Classifications

• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F11/00—Treatment of sludge; Devices therefor
  • C02F11/02—Biological treatment
  • C02F11/04—Anaerobic treatment; Production of methane by such processes
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F11/00—Treatment of sludge; Devices therefor
  • C02F11/06—Treatment of sludge; Devices therefor by oxidation
  • C02F11/08—Wet air oxidation
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F11/00—Treatment of sludge; Devices therefor
  • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
  • C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F11/00—Treatment of sludge; Devices therefor
  • C02F11/18—Treatment of sludge; Devices therefor by thermal conditioning
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E50/00—Technologies for the production of fuel of non-fossil origin
  • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
  • Y02W10/00—Technologies for wastewater treatment
  • Y02W10/20—Sludge processing

Definitions

• the field of the invention is that of the treatment of organic waste, in particular those produced during the treatment of water.
• the invention relates to a sludge treatment process resulting from the treatment of municipal or industrial water, particularly for the purpose of producing energy, for example electricity.
• the particulate portion of the pollution can be partially removed by simple decantation.
• the decantation of water is accompanied by the formation of sludge, called "primary sludge", consisting of a mixture of particles and water, which constitutes organic waste.
• the soluble organic portion of the pollution can be treated, at least in large part, by the implementation of biological treatment processes.
• the biological treatment of water consists in putting the water to be treated in contact with microorganisms that consume, for their growth, the organic pollution dissolved in these waters.
• Digestion is particularly efficient in that it leads to the combined production of: gas (biogas) convertible into energy (s); digestate used for example as a fertilizer or amendment agent (a digestate is a residue of the digestion of an organic compound), and - a relatively small amount of solubilized organic compounds little or not biodegradable.
• gas biogas
• s energy
• digestate used for example as a fertilizer or amendment agent
• a digestate is a residue of the digestion of an organic compound
• solubilized organic compounds little or not biodegradable.
• the digestates thus obtained contain a fraction which is difficult to fermentable, that is to say which is difficult to biologically degradable.
• the technique consisting in implementing a thermal hydrolysis of the sludges prior to the implementation of digestion has been developed.
• This technique is particularly advantageous insofar as thermal hydrolysis makes it possible to degrade, at least in large part, the difficultly fermentable fraction of the sludge.
• the conditions necessary for obtaining a high-performance thermal hydrolysis require a high energy consumption.
• the energy consumption is such that more than half of the biogas from digestion is used to feed a conventional boiler to produce the steam needed for hydrolysis.
• the rest of the biogas feeds a co-generation engine connected to an alternator to produce electricity. It can for example also be used to directly heat premises.
• this technique which certainly makes it possible to produce digests whose concentration of difficultly fermentable fraction is relatively reduced, results in: the production of soluble compounds which is hardly or not biodegradable; - requires an over-dimensioning of the digester to ensure efficient digestion; requires to consume a large part of the biogas to directly produce the steam necessary for hydrolysis, and therefore allows only to produce a small amount of excess energy, for example in the form of electricity, heat ..., which may be used for purposes other than the implementation of the sludge treatment process itself.
• the invention particularly aims to overcome these disadvantages of the prior art.
• an object of the invention is to provide, in at least one embodiment, such a technique whose implementation requires a low power consumption.
• the invention aims to provide, in at least one embodiment, such a technique, the implementation of which leads to limiting the consumption of biogas necessary for the achievement of hydrolysis conditions, and to increase the share of biogas to produce excess energy that can be used for purposes other than the implementation of the sludge treatment process.
• Another objective of the invention is to provide, in at least one embodiment of the invention, a technique for treating sludge resulting from the treatment of water which makes it possible to eliminate the fraction which is difficult to ferment at least largely.
• the objective of the invention is to implement, in at least one embodiment of the invention, such a technique that allows the production of waste containing a residual fraction difficult to fermentable reduced compared to the techniques of the prior art.
• the invention also aims, in at least one embodiment of the invention, to limit the production of soluble compounds little or not biodegradable.
• the invention further aims, in at least one embodiment of the invention, to provide such a technique that allows the treatment of a large amount of sludge.
• the invention also aims, in at least one embodiment of the invention, the provision of such a technique that is reliable, simple to implement and relatively economical.
