EP2010690A1 - Hot dip coating process for a steel plate product made of high strengthheavy-duty steel - Google Patents
Hot dip coating process for a steel plate product made of high strengthheavy-duty steelInfo
- Publication number
- EP2010690A1 EP2010690A1 EP06754869A EP06754869A EP2010690A1 EP 2010690 A1 EP2010690 A1 EP 2010690A1 EP 06754869 A EP06754869 A EP 06754869A EP 06754869 A EP06754869 A EP 06754869A EP 2010690 A1 EP2010690 A1 EP 2010690A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- flat steel
- steel product
- oxide layer
- steel plate
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 68
- 239000010959 steel Substances 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000003618 dip coating Methods 0.000 title description 11
- 239000012298 atmosphere Substances 0.000 claims abstract description 40
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000010438 heat treatment Methods 0.000 claims abstract description 32
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 21
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 16
- 239000011701 zinc Substances 0.000 claims abstract description 16
- 238000005275 alloying Methods 0.000 claims abstract description 15
- 229910052742 iron Inorganic materials 0.000 claims abstract description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000001590 oxidative effect Effects 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 239000000470 constituent Substances 0.000 claims description 14
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 238000005246 galvanizing Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 claims 1
- 230000002045 lasting effect Effects 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 238000003723 Smelting Methods 0.000 abstract 2
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 238000000137 annealing Methods 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000011651 chromium Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000794 TRIP steel Inorganic materials 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
- C23C2/004—Snouts
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0222—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
Definitions
- the invention relates to a method for coating a flat steel product made of high-strength, different alloying constituents, in particular Mn, Al, Si and / or Cr, containing steel, such as steel strip or sheet, with a metallic coating, in which the flat steel product is subjected to a heat treatment, to then be provided in the heated state in a total of at least 85% zinc and / or aluminum melt bath by hot dip coating with the metallic coating.
- hot-rolled or cold-rolled sheets made of steel are used, which are surface-finished for reasons of corrosion protection.
- the demands placed on such sheets are many. They should on the one hand be well deformable and on the other hand have a high strength.
- the high strength is achieved by adding certain alloying constituents, such as Mn, Si, Al and Cr, to the iron.
- RTF Radiant Tube Furnace
- DE 689 12 243 T2 discloses a process for the continuous hot-dip coating of a steel strip with aluminum, in which the strip is heated in a continuous furnace. In a first zone, surface contaminants are removed. But the furnace atmosphere has a very high temperature. However, as the belt passes through this zone at high speed, it is only heated to about half the temperature of the atmosphere. In the subsequent second zone, which is under protective gas, the strip is heated to the temperature of the coating material aluminum.
- DE 695 07 977 T2 discloses a two-stage hot dip coating method of a chromium-containing steel alloy strip. According to this method, the strip is annealed in a first stage to be at the Band surface to obtain an iron enrichment. Subsequently, the tape is heated in a non-oxidizing atmosphere to the temperature of the coating metal.
- JP 02285057 A it is also known to galvanize a steel strip in a multi-stage process.
- the previously cleaned band is treated in a non-oxidizing atmosphere at a temperature of about 820 0 C.
- the tape is treated at about 400 ° C to 700 ° C in a low oxidizing atmosphere before being reduced on its surface in a reducing atmosphere.
- the cooled to about 420 0 C to 500 0 C strip is galvanized in the usual way.
- the invention had the object of specifying a method for hot dip coating of a high-strength steel produced flat steel product with zinc and / or aluminum, with which a steel strip can be produced with an optimally finished surface in a RTF plant.
- the strip is heated in a reducing atmosphere with an H 2 content of at least 2% to 8% to a temperature of> 750 0 C to 850 0 C.
- the predominantly pure iron surface is characterized by a 1 to 10 sec continuous heat treatment of the strip at a temperature of> 750 0 C to 850 0 C in a continuous furnace integrated reaction chamber with an oxidizing atmosphere with a C> 2 content of 0 , 01% to 1% converted into an iron oxide layer.
