EP2310546B1 - Acier martensitique durci à teneur faible en cobalt, procédé de fabrication d'une pièce à partir de cet acier, et pièce ainsi obtenue - Google Patents

Acier martensitique durci à teneur faible en cobalt, procédé de fabrication d'une pièce à partir de cet acier, et pièce ainsi obtenue Download PDF

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EP2310546B1
EP2310546B1 EP09784484.9A EP09784484A EP2310546B1 EP 2310546 B1 EP2310546 B1 EP 2310546B1 EP 09784484 A EP09784484 A EP 09784484A EP 2310546 B1 EP2310546 B1 EP 2310546B1
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steel
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steel according
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EP2310546A1 (fr
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François ROCH
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Aubert and Duval SA
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26—Methods of annealing
    • C21D1/32—Soft annealing, e.g. spheroidising
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/007—Heat treatment of ferrous alloys containing Co
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/04—Hardening by cooling below 0 degrees Celsius
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/28—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for plain shafts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the invention relates to a martensitic steel hardened by a duplex system, that is to say by a precipitation of intermetallic compounds and carbides obtained by means of a suitable steel composition and heat aging treatment.
  • maraging steels contain quite consistently high levels of nickel, cobalt and molybdenum, all of which are expensive and subject to significant changes in their rating in the commodity market. They also contain titanium, used for its strong contribution to secondary hardening, but which is mainly involved in lowering the fatigue strength of maraging steels due to TiN nitride, which it is almost impossible to avoid training during the making of steels even contains only a few tenths of a percent.
  • This steel is said to be "duplex-hardening" because its hardening is achieved by simultaneous hardening precipitation of intermetallic compounds and M 2 C carbides.
  • the object of the invention is to provide a usable steel, in particular, for manufacturing mechanical parts such as transmission shafts, or structural elements, having a higher resilience while having a high mechanical strength.
  • This steel should also have a lower production cost than the best performing steels currently known for these uses, thanks, in particular, to a significantly lower cobalt content.
  • It preferably contains C 0.20 - 0.25%.
  • It preferably contains Cr 2 - 4%.
  • It preferably contains Al 1 - 1.6%, better 1.4 - 1.6%.
  • It preferably contains Mo + W / 2 1 - 2%.
  • It preferably contains V 0.2 - 0.3%.
  • It preferably contains Ni 12-14%, with Ni ⁇ 7 + 3.5 Al.
  • Nb traces - 0.05%
  • It preferably contains Si traces - 0.25%, better traces - 0.10%.
  • It preferably contains O traces - 10 ppm.
  • N traces - 10 ppm.
  • It preferably contains S traces - 10 ppm, better traces - 5 ppm.
  • It preferably contains P traces - 100 ppm.
  • Its measured martensitic transformation temperature Ms is preferably greater than or equal to 100 ° C.
  • Its martensitic transformation temperature Ms measured may be greater than or equal to 140 ° C.
  • It further preferably comprises a cryogenic treatment at -50 ° C or lower, preferably between -80 ° C and 100 ° C or lower but not below -110 ° C, to convert all the austenite to martensite , the temperature being lower than 150 ° C. or more measured Ms, at least one of said treatments lasting between 4h and 50h and preferably between 4h and 10h.
  • It also preferably comprises a softening treatment of the rough quenching martensite carried out at 150-250 ° C for 4-16h, followed by cooling with still air.
  • the part also preferably undergoes carburizing, or nitriding, or carbonitriding.
  • Nitriding, or carburizing, or carbonitriding can be performed during an aging cycle.
  • Nitriding can be carried out between 475 and 600 ° C.
  • Said nitriding or carburising or carbonitriding can be carried out during a thermal cycle prior to or simultaneously with said dissolution.
  • the invention also relates to a mechanical part or component for structural element, characterized in that it is manufactured according to the preceding method.
  • It may be in particular a motor transmission shaft, or a motor suspension device or a landing gear element or a gearbox element or a bearing axis.
