EP2414498A1 - Reinigungsmittel - Google Patents
ReinigungsmittelInfo
- Publication number
- EP2414498A1 EP2414498A1 EP10712421A EP10712421A EP2414498A1 EP 2414498 A1 EP2414498 A1 EP 2414498A1 EP 10712421 A EP10712421 A EP 10712421A EP 10712421 A EP10712421 A EP 10712421A EP 2414498 A1 EP2414498 A1 EP 2414498A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent
- washing
- cleaning agent
- cleaning
- cartridge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 166
- 238000005406 washing Methods 0.000 claims abstract description 195
- 239000003599 detergent Substances 0.000 claims abstract description 188
- 238000002360 preparation method Methods 0.000 claims abstract description 187
- 239000007788 liquid Substances 0.000 claims abstract description 59
- 238000004140 cleaning Methods 0.000 claims abstract description 54
- 102000004190 Enzymes Human genes 0.000 claims abstract description 52
- 108090000790 Enzymes Proteins 0.000 claims abstract description 52
- 229940071118 cumenesulfonate Drugs 0.000 claims abstract description 8
- 239000004753 textile Substances 0.000 claims description 78
- 238000004851 dishwashing Methods 0.000 claims description 61
- 239000000203 mixture Substances 0.000 claims description 57
- 229940088598 enzyme Drugs 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 47
- 230000008569 process Effects 0.000 claims description 34
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 19
- 239000002736 nonionic surfactant Substances 0.000 claims description 19
- 108091005804 Peptidases Proteins 0.000 claims description 17
- 239000004365 Protease Substances 0.000 claims description 17
- 102000035195 Peptidases Human genes 0.000 claims description 16
- 108010065511 Amylases Proteins 0.000 claims description 14
- 102000013142 Amylases Human genes 0.000 claims description 14
- 235000019418 amylase Nutrition 0.000 claims description 14
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 claims description 10
- 230000006641 stabilisation Effects 0.000 claims description 10
- 238000011105 stabilization Methods 0.000 claims description 10
- 229940025131 amylases Drugs 0.000 claims description 9
- 229960004063 propylene glycol Drugs 0.000 claims description 9
- 229940079919 digestives enzyme preparation Drugs 0.000 claims description 8
- 239000002552 dosage form Substances 0.000 claims description 8
- 238000009472 formulation Methods 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000004382 Amylase Substances 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 238000010412 laundry washing Methods 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 1
- -1 glycol ethers Chemical class 0.000 description 33
- 239000000178 monomer Substances 0.000 description 29
- 125000004432 carbon atom Chemical group C* 0.000 description 24
- 239000002253 acid Substances 0.000 description 20
- 238000003860 storage Methods 0.000 description 18
- 229920001577 copolymer Polymers 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- 150000007513 acids Chemical class 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 229920006395 saturated elastomer Polymers 0.000 description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
- 239000000470 constituent Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000003205 fragrance Substances 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 238000004806 packaging method and process Methods 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Natural products CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- 150000001735 carboxylic acids Chemical class 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 239000003112 inhibitor Substances 0.000 description 7
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 7
- 239000011976 maleic acid Substances 0.000 description 7
- 150000003751 zinc Chemical class 0.000 description 7
- XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- 108090001060 Lipase Proteins 0.000 description 5
- 102000004882 Lipase Human genes 0.000 description 5
- 239000004367 Lipase Substances 0.000 description 5
- 108090000637 alpha-Amylases Proteins 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 150000002191 fatty alcohols Chemical class 0.000 description 5
- 235000019421 lipase Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 235000019419 proteases Nutrition 0.000 description 5
- VXWBQOJISHAKKM-UHFFFAOYSA-N (4-formylphenyl)boronic acid Chemical compound OB(O)C1=CC=C(C=O)C=C1 VXWBQOJISHAKKM-UHFFFAOYSA-N 0.000 description 4
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 108090000854 Oxidoreductases Proteins 0.000 description 4
- 102000004316 Oxidoreductases Human genes 0.000 description 4
- 108010056079 Subtilisins Proteins 0.000 description 4
- 102000005158 Subtilisins Human genes 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- 102000004139 alpha-Amylases Human genes 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 125000000542 sulfonic acid group Chemical group 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 108010005400 cutinase Proteins 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- CTMHWPIWNRWQEG-UHFFFAOYSA-N 1-methylcyclohexene Chemical compound CC1=CCCCC1 CTMHWPIWNRWQEG-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical group CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 108010025880 Cyclomaltodextrin glucanotransferase Proteins 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical class OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Natural products OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 101710135785 Subtilisin-like protease Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 241000223258 Thermomyces lanuginosus Species 0.000 description 2
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 description 2
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 108010002430 hemicellulase Proteins 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- 229940065472 octyl acrylate Drugs 0.000 description 2
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 2
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- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
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- 229910052709 silver Inorganic materials 0.000 description 2
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- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
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- 239000003381 stabilizer Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
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- 235000013904 zinc acetate Nutrition 0.000 description 2
- 239000011670 zinc gluconate Substances 0.000 description 2
- 235000011478 zinc gluconate Nutrition 0.000 description 2
- 229960000306 zinc gluconate Drugs 0.000 description 2
- 239000011576 zinc lactate Substances 0.000 description 2
- 235000000193 zinc lactate Nutrition 0.000 description 2
- 229940050168 zinc lactate Drugs 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- VQJMAIZOEPPELO-KYGIZGOZSA-N (1S,2S,6R,14R,15R,16R)-5-(cyclopropylmethyl)-16-(2-hydroxy-5-methylhexan-2-yl)-15-methoxy-13-oxa-5-azahexacyclo[13.2.2.12,8.01,6.02,14.012,20]icosa-8(20),9,11-trien-11-ol hydrochloride Chemical compound Cl.CO[C@]12CC[C@@]3(C[C@@H]1C(C)(O)CCC(C)C)[C@H]1Cc4ccc(O)c5O[C@@H]2[C@]3(CCN1CC1CC1)c45 VQJMAIZOEPPELO-KYGIZGOZSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- NPMRPDRLIHYOBW-UHFFFAOYSA-N 1-(2-butoxyethoxy)propan-2-ol Chemical compound CCCCOCCOCC(C)O NPMRPDRLIHYOBW-UHFFFAOYSA-N 0.000 description 1
- IAUGBVWVWDTCJV-UHFFFAOYSA-N 1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CCC(S(O)(=O)=O)NC(=O)C=C IAUGBVWVWDTCJV-UHFFFAOYSA-N 0.000 description 1
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- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000008297 liquid dosage form Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- AWGZKFQMWZYCHF-UHFFFAOYSA-N n-octylprop-2-enamide Chemical compound CCCCCCCCNC(=O)C=C AWGZKFQMWZYCHF-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910021527 natrosilite Inorganic materials 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 108020004410 pectinesterase Proteins 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical class OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000007909 solid dosage form Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 108010031354 thermitase Proteins 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 108010068608 xanthan lyase Proteins 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 108010083879 xyloglucan endo(1-4)-beta-D-glucanase Proteins 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
- 229940100530 zinc ricinoleate Drugs 0.000 description 1
- MXODCLTZTIFYDV-JHZYRPMRSA-L zinc;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Zn+2].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O.C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O MXODCLTZTIFYDV-JHZYRPMRSA-L 0.000 description 1
- ZPEJZWGMHAKWNL-UHFFFAOYSA-L zinc;oxalate Chemical compound [Zn+2].[O-]C(=O)C([O-])=O ZPEJZWGMHAKWNL-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
Definitions
- the present application describes detergents and cleaners, in particular enzyme-containing detergents and cleaners.
- these temperatures used in a first approximation to those used to carry out the washing or cleaning process Same water temperatures. These temperatures can be up to 95 0 C, wherein in the range of machine dishwashing usually only temperatures between 50 and 75 0 C are reached. Accordingly, a washing or cleaning agent contained in a device provided for multiple dosing is repeatedly heated in the course of several washing or cleaning processes to temperatures well above the temperatures customary for transport and storage, temperature-sensitive ones in particular Active substances can be affected. The group of these temperature-sensitive washing and cleaning-active substances primarily include the washing and cleaning-active enzymes.
- hydrolytic enzymes such as proteases, amylases or lipases are part of numerous textile or dishwashing detergents because of their direct cleaning action.
- proteases in particular serine proteases, to which the subtilases according to the invention are also calculated, are used for degrading proteinaceous soils on the items to be cleaned.
- subtilases occupy an outstanding position due to their favorable enzymatic properties such as stability or pH optimum.
- the ⁇ -amylases are in particular widespread from the enzyme class of the amylases, ⁇ -amylases (E.C. 3.2.1.1) hydrolyze internal ⁇ -1, 4-glycosidic bonds of starch and starch-like polymers.
- Detergents and cleaning enzymes are formulated in both solid and liquid form.