- the temperature control according to the invention in step a) prevents that during the heating essential alloying constituents diffuse to the surface of the flat steel product.
- the diffusion of alloy constituents to the surface is particularly effectively suppressed so that an effective iron oxide layer can be formed in the following step , This prevents further alloying constituents from diffusing to the surface during the subsequently increased annealing temperature.
- a pure iron layer can be formed which is suitable for a full-surface and firmly adhering coating of zinc and / or aluminum is very suitable.
- the work result can be optimized by completely reducing the iron oxide layer produced in the oxidizing atmosphere to pure iron. In this state, the coating also has optimum properties with regard to its deformability and strength.
- the thickness of the forming oxide layer is measured, and depending on this thickness and on the flow rate of the
- a diffusion of alloy constituents to the surface of the flat steel product can also be counteracted by the heating in step a) of the process according to the invention taking place as rapidly as possible.
- Good work results are in particular then if the duration of the heating upstream of the oxidation of the flat steel product to more than 750 0 C to 850 0 C to max. 300 s, in particular max. 250 0 C, is limited.
- the heating rate in the case of the heating of the flat steel product preceding the oxidation according to the invention is at least 2.4 ° C./s, in particular in the range from 2.4 to 4.0 ° C./s.
- the heat treatment followed by the oxidation followed by cooling of the flat steel product should take more than 30 seconds, in particular more than 50 seconds, to ensure a sufficiently sufficient reduction of the previously formed iron oxide layer to pure iron.
- the high-strength steel may contain at least one of the following constituents: Mn> 0.5%, Al> 0.2%, Si> 0.1%, Cr> 0.3%. Other ingredients such. Mo, Ni, V, Ti, Nb and P can be added.
- the heat treatment of the flat steel product in the reducing atmosphere both during warm-up and later annealing, lasts many times longer than the heat treatment in the oxidizing atmosphere.
- the volume of the oxidizing atmosphere is very small compared to the remaining volume of the reducing atmosphere.
- the inventive heat treatment of the flat steel product in the reducing atmosphere can be carried out in a continuous furnace, which is equipped with a chamber containing the oxidizing atmosphere, wherein the volume of the chamber can be many times smaller than the remaining volume of the continuous furnace.
- the inventive method is particularly well suited for hot dip galvanizing.
- the molten bath may also consist of zinc-aluminum or aluminum with silicon additives. Regardless of which melt composition is selected, the total present in the melt zinc and / or aluminum content should be at least 85% in total.
- Such composite melts are z. For example:
- the single figure shows schematically a galvanizing plant with a continuous furnace 5 and a melt bath 7.
- the temperature profile over the cycle time is plotted in the figure for the continuous furnace.
- the galvanizing plant is intended for continuous coating of a flat steel product in the form of hot rolled or cold rolled steel strip 1, which is made of higher strength steel containing at least one alloying element of the Mn, Al, Si and Cr group and optionally further alloying elements containing additional alloying elements.
- the steel may in particular be a TRIP steel.
- the steel strip 1 is withdrawn from a coil 2 and passed through a pickling 3 and / or another system 4 for surface cleaning.
- the cleaned belt 1 then passes through a continuous furnace 5 in a continuous operation and is passed from there via a sealed relative to the surrounding atmosphere trunk 6 in a hot dip bath 7, the hot dip 7 is presently formed by a molten zinc.
- the emerging from the hot dip 7, provided with the zinc coating steel strip 1 passes through a Cooling section 8 or a device for heat treatment to a winding station 9, in which it is wound into a coil.
- the steel strip 1 is meander-shaped passed through the continuous furnace 5 in order to achieve sufficiently long treatment times with practical length of the continuous furnace 5 can.
- the middle zone 5b forms a reaction chamber and is atmospherically closed with respect to the first and last zones 5a, 5c.
- Their length is only about 1/100 of the total length of the continuous furnace 5. For better illustration, the drawing is not to scale extent.
