EP1838588B1 - Fluid product dispensing assembly - Google Patents
Fluid product dispensing assembly Download PDFInfo
- Publication number
- EP1838588B1 EP1838588B1 EP05824240A EP05824240A EP1838588B1 EP 1838588 B1 EP1838588 B1 EP 1838588B1 EP 05824240 A EP05824240 A EP 05824240A EP 05824240 A EP05824240 A EP 05824240A EP 1838588 B1 EP1838588 B1 EP 1838588B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluid
- receptacle
- envelope
- internal
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000012530 fluid Substances 0.000 title claims abstract description 58
- 230000004888 barrier function Effects 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000011521 glass Substances 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000002304 perfume Substances 0.000 claims description 5
- 239000004922 lacquer Substances 0.000 claims description 4
- 239000002966 varnish Substances 0.000 claims description 4
- 238000009826 distribution Methods 0.000 description 9
- 239000003570 air Substances 0.000 description 8
- 238000013022 venting Methods 0.000 description 6
- 239000004033 plastic Substances 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 3
- RHAXKFFKGZJUOE-UHFFFAOYSA-N 7-acetyl-6-ethyl-3,5,8-trihydroxy-9,10-dioxoanthracene-1,2-dicarboxylic acid Chemical compound O=C1C2=CC(O)=C(C(O)=O)C(C(O)=O)=C2C(=O)C2=C1C(O)=C(CC)C(C(C)=O)=C2O RHAXKFFKGZJUOE-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 101100328877 Caenorhabditis elegans col-13 gene Proteins 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 235000021189 garnishes Nutrition 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D23/00—Details of bottles or jars not otherwise provided for
- B65D23/02—Linings or internal coatings
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/02—Scent flasks, e.g. with evaporator
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/0005—Components or details
- B05B11/0037—Containers
- B05B11/0038—Inner container disposed in an outer shell or outer casing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/02—Membranes or pistons acting on the contents inside the container, e.g. follower pistons
- B05B11/026—Membranes separating the content remaining in the container from the atmospheric air to compensate underpressure inside the container
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D2034/005—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes with a cartridge
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/05—Details of containers
- A45D2200/053—Transparent containers
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/05—Details of containers
- A45D2200/054—Means for supplying liquid to the outlet of the container
- A45D2200/057—Spray nozzles; Generating atomised liquid
Definitions
- the present invention relates to a fluid dispenser assembly comprising a container defining an internal space, an inner liner disposed in the inner space and a dispensing member, such as a pump, for dispensing fluid product.
- Perfumery and cosmetics are preferred but not exclusive fields of application of the present invention.
- the fluid product contained in such sets may for example be a lotion, a cream or a perfume.
- These sets related to luxury products require a particularly neat appearance to attract the consumer.
- the designers of such sets can play on different parameters to highlight these sets such as their shape, their color or their design material (s).
- Examples of embodiments of such materials include placing an inner liner in a fluid reservoir.
- This internal lining may for example correspond to plastic leaflets provided with inscriptions or ornamental patterns arranged in a floatation in the fluid reservoir. These leaflets, decorative and / or informative purpose, can then be seen by transparency through the fluid reservoir, thus giving a particularly attractive overall aesthetic appearance.
- the present invention therefore aims to overcome the aforementioned drawbacks of the prior art.
- the present invention aims to provide a dispensing assembly provided with an internal liner insusceptible to generate physico-chemical changes of the fluid contained in the reservoir.
- the present invention also aims to provide a dispensing assembly having a particularly original and attractive physiognomy.
- the present invention also aims to provide a dispensing assembly that is simple to manufacture and assemble and having a low cost.
- Another object of the present invention is to ensure the integrity of the fluid to be dispensed even when the container has a very small opening relative to the body of the container.
- the subject of the present invention is therefore a fluid dispenser assembly according to claim 1.
- This particular arrangement thus makes it possible to separate the internal seal from the fluid product to be dispensed and thus to prevent any alteration of the fluid product by contact with the fluid. garnish.
- this invention imparts a particularly aesthetic decorative appearance to the dispensing assembly.
- the barrier envelope is flexible so as to be enterable through the opening of the container and deployable to inside the trim.
- the deformability properties of such an envelope or flexible pouch facilitate its introduction and its deployment in the internal space by insertion into the opening defined by the neck of the outer container. This insertion can thus be performed with the envelope folded or rolled up. Then, this envelope, unfolds so as to occupy substantially all of this internal space.
- Such a flexible pouch is particularly suitable for use with perfume bottles. Indeed, this type of bottle generally has an upper end provided with a shoulder from which extends a neck defining an opening of restricted diameter.
- the barrier envelope can therefore be defined as a reservoir of fluid product perfectly conforming to the internal space defined by the outer container.
- the outer container may be defined as a covering shell of a fluid reservoir.
- a flexible pouch disposed in a rigid outer container or shell is already known from the prior art.
- the pocket then serves as a reservoir without air and without air intake.
- the flexible pouch is used as a barrier to separate the fluid from the liner with which it could interact.
- the barrier envelope extends inside the lining being at least locally out of contact with the lining. This is for example the case of a flexible pouch.
- the liner is flexible and extends at least locally out of contact with the container.
- the liner can thus be mounted floating in an intermediate space between the inner wall of the outer container and the fluid reservoir, which can be rigid or flexible.
- the lining is formed by a coating, such as lacquer or varnish, applied to the inner wall of the container.
- the liner may extend over all or part of the inner wall of the container. Some areas of the inner wall may remain bare.
- said dispensing member is a pump, of the atmospheric or airless type, capable of taking off the fluid contained in said barrier envelope.
- said envelope is vented by an atmospheric pump and / or by a vent passage formed at the neck of the container.
