EP2103888B1 - Kühlvorrichtung - Google Patents

Kühlvorrichtung Download PDF

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Publication number
EP2103888B1
EP2103888B1 EP07860041.8A EP07860041A EP2103888B1 EP 2103888 B1 EP2103888 B1 EP 2103888B1 EP 07860041 A EP07860041 A EP 07860041A EP 2103888 B1 EP2103888 B1 EP 2103888B1
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EP
European Patent Office
Prior art keywords
refrigerant
pressure
outdoor
indoor
refrigeration apparatus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP07860041.8A
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English (en)
French (fr)
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EP2103888A4 (de
EP2103888A1 (de
Inventor
Yoshio Ueno
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daikin Industries Ltd
Original Assignee
Daikin Industries Ltd
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Priority to EP12187178.4A priority Critical patent/EP2543939A3/de
Publication of EP2103888A1 publication Critical patent/EP2103888A1/de
Publication of EP2103888A4 publication Critical patent/EP2103888A4/de
Application granted granted Critical
Publication of EP2103888B1 publication Critical patent/EP2103888B1/de
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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B13/00—Compression machines, plants or systems, with reversible cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00—Gas cycle refrigeration machines
    • F25B2309/06—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • F25B2309/061—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
    • F25B2313/005—Outdoor unit expansion valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2313/00—Compression machines, plants or systems with reversible cycle not otherwise provided for
    • F25B2313/029—Control issues
    • F25B2313/0294—Control issues related to the outdoor fan, e.g. controlling speed
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2341/00—Details of ejectors not being used as compression device; Details of flow restrictors or expansion valves
    • F25B2341/06—Details of flow restrictors or expansion valves
    • F25B2341/063—Feed forward expansion valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2500/00—Problems to be solved
    • F25B2500/12—Sound
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2500/00—Problems to be solved
    • F25B2500/19—Calculation of parameters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00—Control issues
    • F25B2600/17—Control issues by controlling the pressure of the condenser
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00—Control issues
    • F25B2600/25—Control of valves
    • F25B2600/2513—Expansion valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00—Sensing or detecting of parameters; Sensors therefor
    • F25B2700/19—Pressures
    • F25B2700/193—Pressures of the compressor
    • F25B2700/1931—Discharge pressures
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00—Sensing or detecting of parameters; Sensors therefor
    • F25B2700/21—Temperatures
    • F25B2700/2106—Temperatures of fresh outdoor air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00—Sensing or detecting of parameters; Sensors therefor
    • F25B2700/21—Temperatures
    • F25B2700/2117—Temperatures of an evaporator
    • F25B2700/21174—Temperatures of an evaporator of the refrigerant at the inlet of the evaporator

Definitions

  • the present invention relates to a refrigeration apparatus using refrigerant operating in the supercritical zone.
  • a refrigeration apparatus using supercritical refrigerant (e.g., CO 2 refrigerant) operating in the supercritical zone as refrigerant, has been conventionally produced (see JP-A-2000-234814 ).
  • supercritical refrigerant e.g., CO 2 refrigerant
  • DE 10 2006 003 827 A1 discloses a refrigeration apparatus using a supercritical refrigerant. According to this document, an expansion valve is opened or closed in response to a signal of a pressure sensor and with respect to a calculated target high pressure.
  • WO 2006/087005 A1 and JP 2003 028522 A disclose refrigeration devices using a target high-pressure of a supercritical refrigerant.
  • refrigerant in a gas-liquid two-phase state may flow into an expansion mechanism when high pressure of the refrigerant does not reach a fully pressurized level in the activation of the refrigeration apparatus or when temperature of the refrigerant does not reach the critical temperature because of low external temperature.
  • flow sound of the refrigerant is easily generated in a vicinity of an inlet of the expansion mechanism. This will be a cause of noise to be produced when the refrigeration apparatus is operated.
  • a refrigeration apparatus is a refrigeration apparatus using supercritical refrigerant operating in a zone that high pressure of the supercritical refrigerant is equal to or greater than the critical pressure.
  • the refrigeration apparatus includes a compressor, a gas cooler, an expansion mechanism, an evaporator, discharge pressure detection means and a control section.
  • the compressor is configured to compress the supercritical refrigerant.
  • the gas cooler is configured to cool the supercritical refrigerant compressed by the compressor.
  • the expansion mechanism is configured to decompress the supercritical refrigerant.
  • the evaporator is configured to evaporate the supercritical refrigerant decompressed by the expansion mechanism.
  • the discharge pressure detection means is capable of detecting discharge pressure of the compressor.
  • the control section is configured to regulate opening degree of the expansion mechanism for controlling the discharge pressure to be equal to or greater than the critical pressure when the refrigeration apparatus is activated and the discharge pressure is less than the critical pressure.
  • control section is configured to regulate the opening degree of the expansion mechanism for controlling the discharge pressure to be equal to or greater than the critical pressure when it determines that the discharge pressure is less than the critical pressure in the activation of the refrigeration apparatus.
  • a refrigeration apparatus is the refrigeration apparatus according to the first aspect of the present invention, wherein the control section is configured to execute a first control for setting the opening degree of the expansion mechanism to be fully-closed or a slightly-opened degree when the discharge pressure is less than the critical pressure.