- a typical composition of this atmosphere consists of 2% to 8% H 2 , typically 5% H 2 , and balance N 2 .
- the strip is heated to more than 750 to 850 0 C, typically 800 0 C.
- the heating takes place at a heating rate of at least 3.5 ° C / s. At this temperature and heating rate diffuse in the steel strip. 1 containing alloying ingredients in only small amounts at the surface.
- the steel strip 1 is kept substantially only at the temperature reached in the first zone 5a.
- the atmosphere of the zone 5b is oxygen-containing, so that oxidation of the surface of the steel strip 1 occurs.
- the O 2 content of the atmosphere prevailing in zone 5b is between 0.01% to 1%, typically 0.5%.
- the oxygen content of the atmosphere prevailing in the zone 5b can be adjusted, for example, as a function of the treatment time and the thickness of the oxide layer to be produced on the steel bath 1. If the treatment time is short, for example, a high O 2 - content is set, while for long treatment time, for example, a lower oxygen content can be selected to produce an oxide layer of the same thickness.
- the desired iron oxide layer forms on the surface of the strip.
- the thickness of this iron oxide layer can be detected optically, the result of the measurement being used to set the respective oxygen content of the zone 5b.
- the chamber volume is correspondingly small. Therefore, the reaction time for a change in the composition of the atmosphere is small, so that on a Changing the belt speed or to a different thickness of the target thickness of the oxide layer by a corresponding adjustment of the oxygen content of the prevailing atmosphere in the zone 5b can be reacted quickly.
- the small volume of Zone 5b allows for short control times.
- the steel strip 1 is heated to an annealing temperature of about 900 0 C.
- the annealing carried out in zone 5c takes place in a reducing nitrogen atmosphere which has an H 2 content of 5%.
- the iron oxide layer prevents alloying constituents from diffusing to the strip surface.
- the iron oxide layer is converted into a pure iron layer.
- the steel strip 1 is further cooled on its further way in the direction of the hot dip bath 7, so that it has a temperature on leaving the continuous furnace 5, which is up to 10% higher than the temperature of the hot dip bath 7 of about 480 0 C.
- Da das Band 1 after leaving the continuous furnace 5 is made of pure iron on its surface, it provides an optimal basis for a strong bond of the zinc coating applied in the hot dip 7.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Coating With Molten Metal (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL06754869T PL2010690T3 (en) | 2006-04-26 | 2006-04-26 | Hot dip coating process for a steel plate product made of high strengthheavy-duty steel |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2006/061858 WO2007124781A1 (en) | 2006-04-26 | 2006-04-26 | Hot dip coating process for a steel plate product made of high strengthheavy-duty steel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2010690A1 true EP2010690A1 (en) | 2009-01-07 |
EP2010690B1 EP2010690B1 (en) | 2010-02-24 |
Family
ID=37492622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06754869A Active EP2010690B1 (en) | 2006-04-26 | 2006-04-26 | Hot dip coating process for a steel plate product made of high strengthheavy-duty steel |
Country Status (12)
Country | Link |
---|---|
US (1) | US8636854B2 (en) |
EP (1) | EP2010690B1 (en) |
JP (1) | JP5189587B2 (en) |
KR (1) | KR101275839B1 (en) |
CN (1) | CN101501235B (en) |
AT (1) | ATE458838T1 (en) |
BR (1) | BRPI0621610A2 (en) |
CA (1) | CA2647687C (en) |