• step (iii) obtaining at least partially dehydrated and hydrolysed digested sludge by thermal hydrolysis of the at least partially dehydrated sludge obtained in step (ii); (iv) digestion of the at least partially dehydrated and hydrolysed digested sludge obtained in step (iii); said method further comprising: a step of recovering the biogas formed during said digestion and primary digestion and a step of producing energy from said biogas comprising a substep of producing energy necessary for the implementation of said thermal hydrolysis and a substep of excess energy production, all of said biogas being used to produce electricity.
• Thermal hydrolysis as aimed at a specifically non-biological hydrolysis.
• the invention is based on an original approach that consists of combining the successive implementation of a first digestion, a thermal hydrolysis (non-biological) and a second sludge digestion.
• the first digestion (or primary digestion) makes it possible to degrade the easily fermentable fraction of the sludge, at least to a large extent, and to produce a digest that is difficult to ferment.
• the implementation of the separation step allows the evacuation of an effluent containing the organic material little or no biodegradable produced during digestion.
• the amount of organic material which is little or not biodegradable at the inlet of the hydrolysis step is thus reduced, which ultimately tends to reduce the amount of organic matter which is little or no biodegradable produced during hydrolysis. It also makes it possible to reduce the size of equipment placed downstream, and to reduce the energy consumption necessary for carrying out thermal hydrolysis.
• Thermal hydrolysis is only used to treat the difficultly fermentable fraction of the sludge.
• the energy required for carrying out the thermal hydrolysis according to the invention is less than that required for carrying out the thermal hydrolysis according to the prior art.
• the thermal hydrolysis is conducted to treat all the sludge, that is to say both their fermentable part that their hardly fermentable part, which requires a higher energy input.
• Thermal hydrolysis can degrade the difficultly fermentable digestate into an easily fermentable hydrolytic digestate.
• fermentable sludge are then digested during the second digestion which leads to the production of a digestate free, at least in large part, of fermentable fraction, the digestate containing however a very difficult to fermentable portion still called refractory fraction or hard .
• thermal hydrolysis being performed only on the difficultly fermentable fraction sludge, its implementation generates the production of a lower amount of soluble compounds little or not biodegradable compared to the technique according to the prior art.
• a method according to the invention allows the production of a large amount of biogas.
• the energy required to carry out the hydrolysis is relatively low considering that it is carried out only on the difficultly fermentable portion of the sludge.
• the implementation of the technique according to the invention therefore makes it possible, on the one hand, to produce the energy necessary to reach, in particular, the pressure and temperature conditions of the hydrolysis and, on the other hand, a large part of excess energy which can be used for purposes other than those of the implementation of the sludge treatment process itself (electricity intended for example to feed a station or to be sold to EDF, heat (fluid (liquid, gas) hot ) for space heating ...
• a method according to the invention comprises a step of reconversion of said biogas, said conversion step comprising a biogas feed step of a cogeneration system in order to produce energy necessary for the implementation of of said hydrolysis step and excess energy.
• the biogas feed of a cogeneration system consequently makes it possible, on the one hand, to produce the energy necessary to reach, in particular, the pressure and temperature conditions of the hydrolysis and, on the other hand, to produce an important part of excess energy that can be used for purposes other than those of the implementation of the sludge treatment process itself (electricity intended for example to feed a station or to be sold to EDF, heat (fluid (liquid, gas) for heating premises ...
• said conversion step comprises a step of feeding biogas to an engine connected to means for generating electricity, and a step of recovering the heat released by said engine in order to reach the temperature and pressure conditions of said hydrolysis step.
• a process according to the invention comprises a step of obtaining a second aqueous effluent and treated sludge by a second liquid-solid separation of the sludge obtained in said step (iv).
• this separation step allows the evacuation of an effluent containing the organic matter little or no biodegradable produced in during digestion and dehydrated digested sludge free from easily fermentable organic matter.
• said thermal hydrolysis is carried out at a pressure of between 1 and 20 bar, at a temperature of between 50 ° C. and 200 ° C., and most preferably between 120 ° C. and 180 ° C., for a period of time between 20 and 120 minutes.
• Thermal hydrolysis conditions chosen in these ranges can effectively reduce the difficultly fermentable portion of the sludge.
• said thermal hydrolysis is preferably carried out at a pressure equal to the saturation vapor pressure, at a temperature equal to 165 ° C., for a duration equal to 30 minutes.
• said primary digestion and / or said digestion are of the mesophilic anaerobic type.
• the digestion or digestion is carried out at a temperature between 32 and 38 ° C for 5 to 15 days.
• said primary digestion and / or said digestion are of the thermophilic anaerobic type.
• the digestion or digestion is carried out at a temperature between 52 and 58 ° C for 5 to 15 days.
