feeding or discharging materials to be treated; for feeding or discharging other material
    • C05F17/986—Constructional parts, e.g. floors, covers or doors for feeding or discharging materials to be treated; for feeding or discharging other material the other material being liquid
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00—Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00—Means for pre-treatment of biological substances
    • C12M45/06—Means for pre-treatment of biological substances by chemical means or hydrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Definitions

  • the invention relates to a process and a plant for the multistage hydrolysis of solid biogenic raw materials by percolation with subsequent production of biogas exclusively from the hydrolyzate.
  • biodegradable substances The degradation of biodegradable substances (hereinafter referred to as biogenic substances) during operations in biogas plants takes place in several successive biochemical substeps in an aqueous environment.
  • biogenic substances The degradation of biodegradable substances (hereinafter referred to as biogenic substances) during operations in biogas plants takes place in several successive biochemical substeps in an aqueous environment.
  • water-soluble components are dissolved out of the solid biogenic substances.
  • non-water-soluble biogenic substances are decomposed into water-soluble, generally low molecular weight substances by several types of extracellular enzymes which are produced by different microorganisms. Enzymes can also be added as so-called foreign enzymes to accelerate or facilitate certain degradation processes.
  • Hydrolysis bacteria and enzymes are mainly in the aqueous solution, but can also be located on solid surfaces.
  • these substances formed in the hydrolysis or converted into the aqueous solution are converted into various organic acids (lower fatty acids, amino acids), which are then converted into acetic acid in the third partial step (acetogenesis).
  • the acetic acid is then degraded in the methanogenesis (4th sub-step) using methane bacteria to methane and carbon dioxide.
  • the sub-steps of hydrolysis and acidogenesis (first stage) of the sub-steps acetogenesis and especially methanogenesis (second stage) are separated apparatus and process technology.
  • first stage the first stage of the two-stage biogas process
  • second stage the second stage as a methane stage.
  • the aqueous solution leaving the hydrolysis is commonly referred to as hydrolyzate. In the following, this simplistic language is also used.
  • hydrolysis is considered to be an intensity limiting step.
  • the percolators are operated in parallel, ie the hydrolyzate of each percolator is passed, possibly via an intermediate buffer, into the methane reactor.
  • the output of the percolators By superimposing the output of the percolators, whose contents each have different residence times, one expects a homogenization of the hydrolyzate quality and quantity and thus also of the resulting methane gas. (Fig. 1). It is known that the biochemical conversion in the hydrolysis immediately after the entry of fresh input material is very high, since first the rapidly degradable substances are degraded. At this stage, therefore, a very rapid increase in the hydrolysis bacteria takes place, which is also associated with the increased production of enzymes.
  • DE 199 37 876 C2 discloses a process for the biological conversion of organic substances to methane gas, in which organic wastewaters, but no solids, are hydrolyzed. The hydrolyzate is recycled, with an increase in the concentration of hydrolysis bacteria by membrane filtration and recycling of the filter residue. The injection of air is used as a measure for the targeted growth of (aerobic) acidifiers.
  • DE 199 09 353 A1 describes a process and a plant for processing a mixture of substances contained in an organism.
  • the solid obtained serves as an inoculation material used to initiate the hydrolysis process in the fresh material, but not to increase the concentration.
  • the process disclosed in DE 40 00 834 A1 is suitable only for pumpable substrates, process and plant are not technically suitable for predominantly solid biogenic raw materials.
  • the biogenic material passes through the hydrolysis as a total material flow, larger solid particles are withdrawn directly from the hydrolysis tanks and led to digestion, a multi-stage digestion is therefore not possible for the solid fraction.
  • the recirculation of sludge takes place only from the overflow of the hydrolysis and is only limited possible because otherwise the throughput of fresh material is reduced too much by the hydrolysis.
  • DE 198 46 336 A1 comprises many variants for a waste treatment, which include, inter alia, a two-stage hydrolysis.
  • this two-stage nature is due to the tasks of mechanical material flow separation to be solved because the hydrolysis apparatus flows continuously through the material stream of the biogenic material, in this case "waste in particular.”
