EP1977185B1 - Heat exchanger for a combustion engine - Google Patents
Heat exchanger for a combustion engine Download PDFInfo
- Publication number
- EP1977185B1 EP1977185B1 EP06828871.1A EP06828871A EP1977185B1 EP 1977185 B1 EP1977185 B1 EP 1977185B1 EP 06828871 A EP06828871 A EP 06828871A EP 1977185 B1 EP1977185 B1 EP 1977185B1
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- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- exchanger
- steel
- ferritic
- region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/082—Heat exchange elements made from metals or metal alloys from steel or ferrous alloys
- F28F21/083—Heat exchange elements made from metals or metal alloys from steel or ferrous alloys from stainless steel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/22—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
- F02M26/23—Layout, e.g. schematics
- F02M26/25—Layout, e.g. schematics with coolers having bypasses
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/22—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
- F02M26/29—Constructional details of the coolers, e.g. pipes, plates, ribs, insulation or materials
- F02M26/32—Liquid-cooled heat exchangers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D9/0031—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other
- F28D9/0043—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the plates having openings therein for circulation of at least one heat-exchange medium from one conduit to another
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/02—EGR systems specially adapted for supercharged engines
- F02M26/04—EGR systems specially adapted for supercharged engines with a single turbocharger
- F02M26/05—High pressure loops, i.e. wherein recirculated exhaust gas is taken out from the exhaust system upstream of the turbine and reintroduced into the intake system downstream of the compressor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/02—EGR systems specially adapted for supercharged engines
- F02M26/04—EGR systems specially adapted for supercharged engines with a single turbocharger
- F02M26/06—Low pressure loops, i.e. wherein recirculated exhaust gas is taken out from the exhaust downstream of the turbocharger turbine and reintroduced into the intake system upstream of the compressor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/11—Manufacture or assembly of EGR systems; Materials or coatings specially adapted for EGR systems
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2250/00—Arrangements for modifying the flow of the heat exchange media, e.g. flow guiding means; Particular flow patterns
- F28F2250/10—Particular pattern of flow of the heat exchange media
- F28F2250/104—Particular pattern of flow of the heat exchange media with parallel flow
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
- F28F9/001—Casings in the form of plate-like arrangements; Frames enclosing a heat exchange core
Definitions
- the invention relates to a heat exchanger for an internal combustion engine according to the preamble of claim 1.
- Heat exchangers for cooling recirculated exhaust gas are known from the prior art.
- exhaust gas cooling involves the problem of the high chemical aggressiveness of the exhaust gas and of the low pH of its condensates.
- only exhaust gas heat exchangers made of austenitic steels with high corrosion resistance existed so far.
- Such steels generate high material costs and often further consequential costs due to the more complexerieserie-
- austenitic steels are usually poor heat conductors, so that heat exchangers of a given cooling capacity relatively large and heavy build.
- JP 2003 222498 A discloses a shell-and-tube heat exchanger with heat transfer elements made from super-ferritic stainless steel.
- the publication DE 103 28 846 A discloses a gas cooler with domes made of stainless steel.
- the regularly better thermal performance of ferritic steels is used to a particular extent compared to austenitic steels in that the ferritic part of the heat exchanger is in contact with the fluid. Due to the higher thermal conductivity of the ferritic steel thus a total of a small-sized, material, weight and cost-saving design of a heat exchanger for exhaust gas cooling is possible.
- the fluid is particularly preferably a recirculated exhaust gas or exhaust gas / air mixture of the internal combustion engine, the fluid temperature in the first connection region being more than 300 ° C., in particular more than 500 ° C., under normal operation. As a result, the risk of condensation of acidic condensate from the exhaust gas in the region of the entire heat exchanger is reduced.
- the ferritic part of the heat exchanger essentially corresponds to the first connection region and is adhesively bonded to the exchanger region.
- the temperatures are particularly high, which is why ferritic steels can be used relatively easily.
- ferritic steels usually have a lower coefficient of thermal expansion than austenitic steels, which is why the combination of a ferritic connection region with a subsequent austenitic exchange region is particularly favorable in terms of strain-induced material stresses.
- the first connection region preferably has a widening of a passage cross-section in the direction of the exchanger region.
- an adjustable flap can be arranged in the connection region. By way of example, a distribution of the exhaust gas to a cooled region or a bypass channel can take place through the flap.
- the exchanger region has a plurality of exchanger tubes.
- Tube coolers are mechanically very stable and are particularly suitable in connection with a liquid coolant.
- the exchanger area expediently has an exchanger housing through which the liquid coolant can flow. Since the exchanger housing is not regularly in contact with the exhaust gas, it is particularly appropriate that the exchanger housing is made of ferritic steel, since even in the event of rust through, no liquid coolant gets into the combustion chambers of the engine.
- a further part of the heat exchanger consists of a further ferritic steel.
- ferritic steels with different corrosion resistance and mechanical properties, which is reflected regularly in the material price.
- the various parts of a heat exchanger may consist of different ferritic steels to optimize costs.
- the heat exchanger comprises a plurality of disc-like interconnected disc elements.
- a heat exchanger is particularly suitable as exhaust gas heat exchanger.
- a Berippungselement is arranged between the disc elements, which consists of the ferritic steel. Due to the type of construction, corrosion of the ribbing elements does not regularly entail the risk of a breakthrough of coolant into the fluid area, which would otherwise lead to engine damage due to water hammer. Therefore, in particular separable applicable Berippungsetti for training of ferritic steel are particularly predestined.
