EP2271309A1

EP2271309A1 - Shampoo with fruit juice and/or vegetable juice

Info

Publication number: EP2271309A1
Application number: EP09741917A
Authority: EP
Inventors: Erik Schulze Zur Wiesche; Thomas Förster
Original assignee: Henkel AG and Co KGaA
Current assignee: Henkel AG and Co KGaA
Priority date: 2008-05-07
Filing date: 2009-02-02
Publication date: 2011-01-12
Also published as: US20110052735A1; DE102008022712A1; WO2009135699A1

Abstract

The invention relates to shampoos, which endow the hair, treated therewith, with advantageous properties in relation to strength, handle and tensile strength as well as combability in the dry and wet states and, at the same time, are particularly mild and ecologically compatible, and contain, in a cosmetically acceptable carrier, 0.1 to 35% by weight of at least one surfactant and 15 to 85% by weight of at least one fruit juice or vegetable juice.

Description

"Hair cleanser with fruit and / or vegetable juice"

The present invention relates to hair treatment compositions containing fruit juice and / or vegetable juice or more of these juices.

Particularly in the case of hair cleansing, an increased awareness of hygiene leads to an ever more frequent cleaning of the hair. In order to be here in addition to optimal cleaning and hair care long-term, the funds used must be particularly mild to the hair and scalp. Although mild surfactants from a wide variety of groups are known per se, these do not yet sufficiently satisfy all consumer wishes. For example, it has been shown that frequent hair washing can affect the structure of the keratin fibers, thus requiring the addition of certain substances which enhance the internal structure of the keratin fibers and thus improve the strength, feel and tensile strength of keratin fibers. There is therefore a need for active ingredients or combinations of active ingredients for hair cleansing compositions which not only do not impair the structure of the fibers treated with them but on the contrary improve them. In addition, there is an increasing consumer desire to use "LOHAS" -based cosmetics LOHAS is a marketing term that stands for "Lifestyle of Health and Sustainability" and defines a new lifestyle or consumer type that impacts on consumer health and health Sustainability oriented. It is an object of the present invention to provide hair-cleansing compositions which impart advantageous properties in terms of strength, feel and tensile strength as well as combability in the dry and wet state to the hair treated with them and which are particularly mild and ecologically compatible.

It is known to use plant extracts in cosmetic products to give the products a specific property profile. It has now been found that high amounts of fruit and / or vegetable juices also have a very beneficial effect on keratinic fibers, wherein the effect can be increased even by a special formulation of the products by the products are formulated PEG-free.

In a first embodiment, the subject matter of the present application is hair treatment compositions comprising, in a cosmetically acceptable carrier, based on their weight,

(a) 0.1 to 35% by weight of at least one surfactant,

(B) 15 to 85 wt .-% of at least one fruit or vegetable juice.

The compositions according to the invention can be used as hair shampoos, hair conditioners, conditioning shampoos, as hairsprays, hair rinses, hair treatments, hair wraps, hair tonics, perming solutions, hair dye shampoos, hair dyes, hair fixatives, hair dressings, hairstyling preparations, eg Fönwell lotions, mousses, hair gels, Hair waxes and others Hair cleaning and hair treatment products are formulated. They may be formulated as "leave-on" or "rinse-off" products on the hair, the latter being preferred.

Agents preferred according to the invention comprise at least one fruit juice, this being preferably used within narrower ranges of amounts. Hair treatment agents which are preferred according to the invention are characterized in that they contain, based on their weight, from 20 to 80% by weight, preferably from 25 to 75% by weight, more preferably from 30 to 70% by weight and in particular from 35 to 60% by weight. contain at least one fruit juice.

Fruit juice (fruit juice) in the sense of the present invention is the fermentable, but not fermented juice obtained from fruits by means of mechanical methods. Equally juxtaposed with these fruit juices are concentrated fruit juices obtained by adding concentrated water (in the form of water of appropriate quality) and the separated volatile flavorings to reconstituted juices (so-called reconstituted fruit juices). The pulp separated in the concentration of the original fruit juice or juices of the same fruit type may be added to the reconstituted fruit juice up to the amount contained in the original juice. Fruit juices are either produced directly from fresh fruit as "juice" and bottled or obtained from semi-finished products, such as fruit juice concentrates or powdered fruit pulp or fruit pulp concentrates. Particularly preferred fruit juices to be used are - individually or mixed with one another - apple juice and / or orange juice and / or other citrus fruits. In summary, hair-treatment compositions according to the invention are preferred which contain at least one fruit juice from the group of apple juice, orange juice, grape juice, lemon juice, lime juice, lime juice, grapefruit juice, currant juice, cherry juice, shadow morel juice, apricot juice, peach juice, nectarine juice, plum juice, mirabelle juice, passion fruit juice, plum juice, puree raspberry juice, blackberry juice , Raspberry juice, strawberry juice, pineapple juice, pomegranate juice, lychee juice, mango juice, tangerine juice, papaya juice, pitahaya juice, star fruit juice, pear juice, quince juice, medlar juice, grape juice, rowan juice, gooseberry juice, huckleberry juice, cranberry juice, tangerine juice, cranberry juice, elderberry juice, chokeberry juice, sea buckthorn juice.

In addition to the fruit juice or juices or at its place, the compositions according to the invention may contain vegetable juice or vegetable juices. Again, the amounts are preferably within narrower ranges. Hair treatment agents preferred according to the invention are characterized in that they contain, based on their weight, 20 to 80% by weight, preferably 25 to 75% by weight, more preferably 30 to 70% by weight and in particular 35 to 60% by weight. contain at least one vegetable juice. Vegetable juice is the name given to the juice produced from vegetables after comminution, pressing or centrifuging and pasteurisation or sterilization, undiluted and preserved. According to the German Food Book, vegetable juice is the undiluted, fermentable, fermented and fermented or lactic fermented, liquid vegetable product intended for direct consumption. Vegetable juice can then also be made from concentrate of vegetable juice or -mark. Similar to the fruit juice, a vegetable juice or vegetable concentrate can be produced by thickening, which saves storage and transport costs. To produce the juice then the withdrawn amount of water is added again, the water must have at least drinking water quality. If necessary, the aroma of the vegetable juice is restored by means of the volatile flavorings which have been absorbed during the thickening of the vegetable juice in question. The intermediate thickening must be recognizable in the juice description, z. For example, by stating "from ... concentrate". Tomatoes are mainly processed, but also cucumbers, carrots, radishes, beets, sauerkraut, celery and spinach. In contrast to fruit juice, cellulolytic and hemicellulolytic enzymes may also be used in vegetable juice production. Acidification by lactic acid fermentation or citric acid additives is common. Vegetable juices to be used particularly preferably are - individually or mixed with one another - rhubarb juice and / or chard juice. In summary, hair-treatment compositions according to the invention are preferred which contain at least one vegetable juice from the group rhubarb juice, kohlrabi juice, celeriac juice, carrot juice, beetroot juice, onion juice, leek juice, garlic juice, white cabbage juice, asparagus juice, spinach juice, chard juice, tomato juice, cucumber juice, pumpkin juice, pea juice, bean juice, Artichoke juice, cauliflower juice, kale juice, red cabbage juice, broccoli juice, Brussels sprouts juice included.

