EP2190584A2 - Traitement de minerais de valeur au moyen de particules magnétiques - Google Patents
Traitement de minerais de valeur au moyen de particules magnétiquesInfo
- Publication number
- EP2190584A2 EP2190584A2 EP08803482A EP08803482A EP2190584A2 EP 2190584 A2 EP2190584 A2 EP 2190584A2 EP 08803482 A EP08803482 A EP 08803482A EP 08803482 A EP08803482 A EP 08803482A EP 2190584 A2 EP2190584 A2 EP 2190584A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- substance
- magnetic
- group
- mixture
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006249 magnetic particle Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 claims abstract description 77
- 239000000203 mixture Substances 0.000 claims abstract description 76
- 239000000126 substance Substances 0.000 claims abstract description 75
- 239000006185 dispersion Substances 0.000 claims abstract description 33
- 239000002270 dispersing agent Substances 0.000 claims abstract description 32
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 32
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 230000005291 magnetic effect Effects 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 150000002736 metal compounds Chemical class 0.000 claims description 9
- -1 hydroxide metal compounds Chemical class 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229910000859 α-Fe Inorganic materials 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 230000005294 ferromagnetic effect Effects 0.000 claims description 2
- 235000013980 iron oxide Nutrition 0.000 claims description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 239000010949 copper Substances 0.000 description 36
- 238000000926 separation method Methods 0.000 description 14
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 239000000725 suspension Substances 0.000 description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- NJGCRMAPOWGWMW-UHFFFAOYSA-N octylphosphonic acid Chemical compound CCCCCCCCP(O)(O)=O NJGCRMAPOWGWMW-UHFFFAOYSA-N 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 8
- 238000003776 cleavage reaction Methods 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- 230000007017 scission Effects 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000013543 active substance Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 230000001143 conditioned effect Effects 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 108091005950 Azurite Proteins 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 241000907663 Siproeta stelenes Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000007514 bases Chemical class 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 125000004404 heteroalkyl group Chemical group 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- OMKVZYFAGQKILB-UHFFFAOYSA-M potassium;butoxymethanedithioate Chemical compound [K+].CCCCOC([S-])=S OMKVZYFAGQKILB-UHFFFAOYSA-M 0.000 description 3
- YEEBCCODSASHMM-UHFFFAOYSA-M potassium;octoxymethanedithioate Chemical compound [K+].CCCCCCCCOC([S-])=S YEEBCCODSASHMM-UHFFFAOYSA-M 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 3
- 239000012991 xanthate Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052656 albite Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052951 chalcopyrite Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052955 covellite Inorganic materials 0.000 description 2
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229910052627 muscovite Inorganic materials 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- 239000010414 supernatant solution Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- 150000004325 8-hydroxyquinolines Chemical class 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910020710 Co—Sm Inorganic materials 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052948 bornite Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229910052947 chalcocite Inorganic materials 0.000 description 1
- 150000001793 charged compounds Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000009852 extractive metallurgy Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000005021 gait Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910001172 neodymium magnet Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- QWENMOXLTHDKDL-UHFFFAOYSA-N pentoxymethanedithioic acid Chemical compound CCCCCOC(S)=S QWENMOXLTHDKDL-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- HRANSTGHZSEXRW-UHFFFAOYSA-M potassium;dioctyl-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [K+].CCCCCCCCP([S-])(=S)CCCCCCCC HRANSTGHZSEXRW-UHFFFAOYSA-M 0.000 description 1
- KZMAIULISOIRKM-UHFFFAOYSA-M potassium;octoxy-octylsulfanyl-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [K+].CCCCCCCCOP([O-])(=S)SCCCCCCCC KZMAIULISOIRKM-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910000938 samarium–cobalt magnet Inorganic materials 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- RZFBEFUNINJXRQ-UHFFFAOYSA-M sodium ethyl xanthate Chemical compound [Na+].CCOC([S-])=S RZFBEFUNINJXRQ-UHFFFAOYSA-M 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- BNCXNUWGWUZTCN-UHFFFAOYSA-N trichloro(dodecyl)silane Chemical group CCCCCCCCCCCC[Si](Cl)(Cl)Cl BNCXNUWGWUZTCN-UHFFFAOYSA-N 0.000 description 1
- QZQIWEZRSIPYCU-UHFFFAOYSA-N trithiole Chemical class S1SC=CS1 QZQIWEZRSIPYCU-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/005—Pretreatment specially adapted for magnetic separation
- B03C1/015—Pretreatment specially adapted for magnetic separation by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C2201/00—Details of magnetic or electrostatic separation
- B03C2201/18—Magnetic separation whereby the particles are suspended in a liquid
Definitions
- the present invention relates to a process for separating at least one first substance from a mixture containing said at least one first substance and at least one second substance, wherein the first substance is first contacted with a surface-active substance for its hydrophobization, this mixture being further in contact with at least one magnetic particle is brought so that the magnetic particle and the hydrophobized first material attach and this agglomerate is separated from the at least one second material by the application of a magnetic field, and then the at least one first substance is preferably quantitatively separated from the magnetic particle, wherein Preferably, the magnetic particles can be recycled back into the process.
- the present invention relates to a method of enriching ores in the presence of gait.
