EP2327560B1 - Papier de transfert autocollant amélioré - Google Patents

Papier de transfert autocollant amélioré Download PDF

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Publication number
EP2327560B1
EP2327560B1 EP09177345A EP09177345A EP2327560B1 EP 2327560 B1 EP2327560 B1 EP 2327560B1 EP 09177345 A EP09177345 A EP 09177345A EP 09177345 A EP09177345 A EP 09177345A EP 2327560 B1 EP2327560 B1 EP 2327560B1
Authority
EP
European Patent Office
Prior art keywords
weight
paper
adhesive
printed
aqueous fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP09177345A
Other languages
German (de)
English (en)
Other versions
EP2327560A1 (fr
EP2327560B8 (fr
Inventor
Martinovic Zvonimir
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP09177345A priority Critical patent/EP2327560B8/fr
Application filed by Individual filed Critical Individual
Priority to CA2782002A priority patent/CA2782002A1/fr
Priority to AU2010323047A priority patent/AU2010323047A1/en
Priority to PCT/EP2010/068309 priority patent/WO2011064331A1/fr
Priority to CN2010800589340A priority patent/CN102741057A/zh
Priority to US13/512,376 priority patent/US20120234476A1/en
Priority to JP2012540441A priority patent/JP2013512122A/ja
Publication of EP2327560A1 publication Critical patent/EP2327560A1/fr
Application granted granted Critical
Publication of EP2327560B1 publication Critical patent/EP2327560B1/fr
Publication of EP2327560B8 publication Critical patent/EP2327560B8/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0355—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/504—Backcoats
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D06P5/004—Transfer printing using subliming dyes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • the present invention relates to a process for producing self-adhesive transfer papers, self-adhesive transfer papers and transfer printing processes prepared by the process.
  • Transfer printing refers to the printing of different materials, such as textiles, using transfer papers. Transfer papers are coated with pigments, which are then transferred to the printable materials by sublimation using a thermal transfer press.
  • EP 1 356 953 discloses a phosphorescent transfer layer useful in forming a transfer image, wherein the transfer image is obtained by transferring a comparative image formed on the layer by means of an ink jet printer or other means to, for example, clothes.
  • the transfer layer comprises a support and a transfer layer formed on the support and containing a hot melt adhesive particle and a phosphorescent pigment.
  • EP 2 014 688 discloses a heat-sensitive layer comprising a thermoplastic resin and a hot melt adhesive material.
  • the thermoplastic resin contains as a main component a (meth) acrylic polymer comprising acrylonitrile.
  • the heat-sensitive self-adhesive layer may be applied to a support.
  • An intermediate layer of thermosensitive polymer may be disposed between the thermosensitive layer and the support.
  • WO 00/06392 discloses a transfer paper, in particular for inkjet printing, which is provided at least on the side to be printed with a release or barrier layer, wherein the layer has a porosity of at most 100 ml / min.
  • WO 2008/006434 discloses a transfer paper having a coating with a semisynthetic polymer having thermoplastic properties.
  • thermoplastics are mentioned ethylcellulose, thermoplastic starch, methylhydroxypropylcellulose or hydroxypropylcellulose.
  • a coating with polyacrylates or carboxymethylcellulose is said to be disadvantageous.
  • EP 09 004 614.5 discloses a transfer paper, in particular for ink-jet printing, which is coated with an aqueous liquid containing ammonium polyacrylate.
  • EP 09 164 772.7 discloses a transfer paper, in particular for ink-jet printing, which is coated with an aqueous liquid containing a hydrophilic organic polymer, in particular an acrylate-based polymer and a cellulose.
  • the starting material used for the preparation of the transfer paper is a common paper, for example white or unbleached paper, with a weight of usually 60-140 g, in particular 80-120 g per m 2 of paper.
  • the front side to be printed ie the side which is subsequently coated with pigments
  • a first aqueous liquid containing a hydrophilic organic polymer namely ammonium polyacrylate.
  • the hydrophilic organic polymer may contain a polyacrylate or polymethacrylate based polymer.
  • the polymer used for coating ammonium polyacrylate usually has a weight-average molecular weight of 500 Da or more, eg 1000-5000 Da and especially 1000-2000 Da.
  • the first aqueous liquid preferably contains the polymer, namely ammonium polyacrylate, in a proportion of 10-50% by weight, in particular in an amount of 20-40% by weight, based on the total weight of the liquid.
  • the first aqueous liquid can be applied by conventional methods, for example by means of a doctor such as a doctor blade or a roller blade, or by spraying. After application, the paper is usually dried at elevated temperature, eg 40-80 ° C.
  • Step (b) preferably comprises applying a second aqueous liquid to the back of the paper and then drying.
  • the second aqueous liquid contains a hydrophilic organic polymer, for example a polyacrylate or polymethacrylate based polymer. Preference is given to using a polyacrylate, more preferably ammonium polyacrylate.
  • the second aqueous liquid contains the polymer, e.g. Ammonium polyacrylate, or another organic polymer preferably in a proportion of 2 to 20% by weight, in particular in a proportion of 5 to 15% by weight based on the total weight of the liquid.
  • the application of the second liquid and the subsequent drying can be carried out by known methods as in the case of the first liquid.
  • the first and optionally the second aqueous liquid are usually applied in an amount of 10-40 g, in particular 15-25 g per m 2 of paper, and in some embodiments, higher or lower amounts can be applied.
