EP1946643A1 - Ingrédients alimentaires doté d'une acidité réduite à pH faible - Google Patents

Ingrédients alimentaires doté d'une acidité réduite à pH faible Download PDF

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Publication number
EP1946643A1
EP1946643A1 EP07115771A EP07115771A EP1946643A1 EP 1946643 A1 EP1946643 A1 EP 1946643A1 EP 07115771 A EP07115771 A EP 07115771A EP 07115771 A EP07115771 A EP 07115771A EP 1946643 A1 EP1946643 A1 EP 1946643A1
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European Patent Office
Prior art keywords
food
percent
organic acid
food ingredient
sour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP07115771A
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German (de)
English (en)
Inventor
Jimbay Peter Loh
Yeong-Ching Albert Hong
Alice Shen Cha
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Intercontinental Great Brands LLC
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Kraft Foods Holdings Inc
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Publication of EP1946643A1 publication Critical patent/EP1946643A1/fr
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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00—Cheese; Cheese preparations; Making thereof
    • A23C19/02—Making cheese curd
    • A23C19/05—Treating milk before coagulation; Separating whey from curd
    • A23C19/052—Acidifying only by chemical or physical means
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00—Cheese; Cheese preparations; Making thereof
    • A23C19/06—Treating cheese curd after whey separation; Products obtained thereby
    • A23C19/068—Particular types of cheese
    • A23C19/076—Soft unripened cheese, e.g. cottage or cream cheese
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00—Cheese; Cheese preparations; Making thereof
    • A23C19/06—Treating cheese curd after whey separation; Products obtained thereby
    • A23C19/09—Other cheese preparations; Mixtures of cheese with other foodstuffs
    • A23C19/0904—Liquid cheese products, e.g. beverages, sauces
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/14—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment
    • A23C9/142—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by dialysis, reverse osmosis or ultrafiltration
    • A23C9/1422—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by dialysis, reverse osmosis or ultrafiltration by ultrafiltration, microfiltration or diafiltration of milk, e.g. for separating protein and lactose; Treatment of the UF permeate
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/14—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment
    • A23C9/142—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by dialysis, reverse osmosis or ultrafiltration
    • A23C9/1427—Milk preparations; Milk powder or milk powder preparations in which the chemical composition of the milk is modified by non-chemical treatment by dialysis, reverse osmosis or ultrafiltration by dialysis, reverse osmosis or hyperfiltration, e.g. for concentrating or desalting
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/15—Reconstituted or recombined milk products containing neither non-milk fat nor non-milk proteins
    • A23C9/1504—Spreads, semi-solid products
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/1522—Inorganic additives, e.g. minerals, trace elements; Chlorination or fluoridation of milk; Organic salts or complexes of metals other than natrium or kalium; Calcium enrichment of milk
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/0003—Processes of manufacture not relating to composition or compounding ingredients
    • A23G1/002—Processes for preparing or treating cocoa beans or nibs
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/23—Removal of unwanted matter, e.g. deodorisation or detoxification by extraction with solvents
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the present invention is directed to organic acid reduced food ingredients and methods of making organic acid reduced food ingredients having a less sour taste and better organoleptic properties at low pH than conventional food ingredients with higher total organic acid content.
  • Reduced sourness of the food ingredients of the present invention may be achieved by subjecting the food ingredients to organic acid/organic acid salt reduction methods.
  • Patent Publications 2005/0186312 , 2005/0220969 , 2006/003499 , and 2006/0034994 are not always adequate in mitigating the undesirable sour taste due to the fact that many food ingredients (e.g., milk, milk powder, cheese, cocoa, and the like) contain high level of organic acids (e.g. lactic acid) and/or metal salts of organic acids (e.g. calcium citrate).
  • food ingredients e.g., milk, milk powder, cheese, cocoa, and the like
  • organic acids e.g. lactic acid
  • metal salts of organic acids e.g. calcium citrate
  • Described herein is a method of making a food ingredient or product comprising reducing total organic acid content (TOAC) in the food ingredient by at least about 20 percent (preferably by at least about 50 percent and more preferably by at least about 70 percent), wherein the food Ingredient is not sour compared to a conventional food ingredient at a pH of 5 or less.
  • TOAC total organic acid content
  • the food ingredient or product is a dairy ingredient or product.
  • the food ingredient may be milk or cheese.
  • the food ingredient is cocoa.
  • the finished food product is any of dairy spread, chocolate milk food, and cheese sauce.
  • the food ingredient is incorporated into a finished food product.