- an atmospheric pump mounted in a flexible envelope and the venting of such a flexible envelope can be implemented and protected independently of the characteristics related to the lining. Indeed, by venting the flexible bag, it is diverted from its primary function, namely to maintain the fluid contained in it out of contact with the ambient air. In this, the venting of a flexible pouch is surprising because it goes against its conventional use. In addition, the venting of the pocket keeps it in its maximum deployed configuration. This avoids the formation of folds and compartments that could trap a portion of the fluid.
- said envelope is directly attached to the opening of the container by wedging between the upper edge of the neck and a seal.
- This arrangement makes it possible to dispense with the use of a specific support to maintain the barrier envelope in position in the outer container.
- the fact of dispensing with such a part has the effect of lowering the overall cost of the dispensing device.
- the assembly of said envelope is facilitated due to the suppression of the ultrasonic welding step of the pocket on its support conventionally implemented with this type of pocket.
- said inner liner is physically or chemically incompatible with the fluid product to be dispensed.
- the fluid product is perfume.
- said opening of the outer container has an internal diameter of between 8 and 20 mm.
- the body of the container may have a diameter much greater than 20mm.
- the fluid dispenser assembly comprises an outer container 1, an inner lining 2, and a barrier envelope 3.
- the outer container 1 is made of a transparent or translucent material, such as material (s) (s) plastic (s) or preferably glass.
- This container 1 comprises a side wall 10 comprising a lower end closed by a bottom 12 and an upper end provided with a neck 13.
- the neck 13 has a restricted cross-sectional dimension relative to the cross-sectional dimension of the side wall 10 and is connected to the side wall 10 by a shoulder 11 preferably substantially radial.
- This neck 13 protrudes upwardly from this shoulder 11 and defines an upper edge 14.
- Such a neck defines an opening communicating the interior of the outer container with the outside. This opening is advantageously of the order of 8 to 20 mm in diameter, this range corresponding to standard neck diameters for perfume-cosmetic bottles.
- the bottom 12, the wall 10, the shoulder 11 and the neck 13 respectively define an inner surface 120, 100, 110, 130. These internal surfaces together define the inner wall of the outer container. This inner wall thus delimits an internal space accessible through the opening of the neck 13.
- outer container may have any suitable configuration such as a cylindrical, spherical, parallelepipedic, cubic configuration etc., the invention is not limited to a particular form.
- the internal linings 2, 2 ' have the particularity of being made of a substantially opaque material.
- This opacity allows a liner to be visible from the outside through the transparent or translucent walls of the container and thus allows a user to clearly distinguish the pattern or shape of the liner from the container as such.
- such an opacity has the advantage of partially or completely masking, according to the degree of distribution of said lining in the container, the barrier envelope 3, 3 ', 3 ", in other words, the barrier envelope 3, 3'. , 3 "will not be visible from the outside where the trim will be provided.
- the barrier envelope 3, 3 ', 3 is intended to receive or be in contact with the fluid to be dispensed, this envelope thus constituting the reservoir of fluid product itself.
- the fluid product contained in this reservoir is a perfume, a cream or a lotion chemically or physically incompatible with the internal lining.
- the figures 1 and 2 represent a flexible or deformable barrier envelope 3.
- This envelope corresponds to a flexible pouch generally encountered in "airless” systems.
- Such flexible bags are foldable and therefore adapted to be inserted through the opening of the neck so as to be placed in the internal space defined by the container 1. They are generally made from a complex aluminum / plastic film.
- This flexible bag has a peripheral wall 30 comprising a lower end closed by a bottom 32 and an upper end provided with a neck 33 defining an opening.
- a substantially radial shoulder 31 makes the junction between the neck 33 and the peripheral wall 30.
- this flexible pouch can be dimensioned so that the bottom 32, the wall 30 and the shoulder 31 come into contact respectively against the internal surfaces of the bottom 12, the wall 10 and the shoulder 11 of the outer container 1.
- the flexible pouch can be filled with fluid.
- An outwardly extending fold may then be formed at the upper end of the neck 33 of this pocket. This fold then forms a radial flange 34 adapted to rest on the upper edge 14 of the neck.
- a seal 5 can then be interposed between this radial flange and a dispensing member 4 to seal the dispenser member to the pocket.
- the dispensing member 4 may be a pump.
- This pump may be of the atmospheric type, that is to say with air intake, or airless type, that is to say without air intake.
- an atmospheric pump is advantageously used so as to keep a substantially constant volume of the bag as the fluid product is dispensed. Indeed, the volume of outgoing fluid product will be substituted by an equivalent volume of air entering.
- the incoming air then generally passes through a vent passage formed in the same pump. Therefore, the flexible pouch will not retract on itself contrary to what is the case when used with an airless pump and therefore will not present folds responsible for trapping fluid product. Otherwise a similar result can be obtained with an airless pump if a venting passage is provided at the neck of the bottle so as to allow atmospheric air to enter said flexible bag.
- an airless pump is used without venting the flexible pouch, the fluid product will be kept out of the air. This isolation of the product thus makes it possible to avoid any microbial contamination or physico-chemical modification of the product contained in the flexible pouch.
- the pump conventionally comprises a body 40 provided at its upper end with a collar 41 intended to bear against the seal 5 and at its lower end with a sleeve for fixing a dip tube 42.
- fixing ring 44 holds the flexible pouch 3, the seal 5 and the dispensing member 4 at the neck of the outer container.
- This ring can be a crimp ring, snap or screw.
