EP2377423A1 - Vorrichtung und Verfahren zum Aufbringen einer Flüssigkeit auf einer Komponente - Google Patents

Vorrichtung und Verfahren zum Aufbringen einer Flüssigkeit auf einer Komponente Download PDF

Info

Publication number
EP2377423A1
EP2377423A1 EP11161181A EP11161181A EP2377423A1 EP 2377423 A1 EP2377423 A1 EP 2377423A1 EP 11161181 A EP11161181 A EP 11161181A EP 11161181 A EP11161181 A EP 11161181A EP 2377423 A1 EP2377423 A1 EP 2377423A1
Authority
EP
European Patent Office
Prior art keywords
fluid
applicator
component
brush
etchant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11161181A
Other languages
English (en)
French (fr)
Inventor
Daniel Clark
David William Mills
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rolls Royce PLC
Original Assignee
Rolls Royce PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rolls Royce PLC filed Critical Rolls Royce PLC
Publication of EP2377423A1 publication Critical patent/EP2377423A1/de
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B13/00Brushes with driven brush bodies or carriers
    • A46B13/02Brushes with driven brush bodies or carriers power-driven carriers
    • A46B13/04Brushes with driven brush bodies or carriers power-driven carriers with reservoir or other means for supplying substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/02Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to separate articles
    • B05C1/027Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to separate articles only at particular parts of the articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/06Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length by rubbing contact, e.g. by brushes, by pads
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/02Local etching
    • C23F1/04Chemical milling
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/08Apparatus, e.g. for photomechanical printing surfaces
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/20Brushes for applying products to surfaces in general