- the group of solid enzyme preparations includes, in particular, the enzyme granules consisting of several ingredients, which in turn are preferably incorporated into solid detergents and cleaners.
- liquid or gel detergents and cleaners often contain liquid enzyme preparations, which, unlike the enzyme granules, are much less protected against external influences.
- German patent application DE 2 038 103 (Henkel) teaches the stabilization of enzyme-containing dishwashing detergents by saccharides, while in European patent EP 646 170 B1 (Procter & Gamble) propylene glycol is disclosed for enzyme stabilization in liquid detergents.
- the object of the present application was accordingly in the stabilization of a washing- or cleaning-active enzyme preparation against phase separation / loss of activity at multiple temperature fluctuations, in particular in a temperature range of 10 to 75 0 C.
- Corresponding enzyme preparations should significant in a located in the interior of the dishwasher or washing machine storage device without Loss of activity storable.
- liquid enzyme preparations can be stabilized by the addition of a specific hydrotrope.
- a first subject of this application is therefore a liquid washing or cleaning composition A, comprising a) at least 5 wt .-% of at least one washing or cleaning active enzyme preparation; b) at least 0.5% by weight of cumene sulfonate
- liquid detergent or cleaning agent preparations are preferably water-containing.
- Particularly preferred detergent or cleaner compositions A are characterized in that the weight fraction of the water, based in each case on the total weight of the detergent or cleaning agent preparations, is between 2 and 20% by weight, preferably between 4 and 18% by weight and in particular between 5 and 10% 15 wt .-% is.
- the washing or cleaning agent preparations according to the invention contain as their first essential constituent at least one washing or cleaning-active enzyme.
- the proportion by weight of the washing or cleaning-active enzyme in the total weight of the washing or cleaning agent preparation is preferably between 5 and 80% by weight, preferably between 5 and 60% by weight, particularly preferably between 10 and 50% by weight and in particular between 10 and 30% by weight.
- the enzymes used with particular preference include in particular proteases, amylases, lipases, hemicellulases, cellulases, perhydrolases or oxidoreductases, and preferably mixtures thereof. These enzymes are basically of natural origin; outgoing Of the natural molecules, improved variants are available for use in detergents or cleaning agents, which are preferably used accordingly.
- Detergents or cleaning agents contain enzymes preferably in total amounts of 1 ⁇ 10 -6 to 5 wt .-% based on active protein.
- the protein concentration can be determined by known methods, for example the BCA method or the biuret method.
- liquid washing or cleaning agent preparations A according to the invention characterized in that they contain a washing- or cleaning-active enzyme from the group of amylases and / or proteases, are preferred.
- subtilisin type those of the subtilisin type are preferable.
- these are the subtilisins BPN 'and Carlsberg and their further developed forms, the protease PB92, the subtilisins 147 and 309, the alkaline protease from Bacillus lentus, subtilisin DY and the enzymes thermitase which can no longer be assigned to the subtilisins in the narrower sense, Proteinase K and the proteases TW3 and TW7.
- preferred liquid detergent or cleaning compositions A contain, based on the total weight of the detergent or cleaning agent preparation A, 5 to 50% by weight, preferably 7 to 40 wt .-% and in particular 10 to 30 wt .-% protease preparations. Particular preference is given to washing or cleaning agent preparations A which, based on their total weight, contain 15 to 25% by weight of protease preparations.
- amylases which can be used according to the invention are the ⁇ -amylases from Bacillus licheniformis, from ⁇ . amyloliquefaciens, from ⁇ . stearothermophilus, from Aspergillus niger and A. oryzae, as well as improved for use in detergents and cleaners further developments of the aforementioned amylases. Furthermore, for this purpose, the ⁇ -amylase from Bacillus sp. A 7-7 (DSM 12368) and cyclodextrin glucanotransferase (CGTase) from ⁇ . agaradherens (DSM 9948).
- preferred liquid detergent or cleaning compositions A contain, based on the total weight of the detergent or cleaning agent preparation A, 0.1 to 30% by weight, preferably 1, 0 to 25 wt .-% and in particular 2.0 to 20 wt. -% amylase preparations. Particular preference is given to washing or cleaning agent preparations A which, based on their total weight, contain 4.0 to 16% by weight of amylase preparations. Washing or cleaning-active proteases and amylases are generally not provided in the form of the pure protein but rather in the form of stabilized, storable and transportable preparations.
- Such prefabricated preparations include, for example, the solid preparations obtained by granulation, extrusion or lyophilization or, especially in the case of liquid or gel-form detergents, solutions of the enzymes, advantageously as concentrated as possible, low in water and / or added with stabilizers or further auxiliaries.
- the enzymes may be encapsulated for both the solid and liquid dosage forms, for example by spray-drying or extruding the enzyme solution together with a preferably natural polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in those of the core-shell type, in which an enzyme-containing core is coated with a water, air and / or chemical impermeable protective layer.
- further active ingredients for example stabilizers, emulsifiers, pigments, bleaches or dyes, may additionally be applied.
- Such capsules are applied by methods known per se, for example by shaking or rolling granulation or in fluid-bed processes.
- such granules for example by applying polymeric film-forming agent, low in dust and storage stable due to the coating.
- the enzyme protein forms only a fraction of the total weight of conventional enzyme preparations.
- Protease and amylase preparations preferably used according to the invention contain between 0.1 and 40% by weight, preferably between 0.2 and 30% by weight, particularly preferably between 0.4 and 20% by weight and in particular between 0, 8 and 10 wt .-% of the enzyme protein.
- lipases or cutinases are also usable according to the invention.
- these include, for example, the lipases originally obtainable from Humicola lanuginosa (Thermomyces lanuginosus) or further developed, in particular those with the amino acid exchange D96L.
- the cutinases can be used, which were originally isolated from Fusarium solani pisi and Humicola insolens. It is also possible to use lipases, or cutinases, whose initial enzymes were originally isolated from Pseudomonas mendocina and Fusarium solanii.
- Oxidoreductases for example oxidases, oxygenases, catalases, peroxidases, such as halo, chloro, bromo, lignin, glucose or manganese peroxidases, dioxygenases or laccases (phenol oxidases, polyphenol oxidases) can be used according to the invention to increase the bleaching effect.
- enzymes and / or enzyme preparations preferably liquid protease preparations and / or amylase preparations are used.
- a second essential constituent of the washing or cleaning agent preparations according to the invention is the cumene sulphonate.
- para-isopropylbenzenesulfonate is the preferred compound.
- the cumene sulfonate has been found to be superior not only to solvents such as glycerol, triacetin or diethylene glycol but also to hydrotropes such as xylenesulfonate in terms of its stabilizing properties.
- solvents such as glycerol, triacetin or diethylene glycol
- hydrotropes such as xylenesulfonate
- sufficient stabilization of the enzyme-containing detergent or cleaner preparation A could not be realized by means of any other substance.
- washing or cleaning agent preparations A are characterized in that these washing or cleaning agent preparations contain the cumene sulphonate in amounts of from 0.5 to 60% by weight, preferably in amounts of from 1.0 to 50% by weight, preferably in amounts between 2.0 and 40 wt .-% and in particular in amounts of between 5.0 and 30% by weight, each based on the total weight of the detergent or cleaning agent formulations.
- Particular preference is given to proportions by weight of the cumene sulfonate in the total weight of the detergent or cleaner preparation A between 2.0 and 20% by weight, preferably between 3.0 and 18% by weight and in particular between 4.0 and 15% by weight.
- organic solvent is from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers.
- the solvents are preferably selected from ethanol, n- or i-propanol, butanol, glycol, propane- or butanediol, glycerol, diglycol, propyl- or butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, etheylene glycol mono-n-butyl ether, diethylene glycol methyl ether, di ethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, dipropylene glycol methyl or ethyl ether, methoxy, ethoxy or butoxy triglycol, 1-butoxyeth
- a particularly preferred organic solvent which is particularly effective in stabilizing the detergent or cleaner preparation is 1,2-propylene glycol.
- the proportion by weight of 1,2-propylene glycol in the total weight of the washing or cleaning agent preparations A according to the invention can vary within wide limits, but those preparations which have an organic solvent, preferably 1, 2-propylene glycol, have proven to be particularly stable, the proportion by weight of 1, 2-propylene glycol, in each case based on the total weight of the detergent or cleaning agent preparations, preferably 5 to 80 wt .-%, preferably 10 to 60 wt .-% and in particular 20 to 50 wt .-% is.
- Detergent preparations is the boric acid or the boric acid derivative c).
- the boronic acids or their salts or esters are preferably used in particular, including, in particular, derivatives with aromatic groups, for example ortho, meta or para-substituted phenylboronic acids, in particular 4-formylphenylboronic acid (4-FPBA), or Salts or esters of the compounds mentioned.
- the proportion by weight of boric acid or of boric acid derivatives in the total weight of washing or cleaning agent preparations according to the invention is preferably between 0.001 to 10% by weight, preferably 0.002 to 6% by weight and in particular 0.05 to 3% by weight.