- An actuating rod 43 adapted to move by leaktight sliding in the body 40 is provided to cause volume variations of a metering chamber generally delimited by inlet and outlet valves. This rod internally defines an outlet channel for the fluid product contained in the metering chamber. As shown on figures 1 and 2 this actuating rod can be connected to a pusher 45 forming a dispensing orifice 46.
- the dispensing of fluid contained in the flexible bag 3 is done by exerting an axial manual pressure on the pusher.
- the use of an atmospheric pump allows the flexible pouch to keep a constant volume as previously explained.
- each actuation will tend to gradually reduce the volume of the flexible bag 3.
- the barrier envelope 3 'advantageously forms a coating applied to the internal liner 2.
- This coating then forms an overlayer with respect to the inner lining 2 pressed against the inner wall of the container 1.
- the inner wall of the container is completely covered with internal lining and the barrier envelope completely covers the inner liner.
- the lining is locally interrupted, so that the barrier envelope is visible.
- the fluid product contained inside the barrier envelope 3 'can then in no case come into contact with the inner liner 2. It should be noted that such a barrier envelope in the form of a coating can also be applied on a floating mounted internal seal.
- the dispensing member is formed by a plug 4 'provided with an outlet orifice 46.
- This plug can be secured to the outer container by means of snap lugs or a snap ring 47 which is housed under the upper edge 14 of the neck. It is also possible that this plug has a lip selfjoint. In this case, the side wall 10 of the outer container is deformable and the exercise of manual pressure on the wall tends to cause a displacement of the fluid to the lip. This movement of fluid product then generates a crack in the lip which results in a fluid outlet fluid.
- the dispensing assembly comprises a barrier envelope in the form of a rigid reservoir 3 ", advantageously maintained in the container 1 by a support 6.
- the support 6 forms a holster capable of extending inside the internal lining 2 provided in the form of a coating applied to the inner wall of the container 1.
- This holster may comprise a body 60 provided with a lower end closed by a bottom 61 and an upper end defining an opening.
- the upper end may comprise a bearing flange 62 adapted to bear on the upper edge 14 of the neck in the mounting position.
- the bottom 61 of the case can abut against the bottom 120 of the outer container.
- the fastener 7 comprises a radial plate 70 traversed by a substantially central opening.
- An inner skirt 71 and a peripheral skirt 72 extend downwardly from this radial plate.
- the inner skirt may be provided with projections projecting radially inwardly adapted to snap under the upper edge 14 of the neck. This snapping then makes it possible to hold the case 6 in position on the neck by wedging the bearing flange 62 between the upper edge 14 of the neck and a portion of the radial plate 70.
- the skirt Device 72 is placed in the continuity of the side wall 10 of the outer container during the final assembly of the fastener 9 on the neck.
- the rigid reservoir 3 forms an elongate tube that can be received in the case 6 previously positioned in the outer container
- the rigid reservoir 300 may be made of plastic material or advantageously of glass.
- This rigid reservoir comprises a cylindrical shaft 30 provided with a lower end formed by a bottom 32 and an upper end defining an opening. This upper end advantageously comprises a projecting neck 33.
- a plug 4 "provided with an outlet passage 46 can be assembled at the upper end of the tank 3".
- This cap can be secured to the reservoir by means of a fixing ring 8.
- the reservoir 3 can be introduced through the respective openings of the fastener 7 and the case 6 so as to extend to the The final position of the reservoir is reached when the fixing ring 8 bears against the radial plate 70 of the fixing member 7.
- This reservoir can be easily extracted from the holster and thus can be replaceable charging office by the user as soon as its contents are exhausted It should be noted that it is desirable for the reservoir 3 "to conform perfectly to the appearance of the case.
- the reservoir therefore advantageously has a substantially equal or slightly smaller external diameter.
- the inner diameter of the case and the bottom 32 of the reservoir advantageously comes into contact with the bottom 61 of the case in the final position of mounting the reservoir in the case.
- Such a configuration thus makes it possible to have a distribution assembly with a refill having an optimized fluid volume.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
Abstract
Description
La présente invention concerne un ensemble de distribution de produit fluide comprenant un récipient définissant un espace interne, une garniture interne disposée dans l'espace interne et un organe de distribution, tel qu'une pompe, pour distribuer du produit fluide.The present invention relates to a fluid dispenser assembly comprising a container defining an internal space, an inner liner disposed in the inner space and a dispensing member, such as a pump, for dispensing fluid product.
La parfumerie et la cosmétique sont des domaines d'application privilégiés, mais non exclusifs, de la présente invention.Perfumery and cosmetics are preferred but not exclusive fields of application of the present invention.
De nombreux ensembles de distribution de produit fluide ont été développés dans l'art antérieur. Le produit fluide contenu dans de tels ensembles peut par exemple être une lotion, une crème ou un parfum. Ces ensembles apparentés à des produits de luxes nécessitent une apparence particulièrement soignée afin d'attirer le consommateur. Ainsi, les concepteurs de tels ensembles peuvent jouer sur différents paramètres pour mettre en valeur ces ensembles tels que leur forme, leur couleur ou encore leur(s) matériau(x) de conception. Des exemples de réalisation de tels matériaux consistent notamment à positionner une garniture interne dans un réservoir de produit fluide. Cette garniture interne peut par exemple correspondre à des feuillets en plastique pourvus d'inscriptions ou de motifs ornementaux disposés en flottaison dans le réservoir de produit fluide. Ces feuillets, à but décoratif et/ou informatif, peuvent alors être vus par transparence à travers le réservoir de produit fluide, conférant ainsi un aspect esthétique global particulièrement intéressant.Numerous fluid product distribution assemblies have been developed in the prior art. The fluid product contained in such sets may for example be a lotion, a cream or a perfume. These sets related to luxury products require a particularly neat appearance to attract the consumer. Thus, the designers of such sets can play on different parameters to highlight these sets such as their shape, their color or their design material (s). Examples of embodiments of such materials include placing an inner liner in a fluid reservoir. This internal lining may for example correspond to plastic leaflets provided with inscriptions or ornamental patterns arranged in a floatation in the fluid reservoir. These leaflets, decorative and / or informative purpose, can then be seen by transparency through the fluid reservoir, thus giving a particularly attractive overall aesthetic appearance.