Definitions

  • the present invention relates to an apparatus and method for applying a fluid to a component.
  • the invention is particularly but not exclusively related to an apparatus and method for applying a chemical etchant to a target area of a component.
  • Chemical etching is a commonly used technique for removing one or more surface layers from a metallic component.
  • An acid, base, or other chemical etchant fluid is applied to an area of a component for a period of time and dissolves a surface layer of the component.
  • Various methods may be used to bring the etchant fluid into contact with the component.
  • One known method involves filling a large tank with etchant fluid and immersing a component in the fluid.
  • Masking material may be used to prevent the etchant fluid removing a surface layer from the entirety of the component.
  • Etch tanks may have a negative environmental impact, as well as being inefficient and costly to run. They may also produce large quantities of gas and fluid emissions. Specialist disposal of used and waste product is required, increasing maintenance and running costs. Additional finishing operations are also often required to counteract the effects of the etchant fluid where etching was not required, even when a suitable masking material is used.
  • Swab etching Another known method of applying etchant fluid to a component is "swab etching", where a liquid etchant is painted on to a surface of a component for a given time. This often results in unsightly and inconvenient "runs" of etchant fluid straying into areas where surface etching was not required. Swab etching is also a comparatively labour intensive method of surface etching, involving close operator contact with hazardous chemicals
  • Etchant fluids may be heated or subjected to ultraviolet stimulation to increase etch rate.
  • ultraviolet stimulation to increase etch rate.
  • these practices involve high capital cost as well as increased labour and etchant response is subject to line of sight and illumation issues
  • a particularly difficult problem in surface etching is the removal of material from fine surface features such as are found in laser cut, machined or welded surfaces and the interfaces between such surfaces.
  • Weld contours, particularly in root and toe regions, present difficulties for the manipulation of line of sight based material removal processes.
  • Welds constitute points of material micro structural variation and it is therefore undesirable to unduly thin a weld region or to introduce additional stresses through machining.
  • apparatus for applying a fluid to a target area of a component comprising a fluid applicator and means for guiding the fluid applicator along a predetermined path with respect to the component;
  • the fluid applicator comprising a body, an application head mounted on the body and operable in use to be brought into physical contact with the component, and means for controlling the temperature of the fluid to be applied to the component.
  • the fluid may be any one of a chemical etchant, scale conditioner, washing fluid and/or neutralising solution.
  • the fluid may be of increased viscosity and may be a paste or gel.
  • the paste may be thixotropic.
  • the body may be formed from a deformable material.
  • the body may thus accommodate variations in surface geometry of the component such as convex and concave regions, edge regions and re-entrant features.
  • the application head may comprise a brush having a brush head and a plurality of agitators which may be bristles or fins.
  • the agitators of the brush act to scrub a component surface, forcing etchant fluid into fine surface features and also removing unwanted fluid from such features.
  • the brush head may comprise an opening, suitable to deposit or collect fluid.
  • the apparatus may further comprise means to apply positive and/or negative pressure at the opening.
  • the brush head may comprise at least two such openings and the apparatus may further comprise means to apply positive pressure at one opening and negative pressure at another opening.
  • the openings may comprise two or more independent sections of a single orifice, thus allowing simultaneous deposition and collection of fluid.
  • the apparatus may comprise means for controlling the temperature of the fluid to be applied to the component. It may be desirable for the fluid to be delivered at a raised temperature or at a controlled ambient temperature, according to the particular fluid to be applied.
  • the brush may be mounted for rotation about an axis that is substantially parallel to a surface of the body on which it is mounted, a surface of the brush head from which the agitators project being substantially cylindrical. In this manner, the brush may pass over the component surface in a manner similar to that of a vacuum cleaner, the agitators scouring the component surface.
  • the plurality of agitators may project from the surface of the brush head in a helical pattern that winds about the brush head.
  • the plurality of agitators may project from the surface of the brush head in at least one chevron pattern, which may be formed about the at least one opening of the brush head.
  • the brush may be mounted for rotation about an axis that is substantially normal to a surface of the body on which it is mounted, a surface of the brush head from which the agitators project being substantially planar.
  • the brush may comprise at least two regions, the regions being operable to rotate in different directions.
  • the regions may be concentric.
  • the plurality of agitators may project from the planar surface in a spiral configuration.
  • the length and stiffness of the agitators may vary across the brush.
  • the brush may comprise regions of different length and/or stiffness agitators.
  • the brush may be mounted for rotation in both clockwise and anticlockwise directions.
  • the agitators of the brush head may comprise bristles or they may comprise fins.
  • a plurality of brushes may be mounted for rotation on the body of the fluid applicator about parallel axes.
  • At least two of the plurality of bushes may comprise different agitator configurations.
  • the means for guiding may comprise a mechanical manipulation arm on which the fluid applicator may be operable to be mounted.
  • the means for guiding may comprise a track, along which the fluid applicator may be operable to be driven.
  • the track may be formed from a deformable material and may be assembled into a frame.
  • the track may comprise a racked surface/rack and pinion arrangement.
  • the means for guiding may further comprise means for manipulating the component.
  • a method of applying a fluid to a target region of a component using an apparatus of the first aspect of the present invention comprising connecting a fluid supply to the fluid applicator, mounting the fluid applicator on the means for guiding the applicator along a predetermined path, bringing the applicator head into physical contact with the target region of the component, causing the applicator to be guided along the predetermined path while depositing fluid through the applicator from the fluid supply, and controlling the temperature of the fluid to be applied to the component.
  • the fluid may be any one of a chemical etchant scale conditioner, washing fluid and/or neutralising solution.
  • the fluid may be of increased viscosity and may be a paste or gel.
  • the paste may be thixotropic.
  • the means for guiding may comprise a mechanical manipulation arm and the method may further comprise programming the mechanical manipulation arm to move the applicator such that the applicator traces the predetermined path along the component.
  • the method may further comprise mounting the component for rotation.
  • the means for guiding may further comprise means for manipulating the component, the method may further comprise mounting the component on the means for manipulating the component, and the various means for guiding may cooperate to cause the applicator to be guided along the predetermined path.
  • Depositing fluid through the applicator may comprise applying pressure to the fluid at a fluid opening in the application head. Depositing fluid through the applicator may also comprise causing the application head to rotate.
  • the method may further comprise collecting fluid under a negative pressure applied at the opening in the application head.