- a particularly preferred boric acid derivative which is particularly effective with respect to the stabilization of the washing or cleaning agent preparation is 4-formylphenylboronic acid.
- the proportion by weight of 4-formylphenylboronic acid in the total weight of the washing or cleaning agent preparations A according to the invention can vary within wide limits, but such preparations have proved to be particularly stable, which, based on the total weight of the detergent or cleaning agent preparation A, 0.001 to 10 wt .-%, preferably 0.002 to 6 wt .-% and in particular 0.05 to 3 wt .-%. Corresponding preparations are therefore preferred according to the invention.
- a third preferred constituent of the washing or cleaning agent preparations according to the invention is a Ca or Mg ion source d).
- the proportion by weight of the Ca or Mg ion source in the total weight of washing or cleaning agent preparations according to the invention is preferably between 0.01 to 10% by weight, preferably 0.2 to 8% by weight and in particular 0.5 to 5% by weight.
- the organic calcium salts have been found.
- the proportion by weight of the organic calcium salts in the total weight of the washing or cleaning agent preparations A according to the invention can vary within wide limits, however, such preparations have proven to be particularly stable, which, based on the total weight of the detergent or cleaning agent preparation, 0.01 to 10 wt. %, preferably 0.2 to 8 wt .-% and in particular 0.5 to 5 wt .-%.
- Corresponding preparations are therefore preferred according to the invention.
- An especially preferred organic calcium salt is the calcium lactate.
- preferred washing or cleaning agent preparations A may also contain polyols, in particular sorbitol.
- Polyols, in particular sorbitol are hereby preferably used in amounts of from 1 to 20% by weight, in particular from 2 to 15% by weight, especially from 2 to 10% by weight.
- composition of some exemplary detergent or cleaning agent preparations A according to the invention can be found in the following tables:
- Preferred detergent or cleaning agent preparations A according to the invention are characterized in that they contain as further ingredient a substance from the group of trihydric or polyhydric alcohols, preferably in amounts of from 0.1 to 20% by weight, more preferably from 0.5 to 15 wt .-% and in particular from 1, 0 to 10 wt .-%.
- a further preferred constituent of the washing or cleaning agent preparations A according to the invention are, after all, the nonionic surfactants, where nonionic surfactants of the general formula R 1 -CH (OH) CH 2 ⁇ - (AO) w - (AO) x - (A "O) y - (A '"O) z -R 2 , in the
- R 1 is a linear or branched, saturated or mono- or polyunsaturated C 6 - 24 represents alkyl or alkenyl;
- R 2 is a linear or branched hydrocarbon radical having 2 to 26
- A, A ', A "and A'” independently represent a group from the group
- CH (CH 2 -CH 3 ), w, x, y and z are values between 0.5 and 120, where x, y and / or z can also be 0 are preferred.
- the weight fraction of these nonionic surfactants in preferred liquid detergent formulations A is from 0.5 to 30% by weight, preferably from 2.0 to 25% by weight and in particular 5.0 to 20% by weight.
- nonionic surfactants of the general formula R 1 -CH (OH) CH 2 ⁇ - (AO) w - (A'O) x - (A "O) y - (A '" O) z -R 2 , also referred to below as "hydroxy mixed ethers"
- inventive enzyme-containing preparations can be significantly improved both in comparison to surfactant-free systems and compared to systems containing alternative nonionic surfactants, for example from the group of polyalkoxylated fatty alcohols contain.
- nonionic surfactants having one or more free hydroxyl groups on one or both terminal alkyl radicals, the stability of the enzymes contained in the detergent or cleaning agent preparations according to the invention can be markedly improved.
- end-capped poly (oxyalkylated) nonionic surfactants which, in accordance with the formula R 1 O [CH 2 CH 2 O] x CH 2 CH (OH) R 2 , in addition to a radical R 1 , which is linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having from 2 to 30 carbon atoms, preferably having from 4 to 22 carbon atoms, furthermore having a linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radical R 2 having from 1 to 30 carbon atoms, where x is from 1 to 30 carbon atoms 90, preferably for values between 30 and 80 and in particular for values between 30 and 60.
- surfactants of the formula R 1 O [CH 2 CH (CH 3 ) O] x [CH 2 CH 2 O] y CH 2 CH (OH) R 2 in which R 1 denotes a linear or branched aliphatic hydrocarbon radical 4 to 18 carbon atoms or mixtures thereof, R 2 denotes a linear or branched hydrocarbon radical having 2 to 26 carbon atoms or mixtures thereof and x stands for values between 0.5 and 1, 5 and y for a value of at least 15.
- the group of these nonionic surfactants include, for example, the C 2 .
- nonionic surfactants are the end-capped poly (oxyalkylated) nonionic surfactants of the formula R 1 O [CH 2 CH (R 3 ) O] x [CH 2 ] k CH (OH) [CH 2 ] J OR 2 , in which R 1 and R 2 are linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 1 to 30 carbon atoms, R 3 is H or a methyl, ethyl, n-propyl, iso-propyl, n-butyl, 2 Butyl or 2-methyl-2-butyl radical, x are values between 1 and 30, k and j are values between 1 and 12, preferably between 1 and 5.
- each R 3 may be different in the above formula R 1 O [CH 2 CH (R 3 P] x [CH 2 J k CH (OH) [CH 2] PR.
- R 1 R 2 and R 2 are preferably linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 6 to 22 carbon atoms, with radicals having 8 to 18 carbon atoms being particularly preferred, for the radical R 3 are H, -CH 3 or -CH 2 CH 3 are particularly preferred.
- particularly preferred values for x are in the range of 1 to 20, in particular 6 to 15
- each R 3 in the above formula may be different if x> 2.
- the alkylene oxide unit in the square bracket can be varied.
- the value 3 for x has been selected here by way of example and may well be greater, the range of variation increasing with increasing x values and including, for example, a large number (EO) groups combined with a small number (PO) groups, or vice versa ,
- R 1 , R 2 and R 3 are as defined above and x is from 1 to 30, preferably from 1 to 20 and in particular from 6 to 18.
- Particularly preferred are surfactants in which the radicals R 1 and R 2 has 9 to 14 C atoms, R 3 is H and x assumes values of 6 to 15.
- nonionic surfactants of the general formula R 1 -CH (OH) CH 2 O- (AO) W -R 2 have proved to be particularly effective, in which
- R 1 is a straight-chain or branched, saturated or mono- or polyunsaturated C 6 . 24 alkyl or alkenyl radical; R 2 is a linear or branched hydrocarbon radical having 2 to 26
- A is a radical from the group CH 2 CH 2 , -CH 2 CH 2 -CH 2 , -CH 2 -CH (CH 3 ), and w is from 1 to 120, preferably from 10 to 80, in particular from 20 to
- nonionic surfactants include, for example, the C 4 . 22 fatty alcohol (EO) i 0 - 8 o-2-hydroxyalkyl ethers, in particular the C 8 - I2 fatty alcohol (EO) 22 -2-hydroxydecyl ethers and the C 4 . 22 fatty alcohol (EO) 40 - 8 O-2-hydroxyalkyl ether
- detergent or cleaner compositions A according to the invention may contain further ingredients, for example active ingredients from the group of builders, bleaches, detergents and cleaners, corrosion inhibitors, containing fragrances or dyes.
- active ingredients from the group of builders, bleaches, detergents and cleaners, corrosion inhibitors, containing fragrances or dyes.
- preferred washing or washing compositions according to the invention contain
- washing or cleaning agent preparations A which contain less than 20% by weight, preferably less than 10% by weight and in particular less than 5% by weight of builders. Particularly preferred are those washing or cleaning agent preparations A which are free of builders.
- washing or cleaning agent preparations A which contain less than 10% by weight, preferably less than 5% by weight and in particular less than 2% by weight, of bleaching agent. Particular preference is given to those washing or cleaning agent preparations A which are free of bleaching agents.
- washing or cleaning agent preparations A according to the invention are characterized by a low formulation complexity. This low level of complexity simplifies the preparation of the detergents and thus reduces the costs involved in providing these detergents.
- preferred cleaners according to the invention are characterized in that, in addition to the essential constituents a), b), c) and d), they have at most three, preferably the highest two, more preferably at most one and in particular no further constituents.
- the proportion by weight of further constituents is preferably less than 10% by weight, preferably less than 5% by weight, more preferably less than 2% by weight and most preferably less than 0.1% by weight.
- a detergent combination comprising a) a liquid detergent or cleaning agent preparation A according to the invention; b) at least one, preferably at least two other washing or cleaning agent preparations other than A is a further subject of the present application.
- the further cleaning agents combined with the cleaning agent according to the invention are preferably detergent and / or builder-containing cleaning agents.
- Preferred liquid preparations are characterized in that they are formulated together with one, preferably two or three further liquid washing or cleaning agent preparations to form a combination product.
