EP2316914B1 - Klebende reinigungsmittelzusammensetzung - Google Patents

Klebende reinigungsmittelzusammensetzung Download PDF

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Publication number
EP2316914B1
EP2316914B1 EP10175621.1A EP10175621A EP2316914B1 EP 2316914 B1 EP2316914 B1 EP 2316914B1 EP 10175621 A EP10175621 A EP 10175621A EP 2316914 B1 EP2316914 B1 EP 2316914B1
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Prior art keywords
adhesive composition
composition
weight
formula
amine
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French (fr)
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EP2316914A1 (de
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Francesco Maurizio Orlandini
Gianni Alderuccio
Paola Curi
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Bolton Manitoba SpA
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Bolton Manitoba SpA
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines

Definitions

  • the present invention relates to an adhesive cleaning and/or perfuming and/or hygienizing composition.
  • the present invention falls within the technical field of cleaning and/or perfuming and/or disinfecting products, in solid, gel or paste form, for sanitary fixtures such as interiors of WCs, bidets, pissoirs and washbasins, in particular, for the interior of dishwashers, washing machines, walls, furniture, etc.
  • the present invention falls within the technical field of products, in solid, gel or paste form, for cleaning and/or disinfecting and/or perfuming applied directly onto the surface of interest, inside sanitary fixtures or in the interior of washing machines, dishwashers, walls, furniture, to which they adhere thanks to their intrinsic characteristics, i.e. without the help of supports and/or containers, i.e. external devices.
  • ethoxylated alcohols also defined as polyalkoxyalkanes, known as having adhesive properties.
  • ethoxylated alcohols are non-ionic surfactants which, in order to also have adhesive properties, must be characterized by a long hydrocarbon chain and a high ethoxylation.
  • Ethoxylated alcohols are prepared by the ethoxylation of alcohols, according to the following process
  • hygienizing products which can be applied directly to sanitary fixtures available on the market, however, have various drawbacks, mainly due to the specific presence of ethoxylated alcohols in the composition.
  • these hygienizing products in fact, include compositions based on long-chain ethoxylated alcohols, a characteristic which, as previously indicated, is indispensable for obtaining the necessary adhesiveness, they have a low hygroscopicity.
  • ethoxylated alcohols must be alcohols with very high ethoxylations and this consequently requires that the raw material be present in solid form, in particular in the form of flakes which must be subjected to melting to form the final product, creating considerable productive difficulties. These products are therefore characterized by significant problems in the preparative phase linked specifically to the presence of ethoxylated alcohols.
  • GB 2194957 discloses a thickened acidic cleaner composition including a quaternary ammonium compound and a phase stabilizing surfactant selected form alkyl betaines, alkoxylated tertiary amines, ethoxylated alkylphenols and phosphate esters of amine oxides.
  • the ethoxylated amines have a maximum degree of ethoxylation of 10.
  • GB 1443244 discloses cleaning and descaling compositions effective as lavatory cleaners. These compositions comprise at least one mineral acid or at least one acid salt of a strong inorganic acid in aqueous solution and at least one thickening agent which is an ethoxylated or propoxylated tertiary amines having a maximum degree of ethoxylation/propoxylation of 6.
  • the Applicant has now surprisingly found an adhesive cleaning and/or perfuming and/or hygienizing composition, in the form of a solid or gel, which overcomes the drawbacks revealed by the state of the art.
  • the main objective of the present invention is therefore to find an adhesive cleaning and/or perfuming and/or hygienizing composition, in the form of a solid or gel, which can be applied directly to the surface of interest, to which it adheres without the help of supports and/or containers, which has an optimum adhesion to the surface and duration.
  • a further objective of the present invention is to simplify the preparation of the adhesive cleaning and/or perfuming and/or hygienizing composition, in the form of a solid or gel, which can be applied directly to the surface of interest, with a considerable reduction in the production costs.
  • An object of the present invention therefore relates to an adhesive cleaning and/or perfuming and/or hygienizing composition according to claim 1.
  • the alkoxyl is preferably selected from ethylene oxide, propylene oxide, butylene oxide, possibly with mixed alkoxylation in random and/or block combinations.
  • the alkoxylated amine having formula (I) is preferably an ethoxylated amine or an ethoxylated-propoxylated amine.
  • the adhesive cleaning and/or perfuming and/or hygienizing composition in the form of a gel, according to the present invention preferably comprises an alkanolamide selected from the compounds having formula (II) wherein
  • the compound having formula (II) is a monoethanolamide, whereas when it is a CH 2 CH 2 OH group, the compound having formula (II) is a diethanolamide.