  • the reduction of TOAC is accomplished by any of water extraction, solvent extraction, membrane separation, ion exchange, precipitation, centrifugation, and combinations thereof.
  • Also described herein is a method of making a finished food product comprising reducing TOAC in a food ingredient by at least about 20 percent (preferably by at least about 50 percent and more preferably by at least about 70 percent), and incorporating the food ingredient into a finished food product, wherein the finished food product has a TOAC of 0.2 mole or less per kilogram of the finished food product, and reducing the pH of the finished food product to the range of 5 and below, preferably to the range of 4.5 and blow, wherein the finished food product is shelf stable under ambient and/or refrigeration storage conditions and is not sour compared to a conventional finished food product at a similar pH.
  • TOAC-reduced food ingredients and methods of making TOAC-reduced food ingredients having a less sour taste and better organoleptic properties than conventional food ingredients at low pH values are those food ingredients and food products that have not been subjected to organic acid and/or organic salt reduction methods. Reduced sourness of the food ingredients of the present invention may be achieved by subjecting the food ingredients to organic acid/organic acid salt reduction methods.
  • the TOAC-reduced food ingredients produced by the methods described herein may be used in a variety of foodstuffs and particularly in low pH foodstuffs.
  • An edible inorganic acid e.g., food grade hydrochloric acid
  • the final pH of TOAC-reduced food ingredients of the present invention can be further adjusted to any pH (2 to 11) with food grade inorganic acids (e.g., hydrochloric acid) or inorganic bases (e.g., sodium hydroxide) as appropriate and desired.
  • the TOAC-reduced food ingredients of this invention may be further processed into various physical forms (e.g., liquid concentrates, dry powders, and the like) as needed for storage or transportation purposes.
  • the food ingredients of the present invention taste less sour than the conventional food ingredients having higher TOAC. Because the TOAC-reduced food ingredients described herein are less sour than conventional food ingredients, they are more palatable than conventional food ingredients in low pH or acidified food products.
  • the inventive method may be applied to a wide variety of food ingredients.
  • the inventive food ingredients may also be incorporated into food product achieving the same beneficial properties, such as increased shelf life by lowering product pH without increased sourness.
  • the methodology is useful for reducing sourness of cheese, milk, skim milk, whole milk, cheese curd, dairy spread, cocoa, cheese sauce, chocolate flavored milk food, vanilla flavored milk food, process cheese, and the like.
  • a TOAC-reduced milk or dairy ingredient e.g., whey powder
  • whey powder may be used in the production of a low pH, reduced sour cheese product.
  • food products made from the food ingredients described herein retain the beneficial properties of the food ingredients.
  • low pH food products made with the inventive food ingredients have a longer shelf life, yet do not have adverse organoleptic properties (such as sourness).
  • the methods described herein are useful when applied to high moisture (generally containing at least about 20 percent moisture and/or having a water activity of about 0.85 or greater) food products.
  • Food ingredients can be made to taste significantly less sour at a low pH through effective reduction of TOAC by at least about 20 percent of the untreated food ingredient.
  • the TOAC may be reduced by at least about 50 percent.
  • the TOAC may be reduced by at least about 70 percent.
  • the organic acid/salt reduced food ingredients may be used in the production of low pH foodstuffs without inducing sour off-taste in the finished low pH products. Generally, more than 0.2 mole organic acids per 1 kilogram of finished food product gives rise to an objectionable taste. Thus, it is desirable to reduce the total amount of organic acids to 0.2 mole per 1 kilogram (or lower) of finished food product.
  • acids having a higher pK a and more protons are more sour at equal molar concentration and pH than acids having a lower pK a and fewer ionizable protons.
  • those organic acids having a higher pK a and more ionizable protons will contribute disproportionately to a sour taste. Since most organic acids have a pK a of 2.0 to 5.0 and most low pH foods have a pH between 2.5 and 5.0, the TOAC is a good indication of perceived sourness in a low pH food product.
  • pH is a measure of the acidity of a solution in terms of activity of hydrogen.
  • a neutral solution i.e., a solution where the hydrogen ion activity equals hydroxide ion activity
  • Aqueous solutions with pH values lower than 7 are considered acidic, while pH values higher than 7 are considered basic.
  • acidic substances include lemon juice (pH of approximately 2.4), cola (pH of approximately 2.5), vinegar (pH of approximately 2.9), orange juice (pH of approximately 3.5), beer (pH of approximately 4.5), coffee (pH of approximately 5.0), and tea (pH of approximately 5.5).
