EP2418309B1 - Fabric for protective clothing and protective clothing - Google Patents

Fabric for protective clothing and protective clothing Download PDF

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Publication number
EP2418309B1
EP2418309B1 EP11174836.4A EP11174836A EP2418309B1 EP 2418309 B1 EP2418309 B1 EP 2418309B1 EP 11174836 A EP11174836 A EP 11174836A EP 2418309 B1 EP2418309 B1 EP 2418309B1
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EP
European Patent Office
Prior art keywords
para
fabric
thread
aramide
proportion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP11174836.4A
Other languages
German (de)
French (fr)
Other versions
EP2418309A2 (en
EP2418309A8 (en
EP2418309A3 (en
Inventor
Britta Smeulders
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ibena Textilwerke GmbH
Original Assignee
Ibena Textilwerke GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Ibena Textilwerke GmbH filed Critical Ibena Textilwerke GmbH
Publication of EP2418309A2 publication Critical patent/EP2418309A2/en
Publication of EP2418309A8 publication Critical patent/EP2418309A8/en
Publication of EP2418309A3 publication Critical patent/EP2418309A3/en
Application granted granted Critical
Publication of EP2418309B1 publication Critical patent/EP2418309B1/en
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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D03D1/0041—Cut or abrasion resistant
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/52—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads thermal insulating, e.g. heating or cooling
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/004—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft with weave pattern being non-standard or providing special effects
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments

Definitions

  • the invention relates to a fabric for protective clothing and protective clothing, which is at least partially made of the fabric of the invention.
  • Protective clothing which has a comparatively low heat transfer through the use of suitable materials. As a result, the heat of a fire can be shielded, for example, on firefighter protective suits.
  • Pigmented para-aramid fibers such as Kevlar (trademark of DuPont), usually provide the relatively low heat transfer.
  • thermo-protective suits In the known thermo-protective suits, however, it has been found that the pigmented para-aramid fibers fibrillate during washing and thereby at least partially and in the medium term their non-pigmented interior is exposed. This results in an unsightly appearance of the suit. It should be mentioned in addition that a regular wash of such protective clothing must not be omitted, even if they are relatively rarely worn, because otherwise can form a dust layer on clothing, which in extreme cases Dust layer can form, which burns in extreme cases with appropriate heat and thus endangers the safety of the wearer.
  • the invention has for its object to provide a fabric for protective clothing, which meets the requirements for low heat transfer and at the same time permanently maintains a handsome appearance.
  • the object is achieved by the fabric described in claim 1, which is provided for a protective clothing.
  • this is woven from warp and weft yarns which have a different proportion of pigmented para-aramid fibers, in particular Kevlar (trademark of DuPont).
  • the warp yarn has a lower or higher content of para-aramid fibers than the weft yarn.
  • the fabric according to the invention is woven in such a way with one-sided binding that on the outside of the fabric increasingly a thread with a lower para-aramid content is present.
  • the para-aramid content on the outside can be kept low so that the above-described effect of fibrillation does not lead to an impaired appearance.
  • the para-aramid content on the outside can be kept low so that the above-described effect of fibrillation does not lead to an impaired appearance.
  • the para-aramid content on the outside can in Connection with a thread with higher para-aramid content, which is increasingly on the inside, overall the desired, low heat transfer can be achieved.
  • a percentage of 3% to 8%, in particular about 5% is provided for the thread with the lower para-aramid content.
  • a protective clothing made from the fabric according to the invention meets the requirements with regard to the reduced heat transfer, even if its para-aramid content is less than 23% overall, preferably less than 20%, and in particular only about 14%.
  • the warp yarn have the lower para-aramid content.
  • the predominant use of meta-aramid fibers such as Nomex (trademark of DuPont) is envisaged.
  • the fabric in the unilateral binding of the invention it is presently preferred to weave it with yarns finer than 36.4 tex (Nm (number metric) 55/2).
  • Nm number metric
  • yarns with 28.6 tex (Nm 70/2) are used.
  • This essentially means using thinner threads in weaving than this was previously the case, for example, by using threads with 36.4 tex (Nm 55).
  • the fabric advantageously becomes denser so that the reduction of the para-aramid content is thereby compensated.
  • the basis weight does not increase despite the denser fabric and is presently preferably at 190 g / m 2 to 210 g / m 2 , in particular about 195 g / m 2 .