  • the alkanolamide having formula (II) is preferably a lauric monoethanolamide or a coconut diethanolamide.
  • alkanolamides allows the viscosity of the ethoxylated amine to be increased until a solid block is obtained, having adhesive properties and/or giving the composition, when necessary, cleaning and/or foaming characteristics.
  • detergent/foaming agents as component (iii) of the adhesive composition according to the present invention, is envisaged for example in the case of adhesive detergents for WCs, dishwashers and washing machines, and said detergent/foaming agents can be selected from alkanolamides having formula (II), anionic-and/or non-ionic- and/or amphoteric-based surfactant mixtures (e.g.
  • soap sodium Laureth Sulphate, Alkylben-zensulphonate, cocoamidopropylbetaine, amine oxide etc.
  • Syndet mixtures such as Zetasap sold by Zschimmer & Schwarz, in addition to solvent mixtures based on propylene glycol, glycerine and mixtures of sequestrants such as phosphonates, Edta, citrates, phosphates.
  • Said detergent/foaming agents, component (iii) of the adhesive composition according to the present invention are preferably selected from alkanolamides having formula (II).
  • the adhesive composition according to the present invention can also envisage the presence of viscosity agents, such as xanthan gums, hydroxyethyl cellulose, acrylic polymers or copolymers, polyethylene glycol or polyethylene glycol distearates having a molecular weight ranging from 200 to 8,000, preferably from 1,000 to 6,000, solvents such as propylene glycol, glycerol triacetate, C 5 -C 20 alcohols, preferably C 10 -C 15 , components that modify the rheology of the formulation and are suitably selected for adapting it to the distribution system and/or for vehiculating the consumption of the product.
  • viscosity agents such as xanthan gums, hydroxyethyl cellulose, acrylic polymers or copolymers, polyethylene glycol or polyethylene glycol distearates having a molecular weight ranging from 200 to 8,000, preferably from 1,000 to 6,000
  • solvents such as propylene glycol, glycerol triacetate, C 5 -C 20 alcohol
  • fatty acids (coconut and tallow are the most widely used) are adopted as precursors, which are transformed into amines and then ethoxylated, according to the following process: RC ⁇ N + H 2 ⁇ RCH 2 NH 2
  • ethoxylated amine having formula (I) starting from a primary amine both hydrogens are substituted:
  • R is a linear or branched, saturated or unsaturated alkyl chain, with a number of carbon atoms ranging from C 12 to C 22 , preferably from C 8 to C 18 , x+y is equal to n+2 and varies from 15 to 50, preferably from 20 to 40, even more preferably from 25 to 35.
  • R and R 1 are both a linear or branched, saturated or unsaturated alkyl chain, with a number of carbon atoms ranging from C 12 to C 22 , preferably from C 8 to C 18
  • the synthesis is completely analogous to that previously described for the primary amine, starting from the corresponding secondary amine.
  • Y is not present and x, equal to n+1, varies form 15 to 50, preferably from 20 to 40, even more preferably from 25 to 35.
  • the most widely used fatty acid precursors are coconut, which has, for example, the following composition of the alkyl chain R and/or R 1 : Chain length % C8 8 C10 7 C12 50 C14 16 C16 9 C18 (saturated) 5 C18 (unsaturated) 5 or a tallow fatty acid, which has, for example, the following composition of the alkyl chain R and/or R 1 : Chain length % C14 5 C16 30 C18 (saturated) 20 C18 (unsaturated) 45
  • the alkoxylated amine having formula (I) is present in an amount which ranges from 20% to 60% by weight with respect to the total weight of the composition, preferably from 20% to 50% and, even more preferably from 30% to 45%.
  • the adhesive composition in gel form according to the present invention can comprise the presence of a viscosity agent, such as for example xanthan gum, in an amount which ranges from 0% to 5% by weight with respect to the total weight of the composition, preferably from 0% to 1%, more preferably from 0% to 0.5%.
  • a viscosity agent such as for example xanthan gum
  • the adhesive composition in gel form according to the present invention also comprises a perfuming agent in an amount which ranges from 1% to 10% by weight with respect to the total weight of the composition, preferably from 3% to 7%.
  • the adhesive composition in gel form according to the present invention also comprises water in an amount which ranges from 79% to 25% by weight with respect to the total weight of the composition.