• the suspended matter concentration at the inlet of the primary digestion is between 25 and 65 grams of MES / 1 of sludge.
• the suspension material concentration at the entry of the digestion is between 100 and 150 grams of MES / 1 of sludge.
• said liquid-solid separation step is preceded by a step of defibration of said sludge after primary digestion.
• the defibration step can be carried out before the step of primary digestion.
• Defrosting allows: to make possible the treatment of sludge that the skilled person considers to be impossible by the implementation of the technique according to the prior art; reduce the size of the digester placed upstream or downstream, or increase the residence time of the other organic fractions of the sludge.
• the invention also covers a sludge treatment plant for implementing a method according to the invention, said installation comprising thermal hydrolysis means having an inlet and an outlet and means for digestion of said sludge.
• said digestion means communicate with sludge feed means and said inlet and said outlet of said hydrolysis means communicate with said digestion means, said plant also comprising first liquid-solid separation means disposed to the output of said digestion means and biogas recovery means from said digestion means.
• said digestion means are connected to biogas recovery means which comprise a collector connected to means for producing steam and electricity, comprising a co-generation engine connected to an alternator producing electricity. electricity whose exhaust line opens at the entrance of an air-water heat exchanger producing water vapor and a pipe for supplying steam to said thermal hydrolysis means.
• Such an installation allows the implementation of a method according to the invention, the general principle of which is based on the combined implementation of a first digestion, a thermal hydrolysis and a second digestion of the sludge.
• the implementation of these separation means allows the evacuation of an effluent containing the organic material little or no biodegradable produced during digestion. The amount of organic matter which is little or not biodegradable at the inlet of the hydrolysis step is thus reduced, which ultimately tends to reduce the amount of organic material which is little or not biodegradable produced during this hydrolysis.
• An installation according to the invention comprises a cogeneration system, said biogas recovery means communicating with said cogeneration system.
• the biogas feed of a cogeneration system makes it possible to produce the energy necessary to reach, in particular, the pressure and temperature conditions of the hydrolysis and to produce a large part of excess energy (for example in the form of electricity and / or heat (hot fluid (air and / or water)) which can be used for purposes other than those of the implementation of the sludge treatment process itself.
• said cogeneration system comprises a co-generation engine, said biogas recovery means opening into said engine, said co-generation engine being connected to means for generating electricity and having means for transferring heat released by said engine to water to produce steam.
• the entire biogas formed during digestion feeds the co-generation engine, which is connected to means of generating electricity as an alternator.
• the recovery of the heat released by the engine allows the production of all the thermal fluid (for example steam ) necessary for carrying out thermal hydrolysis.
• the thermal fluid for example steam
• the totality of the biogas is used to produce electricity, unlike the technique according to the prior art in which at least 50% of the biogas is used to produce electricity by the use of electricity.
• a co-generation engine the remaining biogas feeding a conventional boiler for produce for the most part the thermal fluid to obtain the pressure and temperature conditions necessary for carrying out the hydrolysis.
• said digestion means comprise a digester having at least one inlet and one outlet, said outlet communicating with said inlet of said hydrolysis means and said inlet communicating with said outlet of said hydrolysis means.
• said digestion means comprise a primary digester and a secondary digester, said primary and secondary digesters each having an inlet and an outlet, the inlet of said primary digester communicating with said sludge feed means, the outlet said primary digester communicating with the inlet of said hydrolysis means, the inlet of said secondary digester communicating with the outlet of said hydrolysis means.
• an installation according to the invention comprises second liquid-solid separation means arranged at the outlet of said secondary digester.
• an installation according to the invention comprises defibration means arranged between said digester and said separation means or between said primary digester and said first separation means.
• the defibration means are placed upstream of said primary digester or digester.
• said co-generation engine has an exhaust line opening into an air-water heat exchanger having a steam discharge outlet connected to said thermal hydrolysis means.
• FIG. a diagram of a first embodiment of an installation according to the invention
• FIG. 2 illustrates a diagram of a second embodiment of an installation according to the invention
• Figures 3 and 4 are graphs showing the sugar content of sludge respectively before and after the first digestion
• the invention relates to a sludge treatment method.
• sludge comprises primary sludge, secondary sludge and in particular mixed sludge.
• the general principle of the invention is based on the combined implementation of a first digestion, a thermal hydrolysis and a second sludge digestion.
• the first digestion makes it possible to degrade, at least in large part, the easily fermentable fraction of the sludge and to produce a difficultly fermentable digestate.
