JP2006348013A - Composition and method for preventing fading - Google Patents
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- JP2006348013A JP2006348013A JP2005206162A JP2005206162A JP2006348013A JP 2006348013 A JP2006348013 A JP 2006348013A JP 2005206162 A JP2005206162 A JP 2005206162A JP 2005206162 A JP2005206162 A JP 2005206162A JP 2006348013 A JP2006348013 A JP 2006348013A
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本発明は、化粧品や医薬部外品等の組成物に配合される天然又は合成の色素等の着色成分の日光や人工光の紫外線等による退色を防止又は軽減する組成物及び方法に関する。 The present invention relates to a composition and method for preventing or reducing fading caused by sunlight, artificial ultraviolet rays, or the like of coloring components such as natural or synthetic pigments blended in compositions such as cosmetics and quasi drugs.
従来より化粧品や一部の医薬部外品にはイメージアップの為に天然や人工の着色成分を配合したり、また他の効能効果の為に有色の成分を配合することは少なくない。
特に化粧品の場合はイメージアップ目的の色そのものを消費者に訴求するため、透明〜半透明の容器に充填されることが多い。このようなケースでは着色及び有色成分は日光や人工光の照射を余儀なくされ、徐々に退色しやがて商品価値を失う結果となる。Conventionally, cosmetics and some quasi-drugs are often blended with natural or artificial coloring components for image enhancement, or colored components for other efficacy effects.
In particular, cosmetics are often filled in transparent to translucent containers in order to appeal to consumers the color for the purpose of image enhancement. In such a case, the colored and colored components are forced to be irradiated with sunlight or artificial light and gradually faded, resulting in a loss of commercial value.
そのため、このような化粧品には一般的に紫外線吸収剤や紫外線散乱剤を配合して退色を防いでいる。しかしながら退色防止効果としては満足できるものではなく、数々の成分から退色防止効果が確認され提示されている。例えばオリゴ糖（特許文献１）や、炭素数１〜５のα−ヒドロキシ酸（塩）（特許文献２）等が挙げられる。 Therefore, such cosmetics generally contain an ultraviolet absorber or an ultraviolet scattering agent to prevent discoloration. However, the anti-fading effect is not satisfactory, and the anti-fading effect has been confirmed and presented from a number of components. For example, oligosaccharide (patent document 1), C1-C5 alpha-hydroxy acid (salt) (patent document 2), etc. are mentioned.
これらの他にも良好な退色防止効果を得るための既存の成分の組み合わせも研究されている。特許文献３にはヒマワリ種子抽出成分とＬ−アスコルビン酸（塩）からなる退色防止剤が提示されているが、これらをもってしても良好な効果が得られなかった。 In addition to these, a combination of existing components for obtaining a good anti-fading effect has also been studied. Patent Document 3 proposes an anti-fading agent comprising a sunflower seed extract component and L-ascorbic acid (salt), but even with these, a good effect was not obtained.
本発明は、上記従来技術の問題点に鑑み、色素や染料を含む化粧料において、日光等の紫外線や光線による退色を防止又は軽減できる退色防止組成物を提供することにある。 In view of the above-described problems of the prior art, an object of the present invention is to provide an anti-fading composition capable of preventing or reducing fading due to ultraviolet rays such as sunlight or light in cosmetics containing pigments and dyes.
次の成分（Ａ）及び（Ｂ）を含有することを特徴とする退色防止組成物。
（Ａ）カムカム果汁及び／又はカムカム抽出物
（Ｂ）有機系紫外線吸収剤及び／又は無機系紫外線散乱剤A discoloration-preventing composition comprising the following components (A) and (B):
(A) Camcam fruit juice and / or Camcam extract (B) Organic ultraviolet absorber and / or inorganic ultraviolet scattering agent
本発明による退色防止組成物は色素や染料の日光等の紫外線や光線による退色を防止又は軽減することのできる優れた組成物であり、これを化粧品等に配合することにより、特に透明〜半透明の容器に充填した場合の日光や人工光による製品の退色を軽減することのできる優れた組成物である。 The anti-fading composition according to the present invention is an excellent composition capable of preventing or reducing fading due to ultraviolet rays and light rays such as sunlight of pigments and dyes. By blending this in cosmetics, etc., it is particularly transparent to translucent. It is an excellent composition that can reduce fading of the product due to sunlight or artificial light when filled in a container.
