EP2418019A1 - Procédé de matification partielle de couches de laque UV - Google Patents

Procédé de matification partielle de couches de laque UV Download PDF

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Publication number
EP2418019A1
EP2418019A1 EP11006309A EP11006309A EP2418019A1 EP 2418019 A1 EP2418019 A1 EP 2418019A1 EP 11006309 A EP11006309 A EP 11006309A EP 11006309 A EP11006309 A EP 11006309A EP 2418019 A1 EP2418019 A1 EP 2418019A1
Authority
EP
European Patent Office
Prior art keywords
excimer
radiation
template
layer
radiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11006309A
Other languages
German (de)
English (en)
Other versions
EP2418019B1 (fr
Inventor
Gottfried Brandstetter
Georg Aigner
Helmut Käferböck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hueck Folien GmbH
Original Assignee
Hueck Folien GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hueck Folien GmbH filed Critical Hueck Folien GmbH
Priority to SI201131202T priority Critical patent/SI2418019T1/sl
Priority to PL11006309T priority patent/PL2418019T3/pl
Publication of EP2418019A1 publication Critical patent/EP2418019A1/fr
Application granted granted Critical
Publication of EP2418019B1 publication Critical patent/EP2418019B1/fr
Active legal-status Critical Current
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/32—Processes for applying liquids or other fluent materials using means for protecting parts of a surface not to be coated, e.g. using stencils, resists
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2252/00—Sheets
    • B05D2252/04—Sheets of definite length in a continuous process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0486—Operating the coating or treatment in a controlled atmosphere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/066—After-treatment involving also the use of a gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/061—Special surface effect
    • B05D5/062—Wrinkled, cracked or ancient-looking effect