- Such a ribbing element can be arranged in the fluid to be cooled and / or in the coolant. If a ribbing element in both the fluid is arranged as well as in the coolant, so these Berippungseiemente regularly differ in their training.
- a housing which surrounds the disk elements and which consists of the ferritic steel is particularly preferably provided.
- a high-life corrosion of the housing would not lead to a connection between the coolant and the exhaust gas, whereby the risk of engine damage is reduced.
- Such a housing is a component of considerable size, in which considerable costs can be saved by using ferritic steel.
- the disc elements when using a sufficiently corrosion-resistant ferritic steel, it is also preferable for the disc elements to be made of ferritic steel, which serves for the heat conduction and thus the total heat exchanger performance for a given size.
- another part of the heat exchanger is made of an austenitic steel, whereby a material with a high corrosion resistance is used at least at critical points.
- the austenitic steel is preferably a steel from the group 1.4301 and 1.4404. These material designations comply with the standard DIN EN 100 88-2, to which reference is made for all the numbered material designations mentioned in the context of the present invention.
- the part made of ferritic steel with the austenitic steel part is glued directly to one another in a materially bonded manner.
- a particularly secure connection is guaranteed.
- at least the preferred for the heat exchanger ferritic and austenitic steels are usually easily bonded together cohesively.
- the ferritic steel is a steel from the group 1.4016.
- Suitable higher-alloyed ferritic steels with at least 12% Cr content are preferably from the group 1.4000, 1.4002 and 1.4113.
- Higher alloyed and stabilized steels are preferred from the group 1.4509, 1.4513, 1.4512 and 1.4520.
- the coolant is gaseous, in particular air.
- Such exchangers do not harbor the risk of water hammering in the event of corrosion and have particularly high requirements with regard to the heat conduction of the materials in order to achieve a suitable cooling performance.
- the use of ferritic steels is suitable.
- a heat exchanger according to the invention can be arranged in a low-pressure branch after an exhaust gas turbine (low-pressure EGR). In this arrangement occur lower mechanical loads and temperature differences.
- the heat exchanger can also be arranged in a high pressure branch in front of an exhaust gas turbine.
- the fluid is a particular recirculated exhaust gas or exhaust-air mixture of the internal combustion engine, wherein the fluid temperature in the section in the usual mode of operation is more than 300 ° C, in particular more than 500 ° C.
- the first connection region has a widening of a passage cross-section in the direction of the exchanger region.
- an adjustable flap is arranged in the connection area.
- the exchanger area has a plurality of exchanger tubes.
- the exchanger region has an exchanger housing through which the coolant can flow.
- the Berippungselement is arranged in the fluid to be cooled.
- the austenitic steel is a steel from the group 1.4301 and 1.4404, designations according to DIN EN 100 88-2.
- the coolant is gaseous, in particular air.
- the heat exchanger is arranged in a low pressure branch after an exhaust gas turbine.
- the heat exchanger is arranged in a high-pressure branch in front of an exhaust gas turbine.
- the exhaust gas heat exchanger after Fig. 1 is built on the principle of a tube bundle exchanger. He has a first connection area 1 to the feeder of the exhaust gas (or exhaust-air mixture), an exchanger region 2, in which the main part of the heat exchange takes place, and a second connection region 3 for the discharge of the exhaust gas.
- a controllable by means of an actuator 4 via a mechanism 5 adjustable flap 6 is rotatably supported, by means of which the exhaust gas flow between a bypass channel 7 and a bundle of heat exchanger tubes 8 can be deflected adjustable.
- the bypass channel 7 and the exchanger tubes 8 are welded together by means of head elements 9, wherein in addition by a housing shell 10 by welding with the head elements 9 a through-flow of liquid coolant exchanger housing is formed.
- a housing shell 10 by welding with the head elements 9 a through-flow of liquid coolant exchanger housing is formed.
- two connecting pieces 11 are provided for the passage of the liquid coolant through the exchanger housing.
- the housing shell 10 made of this steel.
- the exchanger tubes 8, the head elements 9 as well as the second connection region 3 may consist of a ferritic steel. Due to the higher risk of condensation in the relatively cool region of the gas outlet, the second connection region 3 is preferably made of a ferritic steel of stainless and stabilized quality, in particular 1.4512 or 1.4509.
- the exchanger tubes 8 and / or the bypass channel 7 and / or the head elements 9 are in the case in which they are made of ferritic steel, preferably made of stainless and stabilized quality (in particular 1.4512 and / or 1.4509).
- external attachments such as holding plates, etc.
- the heat exchanger of the second embodiment is designed as a disk heat exchanger.
- an outer housing 101 which has a first connection region 102 for connecting a feed for the exhaust gas and a second connection region 103 for connecting a discharge for the exhaust gas, a number of disk elements 104 are arranged.
- the housing 101 also includes a cover 105, on which there are connections 106, 107 for connection of supply lines and discharges of a coolant.
- the disk elements 104 and areas of the housing 101 and cover 105 together form the exchanger area of the heat exchanger.
- Each of the disk elements 104 is made up of two disks 104a, 104b, wherein a ribbing element 108 is provided between the disks 104a, 104b.
- the respective upper disk 104a has a nozzle-like bulge 104c, which adjoins the edge of an opening in the lower disk of the subsequent disk element.
- the individual sockets 104c of the disk elements are aligned with each other and with the terminals 106, 107 of the lid 105.
- the disk element 104 farthest from the cover has a lower disk 104b which has no apertures.