  • control section is configured to set the opening degree of the expansion mechanism to be fully-closed or a slightly opened degree when the discharge pressure is less than the critical pressure. Therefore, it is possible to easily set high pressure of the refrigerant in the refrigeration cycle to be equal to or greater than the critical pressure. Consequently, it is possible to inhibit generation of flow sound of the refrigerant in a vicinity of the inlet of the expansion mechanism.
  • a refrigeration apparatus is the refrigeration apparatus according to the second aspect of the present invention, wherein the control section is configured to execute a second control for setting the opening degree of the expansion mechanism to be large when the discharge pressure is equal to or greater than the critical pressure after the first control is executed.
  • the refrigerant When the refrigerant is pressurized to be equal to or greater than the critical pressure, the refrigerant enters a supercritical state or a liquid-phase state. In other words, the refrigerant is not in a gas-liquid two-phase state any more. Accordingly, it is possible to reduce generation of flow sound in a vicinity of the inlet of the expansion mechanism without further pressurizing the refrigerant.
  • control section is configured to execute the second control for opening the expansion mechanism when the discharge pressure is equal to or greater than the critical pressure after execution of the first control for easily increasing the high pressure of the refrigerant. Therefore, it is possible to optimally control the discharge pressure without unnecessarily increasing it. Consequently, it is possible to reduce energy consumption.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to third aspects of the present invention, wherein the discharge pressure detection means is a pressure sensor provided at the discharge side of the compressor.
  • the pressure sensor is configured to detect the discharge pressure and determination is made for whether or not the refrigerant is in a supercritical state. Therefore, it is possible to directly detect high pressure of the refrigerant in the refrigeration cycle based on the discharge pressure. Accordingly, it is possible to proceed to the second control from the first control while a period of time necessary for the first control is minimized. Also, it is possible to optimally control high pressure of the refrigerant without unnecessarily increasing it. Consequently, it is capable of reducing energy loss.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to fourth aspects of the present invention, wherein the control section is configured to calculate inlet pressure of the expansion mechanism based on the discharge pressure and operational capacity of the compressor. Additionally, the control section is configured to regulate the opening degree of the expansion mechanism for controlling the discharge pressure to be equal to or greater than the critical pressure when the inlet pressure is less than the critical pressure.
  • the inlet pressure of the expansion mechanism is calculated based on the discharge pressure and the compressor capacity.
  • the discharge pressure and the inlet pressure of the expansion mechanism are different from each other because pressure-loss exists in the refrigerant pipe. Therefore, it is possible to more reliably control a state of the refrigerant in the vicinity of the inlet of the expansion mechanism (i.e., the cause of generation of noise) from a gas-liquid two-phase state to a supercritical state or a liquid-phase state.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to third aspects of the present invention, wherein the pressure detection means is a temperature sensor capable of detecting temperature of the supercritical refrigerant in a range from an outlet of the gas cooler to an inlet of the expansion mechanism. Additionally, the control section is configured to determine that the inlet pressure is less than the critical pressure when the inlet temperature is less than the critical temperature, and is configured to regulate the opening degree of the expansion mechanism for controlling the inlet temperature to be equal to or greater than the critical temperature.
  • the temperature sensor is configured to detect refrigerant temperature in a range from the outlet of the gas cooler to the inlet of the expansion mechanism, and determination is made for whether or not the refrigerant is in a supercritical state. Therefore, it is possible to determine that the refrigerant in a vicinity of the inlet of the expansion mechanism is not in a gas-liquid two-phase state, and it is also possible to reduce a blowout sound of bubbles and the like, which is a factor of flow sound. Furthermore, the pressure sensor in the fourth aspect of the present invention is allowed to be replaced by a temperature sensor, which is cheaper than the pressure sensor. Accordingly, it is possible to reduce its production cost.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to sixth aspects of the present invention, wherein the refrigeration apparatus further includes a blower.
  • the blower promotes cooling of the gas cooler.
  • the control section is configured to control the airflow volume of the blower to be small or zero when the refrigeration apparatus is activated and the discharge pressure is less than the critical pressure.
  • control section is configured to set the airflow volume of the blower, which is configured to blow air to the gas cooler for promoting cooling of the gas cooler, to be small or zero when the refrigeration apparatus is activated and the discharge pressure is less than the critical pressure. Therefore, it is possible to weaken a cooling effect in the gas cooler, and it is also possible to increase both temperature and pressure of the refrigerant in the gas cooler. Accordingly, it is possible to set a state of the refrigerant at the outlet of the gas cooler to be a supercritical state or a liquid-phase state. Consequently, it is possible to reduce generation of flow sound in a vicinity of the inlet of the expansion mechanism.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to seventh aspects of the present invention, wherein the control section is configured to regulate the opening degree of the expansion mechanism for controlling the discharge pressure to be equal to or greater than the critical pressure when a normal operation is executed.
  • control section is configured to control the discharge pressure to be equal to or greater than the critical pressure not only in the activation of the refrigeration apparatus but also in the normal operation. Therefore, it is always possible to set a state of the refrigerant in a vicinity of the inlet of the expansion mechanism to be a supercritical state or a liquid-phase state. Consequently, it is possible to reduce generation of flow sound at the inlet of the expansion mechanism.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to seventh aspects of the present invention, wherein the control section is configured to regulate the opening degree of the expansion mechanism for controlling the discharge pressure to be equal to or greater than the critical pressure even when a normal operation is executed at a low external temperature.