Definitions

  • the invention relates to a method for the partial matting of UV lacquer layers by means of an excimer radiator.
  • UV lacquer coatings generally have high resistance and resistance to mechanical, physical and chemical influences, in particular high scratch resistance.
  • the surface of such lacquer layers after curing usually appears shiny or dull, depending on the composition of the paint used.
  • this is off EP 0 338 221 A a film web consisting of at least two layers, which, inter alia, has a 3 to 30 .mu.m thick acrylate lacquer layer produced using at least one monomeric, di- and / or trimeric acrylate, which consists of a matt lacquer based on an acrylate mixture which passes through Reaction of at least one prepolymeric acrylate with at least one monomeric, di- and / or trimeric acrylate, wherein the lacquer per 100 parts by weight of the acrylate (calculated without any additive, processing aid or blowing agent), 20- 60 parts by weight a matting agent or matting agent mixture, 1-10 parts by weight of a UV initiator or UV initiator mixture, 0-10 parts by weight of a blowing agent or blowing agent mixture contains or consists thereof.
  • matting results from the addition of a matting agent in the paint formulation. This achieves a so-called volume matting, ie the matting agent is more or less homogeneous in the paint matrix distributed there and generates a light scattering, which is perceived as matting.
  • EP 0 706 834 A is a process for the production of UV-curable lacquer-coated sheet-like support materials known with a matte or glossy surface, wherein the degree of matting of the UV coating is adjusted by the addition of mono- and / or difunctional monomers, and for the UV curing multiple radiation sources defined wavelength range can be used.
  • the matting that results here is due to the special shape of the surface during curing.
  • the remaining lacquer layer is not changed. In this case one speaks of a surface matting.
  • All of these methods provide full-surface, frosted lacquer coatings.
  • a partial matting can be achieved at most when already the UV coating is partially applied, in which case the carrier substrate appears at the non-printed areas. However, this also means that at the unprinted areas, the scratch resistance of the film surface is significantly lower than that of the UV lacquer layer.
  • the carrier film can first be coated over the whole area with a scratch-resistant UV lacquer layer and then partially coated with a matt UV lacquer layer. However, two steps are necessary and there is a difference in thickness between the frosted and glossy spots.
  • the object of the invention was to provide a method in which no full-surface, but a partial matting of UV lacquer layers in a single operation is possible.
  • the invention therefore relates to a process for the partial matting of UV coating layers, wherein a UV coating layer is applied to a carrier substrate and this is subsequently treated with an excimer radiator, characterized in that the excimer radiator within a template, the for the excimer radiation permeable and impermeable to the excimer radiation regions, is located, and the UV lacquer layer is partially exposed through the template with the excimer radiator.
  • a UV lacquer layer is first applied to a carrier substrate.
  • carrier films are preferably flexible plastic films, for example of PI, PP, MOPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK, LCP, PEN, PBT, PET, PA, PC, COC, POM, ABS, PVC , PTFE, ETFE (ethylene tetrafluoroethylene), PFA (tetrafluoroethylene-perfluoropropyl vinyl ether fluorocopolymer), MFA (tetrafluoromethylene-perfluoropropyl vinyl ether fluorocopolymer), PTFE (polytetrafluoroethylene), PVF (polyvinyl fluoride), PVDF (polyvinylidene fluoride), and EFEP (ethylene tetrafluoroethylene). Hexafluoropropylene fluoropolymer).
  • the carrier films preferably have a thickness of 5 to 700 .mu.m, preferably 5 to 200 .mu.m, particularly preferably 5 to 50 .mu.m.
  • metal foils for example Al, Cu, Sn, Ni, Fe or stainless steel foils having a thickness of 5-200 ⁇ m, preferably 10 to 80 ⁇ m, particularly preferably 20-50 ⁇ m, may also serve as the carrier substrate.
  • the films can also be surface-treated, coated or laminated, for example, with plastics or painted.
  • thermally activated paper or composites with paper such as composites with plastics having a basis weight of 20 - 500 g / m 2 , preferably 40 - 200 g / m 2 . be used.
  • woven or nonwovens such as continuous fiber webs, staple fiber webs and the like, which may optionally be needled or calendered, may be used as the carrier substrates.
  • fabrics or webs of plastics such as PP, PET, PA, PPS and the like, but it can also be woven or nonwovens made of natural, optionally treated fibers, such as viscose fibers are used.
  • the nonwovens or fabrics used have a weight per unit area of about 20 g / m 2 to 500 g / m 2 . If necessary, the nonwovens or fabrics must be surface-treated.
  • All carrier substrates can be present as web-shaped substrates or as piece goods.
  • the cargo may be, for example in the form of plates, tiles or other formats of optionally coated wood, plastic, metal, ceramics and the like.
  • the thickness of these substrates is usually a few mm or cm.
  • First layers may already be applied to the carrier substrate, e.g. Lacquer or metal layers which cause an optical effect (color, color effects, gloss, reflection) or have functional properties (adhesion, wetting of the UV lacquer layer, electrical conductivity, optically active, in particular diffractive optical or optical properties, magnetic properties).
  • Lacquer or metal layers which cause an optical effect (color, color effects, gloss, reflection) or have functional properties (adhesion, wetting of the UV lacquer layer, electrical conductivity, optically active, in particular diffractive optical or optical properties, magnetic properties).
  • the UV varnish can be applied by known application methods, e.g. Roller application, printing (gravure, flexo, offset or digital printing), casting or spraying, using slot die coating or curtain coating done.
  • application methods e.g. Roller application, printing (gravure, flexo, offset or digital printing), casting or spraying, using slot die coating or curtain coating done.
  • the selection of the application method is basically irrelevant, but the person skilled in the art will prefer to choose such a method which produces a layer on the substrate with as homogeneous a thickness as possible and as smooth a surface as possible.
  • an interesting, visually appealing contrast can also be created by the characteristic surface structure of the respective coating application in conjunction with the partial matting.