- the further one, two or three liquid washing or cleaning agent preparations have a composition differing from the enzyme-containing washing or cleaning agent preparation according to the invention.
- the other one, two or three liquid detergent or cleaning agent preparations are preferably bleach-free and / or phosphate-free.
- the further liquid washing or cleaning agent preparations may contain, in addition to the surfactants and enzymes described, other substances which are active in washing or cleaning, substances from the group of builders, polymers, glass corrosion inhibitors, corrosion inhibitors, fragrances and perfume carriers being preferred. Also usable are bleaching agents and bleach activators. These preferred ingredients will be described in more detail below.
- the builders include in particular the zeolites, silicates, carbonates and organic cobuilders.
- crystalline layered silicates of general formula NaMSi x O 2x + I ⁇ y H 2 O are used, wherein M is sodium or hydrogen, x is a number from 1, 9 to 22, preferably from 1: 9 to 4, wherein particularly preferred Values for x are 2, 3 or 4, and y is a number from 0 to 33, preferably from 0 to 20.
- crystalline layer silicates with the formula NaMSi x O 2x + 1 ⁇ y H 2 O, in which x stands for 2 h.
- x stands for 2 h.
- both .beta.- and ⁇ -sodium Na 2 Si 2 O 5 ⁇ y H 2 O and further in particular Na-SKS-5 ((X-Na 2 Si 2 O 5), Na-SKS-7 (.beta.
- Washing or cleaning composition preferably contain a weight proportion of crystalline layered silicate of the formula NaMSi x O 2x + I ⁇ y H 2 O from 0.1 to 20 wt .-%, preferably from 0.2 to 15 wt .-% and in particular of 0.4 to 10 wt .-%, each based on the total weight of these agents.
- amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which preferably delayed release and have secondary washing properties.
- Further builders are the alkali carriers. Suitable alkali carriers are, for example, alkali metal hydroxides, alkali metal carbonates, alkali metal hydrogencarbonates, alkali metal sesquicarbonates, the alkali silicates mentioned, alkali metal silicates, and mixtures of the abovementioned substances, preference being given to using alkali metal carbonates, in particular sodium carbonate, sodium bicarbonate or sodium sesquicarbonate for the purposes of this invention.
- a builder system comprising a mixture of tripolyphosphate and sodium carbonate.
- a builder system comprising a mixture of tripolyphosphate and sodium carbonate and sodium disilicate.
- the alkali metal hydroxides are preferably only in small amounts, preferably in amounts below 10 wt .-%, preferably below 6 wt .-%, more preferably below 4 wt .-% and in particular below 2 wt .-%, each based on the total weight of the detergent or cleaning agent used.
- agents which, based on their total weight, contain less than 0.5% by weight and in particular no alkali metal hydroxides.
- organic co-builders are polycarboxylates / polycarboxylic acids, polymeric polycarboxylates, aspartic acid, polyacetals, dextrins, further organic cobuilders and phosphonates. These classes of substances are described below.
- Useful organic builders are, for example, the polycarboxylic acids which can be used in the form of the free acid and / or their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function. These are, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such use is not objectionable for ecological reasons, and mixtures of these.
- the free acids also typically have the property of an acidifying component and thus also serve to set a lower and milder pH of detergents or cleaners.
- citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixtures of these can be mentioned here.
- polymeric polycarboxylates for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of from 500 to 70,000 g / mol.
- the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M w of the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.
- Suitable polymers are, in particular, polyacrylates which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility, the short-chain polyacrylates, which have molar masses of from 2000 to 10000 g / mol, and particularly preferably from 3000 to 5000 g / mol, may again be preferred from this group. Also suitable are copolymeric polycarboxylates, in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable. Their relative molecular weight, based on free acids, is generally from 2000 to 70000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular from 30,000 to 40,000 g / mol.
- the polymers may also contain allylsulfonic acids such as allyloxybenzenesulfonic acid and methallylsulfonic acid as a monomer.
- biodegradable polymers of more than two different monomer units for example those which contain as monomers salts of acrylic acid and maleic acid and vinyl alcohol or vinyl alcohol derivatives or as monomers salts of acrylic acid and 2-alkylallylsulfonic acid and sugar derivatives ,
- copolymers are those which have as their monomers acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate.
- Effective polymers as softeners are, for example, the sulfonic acid-containing polymers which are used with particular preference.
- sulfonic acid-containing polymers are copolymers of unsaturated carboxylic acids, sulfonic acid-containing monomers and optionally other ionic or nonionic monomers.
- R 1 to R 3 independently of one another are -H, -CH 3 , a straight-chain or branched saturated alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, NH 2 , -OH or -COOH substituted alkyl or alkenyl radicals or -COOH or -COOR 4 , wherein R 4 is a saturated or unsaturated, straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms.
- Particularly preferred monomers containing sulfonic acid groups are 1-acrylamido-1-propanesulfonic acid, 2-acrylamido-2-propanesulfonic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3 Methacrylamido-2-hydroxypropanesulfonic acid, allylsulfonic acid, methallylsulfonic acid, allyloxybenzenesulfonic acid, methallyloxybenzenesulfonic acid, 2-hydroxy-3- (2-propenyloxy) propanesulfonic acid, 2-methyl-2-propenylsulfonic acid, styrenesulfonic acid, vinylsulfonic acid, 3-sulfopropyl acrylate, 3-sulfopropyl methacrylate , Sulfomethacrylamide, sulfomethylmethacrylamide and water-soluble salts of said acids.
- Particularly suitable other ionic or nonionic monomers are ethylenically unsaturated compounds.
- the content of the polymers used in these other ionic or nonionic monomers is preferably less than 20% by weight, based on the polymer.
- the sulfonic acid groups may be wholly or partially in neutralized form, i. the acidic acid of the sulfonic acid group in some or all sulfonic acid groups can be exchanged for metal ions, preferably alkali metal ions and in particular for sodium ions.
- metal ions preferably alkali metal ions and in particular for sodium ions.
- partially or fully neutralized sulfonic acid-containing copolymers is preferred according to the invention.
- the monomer distribution of the copolymers preferably used according to the invention in the case of copolymers which contain only monomers from groups i) and ii) is preferably in each case from 5 to 95% by weight i) or ii), particularly preferably from 50 to 90% by weight monomer from group i) and from 10 to 50% by weight of monomer from group ii), in each case based on the polymer.
- terpolymers particular preference is given to those containing from 20 to 85% by weight of monomer from group i), from 10 to 60% by weight of monomer from group ii) and from 5 to 30% by weight of monomer from group iii) ,
- the molar mass of the sulfo copolymers preferably used according to the invention can be varied in order to adapt the properties of the polymers to the desired end use.
- Preferred washing or cleaning agents are characterized in that the copolymers have molar masses of 2000 to 200,000 gmol "1 , preferably from 4000 to 25,000 gmol '1 and in particular from 5000 to 15,000 gmol " 1 .
- Enzymes, in particular of the proteases are additionally improved.
- Particularly preferred copolymers d) contain as monomers containing carboxyl groups i) acrylic acid, methacrylic acid, ethacrylic acid, ⁇ -chloroacrylic acid, ⁇ -cyanoacrylic acid, crotonic acid, ⁇ -phenyl-acrylic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, methylenemalonic acid, sorbic acid, cinnamic acid or mixtures thereof.
- monomers containing carboxyl groups i) acrylic acid, methacrylic acid, ethacrylic acid, ⁇ -chloroacrylic acid, ⁇ -cyanoacrylic acid, crotonic acid, ⁇ -phenyl-acrylic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, methylenemalonic acid, sorbic acid, cinnamic acid or mixtures thereof.
- Particularly preferred such monomers are butene, isobutene, pentene, 3-methylbutene, 2-methylbutene, cyclopentene, hexene, hexene-1, 2-methylpentene-1, 3-methylpentene-1, cyclohexene, methylcyclopentene, cycloheptene, methylcyclohexene, 2,4 , 4-trimethylpentene-1, 2,4,4-trimethylpentene-2,3,3-dimethylhexene-1,2,4-dimethylhexene-1, 2,5-dimethlyhexene-1,3,5-dimethylhexene-1,4 , 4-dimethylhexane-1, ethylcyclohexyne, 1-octene,
- polymeric aminodicarboxylic acids their salts or their precursors. Particular preference is given to polyaspartic acids or their salts.
- Ethylenediamine-N, N '- disuccinate (EDDS) is preferably used in form of its sodium or magnesium salts.
- glycerol disuccinates and glycerol trisuccinates are also preferred in this context. Suitable amounts are from 3 to 15 wt .-%.
- the automatic dishwasher detergents according to the invention contain methylglycinediacetic acid or a salt of methylglycinediacetic acid.
- Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may optionally also be present in lactone form and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups.
- Glass corrosion inhibitors prevent the occurrence of haze, streaks and scratches, but also iridescence of the glass surface of machine-cleaned glasses.