  • the invention is based first of all on a steel composition which differs from the prior art represented by WO-2006/114499 in particular by a lower but still significant Co content, between 1.5 and 4%.
  • the contents of the other most commonly present significant alloying elements are only slightly modified, but certain levels of impurities must be carefully controlled.
  • Co is an expensive element whose content has been significantly reduced compared with the prior art, without, however, eliminating it or bringing it to a very low level.
  • the steel according to the invention generally contains relatively few expensive addition elements, apart from nickel, the content of which, however, is not increased with respect to the prior art. But, it is necessary to take special care during development, to limit the nitrogen content to 20 ppm at most to avoid as much as possible the formation of aluminum nitrides. The maximum levels of titanium and zirconium must also be limited accordingly to prevent nitrides from forming with residual nitrogen.
  • the steel of the invention can be machined in the quenched state, with tools adapted to a hardness of 45HRC. It is intermediate between the maragings (rough machining quench since they have a mild low carbon martensite) and carbon steels that must be machined essentially in the annealed state.
  • a "duplex" curing is carried out, that is to say obtained jointly by intermetallics of ⁇ -NiAl type and carbides of M 2 C type, in the presence of reversion austenite formed / stabilized by diffusion-enriched nickel enrichment during curing aging, which gives ductility to the structure by forming a sandwich structure (a few% of stable and ductile austenite between the slats of hardened martensite).
  • nitrides Ti, Zr and Al in particular, which are weakening: they deteriorate the tenacity and fatigue resistance. Since these nitrides can precipitate from 1 to a few ppm of N in the presence of Ti, Zr and / or Al, and the conventional elaboration means make it difficult to achieve less than 5 ppm of N, the steel of the invention respects the following rules.
  • any addition of Ti (maximum allowed: 100 ppm) is limited, and N is limited as much as possible.
  • the N content should not exceed 20 ppm and more preferably 10 ppm, and the Ti content should not exceed 10 times the N content.
  • Ti and Zr are to be considered as impurities to be avoided, and the sum Ti + Zr / 2 must be ⁇ 150 ppm.
  • rare earths at the end of the elaboration, can also contribute to fix a fraction of N, besides the S and O. In this case, it must be ensured that the residual content of rare earths in free form remains less than or equal to 100 ppm, and preferably less than or equal to 50 ppm, because these elements weaken the steel when they are present beyond these values. It is believed that rare earth (eg La) oxynitrides are less harmful than Ti or Al nitrides because of their globular form which would make them less likely to constitute fatigue fracture primers.
  • Calcium treatment may be practiced to complete the deoxidation / desulfurization of the liquid metal. This treatment is preferably conducted with the possible additions of Ti, Zr or rare earths.
  • the M 2 C carbide of Cr, Mo, W and V containing very little Fe is preferred for its hardening and non-embrittling properties.
  • the carbide M 2 C is metastable with respect to equilibrium carbides M 7 C 3 and / or M 6 C and / or M 23 C 6 . It is stabilized by Mo and W.
  • Mo + W / 2 is between 1 and 2%. It is also to prevent the formation of non-hardening Ti carbides which may weaken the grain boundaries that a 100 ppm imperative limitation of the Ti content of the steels according to the invention is required.
  • Cr and V are elements that activate the formation of "metastable" carbides.
  • V also forms carbides of MC type, stable up to the dissolution temperatures, which "block" the grain boundaries and limit the magnification of grains during heat treatments at high temperatures.
  • V 0.3% must not be exceeded in order not to fix too much C in carbides of V, during the dissolution cycle, to the detriment of the M 2 C carbide of Cr, Mo, W, V which is sought precipitation during the subsequent aging cycle.
  • the V content is between 0.2 and 0.3%.