- a total of one of the liquid coolant flow-through cavity is formed by the amount of spaces between each upper plate 104a and lower plate 104b, edge boundaries of the cavities are formed by welding the bent edges 104d of the discs 104a, 104b with each other.
- the coolant flows in each of the disc elements between the one, the port 106 associated with the nozzle, and the other, the port 107 associated nozzle.
- the ribbing 108 flowed around by the coolant ensures additionally improved heat exchange between the coolant and the disks, in particular turbulence of the coolant being produced.
- the intermediate space between two adjacent disk elements 104 is open in each case to the terminal areas 102, 103 of the housing 101 of the heat exchanger at the front side of the disk elements.
- the exhaust gas flows through these intermediate spaces, wherein it is cooled at the large area cooled by the coolant disc elements 104.
- the longitudinal edge regions 104d of the disk elements 104 are bent over and lie partially flat against the inner wall of the housing 101 (see in particular FIG Fig. 3 ).
- the largest possible possible welding or soldering of the disk elements 104 with the inner wall of the housing 101 so that the housing 101 experiences a sufficient cooling performance.
- the housing 101 is made of a ferritic steel. It may in particular be a cost-effective steel such as e.g. 1.1169, 1.0461, 1.0462 and 1.0463. In the case of corrosion of the housing part 101, there would be no leakage of liquid coolant into the exhaust gas, which is why the use of the cheaper material is made possible here in the interest of a cost-risk assessment.
- the disk stack 104 and also the lid 105 may consist of a ferritic steel. Since these elements provide a separation between the exhaust gas and the liquid coolant, the ferritic steel is preferably a particularly corrosion-resistant grade, such as 1.4000, 1.4002 or 1.4113 or even a high-grade ferritic steel such as 1.4513 or 1.4520.
- rib elements 109 may be disposed between the disk elements 104 which are flowed around by the exhaust gas and thus provide an enlarged heat exchange surface. These ribs 109 may be made of ferritic steel. thus provide an enlarged exchanger surface. These ribs 109 may be made of ferritic steel.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Exhaust-Gas Circulating Devices (AREA)
Description
Die Erfindung betrifft einen Wärmetauscher für einen Verbrennungsmotor nach dem Oberbegriff des Anspruchs 1.The invention relates to a heat exchanger for an internal combustion engine according to the preamble of claim 1.
Aus dem Stand der Technik sind Wärmetauscher zur Kühlung von rückgeführtem Abgas bekannt. Allgemein besteht bei der Abgaskühlung die Problematik der hohen chemischen Aggressivität des Abgases sowie des niedrigen pH-Wertes seiner Kondensate. Aus diesem Grund existierten bisher ausschließlich Abgaswärmetauscher, die aus austenitischen Stählen mit hoher Korrosionsbeständigkeit hergestellt wurden. Solche Stähle erzeugen hohe Materialkosten und häufig weitere Folgekosten aufgrund der aufwändigeren Bearbeitungsgänge- Zudem sind austenitische Stähle meist schlechte Wärmeleiter, so dass Wärmetauscher einer vorgegebenen Kühlleistung relativ groß und schwer bauen.Heat exchangers for cooling recirculated exhaust gas are known from the prior art. In general, exhaust gas cooling involves the problem of the high chemical aggressiveness of the exhaust gas and of the low pH of its condensates. For this reason, only exhaust gas heat exchangers made of austenitic steels with high corrosion resistance existed so far. Such steels generate high material costs and often further consequential costs due to the more complex Bearbeitungsgänge- In addition, austenitic steels are usually poor heat conductors, so that heat exchangers of a given cooling capacity relatively large and heavy build.
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Die Druckschrift
Es ist die Aufgabe der Erfindung, einen Wärmetauscher zur Kühlung von Abgas oder Abgas- Luft-Gemisch eines Verbrennungsmotors anzugeben, der zu geringen Kosten herstellbar ist.It is the object of the invention to provide a heat exchanger for cooling exhaust gas or exhaust air mixture of an internal combustion engine, which can be produced at low cost.
Diese Aufgabe wird für einen eingangs genannten Wärmetauscher erfindungsgemäß mit den kennzeichnenden Merkmalen des Anspruchs 1 gelöst.This object is achieved according to the invention for a heat exchanger mentioned above with the characterizing features of claim 1.
Dadurch, dass zumindest ein Teil des Wärmetauschers aus ferritischem Stahl besteht, können aufgrund der zumeist niedrigeren Preise für diese Stähle Kosten gespart werden.The fact that at least part of the heat exchanger is made of ferritic steel, costs can be saved due to the generally lower prices for these steels.
In bevorzugter Ausführung wird die regelmäßig bessere Wärmeleistung von ferritischen Stählen im Vergleich zu austenitischen Stählen in besonderem Maße dadurch genutzt, dass der ferritische Teil des Wärmetauschers mit dem Fluid in Berührung steht. Durch die höhere Wärmeleitfähigkeit des ferritischen Stahls ist somit insgesamt eine kleinbauende, material-, gewichts- und kostensparende Ausführung eines Wärmetauschers zur Abgaskühlung ermöglicht.In a preferred embodiment, the regularly better thermal performance of ferritic steels is used to a particular extent compared to austenitic steels in that the ferritic part of the heat exchanger is in contact with the fluid. Due to the higher thermal conductivity of the ferritic steel thus a total of a small-sized, material, weight and cost-saving design of a heat exchanger for exhaust gas cooling is possible.
