EP1990438B1 - Werkzeug mit Beschichtung - Google Patents
Werkzeug mit Beschichtung Download PDFInfo
- Publication number
- EP1990438B1 EP1990438B1 EP20080450060 EP08450060A EP1990438B1 EP 1990438 B1 EP1990438 B1 EP 1990438B1 EP 20080450060 EP20080450060 EP 20080450060 EP 08450060 A EP08450060 A EP 08450060A EP 1990438 B1 EP1990438 B1 EP 1990438B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tool
- coating
- object according
- body portion
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000576 coating method Methods 0.000 title claims description 30
- 239000011248 coating agent Substances 0.000 title claims description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 229910045601 alloy Inorganic materials 0.000 claims description 19
- 239000000956 alloy Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000011651 chromium Substances 0.000 claims description 13
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 239000011733 molybdenum Substances 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000010936 titanium Substances 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 9
- 229910052721 tungsten Inorganic materials 0.000 claims description 9
- 239000010937 tungsten Substances 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 8
- 239000011572 manganese Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000010955 niobium Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 229910001199 N alloy Inorganic materials 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910001338 liquidmetal Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZMXPKUWNBXIACW-UHFFFAOYSA-N [Fe].[Co].[Mo] Chemical compound [Fe].[Co].[Mo] ZMXPKUWNBXIACW-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000003754 machining Methods 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 230000001419 dependent effect Effects 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 description 32
- 238000005520 cutting process Methods 0.000 description 15
- 229910000997 High-speed steel Inorganic materials 0.000 description 11
- 238000005496 tempering Methods 0.000 description 6
- 238000005275 alloying Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910001080 W alloy Inorganic materials 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910002546 FeCo Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- IVHJCRXBQPGLOV-UHFFFAOYSA-N azanylidynetungsten Chemical compound [W]#N IVHJCRXBQPGLOV-UHFFFAOYSA-N 0.000 description 1
- DIUDTORAKXIZFQ-UHFFFAOYSA-N cobalt iron tungsten Chemical compound [Fe][Co][W] DIUDTORAKXIZFQ-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009956 embroidering Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001513 hot isostatic pressing Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- -1 titanium Chemical class 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
- C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12049—Nonmetal component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12063—Nonparticulate metal component
- Y10T428/12104—Particles discontinuous
- Y10T428/12111—Separated by nonmetal matrix or binder [e.g., welding electrode, etc.]
- Y10T428/12125—Nonparticulate component has Fe-base
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12639—Adjacent, identical composition, components
- Y10T428/12646—Group VIII or IB metal-base
- Y10T428/12653—Fe, containing 0.01-1.7% carbon [i.e., steel]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Definitions
- the invention relates to a tool or article which carries a coating applied by a PVD or CVD method.
- the invention preferably relates to a tool for machining metals, in particular austenitic steels, nickel-base alloys and titanium, and titanium alloys.
- Precipitation-hardenable iron-cobalt-molybdenum and / or tungsten alloys are known as tool materials and state of the art.
- a production of larger tools from these so-called quick-cut alloys is associated with a number of problems because on the one hand given a high separation tendency in the solidification of the melt and on the other hand, a hot working of the material are possible only within narrow limits at high temperature.
- the tool as a composite tool, with only small cutting parts made of an iron-cobalt-tungsten alloy, which are connected to a support member, usually made of an alloy steel, by welding.
- An improvement in the performance characteristics of the cutting parts should be achieved by a powder metallurgical (PM) production.
- the tool has long been known and customary to provide at least the working areas of the cutting tools with a surface hard layer.
- the tool After the tool has been formed in its shape and given a thermal coating, it is applied by applying at least one layer of hard material, usually of carbide and / or nitride and of carbonitride and / or oxide, in particular of the elements Ti and / or Al and / or Cr, after PVD or CVD process at a temperature between 500 ° C and 680 ° C, at most below the tempering temperature of the tool steel alloy, in particular the high speed steel alloy.
- hard material usually of carbide and / or nitride and of carbonitride and / or oxide, in particular of the elements Ti and / or Al and / or Cr
- a carbide coating is also known for hard metals and is used extensively for such tools.