- WO 02/0066168 A1 relates to a process for the separation of ores from mixtures containing them, in which suspensions or slurries of these mixtures are treated with particles which are magnetic and / or floatable in aqueous solutions. After addition of the magnetic and / or buoyant particles, a magnetic field is applied so that the agglomerates are separated from the mixture.
- the degree of attachment of the magnetic particles to the ore and the strength of the bond is not sufficient to perform the process with sufficiently high yield and effectiveness.
- US Pat. No. 4,657,666 discloses a method for enriching ores, wherein the ore in orbit is reacted with magnetic particles, whereby agglomerates form due to the hydrophobic interactions.
- the magnetic particles are rendered hydrophobic by treatment with hydrophobic compounds on the surface, so that binding to the ore is effected.
- the agglomerates are then separated from the mixture by a magnetic field.
- the cited document also discloses that the ores are treated with a surface activating solution of 1% sodium ethylxanthogenate before the magnetic particle is added. Separation of ore and magnetic particles occurs in this process by destroying the surface-activating substance which has been applied to the ore in the form of the surface-activating solution. Furthermore, only C 4 hydrophobizing agents for the ore are used in this process.
- US 4,834,898 discloses a method for separating non-magnetic materials by contacting them with magnetic reagents coated with two layers of surfactants. US 4,834,898 further discloses that the surface charge of the non-magnetic particles to be separated may be affected by various types and concentrations of electrolyte reagents. For example, the surface charge is altered by the addition of multivalent anions, for example tripolyphosphate ions.
- WO 2007/008322 A1 discloses a magnetic particle, which is hydrophobized on the surface, for the separation of impurities from mineral substances by magnetic separation processes. According to WO 2007/008322 A1, a dispersant selected from sodium silicate, sodium polyacrylate or sodium hexametaphosphate can be added to the solution or dispersion.
- the object of the present invention is to provide a method by which at least one first substance can be separated off efficiently from mixtures containing at least one first substance and at least one second substance. Furthermore, it is an object of the present invention to treat the first particles to be separated in such a way that the addition product between the magnetic particle and the first substance is sufficiently stable in order to ensure a high yield of first material during the separation.
- a method for separating at least one first substance from a mixture containing said at least one first substance and at least one second substance comprising the following steps:
- step (A) contacting the mixture containing at least a first substance and at least one second substance with at least one surface-active substance, if appropriate in the presence of at least one dispersing agent, wherein the surface-active substance binds to the at least one first substance, (B) optionally adding at least one dispersant to the mixture obtained in step (A) to obtain a dispersion of suitable concentration,
- step (C) treating the dispersion from step (A) or (B) with at least one hydrophobic magnetic particle so that the at least one first substance to which the at least one surface-active substance is attached and the at least one magnetic particle attach,
- step (D) separating the adduct from step (C) from the mixture by applying a magnetic field
- step (E) cleaving the separated addition product from step (D) to separately obtain the at least one first substance and the at least one magnetic particle.
- the method according to the invention preferably serves to separate at least one first, hydrophobic substance from a mixture comprising said at least one first, hydrophobic substance and at least one second, hydrophilic substance.
- hydrophobic means that the corresponding particle can be subsequently rendered hydrophobic by treatment with the at least one surface-active substance It is also possible for a hydrophobic particle to be additionally hydrophobicized by treatment with the at least one surface-active substance becomes.
- Hydrophobic in the context of the present invention means that the surface of a corresponding "hydrophobic substance” or a “hydrophobized substance” has a contact angle of> 90 ° with water against air.
- Hydrophobic in the context of the present invention means that the surface of a corresponding “hydrophilic substance” has a contact angle of ⁇ 90 ° with water against air.
- the at least one first substance is at least one hydrophobic metal compound or carbon
- the at least one second substance is preferably at least one hydrophilic metal compound.
- the at least one first substance to be separated off is preferably a metal compound selected from the group of sulfidic ores, oxidic and / or carbohydrate ores.
- carbonaceous ores for example, azurite [Cu 3 (CO 3 MOH) 2 ], or malachite [Cu 2 [(OH) 2
- the noble metals and their compounds to which a surfactant compound is selectively added hydrophobic surface properties can attach.
- the at least one hydrophilic metal compound is preferably selected from the group consisting of oxidic and hydroxide metal compounds, for example silicon dioxide SiO 2 , silicates, aluminosilicates, for example feldspars, for example albite Na (Si 3 Al) O 8 , mica, for example muscovite KAI 2 [(OH , F) 2 AISi 3 Oi 0 ], Gra- nates (Mg, Ca, Fe 11 J 3 (Al, Fe '") 2 (Si0 4 ) 3 , Al 2 O 3 , FeO (OH), FeCO 3 , Fe 2 O 3 , Fe 3 O 4 and other related minerals and mixtures thereof.
- oxidic and hydroxide metal compounds for example silicon dioxide SiO 2 , silicates, aluminosilicates, for example feldspars, for example albite Na (Si 3 Al) O 8 , mica, for example muscovite KAI 2 [(OH , F) 2 AIS
- sulfide ores which can be used according to the invention are selected, for example, from the group of copper ores consisting of covellite CuS, molybdenum (IV) sulfide, chalcopyrite (copper gravel) CuFeS 2 , bornite Cu 5 FeS 4 , chalcocite (copper luster) Cu 2 S and mixtures from that.