Toutefois, des interactions physico-chimiques sont susceptibles de se produire entre le produit fluide et la garniture interne. Ces interactions peuvent alors donner lieu à une modification de la composition physico-chimique du produit fluide à distribuer susceptible d'être à l'origine de modifications de propriétés ou de l'aspect du produit. Par conséquent, ces effets sont particulièrement gênants. Il en résulte donc une grande complexité pour réaliser un ensemble de distribution avec une garniture interne insusceptible d'entamer l'intégrité du produit fluide à distribuer. l'intégrité du produit fluide à distribuer.However, physicochemical interactions are likely to occur between the fluid and the inner liner. These interactions can then give rise to a modification of the physicochemical composition of the fluid product to be distributed that may cause changes in properties or the appearance of the product. Therefore, these effects are particularly troublesome. This therefore results in great complexity to achieve a distribution assembly with an internal liner insusceptible to begin the integrity of the fluid product to be dispensed. the integrity of the fluid product to be dispensed.
Dans l'art antérieur on connaît du document
La présente invention a donc pour but de surmonter les inconvénients précités de l'art antérieur.The present invention therefore aims to overcome the aforementioned drawbacks of the prior art.
En particulier, la présente invention a pour but de fournir un ensemble de distribution pourvu d'une garniture interne insusceptible d'engendrer des modifications physico-chimiques du produit fluide contenu dans le réservoir.In particular, the present invention aims to provide a dispensing assembly provided with an internal liner insusceptible to generate physico-chemical changes of the fluid contained in the reservoir.
La présente invention a encore pour but de fournir un ensemble de distribution présentant une physionomie particulièrement originale et attrayante.The present invention also aims to provide a dispensing assembly having a particularly original and attractive physiognomy.
La présente invention a également pour but de fournir un ensemble de distribution qui soit simple à fabriquer et à assembler et présentant un coût de revient peu élevé.The present invention also aims to provide a dispensing assembly that is simple to manufacture and assemble and having a low cost.
Un autre but de la présente invention est d'assurer l'intégrité du produit fluide à distribuer même lorsque le récipient présente une ouverture très réduite par rapport au corps du récipient.Another object of the present invention is to ensure the integrity of the fluid to be dispensed even when the container has a very small opening relative to the body of the container.
La présente invention a donc pour objet un ensemble de distribution de produit fluide d'aprés la revendication 1. Cette disposition particulière permet ainsi de séparer la garniture interne du produit fluide à distribuer et ainsi d'éviter toute altération du produit fluide par contact avec la garniture. En outre, cette invention confère un aspect décoratif particulièrement esthétique à l'ensemble de distribution.The subject of the present invention is therefore a fluid dispenser assembly according to
L'enveloppe barrière est souple de manière à être introduisible à travers l'ouverture du récipient et déployable à l'intérieur de la garniture. Les propriétés de déformabilité d'une telle enveloppe ou poche souple permettent de faciliter son introduction et son déploiement dans l'espace interne par insertion dans l'ouverture définie par le col du récipient externe. Cette insertion peut ainsi être réalisée avec l'enveloppe pliée ou enroulée. Ensuite, cette enveloppe, se déplie de manière à occuper sensiblement la totalité de cet espace interne. Une telle poche souple est en particulier parfaitement adaptée à une utilisation avec des flacons de parfum. En effet, ce type de flacon comporte généralement une extrémité supérieure pourvue d'un épaulement à partir duquel s'étend un col définissant une ouverture de diamètre restreint. Donc si le réservoir est formé par une poche souple, ladite poche pourra se déplier de manière à s'étendre jusque sous cet épaulement afin de faire en sorte que le volume occupé par le produit fluide soit maximal par rapport à l'espace interne défini par le récipient externe. L'utilisation d'une telle poche permet ainsi de ne pas tromper l'acheteur d'un tel flacon sur la quantité de produit fluide présente dans le récipient externe. Selon cet exemple de réalisation, l'enveloppe barrière peut donc être définie comme un réservoir de produit fluide se conformant parfaitement à l'espace interne défini par le récipient externe. Le récipient externe peut être quant à lui défini comme une coque d'habillage d'un réservoir de produit fluide.The barrier envelope is flexible so as to be enterable through the opening of the container and deployable to inside the trim. The deformability properties of such an envelope or flexible pouch facilitate its introduction and its deployment in the internal space by insertion into the opening defined by the neck of the outer container. This insertion can thus be performed with the envelope folded or rolled up. Then, this envelope, unfolds so as to occupy substantially all of this internal space. Such a flexible pouch is particularly suitable for use with perfume bottles. Indeed, this type of bottle generally has an upper end provided with a shoulder from which extends a neck defining an opening of restricted diameter. So if the reservoir is formed by a flexible pouch, said pouch can unfold so as to extend to below this shoulder in order to ensure that the volume occupied by the fluid product is maximum relative to the internal space defined by the outer container. The use of such a pocket thus makes it possible not to mislead the buyer of such a bottle on the amount of fluid present in the outer container. According to this exemplary embodiment, the barrier envelope can therefore be defined as a reservoir of fluid product perfectly conforming to the internal space defined by the outer container. The outer container may be defined as a covering shell of a fluid reservoir.