- Preferred glass corrosion inhibitors come from the group of magnesium and zinc salts and magnesium and zinc complexes.
- preferred zinc salts preferably organic acids, particularly preferably organic carboxylic acids, ranging from salts which are difficult or insoluble in water, ie a solubility below 100 mg / l, preferably below 10 mg / l, in particular below 0.01 have mg / l, to those salts which have a solubility in water above 100 mg / l, preferably above 500 mg / l, more preferably above 1 g / l and in particular above 5 g / l (all solubilities at 2O 0 C. water temperature).
- the first group of zinc salts includes, for example, the zinc nitrate, the zinc oleate and the zinc stearate, and the group of soluble zinc salts includes, for example, zinc formate, zinc acetate, zinc lactate and zinc gluconate.
- the glass corrosion inhibitor at least one zinc salt of an organic carboxylic acid, more preferably a zinc salt from the group zinc stearate, zinc oleate, zinc gluconate, zinc acetate, zinc lactate and Zinkeitrat used.
- Zinc ricinoleate, zinc abietate and zinc oxalate are also preferred.
- Corrosion inhibitors serve to protect the items to be washed or the machine, with particular silver protectants being of particular importance in the field of automatic dishwashing. It is possible to use the known substances of the prior art.
- silver protectants selected from the group of the triazoles, the benzotriazoles, the bisbenzotriazoles, the aminotriazoles, the alkylaminotriazoles and the transition metal salts or complexes can be used in particular.
- Particularly preferred to use are benzotriazole and / or alkylaminotriazole. According to the invention, preference is given to using 3-amino-5-alkyl-1,2,4-triazoles or their physiologically tolerated salts.
- Preferred acids for salt formation are hydrochloric acid, sulfuric acid, phosphoric acid, carbonic acid, sulphurous acid, organic Carboxylic acids such as acetic, glycolic, citric and succinic acid.
- organic Carboxylic acids such as acetic, glycolic, citric and succinic acid.
- perfume oils or perfumes within the scope of the present invention, individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
- perfume oils may also contain natural fragrance mixtures such as are available from vegetable sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil.
- Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of the agents and to light and no pronounced substantivity to the substrates to be treated with the dye-containing agents such as textiles, glass, ceramics or plastic dishes do not stain them.
- a further subject of this application is a process for cleaning dishes in a dishwasher or for cleaning textiles in a textile washing machine using a liquid washing or cleaning agent preparation, comprising a) at least one washing or cleaning-active enzyme; b) 1, 2 propylene glycol c) nonionic surfactant of the general formula R 1 -CH (OH) CH 2 O- (AO) w - (A'O) x - (A "O) y - (A"'O) z -R 2 , in the
- R 1 is a linear or branched, saturated or mono- or polyunsaturated C 6 - 24 represents alkyl or alkenyl;
- R 2 is a linear or branched hydrocarbon radical having 2 to 26
- A, A ', A "and A'” independently represent a group from the group
- CH 2 -, -CH 2 -CH (CH 2 -CH 3 ), w, x, y and z are values between 0.5 and 120, where x, y and / or z can also be 0.
- washing or cleaning agent preparations according to the invention which are used with particular preference in these processes correspond to the agents described in detail above.
- Preferred processes for dishwashing or textile cleaning are characterized in that the liquid washing or cleaning agent preparation from a storage container located in the dishwasher or textile washing machine, which contains the multiple necessary for carrying out a cleaning process amount of washing or cleaning agent preparation into the interior of the dishwasher is dosed.
- the storage container used for dosing can be a storage container integrated in the dishwasher or textile washing machine, ie a storage container permanently attached to the dishwasher or textile washing machine, but also a self-sufficient, that is, self-contained, interior space act the dishwasher or textile washing machine einbringbaren reservoir.
- An example of an integrated storage container is a receptacle integrated in the door of the dishwasher, which is connected via a feed line to the interior of the dishwasher.
- An example of a self-sufficient storage container is a so-called Kopfstehflasche with a bottom-side outlet valve, which can be set for example in the cutlery basket of the dishwasher.
- the storage container has at least one chamber for receiving the liquid detergent or cleaning agent preparations according to the invention.
- the storage container has more than one, preferably two, three, four or more separate, separate receiving chambers, of which at least one chamber contains the liquid detergent or cleaning agent according to the invention, while at least one, preferably at least two further chambers , preferably contains liquid preparations with a composition deviating from the liquid detergent or cleaner compositions according to the invention.
- the volume of preferred storage container with one or more receiving chambers is between 10 and 1000 ml, preferably between 20 and 800 ml and in particular between 50 and 500 ml.
- washing or cleaning agent preparations according to the invention are distinguished by a particular temperature stability and the processes according to the invention are used in particular for the repeated dosing of these preparations from storage containers located in the interior of the dishwasher or textile washing machine.
- Preferred methods according to the invention are characterized in that the liquid detergent or cleaning agent preparation A before its metering into the interior of the dishwasher or textile washing machine for the duration of at least two, preferably at least four, more preferably at least eight and in particular at least twelve separate cleaning method in the remains in the dishwasher storage container remains.
- the term "separate cleaning process” refers to cleaning processes which, in addition to the main cleaning operation, also comprise a prewash cycle and / or a rinse cycle and which can be selected and triggered, for example, by means of the program switch of the dishwasher preferably at least 15 minutes, preferably between 20 and 360 minutes, preferably between 30 and 240 minutes.
- the time period between two separate cleaning processes, within which the liquid detergent or cleaning agent preparation is metered into the interior of the dishwasher, is at least 20 minutes, preferably at least 60 minutes, particularly preferably at least 120 minutes.
- the temperature load of the liquid detergent or cleaning agent preparations according to the invention can vary within the limits of the process according to the invention, wherein the liquid detergent or cleaning agent preparations are particularly suitable for those methods in which the liquid detergent or cleaning agent A in the reservoir at least twice, preferably at least four times, particularly preferably at least eight times and especially at least twelve times to temperatures above 3O 0 C, preferably above 4O 0 C, more preferably above 5O 0 C is heated.
- the liquid washing or cleaning agent preparation A in the storage container is heated by the rinsing liquor surrounding this storage container in each of the separate cleaning processes taking place one after the other.
- the liquid washing or cleaning agent preparation A cools in the reservoir between the separate purification process to temperatures below 3O 0 C, preferably below 26 0 C and in particular below 22 0 C..
- the preparation of the above-described combination of cleaning agents takes place in the form of separate receiving chambers, each of these receiving chambers containing one of the combined detergents.
- Examples of such Kon Stammionsformen are cartridges with two, three, four or more separate receiving chambers, for example, two-, three-, four- or multi-chamber bottles.
- a subject matter of the present application is furthermore a detergent dosage form comprising a) a washing or cleaning agent preparation A according to the invention in an amount sufficient for at least twice, preferably at least eight times and in particular at least eight times a machine dishwashing or a machine textile washing process; b) a cartridge for the washing or cleaning preparation A.
- Another object of the present application is a knowsstoff sosform comprising a) a detergent or cleaner composition according to the invention in a for the at least twice, preferably at least four times and in particular at least eight times
- Textile washing process sufficient amount; b) at least one further washing or cleaning agent preparation B which differs from A in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, the performance of a machine dishwashing process or a machine textile washing process; c) a cartridge for the washing or cleaning agent preparations A and B, in which the washing or cleaning agent preparations A and B are present in separate receiving chambers.
- a detergent dosage form comprising a) a washing or cleaning agent preparation A according to the invention in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, carrying out a machine dishwashing or machine textile washing process; b) at least one further washing or cleaning agent preparation B which differs from A in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, the performance of a machine dishwashing process or a machine textile washing process; c) at least one further washing or cleaning agent preparation C other than A and B in an amount sufficient for the at least twice, preferably at least four times, and in particular at least eight times, carrying out a machine dishwashing or machine textile washing process; d) a cartridge for the washing or cleaning preparations A, B and C, in which the washing or cleaning preparations A, B and C are present in separate receiving chambers.
- a further subject matter of the present application is a detergent dosing system comprising a) a detergent or cleaner composition A according to the invention in an amount sufficient for at least twice, preferably at least eight times, carrying out a machine dishwashing or machine textile washing process; b) a cartridge for the detergent preparation A; c) a metering device connected or connectable to the cartridge.
- the previously described cartridges of the detergent product forms are provided with a dispenser detachable from the cartridge.
- a dispenser detachable from the cartridge can be connected to the cartridge, for example by means of an adhesive, latching, snap or plug connection. Due to the separation of cartridge and dosing device is for example, simplifies the filling of the cartridge.
- the detachable connection of cartridge and dispenser allows the replacement of the cartridges on the dispenser. Such an exchange may be indicated, for example, in the event of a change in the cleaning program or after the cartridge has been completely emptied.