  • the UV coating is present as a mixture of monomers or oligomers with one or more photoinitiators and optionally other ingredients such as pigments, additives or solvents.
  • all radiation-curable UV coating compositions are suitable, but in particular the compositions consisting of DE 44 39 350 are known and react to the curing with excimer radiation with the formation of a micro-rough or -folded surface.
  • the thickness of the applied lacquer layer is usually between 1 and 1000 microns.
  • the layer thickness is usually in the range of 1 - 20 microns, in plates whose thickness is usually much greater, the layer thickness is more in the range of 50 -1000 microns.
  • the coated carrier substrate is then optionally pre-dried in a thermal dryer, whereby any volatile components present in the layer, such as e.g. Solvent, to be removed.
  • a thermal dryer whereby any volatile components present in the layer, such as e.g. Solvent, to be removed.
  • the coated carrier substrate is supplied to the excimer irradiation.
  • the excimer radiator is oriented transversely to the transport direction of the carrier substrate and positioned relative to the web so that the generated UV radiation strikes the coated side of the carrier substrate and initiates a crosslinking reaction on the surface of the UV varnish there.
  • the actual excimer radiator ie the lamp which generates the excimer radiation, is thereby positioned within a circumferential template which rotates around the radiator.
  • the length of the lamp is sized to be wider than the support substrate to ensure homogeneous radiation performance across the entire width.
  • the stencil has UV-transmissive and UV-impermeable areas corresponding to the desired structures to appear frosted.
  • such a template may be designed like a rotary screen printing stencil, ie consist of a cylindrical net-like or fabric-like framework that is partially sealed with a UV-impermeable layer, for example a plastic layer, and thus is no longer transparent at these sealed locations. At locations where the mesh or fabric is not coated, the template is at least partially transparent.
  • the permeability of the template is the diameter of the mesh or fabric fibers and the mesh size of the network or tissue and can also be influenced by suitable selection of the materials.
  • the production of such a template is carried out in the same process that is used for the production of rotary printing screens.
  • the structures that can be created with it are identical to those that can also be generated by rotary screen printing.
  • the net or fabric-like framework can also consist of metal.
  • the template is formed from a metal cylinder having open recesses in which the excimer radiation can pass through the template completely unhindered.
  • the recesses can thereby be mechanically, i. be introduced by a drilling or milling process or by laser cutting in the cylinder.
  • the template is made of a material such as quartz, MgF 2 , or the like that is transparent to the wavelength of the excimer radiation.
  • a cylinder is made of this material and areas are masked on its surface so that excimer radiation no longer penetrates these areas.
  • the surface of the cylinder with a metal layer, which consists for example of chromium or aluminum and is thick enough to prevent the excimer radiation, coated.
  • the coating can be applied by a vacuum coating method or by electroplating.
  • the structuring takes place, for example, with a photolithographic process or with the aid of a laser by ablation.
  • an absorber layer is applied only partially to the areas to be masked, for example by printing or by means of adhesively bonded, impermeable to the excimer radiation, covers. Also at In this embodiment, any structures can be produced, since the cylinder itself constitutes a continuous supporting structure.
  • the template is driven by a motor directly or by means of a toothed or V-belt or gear.
  • the rotational speed of the template is adjusted so that the tangential velocity of the cylinder in the plane of the masking layer is identical to the transport speed of the substrate. This ensures that no relative movement between the template and the carrier substrate is formed and the structures of the template are sharp-edged imaged on the surface of the paint.
  • the distance between the stencil and the lacquer surface is chosen as small as possible, but a small gap must remain, since otherwise the danger of adhesion of the lacquer to the stencil exists.
  • the distance is approximately in the range of 0.1 to 10 mm. A change in this distance would inevitably lead to fluctuations in the edge sharpness, which is why, in a preferred embodiment, a film in the region of the template is guided over a counter roller, whose distance from the template can be precisely controlled. The film is thereby stabilized such that the distance to the radiator can be kept constant within a small tolerance.
  • the template itself consists of an endless, web-shaped fabric tape which, like one of the templates described above, consists of a reticulated or web-shaped substrate, which is partially coated with an excimer-impermeable material.
  • the endless belt is guided over several guide rollers around the excimer radiator, wherein the web speed is selected to be identical to the transport speed of the carrier substrate.
  • a net or tissue-shaped substrate and a metal foil can be used with openings.
  • a micro-rough surface forms locally at the exposed areas.
  • this surface structure produces a matt optical impression because the surface diffuses light diffusely.
  • the micro-cladding and the resulting surface relief create a haptic that differs significantly from a smooth varnish surface.
  • the paint surface is not modified, ie the surface is in the same state as after the application of the paint.
  • the paint is applied so that the surface has a very high smoothness and thus a very high gloss.
  • the contrast between the frosted and glossy areas is then particularly high.
  • the wavelength of the excimer radiation is in the range of 110-300 nm, but mostly at 172 nm. Due to the low penetration depth of the excimer radiation in the lacquer layer, this is cured only on the surface, ie in the first about 10 nm to 1 micron.
  • the remaining lacquer layer under the hardened surface still remains in a liquid or viscous state.
  • the entire unit consisting of excimer lamp and template and possibly a guide roller for adjusting the distance is located in an enclosure within which a controlled, inert atmosphere, for example, by continuous purging with argon, nitrogen or other noble gas, can be adjusted.