L'utilisation d'une poche souple disposée dans un récipient ou coque externe rigide est déjà connue de l'art antérieur. La poche sert alors de réservoir sans air et sans reprise d'air. Dans la présente invention, on se sert de la poche souple comme barrière pour séparer le produit fluide de la garniture avec laquelle il pourrait interagir.The use of a flexible pouch disposed in a rigid outer container or shell is already known from the prior art. The pocket then serves as a reservoir without air and without air intake. In the present invention, the flexible pouch is used as a barrier to separate the fluid from the liner with which it could interact.
Selon une autre caractéristique, l'enveloppe barrière s'étend à l'intérieur de la garniture en étant au moins localement hors de contact de la garniture. C'est par exemple le cas d'une poche souple.According to another characteristic, the barrier envelope extends inside the lining being at least locally out of contact with the lining. This is for example the case of a flexible pouch.
Avantageusement, la garniture est souple et s'étend au moins localement hors de contact du récipient. La garniture peut ainsi être montée flottante dans un espace intermédiaire situé entre la paroi interne du récipient externe et le réservoir de produit fluide, qui peut être rigide ou souple.Advantageously, the liner is flexible and extends at least locally out of contact with the container. The liner can thus be mounted floating in an intermediate space between the inner wall of the outer container and the fluid reservoir, which can be rigid or flexible.
La garniture est formée par un revêtement, tel qu'une laque ou un vernis, appliqué sur la paroi interne du récipient. La garniture peut s'étendre sur toute ou partie de la paroi interne du récipient. Certaines zones de la paroi interne peuvent rester nues.The lining is formed by a coating, such as lacquer or varnish, applied to the inner wall of the container. The liner may extend over all or part of the inner wall of the container. Some areas of the inner wall may remain bare.
Avantageusement, ledit organe de distribution est une pompe, du type atmosphérique ou airless, apte à prélever du produit fluide contenu dans ladite enveloppe barrière. Avantageusement, ladite enveloppe est éventée par une pompe atmosphérique et/ou par un passage d'évent ménagé au niveau du col du récipient.Advantageously, said dispensing member is a pump, of the atmospheric or airless type, capable of taking off the fluid contained in said barrier envelope. Advantageously, said envelope is vented by an atmospheric pump and / or by a vent passage formed at the neck of the container.
Il est à noter que l'utilisation d'une pompe atmosphérique montée dans une enveloppe souple ainsi que l'éventation d'une telle enveloppe souple peuvent être mises en oeuvre et protégées indépendamment des caractéristiques liées à la garniture. En effet, en éventant la poche souple, on la détourne de sa fonction première, à savoir celle de maintenir le produit fluide qu'elle contient hors de contact de l'air ambiant. En cela, l'éventation d'une poche souple est surprenante, car elle va à l'encontre de son utilisation conventionnelle. De plus, l'éventation de la poche permet de la maintenir dans sa configuration déployée maximale. On évite ainsi la formation de plis et de compartiments qui pourraient piéger une partie du produit fluide.It should be noted that the use of an atmospheric pump mounted in a flexible envelope and the venting of such a flexible envelope can be implemented and protected independently of the characteristics related to the lining. Indeed, by venting the flexible bag, it is diverted from its primary function, namely to maintain the fluid contained in it out of contact with the ambient air. In this, the venting of a flexible pouch is surprising because it goes against its conventional use. In addition, the venting of the pocket keeps it in its maximum deployed configuration. This avoids the formation of folds and compartments that could trap a portion of the fluid.
Avantageusement, ladite enveloppe est directement fixée sur l'ouverture du récipient par coincement entre le bord supérieur du col et un joint. Cette disposition permet de se dispenser de l'utilisation d'un support spécifique pour maintenir l'enveloppe barrière en position dans le récipient externe. Le fait de se dispenser d'une telle pièce a bien entendu pour effet d'abaisser le coût de revient d'ensemble du dispositif de distribution. De plus, l'assemblage de ladite enveloppe est facilité du fait de la suppression de l'étape de soudage par ultrason de la poche sur son support classiquement mise en oeuvre avec ce type de poche. En outre, on peut utiliser une pompe de diamètre supérieur, car on libère de la place dans l'ouverture du récipient du fait de l'absence d'un support de poche qui entoure normalement la pompe.Advantageously, said envelope is directly attached to the opening of the container by wedging between the upper edge of the neck and a seal. This arrangement makes it possible to dispense with the use of a specific support to maintain the barrier envelope in position in the outer container. The fact of dispensing with such a part has the effect of lowering the overall cost of the dispensing device. In addition, the assembly of said envelope is facilitated due to the suppression of the ultrasonic welding step of the pocket on its support conventionally implemented with this type of pocket. In addition, it is possible to use a pump of larger diameter, because there is room in the opening of the container because of the absence of a pocket support which normally surrounds the pump.
Avantageusement, ladite garniture interne est physiquement ou chimiquement incompatible avec le produit fluide à distribuer.Advantageously, said inner liner is physically or chemically incompatible with the fluid product to be dispensed.
Avantageusement, le produit fluide est du parfum.Advantageously, the fluid product is perfume.
Avantageusement, ladite ouverture du récipient externe présente un diamètre interne compris entre 8 et 20 mm. Le corps du récipient peut présenter un diamètre largement supérieur à 20mm.Advantageously, said opening of the outer container has an internal diameter of between 8 and 20 mm. The body of the container may have a diameter much greater than 20mm.