Description

Technisches GebietTechnical area

Die Erfindung betrifft ein Gewebe für eine Schutzbekleidung sowie eine Schutzbekleidung, die zumindest teilweise aus dem erfindungsgemäßen Gewebe ausgeführt ist.The invention relates to a fabric for protective clothing and protective clothing, which is at least partially made of the fabric of the invention.

Es sind Schutzkleidungen bekannt, die durch Verwendung von geeigneten Materialien einen vergleichsweise geringen Wärmedurchgang aufweisen. Hierdurch kann beispielsweise an Feuerwehr-Schutzanzügen die Hitze eines Brandes abgeschirmt werden. Für den relativ geringen Wärmedurchgang sorgen in der Regel pigmentierte Para-Aramid-Fasern, beispielsweise Kevlar (Marke von DuPont).Protective clothing is known which has a comparatively low heat transfer through the use of suitable materials. As a result, the heat of a fire can be shielded, for example, on firefighter protective suits. Pigmented para-aramid fibers, such as Kevlar (trademark of DuPont), usually provide the relatively low heat transfer.

Aus der DE 20 2004 005 008 U1 geht ein Gewebe hervor, bei dem die dem Träger zugewandte Seite mehr Para-Aramid-Fasern enthält, als die vom Träger abgewandte Seite.From the DE 20 2004 005 008 U1 shows a fabric in which the wearer facing side contains more para-aramid fibers, as the side facing away from the wearer.

Stand der TechnikState of the art

Bei den bekannten Thermo-Schutzanzügen hat sich jedoch herausgestellt, dass die pigmentierten Para-Aramid-Fasern beim Waschen fibrillieren und hierdurch zumindest teilweise und mittelfristig ihr nicht pigmentiertes Inneres freigelegt wird. Hierdurch ergibt sich ein unansehnliches Erscheinungsbild des Schutzanzugs. Es sei ergänzend erwähnt, dass eine regelmäßige Wäsche derartiger Schutzbekleidung nicht unterbleiben darf, auch wenn sie verhältnismäßig selten getragen werden, weil sich sonst auf der Kleidung eine Staubschicht bilden kann, die im Extremfall bei Staubschicht bilden kann, die im Extremfall bei entsprechender Wärmeeinwirkung abbrennt und insoweit die Sicherheit des Trägers gefährdet.In the known thermo-protective suits, however, it has been found that the pigmented para-aramid fibers fibrillate during washing and thereby at least partially and in the medium term their non-pigmented interior is exposed. This results in an unsightly appearance of the suit. It should be mentioned in addition that a regular wash of such protective clothing must not be omitted, even if they are relatively rarely worn, because otherwise can form a dust layer on clothing, which in extreme cases Dust layer can form, which burns in extreme cases with appropriate heat and thus endangers the safety of the wearer.

Darstellung der ErfindungPresentation of the invention

Vor diesem Hintergrund liegt der Erfindung die Aufgabe zugrunde, ein Gewebe für eine Schutzbekleidung zu schaffen, das die Anforderungen im Hinblick auf einen geringen Wärmedurchgang erfüllt und gleichzeitig dauerhaft ein ansehnliches Erscheinungsbild beibehält. Die Lösung der Aufgabe erfolgt durch das in Anspruch 1 beschriebene Gewebe, das für eine Schutzbekleidung vorgesehen ist.Against this background, the invention has for its object to provide a fabric for protective clothing, which meets the requirements for low heat transfer and at the same time permanently maintains a handsome appearance. The object is achieved by the fabric described in claim 1, which is provided for a protective clothing.

