EP1789732B1 - Refrigeration circuit and method for operating a refrigeration circuit - Google Patents

Refrigeration circuit and method for operating a refrigeration circuit Download PDF

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Publication number
EP1789732B1
EP1789732B1 EP05775838A EP05775838A EP1789732B1 EP 1789732 B1 EP1789732 B1 EP 1789732B1 EP 05775838 A EP05775838 A EP 05775838A EP 05775838 A EP05775838 A EP 05775838A EP 1789732 B1 EP1789732 B1 EP 1789732B1
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EP
European Patent Office
Prior art keywords
line
refrigerant
collecting container
refrigeration circuit
compressor unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP05775838A
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German (de)
French (fr)
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EP1789732A1 (en
Inventor
Bernd Heinbokel
Andreas Gernemann
Uwe Schierhorn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carrier Kaeltetechnik Deutschland GmbH
Original Assignee
Linde Kaeltetechnik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102004038640A external-priority patent/DE102004038640A1/en
Priority to DK07020311.2T priority Critical patent/DK1895246T6/en
Priority to EP10167202.0A priority patent/EP2244040B1/en
Priority to EP07020311.2A priority patent/EP1895246B3/en
Priority to EP10181303.8A priority patent/EP2264385B1/en
Priority to DK10181303.8T priority patent/DK2264385T3/en
Application filed by Linde Kaeltetechnik GmbH filed Critical Linde Kaeltetechnik GmbH
Priority to DK10167202T priority patent/DK2244040T3/en
Publication of EP1789732A1 publication Critical patent/EP1789732A1/en
Publication of EP1789732B1 publication Critical patent/EP1789732B1/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B1/00Compression machines, plants or systems with non-reversible cycle
    • F25B1/10Compression machines, plants or systems with non-reversible cycle with multi-stage compression
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B40/00Subcoolers, desuperheaters or superheaters
    • F25B40/06Superheaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B41/00Fluid-circulation arrangements
    • F25B41/20Disposition of valves, e.g. of on-off valves or flow control valves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00Gas cycle refrigeration machines
    • F25B2309/06Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • F25B2309/061Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/07Details of compressors or related parts
    • F25B2400/075Details of compressors or related parts with parallel compressors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/13Economisers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/22Refrigeration systems for supermarkets
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
    • F25B2400/23Separators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B40/00Subcoolers, desuperheaters or superheaters
    • F25B40/02Subcoolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B40/00Subcoolers, desuperheaters or superheaters
    • F25B40/04Desuperheaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B49/00Arrangement or mounting of control or safety devices
    • F25B49/02Arrangement or mounting of control or safety devices for compression type machines, plants or systems
    • F25B49/022Compressor control arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B5/00Compression machines, plants or systems, with several evaporator circuits, e.g. for varying refrigerating capacity
    • F25B5/02Compression machines, plants or systems, with several evaporator circuits, e.g. for varying refrigerating capacity arranged in parallel