本発明に使用する成分（Ａ）のカムカム（ＣＡＭＵ ＣＡＭＵ： Ｍｙｒｃｉａｒｉａ Ｄｕｂｉａ）はペルーのアマゾン川流域やブラジルの熱帯雨林を原産地とするフトモモ科キブドウ属の潅木の果実であり、その果汁をそのまま利用できる。また、果汁、果肉、果皮及び種子から選ばれる１種又は２種以上の混合物の水及び親水性有機溶媒から選ばれる１種又は２種以上の混合物による抽出物も利用可能である。親水性有機溶媒としてはエタノール、プロパノール、アセトン、プロピレングリコール、ブチレングリコール、グリセリン等が挙げられる。 The camouflage (CAMU CAMU) of the component (A) used in the present invention is a fruit of a shrub belonging to the genus Amaranthaceae that originates in the Amazon river basin in Peru and a tropical rainforest in Brazil, and its juice can be used as it is. . Moreover, the extract by the 1 type, or 2 or more types of mixture chosen from the water of 1 type, or 2 or more types of mixtures chosen from fruit juice, pulp, a fruit peel, and a seed and a hydrophilic organic solvent can also be utilized. Examples of the hydrophilic organic solvent include ethanol, propanol, acetone, propylene glycol, butylene glycol, glycerin and the like.
カムカムについては既にその果汁をもとに、多数の清涼飲料水が市販されている。例えば伊藤園社製、沖縄バヤリース社製等がある。また製剤化に便利な粉末もあり、例えば粉末カムカム果汁（三栄源エフ・エフ・アイ社製）、ＴＯＡ−カムカムパウダー（東亜化成社製）、成分抽出カムカムパウダー（ペルービアン ネイチャー ジャパン社製）等が挙げられる。本発明はこれらの市販品を用いて実施することができる他、特許文献４に記載の方法で抽出した物でもよい。 Regarding cam cams, many soft drinks are already on the market based on the juice. For example, there are ITO EN and Okinawa Bayaris. There are also powders that are convenient for formulation, such as powdered cam cam juice (manufactured by Saneigen FFI Co., Ltd.), TOA-cam cam powder (manufactured by Toa Kasei Co., Ltd.), component extraction cam cam powder (manufactured by Peruvian Nature Japan), etc. Is mentioned. The present invention can be carried out using these commercially available products, and may be a product extracted by the method described in Patent Document 4.
その配合量は乾燥物換算で０．００１重量％〜５重量％が好ましく、０．０１重量％〜１重量％がより好ましい。０．００１重量％未満であると効果が得られず、５重量％を超えて配合しても効果はあまり変わらず不経済である。 The blending amount is preferably 0.001% to 5% by weight, more preferably 0.01% to 1% by weight in terms of dry matter. If it is less than 0.001% by weight, the effect cannot be obtained, and even if it exceeds 5% by weight, the effect is not changed so much and it is uneconomical.
本発明に使用する成分（Ｂ）のうち有機系紫外線吸収剤としてはパラアミノ安息香酸（ＰＡＢＡ）、パラジメチルアミノ安息香酸２−エチルヘキシル等のパラアミノ安息香酸系、オキシベンゾン、オキシベンゾンスルホン酸等のオキシベンゾン系、シノキサート、パラメトキシケイ皮酸２−エチルヘキシル等のケイ皮酸系、ウロカニン酸、ウロカニン酸エチル等のウロカニン酸系、サリチル酸オクチル等のサリチル酸系等が挙げられる。 Among the components (B) used in the present invention, organic ultraviolet absorbers include paraaminobenzoic acid (PABA), paraaminobenzoic acid-based compounds such as 2-ethylhexyl paradimethylaminobenzoate, oxybenzone-based compounds such as oxybenzone and oxybenzonesulfonic acid, Examples thereof include cinnamic acid systems such as synoxate and 2-ethylhexyl paramethoxycinnamate, urocanic acid systems such as urocanic acid and ethyl urocanate, and salicylic acid systems such as octyl salicylate.
一方の無機系紫外線散乱剤としては酸化チタン、酸化亜鉛、シリカ、タルク及びカオリン等が挙げられる。これらの紫外線吸収剤及び紫外線散乱剤から選ばれる１種又は２種以上を組み合わせて使用することができ、配合量は合計で０．０１重量％〜２０重量％が好ましく、特に０．１重量％〜１０重量％が好ましい。０．０１重量％未満では効果が得られず、２０重量％を超えて配合すると製剤化が困難になる。 Examples of the inorganic ultraviolet scattering agent include titanium oxide, zinc oxide, silica, talc, and kaolin. One or two or more kinds selected from these ultraviolet absorbers and ultraviolet scattering agents can be used in combination, and the total amount is preferably 0.01 wt% to 20 wt%, particularly 0.1 wt%. -10 wt% is preferred. If it is less than 0.01% by weight, the effect cannot be obtained, and if it exceeds 20% by weight, formulation becomes difficult.