Demzufolge ist dieses aus Kett- und Schussfäden gewebt, die einen unterschiedlichen Anteil an pigmentierten Para-Aramid-Fasern, insbesondere Kevlar (Marke von DuPont) aufweisen. Mit anderen Worten weist der Kettfaden einen niedrigeren oder höheren Anteil an Para-Aramid-Fasern auf als der Schussfaden. Ferner ist das erfindungsgemäße Gewebe derart mit einseitiger Bindung gewebt, dass auf der Außenseite des Gewebes vermehrt ein Faden mit niedrigerem Para-Aramid-Anteil vorliegt. Den Fachleuten ist geläufig, was unter einseitiger Bindung verstanden wird, so dass lediglich erwähnt sei, das erfindungsgemäß der Faden mit dem niedrigeren Para-Aramid-Anteil dadurch vermehrt auf der Außenseite vorliegt, dass er sich nicht, wie bei einer gleichseitigen Bindung, gleichmäßig zwischen Außen- und Innenseite erstreckt, sondern an der Außenseite regelmäßig über beispielsweise zwei hierzu querverlaufende Fäden läuft, während er an der Innenseite regelmäßig nur über einen quer hierzu verlaufenden Faden läuft.Accordingly, this is woven from warp and weft yarns which have a different proportion of pigmented para-aramid fibers, in particular Kevlar (trademark of DuPont). In other words, the warp yarn has a lower or higher content of para-aramid fibers than the weft yarn. Furthermore, the fabric according to the invention is woven in such a way with one-sided binding that on the outside of the fabric increasingly a thread with a lower para-aramid content is present. It is well known to those skilled in the art what is meant by unilateral bonding, so that only mention is made according to the invention that the thread with the lower para-aramid content is increasingly present on the outside, so that it does not interpose uniformly, as in the case of an equilateral bond Outside and inside extends, but regularly on the outside over, for example, two transverse threads running, while it runs on the inside regularly only over a transverse thereto extending thread.

Durch die erfindungsgemäße Maßnahme kann der Para-Aramid-Anteil an der Außenseite gering gehalten werden, so dass der oben beschriebene Effekt des Fibrillierens nicht zu einem beeinträchtigten Erscheinungsbild führt. Gleichzeitig kann in Verbindung mit einem Faden mit höherem Para-Aramid-Anteil, der vermehrt an der Innenseite vorliegt, insgesamt der angestrebte, geringe Wärmedurchgang erreicht werden.By virtue of the measure according to the invention, the para-aramid content on the outside can be kept low so that the above-described effect of fibrillation does not lead to an impaired appearance. At the same time can in Connection with a thread with higher para-aramid content, which is increasingly on the inside, overall the desired, low heat transfer can be achieved.

Erfindungsgemäß ist für den Faden mit dem geringeren Para-Aramid-Anteil ein prozentualer Anteil von 3 % bis 8 %, insbesondere etwa 5 % vorgesehen.According to the invention a percentage of 3% to 8%, in particular about 5% is provided for the thread with the lower para-aramid content.

Bevorzugte Weiterbildungen sind in den weiteren Ansprüchen beschrieben.Preferred developments are described in the further claims.

Wenngleich grundsätzlich für das erfindungsgemäße Gewebe jede einseitige Bindung, wie beispielsweise eine Atlas-Bindung denkbar ist, wird dennoch derzeit eine 2:1-Köperbindung bevorzugt.Although in principle any unilateral bond, such as an atlas bond, is conceivable for the fabric according to the invention, a 2: 1 twill weave is currently preferred.

Bei ersten Versuchen hat sich ferner für den Faden mit dem höheren Para-Aramid-Anteil ein Bereich von 20 % bis 25 %, insbesondere etwa 23 % als günstig herausgestellt.In first attempts, a range of 20% to 25%, in particular about 23% has also been found to be favorable for the thread with the higher para-aramid content.