- Suitable oxidic metal compounds which can be used according to the invention are preferably selected from the group consisting of silicon dioxide SiO 2 , silicates, aluminosilicates, for example feldspars, for example albite Na (Si 3 Al) O 8 , mica, for example muscovite KAl 2 I (OH, F) 2 AISi 3 Oi 0 ], garnets (Mg, Ca, Fe 11 J 3 (Al, Fe "') 2 (Si0 4 ) 3 and other related minerals and mixtures thereof.
- the mixture comprising at least one first substance and at least one second substance in step (A) is in the form of particles having a size of 100 nm to 100 ⁇ m, see for example US Pat. No. 5,051,199. In a preferred embodiment, this particle size is obtained by grinding. Suitable methods and devices are known to the person skilled in the art, for example wet milling in a ball mill.
- a preferred embodiment of the method according to the invention is characterized in that the mixture containing at least a first material and at least one second material before or during step (A) is ground to particles having a size of 100 nm to 100 microns.
- Preferably usable ore mixtures have a content of sulfidic minerals of at least 0.4 wt .-%, particularly preferably at least 10 wt .-%, on.
- sulfidic minerals which are present in the mixtures which can be used according to the invention are those mentioned above. Additionally, in the mixtures sulfides of metals other than copper, for example sulfides of iron, lead, zinc or molybdenum, ie FeS / FeS 2 , PbS, ZnS or MoS 2 .
- oxidic compounds of metals and semimetals for example silicates or borates or other salts of metals and semimetals, for example phosphates, sulfates or oxides / hydroxides / carbonates and further salts, for example azurite [Cu 3 (COs) 2 (OH) 2 ], malachite [Cu 2 I (OH) 2 (CO 3 )]], barite (BaSO 4 ), monacite ((La-Lu) PO 4 ).
- noble metals for example Au, Pt, Pd, Rh, etc., preferably in a solid state.
- a typically used ore mixture which can be separated by the method according to the invention, has the following composition: about 30 wt .-% SiO 2 , about 10 wt .-% Na (Si 3 AI) O 8 , about 3 wt. -% Cu 2 S, about 1 wt .-% MoS 2 , balance chromium, iron, titanium and magnesium oxides.
- Step (A) of the method according to the invention comprises contacting the mixture containing at least a first substance and at least one second substance with at least one surface-active substance, optionally in the presence of at least one dispersing agent, wherein the surface-active substance binds selectively to the at least one first substance,
- surface-active substance means a substance which is capable of changing the surface of the particle to be separated in the presence of the other particles which are not to be separated in such a way that an attachment of a hydrophobic particle by hydrophobic interactions to Surface-active substances which can be used according to the invention are deposited on the at least one first substance and thereby bring about a suitable hydrophobicity of the first substance.
- A is selected from linear or branched C 3 -C 30 alkyl, C 3 -C 30 heteroalkyl, optionally substituted C 6 -C 30 aryl, optionally substituted C 6 -C 30 heteroalkyl, C 6 -C 30 aralkyl and
- Z is a group with which binds the compound of general formula (I) to the at least one hydrophobic substance.
- A is a linear or branched C 4 -C 2 -alkyl, very particularly preferably a linear C 4 - or C 8 -alkyl.
- optionally present heteroatoms according to the invention are selected from N, O, P, S and halogens such as F, Cl, Br and I.
- A is preferably a linear or branched, preferably linear, C 6 -C 20 -alkyl.
- A is preferably a branched C 6 -C 4 -alkyl, wherein the at least one substituent, preferably having 1 to 6 carbon atoms, is preferably present in the 2-position, for example 2-ethylhexyl and / or 2-propylheptyl.
- n 2 in the abovementioned formulas, then two identical or different, preferably identical, groups A are bound to a group Z.
- compounds are used which are selected from the group consisting of xanthates AO-CS 2 " , dialkyldithiophosphate (AO) 2 -PS 2 " , dialkyldithioposphinates (A) 2 -PS 2 " and mixtures thereof, where A is independently each other is a linear or branched, preferably linear, C 6 -C 20 -alkyl, for example n-octyl, or a branched C 6 -C 4 -alkyl, wherein the branching is preferably in the 2-position, for example 2-ethylhexyl and / or
- preference is given to cations selected from the group consisting of hydrogen, NR 4 + and R are the same and are independently counter-ions from each other hydrogen and / or C 1 -C 5 -alkyl, alkali or alkaline earth metals, in particular sodium or potassium, before.
- Very particularly preferred compounds of general formula (I) are selected from the group consisting of sodium or potassium n-octylxanthate, sodium or potassium butylxanthate, sodium or potassium di-n-octyl dithiophosphinate, sodium or potassium di -n-octyl dithiophosphate, and mixtures of these compounds.
- particularly preferred surface-active substances are mono-, di- and tri-thiols or 8-hydroxyquinolines, for example described in EP 1200408 B1.
- metal oxides for example FeO (OH), Fe 3 O 4 , ZnO etc.
- carbonates for example azurite [Cu (CO 2 ) 2 (OI-I) 2 ], malachite [Cu 2 E (OH) 2 CO 3 ]], particularly preferred surface-active substances octylphosphonic acid (OPS), (EtO) 3 Si-a, (MeO) 3 Si-a, with the abovementioned meanings for A.