  • low pH is any pH at 5 or below.
  • An organic acid is an organic compound with acidic properties.
  • the most common organic acids are the carboxylic acids whose acidity is associated with their carboxyl group (-COOH).
  • Other groups can also confer acidity, although usually weakly. Examples include the hydroxyl group (-OH), sulfhydryl group (-SH), enol group (an alkene with a hydroxyl group), and the phenol group (a phenyl ring with a hydroxyl group).
  • Examples of organic acids include gluconic acid, lactic acid, acetic acid, sorbic acid, adipic acid, maleic acid, carbonic acid, fumaric acid, citric acid, formic acid, butyric acid, and benzoic acid.
  • Salts of organic acids are the ionized form of the acid.
  • Examples of salts of organic acids include gluconate, lactate, acetate, sorbate, adipate, succinate/malate, tartarate/carbonate, fumarate, oxalate, citrate, and formate. Due to its unusually high pK a , phosphoric acid can provide a significant contribution to the sour taste of low pH food products (generally about 2.5 to about 5 pH and particularly below about 4); thus, for purposes of this invention, phosphoric acid is considered as an organic acid within the context of TOAC reduction.
  • Total organic acid content in a food product can influence the perceived sourness intensity.
  • the organic acids in a food mainly come from the added edible food acidulants including, but not limited to, acetic acid, adipic acid, citric acid, fumaric acid, gluconic acid, lactic acid, malic acid, and tartaric acid; as noted, phosphoric acid also contributes to the perceived sourness and, thus, for purposes of this invention, is considered an organic acid. Natural occurring organic acids in food ingredients will also contribute to perceived sourness.
  • total organic acid content or TOAC is defined as the sum of all the above-mentioned food acidulants and all natural occurring organic acids (including those not mentioned above such as oxalic acid, succinic acid, ascorbic acid, chlorogenic acid, and the like), as well as the corresponding salts of such acids.
  • An organic acid profile can be readily obtained using appropriate analytical methods (see e.g., Rantakokko et al., "Ion Chromatographic Method for the Determination of Selected Inorganic Anions and Organic Acids from Raw and Drinking Waters Using Suppressor Current Switching to Reduce The Background Noise," J. Liq. Chrom., 27, 821-842 (2004) , which is hereby incorporated by reference).
  • the quantity of individual organic acids can be measured and summed up to give “total organic acid content” which can be conveniently expressed in "moles per 1000 grams of finished foodstuff.”
  • organic acids may also be present in the form of salts. Therefore, for the purposes of the description herein, reducing the amount of organicacids is synonymous with reducing the amount of the corresponding organic salts. Also for the purposes of the description herein, a reduction of an organic acid may be measured by quantifying the total amount of the organic acids, which includes those from free organic acids and organic acid salts, in a food ingredient or food product before and after treatment.
  • Reduction in total organic acid content of a food product may be achieved using any suitable method so long as the desired reduction can be obtained.
  • methods useful for reducing organic acid content of an ingredient include, but are not limited to, water extraction, solvent extraction, membrane separation, ion exchange, precipitation, centrifugation, and combinations thereof.
  • Solvents useful for reducing total organic acid content of a food product may include, but are not limited to, water, pH-adjusted water (e.g., water containing food grade inorganic acids or bases, water in which the pH is adjusted by methods such as electrodialysis, and the like), aqueous solutions of edible salts (e.g., NaCl), food grade alcohol, and combinations thereof.
  • pH-adjusted water e.g., water containing food grade inorganic acids or bases, water in which the pH is adjusted by methods such as electrodialysis, and the like
  • aqueous solutions of edible salts e.g., NaCl
  • Membrane separation techniques include, but are not limited to, dialysis, ultrafiltration (UF), diafiltration (DF), microfiltration (MF), nano filtration (NF), and electrodialysis (ED), and the like.
  • Precipitation techniques include, but are not limited to, chemical precipitation, physical precipitation, and enzymatic precipitation.
  • shelf stable food products is intended to mean that the preserved food products stored under ambient conditions are safe for consumption.
  • refrigeration stable food products is intended to mean the preserved food products stored under refrigeration conditions are safe for consumption.
  • food compositions that are shelf stable under ambient storage condition are also refrigeration stable.
  • shelf lives of shelf stable food products of this invention are at least about three months, preferably at least about six months, or even more at least about twelve months.
  • shelf lives for refrigeration stable products are at least about one month, preferably at least about two months, even more preferably at least about three months, and most preferably at least about four months.