  • the inerting is imperative in order on the one hand to avoid absorption of the excimer radiation by components of the ambient air (CO 2 , water vapor) and, on the other hand, to prevent the oxygen inhibition of the crosslinking reaction at the paint surface.
  • the oxygen-inhibition causes the radicals or chain parts of the UV varnish to be terminated by incorporation of oxygen and thus can not polymerize further. This effect mainly occurs with thin layers (less than 1 ⁇ m) and is therefore particularly relevant for the surface hardening of paint layers.
  • the partially exposed carrier substrate now passes to a second UV emitter, which, however, operates with radiation of a longer wavelength, typically in the range of 300-500 nm. This ensures that the surface relief produced in the matte areas by the excimer treatment is frozen, so to speak is fixed and the entire coating layer in all areas simultaneously cured or fully crosslinked. If necessary, an enclosure for inerting with noble gases or nitrogen may also be provided around the second UV radiator.
  • UV coating layers with matt and glossy areas are produced in a single operation, wherein the carrier substrate on the entire surface an excellent scratch resistance and a substantially flat surface, so no height difference between smooth and frosted areas has.
  • the substrates produced in this way with a partially matted UV lacquer layer can be used as decorative films or sheets or for decorative surface finishing for furniture surfaces, household appliances, in interior design, the interior of motor vehicles and the like.
  • carrier substrate used, they can be applied to surfaces of different types, for example plastic, wood, composite material or metal substrates, or used as piece goods themselves.
  • the biggest advantage of the method described here is that it runs continuously and does not have to stop the transport of the carrier substrate during the exposure. This enables an efficient, cost-effective and large-volume production of decorative functional parts.
  • FIG. 1 a carrier substrate is shown with a partially frosted UV lacquer layer, which was prepared by a method of the prior art.
  • FIG. 2 a carrier substrate is shown with a partially frosted UV lacquer layer, which was prepared by the process according to the invention.
  • FIGS. 3 to 5 Embodiments of the method according to the invention are shown.
  • 1 denotes the carrier substrate, 2 a glossy UV lacquer layer, 3 a matt UV lacquer layer, 4 a UV lacquer layer according to the invention, 4a a UV lacquer layer according to the invention before curing, 5a matt and 5b glossy areas of the lacquer surface, 6 the Screen printing stencil with regions 6a permeable to the excimer radiation and regions 6b, 7 for the excimer radiation impermeable areas, 8 the excimer radiator, 8 the UV radiator for curing the UV lacquer layer, 9 the enclosures of the excimer or UV radiators, 10 the applicator, 11 the unwinder, 12 the rewinder, 13 pulleys, 14 the drier, 15 the excimer unit with rotating template and housing, 16 the UV dryer unit with housing, 17 the hopper for general cargo, 18 the container for finished piece goods, 19 the piece goods to be coated, 20 a device for applying the UV varnish and 21 the conveyor for transporting the piece goods.
  • FIG. 1 shows the cross section of a coated with a partially frosted UV varnish carrier substrate according to the prior art.
  • the carrier substrate 1 is first coated over its entire surface with a glossy UV lacquer layer 2.
  • a matted UV varnish 3 is partially printed with a printing process. In the areas where the matted UV lacquer is printed, the layer thickness is greater than in the areas where only the glossy UV lacquer is applied.
  • FIG. 2 shows the cross section of a carrier substrate 1 produced by the process according to the invention, which has a UV lacquer layer 4 with frosted areas 5a and shiny areas 5b of the paint surface. Between the frosted and glossy areas, no difference in thickness is visible in the paint layer.
  • FIG. 3 shows schematically the arrangement for carrying out the essential steps of the method according to the invention.
  • the carrier substrate 1 coated with a UV-curable lacquer layer 4 is continuously guided past the excimer radiator 7.
  • the excimer emitter 7 is situated in a template 6 which has regions 6a permeable to the excimer radiation and regions 6b impermeable to the excimer radiation.
  • Excimer radiator and stencil are in turn located in a housing 9, which is placed under inert gas (Ar or N 2 ).
  • the drive unit for the template is in for clarity Fig. 3 Not shown.
  • the radiation of the excimer radiator 7 passes through the regions 6a of the template 6 permeable to the excimer radiation, strikes the surface of the UV lacquer layer and generates a micro-cladding there, whereby a matt surface 5a is formed.
  • no crosslinking of the UV lacquer layer takes place, resulting in a glossy lacquer surface 5b.
  • the carrier substrate is guided to a UV radiator 8 and irradiated so that a continuously crosslinked UV lacquer layer 4 is produced.
  • the UV emitter 8 is optionally located in a housing 9, which may also be under inert gas.
  • FIG. 4 schematically shows the inventive method for the production of web-shaped carrier substrates with a partially frosted UV lacquer layer.
  • the carrier substrate 1 is guided by an unwinding roller 11 via a deflection roller 13 to the Lack Vietnameseswerk 10, then via a further deflection roller 13 through a dryer 14, in which optionally a solvent present in the UV coating solvent is evaporated.
  • the UV-coated carrier substrate by the excimer unit 15 consisting of excimer radiator 7, template 6 and housing 9 (see Fig. 3 ) and so the paint surface partially frosted.
  • the UV lacquer layer is passed through a UV radiator unit 16 consisting of UV radiator 8 and possibly an enclosure 9 (see FIG Fig. 3 ) hardened.
  • the coated carrier substrate is guided over a deflection roller 13 to a winding station 12 and wound up.
  • Fig. 5 schematically shows the inventive method for producing piece goods with a partially frosted UV lacquer layer.
  • the cargo 19 is applied to a conveyor belt 21 and coated by a device 20 with UV varnish.
  • the piece goods 19 is passed through an excimer unit 15 and thus partially matt the paint surface.
  • the UV lacquer layer is completely cured by a UV radiator unit 16.
  • the finished piece goods are stacked in a container 18.
EP11006309.6A 2010-08-13 2011-07-30 Procédé de matification partielle de couches de laque UV Active EP2418019B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SI201131202T SI2418019T1 (sl) 2010-08-13 2011-07-30 Postopek za delno matiranje UV lakirnih slojev
PL11006309T PL2418019T3 (pl) 2010-08-13 2011-07-30 Sposób częściowego matowania warstw lakieru UV