- the technological advancement of coated high-speed steel tools improved their quality and performance characteristics such that similarly coated tools made of carbon-free, precipitation hardened (Fe-Co-Mo) cutting parts have approximately the same property profile or equal cutting strength during chip removal.
- the invention which is based on the object to provide a tool or an object, which or which, in particular in a machining of metals, such as titanium, has a significantly improved performance.
- a tool or article which consists of a substantially carbon-free, precipitation-hardened iron-cobalt-molybdenum / tungsten-nitrogen alloy and carries a coating which is applied by the PVD or CVD method and having a monophasic crystalline structure, said body part using a powder metallurgical (PM) process with atomization of liquid metal for block production from an alloy containing in% by weight: Cobalt (Co) 15.0 to 30.0 Molybdenum (Mo) to 20.0 Nitrogen (N) 0005 to 12:12 Silicon (Si) 0.1 to 0.8 Manganese (Mn) 0.1 to 0.6 Chrome (Cr) 12:02 to 0.2 Vanadium (1 /) 12:02 to 0.2 Tungsten (W) to 25.0 Molybdenum + 0.5 tungsten Mo + W / 2 10.0 to 22.0 Nickel (Ni) 12:01 to 0.5 Titanium (Ti) 0001 to 0.2 Niobium / tantalum
- the advantages of the invention can be seen synergistically in an optimization of the alloying technology as well as the selected production method of the main body and in the coating formation.
- a nitrogen content of the Fe-Co-Mo / WN alloy provided according to the invention not only a favorable precipitation behavior of the intermetallic phase with improved homogeneity is achieved, but also the seeding conditions or the adhesion conditions for a hard material layer are advantageously influenced.
- a PM production improves the uniformity of a fine microstructure and has a favorable effect on the deformability of the material.
- the applied to the tool under improved adhesion according to the invention single-phase crystalline structured coating has not only a high hardness and high toughness and a low surface roughness, which has in a chip of particularly tough metals, as has been shown, particular advantages in terms of reduced Tool heating and an improved chip removal brings.
- the advantages of the article or the like according to the invention are, as it turned out, based on a synergy.
- a powder metallurgical production of the main body which has a significantly higher thermal conductivity, a microstructure with a fine distribution of the phases of the material is achieved, in comparison with high-alloyed high-speed steels no noticeable material softening at high temperatures, eg at 600 ° C, occurs.
- the alloying element nitrogen with a minimum concentration of 0.005 wt .-%, in particular of 0.01 wt .-% in the substrate, because this significantly increases the adhesion of the growing coating.
- a monophasic crystalline layer with face-centered cubic structure proves to be superior, because on the one hand it has improved mechanical properties and, on the other hand, has a low surface roughness, which is advantageous in particular for cutting tools.
- the abovementioned alloy within wide limits of the chemical composition is also particularly suitable for atomization of the liquid metal and subsequent solidification to largely homogeneous, small powder grains. This also results in improved deformation conditions of the hot isostatic pressed (HIP) block.
- HIP hot isostatic pressed
- thermoformed article but also the property profile of the main body of a tool and ultimately of the tool itself can be further improved if the body part using a powder metallurgical (PM) method with atomization of liquid metal for block production and of an alloy containing in% by weight: Cobalt (Co) 20.0 to 30.0 Molybdenum (Mo) 11.0 to 19.0 Tungsten (W) 12:01 to 0.9
- PM powder metallurgical
- Iron (Fe) and production-related impurities is made as a remainder .
- An alloy optimization of the chemical composition according to the above values relates to the concentrations of the basic elements, the ratio of cobalt to molybdenum, a narrow limitation of the micro-alloying elements and a limitation of the impurities in the material.
- the nitrogen content is ambivalent on the one hand with regard to the microstructure, on the other hand advantageous in terms of adhesion and a type of coating.
- the elements of silicon and manganese are particularly suitable, which in particular reduce harmful grain boundary deposits.
- the impurity elements aluminum and carbon are ambivalently effective, but should not exceed the specified maximum concentrations.
