EP2184257B1 - Heißabfüllanlage mit Wärmerückgewinnung - Google Patents
Heißabfüllanlage mit Wärmerückgewinnung Download PDFInfo
- Publication number
- EP2184257B1 EP2184257B1 EP09174042A EP09174042A EP2184257B1 EP 2184257 B1 EP2184257 B1 EP 2184257B1 EP 09174042 A EP09174042 A EP 09174042A EP 09174042 A EP09174042 A EP 09174042A EP 2184257 B1 EP2184257 B1 EP 2184257B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquid
- heat
- heat exchanger
- bottles
- distributor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000011084 recovery Methods 0.000 title claims description 13
- 239000007788 liquid Substances 0.000 claims abstract description 80
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 238000001816 cooling Methods 0.000 claims description 32
- 239000000945 filler Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 239000006163 transport media Substances 0.000 claims description 6
- 238000012546 transfer Methods 0.000 abstract description 12
- 235000014214 soft drink Nutrition 0.000 abstract 1
- 239000002609 medium Substances 0.000 description 9
- 239000002826 coolant Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009928 pasteurization Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 235000013361 beverage Nutrition 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000009849 vacuum degassing Methods 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 239000011551 heat transfer agent Substances 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- 235000015122 lemonade Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/04—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus without applying pressure
- B67C3/045—Apparatus specially adapted for filling bottles with hot liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/06—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus using counterpressure, i.e. filling while the container is under pressure
- B67C3/14—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus using counterpressure, i.e. filling while the container is under pressure specially adapted for filling with hot liquids
Definitions
- the invention relates to a H exertabglallstrom for a liquid according to the preamble of claim 1 and a method for hot filling of liquids according to the preamble of claim 9 and as from DE 10 2005 053 005 A1 known.
- the hot filling after pasteurization, z. B. in a short-term heater, is a proven method to fill drinks durable in bottles or bags.
- the untreated drink is usually preheated, degassed and then pasteurized.
- z. B. After bottling, z. B. at 85 ° C, the filled bottles in a bottle cooling by means of a coolant flow, z. B. by sprinkling, suitable for further processing temperature of z. B. 30 ° C cooled.
- piggable Pasteurstrom with continuous vacuum degassing, liquid fruit, 8/2002, 508-510 is known to cool down in the hot filling of beverages, especially at a standstill of the bottle filler, already pasteurized liquid in a recooler and a buffer of untreated Re-mix liquid.
- the withdrawn the filled bottles or bags heat is z. B. passed into a heat exchanger for preheating the liquid to be treated.
- the heat removed during the re-cooling of the unfilled liquid is disposed of in known hot filling plants in a cooling tower and is an energy loss to book. This is also to be considered in trouble-free normal operation when a certain proportion of the heated, not yet bottled liquid is recooled and the untreated liquid is mixed again to stabilize the operation of the system.
- the invention has the object of the reason to reduce the energy loss during hot filling in comparison to the known systems.
- the liquid can be preheated with heat obtained during the re-cooling and the energy losses can be reduced.
- the first distributor directs the liquid at a standstill of the bottle filler substantially completely through the recooler. This maximizes the amount of energy available for recovery.
- the hot filling plant comprises a second distributor which adjusts the portion of the heat transport medium to be fed from the recooler into the heat exchanger.
- the heat output to be transmitted can be metered in a targeted manner.
- the first distributor divides the liquid during operation of the bottle filler so that the proportion attributable to 10 - 15% of the portion to be filled. This ensures a stable control of the system.
- the hot filling plant further comprises a bottle cooler for cooling the filled bottles, the return of which is connected to the flow of the heat exchanger, to heat energy from the bottle cooler to the heat exchanger transfer.
- a bottle cooler for cooling the filled bottles, the return of which is connected to the flow of the heat exchanger, to heat energy from the bottle cooler to the heat exchanger transfer.
- the H fostab garllstrom further comprises a third manifold, the heat transfer means from the return of the bottle cooler optionally passes into the heat exchanger or the flow of the bottle cooler.
- the amount of heat recovered can be selectively controlled or the heat transport medium can be circulated as needed.