本発明において、退色を防止する対象となる色素や染料としては、天然系及び合成系が挙げられる。天然系としてはフラボン、フラボノール、アントシアン、カルコン、オーロン等のフラボノイド類、ナフトキノン、アントラキノン等のキノン類、カロチン、キサントフィル等のカロチノイド、タンニン等のポリフェノール類、インジゴ等のインドール類の他クロロフィル類、ベンゾピラン、アルカロイド、ジケトン等が挙げられる。 In the present invention, natural pigments and synthetic pigments can be used as pigments and dyes to prevent fading. Natural systems include flavonoids such as flavones, flavonols, anthocyans, chalcones and aurones, quinones such as naphthoquinones and anthraquinones, carotenoids such as carotene and xanthophylls, polyphenols such as tannins, indoles such as indigo, chlorophylls, benzopyrans, etc. , Alkaloids, diketones and the like.
一方合成系としては、色素（直接染料）があり、イオン性で分類すると中性染料、塩基性染料及び酸性染料に大別される。中性染料は更に２−アミノ−６−クロロ−４−ニトロフェノール等のニトロ染料とＤＩＳＰＥＲＳＥ ＢＬＡＣＫ ９等の分散染料に分類でき、ニトロ染料にはＨＣ ＢＬＵＥ Ｎｏ．２等のＨＣ染料が含まれる。中性染料及びＢＡＳＩＣ ＢＲＯＷＮ １６等の塩基性染料はカラーリングトリートメント等に配合され、ＡＣＩＤ ＯＲＡＮＧＥ ３等の酸性染料はいわゆるヘアマニキュアの主要成分である。 On the other hand, synthetic systems include pigments (direct dyes), which are roughly classified into neutral dyes, basic dyes and acid dyes when classified by ionicity. Neutral dyes can be further classified into nitro dyes such as 2-amino-6-chloro-4-nitrophenol and disperse dyes such as DISPERSE BLACK 9. HC dyes such as 2 are included. Neutral dyes and basic dyes such as BASIC BROWN 16 are blended in coloring treatments and the like, and acid dyes such as ACID ORANGE 3 are the main components of so-called hair manicure.
これらの色素や染料は１種又は２種以上を、化粧料中に通常着色料として０．０００１重量％〜１０重量％、特に０．００１重量％〜１重量％配合される。 One or more of these pigments and dyes are usually blended in the cosmetic as 0.0001 wt% to 10 wt%, particularly 0.001 wt% to 1 wt% as a colorant.
本発明における退色防止組成物を化粧料に配合する場合、効果が損なわれない範囲で通常の化粧料に用いられる任意の成分をさらに配合することができる。例えば、溶剤、油剤、界面活性剤、保湿剤、増粘剤、抗炎症剤、防腐剤、着香剤等が挙げられる。 When mix | blending the discoloration prevention composition in this invention with cosmetics, the arbitrary components used for normal cosmetics can be further mix | blended in the range by which an effect is not impaired. For example, a solvent, an oil agent, a surfactant, a humectant, a thickener, an anti-inflammatory agent, an antiseptic, a flavoring agent and the like can be mentioned.
次に実施例を挙げて本発明を詳細に説明するが、本発明はこれらに限定されるものではない。なお、配合量は重量％とする。 EXAMPLES Next, although an Example is given and this invention is demonstrated in detail, this invention is not limited to these. The blending amount is% by weight.
実施例１〜実施例４及び比較例１〜比較例２を表１に示した。なお、実施例及び比例における各成分は、以下の原料を用いた。
赤色成分：赤色１０６号（癸巳化成社製）
緑色成分：銅クロロフィリンナトリウム：クロロンＧ（日本葉緑素社製）
カムカム果汁：粉末カムカム果汁（三栄源エフ・エフ・アイ社製）
オキシベンゾンスルホン酸：ＵＶＩＮＵＬ ＭＳ−４０（五協産業社製）
酸化チタン：ＫＡ−１０Ｍ（チタン工業社製）
ポリビニルアルコール（増粘剤）：ゴーセノールＥＧ−４０（日本合成化学社製）
エタノール（溶剤）：一般アルコール９５度合成（信和アルコール産業社製）
１，３−ブチレングリコール（保湿剤）：１，３−ＢＧ（ダイセル化学工業社製）Examples 1 to 4 and Comparative Examples 1 to 2 are shown in Table 1. In addition, the following raw materials were used for each component in the examples and proportions.