For ecological reasons and taking into account the sustainability aspect, fruits and vegetables from organic cultivation are to be preferred. Hair-treatment compositions according to the invention which contain exclusively fruit and / or vegetable juices from controlled organic cultivation are therefore particularly preferred.

It has further been found that the agents according to the invention should preferably be formulated free of polyethylene glycols, since polyethylene glycols can reduce the positive effects of the fruit and / or vegetable juices. Preferred agents according to the invention are therefore characterized in that they do not contain compounds of the formula (I)

H- (O-CH ₂ CH ₂ ) _n -OH (I),

in which n stands for integers between 1 and 100,000.

The hair treatment compositions of this embodiment according to the invention are free of

Polyethylene glycols of the general formula (I), i. they neither contain ethylene glycol (n = 1) nor

Products with a degree of polymerisation P _n = 2-4 (diethylene glycol, triethylene glycol and

Tetraethylene glycol) or polyethylene glycols with higher degrees of polymerization P _n of about 5 to

100,000, which are no longer molar-uniform producible, but polydisperse.

Surprisingly, the omission of compounds of formula (I) leads to the fruit and / or

Vegetable juices develop their effect on the hair significantly better. In particular, the strengthening of keratinic fibers, resulting in improved combabilities in dry and especially in wet

Condition shows and the fullness and smoothness are improved.

Preferably, the agents according to the invention are not only free of polyethylene glycols but also of polypropylene glycols (PPG). Hair treatment agents preferred according to the invention are characterized in that they do not contain any compounds of the formula (I)) H- (O-CH (CH ₃ ) CH ₂ ) _n -OH (II),

in which n stands for integers between 1 and 100,000.

Such preferred hair treatment compositions according to the invention are free of polypropylene glycols of the general formula (II), ie they contain neither propylene glycol (n = 1) nor products with a degree of polymerisation P _n = 2-4 (dipropylene glycol, tripropylene glycol and tetrapropylene glycol) or polypropylene glycols with higher degrees of polymerization P _n from about 5 to 100,000, which are no longer molar - uniform producible, but polydisperse. These compounds also hinder the development of the effect of the fruit and / or vegetable juices on the hair, so that the improved effects can be observed by dispensing with their use.

It has been found that preferably should be dispensed with the use of ethoxylated compounds. In particular, nonionic surfactants of the alkyl or alkenyl ethoxylate type also reduce the positive effects of the fruit and / or vegetable juices and should therefore not be used in the formulations. According to further preferred hair cleansing compositions are therefore characterized in that they are not compounds of formula (INI)

R- (O-CH ₂ CH ₂ ) _n -OH (III),

wherein R represents any alkyl or alkenyl radical and n represents integers between 1 and 10,000.

Ethoxylated anionic surfactants can also - albeit to a lesser extent - have the positive effect of

Fruit and / or vegetable juices diminish. In particular, alkyl ether sulfates have been found to be problematic here, while alkyl ether carboxylates show less effect-reducing effects than the ether sulfates. Preferred hair treatment compositions according to the invention therefore contain no

Compounds of the formula (IV)

R- (O-CH ₂ CH ₂ J _n -OSO ₃ H (IV),

where R is any alky or alkenyl radical and n is an integer between 1 and 10,000. In particularly preferred inventive agents is completely dispensed with the use of compounds having ethoxylated groups. Interestingly, a hydroxyethyl moiety (eg, in certain surfactants) does not affect the action of the fruit and / or vegetable juices, while ethylene glycol affects the effect. Preferred hair treatment compositions according to the invention therefore contain no compound which contains the grouping - (O-CH ₂ CH ₂ ) _n -O- with n = 1-10,000. Particularly preferred hair treatment compositions according to the invention are characterized in that they contain no compounds which contain the grouping of the formula (V)

- (O-CH ₂ CH ₂ J _n - (V), in which n stands for integers between 2 and 100,000.

The compositions according to the invention contain from 0.1 to 35% by weight of at least one surfactant. As already mentioned above, ethoxylated nonionic surfactants are preferably eliminated; anionic surfactants from the groups of the alkyl ether sulfates are also preferably not used. As will be discussed in detail below, preferred agents are also free of alkyl sulfates. Particularly preferred is the use of amphoteric and / or zwitterionic surfactants.

Particularly preferred hair treatment compositions according to the invention are characterized in that they contain amphoteric surfactant (s) from the groups of N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyl Alkyltaurines, N-alkylsarcosines, 2-Alkylaminopropionsäuren each having about 8 to 24 carbon atoms in the alkyl group, Alkylaminoessigsäuren each having about 8 to 24 carbon atoms in the alkyl group, N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate Ci ₂ - Ci ₈ - acylsarcosine , N-alkyl-N, N-dimethylammonium glycinates, for example, cocoalkyl dimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammoniumglycinate, for example Kokosacylaminopropyl- dimethylammoniumglycinat, 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazoline with in each case 8 to 18 carbon atoms in the alkyl or acyl group Kokosacylaminoethylhydroxyethylcarboxymethylglycinatder known under the INCI name cocamidopropyl betaine n compounds containing compounds known by the INCI name Disodium Cocoamphodiacetate, preferred agents comprising the amphoteric surfactant (s) in amounts of from 0.5 to 9% by weight, preferably from 0.75 to 8 Wt .-% and in particular from 1 to 7.5 wt .-%, each based on the total agent included. Particularly preferred hair treatment compositions contain as amphoteric surfactants betaines of the formula (VI)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms. These surfactants are referred to according to the INCI nomenclature as Amidopropylbetaine, wherein the representatives derived from coconut fatty acids, are preferred and are referred to as Cocoamidopropylbetaine. According to the invention, particular preference is given to using surfactants of the formula (II) which are a mixture of the following representatives: H ₃ C- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) ₉ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) ii-C ( O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) i ₃ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) i ₅ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^~