  • the control section is configured to regulate the opening degree of the expansion mechanism for controlling high pressure of the supercritical refrigerant to be equal to or greater than the critical pressure even at the low external temperature. Therefore, it is possible to set a state of the refrigerant in a vicinity of the inlet of the expansion mechanism to be a supercritical state or a liquid-phase state.
  • a refrigeration apparatus is the refrigeration apparatus according to the ninth aspect of the present invention, wherein the low external temperature is defined as the external temperature equal to or less than 20 degrees Celsius.
  • the discharge pressure is controlled to be equal to or greater than the critical pressure under a condition that the supercritical refrigerant easily enters a gas-liquid two-phase state (e.g., a condition that the external temperature is equal to or less than 20 degrees Celsius). Therefore, it is possible to change a state of the supercritical refrigerant in a vicinity of the inlet of the expansion mechanism from a gas-liquid two-phase state to a supercritical state or a liquid-phase state even when the external temperature is equal to or less than 20 degrees Celsius.
  • a refrigeration apparatus is the refrigeration apparatus according to any of the first to tenth aspects of the present invention, wherein the supercritical refrigerant is carbon dioxide (CO 2 ) refrigerant
  • the CO 2 refrigerant is used as refrigerant Ozone depletion potential (ODP) of the CO 2 refrigerant equals to zero. Therefore, the CO 2 refrigerant does not destroy the ozone layer above the earth. Furthermore, global warming potential (GWP) of the CO 2 refrigerant equals to 1. This is much lower than GWP of fluorocarbon refrigerant of about hundreds to ten thousand. Accordingly, the refrigerant apparatus is capable of inhibiting worsening of global environment with use of the CO 2 refrigerant with less environmental burden.
  • ODP Ozone depletion potential
  • the refrigeration apparatus of the first aspect of the present invention it is possible to change a state of the supercritical refrigerant from a gas-liquid two-phase state to a supercritical state or a liquid-phase state by setting high pressure of the supercritical refrigerant in the refrigeration cycle to be equal to or greater than the critical pressure. Therefore, it is possible to inhibit generation of flow sound due to a blowout of bubbles and the like.
  • the refrigeration apparatus of the second aspect of the present invention it is possible to easily set high pressure of the supercritical refrigerant in the refrigeration cycle to be equal to or greater than the critical pressure. Therefore, it is possible to inhibit generation of flow sound due to a blowout of bubbles and the like.
  • the refrigeration apparatus of the third aspect of the present invention it is possible to optimally control the discharge pressure without unnecessarily increasing it. Consequently, it is possible to reduce energy consumption.
  • the refrigeration apparatus of the fourth aspect of the present invention it is possible to directly detect high pressure of the supercritical refrigerant in the refrigeration cycle based on the discharge pressure. Therefore, it is possible to proceed to the second control from the first control while a period of time necessary for the first control is minimized. Also, it is possible to optimally control high pressure of the supercritical refrigerant without unnecessarily increasing it. Consequently, it is possible to reduce energy loss.
  • the refrigeration apparatus of the fifth aspect of the present invention it is possible to more reliably control a state of the refrigerant in a vicinity of the inlet of the expansion mechanism (i.e., the cause of generation of noise) from a gas-liquid two-phase state to a supercritical state or a liquid-phase state.
  • the refrigeration apparatus of the sixth aspect of the present invention it is possible to determine that the refrigerant in a vicinity of the inlet of the expansion mechanism is not in a gas-liquid two-phase state, and it is also possible to reduce a blowout sound of bubbles and the like, which is a factor of flow sound.
  • the pressure sensor in the fourth aspect of the present invention is allowed to be replaced by a temperature senor, which is cheaper than the pressure sensor. Accordingly, it is possible to reduce its production cost.
  • the refrigeration apparatus of the seventh aspect of the present invention it is possible to weaken a cooling effect in the gas cooler, and it is also possible to increase both temperature and pressure of refrigerant in the gas cooler. Therefore, it is possible to set a state of the refrigerant at the outlet of the gas cooler to be a supercritical state or a liquid-phase state. Consequently, it is possible to reduce generation of flow sound in a vicinity of the inlet of the expansion mechanism.
  • the refrigeration apparatus of the eighth aspect of the present invention it is possible to always set a state of the refrigerant in a vicinity of the inlet of the expansion mechanism to be a supercritical state or a liquid-phase state. Therefore, it is possible to reduce generation of flow sound at the inlet of the expansion mechanism.
  • a state of the refrigerant in a vicinity of the inlet of the expansion mechanism it is possible to set a state of the refrigerant in a vicinity of the inlet of the expansion mechanism to be a supercritical state or a liquid-phase state even at the low external temperature.
  • the refrigeration apparatus of the tenth aspect of the present invention it is possible to change a state of the supercritical refrigerant from a gas-liquid two-phase state to a supercritical state or a liquid-phase state even when the external temperature is equal to or less than 20 degrees Celsius.
  • the refrigeration apparatus of the twelfth aspect of the present invention it is possible to inhibit worsening of global environment with use of the CO 2 refrigerant with less environmental burden.
  • Fig. 1 is a schematic configuration diagram of an air conditioning apparatus 1 according to an embodiment of the present invention.
  • the air conditioning apparatus 1 is an apparatus used for cooling and heating the indoor space of a building and the like.