  • Example 1 Organic Acid Reduced Cheese Curd.
  • a cheese curd having reduced organic acid content was prepared by washing (soaking) fresh cottage cheese curd at 5°C for 60 minutes with an equal amount (by weight) of deionized water pH adjusted to 3.0. The liquid was drained off leaving the curds. The curds were homogenized with a lab blender and pH adjusted to 4.0 with 6.25N HCl. An unwashed control curd was also homogenized with a lab blender and pH adjusted to 4.0 with 6.25N HCl.
  • the experimental curd and the control curd were analyzed for organic acid composition and sensory sourness at an equal pH of 4.0.
  • the washed curd was significantly less sour than the control curd.
  • the control curd was noticeably much more sour tasting.
  • Organic acid analysis indicated that the washed curd had a significant reduction of lactate (76 percent), phosphate (62.5 percent), and citrate (75 percent) in comparison to the control curd.
  • Example 2 Citrate and Phosphate Reduced Milk.
  • Pasteurized cow milk was pH adjusted from 6.6 to 5.5 using food grade 5N HCl and then concentrated using UF and DF to about 3 times the original concentration.
  • the filtered milk was then reconstituted back to the original concentration and adjusted to a pH of 4.0 using 5N HCl, Unfiltered control milk was also adjusted to a pH of 4.0 using 5N HCl.
  • the pH adjusted reconstituted filtered milk and unfiltered control milk were evaluated by three separate sensory panels with five to seven panelists on each panel.
  • the organoleptic evaluation confirmed that the filtered milk did not taste sour whereas the unfiltered control milk was extremely sour.
  • Both samples were subjected to organic acid analysis.
  • Organic acid analysis indicated that the filtered milk had a significant reduction of lactate (at least 87.5 percent), acetate (approximately 75 percent), phosphate (approximately 91 percent), and citrate (approximately 96 percent) in comparison to the control.
  • Example 3 Washed, Organic Acid Reduced Cocoa.
  • Commercial roasted cocoa nibs (D-type alkaline treated from Archer Daniels Midland Co., Cocoa Div., Milwaukee, WI) were mixed with 2 parts deionized water and pH adjusted to 3.0 with 6.25N and 0.1 N HCl. Part of the cocoa mixture was subjected to heat treatment for 5 minutes at 80°C. The remainder of the cocoa mixture was not subjected to any heat treatment. The samples were then equilibrated at 5°C for about 12 hours. Next, the nibs were dried in a convective oven at 65°C. The heat treated, washed cocoa sample and the unheated, washed cocoa sample were ground, separately, into a powder in a small kitchen coffee grinder.
  • a 5 percent aqueous dispersion of each of the heat treated, washed cocoa sample and the unheated, washed cocoa sample were pH adjusted to 4.0.
  • a 5 percent aqueous dispersion of unwashed, unheated cocoa (the control) was also pH adjusted to 4.0.
  • the washed, unheated sample had a significant reduction of gluconate (approximately 23 percent), lactate (approximately 71 percent), acetate (approximately 73 percent), adipate (at least 50 percent), succinate/malate (approximately 71 percent), tartarate (approximately 50 percent), fumarate/oxalate (approximately 41 percent), phosphate (approximately 58 percent), citrate (approximately 72 percent), and formate (approximately 83 percent).
  • Example 4 Dairy Spread.
  • a shelf-stable dairy spread was prepared from the citrate and phosphate reduced milk from Example 2. 60 percent 3x UF/DF milk concentrate from Example 2, 0.2 percent salt, 20.2 percent water, 13 percent anhydrous milk fat, 5 percent sugar, 0.05 percent sorbic acid, 1.5 2.5N food grad HCl, and 0.0006 percent flavorings were mixed together to make a creamy milk spread.
  • the anhydrous milk fat was first melted and mixed with the rest of the ingredient (except for flavorings) and homogenized at 3000/500 psi. Then, the homogenized mixture was pasteurized at about 185°F for 5 minutes. Flavorings were added 2 minutes before completing the pasteurization.
  • the resulting spread was filled into a plastic container. The spread had a pH of 4.2. The spread met the requirements of a shelf stable product under ambient storage conditions for a period of at least 3 months.
  • the spread was evaluated by an expert sensory panel.
  • the spread had a pleasant milky flavor and had no detectable sour off-taste.
  • the dairy spread was successfully used as an intermediate component as a dairy based for other flavored spreads (e.g., strawberry, chocolate) and non-spread products.