  • the polymer for example ammonium polyacrylate (or another hydrophilic polymer), in an amount of 1-25 g, in particular 2-20 g dry weight is applied to the front of the paper.
  • the polymer eg ammonium polyacrylate (or another hydrophilic polymer), preferably in an amount of 0.5-15 g, in particular 1-10 g dry weight is applied.
  • the first aqueous liquid and optionally also the second aqueous liquid may have an acidic, neutral or alkaline pH.
  • the first and second aqueous liquids have an acidic to neutral pH, e.g. a pH of 4-7, for example from 5-6.
  • Step (c) comprises applying a third aqueous liquid comprising a thermoactive adhesive, for example a silicone adhesive or another adhesive, which has adhesive properties at an elevated temperature of, for example, 60-110 ° C or more and adheres to the materials to be printed, eg, textiles. After cooling to lower temperatures, for example to room temperature, the thermoactive adhesive loses its adhesion properties again.
  • a thermoactive adhesive for example a silicone adhesive or another adhesive, which has adhesive properties at an elevated temperature of, for example, 60-110 ° C or more and adheres to the materials to be printed, eg, textiles.
  • Suitable thermoactive adhesives are commercially available, for example from Bayer or Ciba-Geigy.
  • the third aqueous liquid contains a polyvinyl alcohol.
  • the polyvinyl alcohol usually has a weight-average molecular weight of about 10,000 - 100,000 Da, preferably 30,000 - 60,000 Da. Suitable polyvinyl alcohols are commercially available, for example, the product MOWIOL ® 26/28.
  • the remainder of the liquid is preferably water.
  • the proportion of water in the first liquid is preferably ⁇ 40 wt .-%, in particular ⁇ 50 wt .-%.
  • Organic volatile solvents are preferably absent.
  • the third aqueous liquid is usually applied to the paper in an amount of 10-40 g / m 2 , in particular of 20-30 g / m 2 , and in some embodiments also higher or lower amounts are applied.
  • the drying of the third liquid is carried out by known methods as described for the first and second liquid.
  • aqueous liquids according to the invention for coating the paper front are given as follows: Coating liquid 1 ammonium polyacrylate 20-40% by weight Balance H 2 O pH 5-6 Coating liquid 2 NaOH 0.02-0.2% by weight ammonium polyacrylate 5-15% by weight Balance H 2 O pH 5-6 Coating liquid 3 Thermoactive adhesive 2-15% by weight polyvinyl alcohol 10-20% by weight Balance H 2 O
  • Another aspect of the invention is a self-adhesive transfer paper, especially for inkjet printing, which is obtainable by a method as described above.
  • Yet another aspect of the invention is a self-adhesive transfer paper, especially for inkjet printing, which is printed on the front side with a thermoactive adhesive, an acrylate-based polymer, namely ammonium polyacrylate, eg in an amount of 1-25 g / m 2 paper, and a polyvinyl alcohol, in particular in an amount of 0.5-2 g / m 2 paper coated.
  • the transfer paper is optionally with a hydrophilic polymer, eg a Acrylate-based polymer such as ammonium polyacrylate, especially coated in an amount of 0.5-15 g / m 2 paper.
  • Yet another aspect of the invention is a process for printing transfer paper comprising applying a layer of sublimable pigments to the face of a self-adhesive transfer paper as previously described, e.g. by ink jet printing, applying.
  • the pigments can be used in conventional printing inks with common equipment, e.g. Inkjet printers are applied by known methods. After application, the printed transfer paper is dried at room temperature or at elevated temperature up to 80 ° C. Surprisingly, it was found that the pigments show no tendency to smear during application and drying.
  • the printed self-adhesive transfer paper can be used in a known manner for printing on objects, in particular textiles.
  • Yet another aspect of the present invention is thus a printed self-adhesive transfer paper for printing on articles, in particular textiles, which is coated on the front with a thermoactive adhesive, an acrylate-based polymer, namely ammonium polyacrylate, and a polyvinyl alcohol, as well as with sublimable pigments.
  • the textiles to be printed are usually uncoloured or white.
  • pre-dyed textiles can be used.
  • These are conventional textiles, e.g. also polyester and / or polyamide-based textiles, which preferably contain a proportion of at least 40-60 wt.% Polyester and / or polyamide fibers, or which are coated with polyester and / or polyamide.
  • stretchable textiles can also be coated without smearing with the self-adhesive transfer paper according to the invention become.
  • the self-adhesive paper adheres after heating to a temperature of ⁇ 60-110 ° C on the material to be printed, so that the ink transfer of paper on the material to be printed by conventional roller printing without smearing the pigments is possible.
  • the self-adhesive paper after cooling can be readily withdrawn from the material to be printed again.
  • Yet another object of the invention is thus a method for printing on objects, in particular textiles, e.g. polyester or polyamide-based, characterized in that the article to be printed with a printed self-adhesive transfer paper as described above at elevated temperature, e.g. 160-240 ° C, so that sublimable pigments are transferred from the transfer paper to the object to be printed.
  • a printed self-adhesive transfer paper as described above at elevated temperature, e.g. 160-240 ° C, so that sublimable pigments are transferred from the transfer paper to the object to be printed.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Ink Jet (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Paper (AREA)
  • Coloring (AREA)