- OPS octylphosphonic acid
- EtO EtO 3 Si-a
- MeO 3 Si-a
- particularly preferred surface-active substances are mono-, di- and trithiols or xanthates.
- Z is - (X) n -CS 2 " , - (X) n -PO 2 " or - (X) n -S " where X is O and n is 0 or 1 and one Cation selected from hydrogen, sodium or potassium
- Very particularly preferred surface-active substances are 1-octanethiol, potassium n-octylxanthate, potassium-butylxanthate, octylphosphonic acid or a compound of the following formula (IV)
- step (A) of the process according to the invention can be carried out by all methods known to the person skilled in the art.
- Step (A) can be carried out in bulk or in dispersion, preferably in suspension, particularly preferably in aqueous suspension.
- step (A) is carried out in bulk, ie in the absence of a dispersing agent.
- a dispersing agent for example, the mixture to be treated and the at least one surfactant are added and mixed together without additional dispersant in the appropriate amounts.
- Suitable mixing apparatuses are known to the person skilled in the art, for example mills, such as ball mill.
- step (A) is carried out in a dispersion, preferably in suspension.
- the dispersant all dispersants are suitable in which the mixture of step (A) is not completely soluble.
- Suitable dispersants for the preparation of the slurry or dispersion according to step (B) of the process of the invention are selected from the group consisting of water, water-soluble organic compounds, for example alcohols having 1 to 4 carbon atoms, and mixtures thereof.
- the dispersant in step (A) is water.
- Step (A) of the process according to the invention is generally carried out at a temperature of 1 to 80 ° C., preferably at 20 to 40 ° C., more preferably at ambient temperature.
- the at least one surfactant is generally employed in an amount sufficient to achieve the desired effect.
- the at least one surfactant is added in an amount of 0.01 to 5 wt .-%, each based on the total mixture to be treated.
- step (B) of the process of the invention comprises adding at least one dispersing agent to the mixture obtained in step (A) to obtain a dispersion
- step (A) if step (A) is carried out in bulk, the mixture obtained in step (A) contains at least one first substance and at least one second substance which has been modified on the surface with at least one surface-active substance.
- step (B) of the method according to the invention is carried out, i. at least one suitable dispersing agent is added to the mixture obtained in step (A) to obtain a dispersion.
- step (B) is not carried out. It is, however, also at of this embodiment, it is possible to carry out step (B), ie to add further dispersing agent to obtain a dispersion having a lower concentration.
- Suitable dispersants are all dispersants which have already been mentioned with reference to step (A).
- the dispersant in step (A) is water.
- step (B) either the mixture of substance from step (A) is thus converted into a dispersion, or the mixture already present in dispersion from step (A) is converted into a dispersion of lower concentration by addition of dispersing agent.
- the amount of dispersant added in step (A) and / or step (B) may be selected according to the invention such that a dispersion is obtained which is readily stirrable and / or conveyable.
- the amount of mixture to be treated based on the total slurry or dispersion to 100 wt .-%, particularly preferably 0.5 to 10 wt .-%.
- step (B) is not carried out, but step (A) is carried out in aqueous dispersion, so that in step (A) directly a mixture in aqueous dispersion is obtained, which has the correct concentration to Step (C) of the method according to the invention to be used.
- step (B) of the process according to the invention can be carried out according to the invention by all methods known to the person skilled in the art.
- Step (C) of the process according to the invention comprises treating the dispersion from step (A) or (B) with at least one hydrophobic magnetic particle so that the at least one first substance rendered hydrophobic in step (A) to which the at least one surface-active substance bonds is, and attach at least one magnetic particles.
- the at least one magnetic particle is selected from the group consisting of magnetic metals, for example iron, cobalt, nickel and mixtures thereof, ferromagnetic alloys of magnetic metals, for example NdFeB, SmCo and mixtures thereof, magnetic iron oxides, for example magnetite, maghemite, cubic ferrites of the general formula (II) M 2+ x Fe 2+ 1-x Fe 3+ 2 0 4 (II)
- M is selected from Co, Ni, Mn, Zn and mixtures thereof and x ⁇ 1,
- the magnetic particles may additionally have an outer layer, for example of SiO 2 .
- the at least one magnetic particle is magnetite or cobalt ferrite Co 2+ x Fe 2+ i -x Fe 3+ 2 ⁇ 4 with x ⁇ 1.
- the magnetic particles used in step (C) of the process according to the invention are in a size of 100 nm to 100 .mu.m, more preferably 1 to 50 .mu.m before.
- the magnetic particles can be converted into the appropriate size by methods known to the person skilled in the art, for example by grinding.
- the particles produced by a precipitation reaction can be brought to this particle size by adjusting the reaction parameters (eg pH, reaction time, temperature).
- the at least one magnetic particle is hydrophobic on the surface with at least one hydrophobic compound.
- the hydrophobic compound is preferably selected from compounds of the general formula (III)
- B is selected from linear or branched C 3 -C 30 -alkyl, C 3 -C 30 -heteroalkyl, optionally substituted C 6 -C 30 -aryl, optionally substituted C 6 -C 30 -
- Y is a group with which the compound of the general formula (III) binds to the at least one magnetic particle.