Besonders bevorzugt ist das Fluid ein insbesondere rückgeführtes Abgas oder Abgas- Luft-Gemisch des Verbrennungsmotors, wobei die Fluidtemperatur in dem ersten Anschlussbereich bei üblicher Betriebsweise mehr als 300 °C, insbesondere mehr als 500 °C beträgt. Hierdurch ist die Gefahr einer Kondensation von saurem Kondensat aus dem Abgas im Bereich des gesamten Wärmetauschers verringert.The fluid is particularly preferably a recirculated exhaust gas or exhaust gas / air mixture of the internal combustion engine, the fluid temperature in the first connection region being more than 300 ° C., in particular more than 500 ° C., under normal operation. As a result, the risk of condensation of acidic condensate from the exhaust gas in the region of the entire heat exchanger is reduced.
Gemäß der Erfindung entspricht der ferritische Teil des Wärmetauschers im Wesentlichen dem ersten Anschlussbereich und ist mit dem Tauscherbereich stoffschlüssig verklebt. Gerade im ersten Anschlussbereich sind die Temperaturen besonders hoch, weshalb ferritische Stähle relativ problemlos eingesetzt werden können. Zudem haben ferritische Stähle zumeist einen geringeren Wärmeausdehnungskoeffizienten als austenitische Stähle, weswegen die Kombination eines ferritischen Anschlussbereiches mit einem nachfolgenden austenitischen Tauscherbereich im Hinblick auf dehnungsbedingte Materialspannungen besonders günstig ist. Insbesondere in diesem Zusammenhang hat der erste Anschlussbereich bevorzugt eine Aufweitung eines Durchtrittsquerschnitts in Richtung des Tauscherbereichs. Weiterhin bevorzugt kann in dem Anschlussbereich eine stellbare Klappe angeordnet sein. Durch die Klappe kann beispielsweise eine Verteilung des Abgases auf einen gekühlten Bereich oder einen Bypasskanal erfolgen.According to the invention, the ferritic part of the heat exchanger essentially corresponds to the first connection region and is adhesively bonded to the exchanger region. Particularly in the first connection area, the temperatures are particularly high, which is why ferritic steels can be used relatively easily. In addition, ferritic steels usually have a lower coefficient of thermal expansion than austenitic steels, which is why the combination of a ferritic connection region with a subsequent austenitic exchange region is particularly favorable in terms of strain-induced material stresses. In particular in this context, the first connection region preferably has a widening of a passage cross-section in the direction of the exchanger region. Further preferably, an adjustable flap can be arranged in the connection region. By way of example, a distribution of the exhaust gas to a cooled region or a bypass channel can take place through the flap.
In weiterhin bevorzugter Ausführung hat der Tauscherbereich eine Mehrzahl von Tauscherrohren. Rohrkühler sind mechanisch sehr stabil und bieten sich insbesondere in Verbindung mit einem flüssigen Kühlmittel an. Hierzu hat der Tauscherbereich zweckmäßig ein von dem flüssigen Kühlmittel durchströmbares Tauschergehäuse. Da das Tauschergehäuse regelmäßig nicht mit dem Abgas in Berührung steht, bietet es sich besonders an, dass das Tauschergehäuse aus dem ferritischen Stahl besteht, da selbst im Falle einer Durchrostung kein flüssiges Kühlmittel in die Verbrennungsräume des Motors gerät.In a further preferred embodiment, the exchanger region has a plurality of exchanger tubes. Tube coolers are mechanically very stable and are particularly suitable in connection with a liquid coolant. For this purpose, the exchanger area expediently has an exchanger housing through which the liquid coolant can flow. Since the exchanger housing is not regularly in contact with the exhaust gas, it is particularly appropriate that the exchanger housing is made of ferritic steel, since even in the event of rust through, no liquid coolant gets into the combustion chambers of the engine.
Zur Verbesserung einer Wärmetauscherleistung können vorteilhaft die Tauscherrohre aus dem ferritischen Stahl bestehen, da dieses Material eine gute Wärmeleitung hat.To improve a heat exchanger performance can advantageously be the exchanger tubes made of ferritic steel, since this material has a good heat conduction.
Insbesondere vorteilhaft kann es vorgesehen sein, dass ein weiterer Teil des Wärmetauschers aus einem weiteren ferritischen Stahl besteht. Es gibt ferritische Stähle mit unterschiedlichen Korrosionsbeständigkeiten und mechanischen Eigenschaften, was sich regelmäßig im Materialpreis niederschlägt. Je nachdem, in wieweit das betreffende Teil des Wärmetauschers der Korrosion ausgesetzt ist oder an einer Wärmeleitung beteiligt ist können die verschiedenen Teile eines Wärmetauschers zur Optimierung der Kosten aus verschiedenen ferritischen Stählen bestehen.Particularly advantageously, it can be provided that a further part of the heat exchanger consists of a further ferritic steel. There are ferritic steels with different corrosion resistance and mechanical properties, which is reflected regularly in the material price. Depending on the extent to which the part of the heat exchanger in question is exposed to corrosion or involved in heat conduction, the various parts of a heat exchanger may consist of different ferritic steels to optimize costs.
