EP2066771A2 - Schmiermittelzusammensetzung - Google Patents

Schmiermittelzusammensetzung

Info

Publication number
EP2066771A2
EP2066771A2 EP07841460A EP07841460A EP2066771A2 EP 2066771 A2 EP2066771 A2 EP 2066771A2 EP 07841460 A EP07841460 A EP 07841460A EP 07841460 A EP07841460 A EP 07841460A EP 2066771 A2 EP2066771 A2 EP 2066771A2
Authority
EP
European Patent Office
Prior art keywords
oil
lubricating
dispersant
lubricating composition
corrosion inhibitor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07841460A
Other languages
English (en)
French (fr)
Inventor
Betsy J. Butke
Hirohito Hasegawa
Tadashi Yoshimura
Carlos Cerda De Groote
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of EP2066771A2 publication Critical patent/EP2066771A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/06Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/08Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/043Ammonium or amine salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14Metal deactivation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/45Ash-less or low ash content
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/12Gas-turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/12Gas-turbines
    • C10N2040/13Aircraft turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/135Steam engines or turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/14Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron

Definitions

  • Ash-containing and ashless lubricating compositions are utilised in various mechanical devices (for example stationary or mobile machinery requiring a working fluid, a hydraulic fluid, a circulating oil or a turbine oil).
  • the lubricating compositions often operate under high temperatures and/or high pressure regimes in the mechanical device.
  • the high temperatures and/or high pressure regimes are believed to decompose additives in the lubricating composition that are less thermally and/or oxidatively stable.
  • additives that tend to decompose are often ash-containing additives that contain a metal.
  • divalent metals such as zinc, calcium or magnesium, are released into the lubricating composition.
  • International Application WO 00/11 122 discloses lubricating compositions containing (I) 100 pbw of a base oil, (II) an antiwear agent comprising (i) from 0.05 to 10 pbw of a phosphorothionate and from 0.01 to 1.0 pbw of an amine salt of phosphorus compound and/or (ii) from 0.05 to 10 pbw of a dithiophosphate, and (III) a rust preventing agent comprising from 0.01 to 1.0 pbw of an amide obtained by reacting a polyalkylene polyamine and a carboxylic acid having from 4 to 30 carbon atoms.
  • the lubricating composition is suitable for hydraulic systems.
  • US Patent Application 2002/0010103 Al discloses industrial oils such as hydraulic oils containing (a) at least one a compound selected from the group consisting of a phosphoric acid ester, a thiophosphoric acid ester, and amine salts thereof; (b) at least one of a phosphorus acid ester and/or an amine salt thereof; and (c) at least one compound selected from the group consisting of an alkenyl succinimide, an alkenyl succinic acid ester, benzylamine, and derivatives thereof.
  • the present invention provides a lubricating composition and method of lubricating a mechanical device capable of reducing or minimising at least one of filter plugging, limited oxidative stability, limited thermal stability, and produce unacceptable levels of sludge.
  • the invention provides an ashless lubricating composition comprising:
  • the invention provides the ashless lubricating compositions disclosed above in the form of a concentrate.
  • the succinimide dispersant contains an average of at least about 8, or about 30, or about 35 up to about 350, or to about 200, or to about 100 carbon atoms.
  • the long chain alkenyl group is derived from a polyalkene characterised by an Mn (number average molecular weight) of at least 500.
  • the polyalkene is characterised by an Mn of about 500, or about 700, (or about 800, or even about 900) to about 5000, (or to about 2500, or to about 2000, or to about 1500, or to about 1200).
  • the long chain alkenyl group includes those derived from polyolefins.
  • the corrosion inhibitor may also be described as a metal deactivator or a yellow-metal passivator.
  • the corrosion inhibitor includes 2,5-bis(alkyl- dithio)-l,3,4-thiadiazoles.
  • the alkyl groups of 2,5- bis(alkyl-dithio)-l,3,4-thiadiazoles contain 1 to about 30, or about 2 to about 25, or 4 to about 20, or about 6 to about 16 carbon atoms.
  • the corrosion inhibitor is present in ranges including about 0.0001 wt % to about 5 wt %, or about 0.0001 wt % to about 0.5 wt %, or about 0.0001 wt % to about 0.1 wt %, or about 0.0005 wt % to about 0.06 wt % of the lubricating composition.
  • Natural oils useful in making the inventive lubricants include animal oils, vegetable oils (e.g., castor oil, lard oil), mineral lubricating oils such as liquid petroleum oils and solvent-treated or acid-treated mineral lubricating oils of the paraffinic, naphthenic or mixed paraffinic-naphthenic types and oils derived from coal or shale or mixtures thereof.
  • animal oils e.g., castor oil, lard oil
  • mineral lubricating oils such as liquid petroleum oils and solvent-treated or acid-treated mineral lubricating oils of the paraffinic, naphthenic or mixed paraffinic-naphthenic types and oils derived from coal or shale or mixtures thereof.
  • each R'" independently is hydrogen or a hydrocarbyl group, with the proviso that at least one of the R"' groups is hydrocarbyl.
  • Each hydrocarbyl group of R' " in different embodiments contains at least about 2, or at least about 4 carbon atoms. Typically, the combined total sum of carbon atoms present on both R' " groups is less than about 45, or is less than about 35, or is less than about 25. Examples of suitable ranges for the number of carbon atoms present on R groups include about 2 to about 40, about 3 to about 24, or about 4 to about 20.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
EP07841460A 2006-09-01 2007-08-28 Schmiermittelzusammensetzung Withdrawn EP2066771A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US82429906P 2006-09-01 2006-09-01
PCT/US2007/076981 WO2008027883A2 (en) 2006-09-01 2007-08-28 Lubricating composition