  • carbon dioxide (CO 2 ) refrigerant which is supercritical refrigerant
  • the air conditioning apparatus 1 mainly includes an outdoor unit 2, an indoor unit 3 and a refrigerant communication pipe 4.
  • the outdoor unit 2 functions as a heat source unit.
  • the indoor unit 3 is connected to the outdoor unit 2, and functions as a utilization unit.
  • the refrigerant communication pipe 4 connects the indoor unit 3 and the outdoor unit 2.
  • the refrigerant communication pipe 4 is composed of a liquid refrigerant communication pipe 41 and a gas refrigerant communication pipe 42.
  • a refrigerant circuit 10 of the air conditioning apparatus 1 according to the present embodiment is formed by the interconnection among the outdoor unit 2, the indoor unit 3 and the refrigerant communication pipe 4.
  • the outdoor unit 2 is disposed outside a building and the like.
  • the outdoor unit 2 is connected to the indoor unit 3 through the refrigerant communication pipe 4.
  • the outdoor unit 2 forms a part of the refrigerant circuit 10.
  • the outdoor unit 2 mainly includes an outdoor side refrigerant circuit 20.
  • the outdoor side refrigerant circuit 20 forms a part of the refrigerant circuit 10.
  • the outdoor side refrigerant circuit 20 mainly includes a compressor 21, a four-way switch valve V1, an outdoor heat exchanger 23 functioning as a heat source side heat exchanger, an outdoor expansion valve V2 functioning as an expansion mechanism, a liquid side stop valve V3 and a gas side stop valve V4.
  • the compressor 21 is a compressor capable of changing its operation capacity.
  • the compressor 21 is a positive-displacement compressor to be driven by a motor 22.
  • rotation speed of the motor 22 is controlled by an inverter.
  • only single compressor 21 is provided in the present embodiment.
  • the number of the compressor 21 is not limited to this.
  • two or more compressors may be parallel-connected depending on the number of indoor units and the like to be connected to the outdoor unit 2.
  • the four-way switch valve V1 is a valve provided for causing the outdoor heat exchanger 23 to function as a gas cooler and an evaporator.
  • the four-way switch valve V1 is connected to the outdoor heat exchanger 23, a suction side of the compressor 21, a discharge side of the compressor 21 and the gas refrigerant communication pipe 42.
  • the four-way switch valve V1 is configured to connect the discharge side of the compressor 21 and the outdoor heat exchanger 23, and is also configured to connect the suction side of the compressor 21 and the gas refrigerant communication pipe 42 (see a solid-line condition in Fig. 1 ).
  • the four-way switch valve V1 is configured to connect the outdoor heat exchanger 23 and the suction side of the compressor 21, and is also configured to connect the discharge side of the compressor 21 and the gas refrigerant communication pipe 42 (see a dashed-line condition in Fig. 1 ).
  • the outdoor heat exchanger 23 is a heat exchanger allowed to function as a gas cooler or an evaporator.
  • the outdoor heat exchanger 23 is a cross-fin typed fin-and-tube heat exchanger for conducting heat exchange between the refrigerant and air functioning as a heat source.
  • One end of the outdoor heat exchanger 23 is connected to the four-way switch valve V1 while the other end thereof is connected to the outdoor expansion valve V2.
  • the outdoor expansion valve V2 is an electric expansion valve for regulating the pressure, the flow rate and the like of refrigerant flowing through the outdoor side refrigerant circuit 20.
  • the outdoor expansion valve V2 is connected between the outdoor heat exchanger 23 and the liquid side stop valve V3 for this purpose.
  • the outdoor unit 2 includes an outdoor fan 24.
  • the outdoor fan 24 functions as a ventilation fan for sucking outdoor air into the outdoor unit 2 and then discharging the air to the outside after the outdoor heat exchanger 23 conducts heat exchange between the sucked air and the refrigerant.
  • the outdoor fan 24 is a fan capable of changing the flow rate of air to be supplied to the outdoor heat exchanger 23.
  • the outdoor fan 24 is a propeller fan to be driven by a motor 25, for instance.
  • the motor 25 is composed of a DC fan motor.
  • the outdoor unit 2 is provided with a variety of sensors. Specifically, the outdoor unit 2 is provided with a discharge pressure sensor P1 for detecting discharge pressure Pd of the compressor 21. The outdoor unit 2 is also provided with an external temperature sensor T1 for detecting temperature of the outdoor air (i.e., external temperature) flowing into the outdoor unit 2. The external temperature sensor T1 is disposed at the outdoor-air suction side of the outdoor unit 2. In the present embodiment, the external temperature sensor T1 is composed of a thermistor.
  • the outdoor unit 2 includes an outdoor side control unit 27.
  • the outdoor side control unit 27 is configured to control operations of respective elements forming the outdoor unit 2.
  • the outdoor side control unit 27 includes a microcomputer, a memory, an inverter circuit and the like.
  • the microcomputer is provided for controlling the outdoor unit 2.
  • the inverter circuit is configured to control the motor 22 and the like.
  • the outdoor side control unit 27 is capable of transmitting/receiving a control signal and the like to/from an after-mentioned indoor side control unit 34 of the indoor unit 3 through a transmission line 51.
  • the outdoor side control unit 27, the indoor side control unit 34 and the transmission line 51 connecting each of the control units 27 and 34 form a control section 5 for controlling the entire operation of the air conditioning apparatus 1.