- Phosphorus, sulfur and oxygen are to be regarded as pests which should have as low as possible levels in the alloy.
- one or more alloying constituent (s) or accompanying element (s) has a concentration in% by weight: Co 24.0 to 27.0 Not a word 13.5 to 17.5 N 0008 to 12:01 Si 0.2 to 0.6 Mn 0.1 to 0.3 Cr 12:03 to 12:07 V 0025 to 12:06 W 12:03 to 12:08 Ni 12:09 to 0.2 Ti 0003 to 0009 Nb / Ta 0003 to 0009 al 0001 to 0009 C 12:01 to 12:07 P MAX 0008 S MAX 0015
- the hardness of the body part exceeds a value of 66 HRC, in particular of 67 HRC, the highest possible stability of the coating can be achieved. Even in the case of a small-area pressure load, ie a locally high, specific surface load, high hardness of the body part or of the main body prevents the brittle hard material layer from breaking in. An improved support of the coating on the substrate with high hardness causes an intact hard layer, prevents a partial peeling thereof, thereby extending the possible service life of the tool.
- the material toughness can be increased in spite of high material hardness.
- the aforementioned tool according to the invention or a like object has a coating with a largely single-phase crystalline structure.
- a predominantly single-phase, cubic face-centered atomic structure of the applied layer can only be achieved at a coating temperature of substantially above 500 ° C.
- thermodynamic and kinetic energy in the micro-region during layer formation or layer build-up, exerts a decisive influence on the formation of the structure of the growing layer.
- a high energy promotes the diffusion of the atoms in a columnar layer forming and thereby causes a compact, contiguous, face-centered cubic, electrically conductive, substantially single-phase layer structure with high layer hardness.
- a hexagonal atomic structure of a layer is hard, but also brittle and electrically non-conductive.
- a high energy or temperature load in the micron range is achieved on the substrate with an abovementioned chemical composition without a decrease in material hardness, hard, smooth and tough surface coatings can be produced which also have a low tendency to breakdown due to the high substrate hardness due to local stresses have and thus cause a high quality of the tool or object.
- a temperature of about 520 ° C. to 600 ° C. in PVD or CVD processes is usually used for a single-phase crystalline formation thereof.
- high coating temperatures can have a retroactive effect on the material hardness of a main body or body part made of conventional tool steels, eg high-speed steels.
- HIP hot isostatic pressing
- the thus prepared HIP block with a diameter of approx. 400 mm ⁇ was hot-rolled at high temperature onto a round bar with a diameter of 31 mm ⁇ .
- an Fe-Co-Mo-N alloy in the present case the material S 903 PM, in particular in the range between RT and 600 ° C has a significantly higher thermal conductivity than a high-speed steel of type S 6-5-2 ( M2).
- the hardness and Young's modulus of a layer deposited on a substrate by the PVD or CVD method increases with higher coating temperatures. At the same time, the roughness of the surface of the applied layer, in particular of a single-phase crystalline structure, is reduced.
- An increased nitrogen concentration on the surface of the tool body part can also be achieved by embroidering it to a nitrogen content of up to 0.4% by weight.
- a favorable kinetics for growth of the layer on the substrate can be achieved.
- X-ray studies can be used to determine the structure of a PVD or CVD layer applied to a substrate or tool.
- Single-phase crystalline, cubic-face-centered structure having high-temperature layers show at the same X-ray intensity due to the lattice planes of the crystals a much higher reflectance in the angular range of the compound TiN / AIN, as in Fig. 4 is illustrated.
- test results of layers according to Fig. 4 show that high temperature layers applied at 575 ° C are at least 5-fold, preferably at least 10-fold, in intensity as measured in pulses by TiN as compared to low-temperature layers applied to 375 ° C (lower panel) / AIN at 2 theta (2 ⁇ ) between 60 and 80.
- a milling cutter with grinding addition formed by cutting and subjected to a thermal treatment in vacuum at a solution annealing temperature of 1180 ° C with a subsequent quenching in nitrogen at 5 bar. This was followed by hardening of the raw mill at a temperature between 580 ° C and 620 ° C, for a period of between 2 and 4 hours.