  • the method may further comprise controlling the temperature of the component.
  • the method may further comprise heating and/or cooling the component.
  • a chemical etchant comprising titanium dioxide as a thickening agent.
  • the viscosity of the etchant may be above that of the constituent etchants and more specifically between 400 - 7500 cP.
  • Viscosity enhancing media may also include inert oxide powders or gels.
  • an applicator for depositing a fluid on a component surface comprising a body, a brush mounted for rotation on the body, the brush comprising a brush head and a plurality of bristles and a fluid passage extending through the brush head and comprising at least one opening that communicates with a bristled surface of the brush head.
  • the fluid may comprise etchant, detergent containing wash fluid, scale conditioner or neutralising agents.
  • the fluid passage may comprise two sub passages, operable to be brought into communication with each other.
  • the present invention relates to an apparatus and method for applying a fluid such as a chemical etchant to a target area of a component.
  • a weld line as a target feature of a component, an area of which may be appropriate for chemical etching.
  • Figure 1 illustrates a typical weld line 2, such as might be found on a metallic drum assembled using electron bean welding, around which is a heat affected zone 4. If the drum is produced from titanium, an alpha case layer can occur within the heat affected zone 4. This layer is understood to be an oxygen enriched surface layer of titanium that acts to reduce the fatigue life of the component.
  • a locally applied chemical etchant including for example Nitric, Hydrofluoric, Hydrochloric or Hydroflourosilic acids.
  • the etchant is applied over a target area 8 that includes the weld line 2, the heat affected zone 4 and a safety zone 6.
  • a target area 8 that includes the weld line 2, the heat affected zone 4 and a safety zone 6.
  • One aspect of the present invention involves the development of a particularly advantageous chemical etchant for use with the apparatus and method of the invention.
  • Known etchant combinations such as those employing Hydroflourosilic acid with Nitric acid or Hydrofluoric acid with Nitric acid are enriched with Titanium Dioxide.
  • TiO 2 acts as a thickening agent, increasing the viscosity of the etchant to that of a paste.
  • Water based gel and other inert oxide powders may also be employed as a thickening agent to achieve the required viscosity, at which the paste will substantially adhere to a component surface, and will not run along the surface. It is a requirement of the etchant paste that it must remove a controlled and uniform layer of between 0.5 and 15.0 ⁇ m. Certain applications may require removal of a layer of up to 75.0 ⁇ m.
  • an apparatus 5 for applying a fluid to a target area of a component comprises a fluid applicator 10 and means for guiding the fluid applicator along a predetermined path (partially illustrated at 12).
  • the fluid applicator 10 comprises a body 14 and two pairs 16, 18 of application heads in the form of brushes.
  • the brushes are mounted on the body 10 for rotation about parallel axes 20, 22, each of which extends substantially normally to the surface 24 of the body 10 on which the brushes are mounted.
  • the apparatus is brought into proximity with a component 26, a target area of which is to have etchant fluid applied.
  • the means for guiding the fluid applicator 10 causes the applicator to advance towards the component (indicated at arrow 27) such that the brushes are brought into physical contact with a surface 28 of the component 26.
  • Relative motion between the fluid applicator 10 and the component 26 is brought about, as indicated by arrows 29, and the fluid applicator 10 deposits a layer of etchant fluid 30 on the surface 28 of the component 26.
  • the fluid applicator 10 will pass over the surface of the component 26 at least once to deposit etchant fluid 30 and at least once to remove etchant fluid 30.
  • the fluid applicator 10 will make at least two passes over the surface of the component 26, at least one of the passes being to apply etchant fluid 30, and at least one of the passes to remove etchant fluid 30.
  • the fluid applicator 10 may also pass over the surface of the component 26 to agitate the etchant fluid 30. Further detail of the process by which etchant fluid is supplied to the fluid applicator and depositing on the surface are discussed below.
  • FIG. 3 shows expanded sectional and side views of the fluid applicator 10 in contact with the component 26.
  • Each pair 16, 18 of applicator heads comprises two brushes 32, 34, 36, 38, each of which is mounted for independent rotation.
  • An optional extra pair of application heads 40 is illustrated in the sectional view. Further detail of this and other configuration options for the applicator heads is discussed below.
  • each brush 32, 34, 36, 38 in each pair 16, 18 of brushes rotates in an opposite direction.
  • the leading pair 16 of brushes 32, 34 rotate inward with respect to each other and the direction of advance, from right to left across Figure 3 .
  • each pair 16, 18 of brushes may be replaced by a single brush, positioned along the centre line of the target area, in this case the weld line 3.
  • Each single brush may rotate clockwise or anticlockwise as required.
  • FIG. 4a illustrates a sample application head in the form of a brush 50, which may be representative of any of brushes 32, 34, 36, 38 described above.
  • the brush 50 comprises a brush head 52 and a plurality of agitators 54.
  • the agitators may be bristles, as illustrated, or may take the form of fins.
  • the following description refers to agitators in the form of bristles 54, but it will be appreciated that the description could equally be applied to agitators 54 in the form of fins.
  • the bristles 54 project from the brush head 52 to define a domed brush periphery, the furthest extent of which is brought into contact with the surface 28 of the component 26 by a comparatively light force F 1 . This light force results in a relatively small contact area A 1 between brush bristles 54 and component 26 at the component surface 28.
  • the bristles 54 of the brush 50 are relatively flexible and may be deformed as illustrated in Figures 4b and 4c .
  • a larger force F 2 may be applied to the brush 50, deforming the longest bristles and bringing more of the domed periphery 56 into contact with the component surface 28, resulting in a larger contact area A 2 .
  • a larger force still F 3 may be applied, as illustrated in Figure 4c , resulting in a further increased contact area A 3 .
  • the difference in contact area that can be achieved is illustrated in Figure 5 .
  • the target area over which etchant fluid is applied can thus be varied according to requirements.
  • Deformable bristles having a domed periphery as illustrated may also be particularly applicable for certain geometries of feature within the target etch area. For example, certain weld geometries may be suited to longer, deformable bristles such as those illustrated in Figure 4a .
  • Figures 6, 7 and 8 illustrate bristle configuration options for brush 50.
  • the plurality of bristles 54 may define a rectangular, planar brush, as illustrated in Figure 6 , a domed brush, as illustrated in Figures 4a and 7 , or the bristles may define a brush having concentric annular steps, as illustrated in Figure 8 .
  • the strength and type of bristle may also vary within the brush head.
  • the brush 50 may comprise an inner core of short, firm bristles 56, a concentric ring of longer, medium strength bristles 58 and an outer surrounding concentric ring of longer soft bristles capable of increased deformation.
  • Such variation in bristle length and strength results in a progressive scrubbing effect. Varying the separation between the fluid applicator 10 (and hence brush 50) and the component surface 28 not only alters the deformation of the softer outer bristles but may also determine the thickness of the fluid etchant layer deposited on the surface.
  • a single brush 50 may include contra-rotating or oscillating sections, as illustrated in Figures 9 and 10 .