Definitions

  • the invention relates to a refrigeration cycle in which a one- or multi-component refrigerant circulates, comprising in the flow direction a condenser, a collecting container, an expansion device upstream of an evaporator, an evaporator and a single-stage compressing compressor unit.
  • the invention relates to a method for operating a refrigeration cycle.
  • liquefier should be understood to mean both liquefier and gas cooler.
  • Composite refrigerators generally supply a large number of refrigeration consumers, such as refrigerators, refrigerators and freezers. For this purpose circulates in them a one- or multi-component refrigerant or refrigerant mixture.
  • a counting of the prior art refrigeration cycle or a refrigeration system in which such a refrigeration cycle is realized, is based on the in the FIG. 1 illustrated embodiment explained in more detail.
  • condenser or gas cooler A - hereinafter referred to only as a condenser, which is usually outside the supermarket, for example, on the roof, by heat exchange, preferably against outside air condensed.
  • the liquid refrigerant from the condenser A is fed via line B to a (refrigerant) collector C.
  • a (refrigerant) collector C Within a refrigeration cycle always so much refrigerant must be present that even with maximum cooling demand, the evaporator of all refrigeration consumers can be filled. However, with lower cooling requirements individual evaporators are only partially filled or even completely empty, the excess refrigerant must be collected during these times in the designated collector C.
  • the refrigerant passes through the liquid line D to the cold consumers of the so-called normal cooling circuit.
  • the in the FIG. 1 represented consumers F and F 'for any number of consumers of the normal refrigeration cycle.
  • Each of the aforementioned refrigeration consumers is preceded by an expansion valve E or E ', in which the refrigerant flowing into the refrigeration appliance or the evaporator or the evaporator of the refrigeration consumer is expanded.
  • the so-relaxed refrigerant is evaporated in the evaporators of the refrigerant consumers F and F 'and thus cools the corresponding refrigeration cabinets and rooms.
  • the refrigerant evaporated in the refrigeration consumers F and F 'of the normal refrigeration cycle is then fed via the suction line G to the compressor unit H and compressed therein to the desired pressure between 10 and 25 bar.
  • the compressor unit H is designed to be single-stage and has several compressors connected in parallel.
  • the compressed in the compressor unit H refrigerant is then fed via the pressure line I in turn to the aforementioned condenser A.
  • a second liquid line D ' is the condenser C refrigerant supplied to the condenser K and evaporated in this heat exchange with the refrigerant of the still to be explained Tiefkühlniklaufes before it is fed via the line G' of the compressor unit H.
  • the liquefied in the condenser K refrigerant of the freezing circuit is supplied via line L to the collector M of the freezing circuit.
  • the refrigerant to the consumer P - this is for any number of consumers -, which is preceded by a relaxation device O, supplied and evaporated in this.
  • the evaporated refrigerant is fed to the single or multi-stage compressor unit R, in this to a pressure compressed between 25 and 40 bar and then fed via the pressure line S to the aforementioned capacitor K.
  • R 404A As a refrigerant of the normal refrigeration cycle, for example, R 404A is used, while for the freezing cycle carbon dioxide is used.
  • compressor units H and R, the collector C and M and the capacitor K are usually arranged in a separate machine room.
  • about 80 to 90% of the entire pipeline network is located in the sales rooms, the storage areas or other areas of a supermarket accessible to employees and customers.
  • this line network operates at pressures of no more than 35 to 40 bar, this is acceptable to the supermarket operators both from a psychological point of view and for cost reasons.
  • a method for operating a compression refrigeration system with the working fluid carbon dioxide with a two-stage throttling and division of the circulating working fluid flow is known.
  • the working medium mass flow is passed after the first throttle stage in a subcritical working medium pressure collector, which in the lower part of the medium pressure separator collecting, larger liquid Hästoffmassestromanteil supplied to the evaporator, the separating in the upper part of the medium pressure separating, smaller vapor Häffenmassestromanteil a second throttle level close to the Evaporating pressure relaxes.
  • the smaller vapor mass of the working medium mass used by evaporation and overheating serves to subcool the supercritical high-pressure gas. After evaporation and overheating, the smaller working medium mass fraction is mixed in a collecting tube integrated in the evaporator with the outlet of the evaporator strands.
  • a refrigeration cycle comprising a compressor, which comprises a Hochlichsaugeingang and a Niedrigdrucksaugeingang with a condenser, with a collecting container, the liquid refrigerant in its lower part and gaseous refrigerant in its upper part, with a line which the liquid refrigerant of the Capacitor to the Sump leads, with a pressure reducing valve in this line, with a high-pressure cooler, with a line leading from the lower part of the sump to the radiator, with a line leading from the radiator to the upper part of the sump, with a line, which leads from the upper part of the collecting container to the high-pressure inlet of the compressor, with a low-pressure radiator, with a line leading from the lower part of the collecting container to the low-pressure radiator, with a pressure reducing valve in this line and with a line coming from the low-pressure radiator the low pressure suction inlet of the compressor leads.
  • the EP 0 180 904 B1 discloses a cooling device with a multi-cylinder piston compressor, which also includes a subcooler for the refrigerant liquid in the line between the condenser and expansion element.
  • Object of the present invention is to provide a generic refrigeration cycle and a method for operating a refrigeration cycle, which avoids the disadvantages mentioned.
  • a refrigeration cycle which is characterized in that between the condenser and the collecting container, an intermediate-expansion device is arranged.
  • inventive refrigeration cycle the inventive method for operating a refrigeration cycle and other embodiments thereof are described below with reference to in the FIGS. 2 to 5 shown embodiments explained in more detail.
  • FIG. 2 a composite refrigeration system in which a possible embodiment of the refrigeration cycle according to the invention is realized.
  • a procedure is described in which as a refrigerant HFC (s), HFC (s) or CO 2 can be used.
  • the compressed in the compressor unit 6 to a pressure between 10 and 120 bar refrigerant is supplied via the pressure line 7 to the condenser or gas cooler 1 and condensed in this against outside air or deprived.
  • the refrigerant is supplied to the refrigerant collector 3, but now it is relaxed according to the invention in the intermediate expansion device a to an intermediate pressure of 5 to 40.
  • This intermediate relaxation offers the advantage that the downstream line network and the collector 3 only to a lower Pressure must be designed.
  • the pressure to which the refrigerant is expanded in the mentioned intermediate relaxation device a is hereby preferably selected so that it is still below the lowest expected condensing pressure.
  • the pressure line 7 with the collecting container 3, preferably with the gas space, connected or connectable can take place, for example, via a connecting line 17, in which an expansion valve h is arranged.
  • the pressure line 7 is connected or connectable to the line or line sections 2 or 2 ', 2 "connecting the condenser 1 and the collection container 3.
  • the collecting container 3 preferably the gas space, connected to the input of the compressor unit 6 or connectable.
  • This connection between the collecting container 3 and the input of the compressor unit 6 can, for example, via a connecting line 12, as in the FIG. 2 shown, in the suction line 11 opens, done.
  • the selected intermediate pressure can now be kept constant for all operating conditions.
  • a scheme such that a constant difference value to the suction pressure exists. This ensures that the throttle steam fraction at the evaporators is comparatively small, with the result that the liquid and suction lines can be dimensioned correspondingly smaller.
  • This also applies to the condensate line, since now no gaseous components have to flow through them back into the condenser 1.
  • a portion of the withdrawn from the collector 3 via line 4 refrigerant is fed via line 8 to one or more frozen consumers - represented by the heat exchanger E4 -, which is also preceded by an expansion valve d supplied.
  • this partial refrigerant flow is fed via the suction line 9 to the compressor unit 10 and compressed therein to the inlet pressure of the compressor unit 6.
  • the thus compressed refrigerant partial stream is then fed via line 11 to the input side of the compressor unit 6.
  • the invention further, it is proposed that - as in the FIG. 2 represented - the collecting container 3, a heat exchanger E1 can be connected upstream.
  • the heat exchanger E1 is preferably connected on the input side to the output of the condenser 1 or connectable.
  • a partial flow of the liquefied or desiccant refrigerant can now be withdrawn from the condenser or gas cooler 1 or line 2 via line 13, in which an expansion valve f is provided, and in the heat exchanger E1 against the heat exchanger E1 to be heated via line 2 'supplied refrigerant to be evaporated.
  • the vaporized refrigerant partial stream is then fed via line 14 to a compressor 6 ', which is associated with the above-described compressor unit 6 and which preferably sucks at a higher pressure level, and in this compressed to the desired final pressure of the compressor unit 6.
  • the refrigerant stream to be expanded in the intermediate expansion device a is preferably cooled to such an extent that the throttled vapor portion of the expanded refrigerant is minimized.
  • the resulting in the collector 3 throttle steam fractions can be sucked off via the line 12 and the dashed line 15 by means of the compressor 6 'at a higher pressure level.
  • FIG. 3 1 shows an embodiment of the refrigeration cycle according to the invention or of the method according to the invention for operating a refrigeration cycle, in which the refrigerant drawn off from the collecting container 3 via the line 4 is subjected to supercooling in the heat exchanger E5.
  • the supercooling - according to an advantageous embodiment of the invention - in heat exchange with the withdrawn from the reservoir 3 via line 12 flash gas.
  • Liquid lines such as those in the Figures 2 and 3 shown line 4, with a temperature level below the ambient temperature are exposed to heat radiation. This has the consequence that the refrigerant flowing inside the liquid line partially evaporates, thus resulting in the formation of undesirable vapor contents. To prevent this, refrigerant so far either by an expansion of a partial flow of the refrigerant and subsequent evaporation or by an internal heat transfer against a suction gas stream, which is thereby overheated, subcooled.
  • the temperature interval between the suction and liquid line or the circulating refrigerant therein may be too low to realize an internal heat transfer for the required supercooling of the refrigerant flowing in the liquid line.
  • the invention further developing is therefore-as already mentioned - proposed to cool the withdrawn from the sump 3 via line 4 refrigerant in the heat exchanger or subcooler E5 against the relaxed from the sump 3 via line 12 and in the valve e flash gas.
  • the expanded refrigerant which has been overheated in the heat exchanger E5 is fed via the line sections 12 'and 11 to the inlet of the compressor unit 6.
  • the above described method thus has the additional advantage that the reliability of the compressor or compressor unit 6 is increased due to a safe overheating of the flash gas stream.
  • FIG. 4 shows a further, embodiment of the refrigeration cycle according to the invention or the inventive method for operating a refrigeration cycle.
  • the FIG. 4 only a section of the in the FIG. 2 and 3 illustrated refrigeration circuit according to the invention shown.
  • the method according to the invention for operating a refrigeration cycle further develops that at least a partial flow of the flash gas withdrawn from the collecting container is at least temporarily overheated against at least a partial flow of the compressed refrigerant.
  • FIG. 4 shows a possible embodiment of the method according to the invention, in which at least temporarily a partial flow of the withdrawn from the reservoir 3 via line 12 flash gas via line 16 to a heat exchanger E6 and superheated in this against the compressed in the compressor unit 6 refrigerant.
  • the flash gas stream After passing through the heat exchanger superheater E6, the flash gas stream is fed via line 16 'to the inlet of the compressor 6' of the compressor unit 6.

Abstract

Refrigerant is circulated in a predetermined flow direction comprised of a heat-rejecting heat exchanger (4), intermediate throttle valve (6), receiver (8), evaporator throttle valves (10), evaporator (14), compressor (20) and flash gas tapping line (26). The flash gas tapping line is connected to the receiver and to the compressor. An independent claim is also included for a refrigeration circuit operating method.

Description

Die Erfindung betrifft einen Kältekreislauf, in dem ein ein- oder mehrkomponentiges Kältemittel zirkuliert, aufweisend in Strömungsrichtung einen Verflüssiger, einen Sammelbehälter, eine, einem Verdampfer vorgeschaltete Entspannungsvorrichtung, einen Verdampfer und eine einstufig verdichtende Verdichtereinheit.The invention relates to a refrigeration cycle in which a one- or multi-component refrigerant circulates, comprising in the flow direction a condenser, a collecting container, an expansion device upstream of an evaporator, an evaporator and a single-stage compressing compressor unit.

Ferner betrifft die Erfindung ein Verfahren zum Betreiben eines Kältekreislaufes.Furthermore, the invention relates to a method for operating a refrigeration cycle.

Unter dem Begriff "Verflüssiger" seien sowohl Verflüssiger als auch Gaskühler zu verstehen.The term "liquefier" should be understood to mean both liquefier and gas cooler.

Gattungsgemäße Kältekreisläufe sind hinlänglich bekannt. Sie werden beispielsweise in Kälteanlagen, so genannten Verbundkälteanlagen, wie sie in Supermärkten zur Anwendung kommen, realisiert. Verbundkälteanlagen versorgen dort im Allgemeinen eine Vielzahl von Kälteverbrauchern, wie etwa Kühlräume, Kühl- und Tiefkühlmöbel. Zu diesem Zweck zirkuliert in ihnen ein ein- oder mehrkomponentiges Kältemittel bzw. Kältemittelgemisch.Generic refrigeration cycles are well known. They are for example in refrigeration systems, so-called composite refrigeration systems, such as those used in supermarkets, implemented. Composite refrigerators generally supply a large number of refrigeration consumers, such as refrigerators, refrigerators and freezers. For this purpose circulates in them a one- or multi-component refrigerant or refrigerant mixture.