• Thermal hydrolysis is then implemented only to treat the difficultly fermentable fraction of the sludge.
• the thermal hydrolysis is conducted to treat all the sludge, that is to say both the fermentable part that difficultly fermentable part.
• the energy required for carrying out the thermal hydrolysis according to the invention is less than that required for carrying out the thermal hydrolysis according to the prior art.
• Thermal hydrolysis is used to degrade the digestate resulting from the primary digestion which consists of the difficultly fermentable fraction of the sludge and to produce a hydrolyzed digestate consisting of easily fermentable sludge.
• the second digestion then allows to digest these fermentable sludge and to produce a digestate free, at least in large part, of fermentable fraction and containing only a small refractory non-fermentable portion.
• FIG. 1 an embodiment of a sludge treatment plant according to the invention is presented.
• such an installation comprises digestion means comprising a primary digester 10 and a secondary digester 11.
• the primary digester 10 has an input and an output.
• the inlet is connected to means for supplying sludge to be treated constituted by a pipe 12.
• the outlet opens into first liquid-solid separation means 13 and allows to pour a first digestate therein.
• the first liquid-solid separation means 13 comprise a centrifuge making it possible to reach a dryness greater than or equal to 12%. Alternatively, any other equivalent means may be implemented for this purpose such as membranes.
• These first separation means 13 have means for discharging a first effluent comprising a pipe 14 and means for discharging the first dewatered digestate comprising a pipe 15. This pipe 15 opens into thermal hydrolysis means 16.
• the thermal hydrolysis means 16 comprise a reactor operating under conditions of pressure and temperature controlled so as to achieve the conditions of carrying out thermal hydrolysis.
• the thermal hydrolysis means used may be those described in the international patent application bearing the number WO-Al-02064516 filed in the name of the Applicant.
• the thermal hydrolysis means 16 have a discharge outlet of a hydrolyzed digestate which opens into the secondary digester 11.
• the secondary digester 11 has an input and an output.
• the inlet is connected to the outlet of the thermal hydrolysis means 16.
• the outlet opens into second liquid-solid separation means 17 and allows to pour the hydrolyzed digestate therein.
• the second separation means 17 are advantageously similar to the first separation means 13. They have means for evacuating a second effluent comprising a pipe 18 and means for discharging a dehydrated digestate comprising a pipe 19. alternatively, these second separation means may be replaced by sludge treatment means for example by wet oxidation.
• the first and second separation means may consist of band filters, filtration membranes, electro-osmosis means ... without necessarily being identical.
• the primary and secondary digesters 11 are connected to biogas recovery means. These biogas recovery means comprise a collector 20.
• the collector 20 is connected to means for generating steam and electricity.
• the steam generating means comprise a co-generation engine 21. This engine is connected to an alternator which it is capable of animating in order to produce electricity.
• This engine has an exhaust line 22 which opens at the entrance of an air-water heat exchanger 23.
• the heat exchanger 23 has two inputs: an inlet through which heat produced by the cogenerator 21 via the pipe 22; an inlet into which a water supply pipe 24 opens.
• the vapor discharge outlet 25 is connected, via a pipe 27, to the thermal hydrolysis means 16.
• this installation comprises defibration means 28 which are arranged between the primary digester 10 and the first liquid-solid separation means 13.
• defibration means 28 comprise a mechanical grinder.
• defibration means 28 may comprise any other equivalent means for mechanically degrade the first digestate from the first digester 10, that is to say to remove the non-biodegradable fibrous fraction.
• Defibering means known to those skilled in the art are described in the international patent application bearing the number
• the defibration means 28 may be arranged upstream of the primary digester.
• an exchanger will be provided between the hydrolysis means 16 and the secondary digester 11 so as to cool the sludge coming out of the means of hydrolysis to achieve the temperature conditions necessary for secondary digestion.
• Such an installation comprises a single digester 30.
• This digester 30 has a first inlet which is connected to a sludge supply line 31 to be treated. a digestate that is connected to a pipe
• Line 32 opens into liquid-solid separation means 33.
• the liquid-solid separation means 33 have a structure identical to that of the liquid-solid separation means implemented in the first embodiment. These separation means 33 have means for discharging an effluent which comprise a pipe 34 and means for discharging a dehydrated digestate which comprise a pipe 35. This pipe 35 opens into thermal hydrolysis means 36.