- B is a linear or branched
- C 6 -C 8 alkyl preferably linear C 8 -C 2 -alkyl, very particularly preferably a linear Ci 2 alkyl.
- optionally present heteroatoms according to the invention are selected from N, O, P, S and halogens such as F, Cl, Br and I.
- Y is selected from the group consisting of - (X) n -SiHaI 3 , - (X) n -SiHHaI 2 , - (X) n -SiH 2 Hal with HaI equal to F, Cl, Br, I, and anionic groups such as - (X) n -SiO 3 3 " , - (X) n -CO 2 " , - (X) n -PO 3 2 " , - (X) n -PO 2 S 2" , - (X) n -POS 2 2 " , - (X) n -PPS 3 2” , - (X) n -PPS 2 " , - (X) n -POS " , - (X) n -PO 2 " , - (X) n -CO 2 " , - (X) n -CS 2 " , - (X) n
- n 2 in the abovementioned formulas, then two identical or different, preferably identical, groups B are bound to a group Y.
- Very particularly preferred hydrophobizing substances of the general formula (III) are alkyltrichlorosilanes (alkyl group having 6-12 carbon atoms), alkyltrimethoxysilanes (alkyl group having 6-12 carbon atoms), octylphosphonic acid, lauric acid, oleic acid, stearic acid or mixtures thereof.
- step (C) of the process according to the invention can be carried out by all methods known to the person skilled in the art.
- the at least one magnetic particle is dispersed in a suitable dispersing agent.
- Suitable dispersants are all dispersants in which the at least one magnetic particle is not completely soluble.
- Suitable dispersants for dispersion according to step (C) of the process according to the invention are selected from the group consisting of water, water-soluble organic compounds and mixtures thereof, more preferably water. Particularly preferably, in step (C), the same dispersing agent is used as in step (B).
- the amount of dispersant for predispersing the magnetic particles may be selected according to the invention so as to obtain a slurry or dispersion which is readily stirrable and / or recoverable.
- the amount of mixture to be treated, based on the total slurry or dispersion is up to 60% by weight.
- the dispersion of the magnetic particles can be prepared by all methods known to the person skilled in the art.
- the magnetic particles to be dispersed and the corresponding amount of dispersing agent or dispersing agent mixture in a suitable reactor such as a glass reactor, combined and stirred with known in the art devices, for example in a glass pan with a mechanically operated paddle, for example at a temperature of 1 to 80 0 C, preferably at room temperature.
- the treatment of the dispersion from step (B) with at least one hydrophobic magnetic particle is generally carried out so that both components are combined by methods known to the person skilled in the art.
- a dispersion of the at least one magnetic particle is added to the mixture previously treated with at least one surfactant.
- the magnetic particle may be added in solid form to a dispersion of the mixture to be treated.
- both components are present in dispersed form.
- Step (C) is generally carried out at a temperature of 1 to 80 0 C, preferably 10 to 30 0 C.
- step (C) the at least one magnetic particle attaches to the hydrophobic substance of the mixture to be treated.
- the bond between the two components is based on hydrophobic interactions. There is generally no binding interaction between the at least one magnetic particle and the hydrophilic portion of the mixture, so that no attachment takes place between these components.
- step (C) addition products of the at least one hydrophobic substance and of the at least one magnetic particle are thus present in the mixture next to the at least one hydrophilic substance.
- Step (D) of the process according to the invention comprises separating the investment product from step (C) from the mixture by applying a magnetic field.
- Step (D) may be carried out in a preferred embodiment by introducing a permanent magnet into the reactor in which the mixture from step (C) is located.
- a permanent magnet for example, the glass wall of the reactor.
- an electrically switchable magnet is used in step (D) which is magnetic only when an electric current flows. Suitable devices are known in the art.
- Step (D) of the process according to the invention can be carried out at any suitable temperature, for example 10 to 60 ° C.
- step (D) the mixture is preferably stirred continuously with a suitable stirrer, for example a Teflon stirring bar or a paddle stirrer.
- a suitable stirrer for example a Teflon stirring bar or a paddle stirrer.
- step (D) the adduct of step (C) may optionally be separated by any method known to those skilled in the art, for example by draining the liquid with the hydrophilic portion of the suspension from the bottom valve from the reactor used for step (D) or pumping it off held by the at least one magnet portions of the suspension through a hose.
- Step (E) of the process according to the invention comprises cleaving the separated addition product from step (D) in order to obtain the at least one first substance and the at least one magnetic particle separately.
- the cleavage in step (E) is not destructive, i. that the individual components present in the dispersion are not chemically changed.
- the cleavage according to the invention does not take place by oxidation of the hydrophobizing agent, for example to obtain the oxidation products or degradation products of the hydrophobizing agent.
- the splitting can be carried out by all methods known to those skilled in the art, which are suitable for splitting the addition product in such a way that the at least one magnetic particle can be recovered in reusable form.
- the cleaved magnetic particle is used again in step (C).
- the cleavage in step (E) of the process according to the invention is carried out by treating the addition product with a substance selected from the group consisting of organic solvents, basic compounds, acidic compounds, oxidizing agents, reducing agents, surface-active compounds and mixtures thereof.