Ein zum Stand der Technik zählender Kältekreislauf bzw. eine Kälteanlage, in der ein derartiger Kältekreislauf realisiert wird, sei anhand des in der Figur 1 dargestellten Ausführungsbeispieles näher erläutert.A counting of the prior art refrigeration cycle or a refrigeration system in which such a refrigeration cycle is realized, is based on the in the FIG. 1 illustrated embodiment explained in more detail.

Das in dem Kältekreislauf zirkulierende ein- oder mehrkomponentige Kältemittel wird in einem Verflüssiger bzw. Gaskühler A - nachfolgend nurmehr als Verflüssiger bezeichnet-, der im Regelfall außerhalb des Supermarktes, beispielsweise auf dessen Dach, angeordnet ist, durch Wärmetausch, vorzugsweise gegen Außenluft, kondensiert.The circulating in the refrigeration cycle one- or multi-component refrigerant is condensed in a condenser or gas cooler A - hereinafter referred to only as a condenser, which is usually outside the supermarket, for example, on the roof, by heat exchange, preferably against outside air condensed.

Das flüssige Kältemittel aus dem Verflüssiger A wird über Leitung B einem (Kältemittel)Sammler C zugeführt. Innerhalb eines Kältekreislaufes muss immer soviel Kältemittel vorhanden sein, dass auch bei maximalem Kältebedarf die Verdampfer aller Kälteverbraucher gefüllt werden können. Da jedoch bei niedrigerem Kältebedarf einzelne Verdampfer nur teilweise gefüllt oder sogar vollständig leer sind, muss das überschüssige Kältemittel während dieser Zeiten in dem dafür vorgesehenen Sammler C aufgefangen werden.The liquid refrigerant from the condenser A is fed via line B to a (refrigerant) collector C. Within a refrigeration cycle always so much refrigerant must be present that even with maximum cooling demand, the evaporator of all refrigeration consumers can be filled. However, with lower cooling requirements individual evaporators are only partially filled or even completely empty, the excess refrigerant must be collected during these times in the designated collector C.

Aus dem Sammler C gelangt das Kältemittel über die Flüssigkeitsleitung D zu den Kälteverbrauchern des so genannten Normalkühlkreislaufes. Hierbei stehen die in der Figur 1 dargestellten Verbraucher F und F' für eine beliebige Anzahl von Verbrauchern des Normalkühlkreislaufes. Jedem der vorgenannten Kälteverbraucher ist ein Expansionsventil E bzw. E' vorgeschaltet, in welchem das in den Kälteverbraucher bzw. den oder die Verdampfer des Kälteverbrauchers strömende Kältemittel entspannt wird. Das so entspannte Kältemittel wird in den Verdampfern der Kältemittelverbraucher F und F' verdampft und kühlt so die entsprechenden Kühlmöbel und -räume.From the collector C, the refrigerant passes through the liquid line D to the cold consumers of the so-called normal cooling circuit. Here are the in the FIG. 1 represented consumers F and F 'for any number of consumers of the normal refrigeration cycle. Each of the aforementioned refrigeration consumers is preceded by an expansion valve E or E ', in which the refrigerant flowing into the refrigeration appliance or the evaporator or the evaporator of the refrigeration consumer is expanded. The so-relaxed refrigerant is evaporated in the evaporators of the refrigerant consumers F and F 'and thus cools the corresponding refrigeration cabinets and rooms.

Das in den Kälteverbrauchern F und F' des Normalkühlkreislaufes verdampfte Kältemittel wird anschließend über die Saugleitung G der Verdichtereinheit H zugeführt und in dieser auf den gewünschten Druck zwischen 10 und 25 bar verdichtet. Im Regelfall ist die Verdichtereinheit H lediglich einstufig ausgebildet und weist mehrere parallel geschaltete Verdichter auf.The refrigerant evaporated in the refrigeration consumers F and F 'of the normal refrigeration cycle is then fed via the suction line G to the compressor unit H and compressed therein to the desired pressure between 10 and 25 bar. As a rule, the compressor unit H is designed to be single-stage and has several compressors connected in parallel.

Das in der Verdichtereinheit H verdichtete Kältemittel wird anschließend über die Druckleitung I wiederum dem bereits erwähnten Verflüssiger A zugeführt.The compressed in the compressor unit H refrigerant is then fed via the pressure line I in turn to the aforementioned condenser A.

Über eine zweite Flüssigkeitsleitung D' wird aus dem Sammler C Kältemittel dem Kondensator K zugeführt und in diesem im Wärmetausch gegen das Kältemittel des noch zu erläuternden Tiefkühlkreislaufes verdampft, bevor es über die Leitung G' der Verdichtereinheit H zugeführt wird.Via a second liquid line D 'is the condenser C refrigerant supplied to the condenser K and evaporated in this heat exchange with the refrigerant of the still to be explained Tiefkühlkreislaufes before it is fed via the line G' of the compressor unit H.

Das in dem Kondensator K verflüssigte Kältemittel des Tiefkühlkreislaufes wird über Leitung L dem Sammler M des Tiefkühlkreislaufes zugeführt. Aus diesem wird über die Leitung N das Kältemittel dem Verbraucher P - dieser steht für eine beliebige Anzahl von Verbrauchern -, dem eine Entspannungsvorrichtung O vorgeschaltet ist, zugeführt und in diesem verdampft. Über die Saugleitung Q_wird das verdampfte Kältemittel der ein- oder mehrstufigen Verdichtereinheit R zugeführt, in dieser auf einen Druck zwischen 25 und 40 bar verdichtet und anschließend über die Druckleitung S dem bereits erwähnten Kondensator K zugeführt.The liquefied in the condenser K refrigerant of the freezing circuit is supplied via line L to the collector M of the freezing circuit. For this, via the line N, the refrigerant to the consumer P - this is for any number of consumers -, which is preceded by a relaxation device O, supplied and evaporated in this. Via the suction line Q_ the evaporated refrigerant is fed to the single or multi-stage compressor unit R, in this to a pressure compressed between 25 and 40 bar and then fed via the pressure line S to the aforementioned capacitor K.

Als Kältemittel des Normalkühlkreislaufes wird beispielsweise R 404A verwendet, während für den Tiefkühlkreislauf Kohlendioxid zur Anwendung kommt.As a refrigerant of the normal refrigeration cycle, for example, R 404A is used, while for the freezing cycle carbon dioxide is used.

Die in der Figur 1 dargestellten Verdichtereinheiten H und R, die Sammler C und M sowie der Kondensator K sind im Regelfall in einem separaten Maschinenraum angeordnet. Etwa 80 bis 90 % des gesamten Leitungsnetzes sind jedoch in den Verkaufsräumen, den Lagerräumen bzw. anderen für Mitarbeiter und Kunden zugänglichen Räumen eines Supermarktes angeordnet. Solange in diesem Leitungsnetz mit Drücken von nicht mehr als 35 bis 40 bar gearbeitet wird, ist dies für die Supermarktbetreiber sowohl aus psychologischer Sicht als auch aus Kostengründen akzeptabel.The in the FIG. 1 shown compressor units H and R, the collector C and M and the capacitor K are usually arranged in a separate machine room. However, about 80 to 90% of the entire pipeline network is located in the sales rooms, the storage areas or other areas of a supermarket accessible to employees and customers. As long as this line network operates at pressures of no more than 35 to 40 bar, this is acceptable to the supermarket operators both from a psychological point of view and for cost reasons.

Derzeit wird dazu übergegangen, auch den vorbeschriebenen Normalkühlkreislauf mit dem Kältemittel CO2 zu betreiben.Currently, it is going to operate even the above-described normal cooling circuit with the refrigerant CO 2 .