- the third distributor directs the heat transfer agent from the return of the bottle cooler in the flow of the bottle cooler when no bottles are cooled in the bottle cooler. This delays unwanted cooling of the bottle cooler.
- the flow temperature of the heat exchanger 50 - 80 ° C. This allows a particularly effective heat recovery.
- the underlying object is further achieved by a method for hot filling of liquids according to claim 9.
- the liquid is preheated with heat energy recovered by re-cooling the portion to be recycled.
- the portion to be returned is set to be 10 to 15% of the portion to be filled during bottling. This ensures a stable control of the system.
- the liquid is completely returned at an interruption of the bottling. This maximizes the amount of energy available for recovery.
- the method further comprises the steps of: cooling the filled bottles; and preheating the liquid with heat energy recovered as the bottles cool.
- the released during cooling heat energy can be recovered and used again to heat the liquid.
- the liquid is preheated with thermal energy obtained as the bottles cool and with thermal energy recovered upon cooling.
- thermal energy obtained as the bottles cool and with thermal energy recovered upon cooling.
- the thermal energy obtained during cooling of the bottles is only used for preheating the liquid as long as bottles are cooled. This avoids that a device used for bottle cooling cools down quickly.
- FIG. 1 schematically shows a hot filling plant 1 for a liquid 2, in particular for a drink.
- the dashed arrows indicate the flow direction of the liquid 2 again
- the solid arrows indicate the flow direction of a heat transfer medium 3, such. B. water.
- the hot filling plant 1 accordingly comprises a collecting container 4 for temporarily storing the liquid 2 to be treated and to be filled, which in turn comprises a heat exchanger 6, a preheater 8, a heater 10 and a first adjustable three-way distributor 12 having an inlet 12a and two exits 12b and 12c are connected downstream.
- the heat exchanger 6 comprises an input and an output 6a 6b for the liquid 2, and a forward and a return 6c 6d for the heat transport means 3 and warms the liquid 2 to a preheating temperature T v before, the z. B. is required for a conventional degassing of the liquid in a (not shown) degassing.
- the preheater 8 the liquid 2 additionally pre-heated, for. B. inadequate heat output of the heat exchanger 6 or during startup of the system. 1
- the liquid 2 is heated to a treatment temperature T B , which is higher than the preheating temperature T v .
- the first distributor 12 divides the liquid 2 flowing out of the heater 10 into a portion F A to be filled and a portion F R attributable to the product circuit or collecting container 4.
- the output 12b of the first distributor 12 is followed by a bottle filler 14, which fills the liquid component F A into bottles 16.
- the output 12c is followed by a recooler 18 having an inlet 18a and an outlet 18b for the liquid 2, as well as a feed 18c and a return 18d for the heat transporting means 3.
- the outlet 18b of the recooler 18 leads back to the collecting container 4.
- the recooler 18 forms with a second adjustable three-way manifold 20, the heat exchanger 6 and a first cooling tower 22, a first heat transfer medium circuit 24.
- the input 20a of the second manifold 20 is fed from the return 18 d of the heat exchanger 18 and divides the flow of the heat transfer medium 3 in a share W E for external heat disposal in the first cooling tower 22 and a share W R for heat recovery in the heat exchanger 6. Accordingly, an output 20b of the second distributor 20 is connected to the flow of the first cooling tower 22, the other output 12c to the flow 6c of the heat exchanger 6.
- the hot filling plant 1 further comprises a bottle cooler 28 for cooling the filled bottles 16.
- This comprises a supply line 28c and a return line 28d for the heat transporting means 3 and forms with a third adjustable three-way distributor 30, the heat exchanger 6 and a second cooling tower 32, a second heat transfer medium circuit 34.
- the input 30a of the third distributor 30 is fed from the return line 28d of the bottle cooler 28 and passes the heated in the bottle cooler 28 heat transport means 3 in a first position via the output 30b to the flow 6c of the heat exchanger 6 to heat energy from the bottle cooler 28 for Heat exchanger 6 to transfer.
- the third distributor 30 short-circuits the flow 28c and the return 28d of the bottle cooler 28 via the outlet 30c.
- the liquid 2 is z.
- a drink e.g. Water, milk, juice, beer, lemonade or any other liquid that is treated by heat and filled in the heated state.