  • An inner core 56 of stiff bristles may rotate in a different direction to an intermediate ring 58, which in turn is rotating in a different direction to the radially outer ring 60.
  • Such contra-rotation or oscillation provides increased agitation to the etchant fluid being dispensed, improving the mixing of titanium ions from the substrate into the solution and thus assisting with the surface layer removal process.
  • contra-rotating or oscillating sections help to ensure that bristles contact all the variable surface geometry and undulating features associated with surface finishes such as welds.
  • Figure 12 illustrates an advantageous arrangement of brushes on a body of a fluid applicator 10 comprising eight separate brushes.
  • a first stage brush 72 rotating in an anticlockwise direction.
  • the first stage brush 72 is a comparatively small brush with firm bristles, of the type illustrated in Figures 6 or 7 .
  • This brush covers the immediate weld pool 2 and the heat affected zone 4 with the firm bristles employed to scrub the zone while chemical reaction occurs, mechanically assisting the etching process.
  • Etchant fluid is fed through the centre of the brush 72 and the rotation of the brush 72 feeds the etchant fluid outwards under centrifugal forces.
  • Behind the first stage brush 72 is a pair of second stage brushes 74, 76.
  • the second stage brushes 74, 76 scrub the heat affected zone 4 and spread etchant fluid over the area to be treated.
  • Etchant fluid is fed through the centre of the brushes 74, 76 and the rotation of the brushes 74, 76 feeds the etchant fluid outwards under centrifugal forces.
  • the majority of the etchant fluid is deposited along the central line of the target area 8 as a result of the internal rotation of the second stage brushes 74, 76.
  • Behind the second stage brushes 74, 76 is a third stage brush 78.
  • the third stage brush 80 is also a comparatively small brush with firm bristles, of the type illustrated in Figures 6 or 7 .
  • This brush also covers the immediate weld pool 2 and the heat affected zone 4 with the firm bristles employed to scrub the zone while chemical reaction occurs, mechanically assisting the etching process.
  • Etchant fluid is fed through the centre of the brush 78 and the rotation of the brush 80 feeds the etchant fluid outwards under centrifugal forces.
  • Behind the third stage brush 78 is a pair of fourth stage brushes 80, 82. These are larger brushes comprising firm, medium and soft bristles, as illustrated in Figures 8 and 9 , and may include contra-rotating sections.
  • No etchant fluid is fed through the fourth stage brushes 80, 82, these brushes scrub and spread previously deposited etchant fluid over the area to be treated. At least the outermost rings of the fourth stage brushes rotate outwards with respect to each other and the direction of advance, so as to concentrate deposition of etchant fluid away from the centre areas and even the distribution.
  • a pair of fifth stage brushes 84, 86 are medium sized brushes of the type illustrated in Figures 8 and 9 , and comprise firm, medium and soft bristles.
  • No etchant fluid is fed through the fifth stage brushes 84, 86. These brushes spread and agitate the previously deposited etchant fluid, concentrating it from the outer regions to the central region.
  • the brushes do not in fact contact the surface of the component but are raised slightly, thus leaving a thin layer of etchant fluid where the bristles do not make contact (illustrated as area 90 on the Figure).
  • the separation between the fifth stage brushes 84, 86 is increased with respect to the earlier stage pairs so that the brushes extend slightly beyond the target area 8, collecting etchant fluid that has been spread by the fourth stage brushes 80, 82.
  • the fifth stage brushes also act to agitate etchant fluid over the outer reaches of the target area, helping to produce equal etchant effects over the entire area.
  • the combined effect of the five stages of brushes is to leave a fully agitated thin layer of etchant fluid over the entire target area 8, with a thicker deposited layer in the central region of the weld 2 and heat affected zone 4.
  • Figure 13 is a leading end view of the fluid applicator 10, described above with reference to Figure 12 , in position over the component 26.
  • the central first stage brush 72 can be seen partially obscuring the second stage brushes 74, 76.
  • the variable stiffness bristles of the second stage brushes 74, 76 deform whist rotating to scrub and adapt to the variable surface of the component while at the same time agitating the deposited etchant fluid to ensure thorough mixing.
  • Etchant fluid is deposited via the application head brushes as mentioned above.
  • a central opening in the brush head allows fluid etchant to be deposited, while the rotating action of the brush encourages spread of the fluid over the entire contact area.
  • Positive pressure may be applied to fluid at the opening to encourage deposition.
  • the same central opening may be used to collect spent etchant fluid, assisted by negative pressure or a vacuum applied at the opening.
  • Positive or negative pressure may be applied at the opening of a fluid conduit that is in communication with the opening and also with a fluid reserve and other external mechanisms.
  • a water feed may be incorporated to assist with the collection/cleaning of the component surface.
  • FIGS 14 and 15 are end views of an example brush 100, which may be representative of any of the fluid applicator brushes described above.
  • the brush 100 comprises bristles 102 that are arranged to form a spiral, graduating outwards from the central opening 104.
  • the brush rotates in a clockwise direction, as illustrated by arrow A in Figure 14 and Figure 15a .
  • the spiral configuration of the bristles assists the natural spreading motion of the clockwise rotation and encourages even distribution of the deposited fluid.
  • the brush 100 is rotated in an anti clockwise direction, as illustrated by arrow B in Figure 14 and Figure 15b .
  • the anti clockwise rotation of the spiral causes the outer most regions of the spiral to act as a scoop, colleting up the etchant fluid and conveying it into the spiral, towards the central opening where negative pressure is applied to suck the gathered fluid into the fluid conduit (not shown).
  • the bristles of the brush 100 may be of variable stiffness as discussed above but in a preferred example, the spiral arrangement bristles are all of a medium stiffness and uniform length. Such an arrangement assists in maintaining the spiral configuration, and thus improves the efficiency of the distribution/collection action of the bristles.
  • agitation of the etchant fluid while on the component surface assists with mixing and ensuring efficient material removal. Agitation ensures that a layer of depleted etchant fluid and evolved gaseous product from the etching reaction does not build up immediately adjacent to the component surface.
  • One desirable way of agitating and ensuring efficient surface removal is to cycle etchant fluid during the etch process. Continually depositing and collecting fluid ensures that the fluid remains well mixed and spent fluid is not allowed to accumulate. In addition, deposited fluid may be collected and reheated or cooled before being redeposited, thus ensuring the fluid retains optimal efficiency within predefined specification limits within the range 10-90°C.
  • FIG 16 illustrates an end and sectional view of a brush that may be employed to circulate etchant fluid, as well as depositing and/or collecting as necessary.
  • the brush 110 has a central opening that is divided into two independent sections for deposition and removal of fluid. It will be appreciated that while these sections may be in communication with each other at some external location, to allow for the cycling of etchant fluid, at the opening location they are independent, to allow positive pressure to be applied at the fluid outlet and negative pressure to be applied at the fluid inlet.
  • fluid etchant is fed out of the brush head through the outlet indicated at location 1 on the Figure.
  • Relatively firm bristles provide a path from the brush head to the component surface and centrifugal force encourages outward spreading of the etchant fluid once on the component surface.
  • Radially outwards of feed location 1 is a first clearing zone indicated at location 2.