Particular preference is given to using surfactants of the formula (VI) within narrower ranges of amounts. Here, agents according to the invention are preferred which, based on their weight, are from 0.25 to 8% by weight, more preferably from 0.5 to 7% by weight, more preferably from 0.75 to 6.5% by weight and in particular 1 to 5.5 wt .-% of surfactant (s) of the formula (VI). In addition to the amphoteric surfactant (s) of the formula (VI) or in its place, the hair-treatment compositions according to the invention may be used with particular preference as amphoteric surfactants betaines of the formula (VII)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms. These surfactants are referred to according to the INCI nomenclature as amphoacetates, wherein the representatives derived from coconut fatty acids are preferred and are referred to as cocoamphoactetates. For reasons of production technology, surfactants of this type always also contain betaines of the formula (VIIa)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms and M is a cation. These surfactants are referred to according to the INCI nomenclature as Amphodiacetate, wherein the representatives derived from coconut fatty acids are preferred and are referred to as Cocoamphodiactetate. According to the invention, particular preference is given to using surfactants of the formula (VII) which are a mixture of the following representatives: H ₃ C- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH ) CH ₂ CH ₂ COO ^~, H ₃ C- (CH ₂₎ ₉ -C (O) -NH- (CH _Z) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^"H ₃ C- (CH ₂ ) ₁₁ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) ₁₃ -C (O) -NH - (CH ₂₎ ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^~, H ₃ C- (CH ₂₎ ₁₅ -C (O) -NH- (CH ₂₎ ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^" , H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH ) CH ₂ CH ₂ COO ^"

Particular preference is given to using surfactants of the formula (VII) within narrower ranges of amounts. Here, agents according to the invention are preferred which, based on their weight, are from 0.25 to 8% by weight, more preferably from 0.5 to 7% by weight, more preferably from 0.75 to 6.5% by weight and in particular 1 to 5.5 wt .-% of surfactant (s) of the formula (VII). In summary, hair treatment compositions according to the invention are preferred in which the radical R in the formulas (VI) and (VII) is selected from H ₃ C- (CH ₂ ) _/ -, H ₃ C- (CH ₂ ) _9- , H ₃ C- (CH ₂ ) _H -, H ₃ C- (CH ₂ ) ₁₃ -, H ₃ C- (CH ₂ ) ₁₅ -, H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ - or Mixtures of these.

Particularly preferred nonionic surfactants are alkyl polyglycosides. Accordingly, hair treatment compositions according to the invention are preferred which, as nonionic surfactants - based on their weight - 0.1 to 20 % By weight of alkylpolyglycosides of the general formula RO- (Z) _x , where R is alkyl, Z is sugar and x is the number of sugar units.

The agents according to the invention may also contain the alkyl and / or alkenyl oligoglucosides and acylasparaginates in a weight ratio of 1:99 to 99: 1, preferably 10:90 to 90:10 and in particular 80:20 to 50:50.

The care effects of the compositions according to the invention can be further enhanced by using certain care substances. These are preferably selected from certain groups of known care substances, since these care substances harmonize perfectly with the fruit and / or vegetable juices used in accordance with the formulation and from the care effect. According to preferred hair treatment compositions are characterized in that they additionally care substance (s) - based on their weight - in amounts of 0.001 to 10 wt .-%, preferably 0.005 to 7.5 wt .-%, particularly preferably 0.01 to 5 wt .-% and in particular 0.05 to 2.5 wt .-%, with preferred care substance (s) are selected from the group i. L-carnitine and / or its salts; ii. Panthenol and / or panthothenic acid; iii. the 2-furanones and / or their derivatives, in particular pantolactone; iv. Taurine and / or its salts; v. niacinamide; vi. Ubiquinone vii. Ectoin; viii. Allantoin.

In hair treatment compositions according to the invention of this embodiment, the surfactant / fruit and / or vegetable juice combination is combined with at least one care substance which is selected from L-carnitine and / or its salts, panthenol and / or pantothenic acid, 2-furanones and / or their Derivatives, especially pantolactone, taurine and / or its salts, niacinamide, ubiquinones, ectoine, allantoin. These care substances are described in the priority document

Preferred hair treatment compositions according to the invention are characterized in that they contain from -0.001 to 10% by weight, preferably 0.005 to 7.5% by weight, particularly preferably 0.01 to 5% by weight and in particular 0.05% by weight contain up to 2.5 wt .-% L-carnitine or L-carnitine derivatives, with preferred L-carnitine derivatives are selected from acetyl-L-carnitine, L-carnitine fumarate, L-carnitine citrate, lauroyl-L-carnitine and in particular L-carnitine tartrate.

Preferred hair treatment compositions according to the invention are characterized in that they contain, based on their weight, from 0.01 to 5% by weight, preferably from 0.05 to 2.5% by weight, particularly preferably from 0.1 to 1.5% by weight. % and in particular 0.25 to 1 wt .-% of panthenol ((±) -2,4-dihydroxy-Λ / - (3-hydroxypropyl) -3,3-dimethyl-butyramide).

According to the invention preferred hair treatment compositions contain - based on their weight - 0.01 to 15 wt .-%, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7 , 5% by weight and in particular 0.5 to 5% by weight of at least one 2-furanone derivative of the formula (Fur-I) and / or of the formula (Fur-II) in which the radicals R ¹ to R ^{10 are} independently of one another

Hydrogen, -OH, a methyl, methoxy, aminomethyl or hydroxymethyl radical,

--C ₂ - C ₄ - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical,

--C ₂ - C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,

--C ₂ - C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,

a group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear Mono-, di- or trihydroxyhydrocarbyl radical,

- a group -NR ¹² R ¹³ , wherein R ¹² and R ¹³ each independently represent hydrogen, a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,

a group -COOR ¹⁴ , where R ¹⁴ is hydrogen, a methyl, a C ₂ -C ₄

- saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ - C ₄ - saturated mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical, a -C ₂

C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,

- a group -CONR ¹⁵ R ¹⁶ , wherein R ¹⁵ and R ¹⁶ each represent hydrogen, methyl, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ - saturated mono- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,

a group -COR ¹⁶ , wherein R ¹⁶ is a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or -or- or diunsaturated, branched or linear mono-, di- or Trihydroxyhydrocarbyl radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,