  • the presence of C favors the appearance of M 2 C with respect to the ⁇ phase. But an excessive content causes segregations, a lowering of Ms and causes difficulties in manufacturing on an industrial scale: sensitivity to the taps (superficial cracking during rapid cooling), difficult machinability of martensite too hard to l quenching state. Its content must be between 0.20 and 0.30%, preferably 0.20-0.25%.
  • the surface layer of the parts may be enriched in C by carburizing or carbonitriding if a very high surface hardness is required in the envisaged applications.
  • Cobalt slightly raises the ductile / brittle transition temperature, which is not favorable, particularly in compositions with low nickel contents, whereas, contrary to what can be observed in other steels, cobalt does not obviously raise the transformation point Ms compositions of the invention and therefore has no obvious interest either in this respect.
  • the invention is based first of all on a steel composition which differs from the prior art represented by WO-2006/114499 in particular by a lower Co content, between 1.5 and 4%, better between 2 and 3%.
  • the contents of the other most commonly present significant alloying elements are only slightly modified, but certain impurity contents must be carefully controlled, especially the contents of Ti, Zr and N which affect the toughness.
  • Co degrades the transition of resilience of pure Fe ( page 52-54 Materials Science and Technology January 1994 Vol. 10 ). Indeed, as has been said the presence of Co increases the ductile / brittle transition temperature. Furthermore, a Co content greater than 1.5% Co is useful for improving the structural hardening by precipitation of M 2 C carbide and thus significantly increasing Rm.
  • a Co content between about 1.5 and 4%, more preferably between 2 and 3%, significantly improves the mechanical strength virtually without degrading the resilience, compared to a very low Co content ( ⁇ 1%) whose composition would, moreover, be identical.
  • Ni and Al are bonded in the invention, where Ni must be ⁇ 7 + 3.5 Al. These are the two essential elements which participate in a good part of aging hardening, thanks to the precipitation of the nanometric intermetallic phase of type B2 (NiAl for example). It is this phase which gives a large part of the mechanical strength when hot, up to about 400 ° C. Nickel is also the element that reduces brittleness by cleavage because it lowers the ductile / brittle transition temperature of martensites. If Al is too high relative to Ni, the martensitic matrix is too strongly depleted of nickel as a result of the precipitation of the NiAl curing precipitate during aging.
  • martensitic transformation start temperature Ms which, according to the invention, should preferably remain equal to or greater than 140 ° C. if no cryogenic cycle is used, and should preferably be between 100 and 140 ° C. if we practice a cryogenic cycle.
  • this formula is only very approximate, in particular because the effects of Co and Al are highly variable from one type of steel to another. To know whether a steel is or not according to the invention, it is therefore necessary to rely on measurements of the actual temperature Ms, made for example by dilatometry as is conventional. Ni content is one of Ms.'s possible adjustment variables
  • the end-of-cooling temperature after quenching must be less than the actual Ms -150 ° C., preferably lower than the actual Ms -200 ° C., in order to ensure a full martensitic transformation of the steel.
  • the end-of-cooling temperature must therefore be lower than the measured temperature Mf of martensitic transformation end of the steel.
  • a cryogenic treatment may be applied immediately following cooling to room temperature from the solution temperature.
  • the overall rate of cooling should be as high as possible to avoid the mechanisms of stabilization of the carbon-rich residual austenite. However, it is not useful to look for cryogenic temperatures below -110 ° C because the thermal agitation of the structure becomes insufficient to produce the martensitic transformation.
  • the Ms value of the steel is between 100 and 140 ° C if a cryogenic cycle is applied, and greater than or equal to 140 ° C in the absence of this cryogenic cycle.
  • the duration of the cryogenic cycle is between 4 and 50 hours, preferably 4 to 16 hours, and more preferably 4 to 10 hours. It is possible to practice several cryogenic cycles, the essential being that at least one of them has the aforementioned characteristics.
  • steels of the class of the invention prefer the presence of B2 hardening phases, especially NiAl, to obtain a high mechanical strength when hot. Compliance with the conditions on Ni and Al that have been given ensures a sufficient potential content of reversion austenite to maintain ductility and toughness suitable for the intended applications.
