EP2331619A1 - Anstrichmittel mit einem basischen additiv - Google Patents
Anstrichmittel mit einem basischen additivInfo
- Publication number
- EP2331619A1 EP2331619A1 EP09783058A EP09783058A EP2331619A1 EP 2331619 A1 EP2331619 A1 EP 2331619A1 EP 09783058 A EP09783058 A EP 09783058A EP 09783058 A EP09783058 A EP 09783058A EP 2331619 A1 EP2331619 A1 EP 2331619A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- paint
- paints
- titanate
- alkali
- lime
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
Definitions
- the invention relates to a paint with a basic additive.
- Lime paint has long been used as a wall coating agent for inside and outside.
- lime paint consists of slaked lime and water without further additives. From ecological and biological aspects, the lime color is highly recommended. In this water-thinnable coating, the lime acts simultaneously as a binder and pigment. The paint is insensitive to moisture and has a disinfecting and fungicidal effect. For ceilings and walls in kitchens and bathrooms, basements and storage rooms, the lime paint can therefore be used without any problems. In the outdoor area, the color is no longer used because of the acid rain today.
- the paint is applied to lime, lime cement and cement plasters, to formwork concrete, fired and unfired bricks, walls and ceilings.
- Protective goggles and work gloves should be worn when processing lime paint as lime and cement form strong, corrosive alkalis.
- the object of the invention is therefore to provide a paint which on the one hand has a low tendency to form fouling, on the other hand does not tend to chalk.
- such a paint can be provided by adding an alkali titanate to a paint, preferably an emulsion paint.
- a paint preferably an emulsion paint.
- a basic alkali metal titanate compound or mixtures to the formulation of the paint, wherein the or the alkali metal titanates are in an amorphous, ie non-crystalline form.
- JP-56093772 and JP-2002194294 disclose marine paints containing alkali titanates.
- these alkali titanates are present in crystalline form in the formulations described therein and serve for improvement durability against solar radiation, impact resistance and increase of wear resistance.
- sodium titanate Na ⁇ o, 2-4) 0 ⁇ o, 1-2) TiO 2 is preferably suitable according to the invention.
- Sodium titanate usually contains between 50 and 67% NaOH, depending on the composition. All of the compositions according to the invention are colorless and strongly basic with a pH of more than 11. The inventors have found that the paints with the inventive
- alkali titanate causes the coating surface remains strongly basic for a long time and thus acts inhibiting growth.
- the invention is therefore also directed to the use of an alkali titanate or mixtures thereof as an additive in paints.
- Paints also called paints, to which the alkali titanate may be added, consist of liquid to pasty substances or mixtures which, when applied to surfaces, give a physically or chemically drying paint.
- a paint is defined as "liquid to paste-like coating material, which is mainly applied by brushing or rolling."
- a paint is basically composed of: binder, colorant or pigment, filler, solvent, and any additives such as thickeners, dispersants and preservatives. Paints, the pigments (White pigments or colored pigments) are referred to as a paint or paint.
- Emulsion paints are viscous paints consisting of a chemical dispersion (usually an emulsion) of binders and solvents, colorants (usually pigments) and additives. In this general sense the majority of liquid paints (lacquers, paints, etc.) are dispersions. Main ingredients are typically water as
- Solvents resins derived from mineral oil or similar plastics as binders, dyes or pigments such as titanium dioxide, fillers such as calcium carbonate, silicates and quartz powder. According to the invention, adjuvants (so-called additives) which are used for
- the synthetic resins used are e.g. to acrylates or polyvinyl acetates. If binder-rich systems are used (PVK approx. 25 -40% at FK 40 to 50%), this is referred to as latex systems. They usually contain acrylate / styrene dispersions.
- Latex paints Water resistance, for the exterior and facade area as well as for wet areas in the house, are often referred to as latex paints, which have an increased proportion of synthetic resin.