Red component: Red No. 106 (manufactured by Hatake Kasei Co., Ltd.)
Green ingredient: Copper chlorophyllin sodium: Chlorone G (manufactured by Nippon Chlorophyll)
Come cam juice: Powdered cam cam juice (manufactured by Saneigen FFI Co., Ltd.)
Oxybenzonesulfonic acid: UVINUL MS-40 (manufactured by Gokyo Sangyo Co., Ltd.)
Titanium oxide: KA-10M (Titanium Industry Co., Ltd.)
Polyvinyl alcohol (thickener): Gohsenol EG-40 (manufactured by Nippon Synthetic Chemical)
Ethanol (solvent): General alcohol 95 degree synthesis (Shinwa Alcohol Industry Co., Ltd.)
1,3-butylene glycol (humectant): 1,3-BG (manufactured by Daicel Chemical Industries)
上記成分を順次精製水に投入し、撹拌混合して均一とする。ただし、ポリビニルアルコールを配合する場合は、予めエタノール及び１，３−ブチレングリコールに分散してから徐々に精製水に撹拌しながら投入する。 The above components are sequentially added to purified water and mixed by stirring until uniform. However, when blending polyvinyl alcohol, it is dispersed in ethanol and 1,3-butylene glycol in advance and then gradually added to purified water while stirring.
実施例及び比較例の組成物を試験管に入れ密栓し、陽当たりの良好な屋外に７日間置いたのち、着色成分を液体クロマトグラフィーで定量し、元の濃度に対する減少率で表示した。
液体クロマトグラフィー：ＬＣ−１０Ａ（島津製作所社製）
カラム：ＳＴＲ ＯＤＳ−ＩＩ（４×１５０ｍｍ）（同社製）
移動相：０．１ｍｏｌ／Ｌ酢酸アンモニウム：メタノール＝３０：７０
波長：５３０ｎｍ（赤色系）又は６００ｎｍ（青色系）The compositions of Examples and Comparative Examples were put in test tubes and sealed, and after being placed outdoors in good sunlight for 7 days, the color components were quantified by liquid chromatography and displayed as the rate of decrease with respect to the original concentration.
Liquid chromatography: LC-10A (manufactured by Shimadzu Corporation)
Column: STR ODS-II (4 x 150 mm) (manufactured by the same company)
Mobile phase: 0.1 mol / L ammonium acetate: methanol = 30: 70
Wavelength: 530 nm (red) or 600 nm (blue)
表１に示すとおり、成分（Ａ）及び成分（Ｂ）を有する実施例１〜実施例４の組成物は、成分（Ａ）又は成分（Ｂ）の一方しか有さない比較例１〜比較例２より色素又は染料の７日目の減少率が極めて小さく、退色の度合いが小さかった。 As shown in Table 1, the compositions of Examples 1 to 4 having component (A) and component (B) are Comparative Examples 1 to Comparative Example having only one of Component (A) or Component (B). 2, the decrease rate of the pigment or dye on the 7th day was extremely small, and the degree of fading was small.
次にこの退色防止組成物を含む以下処方例１〜処方例５の化粧料を作成し、それぞれの一部を二本の試験管に入れ、一方は上述の方法で日光に晒し、他方は暗所に保管する。７日後両方を目視により比較し、退色の程度を観察した。 Next, the cosmetics of the following Formulation Examples 1 to 5 containing this anti-fading composition are prepared, and a part of each is put in two test tubes, one is exposed to sunlight by the above-described method, and the other is dark. Keep in a safe place. After 7 days, both were visually compared to observe the degree of fading.