- suitable organic solvents are methanol, ethanol, propanol, for example n-propanol or isopropanol, aromatic solvents, for example benzene, toluene, xylene, ethers, for example diethyl ether, methyl t-butyl ether, ketones, for example acetone, aromatic or aliphatic hydrocarbons, for example saturated hydrocarbons having, for example, 8 to 16 carbon atoms, for example dodecane and / or Shellsol®, diesel fuels and Mixtures thereof.
- the main components of the diesel fuel are mainly alkanes, cycloalkanes and aromatic hydrocarbons having about 9 to 22 carbon atoms per molecule and a boiling range between 170 0 C and 390 0 C.
- step (D) is carried out by addition of aqueous NaOH solution up to a pH of 13, for example for the separation of OPS-modified Cu 2 S.
- the acidic compounds may be mineral acids, for example HCl, H 2 SO 4 , HNO 3 or mixtures thereof, organic acids, for example carboxylic acids.
- H 2 O 2 can be used as the oxidizing agent, for example as a 30% strength by weight aqueous solution (perhydrol).
- aqueous solution perhydrol
- For the separation of thiols modified Cu 2 S is preferably H 2 O 2 or Na 2 S 2 O 4 used.
- Examples of surface-active compounds which can be used according to the invention are nonionic, anionic, cationic and / or zwitterionic surfactants.
- the addition product of hydrophobic substance and magnetic particle is cleaved with an organic solvent, particularly preferably with acetone and / or diesel. This process can also be supported mechanically. In a preferred embodiment, ultrasound is used to assist the cleavage process.
- the organic solvent is used in an amount sufficient to cleave as much of the entire addition product as possible. In a preferred embodiment, 20 to 100 ml of the organic solvent are used per gram of hydrophobic and magnetic particle cleavage product.
- the at least one first substance and the at least one magnetic particle are present as a dispersion in said cleavage reagent, preferably an organic solvent.
- the at least one magnetic particle is separated from the dispersion containing this at least one magnetic particle and the at least one first substance by a permanent or switchable magnet from the solution. Details of this separation are analogous to step (D) of the process according to the invention.
- the first material to be separated off preferably the metal compound to be separated, is separated from the organic solvent by distilling off the organic solvent.
- the first substance obtainable in this way can be purified by further methods known to those skilled in the art.
- the solvent can, if appropriate after purification, be recycled back to the process according to the invention.
- a mixture of 10.0 g sea sand (Bernd Kraft GmbH, purified with hydrochloric acid, lot 1046306), 2.02 g Cu 2 S (powder, 325 mesh, Aldrich Lot 01516LD-416) and 1, 7% by weight 1 Octanethiol (98%, eg synthesis by Merck, batch S20709716) is ground in a planetary ball mill (500 mL agate container with 50 agate balls (0 10 mm) for 30 min at 200 rpm Vacuum drying cabinet (p ⁇ 100 mbar) for 16 h at 50 0 C dried.
- Vacuum drying cabinet p ⁇ 100 mbar
- This mixture is mixed with 1.506 g of magnetite which has been modified with dodecyltrichlorosilane (primary particle size: about 10 nm) in a 1 l stirred apparatus, with 580 ml of water and 0.1 g of dodecylamine (Alfa Aeser Lot: 10108955) and mixed for 45 min at 150 U / min, with a Teflonrmixbalken. Then we held a Co-Sm magnet (5 cm in height, 2 cm in length, 2 cm in width) to an outer wall of the stirring apparatus and another 30 min. at 150 rpm, stirred. The water is then removed via a hose and the apparatus is dried for a further 10 minutes with a hot-air blower.
- dodecyltrichlorosilane primary particle size: about 10 nm
- the sand which is on the ground, is weighed back with 9.77 g.
- the residue on the magnet is 1.76 g (87% of the Cu 2 S used).
- the basin is then filled with 400 ml of acetone and stirred for 30 min at 200 rev / min. Then, the acetone in which the Cu 2 S is a fine particle is drained through a tube and dried. This gives 1.59 g (79% Cu 2 S).
- But 1-octanethiol uses potassium butyl xanthate.
- the further experimental procedure is analogous to Example 1.
- the amount of sand on the ground is 9.64 g, the residue on Magnets 1, 61 g (80.0% C11 2 S).
- Type S8 is milled with 0.03 g of octylphosphonic acid (Rhodia; 80%) in 30 ml of water for 1 h.
- the quartz content of the magnet is ⁇ 0.5% by weight.
- the assembly is flooded with 0.1 M NaOH solution, shaken gently and then the liquid is removed. After drying, 60% of the Cu 2 S are found again.
- 0.5 g of Pd-coated ZnO are dispersed in 10 ml of demineralized water, whereupon the solution turns gray. Subsequently, 0.5 g of thiol-modified Fe 3 O 4 are added and stirred vigorously. After 1 h, a Co / Sm magnet is held to the outer wall of the vessel, whereby the solution is largely clarified. The supernatant solution is decanted off from the magnetic components and the volatiles are removed in vacuo. There are found again 0.1 gg Pd-coated ZnO, ie the rest of the ZnO is magnetically separated from the mixture.