  • the first clearing zone 2 receives fluid from the feed location 1 via centrifugal forces and relies upon such forces to spread the fluid as the brush rotates.
  • the bristles in the first clearing zone 2 are softer than those in the feed location 1 to allow spreading of fluid and scrubbing of complex surfaces.
  • Radially outwards of the first clearing zone 2 is a second clearing zone 3.
  • this area receives etchant from the first clearing zone 2 via centrifugal forces and relies on these forces to spread fluid as the brush 110 rotates.
  • the bristles in the second clearing area 3 are slightly firmer than those in the first clearing area, to ensure that only a controlled amount of etchant is passed into the radially outer removal zone 4.
  • the removal zone 4 also has no fluid feed but receives fluid spread from the second clearing zone under centrifugal forces.
  • the removal zone is bounded by a thick wall of fine, firm bristles that allow fluid in removal zone 4 to be evacuated under reduced pressure that is applied via the removal section of the central opening.
  • Figure 17 is a side view of a fluid applicator 10 having a body 14 in position on a component 26 and partially illustrating a means for guiding the fluid applicator, indicated at 12.
  • the body 14, on which application heads in the form of brushes are mounted, is made of a deformable material, for example a polymeric material and may be of different sizes or shapes depending on the component and/ or the geometry of the area to be treated.
  • the deformable material allows the body to adapt to different component surface geometries.
  • the means for guiding the fluid applicator 10 may have several attachment arms 120, 122, 124 by which it is connected to the body 14 of the fluid applicator 10.
  • Each of these attachment arms may be independently moveable or extendable to manipulate the body 14 of the fluid applicator 10 such that the application heads are maintained in precisely the desired spatial relationship with the component surface, no matter what the component surface geometry may be. For example, if the component surface has a distinct concave curve, the outer attachment arms 120, 124 may be retracted, forcing the body to deform into a convex shape to match the surface of the component. Any other surface geometry may be similarly accommodated by appropriate manipulation of the deformable body, ensuring that the application heads are maintained in physical contact with the component surface to deposit, agitate and collect fluid etchant as required.
  • each of the attachment arms may be independently extended, retracted and rotated or pivoted to manipulate the body 14 in the position and shape required.
  • the post 126 on which the attachment arms are supported may also rotate, and the attachment arms may be translated along the post. Further detail of the different embodiments of the means for guiding the fluid applicator 10 is discussed below with respect to Figures 22 to 24 .
  • FIGs 19 to 21 illustrate an alternative embodiment of application head in the form of a brush 200.
  • the brush 200 is mounted in a fluid applicator 10 as described above.
  • the brush 200 is designed to be mounted for rotation about an axis that runs substantially parallel to a mounting surface of the body 14 of the fluid applicator, substantially in the manner of a vacuum cleaner.
  • the brush 200 comprises a brush head 202 having a substantially cylindrical outer surface on which in mounted a plurality of bristles 204.
  • the plurality of bristles 204 is arranged to form a helix, winding about the brush head 202.
  • a plurality of openings 206 open onto the bristled surface of the brush head 202.
  • openings 206 perform the same function as the central openings discussed above with respect to the first described embodiment of application head.
  • the openings 206 permit deposition and collection of etchant fluid that may be provided to (as indicated at arrow 208) and/or removed from (as indicated at arrow 210) the brush 200.
  • Figure 20 illustrates how several of the brushes 200 may be mounted for rotation on a body 14 of a fluid applicator 10.
  • Alternating helical bristle configurations ensure even spread and distribution of a deposited layer of etchant fluid over the target area 8 of the component 26.
  • some or all of the openings may deposit fluid. Any bristles located adjacent an opening that is not depositing fluid assist the process by agitating already deposited fluid.
  • all or some of the bristles may be cause to rotate in the opposite direction, channelling spent fluid towards the openings that receive fluid under negative pressure.
  • the arrangement of the plurality of bristles 204 may be altered to specifically assist with fluid deposition and removal.
  • Figure 21 illustrates an alternative arrangement in which the plurality of bristles 204 are arranged in a series of chevrons, each chevron centred upon an opening in the brush head surface.
  • the brush head rotates such that the chevrons of bristles act to spread the deposited fluid across the surface of the component, as indicated by arrow B.
  • the brush head rotates such that the chevrons of bristles act to scoop up etchant fluid and direct it into the path of the openings that can collect the fluid under the application of negative pressure, as illustrated by arrows D.
  • the means for guiding comprises a flexible track 300 that is assembled into a frame 310 around the component 26 to be etched.
  • the track 300 may be flexible or may be of rigid material and construction.
  • the track 300 is assembled into the frame 310 by a series of clamps 302 that secure the track in place and prevent movement.
  • Pads 304 may be employed to prevent the clamps 302 and/or track 300 coming into contact with the component 26 and perhaps damaging the component surface.
  • the track 300 carries a rack or other means by which the fluid applicator may be secured on and moved along the track 300 in the desired direction.
  • the fluid applicator 10 is mounted on the track such that the application heads can contact the component surface over the target area to deliver, agitate and finally collect etchant fluid.
  • a single track may support multiple heads to reduce treatment time.
  • the precise location of the track may be determined using for example the CAD drawings of the component.
  • the target area to be treated for example a weld on an aerofoil component, can be precisely identified on the drawings or CAD software.
  • a path for the fluid applicator that will result in treatment of the target area may then be determined.
  • the appropriate location for the track may then be calculated from the predetermined path and the known geometry of the fluid applicator 10 and the track location may be fixed and the frame constructed.
  • Figure 23 illustrates another embodiment of the means for guiding the fluid applicator along a predetermined path.
  • the means for guiding is a computer controlled mechanical manipulation arm 400.
  • the mechanical manipulation arm is preferably a multi axis arm that allows fine control and manipulation of the location and orientation of the fluid applicator.
  • the spatial coordinates of the target area 8 may be provided to the control unit which determines a path along which the fluid applicator must travel in order to treat the target area and causes the manipulation arm to position and move the fluid applicator accordingly.
  • a simpler manipulation arm may be employed in combination with manipulation of the component to be treated, as illustrated in Figure 24 .
  • the component for example a drum may be mounted for rotation on a platform about a fixed axis, reducing the amount of translation required of the means for guiding the fluid applicator in order to enable the fluid applicator to contact any point on the surface of the component 26.
  • the fluid applicator may trace a spiral over the component, or may trace a series of discrete circles using an oscillatory pattern, or set concentric path.
  • CAD software to determine a predetermined path for the fluid applicator to follow, and then to instruct a manipulation arm or direct the construction of a frame allows a high degree of accuracy to be achieved while minimising operator contact with etchant media.
  • the predetermined path may involve several discrete sections, over which the fluid applicator may need to pass but which should not have etchant media applied.