  • Nb to control grain size during forging or other hot processing at a content not exceeding 0.1%.
  • the steel according to the invention therefore accepts raw materials that can contain significant residual contents in Nb.
  • a characteristic of the steels of the class of the invention is also the possibility of replacing at least a portion of Mo by W.
  • W segregates less at solidification than Mo and provides an increase in mechanical strength when hot. It has the disadvantage of being expensive and we can optimize this cost by associating it with Mo.
  • Mo + W / 2 must be between 1 and 4%, preferably between 1 and 2% . It is preferred to maintain a minimum content of 1% Mo to limit the cost of steel, especially as the high temperature withstand is not a priority objective of the steel of the invention.
  • Cu can be up to 1%. It is likely to participate in the hardening with the help of its epsilon phase, and the presence of Ni makes it possible to limit its harmful effects, in particular the appearance of superficial cracks during the forging of the pieces, which one observes during additions of copper in steels not containing nickel. But its presence is not essential and it may be present only in the state of residual traces, resulting from the pollution of raw materials.
  • Manganese is not a priori useful for obtaining the properties of steel, but it has no recognized adverse effect.
  • its low vapor pressure at the temperatures of the liquid steel makes its concentration difficult to control in vacuum production and vacuum remelting: its content may vary depending on the radial and axial location in a remelted ingot. As it is often present in the raw materials, and for the reasons above, its content will preferably be at most 0.25%, and in any case limited to 2% at most, because of too great variations in its concentration in the same product will interfere with the repeatability of the properties.
  • Silicon is known to have a solid solution hardening effect of ferrite and, like cobalt, to decrease the solubility of certain elements or phases in ferrite.
  • the steel of the invention comprises only relatively little cobalt, and it can do without silicon, especially since, in addition, silicon generally promotes the precipitation of intermetallic phases harmful in complex steels (Laves phase, silicides ). Its content will be limited to 1%, preferably less than 0.25% and still more preferably less than 0.1%.
  • S traces - 20ppm, preferably traces - 10ppm, better traces - 5ppm
  • P traces - 200ppm, preferably traces - 100ppm, better traces - 50ppm.
  • Ca can be used as a deoxidizer and as a sulfur sensor, finding it in the end ( ⁇ 20ppm).
  • rare earth residues may ultimately remain ( ⁇ 100ppm) following a refining treatment of the liquid metal where they would have been used to capture O, S and / or N.
  • the use of Ca and rare earths for these effects not being mandatory, these elements may be present only in the form of traces in the steels of the invention.
  • the acceptable oxygen content is 50 ppm maximum, preferably 10 ppm maximum.
  • Table 1 Composition of the tested samples
  • S ppm 1 4 7 4 6 7 3 8 10 5 4 P ppm 54 30 29 31 30 25 15 28 80 45 29 Or% 13,43 12.67 13,31 12.42 12,30 14,11 12.99 12.70 15,10 11.25 12.91 Cr% 2.76 3.38 2.99 3.05 3.21 3.19 2.95 3.25 3.17 3.17 2.89 Mo% 1.44 1.52 1.61 1.52
  • Reference steel A corresponds to a steel according to US-A-5,393,488 , thus having a high Co content.
  • the reference steel B corresponds to a steel according to WO-A-2006/114 499, it is distinguished from A by a lower Co content and a higher Al content.
  • Steels C to J are in accordance with the invention in all respects, in particular by their Co content, which is significantly lower than that of steel. B, but which nevertheless remains substantially higher than a simple residual content and is obtained by a deliberate addition during the preparation.
  • Steel D differs from C by a slightly lower Co content for a lower Ni content, and by the absence of V, which is present only in trace amounts.
  • Steel E is distinguished from D by a Co content even lower than that of D and by a V content at a level comparable to steel C.