L'invention sera maintenant plus amplement décrite en référence aux dessins joints donnant, à titre d'exemples non limitatifs, plusieurs modes de réalisation de l'invention et sur lesquels :
- la
figure 1 est une vue schématique en section transversale d'un ensemble de distribution selon un premier mode de réalisation de l'invention, - la
figure 2 est une vue schématique en section transversale d'un ensemble de distribution selon un non couvert par mode de réalisation l'invention, - la
figure 3 est une vue schématique en section transversale d'un ensemble de distribution selon un non couvert par mode de réalisation l'invention, - la
figure 4 est une vue schématique en section transversale d'un ensemble de distribution selon un non couvert par mode de réalisation l'invention.
- the
figure 1 is a schematic cross-sectional view of a distribution assembly according to a first embodiment of the invention, - the
figure 2 is a schematic cross-sectional view of a dispensing assembly according to a non-covered embodiment of the invention, - the
figure 3 is a schematic cross-sectional view of a dispensing assembly according to a non-covered embodiment of the invention, - the
figure 4 is a schematic cross-sectional view of a dispensing assembly according to a non-covered embodiment of the invention.
En référence aux figures, l'ensemble de distribution de produit fluide selon l'invention comprend un récipient externe 1, une garniture interne 2, et une enveloppe barrière 3.With reference to the figures, the fluid dispenser assembly according to the invention comprises an
Le récipient externe 1 est réalisé en un matériau transparent ou translucide, tel qu'en matériau(x) plastique(s) ou de préférence en verre. Ce récipient 1 comporte une paroi latérale 10 comprenant une extrémité inférieure fermée par un fond 12 et une extrémité supérieure pourvue d'un col 13. Le col 13 présente une dimension en section transversale restreinte par rapport à la dimension en section transversale de la paroi latérale 10 et est relié à la paroi latérale 10 par un épaulement 11 de préférence sensiblement radial. Ce col 13 fait saillie vers le haut à partir de cet épaulement 11 et définit un bord supérieur 14. Un tel col définit une ouverture faisant communiquer l'intérieur du récipient externe avec l'extérieur. Cette ouverture est avantageusement de l'ordre de 8 à 20 mm de diamètre, cette gamme correspondant à des diamètres de col standard pour des flacons en parfumerie-cosmétique.The
Le fond 12, la paroi 10, l'épaulement 11 et le col 13 définissent respectivement une surface interne 120, 100, 110, 130. Ces surfaces internes définissent ensemble la paroi interne du récipient externe. Cette paroi interne délimite ainsi un espace interne accessible par l'ouverture du col 13.The bottom 12, the
Il est à noter que le récipient externe peut présenter toutes configurations appropriées telle qu'une configuration cylindrique, sphérique, parallélépipédique, cubique etc., l'invention n'étant pas limitée à une forme particulière.It should be noted that the outer container may have any suitable configuration such as a cylindrical, spherical, parallelepipedic, cubic configuration etc., the invention is not limited to a particular form.
Deux modes de réalisation de la garniture interne 2, 2' ont été représentés sur les figures.
- Les
figures 1 ,3 représentent une garnitureet 4interne 2 sous forme de couche ou de revêtement tapissant la paroi interne du récipientexterne 1. Avantageusement, ce revêtement est une laque, une peinture ou un vernis de finition appliqué sur la totalité ou seulement une partie de la paroi interne du récipient. Cette laque, cette peinture ou ce vernis peuvent par exemple être appliqué au moyen d'une buse de pulvérisation introduite dans l'ouverture définiepar le col 13 du récipient. - La
figure 2 représente une garniture interne 2' non couverte par l'invention montée lâche ou flottante dans l'espace interne du récipient externe. Cette garniture peut par exemple se présenter sous forme de feuillets réalisés en matériau plastique. Ces feuillets peuvent alors être fixés au niveau du bord supérieur 14 du col par thermosoudage ou par coincement. La garniture peut aussi être totalement flottante sans fixation au récipient.
- The
figures 1 ,3 and 4 represent aninternal lining 2 in the form of a layer or coating lining the inner wall of theouter container 1. Advantageously, this coating is a lacquer, a paint or a finishing varnish applied to all or only a portion of the inner wall of the container . This lacquer, this paint or this varnish may for example be applied by means of a spray nozzle introduced into the opening defined by theneck 13 of the container. - The
figure 2 represents an internal lining 2 'not covered by the invention mounted loose or floating in the internal space of the outer container. This lining may for example be in the form of sheets made of plastic material. These leaflets can then be fixed at theupper edge 14 of the neck by heat sealing or by wedging. The lining can also be totally floating without attachment to the container.