Der sinnvolle Einsatz des natürlichen Kältemittels CO2 in der Gewerbekälte scheitert bisher zum einen an der unzureichenden energetischen Effizienz des einfachen, einstufigen Kreisprozesses bei hohen (Außen)Lufttemperaturen. Zum anderen sind aufgrund der Stoffeigenschaften von CO2 hohe Arbeitsdrücke - bis zu 100 bar und darüber - erforderlich, die eine Fertigung von entsprechenden Kältekreisläufen bzw. Kälteanlagen aus ökonomischen Gründen enorm erschweren. Kommerziell wird das Kältemittel CO2 daher bisher nur bei Kaskadensystemen in der Tiefkühlung verwendet - wie dies beispielhaft anhand der Figur 1 erläutert ist -, da die dort realisierten Arbeitsdrücke die übliche, maximale Drucklage von 40 bar nicht überschreiten.The sensible use of the natural refrigerant CO 2 in commercial refrigeration fails on the one hand due to the insufficient energetic efficiency of the simple, single-stage cycle at high (outside) air temperatures. On the other hand, owing to the material properties of CO 2, high working pressures - up to 100 bar and above - are required, which make it extremely difficult to manufacture corresponding refrigeration circuits or refrigeration plants for economic reasons. Commercially, the refrigerant CO 2 is therefore so far only used in cascade systems in the freezing - as exemplified by the FIG. 1 is explained - since the working pressures realized there do not exceed the usual maximum pressure of 40 bar.

Aufgrund der vorerwähnten höheren Drücke bzw. Drucklage muss das Rohrleitungsnetz des Kältekreislaufes auf diese Drücke bzw. Drucklage ausgelegt werden. Die hierfür erforderlichen Materialien sind jedoch weitaus teurer als diejenigen, die bei den bisher realisierten Drucklagen zur Anwendung kommen können. Darüber hinaus sind derartige, vergleichsweise hohe Drucklagen jedoch auch den Anlagenbetreibern nur sehr schwer zu vermitteln.Due to the above-mentioned higher pressures or pressure, the pipe network of the refrigeration cycle must be designed for these pressures or pressure. However, the materials required for this are far more expensive than those that can be used in the previously implemented printing layers. In addition, however, such relatively high pressure levels are also very difficult to convey to plant operators.

Aus P. Ostertag: Kälteprozesse dargestellt mit Hilfe der Entropietafel, Berlin, Verlag von Julius Springer, 1933, XP-001169097, Seiten 39 bis 43 , ist ein Kältekreislauf mit einer zweistufigen Drosselung bekannt. Dabei werden zwei Regulierventile hintereinander geschaltet, zwischen welchen ein Abscheider sitzt. Im ersten Ventil wird auf einen Zwischendruck gedrosselt und der dabei entstehende Dampf ausgeschieden, das zweite Ventil empfängt nur noch den flüssig gebliebenen Teil des Kältemittels, der zum Verdampfer fließt und von da zum Kompressor. Sein Zylinder ist nach Art der Gleichstromdampfmaschine mit Schlitzen versehen, die sich in der Mitte des Mantels befinden und die mit dem Abscheider verbunden sind. Gibt der Kolben diese Schlitze nach Durchlaufen seines Nutzhubes frei, so kann der im Abscheider angesammelte Dampf in den Zylinder einfallen.Out P. Ostertag: cooling processes represented using the Entropietafel, Berlin, published by Julius Springer, 1933, XP-001169097, pages 39 to 43 , a refrigeration cycle with a two-stage throttling is known. In this case, two regulating valves are connected in series, between which a separator sits. In the first valve is throttled to an intermediate pressure and the resulting vapor excreted, the second valve receives only the liquid remained part of the refrigerant flowing to the evaporator and thence to the compressor. Its cylinder is provided in the manner of the DC steam engine with slots, which are located in the middle of the shell and which are connected to the separator. If the piston frees these slots after passing through its useful stroke, the accumulated in the separator steam can fall into the cylinder.

Aus der DE 195 22 884 A1 ist ein Verfahren zum Betrieb einer Kompressionskälteanlage mit dem Arbeitsmittel Kohlendioxid mit einer zweistufigen Drosselung und Teilung des umlaufenden Arbeitsmittelstromes bekannt. Dabei wird der Arbeitsmittelmassestrom nach der ersten Drosselstufe in einen unterkritisch arbeitenden Mitteldruckabscheidesammler geleitet, der sich im unteren Teil des Mitteldruckabscheidesammler separierende, größere flüssige Arbeitsmittelmassestromanteil dem Verdampfer zugeführt, der im oberen Teil des Mitteldruckabscheiders separierende, kleinere dampfförmige Arbeitsmittelmassestromanteil über eine zweite Drosselstufe bis nahe über den Verdampfungsdruck entspannt. In einem inneren Wärmeübertrager dient der kleinere dampfförmige Arbeitsmittelmassestromanteil durch Verdampfung und Überhitzung zur Unterkühlung des überkritischen Hochdruckgases. Nach der Verdampfung und Überhitzung wird der kleinere Arbeitsmittelmassestromanteil in einem im Verdampfer integrierten Sammelrohr mit den Ausgängen der Verdampferstränge gemischt.From the DE 195 22 884 A1 a method for operating a compression refrigeration system with the working fluid carbon dioxide with a two-stage throttling and division of the circulating working fluid flow is known. In this case, the working medium mass flow is passed after the first throttle stage in a subcritical working medium pressure collector, which in the lower part of the medium pressure separator collecting, larger liquid Arbeitsmittelmassestromanteil supplied to the evaporator, the separating in the upper part of the medium pressure separating, smaller vapor Arbeitsmittelmassestromanteil a second throttle level close to the Evaporating pressure relaxes. In an internal heat exchanger, the smaller vapor mass of the working medium mass used by evaporation and overheating serves to subcool the supercritical high-pressure gas. After evaporation and overheating, the smaller working medium mass fraction is mixed in a collecting tube integrated in the evaporator with the outlet of the evaporator strands.

Aus der US 933 682 ist ein Kältekreislauf bekannt, mit einem Kompressor, der einen Hochdrucksaugeingang und einen Niedrigdrucksaugeingang umfasst, mit einem Kondensator, mit einem Sammelbehälter, der flüssiges Kältemittel in seinem unteren Teil und gasförmiges Kältemittel in seinem oberen Teil beinhaltet, mit einer Leitung die das flüssige Kältemittel von dem Kondensator zu dem Sammelbehälter führt, mit einem Druckreduzierungsventil in dieser Leitung, mit einem Hochdruckkühler, mit einer Leitung, die von dem unteren Teil des Sammelbehälters zu dem Kühler führt, mit einer Leitung, die von dem Kühler zu dem oberen Teil des Sammelbehälters führt, mit einer Leitung, die von dem oberen Teil des Sammelbehälters zu dem Hochdruckeingang des Kompressors führt, mit einem Niedrigdruckkühler, mit einer Leitung, die von dem unteren Teil des Sammelbehälters zu dem Niedrigdruckkühler führt, mit einem Druckreduzierungsventil in dieser Leitung und mit einer Leitung, die von dem Niedrigdruckkühler zu dem Niedrigdrucksaugeingang des Kompressors führt.From the US 933 682 a refrigeration cycle is known, comprising a compressor, which comprises a Hochdrucksaugeingang and a Niedrigdrucksaugeingang with a condenser, with a collecting container, the liquid refrigerant in its lower part and gaseous refrigerant in its upper part, with a line which the liquid refrigerant of the Capacitor to the Sump leads, with a pressure reducing valve in this line, with a high-pressure cooler, with a line leading from the lower part of the sump to the radiator, with a line leading from the radiator to the upper part of the sump, with a line, which leads from the upper part of the collecting container to the high-pressure inlet of the compressor, with a low-pressure radiator, with a line leading from the lower part of the collecting container to the low-pressure radiator, with a pressure reducing valve in this line and with a line coming from the low-pressure radiator the low pressure suction inlet of the compressor leads.

Die EP 0 180 904 B1 offenbart eine Kühlvorrichtung mit einem mehrere Zylinder aufweisenden Kolbenverdichter, die auch einen Unterkühler für die Kälteflüssigkeit in der Leitung zwischen Verflüssiger und Expansionsorgan umfasst.The EP 0 180 904 B1 discloses a cooling device with a multi-cylinder piston compressor, which also includes a subcooler for the refrigerant liquid in the line between the condenser and expansion element.