  • Fig. 2 is a control block diagram of the air conditioning apparatus 1.
  • the indoor unit 3 is installed by being embedded in or hanged down from the ceiling of the indoor space of a building and the like, or hanged down on the wall thereof, for instance.
  • the indoor unit 3 is connected to the outdoor unit 2 through the refrigerant communication pipe 4.
  • the indoor unit 3 forms a part of the refrigerant circuit 10.
  • the indoor unit 3 mainly includes an indoor side refrigerant circuit 30.
  • the indoor side refrigerant circuit 30 forms a part of the refrigerant circuit 10.
  • the indoor side refrigerant circuit 30 mainly includes an indoor heat exchanger 31 and an indoor expansion valve V5.
  • the indoor heat exchanger 31 functions as a utilization side heat exchanger.
  • the indoor expansion valve V5 functions as an expansion mechanism.
  • the indoor heat exchanger 31 is a cross-fin typed fin-and-tube heat exchanger formed by a heat transmission tube and a plurality of fins.
  • the indoor heat exchanger 31 is configured to function as an evaporator of the refrigerant for cooling the indoor air in the cooling operation.
  • the indoor heat exchanger 31 is configured to function as a gas cooler of the refrigerant for heating the indoor air in the heating operation.
  • the indoor expansion valve V5 is an electric expansion valve for regulating the pressure, the flow rate and the like of the refrigerant flowing through the indoor side refrigerant circuit 30.
  • the indoor expansion valve V5 is connected to the liquid side of the indoor heat exchanger 31.
  • the indoor expansion valve V5 is similar to the aforementioned outdoor expansion valve V2.
  • the indoor unit 3 includes an indoor fan 32.
  • the indoor fan 32 functions as a ventilation fan for sucking the indoor air into the indoor unit 3 and subsequently supplying the sucked air to the indoor space as the supply air after the indoor heat exchanger 31 conducts heat exchange between the refrigerant and the sucked air.
  • the indoor fan 32 is a fan capable of changing the flow rate of air to be supplied to the indoor heat exchanger 31.
  • the indoor fan 32 is a centrifugal fan, a multi-blade fan and the like to be driven by a motor 33.
  • the motor 33 is composed of a DC fan motor.
  • the indoor unit 3 is provided with the indoor side control unit 34 for controlling operations of each of the elements forming the indoor unit 3.
  • the indoor side control unit 34 includes a microcomputer, a memory and the like provided for controlling the indoor unit 3.
  • the indoor side control unit 34 is capable of transmitting/receiving a control signal and the like to/from a remote controller (not illustrated in the figure) for individually operating a corresponding indoor unit 3.
  • the indoor side control unit 34 is capable of transmitting/receiving a control signal and the like to/from the outdoor unit 2 through the transmission line 51, for instance.
  • the refrigerant communication pipe 4 is attached to the air conditioning apparatus 1 in the installation site.
  • Any suitable refrigerant communication pipes 4 of a variety of lengths and diameters may be used depending on an installation condition (e.g., an installation site and a combination of the outdoor unit 2 and the indoor unit 3).
  • the air conditioning apparatus 1 is configured to be operated in two operation modes.
  • One of the operation modes is an activation mode to be executed in the activation of the air conditioning apparatus 1 until the refrigeration cycle becomes stable.
  • the other of the operation modes is a normal mode to be executed after the refrigeration cycle becomes stable.
  • the normal mode is classified into two operation types.
  • One of the operation types is a cooling operation for causing the indoor unit 3 to cool the indoor space depending on cooling load of the indoor unit 3.
  • the other of the operation types is a heating operation for causing the indoor unit 3 to heat the indoor space depending on heating load of the indoor unit 3.
  • Fig. 3 is a flowchart for illustrating a series of control processing to be executed in the activation mode.
  • the air conditioning apparatus 1 When the air conditioning apparatus 1 is operated for executing either a cooling operation or a heating operation (i.e., when the compressor 21 is activated), the activation mode is accordingly activated.
  • the activation mode will be hereinafter explained with reference to Fig. 3 .
  • Step S1 it is determined if the discharge pressure Pd, detected by the discharge pressure sensor P1, is less than the critical pressure Pk of the CO 2 refrigerant.
  • the control processing proceeds to Step S2.
  • the control processing proceeds to Step S3.
  • Step S2 a throttle control is executed for reducing a throttle opening degree ⁇ 1 of the outdoor expansion valve V2 in a cooling operation, whereas a throttle control is executed for reducing a throttle opening degree ⁇ 2 of the indoor expansion valve V5 in a heating operation.
  • the throttle opening degrees ⁇ 1 and ⁇ 2 are controlled to be an opening degree ⁇ (see Fig. 5 to be described).
  • the throttle opening degrees ⁇ 1 and ⁇ 2 are set to be the opening degree ⁇ , flow sound of the gas-liquid two-phase state CO 2 refrigerant is not generated when the CO 2 refrigerant passes through the outdoor expansion valve V2 or the indoor expansion valve V5.
  • the discharge pressure Pd is less than the critical pressure Pk, the CO 2 refrigerant could be in a gas-liquid two-phase state, not in a supercritical state, at a higher possibility.