- a group -OCOR ¹⁷ , wherein R ¹⁷ is a methyl, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₃₀ - saturated or on or - polyunsaturated, branched or linear mono-, di-, tri- or Polyhydroxykohlenwasserstoffrest, a -C ₂ - C ₃₀ - saturated or mono- or polyunsaturated, branched or linear mono-, di-, tri- or polyamino hydrocarbon radical, with the proviso in that, when R ⁷ and R ^{8 are} -OH and at the same time R ⁹ or R ^{10 is} hydrogen, the remaining group R ⁹ or R ¹⁰ does not represent a dihydroxyethyl radical. According to the invention preferred hair treatment compositions contain - based on their weight - 0.01 to 15 wt .-%, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7 , 5 wt .-% and in particular 0.5 to 5 wt .-% taurine (2-aminoethanesulfonic acid). In summary, hair-treatment compositions according to the invention are preferred which, based on their weight, are 0.1 to 5% by weight, preferably 0.2 to 4% by weight, more preferably 0.25 to 3.5% by weight, more preferably Contain 0.5 to 3 wt .-% and in particular 0.5 to 2.5 wt .-% vitamins and / or pro-vitamins and / or vitamin precursors, preferably the groups A, B, C, E, F and H. 2,4-dihydroxy-Λ / - (3-hydroxypropyl) -3,3-dimethylbutyramide, provitamin B ₅ ) and / or pantothenic acid (vitamin B ₃ , vitamin B ₅ ) and / or Niacin, niacinamide or nicotinamide (vitamin B ₃ ) and / or L-ascorbic acid (vitamin C) and / or thiamine (vitamin B ₁ ) and / or riboflavin (vitamin B ₂ , vitamin G) and / or biotin (vitamin B ₇ , Vitamin H) and / or folic acid (vitamin B ₉ , vitamin B _c or vitamin M) and / or vitamin B ₆ and / or vitamin B ₁₂ .

It has been shown that certain quinones have a special suitability as a care substance. As a further care substance, the compositions according to the invention can therefore contain from 0.0001 to 5% by weight of at least one biochinone of the formula (Ubi)

contained in the

X, Y, Z are independently -O- or -NH- or NR- or a chemical bond

R ^1, R ^2, R ³ independently represent a hydrogen atom or an optionally substituted aryl group or an optionally substituted _(C-ι-C6) alkyl group or a hydroxyalkyl group or a polyhydroxyalkyl group or an optionally substituted (C ₁ -C ₆₎ - Alkylene group, or a (Ci-C ₆ ) acyl radical, wherein preferred radicals are independently selected from -H, -CH ₃ , -CH ₂ CH ₃ , - (CH ₂ ) ₂ CH ₂ , -CH (CH ₃ ) ₂ , - (CH ₂ ) ₃ CH ₃ , -CH (CH ₃ ) CH ₂ CH ₃ , -CH ₂ CH (CH ₃ ) ₂ , -C (CH ₃ ) ₃ R ⁴ is -CH ₃ , -CH ₂ CH ₃ , - (CH ₂ ) ₂ CH ₂ , -CH (CH ₃ ) ₂ , - (CH ₂ ) ₃ CH ₃ , -CH (CH ₃ ) CH ₂ CH ₃ ,

-CH ₂ CH (CH ₃ ) ₂ , -C (CH ₃ ) ₃ n is from 1 to 20, preferably from 2 to 15 and especially 5,

6, 7, 8, 9, 10.

Particularly preferred hair treatment compositions according to the invention are characterized in that they contain as care substance - based on their weight - 0.0001 to 1 wt .-%, preferably 0.001 to 0.5 wt .-% and particularly preferably 0.005 to 0.1 wt .-% containing at least one ubiquinone and / or at least one ubiquinol and / or at least one derivative of these substances, preferred agents containing a ubiquinone of the formula (Ubi)

(Ubi), in which n stands for the values = 6, 7, 8, 9 or 10, particularly preferably 10 (coenzyme Q10).

As an alternative to the particularly preferred ubiquinones or in addition to them, the agents according to the invention may also contain plastoquinones. Here, preferred agents according to the invention are characterized in that they are 0.0002 to 4 wt .-%, preferably 0.0005 to 3 wt .-%, particularly preferably 0.001 to 2 wt .-%, more preferably 0.0015 to 1 and in particular 0.002 to 0.5 wt .-% of at least one plastoquinone of the formula (Ubi-b)

in which n stands for values of 1 to 20, preferably of 2 to 15 and in particular for 5, 6, 7, 8, 9, 10, whereby particularly preferred means Plastochinon PQ-9 of the formula

contain.

Hair treatment compositions which are preferred according to the invention are characterized in that they contain, based on their weight, from 0.001 to 10% by weight, preferably from 0.01 to 5% by weight, particularly preferably from 0.05 to

2.5 wt .-% and in particular 0.1 to 1 wt .-% of (S) -2-methyl-1, 4,5,6-tetrahydro-4-pyrimidinecarboxylic acid

(Ectoine) and the physiologically acceptable salts of this compound and / or (S, S) -5-hydroxy-2-methyl-1, 4,5,6-tetrahydro-4-pyrimidinecarboxylic acid (hydroxyectoine) and the physiologically acceptable

Salts of this compound, included.

Particularly preferred hair treatment compositions according to the invention contain - based on their weight -

0.001 to 10 wt .-%, preferably 0.01 to 5 wt .-%, particularly preferably 0.05 to 2.5 wt .-% and in particular 0.1 to 1 wt .-% 5-ureidohydantoin (allantoin).

Preferred agents of the invention contain purine and / or purine derivatives in closer

Tonnage bands. Here are inventively preferred cosmetic agents characterized in that they - based on their weight - 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt .-% and in particular 0.01 to 0.1% by weight of purine (s) and / or

Purine derivative (s) included.

Among purine, the purines and the purine derivatives, some representatives are particularly preferred according to the invention. Hair treatment compositions which are preferred according to the invention are characterized in that they contain as care substance - based on their weight - from 0.001 to 2.5% by weight, preferably from 0.0025 to 1% by weight, particularly preferably from 0.005 to 0.5% by weight and in particular 0.01 to 0.1% by weight of purine (s) and / or