- a subject matter of the present application is furthermore a detergent dosing system comprising a) a detergent or cleaner composition A according to the invention in an amount sufficient for the at least twice, preferably at least eight times, carrying out a machine dishwashing or machine textile washing process; b) a cartridge for the detergent preparation A; c) a dispenser detachably connected to the cartridge.
- a further subject matter of the present application is a detergent dosing system comprising a) a detergent or cleaner composition A according to the invention in an amount sufficient for at least twice, preferably at least eight times, carrying out a machine dishwashing or machine textile washing process; b) at least one further washing or cleaning agent preparation B which differs from A in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, the performance of a machine dishwashing process or a machine textile washing process; c) a cartridge for the washing or cleaning agent preparations A and B, in which the washing or cleaning agent preparations A and B are present in separate receiving chambers; d) a releasably connected to the cartridge dosing device.
- a particularly preferred subject matter of this application is a detergent dosing system comprising a) a detergent or cleaner composition A according to the invention in an amount sufficient for at least twice, preferably at least eight times, carrying out a machine dishwashing or machine textile washing process; b) at least one further detergent or cleaning agent preparation B different from A in at least one of the at least twice, preferably at least four times and especially Sufficient quantity at least eight times to carry out a machine dishwashing or machine washing process; c) at least one further washing or cleaning agent preparation C other than A and B in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, carrying out a machine dishwashing or machine textile washing process; d) a cartridge for the washing or cleaning agent preparations A, B and C, in which the washing or cleaning agent preparations A, B and C are present in separate receiving chambers; e) a dispenser detachably connected to the cartridge.
- detergent forms are also conceivable in which the cartridge and the dosing device are permanently connected to each other.
- An object of the present application is further a huntsmitteldosiersystem comprising a) a detergent or cleaner composition A according to the invention for at least twice, preferably at least four times and in particular at least eight times performing a dishwasher automatic machine or machine textile washing process sufficient amount; b) a cartridge for the detergent preparation A; c) a metering device undetachably connected to the cartridge.
- a further subject matter of the present application is a detergent dosing system comprising a) a detergent or cleaner composition A according to the invention in an amount sufficient for at least twice, preferably at least eight times, carrying out a machine dishwashing or machine textile washing process; b) at least one further washing or cleaning agent preparation B which differs from A in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, the performance of a machine dishwashing process or a machine textile washing process; c) a cartridge for the washing or cleaning agent preparations A and B, in which the washing or cleaning agent preparations A and B are present in separate receiving chambers; d) a non-releasably connected to the cartridge dosing device.
- a particularly preferred subject matter of this application is a detergent dosing system comprising a) a washing or cleaning agent preparation A according to the invention in an amount sufficient for at least twice, preferably at least eight times, carrying out a machine dishwashing or machine textile washing process; b) at least one further washing or cleaning agent preparation B which differs from A in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, the performance of a machine dishwashing process or a machine textile washing process; c) at least one further washing or cleaning agent preparation C other than A and B in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, carrying out a machine dishwashing or machine textile washing process; d) a cartridge for the cleaning agents A, B and C, in which the washing or cleaning agent preparations A, B and C are present in separate receiving chambers; e) a metering device undetachably connected to the cartridge.
- the vorgenanten starvedosiersysteme comprising a cleaning agent according to the invention (and optionally one or two further, different from the cleaning agent according to the invention cleaning), a cartridge and a releasably connected to the cartridge dosing device are in a preferred embodiment in a common outer packaging, wherein the filled cartridge and the dosing device are particularly preferably contained separately from one another in the outer packaging.
- the outer packaging is used for storage, transport and presentation of the invention makesmitte timessform and protect them from dirt, shock and shock. In particular for the purpose of presentation, the outer packaging should at least partially be made transparent.
- inventive detergents, detergent combinations or detergent product forms in conjunction with a dishwasher.
- Such a combination is particularly advantageous in cases in which the course of the automatic dishwashing process (for example duration, temperature profile, water supply) and the detergent formulation or the control electronics of the dosing device are matched to one another.
- the metering system according to the invention consists of the basic components of a cartridge filled with the cleaning agent according to the invention and one with the cartridge detachable metering device, which in turn from other components, such as component carrier, actuator, closure element, sensor, power source and / or control unit is formed.
- the metering system according to the invention is mobile. Movable in the sense of this application means that the metering system is not inseparably connected to a water-conducting device such as a dishwasher, washing machine, tumble dryer or the like, but for example from a dishwasher by the user removed or positionable in a dishwasher, so is independently handled, is
- the dosing device for the user is not detachably connected to a water-carrying device such as a dishwasher, washing machine, tumble dryer or the like and only the cartridge is movable.
- the preparations to be dosed may have a pH between 2 and 12, depending on the intended use, all components of the dosing system which come into contact with the preparations should have a corresponding acid and / or alkali resistance. Furthermore, these components should be largely chemically inert by a suitable choice of material, for example against nonionic surfactants, enzymes and / or fragrances.
- a cartridge is understood as meaning a packaging material which is suitable for enveloping or holding together flowable or spreadable preparations and which can be coupled to a dosing device for dispensing the preparation.
- a cartridge can also comprise a plurality of chambers which can be filled with mutually different compositions. It is also conceivable that a plurality of containers is arranged to form a cartridge unit.
- the cartridge has at least one outlet opening, which is arranged such that a gravity-induced release of preparation from the container in the position of use of the dosing device can be effected.
- at least one second chamber is provided for receiving at least one second flowable preparation, the second chamber having at least one outlet opening arranged such that a gravity-induced product release from the second chamber in the use position of the dosing is effected.
- the arrangement of a second chamber is particularly advantageous if in the separate containers preparations are stored, which are usually not stable to each other, such as bleaching agents and enzymes.
- one of the chambers can be designed for the delivery of volatile preparations, such as a fragrance to the environment.
- the cartridge is integrally formed.
- the cartridges in particular by suitable blow molding, cost-effectively trained in a manufacturing step.
- the chambers of a cartridge can in this case be separated from one another, for example, by webs or material bridges.
- the cartridge can also be formed in several pieces by injection molded and then assembled components.
- the cartridge is formed in such a multi-piece, that at least one chamber, preferably all chambers, can be removed individually from the metering device or inserted into the metering device.
- This makes it possible, with a different consumption of a preparation from a chamber to exchange an already empty chamber, while the rest, which may still be filled with preparation, remain in the metering device.
- a targeted and needs-based refilling the individual chambers or their preparations can be achieved.
- the chambers of a cartridge can be fixed to one another by suitable connection methods, so that a container unit is formed.
- the chambers can be fixed by a suitable form-fitting, non-positive or cohesive connection releasably or permanently against each other.
- the fixation by one or more of the types of compounds from the group of snap-in compounds, Velcro, press joints, fusions, glued joints, welded joints, solder joints, screw, wedge, clamp or bounce joints can be done.
- the fixation can also be formed by a shrink tube (so-called sleeve), which in a heated state over the entire or sections the cartridge is pulled and firmly encloses the chambers or the cartridge in the cooled state.
- the bottom of the chambers may be funnel-shaped inclined towards the discharge opening.
- the inner wall of a chamber can be formed by suitable choice of material and / or surface design in such a way that a low material adhesion of the preparation to the inner chamber wall is realized. Also by this measure, the residual emptiness of a chamber can be further optimized.
- the chambers of a cartridge may have the same or different filling volumes.
- the ratio of container volumes is preferably 5: 1, with a three-chamber configuration it is preferably 4: 1: 1, and these configurations are particularly suitable for use in dishwashers.
- the cartridge preferably has 3 chambers.
- the first chamber contains an alkaline cleaning preparation
- the second chamber an enzymatic preparation
- the third chamber a rinse aid, wherein the volume ratio of the chambers is approximately 4: 1: 1.
- a metering chamber may be formed in the flow direction of the preparation in front of the outlet opening.
- the preparation amount that is to be released in the release of preparation from the chamber to the environment set. This is particularly advantageous if the closure element of the dosing device, which causes the preparation discharge from a chamber to the environment, can only be put into a dispensing and a closure state without controlling the dispensing quantity. It is then ensured by the metering chamber that a predefined amount of preparation is released without an immediate feedback of the delivered preparation amount.
- the metering chambers can be formed in one piece or in several pieces.
- one or more chambers in addition to an outlet opening each have a liquid-tight sealable chamber opening. Through this chamber opening, it is possible, for example, to refill stored in this chamber preparation.
- ventilation options can be provided in particular in the head region of the cartridge to a pressure equalization in falling Behellstand the Chambers between the interior of the cartridge chambers and the environment to ensure.
- These ventilation options can be designed, for example, as a valve, in particular silicone valve, micro-openings in the cartridge wall or the like.
- the cartridge chambers should not be aerated directly, but via the dosing device or no ventilation, e.g. be provided with the use of flexible containers, such as bags, so this has the advantage that at elevated temperatures in the course of a rinse cycle of a dishwasher by the heating of the chamber contents, a pressure is built up, which presses the preparations to be dosed in the direction of the outlet openings, so that a good residual emptying of the cartridge can be achieved. Furthermore, in the case of such an air-free packaging, there is no risk of oxidation of substances of the preparation, which makes bag packaging or else bag-in-bottle packaging appear expedient, in particular for oxidation-sensitive preparations.