Claims (14)

  1. Procédé de fabrication de papier de transfert autocollant, en particulier pour l'impression par jet d'encre, comprenant les étapes suivantes :
    (a) application d'un premier fluide aqueux sur le recto à imprimer d'un papier, le premier fluide aqueux contenant un polymère organique hydrophile, à savoir du polyacrylate d'ammonium, et ensuite séchage,
    (b) éventuellement, application d'un deuxième fluide aqueux sur le verso du papier, le deuxième fluide aqueux contenant éventuellement un polymère organique hydrophile, et ensuite séchage, et
    (c) application d'un troisième fluide aqueux sur le recto à imprimer du papier, le troisième fluide aqueux contenant un adhésif thermoactif et de l'alcool polyvinylique et ensuite séchage.
  2. Procédé selon la revendication 1,
    caractérisé en ce que
    le premier fluide aqueux contient du polyacrylate d'ammonium en une proportion allant de 10 à 50 % en poids, en particulier en une proportion allant de 20 à 40 % en poids par rapport au poids total du fluide.
  3. Procédé selon la revendication 1 ou 2,
    caractérisé en ce que
    le deuxième fluide aqueux contient un polyacrylate tel que le polyacrylate d'ammonium comme polymère organique hydrophile, par exemple, en une proportion allant de 2 à 20 % en poids, en particulier en une proportion allant de 5 à 15 % en poids par rapport au poids total du fluide.
  4. Procédé selon l'une des revendications 1 à 3,
    caractérisé en ce que
    le premier et éventuellement le deuxième fluide aqueux sont appliqués sur le papier en une quantité allant de 10 à 40 g par m2, en particulier de 15 à 25 g par m2.
  5. Procédé selon l'une des revendications 1 à 4,
    caractérisé en ce que
    le polymère hydrophile est appliqué sur le recto du papier en une quantité allant de 1 à 25 g en poids sec, en particulier de 2 à 20 g en poids sec.
  6. Procédé selon l'une des revendications 1 à 5,
    caractérisé en ce que
    le premier et éventuellement le deuxième fluide aqueux présentent un pH allant de 5 à 6.
  7. Procédé selon l'une des revendications 1 à 6,
    caractérisé en ce que
    le troisième fluide contient les composants suivants, en particulier choisis parmi
    (i) un adhésif thermoactif tel qu'un adhésif de silicone, par exemple en une proportion allant de 1 à 20 % en poids, en particulier de 2 à 15 % en poids, et
    (ii) un alcool polyvinylique, par exemple en une proportion allant de 5 à 30 % en poids, en particulier de 10 à 20 % en poids,
    les proportions en poids se rapportant respectivement au poids total du premier fluide.
  8. Procédé selon l'une des revendications 1 à 7,
    caractérisé en ce que
    le troisième fluide aqueux est appliqué sur le papier en une quantité allant de 10 à 40 g/m2, en particulier de 20 à 30 g/m2.
  9. Papier de transfert autocollant, en particulier pour l'impression à jet d'encre, pouvant être obtenu par un procédé selon l'une des revendications 1 à 8.
  10. Papier de transfert autocollant, en particulier pour l'impression à jet d'encre,
    caractérisé en ce que
    il est revêtu sur le recto à imprimer avec un adhésif thermoactif, du polyacrylate d'ammonium et un alcool polyvinylique.
  11. Procédé d'impression de papier de transfert,
    caractérisé en ce que
    on applique une couche de pigments pouvant être sublimés sur le recto d'un papier de transfert autocollant selon la revendication 9 ou 10, par exemple par impression à jet d'encre.
  12. Papier de transfert autocollant imprimé pour décorer par impression des objets, en particulier des textiles,
    caractérisé en ce que
    il est revêtu sur le recto avec un adhésif thermoactif, du polyacrylate d'ammonium, de l'alcool polyvinylique et des pigments pouvant être sublimés.
  13. Procédé de décoration par impression d'objets, en particulier des textiles,
    caractérisé en ce que
    on met en contact l'objet à décorer avec un papier de transfert autocollant imprimé selon la revendication 11, à une température augmentée, de sorte que les pigments pouvant être sublimés sont transférés du papier de transfert à l'objet à décorer.
  14. Procédé selon la revendication 13,
    caractérisé en ce que
    le transfert des pigments du papier à l'objet à décorer s'effectue par impression au rouleau.
EP09177345A 2009-11-27 2009-11-27 Papier de transfert autocollant amélioré Not-in-force EP2327560B8 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP09177345A EP2327560B8 (fr) 2009-11-27 2009-11-27 Papier de transfert autocollant amélioré
AU2010323047A AU2010323047A1 (en) 2009-11-27 2010-11-26 Improved self-adhesive transfer paper
PCT/EP2010/068309 WO2011064331A1 (fr) 2009-11-27 2010-11-26 Papier transfert autocollant amélioré
CN2010800589340A CN102741057A (zh) 2009-11-27 2010-11-26 改进的自粘转印纸
CA2782002A CA2782002A1 (fr) 2009-11-27 2010-11-26 Papier transfert autocollant ameliore
US13/512,376 US20120234476A1 (en) 2009-11-27 2010-11-26 Self-adhesive transfer paper
JP2012540441A JP2013512122A (ja) 2009-11-27 2010-11-26 改善された粘着性転写紙