Purine derivative (s), preferred agents containing purine and / or purine derivative (s) of formula (Pur-I)

in which the radicals R ¹ , R ² and R ^{3 are} independently selected from -H, - OH, NH ₂ , -SH and the radicals R ⁴ , R ⁵ and R ^{6 are} independently selected from -H, -CH ₃ and -CH ₂ -CH ₃ , where the following compounds are preferred: purine (R ¹ = R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H), adenine (R ¹ = NH ₂ , R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H), guanine (R ¹ = OH, R ² = NH ₂ , R ³ = R ⁴ = R ⁵ = R ⁶ = H), uric acid (R ¹ = R ² = R ³ = OH, R ⁴ = R ⁵ = R ⁶ = H), hypoxanthine (R ¹ = OH, R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H), 6-purine thiol (R ¹ = SH, R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H), 6-thioguanine (R ¹ = SH, R ² = NH ₂ , R ³ = R ⁴ = R ⁵ = R ⁶ = H), xanthine ( R ¹ = R ² = OH, R ³ = R ⁴ = R ⁵ = R ⁶ = H), caffeine (R ¹ = R ² = OH, R ³ = H, R ⁴ = R ⁵ = R ⁶ = CH ₃ ) , Theobromine (R ¹ = R ² = OH, R ³ = R ⁴ = H, R ⁵ = R ⁶ = CH ₃ ), theophylline (R ¹ = R ² = OH, R ³ = H, R ⁴ = CH ₃ , R ⁵ = CH ₃ , R ⁶ = H). It is also advantageous to use purine or purine derivatives and biochinones in a certain ratio to each other. Here, agents according to the invention are preferred in which the weight ratio of purine (derivative (s)) and biochinone (s) is 10: 1 to 1: 100, preferably 5: 1 to 1:50, particularly preferably 2: 1 to 1:20 and in particular 1: 1 to 1:10. As already mentioned, caffeine is a particularly preferred purine derivative, and coenzyme Q10 is a particularly preferred biochinone. Particularly preferred agents according to the invention are therefore characterized in that they contain, based on their weight, from 0.001 to 2.5% by weight, preferably from 0.0025 to 1% by weight, particularly preferably from 0.005 to 0.5% by weight and in particular 0.01 to 0.1 wt .-% caffeine and 0.0002 to 4 wt .-%, preferably 0.0005 to 3 wt .-%, particularly preferably 0.001 to 2 wt .-%, more preferably 0.0015 to 1 and in particular 0.002 to 0.5 wt .-% coenzyme Q10 included. According to the invention particularly preferred hair treatment compositions are characterized in that they - based on their weight - 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt .-% and in particular 0.01 to 0.1% by weight of flavonoids, in particular flavonols, more preferably 3,3 ', 4', 5,7-pentahydroxyflavone (quercetin) and / or 3,3 ', 4', 5,7-pentahydroxyflavone -3-O-rutinoside (rutin), included.

Preference is also the use of bisabolol and / or bisabololoxides as a care substance in the inventive compositions. Hair-treatment compositions according to the invention which additionally contain 0.001 to 5 wt.%, Preferably 0.01 to 4 wt.%, Particularly preferably 0.02 to 2.5 wt.% And in particular 0.1 to 1.5 wt % Bisabolol and / or oxides of bisabolol, preferably (-) - alpha-bisabolol.

Creatine is also suitable as a care substance according to the invention. Particularly preferred hair treatment compositions according to the invention contain - based on their weight - 0.01 to 15 wt .-%, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% Λ / -methyl-guanidino-acetic acid (creatine).

The compositions according to the invention may contain, in addition to the ingredients mentioned above and optional further ingredients, other substances which prevent, alleviate or cure hair loss. In particular, a content of hair root stabilizing agents is advantageous. In summary, hair treatment compositions according to the invention are preferred which additionally contain, based on their weight, from 0.001 to 5% by weight of hair root stabilizing substances, in particular minoxidil and / or finasteride and / or ketoconazole.

In summary, hair treatment compositions according to the invention are preferred which additionally contain, based on their weight, from 0.001 to 5% by weight of antidandruff active ingredients, in particular piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4-tri-methylpentyl) -pyridine-2 ( 1 H) -one, compound with 2-aminoethanol, 1: 1) and / or zinc pyrithione and / or selenium sulfide and / or climbazole and / or salicylic acid or fumaric acid.

In addition to the care substances, the agents according to the invention may contain further care substances. Their presence is not absolutely necessary for achieving the effects according to the invention, but further effects, such as a pleasant touch or a pleasant application feel, can result from the use of these care substances. As a further ingredient, the agents according to the invention may with particular preference contain one or more amino acids. Particularly preferred amino acids which can be used according to the invention are from the group glycine, alanine, valine, leucine, isoleucine, phenylalanine, tyrosine, tryptophan, proline, aspartic acid, glutamic acid, asparagine, glutamine, serine, threonine, cysteine, methionine, lysine, arginine, histidine, β Alanine, 4-aminobutyric acid (GABA), betaine, L-cystine (L-Cyss), L-carnitine, L-citrulline, L-theanine, 3 ', 4'-dihydroxy-L-phenylalanine (L-dopa), 5'-hydroxy L-tryptophan, L-homocysteine, S-methyl-L-methionine, S-allyl-L-cysteine sulfoxide (L-alliin), L-trans-4-hydroxyproline, L-5-oxoproline (L-pyroglutamic acid), L-phosphoserine, creatine, 3-methyl-L-histidine, L-ornithine, whereby both the individual amino acids and mixtures can be used. Preferred agents according to the invention contain one or more amino acids in narrower quantitative ranges. Here, according to the invention preferred hair treatment compositions are characterized in that they as care substance - based on their weight - 0.01 to 5 wt .-%, preferably 0.02 to 2.5 wt .-%, particularly preferably 0.05 to 1, 5 Wt .-%, more preferably 0.075 to 1 wt .-% and in particular 0.1 to 0.25 wt .-% amino acid (s), preferably from the group glycine and / or alanine and / or VaNn and / or lysine and / or leucine and / or threonine. As a further component, the agents according to the invention may contain at least one carbohydrate from the group of monosaccharides, disaccharides and / or oligosaccharides. Here are preferred hair treatment compositions according to the invention characterized in that they are used as care substance - based on their weight - 0.01 to 5 wt .-%, preferably 0.05 to 4.5 wt .-%, particularly preferably 0.1 to 4 wt. -%, more preferably 0.5 to 3.5 wt .-% and in particular 0.75 to 2.5 wt .-% carbohydrate (s) selected from monosaccharides, disaccharides and / or oligosaccharides containing preferred carbohydrates are selected from monosaccharides, in particular, D-ribose and / or, D-xylose and / or, L-arabinose and / or, D-glucose and / or, D-mannose and / or, D-galactose and / or, D-fructose and / or, sorbose and / or, L-fucose and / or, L-rhamnose, disaccharides, in particular, sucrose and / or, maltose and / or, lactose and / or trehalose and / or, cellobiose and / or, gentiobiose and / or isomaltose. Particularly preferred agents according to the invention contain based on their weight

0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of glucose monohydrate,

0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of sucrose, 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of fructose. Particularly preferred agents according to the invention contain, based on their weight, 0.005 to 0.015% by weight of caffeine + 0.75 to 1.5% by weight of glucose monohydrate + 0.1 to 0.25% by weight of glycine,