- a similar milling cutter was made of S-ISO-PM super high speed steel with a previously mentioned composition, thermally tempered and coated with hard material.
- Figure 5 shows that the service life of the tool according to the invention was significantly greater or the cutting wear extremely low. Such a possible duration of use of a tool according to the invention can be extended to a high degree.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
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SI200830049T SI1990438T1 (sl) | 2007-05-08 | 2008-04-22 | Orodje s prevleko |
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AT0070707A AT505221B1 (de) | 2007-05-08 | 2007-05-08 | Werkzeug mit beschichtung |
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EP1990438A1 EP1990438A1 (de) | 2008-11-12 |
EP1990438B1 true EP1990438B1 (de) | 2010-07-07 |
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EP20080450060 Active EP1990438B1 (de) | 2007-05-08 | 2008-04-22 | Werkzeug mit Beschichtung |
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US (1) | US7851067B2 (es) |
EP (1) | EP1990438B1 (es) |
AR (1) | AR066254A1 (es) |
AT (2) | AT505221B1 (es) |
BR (1) | BRPI0801492B1 (es) |
CA (1) | CA2630716C (es) |
DE (1) | DE502008000891D1 (es) |
ES (1) | ES2348322T3 (es) |
RU (1) | RU2384650C2 (es) |
SI (1) | SI1990438T1 (es) |
UA (1) | UA91381C2 (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
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US8740515B2 (en) * | 2008-09-03 | 2014-06-03 | Black & Decker Inc. | Metal cutting drill bit |
EP2502710B1 (en) | 2011-03-22 | 2020-04-22 | Black & Decker Inc. | Chisels |
US9333564B2 (en) | 2013-03-15 | 2016-05-10 | Black & Decker Inc. | Drill bit |
USD734792S1 (en) | 2013-03-15 | 2015-07-21 | Black & Decker Inc. | Drill bit |
USD737875S1 (en) | 2013-03-15 | 2015-09-01 | Black & Decker Inc. | Drill bit |
CN104122710B (zh) * | 2013-04-27 | 2017-08-08 | 北京京东方光电科技有限公司 | 一种显示面板及其制造方法 |
RU2532632C1 (ru) * | 2013-07-12 | 2014-11-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" | Способ получения износостойкого покрытия для режущего инструмента |
RU2532620C1 (ru) * | 2013-07-23 | 2014-11-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" | Способ получения износостойкого покрытия для режущего инструмента |
AT515148B1 (de) * | 2013-12-12 | 2016-11-15 | Böhler Edelstahl GmbH & Co KG | Verfahren zur Herstellung von Gegenständen aus Eisen-Cobalt-Molybdän/Wolfram-Stickstoff-Legierungen |
CN104894483B (zh) * | 2015-05-15 | 2018-07-31 | 安泰科技股份有限公司 | 粉末冶金耐磨工具钢 |
RU2605018C1 (ru) * | 2015-06-22 | 2016-12-20 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") | Способ получения высокотемпературного многослойного композита на металлической поверхности |
SE539733C2 (en) * | 2016-03-16 | 2017-11-14 | Erasteel Sas | A steel alloy and a tool |
RU198076U1 (ru) * | 2020-02-07 | 2020-06-17 | Акционерное общество "Научно-производственное предприятие "Пульсар" | Теплоотвод из композита алюминий-карбид кремния |
RU2748537C1 (ru) * | 2020-09-23 | 2021-05-26 | федеральное государственное бюджетное образовательное учреждение высшего образования «Донской государственный технический университет» (ДГТУ) | Способ изготовления оксидно-кремниевой карбидной режущей керамики новой фракции |
US11946124B2 (en) | 2021-09-29 | 2024-04-02 | Daido Steel Co., Ltd. | Fe-based alloy for melting-solidification shaping and metal powder |