- the cartridge usually has a filling volume of ⁇ 5,000 ml, in particular ⁇ 1,000 ml, preferably ⁇ 500 ml, more preferably ⁇ 250 ml, most preferably ⁇ 50 ml.
- the cartridge can take on any spatial form. It can for example be cube-shaped, spherical or plate-like.
- the cartridge and the dosing device can in particular be configured with respect to their spatial form such that they ensure the least possible loss of useful volume, in particular in a dishwasher.
- the cartridge preferably has a ratio of height: width: depth between 5: 5: 1 and 50: 50: 1, particularly preferably about 10: 10: 1.
- the metering system is dimensioned in an advantageous embodiment of the invention such that a positioning of the metering system is only possible in the receptacles provided for the lower basket.
- the width and the height of the metering system can be selected in particular between 150 mm and 300 mm, particularly preferably between 175 mm and 250 mm.
- the metering unit in cup shape with a substantially circular or square base.
- Another way to reduce the effect of heat on a preparation in a chamber of the cartridge is to isolate the chamber by suitable means, e.g. by the use of thermal insulation materials such as styrofoam, which enclose the chamber or the cartridge in a suitable manner, in whole or in part.
- suitable means e.g. by the use of thermal insulation materials such as styrofoam, which enclose the chamber or the cartridge in a suitable manner, in whole or in part.
- the cartridge has an RFID tag that contains at least information about the contents of the cartridge and that can be read by the sensor unit.
- This information can be used to select a dosing program stored in the control unit. In this way it can be ensured that an optimal dosing program is always used for a particular preparation. It can also be provided that in the absence of an RFID label or an RFID label with a false or faulty identifier, no dosage is done by the dosing and instead an optical or acoustic signal is generated that the user on the present Error indicates.
- the cartridges may also have structural elements which cooperate with corresponding elements of the metering device according to the key-lock principle, so that, for example, only cartridges of a particular type can be coupled to the metering device. Furthermore, this configuration makes it possible for information about the cartridge coupled to the dosing device to be transmitted to the control unit, as a result of which control of the dosing device coordinated with the contents of the corresponding container can take place.
- the cartridge is designed in particular for receiving flowable detergents or cleaning agents. Particularly preferably, such a cartridge has a plurality of chambers for the spatially separated recording in each case of different preparations of a detergent or cleaning agent.
- the cartridge may be designed so that it can be detachably or firmly arranged in or on the dishwasher.
- control unit e.g., a Bosch Sensortec metering device
- sensor unit e.g., a Bosch Sensortec metering device
- actuator necessary for operation are integrated in the dosing device.
- an energy source is also arranged in the metering device.
- the dosing device consists of a splash-proof housing, which prevents the penetration of spray water, as may occur, for example, when used in a dishwasher, into the interior of the dosing.
- the dosing device comprises at least one first interface which interacts with a corresponding interface formed in or on a water-conducting device, in particular a water-conducting domestic appliance, preferably a dishwasher or washing machine, such that a transmission of electrical energy from the water-conducting device is realized for dosing.
- a water-conducting device in particular a water-conducting domestic appliance, preferably a dishwasher or washing machine, such that a transmission of electrical energy from the water-conducting device is realized for dosing.
- the interfaces are formed by connectors.
- the interface cells can be designed such that a wireless transmission of electrical energy is effected.
- the adapter serves for the mechanical and / or electrical connection of the metering system with the water-conducting household appliance.
- the adapter is, preferably fixed, connected to a water-carrying pipe of the household appliance.
- the adapter makes it possible to run a dosing system for either stand-alone or build-in versions, or it can be used as a charging station for the dosing system, which charges the dosing device's power source, for example, or data be exchanged between the dosing device and the adapter.
- the adapter can be arranged in a dishwasher on one of the inner walls of the washing chamber, in particular on the inner side of the dishwasher door.
- the adapter is positioned as such inaccessible to the user in the water-conducting household appliance, so that the dosing device is used for example during assembly of the household appliance in the adapter, wherein the adapter, the dosing device and the household appliance are designed in that a cartridge can be coupled by the user with the dosing device.
- the detergents, detergent combinations or detergent product forms according to the invention are suitable for use in dishwashing as well as for textile cleaning, however, the use of a detergent or cleaner composition A according to the invention, a detergent combination according to the invention or a rotatesitz polesform invention for dishwashing in an automatic dishwashing process is preferred.
- the cleaning agents according to the invention are distinguished by a particular physical and chemical stability, in particular with respect to temperature fluctuations.
- the cleaning agents according to the invention are thus exceptionally suitable for the metering by means of a metering system located in the interior of a washing or dishwashing machine.
- a dosing system which can be immovably integrated into the interior of the washing machine or dishwasher (machine-integrated dosing device) but of course as a movable device in the interior can be introduced (self-sufficient dosing), contains the multiple required to carry out a machine cleaning process amount of detergent ,
- mobile means that the dispensing and metering system is not permanently detachable with a device such as a dishwasher, washing machine, Tumble dryer or the like is connected, but can be removed for example from a dishwasher or positioned in a dishwasher.
- liquid washing or cleaning agent preparation A or a detergent combination for filling i) a cartridge of a dosing system immovably integrated into the interior of a dishwasher or textile washing machine or ii) a cartridge for positioning in the interior of a dishwasher or
- Textile washing provided movable cartridge of a dosing with a for at least twice, preferably at least eight times performing a machine dishwashing or machine textile washing sufficient amount of liquid detergent or cleaning agent combination or this detergent combination are also objects of this application.
- An example of a stationary cartridge is a container immovably integrated into the interior, for example in the side wall or the inner lining of the door of a dishwasher.
- a movable cartridge is a container which is introduced by the consumer into the interior of the dishwasher or textile washing machine and remains there during the entire course of a cleaning cycle.
- a cartridge can be integrated into the interior, for example by simply setting it in the cutlery or crockery basket, but can also be removed again by the consumer from the interior of the dishwasher.
- the dosage of the cleaning agent or the detergent combination from the cartridge into the interior of the dishwasher or textile washing machine is carried out as described above, preferably by means of a detachable from the cartridge dosing.
- a dosing device can be connected to the cartridge by means of an adhesive, latching, snap or plug connection.
- cartridges with a permanently connected metering device can of course also be used.
- a detergent dosage form comprising a) a detergent or cleaner composition A according to the invention in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, a machine dishwashing or machine textile washing process; b) a cartridge for the washing or cleaning agent preparation A as a cleaning agent reservoir for i) a immovable in the interior of a dishwasher or
- Textile washing machine integrated dosing device or ii) a for positioning in the interior of a dishwasher or
- a detergent dosage form comprising a) a washing or cleaning agent preparation A according to the invention for at least twice, preferably at least four times and in particular at least eight times carrying out a machine dishwashing or machine textile washing process; b) at least one further washing or cleaning agent preparation B which differs from A in an amount sufficient for at least twice, preferably at least four times, and in particular at least eight times, the performance of a machine dishwashing process or a machine textile washing process; c) a cartridge for the detergent preparations A and B, in which the washing or cleaning agent preparations A and B in separate receiving chambers are present as a detergent reservoir for i) immovable in the interior of a dishwasher or
- Textile washing machine integrated dosing or ii) one for positioning in the interior of a dishwasher or
- Textile washing machine provided mobile dosing device.
- a detergent dosage form comprising a) a detergent or cleaner composition A according to the invention for at least twice, preferably at least four times, and in particular at least eight times, carrying out a machine dishwashing process; b) at least one further detergent or cleaning agent preparation B different from A in at least one of the at least twice, preferably at least four times and especially Sufficient quantity to carry out a machine dishwashing process at least eight times; c) at least one further detergent or cleaning agent preparation C other than A and B in an amount sufficient for at least twice, preferably at least four, and in particular at least eight times, carrying out a machine dishwashing process; d) a cartridge for the washing or cleaning agent preparation A, B and C, in which the washing or cleaning agent preparations A, B and C are present in separate receiving chambers as a detergent reservoir for i) an immovable integrated into the interior of a dishwasher
- the detergents and cleaning agent combinations according to the invention are preferably used as automatic dishwashing detergents or as mechanical laundry detergents.
- Automatic dishwashing processes according to the invention and textile washing processes using a washing or cleaning agent preparation A according to the invention are characterized in that in the course of these processes, a subset a of the washing or cleaning agent preparation A in the interior is formed from a cartridge located in the interior of the dishwasher or textile washing machine the dishwasher or textile washing machine is metered, wherein a residual amount of the cleaning agent in the cartridge remains in the cartridge until the end of the dishwashing or textile washing process, characterized in that this residual amount of at least twice, preferably at least four times and in particular at least eight times the amount the subset a corresponds.