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ATA1356/2010A AT510217B1 (de) 2010-08-13 2010-08-13 Verfahren zur partiellen mattierung von uv-lackschichten

Publications (2)

Publication Number Publication Date
EP2418019A1 true EP2418019A1 (fr) 2012-02-15
EP2418019B1 EP2418019B1 (fr) 2017-03-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP11006309.6A Active EP2418019B1 (fr) 2010-08-13 2011-07-30 Procédé de matification partielle de couches de laque UV

Country Status (5)

Country Link
EP (1) EP2418019B1 (fr)
AT (1) AT510217B1 (fr)
ES (1) ES2627506T3 (fr)
PL (1) PL2418019T3 (fr)
SI (1) SI2418019T1 (fr)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2786807A1 (fr) * 2013-04-05 2014-10-08 IOT - Innovative Oberflächentechnologie GmbH Dispositif d'inertisation en présence d'un rayonnement UV dans des installations de passage ouvertes
EP2857221A1 (fr) * 2013-10-07 2015-04-08 Flooring Technologies Ltd. Panneau doté d'une surface ultra-mate
EP2979894A1 (fr) 2014-08-01 2016-02-03 Hueck Folien Ges.m.b.H Feuille décorative
FR3042426A1 (fr) * 2015-10-19 2017-04-21 Peugeot Citroen Automobiles Sa Procede de peinture a deux teintes d’elements de carrosserie de vehicule automobile
DE102016120878A1 (de) 2015-11-02 2017-05-04 Schmid Rhyner Ag Verfahren zum Erzeugen von Oberflächeneffekten, insbesondere in UV-härtbaren Schichten, Vorrichtung zur Herstellung derselben sowie erfindungsgemäß erhaltener Artikel
EP3266811A1 (fr) 2016-07-07 2018-01-10 Hueck Folien Ges.m.b.H. Feuilles laquees en couleur ayant une stabilite elevee aux uv
EP3415316A1 (fr) * 2017-06-13 2018-12-19 Hymmen GmbH Maschinen- und Anlagenbau Procédé et dispositif de fabrication d'une surface structurée
WO2019004963A3 (fr) * 2017-03-30 2019-02-07 5K Yuzey Teknolojileri Orm. Urn. Mob. San. Ve Tic. A. S. Procédé de fabrication d'une surface laquée mate, de meuble en bois et de panneaux de porte au moyen d'un procédé à excimères
WO2019034675A1 (fr) * 2017-08-16 2019-02-21 Basf Se Procédé de production de revêtements mats sur des substrats plats
WO2020009592A1 (fr) * 2018-07-02 2020-01-09 SCHATTDECOR Sp. z o.o. Procédé de production d'une surface revêtue mate multicouche et produit contenant une surface revêtue multicouche
IT201900002653A1 (it) * 2019-02-25 2020-08-25 Cefla Soc Cooperativa Apparato e metodo per l’essiccazione/polimerizzazione di prodotti chimici
EP3928880A4 (fr) * 2020-02-19 2022-05-18 Zhejiang Kingdom New Material Group Co., Ltd. Procédé de préparation de plaque super mate
WO2022182259A1 (fr) * 2021-02-24 2022-09-01 SCHATTDECOR Sp. z o.o. Procédé de production d'une surface multicouche revêtue et produit contenant une surface multicouche revêtue
US11559824B2 (en) 2019-05-03 2023-01-24 Hymmen Gmbh Maschinen-Und Anlagenbau Method for producing a structure on a surface
DE102022112010A1 (de) 2022-05-13 2023-11-16 REHAU Industries SE & Co. KG Verfahren zur Herstellung eines Profilkörpers
WO2024022758A1 (fr) * 2022-07-25 2024-02-01 REHAU Industries SE & Co. KG Procédé de fabrication d'un corps profilé
US11969753B2 (en) 2017-08-16 2024-04-30 Basf Se Process for producing matt coatings on sheetlike substrates