Ein weiteres Problem besteht insbesondere bei der Verwendung von CO2 als Kältemittel darin, dass bei entsprechend hohen Außentemperaturen ein überkritischer Betrieb des Kältekreislaufes erforderlich wird. Hohe Außenlufttemperaturen haben zur Folge, dass am Verdampfereintritt vergleichsweise hohe Drosseldampfanteile auftreten. Dadurch wird die effektive volumetrische Kälteleistung des zirkulierenden Kältemittels verringert, jedoch müssen sowohl Saug- als auch Flüssigkeitsleitungen sowie die Verdampfer entsprechend größer dimensioniert werden, um die Druckverluste so niedrig wie möglich zu halten.Another problem is especially when using CO 2 as a refrigerant in that at high ambient temperatures, a supercritical operation of the refrigeration cycle is required. High outside air temperatures have the consequence that at the evaporator inlet comparatively high throttle vapor components occur. This reduces the effective volumetric cooling capacity of the circulating refrigerant, however, both suction and liquid lines and the evaporators must be sized accordingly larger to keep the pressure losses as low as possible.

Aufgabe der vorliegenden Erfindung ist es, einen gattungsgemäßen Kältekreislauf sowie ein Verfahren zum Betreiben eines Kältekreislaufes anzugeben, der bzw. das die genannten Nachteile vermeidet.Object of the present invention is to provide a generic refrigeration cycle and a method for operating a refrigeration cycle, which avoids the disadvantages mentioned.

Zur Lösung dieser Aufgabe wird ein Kältekreislauf vorgeschlagen, der sich dadurch auszeichnet, dass zwischen dem Verflüssiger und dem Sammelbehälter eine Zwischen-Entspannungsvorrichtung angeordnet ist.To solve this problem, a refrigeration cycle is proposed, which is characterized in that between the condenser and the collecting container, an intermediate-expansion device is arranged.

Verfahrensseitg wird die gestellte Aufgabe dadurch gelöst, dass in der zwischen dem Verflüssiger und dem Sammelbehälter angeordneten Zwischen-Entspanriungsvorrichtung eine Entspannung des Kältemittels auf einen (Zwischen)Druck von 5 bis 40 bar erfolgt.Verfahrensseitg the task is achieved in that takes place in the intermediate between the condenser and the collecting intermediate Entspanriungsvorrichtung a relaxation of the refrigerant to an (intermediate) pressure of 5 to 40 bar.

Der erfindungsgemäße Kältekreislauf, das erfindungsgemäße Verfahren zum Betreiben eines Kältekreislaufes sowie weitere Ausgestaltungen desselben seien nachfolgend anhand der in den Figuren 2 bis 5 gezeigten Ausführungsbeispiele näher erläutert.The inventive refrigeration cycle, the inventive method for operating a refrigeration cycle and other embodiments thereof are described below with reference to in the FIGS. 2 to 5 shown embodiments explained in more detail.

Hierbei zeigt die Figur 2 eine Verbundkälteanlage, in der eine mögliche Ausgestaltung des erfindungsgemäßen Kältekreislaufes realisiert ist. Im Folgenden sei eine Verfahrensweise beschrieben, bei der als Kältemittel HFKW(s), FKW(s) oder CO2 zur Anwendung kommen kann.This shows the FIG. 2 a composite refrigeration system in which a possible embodiment of the refrigeration cycle according to the invention is realized. In the following, a procedure is described in which as a refrigerant HFC (s), HFC (s) or CO 2 can be used.

Das in der Verdichtereinheit 6 auf einem Druck zwischen 10 und 120 bar verdichtete Kältemittel wird über die Druckleitung 7 dem Verflüssiger bzw. Gaskühler 1 zugeführt und in diesem gegen Außenluft kondensiert bzw. enthitzt. Über die Leitungen 2, 2' und 2" wird das Kältemittel dem Kältemittelsammler 3 zugeführt, wobei es nunmehr jedoch erfindungsgemäß in der Zwischen-Entspannungsvorrichtung a auf einen Zwischendruck von 5 bis 40 bar entspannt wird. Diese Zwischenentspannung bietet den Vorteil, dass das nachgeschaltete Leitungsnetz sowie der Sammler 3 nurmehr auf eine niedrigere Drucklage ausgelegt sein müssen.The compressed in the compressor unit 6 to a pressure between 10 and 120 bar refrigerant is supplied via the pressure line 7 to the condenser or gas cooler 1 and condensed in this against outside air or deprived. About the lines 2, 2 'and 2 ", the refrigerant is supplied to the refrigerant collector 3, but now it is relaxed according to the invention in the intermediate expansion device a to an intermediate pressure of 5 to 40. This intermediate relaxation offers the advantage that the downstream line network and the collector 3 only to a lower Pressure must be designed.

Der Druck, auf den das Kältemittel in der erwähnten Zwischen-Entspannungsvorrichtung a entspannt wird, wird hierbei vorzugsweise so gewählt, dass er noch unterhalb des niedrigsten zu erwartenden Verflüssigungsdruckes liegt.The pressure to which the refrigerant is expanded in the mentioned intermediate relaxation device a, is hereby preferably selected so that it is still below the lowest expected condensing pressure.

Gemäß einer vorteilhaften Ausgestaltung des erfindungsgemäßen Kältekreislaufes ist die Druckleitung 7 mit dem Sammelbehälter 3, vorzugsweise mit dessen Gasraum, verbunden bzw. verbindbar. Diese Verbindung zwischen Druckleitung 7 und dem Sammelbehälter 3 kann beispielsweise über eine Verbindungsleitung 17, in der ein Entspannungsventil h angeordnet ist, erfolgen.According to an advantageous embodiment of the refrigeration cycle according to the invention, the pressure line 7 with the collecting container 3, preferably with the gas space, connected or connectable. This connection between the pressure line 7 and the collecting container 3 can take place, for example, via a connecting line 17, in which an expansion valve h is arranged.

Gemäß einer vorteilhaften Ausgestaltung des erfindungsgemäßen Kältekreislaufes ist die Druckleitung 7 mit der den Verflüssiger 1 und den Sammelbehälter 3 verbindenden Leitung bzw. Leitungsabschnitte 2 bzw. 2', 2" verbunden bzw. verbindbar. Diese Verbindung zwischen der Druckleitung 7 und der Leitung 2 bzw. 2', 2" kann beispielsweise über die gestrichelt dargestellte Verbindungsleitung 18, in der ein Ventil j angeordnet ist, erfolgen.According to an advantageous embodiment of the refrigeration cycle according to the invention, the pressure line 7 is connected or connectable to the line or line sections 2 or 2 ', 2 "connecting the condenser 1 and the collection container 3. This connection between the pressure line 7 and the line 2 or 2 ', 2 ", for example, via the dashed lines shown connecting line 18, in which a valve j is arranged, take place.

Gemäß einer vorteilhaften Ausgestaltung des erfindungsgemäßen Kältekreislaufes ist der Sammelbehälter 3, vorzugsweise dessen Gasraum, mit dem Eingang der Verdichtereinheit 6 verbunden bzw. verbindbar.According to an advantageous embodiment of the refrigeration cycle according to the invention the collecting container 3, preferably the gas space, connected to the input of the compressor unit 6 or connectable.

Diese Verbindung zwischen Sammelbehälter 3 und Eingang der Verdichtereinheit 6 kann beispielsweise über eine Verbindungsleitung 12, die wie in der Figur 2 dargestellt, in die Saugleitung 11 mündet, erfolgen.This connection between the collecting container 3 and the input of the compressor unit 6 can, for example, via a connecting line 12, as in the FIG. 2 shown, in the suction line 11 opens, done.

Über das in der Leitung 12 vorgesehene Entspannungsventil e und das in der Leitung 17 vorgesehene Entspannungsventil h oder das in der Leitung 18 vorgesehene Ventil j kann der gewählte Zwischendruck nunmehr für alle Betriebsbedingungen konstant gehalten werden. Möglich ist jedoch auch eine Regelung dergestalt, dass ein konstanter Differenzwert zum Saugdruck besteht. Dadurch wird erreicht, dass der Drosseldampfanteil an den Verdampfern vergleichsweise klein ist, was zur Folge hat, dass die Flüssigkeits- und Saugleitungen entsprechend kleiner dimensioniert werden können. Dies gilt auch für die Kondensatleitung, da nunmehr keine gasförmigen Bestandteile über sie zurück in den Verflüssiger 1 strömen müssen. Mittels der Erfindung wird somit auch erreicht, dass sich die erforderliche Kältemittelfüllmenge um bis zu ca. 30 % reduzieren lässt.By way of the expansion valve e provided in the line 12 and the expansion valve h provided in the line 17 or the valve j provided in the line 18, the selected intermediate pressure can now be kept constant for all operating conditions. However, it is also possible a scheme such that a constant difference value to the suction pressure exists. This ensures that the throttle steam fraction at the evaporators is comparatively small, with the result that the liquid and suction lines can be dimensioned correspondingly smaller. This also applies to the condensate line, since now no gaseous components have to flow through them back into the condenser 1. By means of the invention is thus also achieved that can be reduced by up to about 30%, the required refrigerant charge.