Il est à souligner que les garnitures internes 2, 2' ont pour particularité d'être réalisées en un matériau sensiblement opaque. Cette opacité permet à une garniture d'être visible de l'extérieur à travers les parois transparentes ou translucides du récipient et permet ainsi à un utilisateur de clairement distinguer le tracé ou la forme de cette garniture par rapport au récipient en tant que tel. En outre, une telle opacité a pour avantage de masquer partiellement ou totalement, selon le degré de répartition de ladite garniture dans le récipient, l'enveloppe barrière 3, 3', 3". Autrement dit, l'enveloppe barrière 3, 3', 3" ne sera pas visible de l'extérieur aux endroits où la garniture sera prévue.It should be noted that the
Trois modes de réalisation de l'enveloppe barrière vont maintenant être décrits. L'enveloppe barrière 3, 3', 3" est destinée à accueillir ou être en contact avec le produit fluide à distribuer. Cette enveloppe constitue ainsi le réservoir de produit fluide à proprement parlé. Avantageusement, le produit fluide contenu dans ce réservoir est un parfum, une crème ou une lotion chimiquement ou physiquement incompatible avec la garniture interne.Three embodiments of the barrier envelope will now be described. The
Les
Cette poche souple comporte une paroi périphérique 30 comprenant une extrémité inférieure obturée par un fond 32 et une extrémité supérieure pourvue d'un col 33 définissant une ouverture. Un épaulement 31 sensiblement radial fait la jonction entre le col 33 et la paroi périphérique 30.This flexible bag has a
Le fond 32, la paroi 30 et l'épaulement 31, une fois introduits dans l'espace interne du récipient 1, se déploient de préférence de manière à occuper sensiblement la totalité de cet espace interne. Ainsi, cette poche souple peut être dimensionnée de sorte que le fond 32, la paroi 30 et l'épaulement 31 viennent en contact respectivement contre les surfaces internes du fond 12, de la paroi 10 et de l'épaulement 11 du récipient externe 1.The bottom 32, the
Une fois la poche souple en place, la poche souple peut être remplie de produit fluide. Un repli s'étendant vers l'extérieur peut alors être formé au niveau de l'extrémité supérieure du col 33 de cette poche. Ce repli forme alors une bride radiale 34 apte à reposer sur le bord supérieur 14 du col. Un joint d'étanchéité 5 peut ensuite être interposé entre cette bride radiale et un organe de distribution 4 pour fixer de manière étanche l'organe de distribution à la poche.Once the flexible pouch is in place, the flexible pouch can be filled with fluid. An outwardly extending fold may then be formed at the upper end of the
L'organe de distribution 4 peut être une pompe. Cette pompe peut être du type atmosphérique, c'est-à-dire avec reprise d'air, ou de type airless, c'est-à-dire sans reprise d'air. Il est à noter qu'une pompe atmosphérique est avantageusement utilisée de manière à garder un volume sensiblement constant de la poche au fur et à mesure de la distribution du produit fluide. En effet, le volume de produit fluide sortant sera substitué par un volume équivalent d'air entrant. L'air entrant passe alors généralement par un passage d'évent ménagé à même la pompe. Par conséquent, la poche souple ne se rétractera pas sur elle-même contrairement à ce qui est le cas lors d'une utilisation avec une pompe airless et donc ne présentera pas de plissements responsables de piégeage de produit fluide. Autrement un résultat similaire peut être obtenu avec une pompe airless si un passage d'éventation est prévu au niveau du col du flacon de manière à laisser l'air atmosphérique pénétrer dans ladite poche souple. Enfin, si une pompe airless est utilisée sans éventation de la poche souple, le produit fluide sera maintenu à l'abri de l'air. Cet isolement du produit permet ainsi d'éviter toute contamination microbienne ou modification physico-chimique du produit contenu dans la poche souple.The dispensing
La pompe comporte de manière classique un corps 40 pourvu à son extrémité supérieure d'une collerette 41 destinée à venir en appui sur le joint d'étanchéité 5 et à son extrémité inférieure d'un manchon de fixation d'un tube plongeur 42. Une bague de fixation 44 maintient la poche souple 3, le joint d'étanchéité 5 et l'organe de distribution 4 au niveau du col du récipient externe. Cette bague peut être une bague à sertir, à encliqueter ou à visser. Une tige d'actionnement 43 apte à se déplacer par coulissement étanche dans le corps 40 est prévu afin d'entraîner des variations de volume d'une chambre de dosage généralement délimité par des clapets d'entrée et de sortie. Cette tige définit intérieurement un canal de sortie pour le produit fluide contenu dans la chambre de dosage. Comme représenté sur les
Selon ce mode de réalisation particulier, la distribution de produit fluide contenu dans la poche souple 3 se fait en exerçant une pression manuelle axiale sur le poussoir. L'utilisation d'une pompe atmosphérique permet à la poche souple de garder un volume constant comme précédemment expliqué. Au contraire, lorsqu'une pompe airless est mise en oeuvre, chaque actionnement aura tendance à progressivement diminuer le volume de la poche souple 3.According to this particular embodiment, the dispensing of fluid contained in the
Selon un mode de réalisation non couvert par l'invention illustrée sur la
Dans ce mode de réalisation de la
Selon un mode de réalisation non couvert par l'invention représenté sur la
Le support 6 forme un étui apte à s'étendre à l'intérieur de la garniture interne 2 prévue sous forme de revêtement appliqué sur la paroi interne du récipient 1. Cet étui peut comporter un corps 60 pourvu d'une extrémité inférieure obturée par un fond 61 et d'une extrémité supérieure définissant une ouverture. L'extrémité supérieure peut comprendre une bride d'appui 62 apte à venir en appui sur le bord supérieur 14 du col en position de montage. Il est à noter qu'il est souhaitable que le corps cylindrique présente un diamètre externe sensiblement égal ou légèrement inférieur au diamètre interne du col 13 de manière à ce que le remplissage de l'espace interne par l'étui soit optimale. De même, le fond 61 de l'étui peut venir en butée contre le fond 120 du récipient externe.The