0.005 to 0.015% by weight of caffeine + 0.75 to 1.5% by weight of sucrose + 0.1 to 0.25% by weight of glycine, 0.005 to 0.015% by weight of caffeine + 0.75 to 1, 5 wt .-% fructose + 0.1 to 0.25 wt .-% glycine, 0.005 to 0.015 wt .-% caffeine + 0.75 to 1, 5 wt .-% glucose monohydrate + 0.1 to 0.25 wt .-% alanine,

0.005 to 0.015% by weight of caffeine + 0.75 to 1.5% by weight of sucrose + 0.1 to 0.25% by weight of alanine, 0.005 to 0.015% by weight of caffeine + 0.75 to 1, 5 wt .-% fructose + 0.1 to 0.25 wt .-% alanine, 0.005 to 0.015 wt .-% caffeine + 0.75 to 1, 5 wt .-% glucose monohydrate + 0.1 to 0.25 wt % Valine, 0.005 to 0.015 wt% caffeine + 0.75 to 1.5 wt% sucrose + 0.1 to 0.25 wt% valine, 0.005 to 0.015 wt% caffeine + 0 , 75 to 1, 5 wt .-% fructose + 0.1 to 0.25 wt .-% valine. A particularly preferred group of ingredients are the silicones. Particularly preferred agents according to the invention contain the silicone (s) preferably in amounts of 0.1 to 10 wt .-%, preferably from 0.25 to 7 wt .-% and in particular from 0.5 to 5 wt .-%, in each case on the entire remedy. Preferred silicones are described below. Particularly preferred agents according to the invention are characterized in that they contain at least one silicone of the formula Si-I

(CH ₃ ) 3Si- [O-Si (CH ₃ ) 2] χ-O-Si (CH ₃ ) 3 (Si-I), in which x is a number from 0 to 100, preferably from 0 to 50, more preferably from 0 to 20 and especially 0 to 10, stands. Preferred according to the invention can be used silicones have viscosities at 20 ⁰ C for from 0.2 to 2 mmV ^1, wherein silicones having viscosities of 0.5 to 1 mmV ¹ are particularly preferred.

Particularly preferred agents according to the invention contain one or more amino-functional silicones. Particularly preferred agents according to the invention are characterized in that they contain at least one amino-functional silicone of the formula (Si-IIa)

(CH ₃ ) ₃ Si - [O-Si (CH ₃ ) 2] n [OSi (CH 3)] _m - OSi (CH ₃ ) ₃ (Si-IIa),

CH ₂ CH (CH ₃ ) CH ₂ NH (CH ₂ ) ₂ NH ₂ , wherein m and n are numbers whose sum (m + n) is between 1 and 2,000, preferably between 50 and 150, where n is preferably from 0 to 1999 and especially from 49 to 149, and m preferably takes values from 1 to 2000, in particular from 1 to 10. These silicones are referred to as trimethylsilylamodimethicones according to the INCI declaration.

Also particularly preferred are agents according to the invention which are an amino-functional silicone of the formula (Si-IIb)

R- [Si (CH ₃₎ ₂ -O] _n1 [Si (R) -O] _m - [Si (CH ₃₎ _2] n -R ₂ (Si-IIb),

I (CH ₂ ) ₃ NH (CH ₂ ) ₂ NH ₂ wherein R is -OH, -O-CH ₃ or a -CH ₃ group and m, n1 and n2 are numbers whose sum is (m + n1 + n2) is between 1 and 2000, preferably between 50 and 150, wherein the sum (n1 + n2) preferably takes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10 , These silicones are referred to as amodimethicones according to the INCI declaration.

Regardless of which amino-functional silicones are used, agents according to the invention which contain an amino-functional silicone whose amine number is above 0.25 meq / g, preferably above 0.3 meq / g and in particular above 0.4 meq / g, are preferred , The amine number stands for the milliequivalents of amine per gram of the amino-functional silicone. It can be determined by titration and also expressed in mg KOH / g. Agents preferred according to the invention are characterized in that, based on their weight, they contain 0.01 to 10% by weight, preferably 0.1 to 8% by weight, particularly preferably 0.25 to 7.5% by weight and in particular 0, 5 to 5 wt.% Amino-functional silicone (s) included.

For aesthetic reasons, "clear" products are often preferred by consumers, hair treatment agents which are preferred according to the invention are therefore transparent or translucent, transparent or translucent in the context of the present invention means a composition which has an NTU value below 100. The NTU value (Nephelometry Turbidity Unit, Nephelometric Turbidity Value, NTU) is one in water treatment Unit used for turbidity measurements in liquids. It is the unit of turbidity of a fluid measured with a calibrated nephelometer.

Furthermore, in a preferred embodiment of the invention, an agent according to the invention may also contain UV filters (I).

The compositions of the invention may further contain a 2-pyrrolidinone-5-carboxylic acid and its derivatives (J). Preference is given to the sodium, potassium, calcium, magnesium or ammonium salts in which the ammonium ion carries, in addition to hydrogen, one to three C ₁ - to C ₄ -alkyl groups. The sodium salt is most preferred. The amounts used in the compositions according to the invention are preferably from 0.05 to 10% by weight, based on the total composition, particularly preferably from 0.1 to 5, and in particular from 0.1 to 3,% by weight.

In addition, it may prove advantageous if the compositions according to the invention contain penetration aids and / or swelling agents (M). These include, for example, urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerol, glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example propylene glycol monoethyl ether, carbonates, bicarbonates, Diols and triols, and in particular 1, 2-diols and 1, 3-diols such as 1, 2-propanediol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-dodecanediol, 1, 3-propanediol, 1 , 6-hexanediol, 1, 5-pentanediol, 1, 4-butanediol.