Über die Saugleitung 4 wird Kältemittel aus dem Sammler 3 abgezogen und den Kältemittelverbrauchem bzw. deren Wärmetauscher E2 und E3 zugeführt. Diesen vorgeschaltet ist jeweils ein Entspannungsventil b bzw. c, in denen das in die Kälteverbraucher strömende Kältemittel entspannt wird. Das in den Kälteverbrauchern E2 und E3 verdampfte Kältemittel wird anschließend über die Saugleitung 5 wiederum der Verdichtereinheit 6 zugeführt bzw. durch diese aus den Verdampfern E2 und E3 gesaugt.Via the suction line 4 refrigerant is withdrawn from the collector 3 and fed to the Kältemittelverbrauchem or their heat exchanger E2 and E3. This is preceded by a respective expansion valve b and c, in which the refrigerant flowing into the refrigeration consumer is expanded. The refrigerant evaporated in the refrigeration consumers E2 and E3 is then fed back to the compressor unit 6 via the suction line 5 or sucked out of the evaporators E2 and E3 by the latter.

Ein Teil des aus dem Sammler 3 über Leitung 4 abgezogenen Kältemittels wird über Leitung 8 einem oder mehreren Tiefkühlverbrauchern - dargestellt durch den Wärmetauscher E4 -, dem ebenfalls ein Entspannungsventil d vorgeschaltet ist, zugeführt. Dieser Kältemittelteilstrom wird nach der Verdampfung im Wärmetauscher bzw. Kälteverbraucher E4 über die Saugleitung 9 der Verdichtereinheit 10 zugeführt und in dieser auf den Eingangsdruck der Verdichtereinheit 6 verdichtet. Der so verdichtete Kältemittelteilstrom wird anschließend über Leitung 11 der Eingangsseite der Verdichtereinheit 6 zugeführt.A portion of the withdrawn from the collector 3 via line 4 refrigerant is fed via line 8 to one or more frozen consumers - represented by the heat exchanger E4 -, which is also preceded by an expansion valve d supplied. After the evaporation in the heat exchanger or cold consumer E4, this partial refrigerant flow is fed via the suction line 9 to the compressor unit 10 and compressed therein to the inlet pressure of the compressor unit 6. The thus compressed refrigerant partial stream is then fed via line 11 to the input side of the compressor unit 6.

Die Erfindung weiterbildend wird vorgeschlagen, dass - wie in der Figur 2 dargestellt - dem Sammelbehälter 3 ein Wärmeübertrager E1 vorgeschaltet sein kann.The invention further, it is proposed that - as in the FIG. 2 represented - the collecting container 3, a heat exchanger E1 can be connected upstream.

Hierbei ist der Wärmeübertrager E1 vorzugsweise eingangsseitig mit dem Ausgang des Verflüssigers 1 verbunden oder verbindbar.Here, the heat exchanger E1 is preferably connected on the input side to the output of the condenser 1 or connectable.

Wie in der Figur 2 dargestellt, kann nunmehr über Leitung 13, in der ein Entspannungsventil f vorgesehen ist, ein Teilstrom des verflüssigten bzw. enthitzen Kältemittels aus dem Verflüssiger bzw. Gaskühler 1 bzw. der Leitung 2 abgezogen und in dem Wärmeübertrager E1 gegen das zu enthitzende, dem Wärmeübertrager E1 über Leitung 2' zugeführte Kältemittel verdampft werden. Der verdampfte Kältemittelteilstrom wird anschließend über Leitung 14 einem Verdichter 6', der der vorbeschriebenen Verdichtereinheit 6 zugeordnet ist und der vorzugsweise auf einem höheren Druckniveau ansaugt, zugeführt und in diesem auf den gewünschten Enddruck der Verdichtereinheit 6 verdichtet werden.Like in the FIG. 2 a partial flow of the liquefied or desiccant refrigerant can now be withdrawn from the condenser or gas cooler 1 or line 2 via line 13, in which an expansion valve f is provided, and in the heat exchanger E1 against the heat exchanger E1 to be heated via line 2 'supplied refrigerant to be evaporated. The vaporized refrigerant partial stream is then fed via line 14 to a compressor 6 ', which is associated with the above-described compressor unit 6 and which preferably sucks at a higher pressure level, and in this compressed to the desired final pressure of the compressor unit 6.

Alternativ zu dem vorerwähnten (zusätzlichen) Verdichter 6' kann bei der Verwendung mehrylindrischerer Verdichter auch eine Zuführung des abzusaugenden Drosseldampfanteiles auf einem höheren Druckniveau zu einem oder mehreren Zylindern eines jeden Verdichters erfolgen.As an alternative to the above-mentioned (additional) compressor 6 'can be carried out at a higher pressure level to one or more cylinders of each compressor when using mehrylindrischerer compressor also a supply of the sucked throttled vapor portion.

Mittels des Wärmeübertragers E1 wird der in der Zwischen-Entspannungsvorrichtung a zu entspannende Kältemittelstrom vorzugsweise soweit abgekühlt, dass der Drosseldampfanteil des entspannten Kältemittels minimiert wird.By means of the heat exchanger E1, the refrigerant stream to be expanded in the intermediate expansion device a is preferably cooled to such an extent that the throttled vapor portion of the expanded refrigerant is minimized.

Alternativ oder zusätzlich können die im Sammler 3 anfallenden Drosseldampfanteile auch über die Leitung 12 sowie die gestrichelt gezeichnete Leitung 15 mittels des Verdichters 6' auf einem höheren Druckniveau abgesaugt werden.Alternatively or additionally, the resulting in the collector 3 throttle steam fractions can be sucked off via the line 12 and the dashed line 15 by means of the compressor 6 'at a higher pressure level.

In der Figur 3 dargestellt ist eine Ausführungsform des erfindungsgemäßen Kältekreislaufes bzw. des erfindungsgemäßen Verfahrens zum Betreiben eines Kältekreislaufes, bei dem das aus dem Sammelbehälter 3 über die Leitung 4 abgezogene Kältemittel im Wärmetauscher E5 einer Unterkühlung unterworfen wird.In the FIG. 3 1 shows an embodiment of the refrigeration cycle according to the invention or of the method according to the invention for operating a refrigeration cycle, in which the refrigerant drawn off from the collecting container 3 via the line 4 is subjected to supercooling in the heat exchanger E5.

Hierbei erfolgt die Unterkühlung - entsprechend einer vorteilhaften Ausgestaltung der Erfindung - im Wärmetausch mit dem aus dem Sammelbehälter 3 über Leitung 12 abgezogenen Flashgas.Here, the supercooling - according to an advantageous embodiment of the invention - in heat exchange with the withdrawn from the reservoir 3 via line 12 flash gas.

Flüssigkeitsleitungen, wie beispielsweise die in den Figuren 2 und 3 dargestellte Leitung 4, mit einem Temperaturniveau unterhalb der Umgebungstemperatur sind einer Wärmeeinstrahlung ausgesetzt. Diese hat zur Folge, dass das innerhalb der Flüssigkeitsleitung strömende Kältemittel teilweise verdampft, es somit zur Bildung von unerwünschten Dampfanteilen kommt. Um dies zu verhindern, werden Kältemittel bisher entweder durch eine Expansion eines Teilstromes des Kältemittels und anschließender Verdampfung oder durch einen inneren Wärmeübergang gegen einen Sauggasstrom, welches dabei überhitzt wird, unterkühlt.Liquid lines, such as those in the Figures 2 and 3 shown line 4, with a temperature level below the ambient temperature are exposed to heat radiation. This has the consequence that the refrigerant flowing inside the liquid line partially evaporates, thus resulting in the formation of undesirable vapor contents. To prevent this, refrigerant so far either by an expansion of a partial flow of the refrigerant and subsequent evaporation or by an internal heat transfer against a suction gas stream, which is thereby overheated, subcooled.