Cet étui peut être maintenu en place sur le col 13 du récipient au moyen d'un organe de fixation 7. L'organe de fixation 7 comporte un plateau radial 70 traversé par une ouverture sensiblement centrale. Une jupe interne 71 et une jupe périphérique 72 s'étendent vers le bas à partir de ce plateau radial. La jupe interne peut être pourvue de projections faisant saillie radialement vers l'intérieur aptes à s'encliqueter sous le bord supérieur 14 du col. Cet encliquetage permet alors de maintenir l'étui 6 en position sur le col en coinçant la bride d'appui 62 entre le bord supérieur 14 du col et une partie du plateau radiale 70. D'autre part, il peut être prévu que la jupe périphérique 72 se place dans la continuité de la paroi latérale 10 du récipient externe lors de l'assemblage finale de l'organe de fixation 9 sur le col.This case can be held in place on the
Le réservoir rigide 3" forme un tube allongé apte à être reçu dans l'étui 6 préalablement positionné dans le récipient externe. Le réservoir rigide 300" peut être réalisé en matériau plastique ou avantageusement en verre. Ce réservoir rigide comporte un fût cylindrique 30 pourvu d'une extrémité inférieure formée par un fond 32 et d'une extrémité supérieure définissant une ouverture. Cette extrémité supérieure comporte avantageusement un col saillant 33. Par ailleurs, un bouchon 4" muni d'un passage de sortie 46 peut être assemblé au niveau de l'extrémité supérieure du réservoir 3". Ce bouchon peut être solidarisé au réservoir au moyen d'une bague de fixation 8. Le réservoir 3" peut être introduit à travers les ouvertures respectives de l'organe de fixation 7 et de l'étui 6 de manière à s'étendre à l'intérieur de l'étui. La position finale du réservoir est atteinte lorsque la bague de fixation 8 vient en appui contre le plateau radial 70 de l'organe de fixation 7. Ce réservoir peut être facilement extrait de l'étui et ainsi peut faire office de recharge remplaçable à souhait par l'utilisateur dès épuisement de son contenu. Il est à noter qu'il est souhaitable que le réservoir 3" se conforme parfaitement à la physionomie de l'étui. Le réservoir présente donc avantageusement un diamètre externe sensiblement égal ou légèrement inférieur au diamètre interne de l'étui et le fond 32 du réservoir vient avantageusement en contact du fond 61 de l'étui en position finale de montage du réservoir dans l'étui. Une telle configuration permet ainsi d'avoir un ensemble de distribution avec une recharge présentant un volume de produit fluide optimisé.The
Bien que la présente invention ait été décrite en référence à des exemples particuliers, l'homme du métier pourrait y apporter toutes modifications utiles sans sortir du cadre de la présente invention défini par les revendications annexées.Although the present invention has been described with reference to particular examples, those skilled in the art could make any useful modifications without departing from the scope of the present invention defined by the appended claims.
Claims (8)
- A fluid dispenser assembly comprising:. an outer receptacle (1) including an opening, said receptacle including an inside wall defining an inside space, said receptacle (1) being made of a transparent or translucent material, such as glass, the receptacle (1) containing a fluid;. internal trim (2) disposed in the inside space, the internal trim (2) being visible through the receptacle (1);. a dispenser member (4; 4'; 4"), such as a pump, for dispensing the fluid; and. a barrier envelope (3) for containing the fluid, said envelope being disposed inside the internal trim (2) so that the fluid is not in contact with said internal trim (2), the internal trim (2) being opaque so as to mask at least some, and preferably all, of said barrier envelope (3), the barrier envelope (3) is flexible, in such a manner as to be insertable through the opening in the receptacle (1) and deployable inside the trim (2),the assembly being characterized in that the trim (2) is formed by a coating, such as a lacquer or a varnish, that is applied to the inside wall of the receptacle (1).
- A dispenser assembly according to claim 1, in which the barrier envelope (3) extends inside the trim (2), and, at least locally, it is not in contact with the trim (2).
- A dispenser assembly according to claim 1 or claim 2, in which said envelope (3) is fastened directly onto the opening in the receptacle (1) by pinching it between the top edge (14) of the neck and a gasket (5).
- A dispenser assembly according to any preceding claim, in which said internal trim (2) is physically or chemically incompatible with the fluid to be dispensed.
- A dispenser assembly according to any preceding claim, in which the fluid is perfume.
- A dispenser assembly according to any preceding claim, in which said opening in the outer receptacle (1) presents an inside diameter that lies in the range 8 mm to 20 mm.
- A dispenser assembly according to any preceding claim, in which said dispenser member (4) is a pump, of the atmospheric or airless type, that is suitable for taking the fluid contained in said barrier envelope (3).
- A dispenser assembly according to any preceding claim, in which said envelope (3) is vented by an atmospheric pump and/or by a vent hole formed in the neck (13) of the receptacle (1).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR0452844A FR2878835B1 (en) | 2004-12-02 | 2004-12-02 | FLUID PRODUCT DISPENSING ASSEMBLY |
PCT/FR2005/051023 WO2006059046A2 (en) | 2004-12-02 | 2005-12-01 | Fluid product dispensing assembly |
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EP1838588A2 EP1838588A2 (en) | 2007-10-03 |
EP1838588B1 true EP1838588B1 (en) | 2010-09-15 |
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EP05824240A Active EP1838588B1 (en) | 2004-12-02 | 2005-12-01 | Fluid product dispensing assembly |
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EP (1) | EP1838588B1 (en) |
DE (1) | DE602005023660D1 (en) |
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-
2004
- 2004-12-02 FR FR0452844A patent/FR2878835B1/en active Active
-
2005
- 2005-12-01 DE DE602005023660T patent/DE602005023660D1/en active Active
- 2005-12-01 ES ES05824240T patent/ES2349596T3/en active Active
- 2005-12-01 WO PCT/FR2005/051023 patent/WO2006059046A2/en active Application Filing
- 2005-12-01 EP EP05824240A patent/EP1838588B1/en active Active
- 2005-12-01 US US11/791,743 patent/US8074839B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
WO2006059046A3 (en) | 2007-02-15 |
WO2006059046A2 (en) | 2006-06-08 |
ES2349596T3 (en) | 2011-01-05 |
FR2878835B1 (en) | 2008-07-04 |
US8074839B2 (en) | 2011-12-13 |
FR2878835A1 (en) | 2006-06-09 |
EP1838588A2 (en) | 2007-10-03 |
DE602005023660D1 (en) | 2010-10-28 |
US20080011778A1 (en) | 2008-01-17 |
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