  • the flow of etchant fluid to the fluid applicator may be stopped as the fluid applicator passes over such regions.
  • the fluid applicator may be offset from the component surface as it passes over such sections.
  • the fluid applicator may be in close physical contact with the component surface during deposition, slightly further away during manipulation/agitation of the etchant fluid so as to merely mix the etchant rather than remove it from the surface, and then in close contact again for etchant removal.
  • the actual process cycle may be more complicated than has so far been described. For example, a full process cycle may include the following steps:
  • the bristle requirements for the different process stages may be different. For example firmer bristles are required for depositing layers of fluid while longer, softer bristles may be preferred for agitation and cleaning.
  • the various requirements may be accommodated in a single applicator by employing several different brushes on a single applicator and by employing variable bristle types on individual brush heads, as described above. It may also be desirable to employ specific brushes within the applicator for specific tasks. For example it may be desirable to use different brushes for the application and removal of the scale conditioner to those employed for application, agitation and removal of the etchant fluid. Different brushes, tailored to the specific process stage requirements, can be mounted on a carousel and moved between operating and holding positions as required. A water feed may be incorporated to assist with the wash process stages as required.
  • additional agitation or temperature control may be provided by steam or gas jets delivered either from the applicator body or through the application heads of the fluid applicator.
  • Additional agitators may also be provided in the form of flutes, ribs or supplementary bristles.
  • Such agitators may be mounted on the application heads or may be mounted on separately on the body.
  • Heating or cooling may be provided via the circulatory control unit, body or application heads to increase or decrease the temperature of the scale conditioning, wash or etchant fluid. It will be understood that heating etchant fluid may increase the rate at which surface material is removed , although this may result in an increased health and safety concern.
  • Depth probes and/or a surface scanner/analyser may also be incorporated into the fluid applicator, with the potential for incorporation of electrolytic fluid monitoring and control.
  • the temperature of the component may be controlled.
  • the temperature of the component may be controlled by cooling and/or heating the component directly or by cooling and/or heating the atmosphere in which the component is held throughout the process.
  • Figure 25a-e and Figure 26 present a means for temperature control of the component 26, comprising an enclosure 500 for housing the component 26 during the method of the present invention.
  • a door/shutter 510 is lifted from a rest position ( Figure 25a ) by an actuation means 520 and the component 26 is moved inside the enclosure 500 ( Figure 25b ).
  • the actuation means 520 then lowers the door/shutter 510 such that the component 26 is contained within the enclosure 500 ( Figure 25c ).
  • the method of the present invention is worked, with the temperature of the atmosphere inside the enclosure and the temperature of the component 26 being monitored and controlled to within predetermined and desirable limits.
  • the door/shutter 510 is lifted from the closed rest position ( Figure 25d ) by the actuation means 520 and the component 26 is moved outside of the enclosure 500 ( Figure 25e ).
  • a micro switch fitted to the door/shutter 510 is operable to monitor the position of the door/shutter 510 and thus prevent deployment of the application head 10 and chemicals while the door/shutter 510 is open.
  • Figure 26 shows the component 26 when located within the enclosure 500 during the method of the present invention.
  • Thermocouples 530 are arranged around the enclosure to measure the temperature of the atmosphere within the enclosure 500. Additional thermocouples 532 are attached to multiple locations on the surface of the component 26 to thereby measure the temperature of the component 26.
  • Thermocouples 534 are also attached to an output duct of an atmospheric heater/cooler 536.
  • Thermocouples 538, 540 are additionally attached to the input and output respectively of a heater/cooler chemical reservoir 542 used to contain the chemicals used in the method of the present invention.
  • the thermocouples 530, 532, 534, 538, 540 are input to the heater/flow control unit 544.
  • the heater/flow control 544 unit makes adjustments to the atmospheric heater 536 to maintain the atmospheric temperature to within a desired temperature range.
  • the heater/flow control unit 544 makes adjustments to the heater/cooler chemical reservoir 542 to maintain the temperature of the chemicals being applied to the component 26 via the application device 10 to within a desired temperature range.
  • a fluid flow control device 546 recirculates the fluid into the heater/cooler chemical reservoir 542 or channels the fluid into a series of fluid specific reservoirs 548.
  • fluids may then be pumped into heater/cooler chemical reservoir 542 via the fluid flow control device 546 and then recirculated and reheated as required.
  • fluids may be channelled from the fluid specific reservoirs 548 into waste disposal tanks 560.
  • a wash fluid shall cleanse and neutralise the system, with fluid passing directly through the fluid flow control device 546 and fluid specific reservoirs 548 into the waste disposal tanks 560.
  • the component may be maintained at a temperature of about 293K by the temperature control means for scale conditioning part of the process.
  • the component may be maintained at about 363K by the temperature control means for the cleaning and etching parts of the process.
  • the present invention has been described with particular reference to the surface processing of a weld line. However, the present invention is applicable to any circumstance in which surface treatment of a target area of a component is required.
  • the manoeuvrability and versatility of the apparatus of the present invention renders it particularly suited to the treatment of curved components such as aerofoils for gas turbine engines.
  • the adaptability and fine control provided by the apparatus of the present invention enables accurate treatment of convex and concave surface areas including edge and tip surfaces and re-entrant features such as weld crowns and underbeads.
  • the apparatus of the present invention can be employed for the treatment of any kind of component. Such treatment is not limited to the particular application of etchant fluid described, but may also include non destructive testing applications and cleaning as well as surface preparation, diffusion bonding and chemical milling.
  • the apparatus is suitable for use with metallic as well as glass and other material components.
  • the present invention provides an efficient and environmentally sound apparatus and method for applying an etchant or other fluid to a component surface. Fine control is provided to enable exact distribution of fluid and hence accurate surface material removal by etchant media.
  • the apparatus is extremely versatile and adaptable to a wide range of component shapes and sizes. Accurate treatment of target surface areas by the apparatus retains component thickness and reduces chemical usage.
  • the apparatus is self contained, not requiring the use of sealant or masking material.
  • the invention also contains scope for miniaturisation, use on bimetallic components or assemblies and use on assemblies containing non-metallics such as seals, foams, rubbers and hard polymers.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating Apparatus (AREA)
  • ing And Chemical Polishing (AREA)
EP11161181A 2010-04-14 2011-04-05 Vorrichtung und Verfahren zum Aufbringen einer Flüssigkeit auf einer Komponente Withdrawn EP2377423A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1006185.1A GB2479559B (en) 2010-04-14 2010-04-14 Apparatus and method for applying a fluid to a component