（実施例５）
処方例１：シャンプー
１）カチオン化セルロース ０．５％
２）ヤシ油脂肪酸アミドプロピルベタイン液（３０％） １５．０％
３）ラウリル硫酸ナトリウム液（３０％） ２５．０％
４）ヤシ油脂肪酸ジエタノールアミド ４．５％
５）濃グリセリン ０．５％
６）安息香酸ナトリウム １．０％
７）紫色４０１号 ０．１％
８）オキシベンゾンスルホン酸 ０．８％
９）粉末カムカム果汁 ０．８％
１０）香料 ０．１％
１１）精製水 ５１．７％(Example 5)
Formulation Example 1: Shampoo 1) Cationized cellulose 0.5%
2) Palm oil fatty acid amidopropyl betaine solution (30%) 15.0%
3) Sodium lauryl sulfate solution (30%) 25.0%
4) Palm oil fatty acid diethanolamide 4.5%
5) Concentrated glycerin 0.5%
6) Sodium benzoate 1.0%
7) Purple 401 0.1%
8) Oxybenzonesulfonic acid 0.8%
9) Powdered cam cam juice 0.8%
10) Fragrance 0.1%
11) 51.7% purified water
（実施例６）
処方例２：ヘアリンス
１）セタノール ４．５％
２）ステアリルアルコール ３．０％
３）ヒマシ油 ３．０％
４）塩化アルキルトリメチルアンモニム ２．０％
５）イソプロパノール ０．５％
６）ヤシ油脂肪酸モノエタノールアミド ０．５％
７）メチルパラベン ０．４％
８）ＨＣ ＢＬＵＥ Ｎｏ．２ ０．１％
９）Ｂａｓｉｃ Ｖｉｏｌｅｔ １０（赤色２１３号） ０．１％
１０）オキシベンゾンスルホン酸 ０．５％
１１）粉末カムカム果汁 １．０％
１２）香料 ０．１％
１３）精製水 ８４．３％(Example 6)
Formulation Example 2: Hair Rinse 1) Cetanol 4.5%
2) Stearyl alcohol 3.0%
3) Castor oil 3.0%
4) Alkyltrimethylammonium chloride 2.0%
5) Isopropanol 0.5%
6) Palm oil fatty acid monoethanolamide 0.5%
7) Methylparaben 0.4%
8) HC BLUE No. 2 0.1%
9) Basic Violet 10 (Red No. 213) 0.1%
10) Oxybenzonesulfonic acid 0.5%
11) Powdered cam cam juice 1.0%
12) Fragrance 0.1%
13) Purified water 84.3%
（実施例７）
処方例３：水性ヘアワックス
１）流動パラフィン １０．０％
２）パラフィン ５．０％
３）ステアリルアルコール ６．０％
４）キャンデリラロウ ２．０％
５）ジプロピレングリコール ５．０％
６）ポリオキシエチレン（６Ｅ．Ｏ．）セチルエーテル ６．５％
７）メチルポリシロキサン ０．５％
８）メチルパラベン ０．２％
９）ＤＩＳＰＥＲＳＥ ＢＬＡＣＫ ９ ０．８％
１０）酸化チタン １．０％
１１）オキシベンゾンスルホン酸 １．２％
１２）粉末カムカム果汁 ０．８％
１３）香料 ０．１％
１４）精製水 ６０．９％(Example 7)
Formulation Example 3: Aqueous hair wax 1) Liquid paraffin 10.0%
2) Paraffin 5.0%
3) Stearyl alcohol 6.0%
4) Candelilla wax 2.0%
5) Dipropylene glycol 5.0%
6) Polyoxyethylene (6E.O.) cetyl ether 6.5%
7) Methyl polysiloxane 0.5%
8) Methylparaben 0.2%
9) DISPERSE BLACK 9 0.8%
10) Titanium oxide 1.0%
11) Oxybenzonesulfonic acid 1.2%
12) Powdered cam cam juice 0.8%
13) Fragrance 0.1%
14) Purified water 60.9%
（実施例８）
処方例４：スキンクリーム
１）セタノール ５．０％
２）自己乳化型モノステアリン酸グリセリン ５．０％
３）流動パラフィン ５．０％
４）ミリスチン酸イソプロピル ５．０％
５）ポリオキシエチレン（６Ｅ．Ｏ．）セチルエーテル ３．０％
６）濃グリセリン １３．０％
７）メチルパラベン ０．２％
８）プロピルパラベン ０．２％
９）酸化チタン ０．６％
１０）オキシベンゾンスルホン酸 ０．９％
１１）赤色１０６号 ０．１％
１２）粉末カムカム果汁 １．２％
１３）香料 ０．１％
１４）精製水 ６０．７％(Example 8)
Formulation Example 4: Skin Cream 1) Cetanol 5.0%
2) Self-emulsifying glyceryl monostearate 5.0%
3) Liquid paraffin 5.0%
4) Isopropyl myristate 5.0%
5) Polyoxyethylene (6E.O.) cetyl ether 3.0%
6) Concentrated glycerin 13.0%
7) Methylparaben 0.2%
8) Propylparaben 0.2%
9) Titanium oxide 0.6%
10) Oxybenzonesulfonic acid 0.9%
11) Red No. 106 0.1%
12) Powdered cam cam juice 1.2%
13) Fragrance 0.1%
14) Purified water 60.7%
（実施例９）
処方例５：スキンローション
１）エチルアルコール（９５％） ６．０％
２）濃グリセリン ５．０％
３）１，３−ブチレングリコール ５．０％
４）モノラウリン酸ポリオキシエチレン
（２０Ｅ．Ｏ．）ソルビタン ０．５％
５）安息香酸ナトリウム ０．２％
６）オキシベンゾンスルホン酸 ０．５％
７）粉末カムカム果汁 １．２％
８）銅クロロフィリンナトリウム ０．１％
９）香料 ０．１％
１０）精製水 ８１．４％Example 9
Formulation Example 5: Skin lotion 1) Ethyl alcohol (95%) 6.0%
