EP1954651B1 - Brandmasse mit einem metallischen brennstoff aus der gruppe ivb des periodischen systems sowie geschoss mit dieser brandmasse - Google Patents
Brandmasse mit einem metallischen brennstoff aus der gruppe ivb des periodischen systems sowie geschoss mit dieser brandmasse Download PDFInfo
- Publication number
- EP1954651B1 EP1954651B1 EP06828965.1A EP06828965A EP1954651B1 EP 1954651 B1 EP1954651 B1 EP 1954651B1 EP 06828965 A EP06828965 A EP 06828965A EP 1954651 B1 EP1954651 B1 EP 1954651B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- projectile
- incendiary
- binder
- incendiary compound
- duroplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000001875 compounds Chemical class 0.000 title claims 12
- 230000000737 periodic effect Effects 0.000 title claims 2
- 239000011230 binding agent Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 18
- 239000002360 explosive Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 238000013467 fragmentation Methods 0.000 claims description 2
- 238000006062 fragmentation reaction Methods 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 230000006835 compression Effects 0.000 claims 2
- 238000007906 compression Methods 0.000 claims 2
- 238000007669 thermal treatment Methods 0.000 claims 2
- 238000001033 granulometry Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 17
- 239000002184 metal Substances 0.000 description 17
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- -1 polytetrafluoroethylene Polymers 0.000 description 3
- 206010041662 Splinter Diseases 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 1
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical group CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 1
- 229920001342 Bakelite® Polymers 0.000 description 1
- 239000000028 HMX Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C15/00—Pyrophoric compositions; Flints
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C9/00—Chemical contact igniters; Chemical lighters
Definitions
- the invention relates to a fire mass according to the preamble of patent claim 1 and a projectile according to claim 5 or 6.
- Known splinter firing munitions contain mixtures of highly explosive explosives such as hexogen, octogen, trotyl and aluminum powder.
- the DE 29 01 517 describes a fire mass with an organic binder and a metal sponge, such as zirconium or hafnium, wherein polytetrafluoroethylene is used as a binder in a proportion of 2 to 15 mass%.
- the invention has as its object to show a fire mass, which has a sufficiently high flame life.
- the invention is based on the knowledge gained in investigations that with a corresponding Kornvertellung the preferably spherical metal powder in the range of 50-250 ⁇ m only a proportion of the binder in the fire mass even less than 1 mass% is needed, Thus, the binder Be used in the smallest possible concentration, which still ensures sufficient compressibility and fixation of the fire mass. Especially in the use of explosives-free projectiles, this distribution has also given the best results in practice.
- the use of spherical metal powders, in particular zirconium metal powder, with a higher surface area allows the binder to be applied dry to the surface of the metal powder, thereby increasing the readability and allowing volumetric metering. Volumetric means to make the powder slippery by using coarse granules with ultrafine powder and at a given temperature.
- a good organic binder is Bakelite® which is incorporated in micronized form to aid in volumetric dosing.
- an organic binder preferably halogen-free, is also incorporated in this fire mass.
- This is, as already stated, preferably a thermoset or thermoplastic micronized organic binder
- the fire mass is inert in the projectile inert, its function in the target is developed by chemical reaction with atmospheric oxygen (air-breathing system with thermobaric reaction as non ideal high blast explosives).
- the fixation of the fire mass in the projectile or warhead is carried out by pressing and subsequent heat treatment to activate the thermoset crosslinking or melting of the thermoplastic binder.
- metal powders are titanium or hafnium. This type of metal powder is not produced from the reaction of the individual basic substances themselves, but from starting materials processed into bars. Thus, the zirconium powder with a mean grain size is not obtained from zircon itself, but from a zirconium rod.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Powder Metallurgy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005057182A DE102005057182A1 (de) | 2005-11-29 | 2005-11-29 | Brandmasse mit einem metallischen Brennstoff aus der Gruppe IVB des periodischen Systems sowie Geschoss mit dieser Brandmasse |
PCT/EP2006/010709 WO2007062732A2 (de) | 2005-11-29 | 2006-11-09 | Brandmasse mit einem metallischen brennstoff aus der gruppe ivb des periodischen systems sowie geschoss mit dieser brandmasse |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1954651A2 EP1954651A2 (de) | 2008-08-13 |
EP1954651B1 true EP1954651B1 (de) | 2014-07-09 |
Family
ID=38042583
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06828965.1A Active EP1954651B1 (de) | 2005-11-29 | 2006-11-09 | Brandmasse mit einem metallischen brennstoff aus der gruppe ivb des periodischen systems sowie geschoss mit dieser brandmasse |
Country Status (6)
Country | Link |
---|---|
US (1) | US8518197B2 (no) |
EP (1) | EP1954651B1 (no) |
CA (1) | CA2620844C (no) |
DE (1) | DE102005057182A1 (no) |
NO (1) | NO339632B1 (no) |
WO (1) | WO2007062732A2 (no) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007021451A1 (de) | 2007-04-05 | 2008-10-09 | Rwm Schweiz Ag | Subprojektil mit energetischem Inhalt |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3809586A (en) | 1969-07-09 | 1974-05-07 | H Waite | Incendiary composition including zinc-mischmetal alloy |
US4131498A (en) | 1978-01-25 | 1978-12-26 | Teledyne Industries, Inc. | Metallic sponge incendiary compositions |
DE3164190D1 (en) * | 1980-10-31 | 1984-07-19 | Oerlikon Buehrle Ag | Incendiary compound comprising a metallic fuel from group iva of the periodic system |
JPS62124201A (ja) | 1985-11-21 | 1987-06-05 | Kawasaki Steel Corp | 非凝集性粉末と凝集性微粉末の混合方法 |
US5707419A (en) | 1995-08-15 | 1998-01-13 | Pegasus Refractory Materials, Inc. | Method of production of metal and ceramic powders by plasma atomization |
US6551376B1 (en) | 1997-03-14 | 2003-04-22 | Doris Nebel Beal Inter Vivos Patent Trust | Method for developing and sustaining uniform distribution of a plurality of metal powders of different densities in a mixture of such metal powders |
AUPP115497A0 (en) | 1997-12-23 | 1998-01-29 | University Of Queensland, The | Binder treated aluminium powders |
DE10140600A1 (de) | 2001-08-18 | 2003-03-06 | Rheinmetall W & M Gmbh | Brandsatz für ein flügelstabilisiertes Wuchtgeschoß |
-
2005
- 2005-11-29 DE DE102005057182A patent/DE102005057182A1/de not_active Withdrawn
-
2006
- 2006-11-09 US US12/085,014 patent/US8518197B2/en active Active
- 2006-11-09 WO PCT/EP2006/010709 patent/WO2007062732A2/de active Application Filing
- 2006-11-09 CA CA2620844A patent/CA2620844C/en active Active
- 2006-11-09 EP EP06828965.1A patent/EP1954651B1/de active Active
-
2007
- 2007-12-04 NO NO20076237A patent/NO339632B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
DE102005057182A1 (de) | 2007-06-06 |
WO2007062732A2 (de) | 2007-06-07 |
US8518197B2 (en) | 2013-08-27 |
NO339632B1 (no) | 2017-01-16 |
EP1954651A2 (de) | 2008-08-13 |
CA2620844A1 (en) | 2007-06-07 |
NO20076237L (no) | 2008-01-09 |
CA2620844C (en) | 2016-01-05 |
WO2007062732A3 (de) | 2007-08-02 |
US20090266261A1 (en) | 2009-10-29 |
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