  • This is characterized, inter alia, by mechanical transport facilities for the biogenic material is thus only several hours, a maximum of a few days.
  • the object is achieved by a process for the multistage hydrolysis of solid biogenic substances in which a plurality of solid biogenic raw materials are hydrolysed in a time-shifted manner, the drolysate being discharged from the fresher quantity being fed to the next-largest amount as percolation liquid.
  • the solution according to the invention is particularly applicable to biogas plants and processes, which are characterized by a separate hydrolysis stage before the actual biogas production stage (Methansrufe) and use the solid biogenic raw materials as the main feedstock (primary energy source).
  • biogenic waste and waste mixtures can be used, provided that they have a percolation permeability sufficient for the percolation process for the percolate (ie a permeability). This permeability can also be achieved by the addition of structural materials that may be reusable.
  • the technical measure which serves to achieve the objective of the invention the material flow of the hydrolyzate in the percolation process in a kind of series connection via each spatially delimited subsets of present in homogeneous bed biogenic input material.
  • several quantities of solid biogenic raw materials but also portions of the biogenic raw materials can be hydrolyzed with a time offset.
  • at least two, but more preferably three or more, approximately equal amounts or partial amounts of input material are required.
  • the hydrolysis process is started at different times, the time interval of the beginning of the process is determined as follows: Total duration of the hydrolysis process (biochemically required period up to which most of the organically degradable substance has been released from the solid biogenic input material so that the hydrolysis process can be stopped)
  • the material flow guide is characterized in that the newly introduced into the process amount of biogenic raw material is percolated with liquid that has only a low concentration of organically degradable solutes, but hydrolysis bacteria and enzymes and a high nutrient concentration (eg., Liquid from the process the methane level).
  • the rapidly biodegradable substances present in fresh biogenic raw material lead to a rapid multiplication of hydrolysis bacteria and a corresponding increase in the enzyme concentration and the concentration of organic acids.
  • the running of this fresh amount hydrolyzate is now fed to the next older amount as percolation liquid, the expiring of this amount hydrolyzate turn the next older, etc.
  • This material flow guidance ensures that the high concentration of hydrolysis bacteria and enzymes in fresh input material is still available for the hydrolysis process of older input material, so that a much more efficient degradation of the less degradable organic substance is possible.
  • the high acid potential (low pH value) from the hydrolyzate of the fresh input subset also ensures a low pH value in the case of percolation of the subsequent subsets.
  • This inhibits methane formation, which, on the one hand, ensures a consistent separation between the hydrolysis and the methane stage and, on the other hand, ensures that the enzymes that are important for the hydrolysis are not prematurely decomposed by methane bacteria, which could reduce their concentration.
  • percolators are used, which can be constructed identically and each of which can be equipped with a corresponding buffer. These percolators are now operated in a series circuit, wherein the percolate flow is conducted in quasi-direct current. The percolators are filled or emptied in regular operation with a time interval, so that in the overall process both fresh input material as well as those with a longer residence time, d. H. Already treated with hydrolyzate material - here referred to as older material - finds.
  • the access of air is made possible in the hydrolysis step.
  • the acetogenic and methanogenic bacteria which are usually in the methane stage, contribute significantly to reducing the effectiveness of the enzymes formed by the hydrolysis bacteria.
  • the presence or activity of these methane-forming bacteria in the hydrolysis step must therefore be avoided in order to maintain a high concentration of the enzymes.
  • the methane-forming bacteria in the presence of (air) oxygen adjust their activity and possibly killed.
  • the access of air is made possible in the hydrolysis step.
  • the hydrolyzate storage containers and also the percolators can be aerated by blowing in air.
  • the supply of atmospheric oxygen can also be carried out according to claim 4 by the aeration of the recirculated to the hydrolysis process from the Methanement.
  • biogas production from renewable raw materials eg cereal crops, which in chopped form the As a boundary condition