In einer weiteren bevorzugten Ausführungsform umfasst der Wärmetauscher eine Mehrzahl von stapelartig miteinander verbundenen Scheibenelementen. Ein solcher Wärmetauscher ist auf besonders günstige Weise als Abgaswärmetauscher geeignet. Vorteilhaft ist dabei zwischen den Scheibenelementen ein Berippungselement angeordnet, das aus dem ferritischen Stahl besteht. Eine Korrosion der Berippungselemente bringt aufgrund der Bauart regelmäßig nicht die Gefahr eines Durchbruchs von Kühlflüssigkeit in den Fluidbereich mit sich, was sonst zu Motorschäden durch Wasserschlag führen würde. Daher sind insbesondere separiert einsetzbare Berippungselemente zur Ausbildung aus ferritischem Stahl besonders prädestiniert. Ein solches Berippungselement kann in dem zu kühlenden Fluid und/oder in dem Kühlmittel angeordnet sein. Wenn ein Berippungselement sowohl in dem Fluid als auch in dem Kühlmittel angeordnet ist, so unterscheiden sich diese Berippungseiemente regelmäßig in ihrer Ausbildung.In a further preferred embodiment, the heat exchanger comprises a plurality of disc-like interconnected disc elements. Such a heat exchanger is particularly suitable as exhaust gas heat exchanger. Advantageously, a Berippungselement is arranged between the disc elements, which consists of the ferritic steel. Due to the type of construction, corrosion of the ribbing elements does not regularly entail the risk of a breakthrough of coolant into the fluid area, which would otherwise lead to engine damage due to water hammer. Therefore, in particular separable applicable Berippungselemente for training of ferritic steel are particularly predestined. Such a ribbing element can be arranged in the fluid to be cooled and / or in the coolant. If a ribbing element in both the fluid is arranged as well as in the coolant, so these Berippungseiemente regularly differ in their training.
Besonders bevorzugt ist dabei ein die Scheibenelemente umfangendes Gehäuse vorgesehen, welches aus dem ferritischen Stahl besteht. Eine durch hohe Lebensdauer bedingte Korrosion des Gehäuses würde nicht zu einer Verbindung zwischen Kühlmittel und Abgas führen, wodurch die Gefahr eines Motorschadens verringert ist. Ein solches Gehäuse stellt ein Bauteil von erheblicher Größe dar, bei dem durch Verwendung von ferritischem Stahl erhebliche Kosten gespart werden können. Bei Verwendung eines ausreichend korrosionsfesten ferritischen Stahls können jedoch auch bevorzugt die Scheibenelemente aus ferritischem Stahl bestehen, was der Wärmeleitung und somit der Gesamttauscherleistung bei gegebener Baugröße dient.In this case, a housing which surrounds the disk elements and which consists of the ferritic steel is particularly preferably provided. A high-life corrosion of the housing would not lead to a connection between the coolant and the exhaust gas, whereby the risk of engine damage is reduced. Such a housing is a component of considerable size, in which considerable costs can be saved by using ferritic steel. However, when using a sufficiently corrosion-resistant ferritic steel, it is also preferable for the disc elements to be made of ferritic steel, which serves for the heat conduction and thus the total heat exchanger performance for a given size.
Gemäß der Erfindung besteht ein weiterer Teil des Wärmetauschers aus einem austenitischen Stahl, wodurch ein Material mit einer hohen Korrosionsfestigkeit zumindest an kritischen Stellen eingesetzt wird. Der austenitische Stahl ist bevorzugt ein Stahl aus der Gruppe 1.4301 und 1.4404. Diese Werkstoffbezeichnungen entsprechen der Norm DIN EN 100 88-2, auf die für sämtliche im Rahmen der vorliegenden Erfindung genannten nummerierten Werkstoffbezeichnungen Bezug genommen ist.According to the invention, another part of the heat exchanger is made of an austenitic steel, whereby a material with a high corrosion resistance is used at least at critical points. The austenitic steel is preferably a steel from the group 1.4301 and 1.4404. These material designations comply with the standard DIN EN 100 88-2, to which reference is made for all the numbered material designations mentioned in the context of the present invention.
Gemäß der Erfindung ist der Teil aus ferritischem Stahl mit dem Teil aus austenitischem Stahl unmittelbar miteinander stoffschlüssig verklebt. Durch eine solche stoffschlüssige Verbindung, ist eine besonders sichere Verbindung gewährleistet. Versuche haben ergeben, dass zumindest die für den Wärmetauscherbau bevorzugten ferritischen und austenitischen Stähle im Regelfall problemlos miteinander stoffschlüssig verklebbar sind.According to the invention, the part made of ferritic steel with the austenitic steel part is glued directly to one another in a materially bonded manner. By such a cohesive connection, a particularly secure connection is guaranteed. Experiments have shown that at least the preferred for the heat exchanger ferritic and austenitic steels are usually easily bonded together cohesively.
Bevorzugt ist der ferritische Stahl ein Stahl aus der Gruppe 1.4016. Geeignete höher legierte ferritische Stähle mit mindestens 12% Cr- Gehalt sind bevorzugt aus der Gruppe 1.4000, 1.4002 und 1.4113. Höher legierte und stabilisierte Stähle (mit Titan und Niob) sind bevorzugt aus der Gruppe 1.4509, 1.4513, 1.4512 und 1.4520.Preferably, the ferritic steel is a steel from the group 1.4016. Suitable higher-alloyed ferritic steels with at least 12% Cr content are preferably from the group 1.4000, 1.4002 and 1.4113. Higher alloyed and stabilized steels (with titanium and niobium) are preferred from the group 1.4509, 1.4513, 1.4512 and 1.4520.