DE (1) | DE502006006289D1 (en) |
ES (1) | ES2339804T3 (en) |
PL (1) | PL2010690T3 (en) |
WO (1) | WO2007124781A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013007578A2 (en) | 2011-07-11 | 2013-01-17 | Thyssenkrupp Steel Europe Ag | Method for producing a flat steel product which is provided with a metallic protective layer by means of hot dip coating |
US9279175B2 (en) | 2010-08-31 | 2016-03-08 | Thyssenkrupp Steel Europe Ag | Method for hot dip coating a flat steel product |
US20190275766A1 (en) * | 2016-05-30 | 2019-09-12 | Jfe Steel Corporation | Ferritic stainless steel sheet |
EP3686534A1 (en) | 2019-01-23 | 2020-07-29 | Drever International | Method and furnace for thermal treatment of a high-resistance steel strip including a temperature homogenisation chamber |
WO2020201136A1 (en) * | 2019-04-01 | 2020-10-08 | Salzgitter Flachstahl Gmbh | Method for producing a steel strip with improved bonding of metallic hot-dip coatings |
WO2020201133A1 (en) * | 2019-04-01 | 2020-10-08 | Salzgitter Flachstahl Gmbh | Method for producing a steel strip with improved bonding of metallic hot-dip coatings |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5555992B2 (en) * | 2008-09-05 | 2014-07-23 | Jfeスチール株式会社 | Manufacturing method of high-strength hot-dip galvanized steel sheet with excellent surface appearance and plating adhesion |
JP5556033B2 (en) * | 2009-03-19 | 2014-07-23 | Jfeスチール株式会社 | Method for producing high-strength hot-dip galvanized steel sheet |
EP2415896B1 (en) | 2009-03-31 | 2016-11-16 | JFE Steel Corporation | Method for producing high-strength hot-dip galvanized steel plate |
EP2374910A1 (en) | 2010-04-01 | 2011-10-12 | ThyssenKrupp Steel Europe AG | Steel, flat, steel product, steel component and method for producing a steel component |
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WO2015001367A1 (en) * | 2013-07-04 | 2015-01-08 | Arcelormittal Investigación Y Desarrollo Sl | Cold rolled steel sheet, method of manufacturing and vehicle |
JP6792561B2 (en) | 2015-04-02 | 2020-11-25 | コケリル メンテナンス アンド インジェニエリー ソシエテ アノニム | Methods and equipment for reaction control |
EP3170913A1 (en) | 2015-11-20 | 2017-05-24 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
EP3286343B1 (en) | 2015-04-22 | 2019-06-05 | Cockerill Maintenance & Ingéniérie S.A. | Method for reaction control |
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JP6397806B2 (en) * | 2015-09-11 | 2018-09-26 | 東芝メモリ株式会社 | Semiconductor device manufacturing method and semiconductor device |
DE102017218704A1 (en) | 2017-10-19 | 2019-04-25 | Thyssenkrupp Ag | Process for producing a steel component provided with a metallic, corrosion-protective coating |
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Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3420656A (en) * | 1966-09-02 | 1969-01-07 | Lummus Co | Process for forming hard oxide pellets and product thereof |
GB1231478A (en) | 1968-11-05 | 1971-05-12 | ||
US3925579A (en) | 1974-05-24 | 1975-12-09 | Armco Steel Corp | Method of coating low alloy steels |
US5023113A (en) | 1988-08-29 | 1991-06-11 | Armco Steel Company, L.P. | Hot dip aluminum coated chromium alloy steel |
JPH02285057A (en) | 1989-04-27 | 1990-11-22 | Sumitomo Metal Ind Ltd | Method for continuously annealing steel sheet to be galvanized |
JPH0448062A (en) * | 1990-06-18 | 1992-02-18 | Nippon Steel Corp | Production of galvannealed steel sheet |
JPH04254531A (en) * | 1991-02-01 | 1992-09-09 | Nippon Steel Corp | Method for annealing high si-containing high tensile strength steel before galvanizing |
JPH05247614A (en) * | 1992-03-06 | 1993-09-24 | Sumitomo Metal Ind Ltd | Galvanizing method for silicon-containing steel sheet |