Advantageously in the context of the invention, short-chain carboxylic acids (N) may additionally support the active substance complex (A). Short-chain carboxylic acids and their derivatives in the context of the invention are understood to mean carboxylic acids which may be saturated or unsaturated and / or straight-chain or branched or cyclic and / or aromatic and / or heterocyclic and have a molecular weight of less than 750. For the purposes of the invention, preference may be given to saturated or unsaturated straight-chain or branched carboxylic acids having a chain length of from 1 to 16 C atoms in the chain, very particular preference being given to those having a chain length of from 1 to 12 C atoms in the chain. The short-chain carboxylic acids according to the invention may have one, two, three or more carboxy groups. Preferred within the meaning of the invention are carboxylic acids having a plurality of carboxy groups, in particular di- and tricarboxylic acids. The carboxy groups may be wholly or partly present as esters, acid anhydride, lactone, amide, imidic acid, lactam, lactim, dicarboximide, carbohydrazide, hydrazone, hydroxam, hydroxime, amidine, amidoxime, nitrile, phosphonic or phosphate ester. The carboxylic acids used according to the invention may of course be substituted along the carbon chain or the ring skeleton. The substituents of the carboxylic acids used according to the invention include, for example, C 1 -C 8 -alkyl, C 2 -C 8 -alkenyl, aryl, aralkyl and aralkenyl, hydroxymethyl, C 2 -C 8 -hydroxyalkyl, C 2 -C 8 -hydroxyalkenyl , Aminomethyl, C 2 -C 8 -aminoalkyl, cyano, formyl, oxo, thioxo, hydroxy, mercapto, amino, carboxy or imino groups. Preferred substituents are C 1 -C 8 alkyl, hydroxymethyl, hydroxy, amino and carboxy groups. Particular preference is given to substituents in the D position. Very particularly preferred substituents are hydroxy, alkoxy and amino groups, where the amino function may optionally be further substituted by alkyl, aryl, aralkyl and / or alkenyl radicals. Furthermore, preferred carboxylic acid derivatives are the phosphonic and phosphate esters. In a further preferred embodiment, the agents according to the invention may contain emulsifiers (F). Emulsifiers effect at the phase interface the formation of water- or oil-stable adsorption layers, which protect the dispersed droplets against coalescence and thus stabilize the emulsion. Emulsifiers are therefore constructed like surfactants from a hydrophobic and a hydrophilic part of the molecule. Hydrophilic emulsifiers preferably form O / W emulsions and hydrophobic emulsifiers preferably form W / O emulsions. An emulsion is to be understood as meaning a droplet-like distribution (dispersion) of a liquid in another liquid under the expense of energy in order to create stabilizing phase interfaces by means of surfactants. The selection of these emulsifying surfactants or emulsifiers depends on the substances to be dispersed and the respective outer phase and the fineness of the emulsion. Emulsifiers which can be used according to the invention are, for example

Addition products of 4 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear

Fatty alcohols having 8 to 22 carbon atoms, fatty acids having 12 to 22 carbon atoms and alkylphenols having 8 to 15 carbon atoms in the alkyl group,

Ci ₂ -C ₂₂ fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide

Polyols having 3 to 6 carbon atoms, in particular glycerol,

Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters,

Fatty acid alkanolamides and fatty acid glucamides,

C ₈ -C ₂₂ -alkylmono- and -oligoglycosides and their ethoxylated analogues, with degrees ofomerization of from 1.1 to 5, in particular from 1.2 to 2.0, and glucose as sugar component being preferred,

Mixtures of alkyl (oligo) glucosides and fatty alcohols, for example, the commercially available

Product Montanov ^® 68,

Addition products of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,

Partial esters of polyols having 3-6 carbon atoms with saturated fatty acids having 8 to 22 C

atoms,

Sterols. Sterols are understood to mean a group of steroids which have a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols.

Phospholipids. Of these, especially the glucose phospholipids, e.g. as lecithins or

Phosphatidylcholines from e.g. Egg yolk or plant seeds (e.g., soybeans) are understood.

Fatty acid esters of sugars and sugar alcohols, such as sorbitol,

Polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate

(Dehymuls ^® PGPH commercial product)

Linear and branched fatty acids with 8 to 30 C atoms and their Na, K, ammonium, Ca, Mg and Zn salts. The agents according to the invention preferably contain the emulsifiers in amounts of 0.1-25% by weight, in particular 0.5-15% by weight, based on the total agent.

The compositions according to the invention may preferably contain at least one nonionic emulsifier having an HLB value of 8 to 18. Nonionic emulsifiers having an HLB value of 10 to 15 may be particularly preferred according to the invention.

It has furthermore proven to be advantageous if, in addition to the polymer (s) from the group of cationic and / or amphoteric polymers, further polymers (G) are contained in the agents according to the invention. In a preferred embodiment, therefore, further polymers are added to the compositions according to the invention, both anionic and nonionic polymers having proven effective.

The anionic polymers (G2) are anionic polymers which have carboxylate and / or sulfonate groups. Examples of anionic monomers from which such polymers may consist are acrylic acid, methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The acidic groups may be wholly or partly present as sodium, potassium, ammonium, mono- or triethanolammonium salt. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer can be found to be particularly effective, it being possible for all or part of the sulfonic acid group to be in the form of sodium, potassium, ammonium, mono- or triethanolammonium salt , More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid, which is available for example under the name Rheothik ^® 11-80 is commercially.

Within this embodiment, it may be preferable to use copolymers of at least one anionic monomer and at least one nonionic monomer. With regard to the anionic monomers, reference is made to the substances listed above. Preferred nonionic monomers are acrylamide, methacrylamide, acrylic esters, methacrylic esters, vinylpyrrolidone, vinyl ethers and vinyl esters.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with sulfonic acid-containing monomers. A particularly preferred anionic copolymer consists of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, wherein the sulfonic acid group is wholly or partly in the form of sodium, potassium, ammonium, mono- or triethanolammonium Salt is present. This copolymer can also be crosslinked, with crosslinking agents preferably polyolefinically unsaturated compounds such as tetra-allyloxyethane, allylsucrose, allylpentaerythritol and methylene-bisacrylamide are used. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC. The use of this compound, which contains, in addition to the polymer component, a hydrocarbon mixture (C ₃ -C ₄ -isoparaffin) and a nonionic emulsifier (laureth-7), has proved to be particularly advantageous in the context of the teaching according to the invention.

Also sold under the name Simulgel ^® 600 as a compound with isohexadecane and polysorbate-80 Natriumacryloyldimethyltaurat copolymers have proved to be particularly effective according to the invention. Likewise preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene may be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-retaining polymers. A 1,9-decadiene crosslinked maleic acid-methyl vinyl ether

Copolymer available under the name Stabileze® ^® QM.

In another embodiment, the agents according to the invention may contain nonionic polymers (G4).

Suitable nonionic polymers are, for example: vinylpyrrolidone / vinyl ester copolymers,

Cellulose ethers, such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose,

Starch and its derivatives, in particular starch ethers, shellac, polyvinylpyrrolidones, siloxanes,

Glycosidically substituted silicones.

It is also possible according to the invention that the preparations have several, in particular two different

Polymers of the same charge and / or in each case an ionic and an amphoteric and / or nonionic

Polymer included.

The further polymers (G) are preferred in amounts of from 0.05 to 10 in the compositions according to the invention

Wt .-%, based on the total agent included. Amounts of 0.1 to 5, especially from 0.1 to 3

Wt .-%, are particularly preferred.