  • the adhesive composition in gel form according to the present invention can also comprise further components for modulating the viscosity/consistency of the gel, its duration in use, for example in a WC or inside a piece of furniture, or its melting point or again for introducing cleaning and/or foaming properties into the product, when necessary.
  • Said further components can be selected from an alkanolamide having formula (II), anionic- and/or non-ionic- and/or amphoteric-based surfactant mixtures (e.g.
  • soap sodium Laureth Sulphate, Alkylbenzensulphonate, cocoamidopropylbetaine, amine oxide etc.
  • Syndet mixtures such as Zetasap sold by Zschimmer & Schwarz, in addition to solvent mixtures based on propylene glycol, glycerine and mixtures of sequestrants such as phosphonates, Edta, citrates, phosphates, PEG, PEG distearate or a solvent such as monopropyleneglycol.
  • the adhesive cleaning compositions in gel form according to the present invention have a viscosity ranging from 1,500 Pa ⁇ s to 5,000 Pa ⁇ s, preferably from 2,000 Pa ⁇ s to 4,000 Pa ⁇ s (measured with a Rheometrics RDAII rheometer with a plate/plate system, diameter of the plates 10 mm, shear rate 2.62 s -1 , temperature 20°C).
  • the adhesive cleaning compositions in gel form according to the state of the art based on ethoxylated alcohol are characterized by viscosity values lower than 1,500 Pa ⁇ s.
  • the process for obtaining an adhesive composition in gel form according to the present invention comprises the following phases.
  • the alkoxylated amine (preferably ethoxylated) having formula (I) is inserted in a mixer containing water at a temperature of about 40°C, and subjected to stirring until complete dissolution.
  • the temperature of the water can be increased if the mixing time is to be reduced, or if the percentages and/or starting components are such as to obtain a final adhesive composition having a melting point higher than 40°C.
  • the adhesive composition in gel form according to the present invention comprises the addition of a viscosity agent such as xanthan gum, this must be dispersed in water before the addition of the alkoxylated amine having formula (I).
  • the amine having formula (I) is present in a quantity which varies from 20 to 76% by weight with respect to the total weight of the composition, preferably from 20 to 70%, even more preferably from 30 to 65%.
  • the adhesive composition in solid form according to the present invention also comprises an alkanolamide having formula (II), preferably monoethanolamide or diethanolamide having formula (II), even more preferably lauric monoethanolamide, in an amount ranging from 10 to 70% by weight with respect to the total weight of the composition, preferably from 20 to 60%, to obtain a solid consistency of the formulation and/or to give cleaning properties to the product.
  • an alkanolamide having formula (II) preferably monoethanolamide or diethanolamide having formula (II), even more preferably lauric monoethanolamide, in an amount ranging from 10 to 70% by weight with respect to the total weight of the composition, preferably from 20 to 60%, to obtain a solid consistency of the formulation and/or to give cleaning properties to the product.
  • the adhesive composition in solid form according to the present invention also comprises a perfuming agent in an amount which ranges from 1% to 10% by weight with respect to the total weight of the composition, preferably from 4 to 7%.
  • a particular mixture of surfactants can be used, such as soaps, lauryl ether sulfates and solvents, such as the product Zetasap C11 sold by Zschimmer & Schwarz, which in this case is a mixture of propylene glycol, soap, anionic surfactant (sodium Laureth Sulfate), sorbitol, glycerine and sequestering agents.
  • surfactants such as soaps, lauryl ether sulfates and solvents, such as the product Zetasap C11 sold by Zschimmer & Schwarz, which in this case is a mixture of propylene glycol, soap, anionic surfactant (sodium Laureth Sulfate), sorbitol, glycerine and sequestering agents.
  • anionic surfactant sodium Laureth Sulfate
  • sorbitol sodium Laureth Sulfate
  • glycerine glycerine
  • the adhesive composition in solid form according to the present invention can comprise the presence of a viscosity agent, such as for example xanthan gum, or a solvent such as monopropylene glycol.
  • a viscosity agent such as for example xanthan gum
  • a solvent such as monopropylene glycol
  • the process for obtaining an adhesive composition according to the present invention in solid form comprises the following phases.
  • the solidifying component indispensable for obtaining the adhesive composition in solid form such as for example lauric monoethanolamide, is melted.
  • the adhesion promoter i.e. the alkoxylated amine having formula (I) is added to the molten paste thus obtained.