Publications (1)

Publication Number Publication Date
EP2377423A1 true EP2377423A1 (de) 2011-10-19

Family

ID=42245166

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11161181A Withdrawn EP2377423A1 (de) 2010-04-14 2011-04-05 Vorrichtung und Verfahren zum Aufbringen einer Flüssigkeit auf einer Komponente

Country Status (3)

Country Link
US (1) US20110253170A1 (de)
EP (1) EP2377423A1 (de)
GB (1) GB2479559B (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020025902A1 (fr) * 2018-07-31 2020-02-06 Safran Aircraft Engines Procédé et dispositif pour l'amélioration de l'etat de surface d'une pièce de turbomachine

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9827401B2 (en) 2012-06-01 2017-11-28 Surmodics, Inc. Apparatus and methods for coating medical devices
US11090468B2 (en) * 2012-10-25 2021-08-17 Surmodics, Inc. Apparatus and methods for coating medical devices
EP2911804B1 (de) * 2012-10-25 2020-07-08 SurModics, Inc. Vorrichtung und verfahren zur beschichtung medizinischer vorrichtungen
CN108745759A (zh) * 2018-06-05 2018-11-06 珠海健帆生物科技股份有限公司 缝合线绕线机、缝合线硬化剂涂覆装置及其控制方法
CN109622291B (zh) * 2018-11-16 2020-11-20 绍兴市卓诚新材料有限公司 一种行道树涂白高度画线机
WO2020112816A1 (en) 2018-11-29 2020-06-04 Surmodics, Inc. Apparatus and methods for coating medical devices
US11819590B2 (en) 2019-05-13 2023-11-21 Surmodics, Inc. Apparatus and methods for coating medical devices
CN115155930B (zh) * 2022-07-29 2023-04-25 华侨大学 一种石材表面刷胶装置

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537639A (en) * 1983-09-12 1985-08-27 Nlb Corp. Method for cleaning weld smut from a surface
US4928675A (en) * 1987-10-26 1990-05-29 Thornton Thomas F Dental treatment apparatus
JP2000288937A (ja) * 1999-04-05 2000-10-17 Sintokogio Ltd 溶接ビードの自動研掃方法
US20030190874A1 (en) * 2002-04-02 2003-10-09 So Joseph K. Composite conditioning tool
DE10327413A1 (de) * 2003-06-18 2005-01-05 Airmatic Gmbh Verfahren und Vorrichtung zur Entfernung von klebigen und/oder getrockneten Substanzen von Flächen
WO2008139332A2 (es) * 2007-05-09 2008-11-20 Ignacio Fernadez Gonzalez Hidrolavaspira
DE202009009091U1 (de) * 2009-07-02 2009-09-17 Kullen Gmbh & Co. Kg Rotierend antreibbare Pinselbürste