Another object of the present invention is the use of fruit juices and / or

Vegetable juices in hair treatment compositions for improving at least one of the properties of the body and / or the volume of keratinic fibers, in particular human

Hair and / or, the combability, in particular the wet combability of keratinic fibers, in particular human hair and / or the tensile strength of keratinic fibers, in particular human hair and / or

Stabilization of the moisture balance of keratinic fibers, in particular human hair and / or

Combability of keratinic fibers, in particular human hair and / or;

Delaying the aging process of keratinic fibers, especially human hair and / or

Restrukturability of keratinic fibers, in particular human hair, during and after the permanent wave process and / or

Reduction in elasticity of keratinic fibers, especially human hair, when damaged by atmospheric agents.

With respect to preferred embodiments of the uses according to the invention mutatis mutandis applies to the means of the invention.

Claims

claims:

1. hair treatment composition containing in a cosmetically acceptable carrier - based on its weight -

(a) 0.1 to 35% by weight of at least one surfactant,

(B) 15 to 85 wt .-% of at least one fruit or vegetable juice.

2. hair treatment composition according to claim 1, characterized in that it - based on its weight - 20 to 80 wt .-%, preferably 25 to 75 wt .-%, more preferably 30 to 70 wt .-% and in particular 35 to 60 wt .-% contains at least one fruit juice.

3. Hair treatment composition according to one of claims 1 or 2, characterized in that it - based on its weight - 20 to 80 wt .-%, preferably 25 to 75 wt .-%, more preferably 30 to 70 wt .-% and in particular Contains 35 to 60 wt .-% of at least one vegetable juice.

4. hair treatment composition according to one of claims 1 to 3, characterized in that it contains at least one fruit juice from the group apple juice, orange juice, grape juice, lemon juice, lime juice, lime juice, grapefruit juice, currant juice, cherry juice, Schattenmorellensaft, apricot juice, peach juice, nectarine juice, plum juice, Mirabelle juice, passion fruit juice, plum juice, puree juice, blackberry juice, raspberry juice, strawberry juice, pineapple juice, pomegranate juice, litchi juice, mango juice, mandarin juice, papaya juice, pitahaya juice, star fruit juice, pear juice, quince juice, medlar juice, grape juice, rowan juice, gooseberry juice, huckleberry juice, cranberry juice, tangerine juice, cranberry juice, Elderberry juice, apple juice, sea buckthorn juice contains.

5. hair treatment composition according to one of claims 1 to 4, characterized in that it contains at least one vegetable juice from the group rhubarb juice, kohlrabisaft, celeriac juice, carrot juice, beetroot juice, onion juice, leek juice, garlic juice, white cabbage juice, asparagus juice, spinach juice, chard juice, tomato juice , Cucumber juice, pumpkin juice, pea juice, bean juice, artichoke juice, cauliflower juice, kale juice, red cabbage juice, broccoli juice, Brussels sprouts juice.

6. hair treatment composition according to one of claims 1 to 5, characterized in that it contains only fruit and / or vegetable juices from certified organic cultivation.

Hair treatment composition according to any one of claims 1 to 6, characterized in that there are no compounds containing the grouping of formula (V)

- (O-CH ₂ CH ₂ ) _n - (V),

in which n stands for integers between 2 and 100,000.

8. hair treatment composition according to one of claims 1 to 7, characterized in that it amphoteric (s) surfactant (s) from the groups of

N-alkyl,

N-alkyl propionic acids,

N-alkyl aminobutyric acids,

N-alkyliminodipropionic,

N-hydroxyethyl-N-alkylamido,

N-alkyltaurines

N-alkylsarcosines,

2-Alkylaminopropionsäuren each having about 8 to 24 carbon atoms in the alkyl group,

Alkylaminoacetic acids each having about 8 to 24 carbon atoms in the alkyl group,

N-cocoalkyl,

cocoacylaminoethylaminopropionate

CI ₂ - Ci8 - acylsarcosine,

N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammoniumglycinate,

N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate,

2-Alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the

Alkyl or acyl group

Kokosacylaminoethylhydroxyethylcarboxymethylglycinat known under the INCI name cocamidopropyl betaine compounds known under the INCI name Disodium Cocoamphodiacetate

Compounds containing preferred compounds, the amphoteric surfactant (s) in amounts of 0.5 to 9 wt .-%, preferably from 0.75 to 8 wt .-% and in particular from 1 to 7.5 Wt .-%, each based on the total agent included.

9. Hair treatment composition according to one of claims 1 to 8, characterized in that it contains as amphoteric surfactants betaines of the formula (VI)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms.

10. Hair treatment composition according to one of claims 1 to 9, characterized in that it contains as amphoteric surfactants betaines of the formula (VII) in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms.

1 1. hair treatment composition according to any one of claims 9 or 10, characterized in that the radical R in the formulas (VI) and (VII) is selected from

H ₃ C- (CH ₂ ) _/ - H ₃ C- (CH ₂ ) -ι-r H ₃ C- (CH ₂ ) ₁₃ - H ₃ C- (CH ₂ ) ₁₅ -

- H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ - or mixtures of these.

12. Hair treatment composition according to one of claims 1 to 11, characterized in that it contains as nonionic surfactants - based on its weight - 0.1 to 20 wt .-% alkylpolyglycosides of the general formula RO- (Z) _x , wherein R is alkyl , Z is sugar and x is the number of sugar units.

13. hair treatment agent according to any one of claims 1 to 12, characterized in that it - based on its weight - 0.1 to 20 wt .-% fatty acid glutamates (acylglutamates) and / or Fettsäureasparaginate (acylasparaginates) and / or alkylsulfoacetates (sulfoacetic acid alkyl ester ) contains.

14. Hair treatment composition according to one of claims 1 to 13, characterized in that it additionally care substance (s) - in terms of its weight - in amounts of 0.001 to 10 wt .-%, preferably 0.005 to 7.5 wt .-%, especially preferably 0.01 to 5 wt .-% and in particular 0.05 to 2.5 wt .-%, with preferred care substance (s) are selected from the group

I. L-carnitine and / or its salts; ii. Panthenol and / or panthothenic acid; iii. the 2-furanones and / or their derivatives, in particular pantolactone; iv. Taurine and / or its salts;

V. niacinamide; vi. Ubiquinone vii. Ectoin; viii. Allantoin.

15. Use of fruit juices and / or vegetable juices in hair treatment compositions for improving at least one of the properties of the body and / or the volume of keratinic fibers, in particular human

Combability of keratinic fibers, in particular human hair and / or;

Delaying the aging process of keratinic fibers, especially human hair and / or