  • the adhesive composition according to the present invention can also contain, as minority components, disinfecting agents, dyes and/or cleaning adjuvants and/or foaming agents and/or cleaning agents and/or thickening agents, selected from those commonly known to experts in the field.
  • a further object of the present invention therefore relates to a process for the preparation of said adhesive cleaning and/or perfuming and/or hygienizing compositions in the form of a solid or gel according to claim 9.
  • An object of the present invention also relates to the use of said adhesive cleaning and/or perfuming and/or hygienizing compositions in the form of a solid or gel, by application onto the surface of interest of sanitary fixtures, household appliance, walls, furniture, etc.
  • a further object of the present invention relates to the application process of said adhesive composition directly to the surface of interest, to which it adheres without the help of supports and/or containers.
  • An adhesive composition in gel form according to the present invention is preferably composed of the following components:
  • the adhesive composition in gel form according to the present invention consists of the following components:
  • the adhesive composition in solid form according to the present invention can consist of the following components:
  • the main advantages of the adhesive composition according to the present invention consist in its direct applicability to the surface of interest of the sanitary fixture or interior of household appliances or furniture, its high efficacy, the modulability of its duration with time depending on the type of application, and production simplicity.
  • the preparation process of the adhesive composition according to the present invention has definite advantages: the ethoxylated amine, in fact, does not have to be melted and can be mixed more easily with the other components of the adhesive composition according to the present invention, such as, for example, the perfuming agent.
  • the polyalkoxyalkane in the adhesive compositions according to the state of the art based on polyalkoxyalkanes, the polyalkoxyalkane must be melted at temperatures ranging from 50°C to 80°C to be able to be subsequently used for the production of adhesive compositions in paste form.
  • the alkoxylated, in particular ethoxylated, amine is, on the other hand, always in liquid form and can therefore also be used at temperatures lower than 40°C with a consequent enormous advantage from an industrial and productive point of view: the alkoxylated amine is much easier to manage and manipulate, it requires less energy for its synthesis and its mixing with the other components of the adhesive composition is much simpler.
  • the insertion of the perfuming agent in the adhesive composition based on ethoxylated amine having formula (I) according to the present invention can also be effected at lower temperatures with respect to those necessary in the case of adhesive compositions based on ethoxylated alcohol, thus reducing the evaporation of the perfuming agent itself and increasing the yield.
  • an adhesive composition was tested, in gel form, according to the present invention, based on ethoxylated amine having formula (I), in particular containing compound 2 previously defined, as ethoxylated amine, i.e. ethoxylated tallow amine 25 moles of EO: this composition has a higher consistency and viscosity with respect to the adhesive composition based on ethoxylated alcohol in gel form, obtained with compound 1 according to the state of the art, and shows a greater adhesion/gluing capacity to the glass walls of a glass.
  • the alkoxylated amines, in particular ethoxylated, having formula (I) have a high foaming capacity, whereas ethoxylated alcohols produce a moderate foam; they are in fact used for minimizing the foam of anionic surfactants: in adhesive cleaning compositions the foam, together with the perfume, is a characteristic of fundamental importance for obtaining a particularly effective adhesive composition.
  • the adhesive composition will require an anionic surfactant as foaming agent, but the amount of foam it produces will in any case be minimized by the presence of the same ethoxylated alcohol.
  • just one ethoxylated amine can be used together with the perfuming agent, obtaining an adhesive composition in the form of a paste with adhesive perfuming properties and which produces a good quantity of foam.
  • the alkoxylated amines, in particular ethoxylated, having formula (I) also have another characteristic of particular interest: they have proved to be extremely hygroscopic, this means that they easily absorb water, favouring the dissolution of the adhesive composition in solid form during use, for example in WCs where, during the flushing of the water, part of the cleaning, perfuming and/or hygienizing composition must dissolve to exert its specific activities of an adhesive composition of this type (foam, perfume and detergent).
  • the alkoxylated, in particular ethoxylated, amine having formula (I) present in the adhesive composition according to the present invention facilitates dissolution, whereas in the adhesive compositions based on ethoxylated alcohols according to the state of the art, as the ethoxylated alcohol has lower hygroscopic properties, the dissolution of the adhesive composition must be helped by the insertion in the formula of humectants such as polyethylene glycols or other solvents: the presence of these components can negatively influence two of the three fundamental characteristics of a cleaning composition in general, i.e. the perfume and the foam. Solvents are in fact the source of additional strong odours which conceal the perfume and are foam demolishers.