  • these feedstocks are usually only harvested in a short period of time during one year.
  • these substances are usually stored in durable form (silage) in appropriate storage areas.
  • an alternative embodiment of the method is to use the storage areas required for temporary storage of these feedstocks directly percolation / hydrolysis.
  • part of the material stored in the storage area (defined zones, each with separate collection of seep liquid) is directly charged with percolate.
  • the percolate is buffered in one or more buffer stores and can thus be fed several times to the feedstock.
  • a partial stream is discharged directly to the biogas reactor according to the basic method described above.
  • the irrigation system is made locally variable (for example, by the targeted activation of individual irrigation openings or by the design as a movable / displaceable irrigation system).
  • the percolation of the respective partial surface of the storage area is started with a time delay, so that different degradation states result in the individual subareas of the storage area.
  • a homogenization of Perkolat supplements and thus the biogas production in the subsequent methane reactor can be achieved.
  • the percolate of the last merged into the percolation operation partial area is applied to a previously passed into the percolation operation partial area with the aim of achieving better degradation of the starting materials.
  • the material flow guidance is thus comparable to the material flow guidance when using percolators in series connection.
  • the object is achieved by a system for the multistage hydrolysis of solid biogenic raw materials with a plurality of hydrolysis devices for producing biogas, in which the hydrolysis devices are connected with quantities of biogenic raw materials such that they are operable offset in time and the hydrolyzate which runs from a hydrolyzer having a fresh amount is respectively supplied to the hydrolysis device having the next-highest amount as percolation liquid.
  • the hydrolysis devices are connected according to an advantageous embodiment of the invention with a drain of a methane reactor.
  • the storage volume located after the drain has a device for supplying air.
  • the device for supplying air may also be arranged elsewhere in the connection between drain and hydrolysis devices. This facility ensures that vented effluent of the methane reactor can be used as percolate or percolate additive for the hydrolysis of fresh quantities of biogenic raw materials.
  • the hydrolysis devices with associated reservoirs and pump wells have means for supplying air.
  • the hydrolysis devices have means for removing air and gas which develops during the hydrolysis.
  • the hydrolysis devices are percolators with a sprinkler device and a device for solid / liquid separation.
  • the percolators have a temporary storage for the hydrolyzate or the percolators are followed by a buffer for the hydrolyzate.
  • the percolators are connected in such a way that the hydrolyzate proceeding from a fresher quantity is supplied in each case to the next-highest quantity as percolation liquid.
  • a plurality of percolators are used, which can be constructed identically and each of which percolator is provided with a corresponding buffer (eg. larger shaft at the outlet of the percolator) can be equipped.
  • These percolators are now operated in a series circuit, wherein the percolate flow is conducted in quasi-direct current.
  • the percolators are filled or emptied in regular operation with a time interval, so that in the overall process both fresh input material as well as those with longer residence time - referred to here as older material - finds.
  • the cargo of hydrolyzed organic substances, which are then passed into the methane stage after the last percolate stage - possibly after buffer storage - increases accordingly, so that the economy of the process improves because of the higher specific yield of biogenic raw materials.
  • concentration of organic substances in the hydrolyzate increases from stage to stage (see Fig. 3). This increases the specific gas yield of the methane reactor, which can now be built smaller. In addition, the amount of liquid in circulation decreases.
  • a single pump shaft is used for all percolators (in Fig. 2 eg 3 percolators).
  • the stepped material flow guide is achieved by the fact that the inlet to the pump shaft via a valve control at the end of the buffer only one percolator and accordingly at a certain time only the spraying with hydrolyzate takes place only in a percolator. After a set period of time is the percolation is interrupted, the inlet valve of the next buffer is opened and the percolation is switched over to the next corresponding assigned percolator. The effluent of the percolator with the oldest material is directed to the reservoir, from which the highly enriched hydrolyzate is metered into a methane stage.
  • mobile percolators can be used with stationary or movable sprinkler.