  • Step S2 When the CO 2 refrigerant is in a gas-liquid two-phase state, flow sound of the CO 2 refrigerant is easily generated in a vicinity of the outdoor expansion valve V2 or.the indoor expansion valve V5. Therefore, high pressure of the CO 2 refrigerant is promoted to be equal to or greater than the critical pressure Pk in the refrigeration cycle in a shorter period of time by setting the throttle opening degree ⁇ 1 of the outdoor expansion valve V2 or the throttle opening degree ⁇ 2 of the indoor expansion valve V5 to be the opening degree ⁇ .
  • Step S3 the activation mode proceeds to the normal mode.
  • Fig. 4 is a flowchart for illustrating a series of control processing to be executed in the normal mode.
  • the normal mode is started after the aforementioned activation mode is completed.
  • Step S11 it is determined if the discharge pressure Pd, detected by the discharge pressure sensor P1, is less than the critical pressure Pk of the CO 2 refrigerant.
  • the control processing proceeds to Step S12.
  • Step S15 when the discharge pressure Pd is equal to or greater than the critical pressure Pk, the control processing proceeds to Step S15.
  • Step S12 throttle control is executed for reducing the throttle opening degree ⁇ 1 of the outdoor expansion valve V2 in a cooling operation, whereas throttle control is executed for reducing the throttle opening degree ⁇ 2 of the indoor expansion valve V5 in a heating operation.
  • Step S13 it is determined if the outdoor fan 24 is being driven in the cooling operation, whereas it is determined if the indoor fan 32 is being driven in the heating operation.
  • the control processing proceeds to Step S14.
  • the control processing returns to Step S11.
  • Step S14 the outdoor fan 24 or the indoor fan 32 is stopped.
  • Step S14 the control processing returns to Step S11.
  • Step S15 to be executed when the external temperature exceeds 20 degrees Celsius in Step S11, it is determined if throttle control is being executed with respect to the outdoor expansion valve V2 or the indoor expansion valve V5.
  • Step S16 When throttle control is being executed with respect to the outdoor expansion valve V2 or the indoor expansion valve V5, the control processing proceeds to Step S16.
  • Step S16 normal control is executed with respect to the outdoor expansion valve V2 or the indoor expansion valve V5.
  • Step S17 it is determined if the outdoor fan 24 or the indoor fan 32 is being stopped. When the outdoor fan 24 or the indoor fan 32 is being stopped, the control processing proceeds to Step S18.
  • Step S18 the outdoor fan 24 or the indoor fan 32 is activated, and normal control is executed with respect to the outdoor fan 24 or the indoor fan 32.
  • Step S18 the control processing returns to Step S11.
  • the control section 5 is configured to switch controls of the outdoor expansion valve V2 or the indoor expansion valve V5 between the throttle control and the normal control.
  • Fig. 5 is a time-flow chart for illustrating timing of switching the throttle control and the normal control back and forth.
  • the horizontal axis represents time t while the vertical axis represents the discharge pressure Pd and the throttle opening degree ⁇ 1 of the outdoor expansion valve V2 or the throttle opening degree ⁇ 2 of the indoor expansion valve V5.
  • throttle control is started at time t1 and the throttle opening degree ⁇ 1 of the outdoor expansion valve V2 or the throttle opening degree ⁇ 2 of the indoor expansion valve V5 is set to be the opening degree ⁇ . Subsequently, when time t2 is elapsed and the discharge pressure Pd is changed from the initial discharge pressure P0 to critical pressure Pk, the throttle control is switched to the normal control. Accordingly, the throttle opening degree ⁇ 1 of the outdoor expansion valve V2 or the throttle opening degree ⁇ 2 of the indoor expansion valve V5 is set to be opening degree ⁇ .
  • the normal control is again switched to the throttle control.
  • the throttle opening degree ⁇ 1 of the outdoor expansion valve V2 or the throttle opening degree ⁇ 2 of the indoor expansion valve V5 is set to be the opening degree ⁇ .
  • a cooling operation will be hereinafter explained with reference to Fig. 1 .
  • the four-way switch valve V1 in the outdoor side refrigerant circuit 20 of the outdoor unit 2 is switched to the solid-line condition in Fig. 1 .
  • the outdoor heat exchanger 23 is configured to function as a gas cooler whereas the indoor heat exchanger 31 is configured to function as an evaporator.
  • the gas refrigerant of low pressure Pl is sucked into the compressor 21 and is therein compressed.
  • the gas refrigerant changes into the gas refrigerant of high pressure Ph.
  • the gas refrigerant, compressed to the high pressure Ph flows into the outdoor heat exchanger 23.
  • the outdoor heat exchanger 23 functions as a gas cooler and cools the refrigerant by releasing heat of the refrigerant into the outdoor air to be supplied by the outdoor fan 24.
  • the outdoor expansion valve V2 decompresses the refrigerant from the high pressure Ph to the low pressure Pl.
  • the refrigerant decompressed to the low pressure Pl, changes into gas-liquid two-phase refrigerant.
  • the gas-liquid two-phase refrigerant is transported to the indoor unit 3 via the liquid side stop valve V3 and the liquid refrigerant communication pipe 41.
  • the indoor expansion valve V5 controls the flow rate of the gas-liquid two-phase refrigerant of the low pressure Pl transported to the indoor unit 3.
  • the indoor heat exchanger 31 then conducts heat change between the refrigerant and the indoor air.
  • the refrigerant accordingly evaporates and changes into gas refrigerant of the low pressure Pl.