Bei dem erfindungsgemäßen Kältekreislauf bzw. der erfindungsgemäßen Verfahrensweise kann der Temperaturabstand zwischen Saug- und Flüssigkeitsleitung bzw. des darin zirkulierenden Kältemittels unter Umständen zu gering sein, um eine innere Wärmeübertragung für die erforderliche Unterkühlung des in der Flüssigkeitsleitung strömenden Kältemittels zu realisieren.In the refrigeration cycle according to the invention or the procedure according to the invention, the temperature interval between the suction and liquid line or the circulating refrigerant therein may be too low to realize an internal heat transfer for the required supercooling of the refrigerant flowing in the liquid line.

Die Erfindung weiterbildend wird daher-wie bereits erwähnt - vorgeschlagen, das aus dem Sammelbehälter 3 über Leitung 4 abgezogene Kältemittel im Wärmetauscher bzw. Unterkühler E5 gegen das aus dem Sammelbehälter 3 über Leitung 12 und im Ventil e entspannte Flashgas zu unterkühlen. Nach Durchgang durch den Wärmetauscher bzw. Unterkühler E5 wird das entspannte und im Wärmetauscher E5 überhitzte Kältemittel über die Leitungsabschnitte 12' und 11 dem Eingang der Verdichtereinheit 6 zugeführt. Durch die Überhitzung des aus dem Sammelbehälter 3 über Leitung 12 abgezogenen Flashgasstromes wird in der Flüssigkeitsleitung 4 eine ausreichende Unterkühlung des in ihr strömenden Kältemittels erreicht; diese Unterkühlung des Kältemittels verbessert den Regelbetrieb der Entspannungs- bzw. Einspritzventile b, c und d, die den Verdampfern E2, E3 und E4 vorgeschaltet sind.The invention further developing is therefore-as already mentioned - proposed to cool the withdrawn from the sump 3 via line 4 refrigerant in the heat exchanger or subcooler E5 against the relaxed from the sump 3 via line 12 and in the valve e flash gas. After passing through the heat exchanger or subcooler E5, the expanded refrigerant which has been overheated in the heat exchanger E5 is fed via the line sections 12 'and 11 to the inlet of the compressor unit 6. Due to the overheating of the withdrawn from the reservoir 3 via line 12 Flashgasstromes a sufficient subcooling of the refrigerant flowing in it is achieved in the liquid line 4; This supercooling of the refrigerant improves the regular operation of the expansion or injection valves b, c and d, which are upstream of the evaporators E2, E3 and E4.

Flüssigkeitströpfchen, die aus dem Sammelbehälter 3 über Leitung 12 aufgrund einer zu kleinen Dimensionierung und/oder Überfüllung des Sammelbehälters 3 nicht abgeschieden und mit dem Flashgas mitgeführt werden, werden spätestens im Wärmetauscher/Unterkühler E5 verdampft Die beschriebene Verfahrensweise hat somit darüber hinaus den Vorteil, dass die Betriebssicherheit der Verdichter bzw. Verdichtereinheit 6 aufgrund einer sicheren Überhitzung des Flashgasstromes erhöht wird.Liquid droplets which are not separated from the collecting container 3 via line 12 due to a too small dimensioning and / or overfilling of the collecting container 3 and entrained with the flash gas, are vaporized latest in the heat exchanger / subcooler E5 The above described method thus has the additional advantage that the reliability of the compressor or compressor unit 6 is increased due to a safe overheating of the flash gas stream.

Die Figur 4 zeigt eine weitere, Ausgestaltung des erfindungsgemäßen Kältekreislaufes bzw. des erfindungsgemäßen Verfahrens zum Betreiben,eines Kältekreislaufes. Der Übersichtlichkeit halber ist in der Figur 4 lediglichein Ausschnitt des in der Figur 2 und 3 dargestellten erfindungsgemäßen Kältekreislaufes dargestellt.The FIG. 4 shows a further, embodiment of the refrigeration cycle according to the invention or the inventive method for operating a refrigeration cycle. For the sake of clarity is in the FIG. 4 only a section of the in the FIG. 2 and 3 illustrated refrigeration circuit according to the invention shown.

Das erfindungsgemäße Verfahren zum Betreiben eines Kältekreislaufes weiterbildend wird vorgeschlagen, dass zumindest ein Teilstrom des aus dem Sammelbehälter abgezogenen Flashgases zumindest zeitweilig gegen wenigstens einen Teilstrom des verdichteten Kältemittels überhitzt wird.The method according to the invention for operating a refrigeration cycle further develops that at least a partial flow of the flash gas withdrawn from the collecting container is at least temporarily overheated against at least a partial flow of the compressed refrigerant.

Die Figur 4 zeigt eine mögliche Ausgestaltung des erfindungsgemäßen Verfahrens, bei der zumindest zeitweilig ein Teilstrom des aus dem Sammelbehälter 3 über Leitung 12 abgezogenen Flashgases über die Leitung 16 einem Wärmetauscher E6 zugeführt und in diesem gegen das in der Verdichtereinheit 6 verdichtete Kältemittel überhitzt wird.The FIG. 4 shows a possible embodiment of the method according to the invention, in which at least temporarily a partial flow of the withdrawn from the reservoir 3 via line 12 flash gas via line 16 to a heat exchanger E6 and superheated in this against the compressed in the compressor unit 6 refrigerant.

Bei der in der Figur 4 dargestellten Verfahrensweise wird der zu überhitzende Flashgasstrom im Wärmetauscher E6 gegen den gesamten, in der Verdichtereinheit 6 verdichteten Kältemittelstrom, der über Leitung 7 dem in der Figur 4 nicht dargestellten Verflüssiger bzw. Enthitzer zugeführt wird, überhitztWhen in the FIG. 4 As shown, the Flashgasstrom to be overheated in the heat exchanger E6 against the entire, compressed in the compressor unit 6 refrigerant flow via line 7 in the FIG. 4 not shown condenser or desuperheater is supplied, superheated

Nach Durchgang durch den WärmetauscherlÜberhitzer E6 wird der Flashgasstrom über Leitung 16' dem Eingang des Verdichters 6' der Verdichtereinheit 6 zugeführt.After passing through the heat exchanger superheater E6, the flash gas stream is fed via line 16 'to the inlet of the compressor 6' of the compressor unit 6.

Die in der Figur 4 dargestellte Verfahrensweise ermöglicht es sicherzustellen, dass in dem Flashgas enthaltene Flüssiganteile zweifelsfrei verdampft werden, woraus eine erhöhte Sicherheit für die Verdichter bzw. die Verdichtereinheit 6 resultiert.The in the FIG. 4 The procedure described makes it possible to ensure that liquid components contained in the flash gas are unambiguously vaporized, resulting in increased safety for the compressor or compressor unit 6.

Claims (19)