Bei einem weiteren bevorzugten Wärmetauscher ist das Kühlmittel gasförmig, insbesondere Luft. Solche Tauscher beherbergen bei Korrosion nicht die Gefahr eines Wasserschlags und haben hinsichtlich der Wärmeleitung der Materialien zur Erzielung einer geeigneten Kühlleistung besonders hohe Anforderungen. Somit ist die Verwendung von ferritischen Stählen geeignet.In a further preferred heat exchanger, the coolant is gaseous, in particular air. Such exchangers do not harbor the risk of water hammering in the event of corrosion and have particularly high requirements with regard to the heat conduction of the materials in order to achieve a suitable cooling performance. Thus, the use of ferritic steels is suitable.
Ein erfindungsgemäßer Wärmetauscher kann in einem Niederdruck-Zweig nach einer Abgasturbine angeordnet sein (Niederdruck-AGR). In dieser Anordnung treten geringere mechanische Belastungen und Temperaturdifferenzen auf. Alternativ kann der Wärmetauscher aber auch in einem Hochdruck-Zweig vor einer Abgasturbine angeordnet sein.A heat exchanger according to the invention can be arranged in a low-pressure branch after an exhaust gas turbine (low-pressure EGR). In this arrangement occur lower mechanical loads and temperature differences. Alternatively, however, the heat exchanger can also be arranged in a high pressure branch in front of an exhaust gas turbine.
Weitere Vorteile und Merkmale eines erfindungsgemäßen Wärmetauschers ergeben sich aus den nachfolgend beschriebenen Ausführungsbeispielen sowie aus den abhängigen Ansprüchen.Further advantages and features of a heat exchanger according to the invention will become apparent from the embodiments described below and from the dependent claims.
Vorteilhaft ist, dass das Fluid ein insbesondere rückgeführtes Abgas oder Abgas-Luft-Gemisch des Verbrennungsmotors ist, wobei die Fluidtemperatur in dem Abschnitt in üblicher Betriebsweise mehr als 300 °C, insbesondere mehr als 500 °C beträgt.It is advantageous that the fluid is a particular recirculated exhaust gas or exhaust-air mixture of the internal combustion engine, wherein the fluid temperature in the section in the usual mode of operation is more than 300 ° C, in particular more than 500 ° C.
Vorteilhaft ist, dass der erste Anschlussbereich eine Aufweitung eines Durchtrittsquerschnitts in Richtung des Tauscherbereichs aufweist.It is advantageous that the first connection region has a widening of a passage cross-section in the direction of the exchanger region.
Vorteilhaft ist, dass in dem Anschlussbereich eine stellbare Klappe angeordnet ist.It is advantageous that an adjustable flap is arranged in the connection area.
Vorteilhaft ist, dass der Tauscherbereich eine Mehrzahl von Tauscherrohren aufweist.It is advantageous that the exchanger area has a plurality of exchanger tubes.
Vorteilhaft ist, dass der Tauscherbereich ein von dem Kühlmittel durchströmbares Tauschergehäuse aufweist.It is advantageous that the exchanger region has an exchanger housing through which the coolant can flow.
Vorteilhaft ist, dass das Berippungselement in dem zu kühlenden Fluid angeordnet ist.It is advantageous that the Berippungselement is arranged in the fluid to be cooled.
Vorteilhaft ist, dass das Berippungselement in dem Kühlmittel angeordnet ist.It is advantageous that the Berippungselement is arranged in the coolant.
Vorteilhaft ist, dass der austenitische Stahl ein Stahl aus der Gruppe 1.4301 und 1.4404, Bezeichnungen nach DIN EN 100 88-2, ist.It is advantageous that the austenitic steel is a steel from the group 1.4301 and 1.4404, designations according to DIN EN 100 88-2.
Vorteilhaft ist, dass das Kühlmittel gasförmig, insbesondere Luft ist.It is advantageous that the coolant is gaseous, in particular air.
Vorteilhaft ist, dass der Wärmetauscher in einem Niederdruck-Zweig nach einer Abgasturbine angeordnet ist.It is advantageous that the heat exchanger is arranged in a low pressure branch after an exhaust gas turbine.
Vorteilhaft ist, dass der Wärmetauscher in einem Hochdruck-Zweig vor einer Abgasturbine angeordnet ist.It is advantageous that the heat exchanger is arranged in a high-pressure branch in front of an exhaust gas turbine.
Nachfolgend werden zwei bevorzugte Ausführungsbeispiele eines erfindungsgemäßen Wärmetauschers beschrieben und anhand der anliegenden Zeichnungen näher erläutert.
- Fig. 1
- zeigt eine räumliche, teilweise aufgeschnittene Ansicht eines ersten Ausführungsbeispiels eines erfindungsgemäßen Wärmetauschers.
- Fig. 2
- zeigt eine räumliche Explosionsdarstellung eines zweiten Ausführungsbeispiels eines Wärmetauschers.
- Fig. 3
- zeigt eine schematische Schnittansicht durch einen fertig montierten Wärmetauscher nach
Fig. 2 .
- Fig. 1
- shows a spatial, partially cutaway view of a first embodiment of a heat exchanger according to the invention.
- Fig. 2
- shows a spatial exploded view of a second embodiment of a heat exchanger.