  • Example 5 Chocolate Milk Food.
  • a shelf stable, low pH (4.2), non-sour chocolate milk food was prepared from the dairy spread from Example 4.
  • 80 percent of the dairy base from Example 4, 6.5 percent water, 0.28 percent gums, 11 percent sugar, 1.5 percent commercial cocoa (D-11-S from Archer Daniels Midland Co., Cocoa Div., Milwaukee, WI), 0.6 percent 2.5 N HCl, and 0.1 percent flavorings were mixed together to make the chocolate milk food.
  • the composition was pasteurized at 185°F for 5 minutes. Flavorings were added 2 minutes before completing the pasteurization.
  • the chocolate milk food was used as a spread and shaped into various shapes (bits and slices) as a milk snack.
  • the chocolate milk food had a pH of 4.2.
  • the spread met the requirements of a shelf stable product under ambient storage conditions for at least about 3 months.
  • the chocolate milk food was evaluated by a six person expert sensory panel.
  • the milk chocolate product had normal chocolate milk flavor/taste profile and was not sour in taste.
  • Example 6 Cheese Sauce.
  • a shelf stable, low pH cheese sauce with normal protein content was made using the citrate and phosphate reduced milk concentrate from Example 2.
  • the anhydrous milk fat was pre-melted.
  • Starch slurry was pre-formed with 1 part starch to 3 parts water.
  • the cheese sauce was evaluated by a six person expert sensory panel.
  • the cheese sauce had excellent flavor, texture, was not sour, and exhibited the taste profile of a regular cheese sauce.
  • Example 7 Acidified cheese.
  • An acidified cheese was made using the citrate and phosphate reduced UF/DF milk from Example 2.
  • Citrate and phosphate reduced UF/DF concentrated milk from Example 2 (90 percent), water (9.95 percent), and 45 percent (w/v) calcium chloride solution (0.05 percent) were mixed together and kept at refrigeration temperature.
  • 2.5N HCl percent (2.2 percent by weight of the mixture) was quickly mixed into the composition.
  • Approximately 0.01 percent Chymax solution was added after the acidification step.
  • the composition was incubated at 90°F for 40 minutes. Then, the curds were cut and were incubated at 110°F for 60 minutes. The curds were then drained on cheesecloth and pressed to extract excess whey and salted (2 percent by weight of the curds).
  • the end product was an acidified cheese (pH 4.6) that may be used in processed cheese, cheese sauce, or other food products.
  • Example 8 Citrate and Phosphate Reduced Skim Milk.
  • Pasteurized skim milk was adjusted to a pH of 5.5 from a pH of 6.8 using a food grade 5N HCl.
  • the skim milk was filtered and concentrated using UF and DF to about 4 time of the original concentration.
  • the resulting milk was then reconstituted with deionized water to achieve approximately the same protein concentration of regular skim milk.
  • Part of the reconstituted milk was acidified with citric acid to a pH of 4.0.
  • the other part of the reconstituted milk was acidified with HCl to a pH of 4.0.
  • a control sample of skim milk was also acidified with HCl to a pH of 4.0.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Water Supply & Treatment (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dairy Products (AREA)
  • Seeds, Soups, And Other Foods (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • General Preparation And Processing Of Foods (AREA)
EP07115771A 2006-12-15 2007-09-05 Ingrédients alimentaires doté d'une acidité réduite à pH faible Withdrawn EP1946643A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/611,479 US20080145497A1 (en) 2006-12-15 2006-12-15 Food Ingredients With Reduced Sourness At Low pH

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EP1946643A1 true EP1946643A1 (fr) 2008-07-23

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US (1) US20080145497A1 (fr)
EP (1) EP1946643A1 (fr)
AU (1) AU2007211909B2 (fr)
BR (1) BRPI0704166A (fr)
CA (1) CA2599041A1 (fr)
MX (1) MX2007012008A (fr)
RU (1) RU2007136068A (fr)
ZA (1) ZA200707297B (fr)

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US9107430B2 (en) 2008-01-22 2015-08-18 Barry Callebaut Ag Process for producing red or purple cocoa-derived material

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ZA200707297B (en) 2008-06-25
US20080145497A1 (en) 2008-06-19
RU2007136068A (ru) 2009-04-10
AU2007211909A1 (en) 2008-07-03
AU2007211909B2 (en) 2013-05-02
BRPI0704166A (pt) 2008-08-12
CA2599041A1 (fr) 2008-06-15
MX2007012008A (es) 2009-01-13

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