  • Steel F is distinguished from C, D, E mainly by a slightly higher Ni content, its Co content being comparable to that of E steel.
  • Steel G differs from steels C to F by an even lower Co content and has no V.
  • Steel H is distinguished from Steel G by a further steepening of the Co content and a significantly higher boron content.
  • Steel I is distinguished from Steel H by further lowering of Co content, and lower C content with higher Ni content.
  • Steel J is the one whose composition has the lowest Co content, while corresponding to a voluntary addition and which remains in accordance with the invention. It also has the lowest Ni content and contains V.
  • the reference steel K has a low Co content and below the minimum required by the invention. It is comparable on the other points to steels according to the invention without V and B and very low N.
  • the samples were softened at a temperature of at least 600 ° C.
  • this softening income was carried out at 650 ° C. for 8 hours and followed by cooling in air. Thanks to this, the raw products of thermomechanical transformations can undergo without particular problems the finishing operations (straightening, peeling, machining ...) giving the piece its final form. It will be noted that the softening income does not contribute to obtaining the final mechanical characteristics.
  • the desired resilience / resilience tradeoff could be further refined through a modification of the aging conditions, but the adjustment of the Co content remains the key parameter that must be used to achieve this compromise.
  • the hardening provided by the increase of Al, with the high Ni, to form the hardening phase NiAl, is not proportional to the concentration of Al, and exceed a value of 2% in Al does not bring gain significant on the tensile strength.
  • Nb and B of the samples D and H respectively are not necessary to obtain the high mechanical strengths targeted primarily in the steels of the class of the invention.
  • the addition of Nb makes it possible to refine the grain size, described by the conventional ASTM index (the highest ASTM values corresponding to the finest grains).
  • thermomechanical treatments for hot and / or cold forming can be carried out in addition to or in place of this forging, depending on the type of end product that is desired (stamped parts, bars). , semi-finished products ).
  • the preferred applications of the steel according to the invention are the endurance parts for mechanics and structural elements, for which a tensile strength greater than 2150 MPa must be cold, combined with higher values of resilience than better high-strength steels, and hot (400 ° C) a tensile strength of the order of 1800 MPa, as well as optimal fatigue properties.
  • the steel according to the invention also has the advantage of being cementable, nitrurable and carbonitrurable.
  • the parts that use it can therefore be given high abrasion resistance without affecting its core properties. This is particularly advantageous in the intended applications that have been cited.
  • the carburizing, or the nitriding, or the carbonitriding can, possibly, be carried out during the heat treatments of aging or dissolution in solution, instead of being carried out during a separate step.
  • nitriding can be carried out between 475 and 500 ° C during an aging cycle.

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EP09784484.9A 2008-07-15 2009-07-08 Acier martensitique durci à teneur faible en cobalt, procédé de fabrication d'une pièce à partir de cet acier, et pièce ainsi obtenue Active EP2310546B1 (fr)

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PCT/FR2009/051351 WO2010007297A1 (fr) 2008-07-15 2009-07-08 Acier martensitique durci à teneur faible en cobalt, procédé de fabrication d'une pièce à partir de cet acier, et pièce ainsi obtenue

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Publication number Publication date
FR2933990B1 (fr) 2010-08-13
RU2011105417A (ru) 2012-08-20
ES2624912T3 (es) 2017-07-18
JP5710478B2 (ja) 2015-04-30
WO2010007297A1 (fr) 2010-01-21
CA2730520C (fr) 2016-11-22
CN102131947B (zh) 2013-03-27
US9175370B2 (en) 2015-11-03
CN102131947A (zh) 2011-07-20
PL2310546T3 (pl) 2017-08-31
CA2730520A1 (fr) 2010-01-21
US20110226386A1 (en) 2011-09-22
RU2497974C2 (ru) 2013-11-10
EP2310546A1 (fr) 2011-04-20
FR2933990A1 (fr) 2010-01-22
JP2011528068A (ja) 2011-11-10

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