- the liquid may include an emulsion, suspension and / or a foam.
- the heat exchanger 6 may, for. Example, be a conventional plate or tubular heat exchanger and is preferably operated at a flow temperature of 50 to 80 ° C.
- both heat transport medium circuits 24 and 34 are in each case connected in parallel to the supply line 6c and the return line 6d.
- the circuits could also be separated from each other, z. B. by check valves, by a separate flow and return 6c, 6d for each circuit or by a two-stage design of the heat exchanger 6. It is crucial that both circuits 24, 34 used for preheating the liquid 2 and can be combined and optimized if necessary , Likewise, the cooling towers 22 and 32 or their cooling capacity and the respective volume flows could deviate from FIG. 1 be interconnected or regulated, as long as they fulfill the function described.
- the preheater 8 may, for. B. be heated with steam.
- the heater 10 is, for example, a conventional, steam-operated, short-lived, heat-retaining heater in which the liquid 2 to be treated is kept at the treatment temperature T B for a certain duration, e.g. B. for pasteurization.
- the heater 10 may include a correction cooler (not shown) to adjust the treated liquid 2 to a suitable temperature for bottling, such as a bottle. B. 85 ° C, adjust.
- the amount of heat withdrawn from the liquid 2 is returned as far as possible to the inlet of the heater 10 in order to heat the inflowing liquid 2.
- the distributor 12 is z. B. an electrically controlled mixing valve, with which the liquid fractions F R and F A can be graded as finely as possible in relation to each other or continuously changed as can also be adjusted so the liquid 2 is conducted exclusively to the bottle filler 14 or to the recooler 18.
- the bottle filler 14 fills the heated liquid 2 supplied to it continuously in bottles 16 in a conventional manner.
- the bottles 16 may, for. B. made of glass or plastic.
- other containers such. B. bag, to be filled.
- the filled bottles 16 are in the bottle cooler 28 z. B. by sprinkling with water to a temperature suitable for further processing, such. B. 30 ° C, cooled.
- the bottle cooler 28 may, for. B. be designed as a multi-stage cooling tunnel.
- the bottle cooler 28 is designed so that the highest possible return temperature is achieved, for. B. in the range of 50 to 80 ° C to optimize the efficiency of heat recovery at the heat exchanger 6. This can be z. B. by a suitable design of individual cooling stages of the cooling tunnel and / or by increasing the residence time of the bottles 16 in the bottle cooler 28 or by reducing the volume flow of the heat transfer medium 3 through the bottle cooler 28th
- the third distributor 30 is preferably an electrically controlled switching valve that either passes the heated heat transfer medium 3 flowing out of the return 28d of the bottle cooler 28 completely to the inlet 6c of the heat exchanger 6 or, in short-circuit operation, returns it to the inlet 28c of the bottle cooler 28.
- the short-circuit operation prevents or delays the cooling of the bottle cooler 28, if temporarily no filled bottles 16 arrive at the bottle cooler 28.
- the third distributor 30 could also be designed as a mixing valve.
- the recooler 18 is preferably designed so that the highest possible return temperature is achieved, for. B. 50 - 80 ° C in order to achieve the highest possible efficiency of heat recovery at the heat exchanger 6.
- the liquid 2 is intended to be cooled approximately to the temperature of the untreated liquid 2, for example to a temperature of about 20-40 ° C, before it mixes in the collecting container 4 with untreated liquid 2.
- the ratio of the heat transfer medium circuits 24 and 34 respectively at the returns 18d and 28d available heat outputs in normal operation corresponds approximately to the ratio F R / F A.
- the heat recovery in the bottle cooler 28 and in the recooler 18, or in the heat medium circuits 34 and 24, can be combined to minimize the energy losses of the filling system 1 in normal operation and / or to optimize their control.
- the entire heated liquid 2 is possible under the conditions of normal operation to cycle in order to continue the filling process quickly.
- FIG. 2 shows the potential for energy recovery in the circuits 24 and 34 available heat output during operation B and during a temporary stoppage S of the bottle filler 14. In normal operation are each substantially constant in time amounts of heat from the circuits 24 and 34 are available.
- the entire liquid 2 is passed from the first manifold 12 in the recooler 18 and cooled in this approximately to the starting temperature of the untreated liquid 2.