CN114473384B (zh) * | 2022-04-15 | 2022-12-09 | 泉州信息工程学院 | 一种数控矿山绳锯机主电机托板孔系精密加工工艺 |
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US3463677A (en) * | 1968-08-14 | 1969-08-26 | Ishikawajima Harima Heavy Ind | Weldable high strength steel |
SE401689B (sv) | 1974-12-18 | 1978-05-22 | Uddeholms Ab | Verktyg for skerande bearbetning och sett att framstella detta |
US4011108A (en) * | 1976-01-19 | 1977-03-08 | Stora Kopparbergs Bergslags Aktiebolag | Cutting tools and a process for the manufacture of such tools |
DE2757639B2 (de) | 1977-12-23 | 1980-02-28 | Friedr. Lohmann Gmbh Werk Fuer Spezial- & Edelstaehle, 5810 Witten | Schnellstahllegierung |
US4366008A (en) * | 1979-02-09 | 1982-12-28 | Kabushiki Kaisha Fujikoshi | Method for hardening steel |
US7235212B2 (en) * | 2001-02-09 | 2007-06-26 | Ques Tek Innovations, Llc | Nanocarbide precipitation strengthened ultrahigh strength, corrosion resistant, structural steels and method of making said steels |
DE59607891D1 (de) | 1995-08-19 | 2001-11-15 | Widia Gmbh | Verbundkörper und verfahren zu dessen herstellung |
DE19530517A1 (de) | 1995-08-19 | 1997-02-20 | Widia Gmbh | Verbundkörper und Verfahren zu dessen Herstellung |
JP4369545B2 (ja) | 1998-11-30 | 2009-11-25 | 新日本製鐵株式会社 | ひずみ速度依存性に優れたフェライト系薄鋼板およびそれを用いた自動車 |
AT411441B (de) | 2000-06-02 | 2004-01-26 | Boehler Ybbstal Band Gmbh & Co | Verbundwerkzeug |
US6685881B2 (en) * | 2000-09-25 | 2004-02-03 | Daido Steel Co., Ltd. | Stainless cast steel having good heat resistance and good machinability |
US6767627B2 (en) * | 2002-12-18 | 2004-07-27 | Kobe Steel, Ltd. | Hard film, wear-resistant object and method of manufacturing wear-resistant object |
DE102005032860B4 (de) * | 2005-07-04 | 2007-08-09 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Hartstoffbeschichtete Körper und Verfahren zu deren Herstellung |
-
2007
- 2007-05-08 AT AT0070707A patent/AT505221B1/de active
-
2008
- 2008-04-22 AT AT08450060T patent/ATE473309T1/de active
- 2008-04-22 DE DE200850000891 patent/DE502008000891D1/de active Active
- 2008-04-22 ES ES08450060T patent/ES2348322T3/es active Active
- 2008-04-22 SI SI200830049T patent/SI1990438T1/sl unknown
- 2008-04-22 EP EP20080450060 patent/EP1990438B1/de active Active
- 2008-04-23 AR ARP080101696 patent/AR066254A1/es unknown
- 2008-05-05 UA UAA200805742A patent/UA91381C2/ru unknown
- 2008-05-06 US US12/115,746 patent/US7851067B2/en active Active
- 2008-05-07 RU RU2008118281A patent/RU2384650C2/ru active
- 2008-05-07 CA CA 2630716 patent/CA2630716C/en active Active
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Also Published As
Publication number | Publication date |
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ATE473309T1 (de) | 2010-07-15 |
RU2384650C2 (ru) | 2010-03-20 |
US20090007992A1 (en) | 2009-01-08 |
BRPI0801492A2 (pt) | 2008-12-30 |
BRPI0801492B1 (pt) | 2019-11-26 |
ES2348322T3 (es) | 2010-12-02 |
RU2008118281A (ru) | 2009-11-20 |
US7851067B2 (en) | 2010-12-14 |
DE502008000891D1 (de) | 2010-08-19 |
UA91381C2 (en) | 2010-07-26 |
AR066254A1 (es) | 2009-08-05 |
SI1990438T1 (sl) | 2010-09-30 |
AT505221A1 (de) | 2008-11-15 |
EP1990438A1 (de) | 2008-11-12 |
AT505221B1 (de) | 2009-09-15 |
CA2630716A1 (en) | 2008-11-08 |
CA2630716C (en) | 2012-02-14 |
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