  1. Refrigeration circuit having a mono- or multi-component refrigerant, especially CO2, circulating therein, said refrigeration circuit enabling an overcritical operation, said refrigeration circuit comprising, in the direction of flow, a condenser/gascooler (1), an intermediate relief device (a), a collecting container (3), a relief device (b, c) connected upstream of an evaporator (E2, E3), an evaporator (E2, E3) and a compressor unit (6) with single-stage compression, wherein the gas space of the collecting container (3) is connected or connectible to the input of the compressor unit (6), and wherein a relief valve (e) is provided in the connection line (11, 12) between the gas space of the collecting container (3) and the input of the compressor unit (6),
    characterized in that
    between the collecting container (3) and the expansion device (b, c) connected upstream of an evaporator (E2, E3) there is arranged a heat exchanger/subcooler (E5) and that in the heat exchanger/subcooler (E5) the refrigerant drawn off the collecting container (3) is subcooled with respect to the flash gas being drawn off the collecting container (3) via the connection line (11, 12) and being expanded by the expansion valve (e).
  2. Refrigeration circuit according to claim 1, wherein a heat transfer means (E1) is connected upstream of the collecting container (3).
  3. Refrigeration circuit according to claim 2, wherein the heat transfer means (E1) is connected or connectible (2, 13) on the input side to the output of the condenser/gascooler (1).
  4. Refrigeration circuit according to claim 2 or 3, wherein the line (2) from the condenser/gascooler (1) divides into a first line portion (2') and into a second line portion (13), wherein a relief device (f) is arranged in the second line portion (13), and wherein the refrigerant in the second line portion (13) is evaporated in the heat exchanger (E1) with respect to the refrigerant in the first line portion (2').
  5. Refrigeration circuit according to claim 4, wherein the second line portion (13, 14) after the heat exchanger (E1) is connected or connectible to the input of the compressor (6') of the compressor unit (6).
  6. Refrigeration circuit according to claim 4 or 5, wherein a pressure line (7) is provided for feeding compressed refrigerant from the compressor unit (6) to the compressor/gascooler (1), and wherein the pressure line (7) is connected or connectible to the line (2, 2', 2") that connects the condenser/gascooler (1) and the collecting container (3).
  7. Refrigeration circuit according to any of the claims 4 to 6, wherein a pressure line (7) is provided for feeding compressed refrigerant from the compressor unit (6) to the condenser/gascooler (1), and wherein the line (18) having a valve (j) arranged therein connects the first line portion (2') after the heat exchanger (E1) to the pressure line (7) after the compressor unit (6).
  8. Refrigeration circuit according to any of the preceding claims, wherein the gas space of the collecting container (3) is connected or connectible to the input of a compressor (6') of the compressor unit (6).
  9. Refrigeration circuit according to any of the preceding claims, wherein a pressure line (7) is provided for feeding compressed refrigerant from the compressor unit (6) to the condenser/gascooler (1), and wherein the pressure line (7) is connected or connectible to the collecting container (3), preferably with the gas space thereof.
  10. Refrigeration circuit according to claim 9, wherein a relief valve (h) is provided in the line (17) that connects the pressure line (7) to the collecting container (3).
  11. Refrigeration circuit according to any of the preceding claims, wherein a pressure line (7) is provided for feeding compressed refrigerant from the compressor unit (6) to the condenser/gascooler (1) and wherein a heat exchanger (E6) is provided in which the flash gas drawn off the collecting container is superheated against compressed refrigerant in the pressure line (7).
  12. Refrigeration circuit according to claim 11, wherein the flash gas after passage through the heat exchanger/superheater (E6) is fed via a line (16') to the input of the compressor (6') of the compressor unit (6).
  13. Refrigeration circuit according to any of the preceding claims, wherein the refrigerant drawn off the collecting container (3) is fed via a line (8) to one or more freezing cold consumers (E4) having an expansion valve (d) connected upstream thereof.
  14. Refrigeration circuit according to claim 13, wherein a compressor unit (10) is provided that is supplied via a suction line (9) with refrigerant evaporated in the freezing cold consumer (E4), and wherein the refrigerant compressed in the compressor unit (10) is fed to the compressor unit (6) via a suction line (11).
  15. Method for overcritical operation of a refrigeration circuit according to any of the preceding claims, in which a mono- or multi-component refrigerant, especially CO2, circulates, wherein pressure relief of the refrigerant to an intermediate pressure of 5 to 40 bar is effected in the intermediate relief device (a) arranged between the condenser/gascooler (1) and the collecting container (3),
    characterized in that
    the intermediate pressure is kept constant by means of the relief valve (e) in the connection line (11, 12) between the gas space of the collecting container (3) and the input of the compressor unit (6) and that the refrigerant drawn off the collecting container (3) is subcooled in a heat exchanger/subcooler (E5) with respect to the flash gas being drawn off the collecting container (3) via the connection line (11, 12) and being expanded in the relief valve (e).
  16. Method according to claim 15, wherein the refrigerant (2) is subjected to cooling (E1) prior to intermediate pressure-relief (a) of the same.
  17. Method according to claim 16, wherein the cooling (E1) of the refrigerant (2) is effected with respect to a partial flow of the refrigerant (13).
  18. Method according to any of claims 15 to 17, wherein at least a partial flow of the flash gas (12) withdrawn from the collecting container (3) is superheated (E6, E7) at least temporarily with respect to the compressed refrigerant (7).
  19. Method according to any of claims 15 to 18, wherein the intermediate pressure is regulated to a constant value and/or to a constant difference from the suction pressure by means of at least one valve (e, h, j).
EP05775838A 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit Active EP1789732B1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP10167202.0A EP2244040B1 (en) 2004-08-09 2005-07-29 Flashgas removal from a receiver in a refrigeration circuit
EP07020311.2A EP1895246B3 (en) 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit
EP10181303.8A EP2264385B1 (en) 2004-08-09 2005-07-29 Refrigeration cycle and method of operating a refrigerating cycle
DK10181303.8T DK2264385T3 (en) 2004-08-09 2005-07-29 Cooling circuits and method for operating a cooling circuit.
DK07020311.2T DK1895246T6 (en) 2004-08-09 2005-07-29 Cooling circuit and method for operating a cooling circuit
DK10167202T DK2244040T3 (en) 2004-08-09 2005-07-29 Cooling circuits and method for operating a cooling circuit

Applications Claiming Priority (2)

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DE102004038640A DE102004038640A1 (en) 2004-08-09 2004-08-09 Refrigeration circuit and method for operating a refrigeration cycle
PCT/EP2005/008255 WO2006015741A1 (en) 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit

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EP07020311.2A Division EP1895246B3 (en) 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit
EP10167202.0A Division EP2244040B1 (en) 2004-08-09 2005-07-29 Flashgas removal from a receiver in a refrigeration circuit
EP10181303.8A Division EP2264385B1 (en) 2004-08-09 2005-07-29 Refrigeration cycle and method of operating a refrigerating cycle
EP07020311.2 Division-Into 2007-10-17
EP10167202.0 Division-Into 2010-06-24
EP10181303.8 Division-Into 2010-09-28

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EP05723393A Not-in-force EP1794510B1 (en) 2004-08-09 2005-02-18 Co2 refrigeration circuit with sub-cooling of the liquid refrigerant against the receiver flash gas and method for operating the same
EP05715407.2A Active EP1782001B1 (en) 2004-08-09 2005-02-18 Flashgas removal from a receiver in a refrigeration circuit
EP05775838A Active EP1789732B1 (en) 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit
EP10167202.0A Active EP2244040B1 (en) 2004-08-09 2005-07-29 Flashgas removal from a receiver in a refrigeration circuit
EP10181303.8A Active EP2264385B1 (en) 2004-08-09 2005-07-29 Refrigeration cycle and method of operating a refrigerating cycle
EP07020311.2A Active EP1895246B3 (en) 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit

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EP05723393A Not-in-force EP1794510B1 (en) 2004-08-09 2005-02-18 Co2 refrigeration circuit with sub-cooling of the liquid refrigerant against the receiver flash gas and method for operating the same
EP05715407.2A Active EP1782001B1 (en) 2004-08-09 2005-02-18 Flashgas removal from a receiver in a refrigeration circuit

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EP07020311.2A Active EP1895246B3 (en) 2004-08-09 2005-07-29 Refrigeration circuit and method for operating a refrigeration circuit

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EP (6) EP1794510B1 (en)
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RU2007107807A (en) 2008-09-20
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EP2244040B1 (en) 2019-08-28
EP1794510A1 (en) 2007-06-13
EP2244040A3 (en) 2011-10-12
DK1895246T3 (en) 2017-03-06
CN101040153A (en) 2007-09-19
EP1782001A1 (en) 2007-05-09
CN100507402C (en) 2009-07-01
NO20071229L (en) 2007-03-06
EP2264385A2 (en) 2010-12-22
HK1101199A1 (en) 2007-10-12
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CN101014815A (en) 2007-08-08
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ATE544992T1 (en) 2012-02-15
EP2264385A3 (en) 2011-10-19
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US20080104981A1 (en) 2008-05-08
EP1895246B1 (en) 2016-11-23
DK2244040T3 (en) 2019-12-02
EP2244040A2 (en) 2010-10-27
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CN101713596B (en) 2012-08-08
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US7644593B2 (en) 2010-01-12
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US8113008B2 (en) 2012-02-14
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DK1895246T6 (en) 2019-06-11
EP1782001B1 (en) 2016-11-30

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