  • a further advantageous embodiment of the plant according to the invention consists in using the flax silos required for intermediate storage of the feedstocks (for example maize silage) directly for percolation / hydrolysis.
  • the feedstocks for example maize silage
  • each part of the material stored in the flax silo is directly exposed to percolate.
  • the percolate is buffered in one or more buffer stores and can thus be fed several times to the feedstock.
  • a partial stream is discharged directly to the biogas reactor according to the basic method described above.
  • the irrigation system is made locally variable (for example, by the targeted control of individual sprinkler openings or by the design as a movable / movable sprinkler system).
  • the percolation of the respective zone in the storage area is started with a time delay, resulting in different degradation states in the individual zones.
  • a homogenization of Perkolat supplement and thus the biogas production in the subsequent methane reactor can be achieved.
  • FIG. 2 flow diagram of an example plant with 3 percolators
  • FIG. 2 shows a flow diagram of a plant for the production of biogas with 3 percolators H1 to H3 and a methane reactor R.
  • the percolators H1 to H3 have the same structure, are lined with an acid-proof lining and can be loaded and unloaded using conventional technology, for example wheel loaders.
  • the percolators H1 to H3 each have a sprinkler for the supply of percolate and in each case a sieve plate, which allows a solid / liquid separation of the hydrolyzate from the fixed bed.
  • the percolators H1 to H3 are each followed by a buffer ZW1 to ZW3, which collects the hydrolyzate leaving the fixed bed.
  • the percolators H1 to H3 are connected via a collecting air line with a biofilter BF for exhaust air removal and purification and odor neutralization.
  • the latches ZWl to ZW3 are connected via valves with controllable and lockable connection lines with the pump shaft Pl.
  • the pump shaft Pl is connected to the sprinkler systems of the percolators H1 to H3 and to a reservoir S1.
  • the hydrolyzate collecting in the pump shaft with pump P1 can be equipped with a heat exchanger W1 (for setting the optimum temperature for the hydrolysis process) Connecting line the respective sprinkler systems of percolators Hl to H3 are supplied as percolate.
  • Memory Sl is connected to the methane reactor Rl for biogas production. Via this connecting line, the methane reactor can be supplied with the aid of the pump P2 hydrolyzate. In the heat exchanger W2 the optimum temperature for the methane production of the hydrolyzate is set.
  • hydrolyzate from the reservoir Sl by means of the pump P3 via the heat exchanger Wl again be supplied to the percolators, z. B. if the hydrolyzate has not yet reached the optimum concentration of organic matter.
  • Memory S2 allows the intake of effluent from the methane reactor Rl.
  • Memories Sl and S2 each have a means for supplying air.
  • Vented drain can be supplied via a connecting line from the reservoir S2 by means of the pump P4 the sprinkler of the percolator with fresh biogenic raw material.
  • the valve control associated with the connection line allows a corresponding supply line.
  • Buffer, pump shaft and memory Sl and S2 have a sludge outlet.
  • Excess liquid produced in the overall process is discharged from the container S2 and can be filled into tank trucks by means of pump P5 and utilized externally (preferably as fertilizer for closing nutrient cycles).
  • the plant of Fig. 2 operates as follows:
  • the percolators Hl to H3 are filled at different times with biogenic raw materials. For example, percolator H3 may have the oldest charge, percolator H2 may have the next charge, and percolator H1 may just have been refilled.
  • the aerated discharge from the methane reactor Rl is fed via the sprinkler system to the percolator Hl filled with fresh input material.
  • This percolate has only a low concentration of degradable organic matter, but enzymes, hydrolysis bacteria and in particular nutrients.
  • the effluent from the fixed bed of percolator Hl hydrolyzate is collected in the buffer ZWl, fed to the pump shaft Pl and fed from there via the connecting line and a heat exchanger of the sprinkler system of the percolator H2.
  • the hydrolyzate passing through the fixed bed is collected in the buffer ZW2 and, after the pump shaft P 1 has been emptied, transferred to it.
  • the hydrolyzate collected in the pump shaft Pl is supplied to the sprinkler system of the percolator H3 via the corresponding connecting line with associated heat exchanger, collected after passing through the fixed bed in the buffer ZW3 and, after emptying the pump shaft, transferred to the storage device S1 for forwarding. From the storage 1, the enriched percolation liquid can then be fed to the methane reactor Rl.
  • Fig. 3 shows a scheme of the inventive solution based on 3-stage current control of the hydrolyzate as shown in Scheme Fig. 2.
  • oTS organic dry matter