• the thermal hydrolysis means 36 are similar to the hydrolysis means used in the first embodiment. They have an evacuation outlet of the hydrolyzed digestate which is connected by a pipe 37 to a second inlet of the digester 30.
• the digester 30 is connected to biogas recovery means. These biogas recovery means comprise a pipe 38. This pipe 38 is connected to means for generating steam and electricity. Line 35 communicates with a treated sludge discharge line 47.
• the means for producing steam comprise a co-generation engine 39.
• This engine is connected to an alternator that it is capable of animating in order to produce electricity.
• This engine has an exhaust line 40 which opens at the entrance of an air-water heat exchanger 41.
• the heat exchanger 41 has two inputs: an inlet through which heat produced by the cogenerator 39 arrives via the pipe 40; an inlet in which opens a water supply line 42. It also has two outputs: an outlet 43 for the evacuation of water vapor; an outlet 44 for the evacuation of fumes.
• the outlet 43 for steam evacuation is connected, via a pipe 45, to the thermal hydrolysis means 36.
• the installation according to this second embodiment comprises deflashing means 46 which are arranged between the digester 30 and the liquid-solid separation means 33.
• deflashing means 46 comprise a mechanical grinder or any other equivalent means allowing to mechanically degrade the digestate. In another variant, they may be placed upstream of the digester.
• an exchanger will be provided between the hydrolysis means
• Example of a first embodiment of a method according to the invention A first embodiment of a sludge treatment method according to the invention is presented with reference to FIG.
• sludge to be treated is conveyed to a primary digester 10 so that it undergoes a primary digestion step.
• the duration of this digestion is about 10 days. In variants, it may be between 5 and 15 days.
• this digestion there is produced: a reduction of the fermentable fraction of the sludge and consequently a reduction of the dry matter to be treated; biological hydrolysis of some non-fermentable minerals (such as nitrogen and phosphorus); an elimination of a large quantity of sugars contained in the sludge
• FIGS. 3 and 4 illustrate the sugar content of the sludges respectively before and after the implementation of the first digestion); the generation of organic materials that are not or only slightly biodegradable, such as COD and refractory nitrogen; the solubilization of volatile fatty acids.
• the fermentable fraction of the sludge was digested so that the first digestate discharged at the outlet of the primary digester 10 consists essentially of the non-fermentable fraction of the sludge.
• This first digestate is conveyed to the first liquid-solid separation means 13.
• the activation of these separation means allows the implementation of a liquid-solid separation step which leads to the production of: a first effluent which flows through line 14; - A first dehydrated digestate having a dryness greater than 12%.
• the dryness of the sludge corresponds to its dry matter content calculated by subtracting 100% the moisture content of the sludge.
• the first effluent is rich in little or no biodegradable soluble compounds formed during primary digestion.
• These compounds can be: inorganic and resulting from the solubilization of nitrogen or phosphorus; created by organic compounds such as COD and organic nitrogen
• the first dehydrated digestate is conveyed inside the thermal hydrolysis means 16 in order to undergo a thermal hydrolysis step with water vapor.
• the thermal hydrolysis is carried out at a temperature of 165 ° C., at the saturation vapor pressure, for 30 minutes.
• the hydrolysis will be carried out at a pressure of between 1 and 20 bar, at a temperature of between 120 ° C. and 180 ° C., for between 20 and 120 minutes.
• the volume of the hydrolysis means is reduced by approximately 20 to 50% and the more often about 40% compared to that of the hydrolysis means implemented in the prior art technique.
• liquid-solid separation undergone by the first digestate allows the evacuation within the first effluent of little or no bio logically degradable bio-solubilized products logically during the primary digestion, the quantity of these products which is treated during thermal hydrolysis is reduced.
• the reduction of the amount of sugar in the hydrolysed sludge thanks to the first digestion step makes it possible to reduce the production of Maillard compounds, contributing to the production of hard COD, in the thermal hydrolysis step.
• the Maillard reaction involves reducing sugars and proteins at a temperature above 120 0 C involving the formation, inter alia, soluble compounds hardly biodegradable.
• thermal hydrolysis leads to the production of soluble organic compounds with little or no biodegradability, these are produced in relatively small amounts.
• the successive implementation of the primary digestion, the separation and the thermal hydrolysis thus leads to the production of a smaller quantity of soluble organic compounds which are not or only slightly biodegradable than that which is produced during the implementation.
• successive thermal hydrolysis and digestion according to the technique of the prior art.