  • alkoxylated amines having formula (I) in the adhesive compositions according to the present invention allows cases in which it is necessary to insert humectants and/or solvents in the formulation to be reduced to the minimum and in these cases however, to add an extremely limited quantity of said components.
  • an adhesive composition based on alkoxylated amine, in particular ethoxylated amine, having formula (I), as adhesion promoter, also comprising a component having a solidifying action, such as an alkanolamide having formula (II) and in particular a lauric monoethanolamide or another solidifying and/or cleaning agent, can in fact be easily produced in the form of a solid block having adhesive properties.
  • the solid can be enclosed in a plastic container without particular problems of detachment of the adhesive composition from the container during the application of the adhesive composition to the surface of interest.
  • the hygroscopicity of the alkoxylated, in particular ethoxylated, amine allows the formation of a light layer of hydrated, and therefore liquid, ethoxylated amine to be obtained between the surface of the plastic container and the solid block, and this layer of hydrated ethoxylated amine acts as detaching agent of the solid block from the support.
  • the adhesive cleaning and/or perfuming and/or hygienizing composition in solid or gel form i.e. based on alkoxylated amine (preferably ethoxylated) having formula (I), capable, as a result of its intrinsic characteristics, of adhering to sides, such as the inside of WCs, the interior of dishwashers, walls, etc., i.e. without the help of an external device, therefore has the following advantages both as final benefits for the user, and also from a productive/industrial point of view, with respect to adhesive compositions based on polyalkoxyalkanes as adhesion promoters according to the state of the art:
  • the adhesive composition in solid form according to the present invention can be produced in the form of a tablet having dimensions of about 4 x 2 x 1 cm, making it only slightly visible inside the surface of interest to which it is applied, unlike the much more encumbering products which can be obtained according to the disclosures of the state of the art.
  • the encumbrance of the adhesive composition according to the present invention mainly depends on the duration of the hygienizing efficacy to be obtained.
  • an adhesive composition is considered to be subjected to flushings of discharge water varying from 6 to 9 litres each
  • the adhesive composition according to the present invention formulated as a tablet having a weight of about 10 grams, is completely washed away only after 90-130 flushings approximately, bearing in mind that the number of flushings necessary for the complete washing away also depends on the geometry of the tablet and flushing mode of the water in the WC.
  • the use of the adhesive composition according to the present invention for cleaning and/or disinfecting and/or perfuming sanitary fixtures occurs through the direct application to the sanitary fixture, to which it adheres without the help of supports and/or containers.
  • the composition in order to facilitate the application of the composition to the sanitary fixture, can be provided with a support, such as for example a plastic thermoformed support from which the adhesive composition can be easily detached thanks to the hygroscopic characteristics described above, of the alkoxylated amine itself.
  • a support such as for example a plastic thermoformed support from which the adhesive composition can be easily detached thanks to the hygroscopic characteristics described above, of the alkoxylated amine itself.
  • a fundamental characteristic is the duration of the same in the WC subjected to water flushings: a formulation such as that indicated in Table 1 as Example 2, applied to a WC with a dimension of about 10 grams, has an average duration of 100 flushings, i.e. about 7 days, considering an average of 15 water flushings a day in an average family composed of 4 persons.
  • the melting point/dissolution of the composition is important: a formulation such as that indicated in Table 1 as Example 1, dissolves completely at 36°C and can therefore be used in short cycles in a washing machine or prewashing in dishwashers, where the temperature of the water ranges from 30 to 40°C.
  • the adhesive composition according to the present invention In use in dishwashers and washing machines, it is also important for the adhesive composition according to the present invention not to produce too much foam and monopropylene glycol can therefore be inserted (see Table 1, Example 5) as solvent in the composition.
  • the cleaning action of the coconut diethanolamide is maintained, reducing however its foaminess thanks to the presence of the solvent.
  • the duration of the adhesive composition in solid form (tablet) must be much greater and, as the adhesive composition is not subjected to water flushings, an extremely hard formulation is selected (see Table 2, Example 6).
  • the adhesive compositions based on ethoxylated amine in gel form according to the present invention have a greater adhesiveness with respect to the compositions known in the state of the art.
  • the adhesiveness of the compositions of Example 2 and 4 was measured experimentally and compared with that of an adhesive cleaning composition in gel form available on the market and containing, as adhesion promoter, a non-ionic surfactant (ethoxylated alcohol). The adhesiveness was measured with a TAXTplus structure analyzer produced by StableMicroSystems.