- Resin dispersion paints with decorative additives (such as glitter) are often referred to as such.
- thixotropic (so-called compact) paints better known as solid color®; they should be less blotchy and squirt when painting.
- the solvent used for the paint according to the invention is generally water. However, paints containing organic solvents are also possible.
- Pigments are used because of their light-scattering property. They give the coating its color impression by reflection or selective or complete absorption of the light.
- Fillers are used essentially to cheapen, but also to modify the properties of paints. With fillers the PVK can be adjusted in the paints to values above the KPVK which causes the dry-hiding effect.
- Typical fillers are calcium carbonate, kaolin, talc and mica.
- the paints of the invention may also contain surfactants which physically affect the interfaces between different phases.
- wetting agents are used, which the Facilitate dispersion of pigments and fillers or make it possible in the first place. They also serve to stabilize pigments and fillers to prevent undesirable phenomena such as flocculation or sedimentation.
- thickeners which are primarily capable of binding water. Removal of unbound water increases the viscosity. From a characteristic of each thickener concentration occur to this effect also network effects that lead to a mostly disproportionate increase in viscosity.
- the thickeners are generally linear or branched macromolecules (eg polysaccharides or
- Proteins that interact with each other through intermolecular interactions such as hydrogen bonding, hydrophobic interactions, or ionic relationships.
- thickeners are sheet silicates (bentonites, hectorites) or hydrated SiO 2 particles, which are known as
- Particles are dispersed and can bind water in their solid-like structure or can interact with each other due to the interactions described.
- plasticizers usable in the present invention there are exemplified dibutyl phthalate, dioctyl phthalate and tripropylene glycol monoisobutyrate which are added to lower the MFT.
- the plasticizers do not chemically react with the material, but only physically change it.
- solvents are also used to lower the MFT. They are referred to as film-forming aids or coalescing agents.
- Typical solvents are glycol ethers and their acetate and increasingly also high boilers such as Texanol or esters of dicarboxylic acids.
- defoamers according to the invention, it is possible to use formulations such as mineral oil and silicone defoamers with pronounced interfacial activity which are suitable for suppressing undesired foam formation or destroying foam which has already formed. It is also possible to use compounds of silicone oils and hydrophobic silica or wax particles implemented therein as heterogeneous defoamers.
- the paint according to the invention may additionally contain preservatives which are resistant to attack by microorganisms such as
- preparations may also be added to the paint material as a film preservative to hinder microorganism attack.
- the paint of the invention may be in the form of paints, plasters, grouts, wallpaper, or wallpaper paste. There are no known restrictions that limit the usability as long as the chosen ones
- a facade paint with 3% Na titanate was prepared according to the following recipe:
- a facade paint with 5% Na titanate was prepared according to the following recipe:
- a facade paint without Na titanate was prepared according to the following recipe:
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008047534A DE102008047534A1 (de) | 2008-09-16 | 2008-09-16 | Anstrichmittel mit einem basischen Additiv |