• the first dehydrated digestate, rendered fermentable by the thermal hydrolysis treatment, is conveyed to the secondary digester 11 in order to undergo a second digestion step for 10 days. In variants, this duration may vary from 7 to 15 days.
• Soluble or not biodegradable soluble compounds produced during primary digestion tend to disadvantage second digestion.
• the prior elimination of these products which makes it possible to limit the amount of soluble compounds that are hardly or not biodegradable, produced during hydrolysis, makes it possible to increase the yield of the second digestion.
• the second digestion leads to the production of a second digestate free, at least in large part, fermentable fraction and containing a difficultly biodegradable refractory part, and a small amount of soluble organic compounds little or no biodegradable.
• This mixture is conveyed to the second separation means in order to undergo a liquid-solid separation step 17 so as to produce: a second effluent which flows through the pipe 18; a second dehydrated digestate.
• the second digestate free of fermentable fraction, at least in large part, can be revalorized.
• the digested sludge constituted by this second digestate may for example be dehydrated and then discharged or sent to another processing step such as a wet oxidation step.
• Thermal hydrolysis processes have been implemented to improve the dewaterability of sludge by thermal pretreatment.
• Thermal hydrolysis of the digestate from the first digestion step also improves the dewaterability of the sludge.
• the implementation of an additional digestion makes it possible to improve from 1 to 2% the dehydratability of digested sludge compared to raw sludge.
• the level of dehydration that can be reached on raw sludge varies from 19 to 25%; on digested sludge ranges from 21 to 30%; on hydrolysed sludge ranges from 29 to 40%.
• the second effluent is rich in soluble organic compounds with little or no biodegradability produced during secondary digestion.
• the first and second effluents can also be upgraded or recirculated at the head of a water treatment plant whose implementation leads to the production of sludge that is treated by the process according to the invention. Given that the readily biodegradable soluble compounds are produced during the implementation of the process in small quantities compared to the technique according to the prior art, this recycling has a reduced impact on the treated water produced.
• the implementation of the first and second digestion stages is accompanied by the production of biogas.
• a recovery step collects these biogas to undergo a conversion step in order to produce the steam required to perform the hydrolysis step and electricity. For this, the biogas is fed into the co-generation engine
• the fumes produced in exchanger 23 are discharged via line 26.
• sludge to be treated is conveyed into a digester 30 so that it undergoes a primary digestion step for about 10 days. In variants, it may be between 5 and 15 days.
• a primary digestion there occurs: a reduction of the fermentable fraction of the sludge and consequently a reduction of the dry matter to be treated; biological hydrolysis of some non-fermentable minerals (such as nitrogen and phosphorus); elimination of a large quantity of sugars contained in the sludge; the generation of soluble organic matter which is not or only slightly biodegradable, such as COD and refractory nitrogen; the solubilization of volatile fatty acids.
• the fermentable fraction of the sludge has been digested so that the digestate discharged at the outlet of the digester 30 essentially consists of the non-fermentable fraction of the sludge.
• This digestate is then conveyed to the separation means 33 in order to undergo a liquid-solid separation step.
• the implementation of these separation means allows the production of: an effluent flowing through the pipe 34; dehydrated digestate.
• the effluent is rich in soluble organic compounds that are little or not bio-logically produced during primary digestion. These compounds can be: inorganic and resulting from the solubilization of nitrogen or phosphorus; - created by organic compounds such as COD and organic nitrogen
• the dehydrated digestate is more concentrated so that its subsequent treatment requires the implementation of smaller equipment and generates lower energy consumption. All this tends to reduce the cost of sludge treatment.
• the dehydrated digestate is conveyed inside the thermal hydrolysis means 36 to undergo a thermal hydrolysis step with water vapor.
• the thermal hydrolysis is carried out at a temperature of 165 ° C., at the saturation vapor pressure, for 30 minutes. In variants, the hydrolysis will be carried out at a pressure of between 1 and 20 bar, at a temperature of between 120 ° C. and 180 ° C., for between 20 and 120 minutes.
• the volume of the hydrolysis means is reduced by approximately 20 to 50% and most often about 40% compared to that of the hydrolysis means used in the prior art technique.
• only the non-fermentable portion of the initial sludge undergoes thermal hydrolysis treatment. As a result, the amount of energy required for its production is also significantly reduced.
• the reduction in the amount of sugar in the hydrolysed sludge thanks to the first digestion step makes it possible to reduce the production of Maillard compounds, contributing to the production of hard COD, in the thermal hydrolysis stage.