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019124309A1 (de) * 2019-09-10 2021-03-11 Ist Metz Gmbh Vorrichtung und Verfahren zur Erzeugung mattierungsmodulierter Polymerschichten

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0338221A2 (fr) 1988-04-12 1989-10-25 Alkor Gmbh Kunststoffe Bande de feuille
EP0706834A1 (fr) 1994-10-11 1996-04-17 Alkor Gmbh Kunststoffe Procédé pour revêtir un substrat plat avec une laque réticulable aux U.V.
DE19810455A1 (de) * 1998-03-11 1999-09-23 Michael Bisges Kaltlicht-UV-Bestrahlungsvorrichtung
DE19842510A1 (de) 1998-09-17 2000-03-23 Reisewitz Beschichtungs Gmbh Verfahren zur Strukturierung der Oberfläche strahlenhärtbarer Lacke und Farben mittels kurzwelliger UV-Strahlung
EP1779737A1 (fr) * 2005-10-26 2007-05-02 Cryovac, Inc. Procédé et dispositif pour l'activation contrôlée de compositions desoxigénantes en utilisant une protection enveloppante
WO2007068322A1 (fr) 2005-12-14 2007-06-21 Leibniz-Institut für Oberflächenmodifizierung e.V. Dispositif en vue de la mise en oeuvre d'un procede de modification de la surface de couleurs et de vernis durcissables par rayonnement, par microdissociation photochimique a l'aide d'un rayonnement uv monochromatique de courte longueur d'onde dans des conditions stables d'irradiation et d'inertisation
DE102008024149A1 (de) * 2008-05-19 2009-12-03 Institut für Oberflächenmodifizierung e.V. Vorrichtung zur Ermittlung der Faltungskinetik und der Faltungsgeschwindigkeit strahlenhärtbarer Farben und Lacke während des Prozesses der photochemische Mikrofaltung initiiert durch kurzwellige monochromatische Excimer-UV-Strahlung

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6383690B1 (en) * 1999-12-09 2002-05-07 Autologic Information International, Inc. Platemaking system and method using an imaging mask made from photochromic film
JP5102879B2 (ja) * 2008-01-22 2012-12-19 ローイス インコーポレイテッド 大面積ナノパターン形成方法および装置