Durch Versuche konnte ferner festgestellt werden, dass eine aus dem erfindungsgemäßen Gewebe hergestellte Schutzbekleidung die Anforderungen im Hinblick auf den verringerten Wärmedurchgang erfüllt, auch wenn sein Para-Aramid-Anteil insgesamt geringer als 23 %, bevorzugt geringer als 20 % ist, und insbesondere bei nur etwa 14 % liegt.It has also been found by experiments that a protective clothing made from the fabric according to the invention meets the requirements with regard to the reduced heat transfer, even if its para-aramid content is less than 23% overall, preferably less than 20%, and in particular only about 14%.

Ferner wird derzeit bevorzugt, dass der Kettfaden den niedrigeren Para-Aramid-Anteil aufweist. Allgemein ist für den Faden mit dem niedrigeren Para-Aramid-Anteil die überwiegende Verwendung von Meta-Aramid-Fasern, wie z.B. Nomex (Marke von DuPont) vorgesehen.Further, it is presently preferred that the warp yarn have the lower para-aramid content. Generally, for the thread with the lower para-aramid content, the predominant use of meta-aramid fibers such as Nomex (trademark of DuPont) is envisaged.

Um bei der erfindungsgemäßen einseitigen Bindung dennoch ein "feines" Erscheinungsbild des Gewebes zu erreichen, wird derzeit bevorzugt, dieses mit Garnen zu weben, die feiner sind als 36,4 tex (Nm (Nummer metrisch) 55/2). Insbesondere werden derzeit Garne mit 28,6 tex (Nm 70/2) verwendet. Dies bedeutet im Wesentlichen die Verwendung dünnerer Fäden beim Weben, als dies bisher beispielsweise durch Verwendung von Fäden mit 36,4 tex (Nm 55) der Fall war. Durch die Verwendung dünnerer, feinerer Fäden kann trotz der einseitigen Bindung ein gleichmäßiges und ansehnliches Erscheinungsbild des Gewebes erhalten werden. Ferner wird das Gewebe in vorteilhafter Weise dichter, so dass die Reduzierung des Para-Aramid-Anteils dadurch ausgeglichen wird. Darüber hinaus erhöht sich das Flächengewicht trotz des dichteren Gewebes nicht und liegt derzeit bevorzugt bei 190 g/m2 bis 210 g/m2, insbesondere etwa 195 g/m2.To still achieve a "fine" appearance of the fabric in the unilateral binding of the invention, it is presently preferred to weave it with yarns finer than 36.4 tex (Nm (number metric) 55/2). In particular, currently yarns with 28.6 tex (Nm 70/2) are used. This essentially means using thinner threads in weaving than this was previously the case, for example, by using threads with 36.4 tex (Nm 55). By using thinner, finer threads, a uniform and attractive appearance of the fabric can be obtained despite the unilateral bonding. Furthermore, the fabric advantageously becomes denser so that the reduction of the para-aramid content is thereby compensated. In addition, the basis weight does not increase despite the denser fabric and is presently preferably at 190 g / m 2 to 210 g / m 2 , in particular about 195 g / m 2 .

Claims (7)

  1. Fabric for protective clothing, wherein the warp thread of the fabric has a lower or higher proportion of pigmented para-aramide than the weft thread, wherein the fabric is woven with one-sided weave such that on the outer side of the fabric, more thread with lower para-aramide proportion is present than thread with higher para-aramide proportion, characterised in that the thread with lower para-aramide proportion has a para-aramide proportion of 3 % to 8 %, in particular about 5 %.
  2. Fabric according to claim 1, characterised in that the latter is woven with a 2:1 twill weave.
  3. Fabric according to claim 1 or 2, characterised in that the thread with higher para-aramide proportion has a para-aramide proportion of 20 % to 25 %, in particular about 23 %.
  4. Fabric according to one of the preceding claims, characterised in that the para-aramide proportion on the whole is less than 23 %, preferably less than 20 %, and in particular lies at about 14 %.
  5. Fabric according to one of the preceding claims, characterised in that the warp thread has the lower para-aramide proportion.
  6. Fabric according to one of the preceding claims, characterised in that the latter is woven at least partly from a thread which is finer than 36.4 tex (Nm (number metric) 55/2), in particular at about 28.6 tex (Nm 70/2).
  7. Protective clothing which is made at least partly from a fabric according to one of the preceding claims.
EP11174836.4A 2010-08-09 2011-07-21 Fabric for protective clothing and protective clothing Active EP2418309B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE202010011193U DE202010011193U1 (en) 2010-08-09 2010-08-09 Fabrics for protective clothing and protective clothing