2) Concentrated glycerin 5.0%
3) 1,3-butylene glycol 5.0%
4) Polyoxyethylene monolaurate
(20EO) Sorbitan 0.5%
5) Sodium benzoate 0.2%
6) Oxybenzonesulfonic acid 0.5%
7) Powdered cam cam juice 1.2%
8) Copper chlorophyllin sodium 0.1%
9) Fragrance 0.1%
10) Purified water 81.4%
上記実施例５〜実施例９の全ての化粧料において、殆ど退色は無いか又はごくわずかであり、良好な退色防止の結果を得た。 In all the cosmetics of Examples 5 to 9, there was almost no fading or very little, and good fading prevention results were obtained.
Claims (6)
（Ａ）カムカム果汁及び／又はカムカム抽出物
（Ｂ）有機系紫外線吸収剤及び／又は無機系紫外線散乱剤A discoloration-preventing composition comprising the following components (A) and (B):
(A) Camcam fruit juice and / or Camcam extract (B) Organic ultraviolet absorber and / or inorganic ultraviolet scattering agent
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005206162A JP2006348013A (en) | 2005-06-17 | 2005-06-17 | Composition and method for preventing fading |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005206162A JP2006348013A (en) | 2005-06-17 | 2005-06-17 | Composition and method for preventing fading |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2006348013A true JP2006348013A (en) | 2006-12-28 |
Family
ID=37644210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005206162A Pending JP2006348013A (en) | 2005-06-17 | 2005-06-17 | Composition and method for preventing fading |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2006348013A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009135699A1 (en) * | 2008-05-07 | 2009-11-12 | Henkel Ag & Co. Kgaa | Shampoo with fruit juice and/or vegetable juice |
| JP2010270184A (en) * | 2009-05-19 | 2010-12-02 | Maruzen Pharmaceut Co Ltd | Fading-preventing agent for acid dye and acidic hair-dyeing agent composition, and fading-preventing agent for oxidative dye, fading-preventing agent after hair dyeing and oxidative hair-dyeing agent composition |
| JPWO2018225765A1 (en) * | 2017-06-08 | 2020-04-09 | 株式会社 資生堂 | Water-in-oil emulsion cosmetics |
| JP2020189790A (en) * | 2019-05-20 | 2020-11-26 | 株式会社ダリヤ | Hair temporary colorant composition |
-
2005
- 2005-06-17 JP JP2005206162A patent/JP2006348013A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009135699A1 (en) * | 2008-05-07 | 2009-11-12 | Henkel Ag & Co. Kgaa | Shampoo with fruit juice and/or vegetable juice |
| JP2010270184A (en) * | 2009-05-19 | 2010-12-02 | Maruzen Pharmaceut Co Ltd | Fading-preventing agent for acid dye and acidic hair-dyeing agent composition, and fading-preventing agent for oxidative dye, fading-preventing agent after hair dyeing and oxidative hair-dyeing agent composition |
| JPWO2018225765A1 (en) * | 2017-06-08 | 2020-04-09 | 株式会社 資生堂 | Water-in-oil emulsion cosmetics |
| JP2020189790A (en) * | 2019-05-20 | 2020-11-26 | 株式会社ダリヤ | Hair temporary colorant composition |
| JP7264457B2 (en) | 2019-05-20 | 2023-04-25 | 株式会社ダリヤ | Temporary hair coloring composition |
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