  • the gas refrigerant of the low pressure Pl is transported to the outdoor unit 2 via the gas refrigerant communication pipe 42.
  • the gas refrigerant is again sucked into the compressor 21 via the gas side stop valve V4.
  • the four-way switch valve V1 in the outdoor side refrigerant circuit 20 of the outdoor unit 2 is switched to the dashed-line condition in Fig. 1 . Accordingly, the outdoor heat exchanger 23 is configured to function as an evaporator whereas the indoor heat exchanger 31 is configured to function as a gas cooler.
  • the indoor heat exchanger 31 conducts heat exchange between the refrigerant and the indoor air.
  • the refrigerant is accordingly cooled, and changes into liquid refrigerant of the high pressure Ph.
  • the refrigerant passes through the indoor expansion valve V5, it is decompressed to the low pressure Pl in accordance with the throttle opening degree ⁇ 2 of the indoor expansion valve V5.
  • the refrigerant accordingly changes into gas-liquid two-phase refrigerant.
  • the gas-liquid two-phase refrigerant is transported to the outdoor unit 2 via the liquid refrigerant communication pipe 41.
  • the refrigerant flows into the outdoor heat exchanger 23 via the liquid side stop valve V3 and the outdoor expansion valve V2.
  • the outdoor heat exchanger 23 conducts heat exchange between the refrigerant and the external air.
  • the refrigerant accordingly evaporates and changes into gas refrigerant of the low pressure Pl.
  • the outdoor expansion valve V2 is fully opened.
  • the gas refrigerant of the low pressure Pl is again sucked into the compressor 21 via the four-way switch valve V1.
  • FIG. 6 illustrates a refrigeration cycle under the supercritical condition with a P-H chart (Mollier chart).
  • points A, B, C and D indicate states of refrigerant at the corresponding points in Fig. 1 of the cooling operation.
  • points (A), (F), (E) and (D) indicate states of refrigerant at the corresponding points in Fig. 1 of the heating operation.
  • the compressor 21 compresses the refrigerant and the compressed refrigerant changes into high-temperature refrigerant of the high pressure Ph (A ⁇ B).
  • the gas refrigerant, CO 2 enters a supercritical state.
  • supercritical state herein referred means a state of material at temperature and pressure equal to or greater than the critical point K. In the supercritical state, material has both gas diffusivity and liquid solubility.
  • the supercritical state is a state of refrigerant shown in the area positioned rightward of a critical temperature isothermal curve Tk at the critical pressure Pk or greater.
  • gas phase herein referred is a state of refrigerant shown in the area positioned rightward of a saturated vapor curve Sv at the critical pressure Pk or less.
  • liquid phase is a state of refrigerant shown in the area positioned leftward of a saturated liquid curve Sl and leftward of the critical temperature isothermal curve Tk.
  • the refrigerant is in a supercritical state, and therefore operates with sensible heat changes (temperature changes) in the interior of the outdoor heat exchanger 23.
  • the refrigerant, heat of which has been released by the outdoor heat exchanger 23 is expanded by the outdoor expansion valve V2 being opened.
  • the refrigerant is decompressed from the high pressure Ph to the low pressure Pl (C ⁇ D).
  • the refrigerant, decompressed by the outdoor expansion valve V2 absorbs heat and evaporates in the indoor heat exchanger 31 functioning as an evaporator, and returns to the compressor 21 (D ⁇ A).
  • the refrigeration apparatus of the present invention achieves a working effect for inhibiting generation of noise, and is useful as a refrigeration apparatus and the like using refrigerant operating in the supercritical zone.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Air Conditioning Control Device (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)

Claims (8)

  1. Kühlapparat (1), der überkritisches Kältemittel einsetzt, der in einer Zone betrieben wird, in welcher der Hochdruck des überkritischen Kältemittels gleichwertig oder höher als der kritische Druck ist, wobei der Kühlapparat (1) Folgendes umfasst:
    einen Kompressor (21) zum Verdichten des überkritischen Kältemittels;
    einen Gaskühler (23, 31) zum Kühlen des überkritischen Kältemittels, das durch den Kompressor (21) verdichtet wird;
    einen Expansionsmechanismus (V2, V5) zum Druckentlasten des überkritischen Kältemittels;
    einen Verdampfer (31, 23) zum Verdampfen des überkritischen Kältemittels, das durch den Expansionsmechanismus (V2, V5) druckentlastet wird;
    Ablassdruckerfassungsmittel (P1, T2, T3), die in der Lage sind, den Ablassdruck des Kompressors (21) zu erfassen; und
    einen Steuerungsabschnitt (5), der konfiguriert ist, einen Öffnungsgrad des Expansionsmechanismus (V2, V5) zum Steuern des Ablassdrucks derart zu regulieren, dass dieser gleichwertig oder größer als der überkritische Druck ist, wenn der Kühlapparat (1) aktiviert und der Ablassdruck geringer als der kritische Druck ist,
    dadurch gekennzeichnet, dass der Steuerungsabschnitt (5) konfiguriert ist, einen Einlassdruck des Expansionsmechanismus (V2, V5) basierend auf dem Ablassdruck und einer Betriebskapazität des Kompressors (21) zu berechnen, und konfiguriert ist, den Öffnungsgrad des Expansionsmechanismus (V2, V5) zum Steuern des Ablassdrucks derart zu regulieren, dass dieser gleichwertig oder größer als der kritische Druck ist, wenn der Einlassdruck geringer als der kritische Druck ist.