• the Maillard reaction involves reducing sugars and proteins at a temperature above 120 0 C involving the formation, inter alia, solubility compounds difficult to biodegradable.
• thermal hydrolysis leads to the production of soluble organic compounds with little or no biodegradability, these are produced in relatively small amounts.
• the successive implementation of the primary digestion, the separation and the thermal hydrolysis thus leads to the production of a smaller quantity of soluble organic compounds which are not or only slightly biodegradable than that which is produced during the implementation.
• the dehydrated digestate rendered fermentable by the thermal hydrolysis treatment, is recirculated to the digester 30 where it is mixed with fresh sludge for further digestion.
• the digestion that then occurs is in fact the combination of a first digestion of the fresh sludge and a second digestion of the previously digested and hydrolysed sludge, this combination making it possible to reduce the fermentable portion of the mixture of sludge and digested sludge and leading to the production of a mixture of digestates free, at least in large part, fermentable fraction, and containing a difficult refractory fermentable portion and a small amount of soluble organic compounds little or no biodegradable.
• the portion of digestate introduced into the hydrolysis means is 100%. In other words, all the digestate obtained at the outlet of the digester undergoes the hydrolysis treatment. In variants, the rate of Recirculation of the digestate in the hydrolysis means may vary between 30% and 300%.
• This digestate mixture is conveyed to the separation means 33 in order to undergo a liquid-solid separation step so as to produce, as described above: an effluent flowing through the pipe 34; a dehydrated digestate.
• the process is accomplished by making at least one loop, ie carrying out a digestion of previously digested and hydrolysed sludge. A portion of the digestate obtained after treatment, that is to say after completion of at least one loop is discharged via line 47 to be upgraded.
• This digestate may for example be dehydrated and then discharged or sent to another treatment stage such as a wet oxidation step.
• Thermal hydrolysis processes have been implemented to improve the dewaterability of sludge by thermal pretreatment.
• Thermal hydrolysis of the digestate from the first digestion step also improves the dewaterability of the sludge.
• the implementation of an additional digestion makes it possible to improve from 1 to 2% the dehydratability of digested sludge compared to raw sludge.
• the level of dehydration that can be reached: on raw sludge varies from 19 to 25%; on digested sludge ranges from 21 to 30%; on hydrolysed sludge ranges from 29 to 40%.
• the collected effluent is rich in soluble organic compounds with little or no biodegradability produced during secondary digestion. It can also be upgraded or recirculated at the head of a water treatment plant whose implementation leads to the production of sludge that is treated by the method according to the invention. Considering that the easily biodegradable soluble compounds are produced during the implementation of the process in small quantities compared to the technique according to the prior art, this recycling has a reduced impact on the treated water produced.
• the implementation of the first and second digestion stages is accompanied by the production of biogas.
• a recovery step collects these biogas to undergo a conversion step in order to produce the steam required to perform the hydrolysis step and electricity.
• the biogas are fed into the co-generation engine 39.
• the implementation of this engine allows to animate the alternator to which it is connected in order to produce electricity.
• the exhaust gases from this engine are fed into the exchanger 41 inside which water circulates in order to produce steam.
• the steam thus produced is conveyed to the thermal hydrolysis means 36 via line 45 so as to allow the realization of the thermal hydrolysis step of the first dehydrated digestate.
• the fumes produced in the exchanger 41 are discharged via the pipe 44.
• the digestions used in the technique according to the invention are anaerobic digestions.
• the anaerobic digestion may be of mesophilic or thermophilic types.
• the temperature at which mesophilic digestion is performed is between 32 and 38 ° C.
• the temperature at which a thermophilic digestion is carried out is between 52 and 58 ° C.
• the input concentration of a first digester is advantageously between 25 and 65 grams of feedstock (MES) per liter of sludge.
• the input concentration of a second digester is advantageously between 100 and 150 grams of feedstock (MES) per liter of sludge.
• the characteristics of each of the digestions may be different.
• one or more of the digestions used are of the aerobic type.
• the digestions used may be of the aerobic type.
• the methods according to the invention described above may include a step consisting of subjecting the sludge before a first digester (first or only) or the first digest to a de-icing step by using the defibbler. or 46.
• the sludge comprises a fibrous fraction very difficult to biodegrade under conventional anaerobic digestion conditions. At the outlet of the digester, this fraction can represent between 30 and 60% of the organic matter present in the digestate. This fraction is hardly attacked by thermal hydrolysis.