- Fig. 3
- shows a schematic sectional view through a finished mounted heat exchanger after
Fig. 2 ,
Der Abgas-Wärmetauscher nach
Der Bypasskanal 7 und die Tauscherrohre 8 sind mittels Kopfelementen 9 miteinander verschweißt, wobei zudem durch einen Gehäusemantel 10 durch Verschweißung mit den Kopfelementen 9 ein von flüssigem Kühlmittel durchströmbares Tauschergehäuse ausgebildet ist. An dem Gehäusemantel 10 sind zwei Anschlussstutzen 11 zur Durchleitung des flüssigen Kühlmittels durch das Tauschergehäuse vorgesehen.The bypass channel 7 and the
Bei dem beschriebenen Wärmetauscher besteht zumindest der erste Anschlussbereich 1, welcher aus einem sich in Richtung des Tauscherbereichs 2 erweiternden Gehäuse besteht, aus einem ferritischen Stahl. Zweckmäßig besteht zudem der Gehäusemantel 10 aus diesem Stahl.In the described heat exchanger, at least the first connection region 1, which consists of a housing which widens in the direction of the
Je nach Temperaturbereich des Abgasstroms, wobei dieser unter anderem davon abhängen kann, ob der Kühler in einem Niederdruck- oder Hochdruck- Abgasrückführsystem eingesetzt ist, können zudem die Tauscherrohre 8, die Kopfelemente 9 sowie auch der zweite Anschlussbereich 3 aus einem ferritischen Stahl bestehen. Aufgrund der höheren Kondensationsgefahr im relativ kühlen Bereich des Gasaustritts ist der zweite Anschlussbereich 3 bevorzugt aus einem ferritischen Stahl von nichtrostender und stabilisierter Qualität, insbesondere 1.4512 oder 1.4509, hergestellt. Die Tauscherrohre 8 und/oder der Bypasskanal 7 und/oder die Kopfelemente 9 sind in dem Fall, in dem sie aus ferritischen Stahl bestehen, bevorzugt aus nichtrostender und stabilisierter Qualität hergestellt (insbesondere 1.4512 und/oder 1.4509).Depending on the temperature range of the exhaust gas flow, which may depend inter alia on whether the radiator is used in a low-pressure or high-pressure exhaust gas recirculation system, the
Zur Kostenersparnis können insbesondere äußere Anbauteile wie etwa Haltebleche etc. aus ferritischem Stahl bestehen.In order to save costs, in particular external attachments, such as holding plates, etc., may consist of ferritic steel.
Der Wärmetauscher des zweiten Ausführungsbeispiels (
Jedes der Scheibenelemente 104 ist aus zwei Scheiben 104a, 104b aufgebaut, wobei zwischen den Scheiben 104a, 104b ein Berippungselement 108 vorgesehen ist. Die jeweils obere Scheibe 104a hat eine stutzenartige Aufwölbung 104c, welche an den Rand einer Durchbrechung der unteren Scheibe des nachfolgenden Scheibenelements anschließt. Die einzelnen Stutzen 104c der Scheibenelemente fluchten miteinander und mit den Anschlüssen 106, 107 des Deckels 105. Das dem Deckel am weitesten entfernte Scheibenelement 104 hat eine untere Scheibe 104b, die keine Durchbrechungen aufweist. Auf diese Weise ist durch die Menge der Zwischenräume zwischen jeweils oberer Scheibe 104a und unterer Scheibe 104b insgesamt ein von dem flüssigen Kühlmittel durchfließbarer Hohlraum ausgebildet, wobei randseitige Begrenzungen der Hohlräume durch Verschweißung der umgebogenen Ränder 104d der Scheiben 104a, 104b miteinander gebildet sind.Each of the
Das Kühlmittel fließt in jedem der Scheibenelemente zwischen dem einen, dem Anschluss 106 zugeordneten Stutzen, und dem anderen, dem Anschluss 107 zugeordneten Stutzen. Die von dem Kühlmittel umströmte Berippung 108 sorgt dabei für einen zusätzlich verbesserten Wärmeaustausch zwischen dem Kühlmittel und den Scheiben, wobei insbesondere Turbulenzen des Kühlmittels erzeugt werden.The coolant flows in each of the disc elements between the one, the
Der vor allem durch die Höhe der Stutzen 104c definierte Zwischenraum zwischen zwei benachbarten Scheibenelementen 104 ist jeweils stirnseitig der Scheibenelemente zu den Anschlussbereichen 102, 103 des Gehäuses 101 des Wärmetauschers offen. Das Abgas durchströmt diese Zwischenräume, wobei es an den großflächigen durch das Kühlmittel gekühlten Scheibenelementen 104 abgekühlt wird.The intermediate space between two
Zur mechanischen Stabilisierung sowie zur Kühlung des Gehäuses 101 sind die längsseitigen Randbereiche 104d der Scheibenelemente 104 umgebogen und liegen bereichsweise flächig an der Innenwand des Gehäuses 101 an (siehe insbesondere
Bevorzugt ist das Gehäuse 101 aus einem ferritischen Stahl hergestellt. Es kann sich insbesondere um einen kostengünstigen Stahl wie z.B. 1.1169, 1.0461, 1.0462 und 1.0463 handeln. Bei Korrosion des Gehäuseteils 101 würde kein Austritt von flüssigem Kühlmittel in das Abgas erfolgen, weswegen hier im Interesse einer Kosten-Risiko-Abwägung die Verwendung des preiswerteren Materials ermöglicht ist.Preferably, the
Zur Verbesserung der Tauscherleistung, somit auch zur Verkleinerung der Baugröße bei vorgegebener Tauscherleistung, kann der Scheibenstapel 104 und auch der Deckel 105 aus einem ferritischen Stahl bestehen. Da durch diese Elemente eine Trennung zwischen Abgas und flüssigem Kühlmittel gegeben ist, ist der ferritische Stahl bevorzugt eine besonders korrosionsbeständige Sorte, etwa 1.4000, 1.4002 oder 1.4113 oder auch ein hochwertiger ferritischer Stahl wie 1.4513 oder 1.4520.To improve the heat exchanger performance, thus also to reduce the size for a given heat exchanger performance, the
Wie
Claims (11)
- A heat exchanger for an internal combustion engine, comprising
a first connecting region (1, 102) for the supply of a fluid to be cooled, wherein the fluid is at least proportionately composed of exhaust gas of the internal combustion engine,
a second connecting region (3, 103) for the discharge of the fluid, and
an exchanger region (2, 101, 104, 105) arranged between the first and the second connecting region with regard to a flow path of the fluid,
wherein a coolant is able to flow around the exchanger region (2, 101, 104, 105),
characterised in that
at least a part of the heat exchanger is composed of ferritic steel, wherein the ferritic part of the heat exchanger corresponds substantially to the first connecting region (1, 102) and is glued to the exchanger region (2, 101, 104, 105) in a firmly bonded fashion,
wherein a further part of the heat exchanger is composed of an austenitic steel, and
wherein the part composed of ferritic steel and the part composed of austenitic steel are directly glued to one another in a firmly bonded fashion. - The heat exchanger as claimed in claim 1, characterised in that the ferritic part is in contact with the fluid.