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Organic Chemistry (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Genetics & Genomics (AREA)
  • Biomedical Technology (AREA)
  • Sustainable Development (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

L'invention concerne un procédé et une installation d'hydrolyse en plusieurs étapes de matières premières biogènes solides au moyen de percolateurs (Hl, H2, H3), avec génération subséquente de biogaz (Rl) exclusivement à partir de l'hydrolysat. Selon l'invention, plusieurs quantités de matières premières biogènes solides sont hydrolysées de manière décalée dans le temps, l'hydrolysat produit par la quantité de matières la plus récente étant introduit en tant que percolat dans la quantité de matières précédant immédiatement. L'installation comprend plusieurs dispositifs d'hydrolyse, de préférence des percolateurs.
PCT/DE2006/001325 2005-07-26 2006-07-25 Procede et installation d'hydrolyse en plusieurs etapes de matieres premieres biogenes solides WO2007012328A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP06761833A EP1907139A1 (fr) 2005-07-26 2006-07-25 Procede et installation d'hydrolyse en plusieurs etapes de matieres premieres biogenes solides
DE200611001877 DE112006001877A5 (de) 2005-07-26 2006-07-25 Verfahren und Anlage zur mehrstufigen Hydrolyse fester biogener Rohstoffe

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005036086.6 2005-07-26
DE102005036086 2005-07-26

Publications (1)

Publication Number Publication Date
WO2007012328A1 true WO2007012328A1 (fr) 2007-02-01

Family

ID=37395991

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2006/001325 WO2007012328A1 (fr) 2005-07-26 2006-07-25 Procede et installation d'hydrolyse en plusieurs etapes de matieres premieres biogenes solides

Country Status (3)

Country Link
EP (1) EP1907139A1 (fr)
DE (1) DE112006001877A5 (fr)
WO (1) WO2007012328A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2216301A1 (fr) * 2009-02-10 2010-08-11 Niels Christian Holm Procédé de traitement d'eau de percolateur produite dans la fermentation sèche
DE102010028707A1 (de) 2010-05-06 2011-11-10 GICON-Großmann Ingenieur Consult GmbH Verfahren zur Prozessführung von Perkolatoren in zweistufigen Biogaserzeugungsverfahren
US8329455B2 (en) 2011-07-08 2012-12-11 Aikan North America, Inc. Systems and methods for digestion of solid waste
CN105174473A (zh) * 2015-09-21 2015-12-23 中国农业大学 一种曝气强化人工湿地深度处理沼液的方法
DE102014011479A1 (de) 2014-07-31 2016-02-04 Christoph Bürger Neues Verfahren zur Vergärung biogener Energieträger
WO2020020392A1 (fr) * 2018-07-03 2020-01-30 Biosure Waste And Energy Gmbh Hydrolyse