- 1, 00 g of palladium powder are mixed with 1, 7 wt .-% octanethiol in the ball mill and placed in 50 mL of deionized water. Subsequently, 4.00 g are hydrophobicized. Fe 3 O 4 is added and the system is shaken for 3 times 15 min. Subsequently, a Co / Sm magnet is held to one side of the reaction vessel. The water is decanted off, with the magnet holding the solid components on the glass wall. From the supernatant solution, 0.11 g of palladium are isolated. The remainder (0.89 g, corresponding to 89%) are correspondingly magnetically separated from the solution and collected on the magnet.
- Example 7 Processing of natural copper ore from Pelambres (Chile)
- the ore rock is comminuted dry in a hammer mill until 90% by weight of the ore in the fraction is less than 125 ⁇ m in size.
- Magnetic Pigment 345 (BASF SE) is treated with 0.5% by weight of octylphosphonic acid in aqueous solution for 30 minutes at room temperature (RT). The solid is filtered off, washed until the conductivity of about 50 .mu.s with hot water (50 0 C) and dried at 80 0 C in a vacuum.
- 100 g of ore are conditioned in a vibrating mill (160 ml ZrO 2 balls, 0 1, 7-2.7 mm) with 60 ml water, 0.065 g potassium n-octyl xanthate and 0.04 g Shellsol D40 for 5 min.
- a suspension of 3 g of hydrophobized magnetite in 3 g of isopropanol is added to the grinding vessel and conditioned again for 5 min.
- the grinding suspension is separated from the grinding media, diluted to 1 L and subjected to the separation procedure (see above).
- the fraction R (6.4 g) contains all the magnetite used and 92.4% of the copper and 86.1% of the molybdenum.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Iron (AREA)
- Soft Magnetic Materials (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Priority Applications (2)
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EP08803482.2A EP2190584B1 (fr) | 2007-09-03 | 2008-09-01 | Traitement de minerais de valeur au moyen de particules magnétiques |
PL08803482T PL2190584T3 (pl) | 2007-09-03 | 2008-09-01 | Przerób wartościowych rud z użyciem cząstek magnetycznych |
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EP07115542 | 2007-09-03 | ||
EP08803482.2A EP2190584B1 (fr) | 2007-09-03 | 2008-09-01 | Traitement de minerais de valeur au moyen de particules magnétiques |
PCT/EP2008/061503 WO2009030669A2 (fr) | 2007-09-03 | 2008-09-01 | Traitement de minerais de valeur au moyen de particules magnétiques |
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EP2190584B1 EP2190584B1 (fr) | 2013-06-05 |
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US (1) | US8318025B2 (fr) |
EP (1) | EP2190584B1 (fr) |
JP (1) | JP2010537818A (fr) |
CN (1) | CN101815581B (fr) |
AR (1) | AR068164A1 (fr) |
AU (1) | AU2008294826B2 (fr) |
BR (1) | BRPI0816189A2 (fr) |
CA (1) | CA2698216C (fr) |
CL (1) | CL2008002609A1 (fr) |
EA (1) | EA017511B1 (fr) |
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MX (1) | MX2010002462A (fr) |
PE (1) | PE20090869A1 (fr) |
PL (1) | PL2190584T3 (fr) |
PT (1) | PT2190584E (fr) |
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WO2010084635A1 (fr) * | 2009-01-23 | 2010-07-29 | 財団法人大阪産業振興機構 | Dispositif et procédé de traitement de mélange |
CA2753486C (fr) | 2009-02-24 | 2016-11-01 | Basf Se | Separation cu-mo |
CN102341178B (zh) | 2009-03-04 | 2015-06-03 | 西门子公司 | 通过多级式调节进行有色金属矿物的磁分离 |
EP2403649B1 (fr) * | 2009-03-04 | 2013-08-28 | Basf Se | Agglomérats hydrophobes magnétiques |
DE102009038666A1 (de) * | 2009-08-24 | 2011-03-10 | Siemens Aktiengesellschaft | Verfahren zur kontinuierlichen magnetischen Erztrennung und/oder -aufbereitung sowie zugehörige Anlage |
BR112012011217A2 (pt) * | 2009-11-11 | 2016-07-05 | Basf Se | processo para separar aglomerados de mineral de minério e pelo menos uma partícula magnética como constituintes magnéticos de uma dispersão aquosa , reator, e, uso do reator |
EP2498913B8 (fr) * | 2009-11-11 | 2014-10-08 | Basf Se | Procédé permettant d'augmenter le rendement lors d'un processus de séparation de minerais au moyen de particules magnétiques hydrophobes par l'apport ciblé d'énergie mécanique |
US8475662B2 (en) * | 2009-11-30 | 2013-07-02 | Basf Se | Modified HIMS process |
WO2011138243A1 (fr) | 2010-05-06 | 2011-11-10 | Basf Se | Formulation de magnétite rendue hydrophobe |