  • a first measurement of the adhesiveness (Test 1) of the compositions was effected as follows.
  • the cylindrical probe having a diameter of 10 mm of the analyzer was lowered onto the sample at a rate of 1 mm/s, penetrating the sample for a distance of 10 mm.
  • the probe is then brought to the starting position at a rate of 1 mm/s.
  • the hardness of the sample max force
  • the minimum force in negative value
  • the adhesiveness negative area
  • Test 1 The results of Test 1 are indicated in Table 3.
  • the values indicated in the table correspond to the average value of three measurements.
  • Table 3 Sample Max force [g] Consistency [g ⁇ sec] Min force [g] Adhesiveness [g ⁇ sec]
  • Example 2 (average value) 650.585 4137.195 -569.163 -4019.546
  • Example 2 standard deviation 37.936 379.728 24.834 321.375
  • Reference average value 419.316 2641.533 -370.716 -2758.157
  • composition according to the present invention adheresion promoter: ethoxylated amine
  • adheresion promoter non-ionic surfactant
  • a second measurement of the adhesiveness of the compositions was effected as follows. A sample of the composition is deposited on the base of the instrument. The sample is compressed to 90% of its dimensions with a cylindrical probe made of Plexiglas (diameter 25 mm); a force of 2 kg is maintained on the sample, by means of the probe, for 10 seconds, the probe then reascends to its starting position. With this test, the adhesiveness of the sample to the probe is measured.
  • Test 2 The results of Test 2 are indicated in Table 4. The values indicated in the table correspond to the average value of three measurements. Table 4 Sample Max force [g] Adhesiveness [g ⁇ sec] Example 2 (average value) 3569.443 561.87 Example 2 standard deviation 70 . 774 98.069 Example 4 4303.815 350.142 (average value) Example 4 standard deviation 83.719 56 . 444 Reference (average value) 3276.106 274.227 Reference standard deviation 30.179 12.138
  • Test 2 shows that the product with the greatest adhesiveness is the sample of Example 2 based on ethoxylated amine.
  • a further composition based on ethoxylated amine, Example 4 has higher maximum force values (detaching force), as it adheres better to the Plexiglas probe.
  • the reference sample, based on non-ionic surfactant is the least adhesive and least resistant among the samples tested.

Claims (11)

  1. Adhäsive Zusammensetzung in fester Form oder Gelform zum Reinigen und/oder Parfümieren und/oder sich waschen, wobei die Zusammensetzung unmittelbar auf eine interessierende Oberfläche aufbringbar ist, an der sie ohne Zuhilfenahme von Haltern und/oder Behältern haftet und, wenn sie Spülungen mit Wasser ausgesetzt wird, nur nach mehreren Spülungen vollständig abgewaschen werden kann, wobei die Zusammensetzung dadurch gekennzeichnet ist, dass sie umfasst:
    i) einen Adhäsionspromoter, ausgewählt aus:
    A) mindestens einem Amin der Formel (I)
    Figure imgb0010
     wobei
    - R und R1, gleich oder verschieden voneinander, eine lineare oder verzweigte, gesättigte oder ungesättigte Alkyl-Kette darstellen, die eine Kohlenstoffatom-Anzahl aufweist, welche von C12 bis C22, vorzugsweise von C8 bis C18 variiert;
    - m von 2 bis 4 variiert,
    - mit einer Alkoxylierung gleich x variierend von 15 bis 50, vorzugsweise von 20 bis 40, noch bevorzugter von 25 bis 35 Alkoxyl-Mol; oder
    B) mindestens ein Amin der Formel (I)
    Figure imgb0011
     wobei
    - R eine lineare oder verzweigte, gesättigte oder ungesättigte Alkyl-Kette ist, die eine Kohlenstoffatom-Anzahl aufweist, welche von C12 bis C22, vorzugsweise von C8 bis C18 variiert;
    - R1 eine - (CmH2mO)yH-Gruppe darstellt;
    - m von 2 bis 4 variiert,
    - mit einer Alkoxylierung gleich x+y variierend von 15 bis 50, vorzugsweise von 20 bis 40, noch bevorzugter von 25 bis 35 Alkoxyl-Mol;
    wobei der Adhäsionspromoter in einer Menge im Bereich von 20 Gewichts-% bis 60 Gewichts-% vorliegt, wenn die adhäsive Zusammensetzung in Gelform vorliegt; wobei der Adhäsionspromoter in einer Menge im Bereich von 20 Gewichts-% bis 76 Gewichts-% vorliegt, wenn die adhäsive Zusammensetzung in fester Form vorliegt;
    ii) ein Parfümierungs-Mittel in einer Menge im Bereich von 1 Gewichts-% bis 10 Gewichts-%,
    iii) gegebenenfalls ein Reinigungs-/Schäummittel;
    und wobei die adhäsive Zusammensetzung in fester Form des Weiteren umfasst:
    iv) eine Menge im Bereich von 10 Gewichts-% bis 70 Gewichts-% einer verfestigenden Komponente, die aus Alkanolamiden der Formel (II) ausgewählt ist
    Figure imgb0012
     wobei
    - R2 eine lineare oder verzweigte, gesättigte oder ungesättigte Alkylkette darstellt, die eine Kohlenstoffatom-Anzahl aufweist, welche von C11 bis C17, vorzugsweise von C12 bis C16, noch bevorzugter von C12 bis C14 variiert, und
    - X ein Wasserstoffatom oder eine CH2CH2OH-Gruppe ist;
    wobei die oben angegebenen Gewichtsprozente in Bezug auf das Gesamtgewicht der Zusammensetzung ausgedrückt sind.