- the heat output available at the return 18d of the recooler 18 increases until it corresponds to the output of the bottle cooler 28 during normal operation.
- the third distributor 30 closes the supply line 28 c and the return line 28 d of the bottle cooler 28 at the instant S 'and at the same time prevents the supply 28 c from the second cooling tower 32 from being fed.
- the heat output available overall on the heat exchanger 6 may temporarily fall below a minimum value necessary for preheating the liquid 2, so that additional heat output must be applied by the preheater 8 for this purpose.
- the liquid 2 can be preheated mainly by recovered energy and additional, external energy input compared to conventional systems can be significantly reduced.
Landscapes
- Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
- Steam Or Hot-Water Central Heating Systems (AREA)
- Heat-Pump Type And Storage Water Heaters (AREA)
- Coating With Molten Metal (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL09174042T PL2184257T3 (pl) | 2008-11-10 | 2009-10-26 | Instalacja do rozlewu na gorąco z odzyskiwaniem ciepła |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008056597A DE102008056597A1 (de) | 2008-11-10 | 2008-11-10 | Heißabfüllanlage mit Wärmerückgewinnung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2184257A1 EP2184257A1 (de) | 2010-05-12 |
EP2184257B1 true EP2184257B1 (de) | 2011-09-07 |
Family
ID=41698368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09174042A Active EP2184257B1 (de) | 2008-11-10 | 2009-10-26 | Heißabfüllanlage mit Wärmerückgewinnung |
Country Status (8)
Country | Link |
---|---|
US (1) | US8356643B2 (es) |
EP (1) | EP2184257B1 (es) |
CN (1) | CN101734591B (es) |
AT (1) | ATE523465T1 (es) |
DE (1) | DE102008056597A1 (es) |
DK (1) | DK2184257T3 (es) |
ES (1) | ES2369054T3 (es) |
PL (1) | PL2184257T3 (es) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8356643B2 (en) | 2008-11-10 | 2013-01-22 | Krones Ag | Hot filling system with heat recovery |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008048812A1 (de) * | 2008-09-24 | 2010-04-01 | Khs Ag | Verfahren und Vorrichtung zur kombinierten Herstellung und Abfüllung von Behältern aus Kunststoff |
SE1000367A1 (sv) * | 2010-04-13 | 2011-08-23 | Tetra Laval Holdings & Finance | Metod och anordning för att återvinna energi vid varmfyllning av en flytande livsmedelsprodukt |
DE102011007787A1 (de) * | 2011-04-20 | 2014-01-16 | Krones Aktiengesellschaft | Vorrichtung und Verfahren zum Behandeln eines flüssigen Lebensmittelproduktes |
DE102011082286A1 (de) * | 2011-09-07 | 2013-03-07 | Krones Aktiengesellschaft | Verfahren und Vorrichtung zum Erhitzen eines flüssigen Produkts |
DE102012219759A1 (de) * | 2012-10-29 | 2014-04-30 | Krones Ag | Wärmerückgewinnung aus Tunnelrückkühlerprozess |
DE102014100733A1 (de) * | 2014-01-23 | 2015-07-23 | Krones Ag | Kühlsystem für Behälterbehandlungsanlagen |
DE102014102854A1 (de) | 2014-03-04 | 2015-09-10 | Ziemann International GmbH | Verfahren und Vorrichtung zur Herstellung eines flüssigen Lebensmittels |
DE102016217342A1 (de) | 2016-09-12 | 2018-03-15 | Krones Ag | Abfüllanlage zum Wärmebehandeln und Abfüllen einer Flüssigkeit |
DE102019126946A1 (de) * | 2019-10-08 | 2021-04-08 | Krones Aktiengesellschaft | Verfahren und Vorrichtung zur Heißabfüllung von flüssigem Produkt |