Publications (4)

Publication Number Publication Date
EP2418309A2 EP2418309A2 (en) 2012-02-15
EP2418309A8 EP2418309A8 (en) 2012-04-25
EP2418309A3 EP2418309A3 (en) 2013-09-18
EP2418309B1 true EP2418309B1 (en) 2015-09-30

Family

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EP11174836.4A Active EP2418309B1 (en) 2010-08-09 2011-07-21 Fabric for protective clothing and protective clothing

Country Status (4)

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EP (1) EP2418309B1 (en)
CN (1) CN102373547A (en)
DE (1) DE202010011193U1 (en)
EA (1) EA021998B1 (en)

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DE102011090173B3 (en) * 2011-12-30 2013-05-08 Ibena Textilwerke Gmbh fabric combination
US9386816B2 (en) 2012-02-14 2016-07-12 International Textile Group, Inc. Fire resistant garments containing a high lubricity thermal liner
CN102677297A (en) * 2012-05-29 2012-09-19 蔡紫林 Yarn-dyed fabric
CN102677347A (en) * 2012-05-29 2012-09-19 蔡紫林 Yarn-dyed fabric
CN103603123A (en) * 2013-11-11 2014-02-26 绍兴市恒睿无纺布科技有限公司 High-strength flame-retardant jean and production process and uses thereof
CN104908390A (en) * 2014-03-13 2015-09-16 宜兴市宜泰碳纤维织造有限公司 PVC carbon fiber composite fabric
CN104908395A (en) * 2014-03-13 2015-09-16 宜兴市宜泰碳纤维织造有限公司 Hybrid twill
DE202015102141U1 (en) 2015-04-29 2015-05-27 Ibena Textilwerke Gmbh Fabrics for protective clothing and protective clothing
US10405594B2 (en) 2015-05-21 2019-09-10 International Textile Group, Inc. Inner lining fabric
CN106222844A (en) * 2016-08-17 2016-12-14 长兴艾佳纺织有限公司 A kind of tencel textile cloth
DE102018203761B3 (en) 2018-03-13 2019-02-21 Ibena Textilwerke Gmbh Double fabric made of flame retardant fibers
CN108936863A (en) * 2018-08-10 2018-12-07 繁昌县亘通智能装备有限公司 A kind of electric welding radiation protection integrated protective clothing
WO2020198668A1 (en) 2019-03-28 2020-10-01 Southern Mills, Inc. Flame resistant fabrics
US11891731B2 (en) 2021-08-10 2024-02-06 Southern Mills, Inc. Flame resistant fabrics

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DE202004005008U1 (en) * 2004-03-30 2004-06-24 E.I. Du Pont De Nemours And Company, Wilmington Textile fabrics for protective clothing
JP2006016709A (en) * 2004-06-30 2006-01-19 Teijin Techno Products Ltd Heat-resistant protective wear
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KR101270782B1 (en) * 2005-08-09 2013-06-04 데이진 가부시키가이샤 Woven fabric of two-layer structure and heat-resistant protective garment comprising the same
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Also Published As

Publication number Publication date
DE202010011193U1 (en) 2010-11-04
EA021998B1 (en) 2015-10-30
CN102373547A (en) 2012-03-14
EP2418309A2 (en) 2012-02-15
EA201101064A1 (en) 2012-04-30
EP2418309A8 (en) 2012-04-25
EP2418309A3 (en) 2013-09-18

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