  2. Adhäsive Zusammensetzung nach Anspruch 1,
    dadurch gekennzeichnet, dass sie in Gelform vorliegt und eine Viskosität im Bereich von 1.500 Pa·s bis 5.000 Pa·s, vorzugsweise von 2.000 Pa·s bis 4.000 Pa·s aufweist.
  3. Adhäsive Zusammensetzung nach einem der vorhergehenden Ansprüche,
    dadurch gekennzeichnet, dass das Alkoxyl aus Ethylenoxid, Propylenoxid, Butylenoxid mit gemischter Alkoxylierung in Zufalls- und/oder Block-Kombinationen ausgewählt ist.
  4. Adhäsive Zusammensetzung nach einem der vorhergehenden Ansprüche,
    dadurch gekennzeichnet, dass das Amin der Formel (I) ein ethoxyliertes Amin oder ein ethoxyliertes-propoxyliertes Amin ist.
  5. Adhäsive Zusammensetzung nach Anspruch 1,
    dadurch gekennzeichnet, dass das Alkanolamid der Formel (II) Laurinmonoethanolamid oder Kokosnussdiethanolamid ist.
  6. Adhäsive Zusammensetzung nach einem der vorhergehenden Ansprüche,
    dadurch gekennzeichnet, dass die Komponente iii) aus Alkanolamiden der Formel II), aus anionisch- und/oder nicht-ionisch- und/oder amphoterisch-basierten oberflächenaktiven Mischungen und/oder aus Lösemittelmischungen, die auf Propylenglykol, Glycerol und Mischungen von Komplexbildnern wie Phosphonaten, EDTA, Zitraten, Phosphaten, basieren, ausgewählt ist, wobei die Komponente iii) vorzugsweise aus Alkanolamiden der Formel (II) ausgewählt ist.
  7. Adhäsive Zusammensetzung nach einem der vorhergehenden Ansprüche,
    dadurch gekennzeichnet, dass sie ein oder mehrere Verdickungsmittel ausgewählt aus Xanthangummi, Hydroxyethylcellulose, Acrylpolymeren oder Copolymeren, Polyethylenglykol oder Polyethylenglykoldistearaten mit einem Molekulargewicht im Bereich von 200 bis 8.000, Lösemitteln wie Propylenglykol, Glyceroltriacetat, C5-C20 Alkoholen, vorzugsweise C10-C15, umfasst.
  8. Adhäsive Zusammensetzung nach einem der vorhergehenden Ansprüche in Gelform umfassend das alkoxylierte Amin der Formel (I) in einer Menge im Bereich von 20 bis 60 Gewichts-% bezogen auf das Gesamtgewicht der Zusammensetzung, ein Verdickungsmittel in einer Menge im Bereich von 0 bis 5 Gewichts-% bezogen auf das Gesamtgewicht der Zusammensetzung, ein Parfümierungsmittel in einer Menge im Bereich von 1 bis 10 Gewichts-% bezogen auf das Gesamtgewicht der Zusammensetzung und Wasser in einer Menge im Bereich von 79 bis 25 Gewichts-% bezogen auf das Gesamtgewicht der Zusammensetzung.