PL2579987T3 (pl) | 2010-06-11 | 2020-08-24 | Basf Se | Zastosowanie naturalnie występujących składników magnetycznych z rud |
US8865000B2 (en) | 2010-06-11 | 2014-10-21 | Basf Se | Utilization of the naturally occurring magnetic constituents of ores |
US20120132032A1 (en) * | 2010-11-29 | 2012-05-31 | Basf Corporation | Magnetic recovery of valuables from slag material |
MX2013006028A (es) * | 2010-11-29 | 2013-07-29 | Basf Corp | Recuperacion magnetica de elementos de valor a partir de escoria. |
DE102010064139A1 (de) * | 2010-12-23 | 2012-06-28 | Siemens Aktiengesellschaft | Verfahren und Vorrichtung zur Trennung von Öl und Wasser aus einer Öl/Wasser-Emulsion |
AU2012213470A1 (en) | 2011-02-01 | 2013-08-15 | Basf Corporation | Apparatus for continuous separation of magnetic constituents and cleaning magnetic fraction |
US9981272B2 (en) | 2011-05-25 | 2018-05-29 | Cidra Corporate Services, Inc. | Techniques for transporting synthetic beads or bubbles in a flotation cell or column |
US9731221B2 (en) | 2011-05-25 | 2017-08-15 | Cidra Corporate Services, Inc. | Apparatus having polymer surfaces having a siloxane functional group |
GB201115823D0 (en) | 2011-09-13 | 2011-10-26 | Novel Polymer Solutions Ltd | Mineral processing |
US9932525B2 (en) | 2012-02-28 | 2018-04-03 | Cidra Corporate Services, Inc. | Method and system for flotation separation in a magnetically controllable and steerable medium |
US9387485B2 (en) | 2012-04-23 | 2016-07-12 | Basf Se | Magnetic separation of particles including one-step-conditioning of a pulp |
AU2013254846B2 (en) * | 2012-04-23 | 2017-12-07 | Basf Se | Magnetic separation of particles including one-step-conditioning of a pulp |
AU2013258104A1 (en) * | 2012-05-09 | 2014-11-13 | Basf Se | Apparatus for resource-friendly separation of magnetic particles from non-magnetic particles |
US9216420B2 (en) | 2012-05-09 | 2015-12-22 | Basf Se | Apparatus for resource-friendly separation of magnetic particles from non-magnetic particles |
WO2014029715A1 (fr) | 2012-08-21 | 2014-02-27 | Basf Se | Agencement magnétique pour le transport de matériau magnétisé |
WO2014068142A1 (fr) | 2012-11-05 | 2014-05-08 | Basf Se | Appareil permettant la séparation continue de constituants magnétiques |
WO2015104324A1 (fr) | 2014-01-08 | 2015-07-16 | Basf Se | Procédé pour réduire par élutriation le débit volumique d'un flux comprenant des agglomérats magnétiques |
WO2016083575A1 (fr) * | 2014-11-27 | 2016-06-02 | Basf Se | Entrée d'énergie pendant l'agglomération de séparation magnétique |
CA2967215A1 (fr) * | 2014-11-27 | 2016-06-02 | Basf Se | Amelioration de la qualite de concentre |
AU2016200868B2 (en) | 2015-02-10 | 2021-05-13 | Scandium International Mining Corporation | Systems and processes for recovering scandium values from laterite ores |
JP6690565B2 (ja) * | 2017-01-31 | 2020-04-28 | Jfeスチール株式会社 | 磁力選別方法及び装置 |
CA3058159C (fr) * | 2017-03-27 | 2021-11-30 | Cidra Corporate Services Llc | Elimination de particules hydrophobes a l'aide de dioxyde de carbone |
MX2020001255A (es) | 2017-08-03 | 2020-03-20 | Basf Se | Separacion de una mezcla utilizando particulas portadoras magneticas. |
PE20210804A1 (es) * | 2018-08-13 | 2021-04-23 | Basf Se | Combinacion de separacion de portador magnetico y una separacion adicional para el procesamiento de minerales |
CN111500879B (zh) * | 2020-05-28 | 2021-07-27 | 清华大学 | 基于磁性Janus颗粒的萃取稀土元素的方法 |
CN112718231B (zh) * | 2020-12-15 | 2023-04-21 | 中国地质科学院郑州矿产综合利用研究所 | 富镁矿物的辉钼矿的选矿方法 |
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UA97543C2 (uk) | 2012-02-27 |
MX2010002462A (es) | 2010-03-26 |
ZA201002330B (en) | 2011-06-29 |
PT2190584E (pt) | 2013-08-28 |
CA2698216C (fr) | 2017-01-10 |
CA2698216A1 (fr) | 2009-03-12 |
JP2010537818A (ja) | 2010-12-09 |
US20100300941A1 (en) | 2010-12-02 |
BRPI0816189A2 (pt) | 2015-04-14 |
CL2008002609A1 (es) | 2009-10-23 |
PE20090869A1 (es) | 2009-08-08 |
ES2426614T3 (es) | 2013-10-24 |
WO2009030669A3 (fr) | 2009-04-23 |
AR068164A1 (es) | 2009-11-04 |
US8318025B2 (en) | 2012-11-27 |
EA017511B1 (ru) | 2013-01-30 |
PL2190584T3 (pl) | 2013-11-29 |
WO2009030669A2 (fr) | 2009-03-12 |
EP2190584B1 (fr) | 2013-06-05 |
AU2008294826A1 (en) | 2009-03-12 |
CN101815581A (zh) | 2010-08-25 |
AU2008294826B2 (en) | 2013-02-07 |
CN101815581B (zh) | 2015-01-21 |
EA201000407A1 (ru) | 2010-10-29 |
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