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP09177345A EP2327560B8 (fr) 2009-11-27 2009-11-27 Papier de transfert autocollant amélioré

Publications (3)

Publication Number Publication Date
EP2327560A1 EP2327560A1 (fr) 2011-06-01
EP2327560B1 true EP2327560B1 (fr) 2012-06-20
EP2327560B8 EP2327560B8 (fr) 2012-07-25

Family

ID=41591605

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09177345A Not-in-force EP2327560B8 (fr) 2009-11-27 2009-11-27 Papier de transfert autocollant amélioré

Country Status (7)

Country Link
US (1) US20120234476A1 (fr)
EP (1) EP2327560B8 (fr)
JP (1) JP2013512122A (fr)
CN (1) CN102741057A (fr)
AU (1) AU2010323047A1 (fr)
CA (1) CA2782002A1 (fr)
WO (1) WO2011064331A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN2014MU00683A (fr) * 2014-02-26 2015-09-25 M S Can Image Media Tech
CN107345370A (zh) * 2016-05-04 2017-11-14 全斯福新材料（苏州）有限公司 涤纶高渗透免洗转移印花方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4008663B2 (ja) 1998-07-29 2007-11-14 ダブリュー．エー． サンデルス パピエルファブリック コッデンホーヴェ ビー．ヴィー インクジェット印刷用転写紙
JP2003312196A (ja) 2002-04-24 2003-11-06 Daicel Chem Ind Ltd 転写シート
EP1878829A1 (fr) * 2006-07-12 2008-01-16 Papierfabriken Cham-Tenero AG Papier de support revetu
JP5100223B2 (ja) 2007-07-09 2012-12-19 株式会社リコー 感熱性粘着材料

Also Published As

Publication number Publication date
JP2013512122A (ja) 2013-04-11
CN102741057A (zh) 2012-10-17
EP2327560A1 (fr) 2011-06-01
AU2010323047A1 (en) 2012-07-05
CA2782002A1 (fr) 2011-06-03
EP2327560B8 (fr) 2012-07-25
WO2011064331A1 (fr) 2011-06-03
US20120234476A1 (en) 2012-09-20

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