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4652374A (en) * 1983-09-09 1987-03-24 Gist-Brocades N.V. Process for anaerobic fermentation of solid wastes in water in two phases
US5269634A (en) * 1992-08-31 1993-12-14 University Of Florida Apparatus and method for sequential batch anaerobic composting of high-solids organic feedstocks
EP0803568A1 (fr) * 1996-04-26 1997-10-29 CT Umwelttechnik AG Installation de fermentation et procédé à plusieurs étapes exécutable au moyen de ce procédé
DE19702712A1 (de) * 1997-01-25 1998-07-30 Goehner Gilbert Dipl Ing Fh Abwasser-Kläreinrichtung
DE19909353A1 (de) * 1998-11-06 2000-05-11 Patrick Mueller Verfahren und Vorrichtung zur Aufbereitung eines Organik enthaltenden Stoffgemisches
DE29907836U1 (de) * 1999-05-03 2000-09-21 Etterer Manfred Festinstallierte oder mobile chemisch/physikalische Behandlungsanlage zur überwiegenden/vollständigen Verwertung von industriellen Abfällen
DE19937876A1 (de) * 1999-08-17 2001-03-01 Uwe Heinemann Verfahren zur biologischen Umsetzung von organischen Stoffen zu Methangas

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4652374A (en) * 1983-09-09 1987-03-24 Gist-Brocades N.V. Process for anaerobic fermentation of solid wastes in water in two phases
US5269634A (en) * 1992-08-31 1993-12-14 University Of Florida Apparatus and method for sequential batch anaerobic composting of high-solids organic feedstocks
EP0803568A1 (fr) * 1996-04-26 1997-10-29 CT Umwelttechnik AG Installation de fermentation et procédé à plusieurs étapes exécutable au moyen de ce procédé
DE19702712A1 (de) * 1997-01-25 1998-07-30 Goehner Gilbert Dipl Ing Fh Abwasser-Kläreinrichtung
DE19909353A1 (de) * 1998-11-06 2000-05-11 Patrick Mueller Verfahren und Vorrichtung zur Aufbereitung eines Organik enthaltenden Stoffgemisches
DE29907836U1 (de) * 1999-05-03 2000-09-21 Etterer Manfred Festinstallierte oder mobile chemisch/physikalische Behandlungsanlage zur überwiegenden/vollständigen Verwertung von industriellen Abfällen
DE19937876A1 (de) * 1999-08-17 2001-03-01 Uwe Heinemann Verfahren zur biologischen Umsetzung von organischen Stoffen zu Methangas

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
S. HALL, A. THOMAS, F. HAWKES, D. HAWKES: "Operation of linked percolating packed bed anaerobic digesters", FIFTH INTERNATIONAL SYMPOSIUM ON ANAEROBIC DIGESTION, 22 May 1988 (1988-05-22) - 26 May 1988 (1988-05-26), Bologna, Italy, pages 273 - 279, XP008071579 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2216301A1 (fr) * 2009-02-10 2010-08-11 Niels Christian Holm Procédé de traitement d'eau de percolateur produite dans la fermentation sèche
DE102010028707A1 (de) 2010-05-06 2011-11-10 GICON-Großmann Ingenieur Consult GmbH Verfahren zur Prozessführung von Perkolatoren in zweistufigen Biogaserzeugungsverfahren
WO2011138426A1 (fr) 2010-05-06 2011-11-10 Gicon Grossmann Ingenieur Consult Gmbh Procédé et installation d'exécution de traitement étanche aux gaz par des appareils de percolation dans un procédé de production de biogaz en deux étapes ou plus
CN102959072A (zh) * 2010-05-06 2013-03-06 智康工程顾问有限公司 在具有两个或更多个级的生物气体方法中用于渗滤器的气密过程控制的方法和系统
US8969032B2 (en) 2010-05-06 2015-03-03 GICON Grossman Ingenieur Consult GmbH Method and system for the gas-tight process control of percolators in a biogas method having two or more stages
US8329455B2 (en) 2011-07-08 2012-12-11 Aikan North America, Inc. Systems and methods for digestion of solid waste
US8492134B2 (en) 2011-07-08 2013-07-23 Aikan North America, Inc. Systems and methods for digestion of solid waste
US9328323B2 (en) 2011-07-08 2016-05-03 Aikan North America, Inc. Systems and methods for digestion of solid waste
DE102014011479A1 (de) 2014-07-31 2016-02-04 Christoph Bürger Neues Verfahren zur Vergärung biogener Energieträger
CN105174473A (zh) * 2015-09-21 2015-12-23 中国农业大学 一种曝气强化人工湿地深度处理沼液的方法
CN105174473B (zh) * 2015-09-21 2017-10-31 中国农业大学 一种强化曝气人工湿地深度处理沼液的系统
WO2020020392A1 (fr) * 2018-07-03 2020-01-30 Biosure Waste And Energy Gmbh Hydrolyse