PCT/EP2009/061978 WO2010031778A1 (de) | 2008-09-16 | 2009-09-15 | Anstrichmittel mit einem basischen additiv |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2331619A1 true EP2331619A1 (de) | 2011-06-15 |
Family
ID=41509052
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09783058A Withdrawn EP2331619A1 (de) | 2008-09-16 | 2009-09-15 | Anstrichmittel mit einem basischen additiv |
Country Status (10)
Country | Link |
---|---|
US (1) | US20110189403A1 (ko) |
EP (1) | EP2331619A1 (ko) |
JP (1) | JP2012503050A (ko) |
KR (1) | KR20110056414A (ko) |
BR (1) | BRPI0918627A2 (ko) |
CA (1) | CA2737371A1 (ko) |
DE (1) | DE102008047534A1 (ko) |
MX (1) | MX2011002812A (ko) |
MY (1) | MY150577A (ko) |
WO (1) | WO2010031778A1 (ko) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5189333B2 (ja) * | 2007-09-14 | 2013-04-24 | 株式会社クボタ | 非晶質複合チタン酸アルカリ金属組成物及び摩擦材 |
SI2883918T1 (sl) | 2013-12-12 | 2016-02-29 | Sto Se & Co. Kgaa | Sestavek za premaz |
WO2016180454A1 (de) | 2015-05-08 | 2016-11-17 | Sto Se & Co. Kgaa | Zusammensetzung zur oberflächenbeschichtung |
DE102017010626A1 (de) | 2017-11-16 | 2019-06-13 | Luca Marius Meyers | Optisches Frühwarnsystem zur Identifikation, Lokalisation und somit zur Prävention von Schimmelbefall ... |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3258392A (en) * | 1963-09-16 | 1966-06-28 | Du Pont | Color stabilized paper containing fluorescent dye and titanate |
CA1091914A (en) * | 1976-07-05 | 1980-12-23 | Hideo Kogure | Metal surface treatment liquid and rust preventive paint |
JPS5693772A (en) * | 1979-12-27 | 1981-07-29 | Otsuka Chem Co Ltd | Coating composition |
JPS58120677A (ja) * | 1982-01-12 | 1983-07-18 | Otsuka Chem Co Ltd | 高温断熱塗料 |
JPS60203680A (ja) * | 1984-03-28 | 1985-10-15 | Otsuka Chem Co Ltd | 高温耐熱、断熱及び防錆性コ−テイング |
DE3469545D1 (en) * | 1984-11-23 | 1988-04-07 | Otsuka Kagaku Kk | Resin composition containing a saponified ethylene-vinyl acetate copolymer |
JP3599304B2 (ja) * | 1997-08-14 | 2004-12-08 | 株式会社クボタ | 非晶質抗菌性チタン酸化合物 |
JP2002194294A (ja) * | 2000-12-27 | 2002-07-10 | Otsuka Chem Co Ltd | 内装材用水性塗料及び内装材 |
DE10258709A1 (de) * | 2002-12-12 | 2004-07-01 | Carl Zeiss Smt Ag | Schutzsystem für reflektive optische Elemente, reflektives optisches Element und Verfahren zu deren Herstellung |
-
2008
- 2008-09-16 DE DE102008047534A patent/DE102008047534A1/de not_active Ceased
-
2009
- 2009-09-15 MX MX2011002812A patent/MX2011002812A/es active IP Right Grant
- 2009-09-15 US US13/063,942 patent/US20110189403A1/en not_active Abandoned
- 2009-09-15 KR KR1020117008653A patent/KR20110056414A/ko not_active Application Discontinuation
- 2009-09-15 JP JP2011527306A patent/JP2012503050A/ja active Pending
- 2009-09-15 MY MYPI20111126 patent/MY150577A/en unknown
- 2009-09-15 BR BRPI0918627A patent/BRPI0918627A2/pt not_active IP Right Cessation
- 2009-09-15 EP EP09783058A patent/EP2331619A1/de not_active Withdrawn
- 2009-09-15 CA CA2737371A patent/CA2737371A1/en not_active Abandoned
- 2009-09-15 WO PCT/EP2009/061978 patent/WO2010031778A1/de active Application Filing
Non-Patent Citations (1)
Title |
---|
See references of WO2010031778A1 * |
Also Published As
Publication number | Publication date |
---|---|
BRPI0918627A2 (pt) | 2015-12-01 |
MY150577A (en) | 2014-01-30 |
DE102008047534A1 (de) | 2010-04-15 |
US20110189403A1 (en) | 2011-08-04 |
WO2010031778A1 (de) | 2010-03-25 |
JP2012503050A (ja) | 2012-02-02 |
KR20110056414A (ko) | 2011-05-27 |
MX2011002812A (es) | 2011-04-21 |
CA2737371A1 (en) | 2010-03-25 |
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