Publications (1)

Publication Number Publication Date
EP2066771A2 true EP2066771A2 (de) 2009-06-10

Family

ID=38988936

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07841460A Withdrawn EP2066771A2 (de) 2006-09-01 2007-08-28 Schmiermittelzusammensetzung

Country Status (5)

Country Link
US (2) US20100160191A1 (de)
EP (1) EP2066771A2 (de)
JP (3) JP2010502788A (de)
CA (1) CA2662311C (de)
WO (1) WO2008027883A2 (de)

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* Cited by examiner, † Cited by third party
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US20090253597A1 (en) * 2008-03-31 2009-10-08 Exxonmobil Research And Engineering Company Lubricant composition with improved varnish deposit resistance
CA2801249A1 (en) 2010-06-02 2011-12-08 The Lubrizol Corporation Lubricating composition containing a carboxylic functionalised polymer
WO2012096860A1 (en) * 2011-01-11 2012-07-19 The Lubrizol Corporation Composition with improved cleanliness for lubrication of steam and gas turbine systems
US8410032B1 (en) * 2012-07-09 2013-04-02 Afton Chemical Corporation Multi-vehicle automatic transmission fluid
US20140187453A1 (en) * 2012-12-28 2014-07-03 Chevron Oronite LLC Ultra-low saps lubricants for internal combustion engines
US20140187455A1 (en) * 2012-12-28 2014-07-03 Chevron Oronite LLC Ultra-low saps lubricants for internal combustion engines
CN105985460B (zh) * 2015-02-27 2018-10-16 中国石油天然气股份有限公司 高分子量无灰分散剂的制备方法和应用
JP6041014B1 (ja) * 2015-05-26 2016-12-07 ダイキン工業株式会社 冷凍装置の蒸発器の製造方法
WO2018048781A1 (en) * 2016-09-12 2018-03-15 The Lubrizol Corporation Total base number boosters for marine diesel engine lubricating compositions
US10647939B2 (en) * 2016-11-18 2020-05-12 International Petroleum Products & Additives Company, Inc. Thiadiazole components, compositions, and methods
JP2019073628A (ja) 2017-10-16 2019-05-16 出光興産株式会社 油圧作動油組成物
FR3099176B1 (fr) * 2019-07-26 2022-02-18 Total Marketing Services Composition lubrifiante pour turbines à gaz

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Also Published As

Publication number Publication date
WO2008027883A3 (en) 2008-05-02
US20150045263A1 (en) 2015-02-12
JP2014132097A (ja) 2014-07-17
JP2010502788A (ja) 2010-01-28
JP2016172877A (ja) 2016-09-29
CA2662311A1 (en) 2008-03-06
CA2662311C (en) 2016-05-24
WO2008027883A2 (en) 2008-03-06
US20100160191A1 (en) 2010-06-24

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