DE102020127542A1 (de) | 2020-10-20 | 2022-04-21 | Krones Aktiengesellschaft | Abfüllanlage und Verfahren zur Heißabfüllung eines flüssigen Produkts in Behälter |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1188164A (en) * | 1966-04-25 | 1970-04-15 | Alfa Laval Ab | A Plant for Continuous Heat Treatment of a Liquid Product |
US5167976A (en) * | 1991-05-24 | 1992-12-01 | Papetti's Hygrade Egg Products Inc. | Method of producing extended refrigerated shelf life bakeable liquid egg |
US5290583A (en) * | 1992-04-02 | 1994-03-01 | David Reznik | Method of electroheating liquid egg and product thereof |
DE29710507U1 (de) * | 1996-06-24 | 1997-08-07 | Fischer, Harald, Dr., Wampersdorf | Vorrichtung zum vorübergehenden Erhitzen, insbesondere Pasteurisieren, eines fließfähigen Lebensmittelproduktes |
AT412064B (de) | 2002-03-28 | 2004-09-27 | Katschnig Helmut | Anlage zum sterilisieren, pasteurisieren und/oder desinfizieren pump- oder rieselfähiger medien |
US7694858B2 (en) * | 2002-12-12 | 2010-04-13 | Suntory Holdings Limited | Liquid filling method and device |
DE10351689A1 (de) * | 2003-11-06 | 2005-06-16 | Khs Maschinen- Und Anlagenbau Ag | Verfahren zum Betreiben einer Pasteurisierungsanlage |
US7435440B2 (en) | 2003-11-20 | 2008-10-14 | Feldmeier Equipment, Inc. | UHT pasteurizer with regeneration and ultra high temperature homogenization |
FR2887238B1 (fr) * | 2005-06-21 | 2007-09-28 | Jean Tristan Outreman | Procede de remplissage a chaud d'un contenant a paroi mince et contenant rempli ainsi obtenu |
ITVI20050282A1 (it) | 2005-10-18 | 2007-04-19 | Manzini Spa | Impianto per il trattamento termicamente controllato di prodotti alimentari, in particolare latte o similari |
DE102005053005B4 (de) | 2005-11-05 | 2014-05-22 | Kelterei Walter Gmbh & Co. Kg | Verfahren und Vorrichtung zum Abfüllen von Getränken |
CN2853757Y (zh) * | 2005-11-11 | 2007-01-03 | 钱志财 | 一种新型灌装机烘箱 |
US20090007522A1 (en) * | 2006-02-28 | 2009-01-08 | Toyo Seikan Kaisha, Ltd | Method of Producing a Drink Contained in a Container |
CN2878340Y (zh) * | 2006-04-05 | 2007-03-14 | 罗晓 | 直线式上下两层塑料瓶大输液洗灌封一体机 |
CN101077764A (zh) * | 2006-05-08 | 2007-11-28 | 桂格燕麦公司 | 具有调味剂注入的热灌装饮料生产 |
DE102008056597A1 (de) | 2008-11-10 | 2010-05-12 | Krones Ag | Heißabfüllanlage mit Wärmerückgewinnung |
-
2008
- 2008-11-10 DE DE102008056597A patent/DE102008056597A1/de not_active Withdrawn
-
2009
- 2009-10-26 DK DK09174042.3T patent/DK2184257T3/da active
- 2009-10-26 PL PL09174042T patent/PL2184257T3/pl unknown
- 2009-10-26 ES ES09174042T patent/ES2369054T3/es active Active
- 2009-10-26 EP EP09174042A patent/EP2184257B1/de active Active
- 2009-10-26 AT AT09174042T patent/ATE523465T1/de active
- 2009-11-09 US US12/614,636 patent/US8356643B2/en active Active
- 2009-11-10 CN CN2009102121457A patent/CN101734591B/zh not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8356643B2 (en) | 2008-11-10 | 2013-01-22 | Krones Ag | Hot filling system with heat recovery |
Also Published As
Publication number | Publication date |
---|---|
PL2184257T3 (pl) | 2012-02-29 |
CN101734591A (zh) | 2010-06-16 |
ATE523465T1 (de) | 2011-09-15 |
DE102008056597A1 (de) | 2010-05-12 |
ES2369054T3 (es) | 2011-11-24 |
EP2184257A1 (de) | 2010-05-12 |
CN101734591B (zh) | 2012-09-05 |
DK2184257T3 (da) | 2011-12-12 |
US20100139214A1 (en) | 2010-06-10 |
US8356643B2 (en) | 2013-01-22 |
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