- The heat exchanger as claimed in claim 1 or 2, characterised in that the exchanger region (2, 101, 104, 105) has an exchanger housing (10, 101) through which the coolant can flow, wherein the exchanger housing (10, 101) is composed at least partially of the ferritic steel.
- The heat exchanger as claimed in one of claims 1 to 3, characterised in that the exchanger region (2, 101, 104, 105) has a plurality of exchanger tubes (8), wherein the exchanger tubes (8) are composed of the ferritic steel.
- The heat exchanger as claimed in one of the preceding claims, characterised in that a further part of the heat exchanger is composed of a further ferritic steel.
- The heat exchanger as claimed in one of the preceding claims, characterised in that the heat exchanger comprises a plurality of plate elements (104) which are connected to one another in a stacked manner.
- The heat exchanger as claimed in claim 6, characterised in that a fin element (108, 109) for increasing a thermal contact is arranged between the plate elements (104), wherein the fin element (108, 109) is composed of the ferritic steel.
- The heat exchanger as claimed in one of claims 6 or 7, characterised in that a housing (101) which is composed of the ferritic steel and which encompasses the plate elements (104) is provided.
- The heat exchanger as claimed in one of the preceding claims, characterised in that the ferritic steel is a steel from the group 1.4016.
- The heat exchanger as claimed in one of the preceding claims, characterised in that the ferritic steel is a steel from the group 1.400, 1.4002 and 1.4113.
- The heat exchanger as claimed in one of the preceding claims, characterised in that the ferritic steel is a steel from the group 1.4513 and 1.4520.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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EP14193540.3A EP2851645A3 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
EP14193543.7A EP2851646B1 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
Applications Claiming Priority (2)
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DE102005055481A DE102005055481A1 (en) | 2005-11-18 | 2005-11-18 | Heat exchanger for an internal combustion engine |
PCT/EP2006/010343 WO2007057099A1 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
Related Child Applications (4)
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EP14193543.7A Division-Into EP2851646B1 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
EP14193543.7A Division EP2851646B1 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
EP14193540.3A Division-Into EP2851645A3 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
EP14193540.3A Division EP2851645A3 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
Publications (2)
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EP1977185A1 EP1977185A1 (en) | 2008-10-08 |
EP1977185B1 true EP1977185B1 (en) | 2017-12-13 |
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EP14193540.3A Withdrawn EP2851645A3 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
EP06828871.1A Not-in-force EP1977185B1 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
EP14193543.7A Active EP2851646B1 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
Family Applications Before (1)
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EP14193540.3A Withdrawn EP2851645A3 (en) | 2005-11-18 | 2006-10-26 | Heat exchanger for a combustion engine |
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US (1) | US7882827B2 (en) |
EP (3) | EP2851645A3 (en) |
JP (1) | JP2009516122A (en) |
CN (1) | CN101313192B (en) |
DE (1) | DE102005055481A1 (en) |
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- 2005-11-18 DE DE102005055481A patent/DE102005055481A1/en not_active Withdrawn
-
2006
- 2006-10-26 EP EP14193540.3A patent/EP2851645A3/en not_active Withdrawn
- 2006-10-26 EP EP06828871.1A patent/EP1977185B1/en not_active Not-in-force
- 2006-10-26 WO PCT/EP2006/010343 patent/WO2007057099A1/en active Application Filing
- 2006-10-26 US US12/093,481 patent/US7882827B2/en active Active
- 2006-10-26 EP EP14193543.7A patent/EP2851646B1/en active Active
- 2006-10-26 JP JP2008540483A patent/JP2009516122A/en active Pending
- 2006-10-26 CN CN2006800425768A patent/CN101313192B/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
EP2851646B1 (en) | 2021-07-28 |
EP2851645A2 (en) | 2015-03-25 |
EP2851645A3 (en) | 2015-04-08 |
CN101313192A (en) | 2008-11-26 |
JP2009516122A (en) | 2009-04-16 |
EP1977185A1 (en) | 2008-10-08 |
US7882827B2 (en) | 2011-02-08 |
WO2007057099A1 (en) | 2007-05-24 |
EP2851646A3 (en) | 2015-04-08 |
US20080271722A1 (en) | 2008-11-06 |
EP2851646A2 (en) | 2015-03-25 |
CN101313192B (en) | 2010-09-01 |
DE102005055481A1 (en) | 2007-05-24 |
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