Also Published As

Publication number Publication date
EP1907139A1 (fr) 2008-04-09
DE112006001877A5 (de) 2008-04-30

Similar Documents

Publication Publication Date Title
EP1929024B1 (fr) Procédé de production de biogaz utilisant un substrat à haute teneur en solides et en azote
EP2346997B1 (fr) Procédé de production de méthane à partir d'eaux industrielles et d'un matériau biogène
EP2155854B1 (fr) Fermenteur destiné à la production de biogaz à partir d'un matériau organique susceptible d'être pompé
DE102009009985A1 (de) Verfahren zur Aufkonzentration von Mikroorganismen in wässrigen Substraten
EP2501818B1 (fr) Procédé optimisé au plan énergétique pour l'exploitation d'une installation de production de bioéthanol
DE102007004892A1 (de) Verfahren und Vorrichtung zur Aufbereitung organischer Reststoffe aus Biogasanlagen
DE2952794A1 (de) Verfahren und vorrichtung zur behandlung von stickstoffverbindungen enthaltenden organischen massen
DE102008015609A1 (de) Biogasanlage und Verfahren zur Erzeugung von Biogas
EP2566947B1 (fr) Procédé et dispositif de fabrication de biogaz à partir d'un substrat de fermentation
WO2007012328A1 (fr) Procede et installation d'hydrolyse en plusieurs etapes de matieres premieres biogenes solides
DE3049302C2 (de) Verfahren zur Verwertung von Lebenstätigkeitsprodukten von Tieren und Anlage zur Ausführung desselben
WO2018138368A1 (fr) Procédé et dispositif pour produire du biogaz
DE102007004135A1 (de) Verfahren und Vorrichtung zur Vergärung von Biomassen
DE102006012130B4 (de) Verfahren und Vorrichtung zur Gewinnung von Biogas
EP0589155A1 (fr) Traitement anaérobique de substrats à forte concentration en graisses
DE29605625U1 (de) Anlage zur Vergärung von organischen Abfallstoffen
DE102014011479A1 (de) Neues Verfahren zur Vergärung biogener Energieträger
DE102010033442A1 (de) Verfahren zur Aufkonzentration von Mikroorganismen in wässrigen Substraten
EP2821475A1 (fr) Production de biogaz à partir de biomasse
DE102018120117A1 (de) Verfahren, Anlage und System zur Gärrestaufbereitung
CH697136A5 (de) Vergärungsverfahren und Anlage zum Vergären.
EP2760978B1 (fr) Procédé de production de biogaz
DE102021101167A1 (de) Verfahren und Vorrichtung zur Verwertung von organischen Materialien
EP3012007A1 (fr) Méthode et procédé pour évaporer un substrat liquide
DE102010032916A1 (de) Verfahren und System zur Aufkonzentration von Wirtschaftsdünger, insbesondere Gülle für den Einsatz in einer Biogasanlage

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1120060018779

Country of ref document: DE

REEP Request for entry into the european phase

Ref document number: 2006761833

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2006761833

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2006761833

Country of ref document: EP

REF Corresponds to

Ref document number: 112006001877

Country of ref document: DE

Date of ref document: 20080430

Kind code of ref document: P