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0338221A2 (fr) 1988-04-12 1989-10-25 Alkor Gmbh Kunststoffe Bande de feuille
EP0706834A1 (fr) 1994-10-11 1996-04-17 Alkor Gmbh Kunststoffe Procédé pour revêtir un substrat plat avec une laque réticulable aux U.V.
DE4439350A1 (de) 1994-10-11 1996-04-18 Alkor Gmbh Verfahren zur Herstellung eines mit UV-härtbarem Lack beschichteten flächenförmigen Trägermaterials
DE4439350C2 (de) 1994-10-11 1997-09-11 Alkor Gmbh Verfahren zur Herstellung eines mit UV-härtbarem Lack beschichteten flächenförmigen Trägermaterials
DE19810455A1 (de) * 1998-03-11 1999-09-23 Michael Bisges Kaltlicht-UV-Bestrahlungsvorrichtung
DE19842510A1 (de) 1998-09-17 2000-03-23 Reisewitz Beschichtungs Gmbh Verfahren zur Strukturierung der Oberfläche strahlenhärtbarer Lacke und Farben mittels kurzwelliger UV-Strahlung
EP1779737A1 (fr) * 2005-10-26 2007-05-02 Cryovac, Inc. Procédé et dispositif pour l'activation contrôlée de compositions desoxigénantes en utilisant une protection enveloppante
WO2007068322A1 (fr) 2005-12-14 2007-06-21 Leibniz-Institut für Oberflächenmodifizierung e.V. Dispositif en vue de la mise en oeuvre d'un procede de modification de la surface de couleurs et de vernis durcissables par rayonnement, par microdissociation photochimique a l'aide d'un rayonnement uv monochromatique de courte longueur d'onde dans des conditions stables d'irradiation et d'inertisation
DE102008024149A1 (de) * 2008-05-19 2009-12-03 Institut für Oberflächenmodifizierung e.V. Vorrichtung zur Ermittlung der Faltungskinetik und der Faltungsgeschwindigkeit strahlenhärtbarer Farben und Lacke während des Prozesses der photochemische Mikrofaltung initiiert durch kurzwellige monochromatische Excimer-UV-Strahlung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SCHUBERT R ET AL: "VUV-induced micro-folding of acrylate-based coatings", SURFACE AND COATINGS TECHNOLOGY, ELSEVIER, AMSTERDAM, NL, vol. 203, no. 13, 25 March 2009 (2009-03-25), pages 1844 - 1849, XP025993968, ISSN: 0257-8972, [retrieved on 20090115], DOI: 10.1016/J.SURFCOAT.2009.01.007 *

Cited By (36)