JPH06212384A (en) * | 1993-01-18 | 1994-08-02 | Sumitomo Metal Ind Ltd | Hot dip galvanizing method for silicon-containing steel sheet |
JPH0797670A (en) * | 1993-09-30 | 1995-04-11 | Sumitomo Metal Ind Ltd | Galvanizing method for silicon-containing steel sheet |
US5447754A (en) | 1994-04-19 | 1995-09-05 | Armco Inc. | Aluminized steel alloys containing chromium and method for producing same |
JP3444007B2 (en) * | 1995-03-10 | 2003-09-08 | Jfeスチール株式会社 | Manufacturing method of high workability, high strength galvanized steel sheet |
JP3016122B2 (en) * | 1995-10-13 | 2000-03-06 | 住友金属工業株式会社 | Galvannealed steel sheet with excellent paintability and its manufacturing method |
FR2828888B1 (en) | 2001-08-21 | 2003-12-12 | Stein Heurtey | METHOD FOR HOT GALVANIZATION OF HIGH STRENGTH STEEL METAL STRIPS |
FR2852330B1 (en) | 2003-03-12 | 2007-05-11 | Stein Heurtey | METHOD OF CONTROLLED OXIDATION OF STRIPS BEFORE CONTINUOUS GALVANIZATION AND LINE OF GALVANIZATION |
JP3907656B2 (en) * | 2004-12-21 | 2007-04-18 | 株式会社神戸製鋼所 | Hot dip galvanizing method |
-
2006
- 2006-04-26 AT AT06754869T patent/ATE458838T1/en active
- 2006-04-26 PL PL06754869T patent/PL2010690T3/en unknown
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- 2006-04-26 DE DE502006006289T patent/DE502006006289D1/en active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2007124781A1 * |
Cited By (9)
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US9279175B2 (en) | 2010-08-31 | 2016-03-08 | Thyssenkrupp Steel Europe Ag | Method for hot dip coating a flat steel product |
WO2013007578A2 (en) | 2011-07-11 | 2013-01-17 | Thyssenkrupp Steel Europe Ag | Method for producing a flat steel product which is provided with a metallic protective layer by means of hot dip coating |
US9096919B2 (en) | 2011-07-11 | 2015-08-04 | Thyssenkrupp Steel Europe Ag | Method for producing a flat steel product provided with a metal protective layer by way of hot dip coating |
RU2573843C2 (en) * | 2011-07-11 | 2016-01-27 | Тиссенкрупп Стил Юроп Аг | Production of flat steel rolled stock |
US20190275766A1 (en) * | 2016-05-30 | 2019-09-12 | Jfe Steel Corporation | Ferritic stainless steel sheet |
EP3686534A1 (en) | 2019-01-23 | 2020-07-29 | Drever International | Method and furnace for thermal treatment of a high-resistance steel strip including a temperature homogenisation chamber |
BE1026986A1 (en) | 2019-01-23 | 2020-08-17 | Drever Int Sa | Method and furnace for the heat treatment of a strip of high strength steel comprising a temperature homogenization chamber |
WO2020201136A1 (en) * | 2019-04-01 | 2020-10-08 | Salzgitter Flachstahl Gmbh | Method for producing a steel strip with improved bonding of metallic hot-dip coatings |
WO2020201133A1 (en) * | 2019-04-01 | 2020-10-08 | Salzgitter Flachstahl Gmbh | Method for producing a steel strip with improved bonding of metallic hot-dip coatings |
Also Published As
Publication number | Publication date |
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CN101501235B (en) | 2012-07-04 |
PL2010690T3 (en) | 2010-07-30 |
US8636854B2 (en) | 2014-01-28 |
KR101275839B1 (en) | 2013-06-18 |
JP2009534537A (en) | 2009-09-24 |
BRPI0621610A2 (en) | 2011-12-13 |
ATE458838T1 (en) | 2010-03-15 |
DE502006006289D1 (en) | 2010-04-08 |
JP5189587B2 (en) | 2013-04-24 |
EP2010690B1 (en) | 2010-02-24 |
CA2647687C (en) | 2012-10-02 |
KR20080111492A (en) | 2008-12-23 |
US20090199931A1 (en) | 2009-08-13 |
ES2339804T3 (en) | 2010-05-25 |
CA2647687A1 (en) | 2007-11-08 |
CN101501235A (en) | 2009-08-05 |
WO2007124781A1 (en) | 2007-11-08 |
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