- Detergent offer form or detergent dosing be used.
- An object of this application is therefore further a machine dishwashing or machine textile washing process using a detergent combination according to the invention comprising a detergent A according to the invention as well as a Another cleaning agent B different from A, in the course of which a cartridge located in the interior of the dishwasher or a washing machine a subset a of the present in the cartridge cleaning agent A and further a subset b of the present in the cartridge cleaning agent B in the interior of the dishwasher or Washing machine is dosed, with residual amounts of cleaning agents A and B remain in the cartridge until the end of dishwashing or textile washing process and the remaining amount of the detergent A at least twice, preferably at least four times and in particular at least eight times the amount of subset a and the remaining amount of the cleaning agent B at least twice, preferably at least four times and in particular at least eight times the amount of subset b corresponds.
- a subject of this application is further a machine dishwashing or machine textile washing process using a combination of detergents according to the invention comprising a detergent A according to the invention and a further cleaning agent B different from A and a third cleaning agent C different from A and B, in the course of which an agent in the interior A subset a of the present in the cartridge detergent A and also a subset b of the present in the cartridge detergent B and in addition a subset c of the present in the cartridge detergent C is dosed into the interior of the dishwasher or textile washing machine , Wherein remaining quantities of the cleaning agents A, B and C remain in the cartridge until the end of the dishwashing process or textile washing process and the residual amount of the cleaning agent A min at least twice, preferably at least four times, and in particular at least eight times, the amount of subset b corresponds to the residual amount of the cleaning agent B and the remaining amount of the cleaning agent C at least the double, preferably at least four times and in particular at least eight times the amount of subset c corresponds.
- the metering of the different cleaning agents preferably takes place at different times of the cleaning cycle.
- a further subject of this application is therefore a machine dishwashing or machine textile washing process using a cleaning agent according to the invention or a detergent combination according to the invention or a novel detergent Detergent supply form or a makesmitteldosiersystems according to the invention, in the course of which a) at a time t1 from a cartridge located in the interior of the dishwasher or washing machine, a subset a of the present invention in the detergent detergent or detergent A is dosed into the interior of the dishwasher, with a Residual amount of the detergent present in the cartridge remains in the cartridge until the end of the dishwashing or textile washing process, which corresponds to at least twice, preferably at least four times, and in particular at least eight times, the amount of subset a; b) at least one further time t2 ⁇ t1 from a cartridge located in the interior of the dishwasher or textile washing machine, a subset b of the washing or cleaning agent preparation B in the second compartment of the washing or cleaning agent preparation A in the interior of the dishwasher or resp Washing machine is
- Dishwasher or textile washing cartridge located a subset c of located in the third cartridge of the washing or cleaning composition A and the detergent or cleaning agent preparation B different washing or cleaning agent preparation C is dosed into the interior of the dishwasher or textile washing machine, wherein a residual amount the washing or cleaning agent preparation C present in this cartridge remains in the cartridge until the end of the dishwashing or textile washing process, which corresponds to at least twice, preferably at least four times, and in particular at least eight times, the quantity of the subset c.
- the time t2 is at least 1 minute, preferably at least 2 minutes and especially between 3 and 20 minutes or after time t1.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10712421T PL2414498T3 (pl) | 2009-04-01 | 2010-03-31 | Środek czyszczący |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009002095A DE102009002095A1 (de) | 2009-04-01 | 2009-04-01 | Reinigungsmittel |
PCT/EP2010/054305 WO2010112548A1 (de) | 2009-04-01 | 2010-03-31 | Reinigungsmittel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2414498A1 true EP2414498A1 (de) | 2012-02-08 |
EP2414498B1 EP2414498B1 (de) | 2020-12-09 |
Family
ID=42306660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10712421.6A Active EP2414498B1 (de) | 2009-04-01 | 2010-03-31 | Reinigungsmittel |
Country Status (6)
Country | Link |
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US (1) | US8328951B2 (de) |
EP (1) | EP2414498B1 (de) |
DE (1) | DE102009002095A1 (de) |
ES (1) | ES2844278T3 (de) |
PL (1) | PL2414498T3 (de) |
WO (1) | WO2010112548A1 (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010002196A1 (de) * | 2010-02-22 | 2011-11-17 | Henkel Ag & Co. Kgaa | Kartusche für ein wasserführendes Haushaltsgerät |
DE102011000889A1 (de) * | 2011-02-23 | 2012-08-23 | Witty Chemie Gmbh & Co. Kg | Reinigungsmittel für Geschirrspülanlagen und Verfahren dafür |
KR102463726B1 (ko) * | 2012-07-19 | 2022-11-07 | 닛산 가가쿠 가부시키가이샤 | 반도체용 세정액 및 이것을 이용한 세정방법 |
DE102012107728A1 (de) * | 2012-08-22 | 2014-02-27 | Witty-Chemie Gmbh & Co. Kg | Phosphorfreies Reinigungsmittel für Geschirrspülanlagen und Verfahren dafür |
RU2642077C2 (ru) | 2013-11-11 | 2018-01-24 | ЭКОЛАБ ЮЭсЭй ИНК. | Многоцелевой ферментный детергент и способы стабилизации применяемого раствора |
CN109312523B (zh) | 2016-06-09 | 2021-03-16 | 荷兰联合利华有限公司 | 洗衣液混合设备 |
TR202004710U5 (tr) | 2017-10-05 | 2021-01-21 | Unilever Nv | Özelleştirilmiş çamaşır yıkama için usuller ve aygıtlar. |
GB2571336A (en) | 2018-02-26 | 2019-08-28 | Unilever Plc | Methods and system for monitoring and replenishing one or more laundry components |
EP3693895B1 (de) * | 2019-02-05 | 2023-05-03 | Nxp B.V. | Verbrauchsprodukt und verfahren für dessen bereitstellung |
CN114630934A (zh) | 2019-11-01 | 2022-06-14 | 联合利华知识产权控股有限公司 | 可回收自动定量配给容器 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2038103A1 (de) | 1970-07-31 | 1972-02-10 | Henkel & Cie Gmbh | Waessrige Reinigungsmittelkonzentrate mit einem Gehalt an stabilisierten Enzymen |
US4305837A (en) * | 1980-10-30 | 1981-12-15 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
WO1994000558A1 (en) | 1992-06-19 | 1994-01-06 | Joslin Diabetes Center, Inc. | DIABETOGENE rad: A TYPE II DIABETES SPECIFIC GENE |
SI0730024T1 (en) * | 1995-03-01 | 2000-02-29 | Chemische Fabrik Dr. Weigert (Gmbh & Co.) | Surgical instruments cleaning composition |
DE19717329A1 (de) * | 1997-04-24 | 1998-10-29 | Henkel Ecolab Gmbh & Co Ohg | Flüssige Enzymzubereitung und ihre Verwendung |
EP1081215B1 (de) * | 1999-09-02 | 2004-03-17 | Chemische Fabrik Dr. Weigert GmbH & Co. KG. | Enzymkonzentrat und Verfahren zum Reinigen von Oberflächen |
DE10148571B4 (de) * | 2001-10-01 | 2004-01-15 | Henkel Kgaa | Semiautomatische Dosierung |
GB2386129B (en) | 2002-03-06 | 2004-12-01 | Reckitt Benckiser Nv | Detergent dosing device |
ATE415467T1 (de) * | 2005-04-27 | 2008-12-15 | Mifa Ag Frenkendorf | Flüssigwaschmittel für tieftemperaturprogramme und kurzprogramme |
DE102005062479A1 (de) | 2005-12-27 | 2007-07-05 | BSH Bosch und Siemens Hausgeräte GmbH | Dosiervorrichtung für die Zugabe eines Zuschlagmittels in einen Behandlungsraum und Geschirrspülmaschine mit einer Dosiervorrichtung |
DE102007039655A1 (de) * | 2007-08-22 | 2009-02-26 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
-
2009
- 2009-04-01 DE DE102009002095A patent/DE102009002095A1/de not_active Withdrawn
-
2010
- 2010-03-31 EP EP10712421.6A patent/EP2414498B1/de active Active
- 2010-03-31 PL PL10712421T patent/PL2414498T3/pl unknown
- 2010-03-31 WO PCT/EP2010/054305 patent/WO2010112548A1/de active Application Filing
- 2010-03-31 ES ES10712421T patent/ES2844278T3/es active Active
-
2011
- 2011-09-29 US US13/248,246 patent/US8328951B2/en active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2010112548A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20120021965A1 (en) | 2012-01-26 |
US8328951B2 (en) | 2012-12-11 |
EP2414498B1 (de) | 2020-12-09 |
PL2414498T3 (pl) | 2021-05-31 |
ES2844278T3 (es) | 2021-07-21 |
DE102009002095A1 (de) | 2010-10-07 |
WO2010112548A1 (de) | 2010-10-07 |
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