* Cited by examiner, † Cited by third party
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EP2786807A1 (fr) * 2013-04-05 2014-10-08 IOT - Innovative Oberflächentechnologie GmbH Dispositif d'inertisation en présence d'un rayonnement UV dans des installations de passage ouvertes
EP2857221A1 (fr) * 2013-10-07 2015-04-08 Flooring Technologies Ltd. Panneau doté d'une surface ultra-mate
EP2979894A1 (fr) 2014-08-01 2016-02-03 Hueck Folien Ges.m.b.H Feuille décorative
FR3042426A1 (fr) * 2015-10-19 2017-04-21 Peugeot Citroen Automobiles Sa Procede de peinture a deux teintes d’elements de carrosserie de vehicule automobile
DE102016120878A1 (de) 2015-11-02 2017-05-04 Schmid Rhyner Ag Verfahren zum Erzeugen von Oberflächeneffekten, insbesondere in UV-härtbaren Schichten, Vorrichtung zur Herstellung derselben sowie erfindungsgemäß erhaltener Artikel
WO2017076901A2 (fr) 2015-11-02 2017-05-11 Schmid Rhyner Ag Procédé pour générer des effets de surface, en particulier dans des couches durcissables par uv, dispositif pour réaliser ces effets et article ainsi obtenu
WO2017076901A3 (fr) * 2015-11-02 2017-07-13 Schmid Rhyner Ag Procédé pour générer des effets de surface, en particulier dans des couches durcissables par uv, dispositif pour réaliser ces effets et article ainsi obtenu
CN108348955A (zh) * 2015-11-02 2018-07-31 施密德吕纳股份公司 用于尤其在可uv固化层中产生表面效果的方法、用于其制造的装置以及根据本发明获得的物品
EP3266811A1 (fr) 2016-07-07 2018-01-10 Hueck Folien Ges.m.b.H. Feuilles laquees en couleur ayant une stabilite elevee aux uv
WO2019004963A3 (fr) * 2017-03-30 2019-02-07 5K Yuzey Teknolojileri Orm. Urn. Mob. San. Ve Tic. A. S. Procédé de fabrication d'une surface laquée mate, de meuble en bois et de panneaux de porte au moyen d'un procédé à excimères
CN113212020A (zh) * 2017-06-13 2021-08-06 海曼机械和设备有限公司 用于制作结构化表面的方法
US11883843B2 (en) 2017-06-13 2024-01-30 Hymmen Gmbh Maschinen-Und Anlagenbau Method for producing a structured surface
US11717850B2 (en) 2017-06-13 2023-08-08 Hymmen Gmbh Maschinen-Und Anlagenbau Method and apparatus for producing a decorative workpiece and workpiece
CN110290925A (zh) * 2017-06-13 2019-09-27 海曼机械和设备有限公司 用于制作结构化表面的方法
US11511318B2 (en) 2017-06-13 2022-11-29 Hymmen GmbH Maschinen- und Anlagenbau Method and apparatus for producing a decorative workpiece and workpiece
EP3415316B1 (fr) 2017-06-13 2020-04-08 Hymmen GmbH Maschinen- und Anlagenbau Procédé et dispositif de fabrication d'une surface structurée
EP3666525A1 (fr) * 2017-06-13 2020-06-17 Hymmen GmbH Maschinen- und Anlagenbau Procédé et dispositif de fabrication d'une surface structurée
CN113212020B (zh) * 2017-06-13 2023-08-08 海曼机械和设备有限公司 用于制作结构化表面的方法
EP3415316A1 (fr) * 2017-06-13 2018-12-19 Hymmen GmbH Maschinen- und Anlagenbau Procédé et dispositif de fabrication d'une surface structurée
US11420229B2 (en) 2017-06-13 2022-08-23 Hymmen GmbH Maschinen—und Anlagenbau Method and apparatus for producing a decorative surface
WO2018229170A1 (fr) * 2017-06-13 2018-12-20 Hymmen GmbH Maschinen- und Anlagenbau Procédé de production d'une surface structurée
US11717851B2 (en) 2017-06-13 2023-08-08 Hymmen GmbH Maschinen—und Anlagenbau Method and apparatus for producing a decorative workpiece and workpiece
US11141759B2 (en) 2017-06-13 2021-10-12 Hymmen GmbH Maschinen- und Anlagesbas Method and apparatus for producing a decorative surface
US11969753B2 (en) 2017-08-16 2024-04-30 Basf Se Process for producing matt coatings on sheetlike substrates
WO2019034675A1 (fr) * 2017-08-16 2019-02-21 Basf Se Procédé de production de revêtements mats sur des substrats plats
CN112437699A (zh) * 2018-07-02 2021-03-02 夏特德科尔公司 用于制备多层哑光涂覆表面的方法和包含多层涂覆表面的产品
KR20210014158A (ko) * 2018-07-02 2021-02-08 샤트데코 에스피.제트.오.오. 다층 무광 코팅된 표면의 제조를 위한 공정 및 다층 코팅된 표면을 포함하는 제품
WO2020009592A1 (fr) * 2018-07-02 2020-01-09 SCHATTDECOR Sp. z o.o. Procédé de production d'une surface revêtue mate multicouche et produit contenant une surface revêtue multicouche
WO2020174352A1 (fr) * 2019-02-25 2020-09-03 Cefla Societa' Cooperativa Appareil et procédé de séchage/durcissement de produits chimiques
US11541419B2 (en) 2019-02-25 2023-01-03 CEFLA Società Cooperativa Apparatus and method for the drying/curing of chemical products
IT201900002653A1 (it) * 2019-02-25 2020-08-25 Cefla Soc Cooperativa Apparato e metodo per l’essiccazione/polimerizzazione di prodotti chimici
US11559824B2 (en) 2019-05-03 2023-01-24 Hymmen Gmbh Maschinen-Und Anlagenbau Method for producing a structure on a surface
EP3928880A4 (fr) * 2020-02-19 2022-05-18 Zhejiang Kingdom New Material Group Co., Ltd. Procédé de préparation de plaque super mate
WO2022182259A1 (fr) * 2021-02-24 2022-09-01 SCHATTDECOR Sp. z o.o. Procédé de production d'une surface multicouche revêtue et produit contenant une surface multicouche revêtue
DE102022112010A1 (de) 2022-05-13 2023-11-16 REHAU Industries SE & Co. KG Verfahren zur Herstellung eines Profilkörpers
WO2024022758A1 (fr) * 2022-07-25 2024-02-01 REHAU Industries SE & Co. KG Procédé de fabrication d'un corps profilé

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ES2627506T3 (es) 2017-07-28
EP2418019B1 (fr) 2017-03-08

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