  2. Kühlapparat (1) nach Anspruch 1, wobei der Steuerungsabschnitt (5) konfiguriert ist, eine erste Steuerung zum Einstellen des Öffnungsgrads des Expansionsmechanismus (V2, V5) derart auszuführen, dass dieser ein vollständig geschlossener oder ein leicht geöffneter Grad ist, wenn der Auslassdruck geringer als der kritische Druck ist.
  3. Kühlapparat (1) nach Anspruch 2, wobei der Steuerungsabschnitt (5) konfiguriert ist, eine zweite Steuerung zum Einstellen des Öffnungsgrads des Expansionsmechanismus (V2, V5) derart auszuführen, dass dieser groß ist, wenn der Ablassdruck gleichwertig oder größer als der kritische Druck ist, nachdem die erste Steuerung ausgeführt worden ist.
  4. Kühlapparat (1) nach einem der Ansprüche 1 bis 3, wobei das Ablassdruckerfassungsmittel ein Drucksensor (P1) ist, der an der Ablassseite des Kompressors (21) bereitgestellt ist.
  5. Kühlapparat (1, 1a) nach einem der Ansprüche 1 bis 4, wobei der Steuerungsabschnitt (5) konfiguriert ist, den Öffnungsgrad des Expansionsmechanismus (V2, V5) zum Steuern des Ablassdrucks derart zu regeln, dass dieser gleichwertig oder größer als der kritische Druck ist, wenn ein normaler Betrieb ausgeführt wird.
  6. Kühlapparat (1, 1a) nach einem der Ansprüche 1 bis 4, wobei der Steuerungsabschnitt (5) konfiguriert ist, den Öffnungsgrad des Expansionsmechanismus (V2, V5) zum Steuern des Ablassdrucks derart zu regeln, dass dieser gleichwertig oder größer als der kritische Druck ist, auch wenn ein normaler Betrieb bei einer niedrigen Außentemperatur ausgeführt wird.
  7. Kühlapparat (1, 1a) nach Anspruch 6, wobei die niedrige Außentemperatur eine Außentemperatur ist, die gleichwertig oder geringer als 20 Grad Celsius ist.
  8. Kühlapparat (1, 1a) nach einem der Ansprüche 1 bis 7, wobei das überkritische Kältemittel ein Kohlendioxid-(CO2)-Kältemittel ist.
EP07860041.8A 2006-12-28 2007-12-25 Kühlvorrichtung Active EP2103888B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12187178.4A EP2543939A3 (de) 2006-12-28 2007-12-25 Kälteanlage

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006354392A JP4386071B2 (ja) 2006-12-28 2006-12-28 冷凍装置
PCT/JP2007/074812 WO2008081771A1 (ja) 2006-12-28 2007-12-25 冷凍装置

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP12187178.4A Division-Into EP2543939A3 (de) 2006-12-28 2007-12-25 Kälteanlage
EP12187178.4A Division EP2543939A3 (de) 2006-12-28 2007-12-25 Kälteanlage

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EP2103888A1 EP2103888A1 (de) 2009-09-23
EP2103888A4 EP2103888A4 (de) 2012-06-06
EP2103888B1 true EP2103888B1 (de) 2018-07-11

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ES (1) ES2680501T3 (de)
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JP5423083B2 (ja) 2009-03-19 2014-02-19 ダイキン工業株式会社 空気調和装置
KR101283284B1 (ko) 2009-03-19 2013-07-11 다이킨 고교 가부시키가이샤 공기 조화 장치
US9046275B2 (en) 2009-03-19 2015-06-02 Daikin Industries, Ltd. Air conditioner with electromagnetic induction heating unit
JP2010223457A (ja) * 2009-03-19 2010-10-07 Daikin Ind Ltd 空気調和装置
EP2410265A4 (de) 2009-03-19 2017-05-31 Daikin Industries, Ltd. Klimaanlage
KR20110092147A (ko) * 2010-02-08 2011-08-17 삼성전자주식회사 공기조화기 및 그 제어방법
CN104896750A (zh) * 2015-04-10 2015-09-09 广东美的暖通设备有限公司 一种跨临界co2热泵热水机压力的控制方法及系统
JP6998043B2 (ja) * 2016-12-21 2022-01-18 アイリスオーヤマ株式会社 冷蔵庫
WO2018117178A1 (ja) * 2016-12-21 2018-06-28 アイリスオーヤマ株式会社 冷蔵庫
JP6902390B2 (ja) * 2017-04-27 2021-07-14 日立ジョンソンコントロールズ空調株式会社 冷凍サイクル装置
JP6716037B2 (ja) * 2017-07-04 2020-07-01 三菱電機株式会社 空気調和システム

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Also Published As

Publication number Publication date
JP4386071B2 (ja) 2009-12-16
EP2543939A2 (de) 2013-01-09
JP2008164226A (ja) 2008-07-17
TR201810756T4 (tr) 2018-08-27
EP2103888A4 (de) 2012-06-06
EP2543939A3 (de) 2014-04-23
EP2103888A1 (de) 2009-09-23
WO2008081771A1 (ja) 2008-07-10
ES2680501T3 (es) 2018-09-07

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