• the implementation of the defibration makes it possible in particular to reduce the viscosity of the sludge, which advantageously has a dryness greater than 30% after defibration.
• the defibration thus makes it possible: to make possible the treatment of sludge which the person skilled in the art considers to be impossible by the implementation of the technique according to the prior art; to reduce the size of the digester placed upstream or downstream, or to increase the residence time of the other organic fractions of the sludge (indeed, at the same size of digester, the defibration makes it possible to reduce the fibrous fraction and thus the amount of dry matter entering the digester, which leads to increase the residence time).
• the first liquid-solid separation may be implemented between the thermal hydrolysis and the second digestion. 7.7. Energy gains
• the biogas produced during the digestion that follows the thermal hydrolysis is used as follows: at least 50% of the biogas produced feeds a boiler to produce the steam necessary for hydrolysis; the remaining biogas feeds a co-generation engine, which is associated with an alternator so as to produce electricity that can be used for a purpose other than that of the implementation of the method.
• the heat of the co-generation engine exhaust can be recovered to produce a portion of the steam required for thermal hydrolysis. This reduces to 35 to 40% the share of biogas used to produce steam by the implementation of a conventional boiler.
• the heat generated by the co-generation engine can also be recovered to preheat the water required for steam production. This reduces to 30 to 35% the share of biogas used to produce steam by the implementation of a conventional boiler.
• an optimal implementation of the technique according to the prior art makes it possible to use between 65 and 70% of the biogas produced by the digestion to produce energy that can be used for purposes other than that of the implementation of the sludge treatment process.
• the digestate from the primary digestion contains only between 60 and 80% of the dry matter contained in the initial sludge.
• the digested sludge has a lower viscosity than raw sludge, with an equal content of dry matter. This facilitates the increase in the dryness of the digestate obtained after the first liquid-solid separation step.
• the amount of sludge treated by thermal hydrolysis according to the invention is significantly lower than that treated by thermal hydrolysis according to the prior art.
• the thermal requirements for the hydrolysis being proportional to the amount of dry matter to be hydrolysed, the implementation of the invention makes it possible to reduce these thermal requirements by 30 to 40%.
• the implementation of the invention makes it possible to increase up to 20% the amount of biogas formed during the two digestions according to the types of sludge admitted and their residence time in the digesters.
• the temperature of the digestate feeding the hydrolysis means is approximately equal to 35 ° C or 55 ° C depending on whether the digestion from which it is derived is mesophilic or thermophilic.
• the implementation of the invention reduces by about 40 to 55% the steam requirement for thermal hydrolysis compared to the technique according to the prior art. This requirement can therefore be fully covered by the steam obtained from the heat recovered from the engine exhaust of the co-generator. Under these conditions, almost all of the biogas produced during the digestions can allow the production of electrical energy that can be used for purposes other than the simple implementation of the sludge treatment process. A small amount of the biogas produced, however, can be used to produce steam at the start of treatment.
• the digestate feeding the hydrolysis reactor may be reheated by mixing it, at the outlet of the separation means, with hot water produced from the heat recovery either on the hydrolysed sludge at the output of the hydrolysis reactor, or on the coolant and the co-generator engine oils, or both; sludge feeding the first digester can be reheated by mixing with hot water produced from the recovery of heat on the hydrolysed sludge output of the hydrolysis reactor.
• the sludge feeding the second digester can be mixed with water to obtain optimal dryness to improve the performance of the second digestion.
• the concentration of MES sludge at the inlet of the digester is limited to 100 to 130 g / 1. Indeed, the nitrogen present in the sludge is converted into NH 3 during digestion, NH 3 constituting an inhibitor compound for digestion. It is therefore necessary to limit the concentration
• the first digestion according to the invention makes it possible to significantly reduce the amount of nitrogen contained in the sludge.
• Thermal hydrolysis of the sludge tends to reduce their viscosity, it is possible to increase the concentration of MES sludge input of the secondary digester up to values included between 110 and 160 g / l. This sludge can therefore be mixed with water to achieve such a concentration of MES.
• the digestate feeding the hydrolysis reactor may be reheated by mixing it, at the outlet of the separation means, with water hot produced from the recovery of heat either on the hydrolysed sludge at the output of the hydrolysis reactor, or on the coolant and the co-generator engine oils, or both;
• the sludges feeding the first digester can be reheated by mixing them with hot water produced from heat recovery either on the hydrolysed sludge at the outlet of the hydrolysis reactor, or on the cooling liquid and the oils of the co-generator motor, or both.

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