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD242010B1 (de) * 1985-10-30 1989-01-04 Colditz Veb Porzellan Vorrichtung zum automatischen linieren und bandern von keramischen erzeugnissen
US4790259A (en) * 1988-02-29 1988-12-13 Genesis Systems Group, Ltd. Tool for robotic application of liquid to a work surface
DE3822077C2 (de) * 1988-06-30 1999-01-21 Haw Linings Gmbh Vorrichtung und ihre Verwendung zum Auftragen eines zähflüssigen Klebers auf ausgedehnte Flächen
US6103636A (en) * 1997-08-20 2000-08-15 Micron Technology, Inc. Method and apparatus for selective removal of material from wafer alignment marks
US20050020001A1 (en) * 1998-03-13 2005-01-27 Brian Aegerter Selective treatment of the surface of a microelectronic workpiece
JP2000228391A (ja) * 1998-11-30 2000-08-15 Canon Inc 半導体基板の精密研磨方法および装置
JP2002155381A (ja) * 2000-11-15 2002-05-31 Mimasu Semiconductor Industry Co Ltd 塗布式エッチング方法及び装置
US6454870B1 (en) * 2001-11-26 2002-09-24 General Electric Co. Chemical removal of a chromium oxide coating from an article
US8367551B2 (en) * 2005-03-25 2013-02-05 E I Du Pont De Nemours And Company Spin-printing of etchants and modifiers
US20090194020A1 (en) * 2008-02-05 2009-08-06 Ennis G Thomas Vehicle tire coating apparatus

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537639A (en) * 1983-09-12 1985-08-27 Nlb Corp. Method for cleaning weld smut from a surface
US4928675A (en) * 1987-10-26 1990-05-29 Thornton Thomas F Dental treatment apparatus
JP2000288937A (ja) * 1999-04-05 2000-10-17 Sintokogio Ltd 溶接ビードの自動研掃方法
US20030190874A1 (en) * 2002-04-02 2003-10-09 So Joseph K. Composite conditioning tool
DE10327413A1 (de) * 2003-06-18 2005-01-05 Airmatic Gmbh Verfahren und Vorrichtung zur Entfernung von klebigen und/oder getrockneten Substanzen von Flächen
WO2008139332A2 (es) * 2007-05-09 2008-11-20 Ignacio Fernadez Gonzalez Hidrolavaspira
DE202009009091U1 (de) * 2009-07-02 2009-09-17 Kullen Gmbh & Co. Kg Rotierend antreibbare Pinselbürste

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020025902A1 (fr) * 2018-07-31 2020-02-06 Safran Aircraft Engines Procédé et dispositif pour l'amélioration de l'etat de surface d'une pièce de turbomachine
FR3084601A1 (fr) * 2018-07-31 2020-02-07 Safran Aircraft Engines Procede et dispositif pour l'amelioration de l'etat de surface d'une piece de turbomachine
US11655545B2 (en) 2018-07-31 2023-05-23 Safran Aircraft Engines Method and device for improving the surface condition of a turbomachine component

Also Published As

Publication number Publication date
GB2479559B (en) 2012-07-25
GB201006185D0 (en) 2010-06-02
GB2479559A (en) 2011-10-19
US20110253170A1 (en) 2011-10-20

Similar Documents

Publication Publication Date Title
EP2377423A1 (de) Vorrichtung und Verfahren zum Aufbringen einer Flüssigkeit auf einer Komponente
CN102049629B (zh) 向点焊电极施加表面起伏
CA3012304A1 (en) Device and method for cleaning of pipetting needles
KR102045739B1 (ko) 터빈 날개의 보수 방법
CN106864009A (zh) 丝网印刷系统和该丝网印刷系统的清洁方法
EP1397533B1 (de) Verfahren und vorrichtung zum lokalen entschichten von bauteilen
CN103834948B (zh) 一种双槽沟槽蚀刻机
CN109162043A (zh) 一种棉织布料的清洗设备
CN103357560B (zh) 具有槽浸和喷淋功能的涂装前处理模拟装置
WO2010039491A2 (en) Electrolytic deburring apparatus and method
JP4126204B2 (ja) 歯車ラッピング方法および歯車ラッピング機
CN108816986A (zh) 一种化工搅拌桶清洁方法
JP2003275637A (ja) 塗布ノズル用クリーニング装置
KR102045742B1 (ko) 터빈 날개의 보수 방법
CN214351485U (zh) 一种三维立体成像打磨系统
CN213004515U (zh) 一种自行车零部件电泳加工中用除锈装置
CN104162518A (zh) 小型化清洗机
CN114713894A (zh) 具有自动换刀功能的铣床
JPH07314142A (ja) アーク溶接トーチのノズルクリーニング方法
CN210676142U (zh) 一种半导体清洗快排清洗治具
JP2003001554A (ja) 塗装塗膜の除去装置
JP2008073638A (ja) 塗布針洗浄方法、塗布針洗浄装置およびこれを備えたパターン修正装置
JP2010126760A (ja) エアーブロー装置
US11655545B2 (en) Method and device for improving the surface condition of a turbomachine component
CN215613555U (zh) 汽车零部件电泳涂装浸渍清洗装置

Legal Events

Date Code Title Description
AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20120126

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: ROLLS-ROYCE PLC

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20151103