  9. Verfahren zur Herstellung einer adhäsiven Reinigungs- und/oder Parfümierungs- und/oder Wasch-Zusammensetzung gemäß Anspruch 1, umfassend die folgenden operativen Phasen:
    - falls vorhanden, Erhitzen einer verfestigenden Komponente, um die adhäsive Zusammensetzung in fester Form zu erhalten, auf eine Temperatur, die höher ist als ihr Schmelzpunkt;
    - falls vorhanden, Einarbeiten von Komponente i), Komponente iii) und jeder weiteren Komponente der Zusammensetzung in die Schmelze in beliebiger Reihenfolge, oder, wenn die erste Phase des Vorgangs fehlt, unmittelbares Auflösen in Wasser unter der Voraussetzung, dass das Parfümierungsmittel ii) zuletzt hinzugefügt wird,
    - Homogenisieren der Zusammensetzung durch Mischen bei einer Temperatur im Bereich von 35°C bis 55°C für eine Zeitdauer von 5 bis 30 Minuten,
    - Schütten der Zusammensetzung in einen Behälter,
    - Kühlen der Zusammensetzung bis zur Verfestigung oder bis zur Bildung eines Gels.
  10. Verwendung einer adhäsiven Zusammensetzung in fester Form oder Gelform gemäß einem der Ansprüche 1 bis 8 zum Reinigen und/oder Desinfizieren und/oder Parfümieren von Sanitärvorrichtungen, Haushaltsgeräten, Wänden, Mobiliar durch Aufbringen auf die interessierende Oberfläche.
  11. Verfahren zum Aufbringen einer adhäsiven Zusammensetzung gemäß einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die Zusammensetzung unmittelbar auf die interessierende Oberfläche aufgetragen wird, an der sie ohne Zuhilfenahme von Haltern und/oder Behältern haftet.
EP10175621.1A 2009-10-28 2010-09-07 Klebende reinigungsmittelzusammensetzung Active EP2316914B1 (de)

Priority Applications (2)

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SI201031500T SI2316914T1 (sl) 2009-10-28 2010-09-07 Adheziven detergenten sestavek
HRP20170993TT HRP20170993T1 (hr) 2009-10-28 2017-06-30 Pripravak ljepljivog deterdženta

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Application Number Priority Date Filing Date Title
ITMI2009A001874A IT1396369B1 (it) 2009-10-28 2009-10-28 Composizione adesiva detergente e/o profumante e/o igienizzante.

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EP2316914A1 EP2316914A1 (de) 2011-05-04
EP2316914B1 true EP2316914B1 (de) 2017-04-12

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ES (1) ES2631513T3 (de)
HR (1) HRP20170993T1 (de)
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MX355804B (es) 2012-11-09 2018-04-27 Reckitt Benckiser Llc Dispensador plegable de un solo uso para una composición adhesiva de tratamiento de tocador.
EP2987850A1 (de) * 2014-08-20 2016-02-24 Huntsman International Llc Zusammensetzung für sanitäre Reinigungsmittel
IT201700030886A1 (it) * 2017-03-21 2018-09-21 Deco Ind S Coop P A Formulazione gel deodorante e/o detergente, in particolare per applicazione nei sanitari
JP2022531617A (ja) * 2019-05-10 2022-07-07 ダウ グローバル テクノロジーズ エルエルシー 界面活性剤ブレンド組成物

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WO2009106220A1 (de) 2008-02-29 2009-09-03 Buck-Chemie Gmbh Haftendes mittel zur applikation auf einem sanitärgegenstand
EP1978080B1 (de) 2007-03-29 2016-09-07 Bolton Manitoba SpA Klebrige Hygienisierungszusammensetzung zum Reinigen und/oder Desinfizieren und/oder Parfümieren von sanitären Befestigungsmitteln

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EP1318191B1 (de) 2001-12-06 2006-06-14 Buck-Chemie GmbH . Haftende Paste zur Duftstoffabgabe, insbesondere für den Sanitärbereich
EP1978080B1 (de) 2007-03-29 2016-09-07 Bolton Manitoba SpA Klebrige Hygienisierungszusammensetzung zum Reinigen und/oder Desinfizieren und/oder Parfümieren von sanitären Befestigungsmitteln
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Publication number Publication date
ES2631513T3 (es) 2017-08-31
SI2316914T1 (sl) 2017-10-30
EP2316914A1 (de) 2011-05-04
IT1396369B1 (it) 2012-11-19
ITMI20091874A1 (it) 2011-04-29
PL2316914T3 (pl) 2017-09-29
HRP20170993T1 (hr) 2017-09-22

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