EP1760086A3 - Single site palladium catalyst complexes - Google Patents
Single site palladium catalyst complexes Download PDFInfo
- Publication number
- EP1760086A3 EP1760086A3 EP06254433A EP06254433A EP1760086A3 EP 1760086 A3 EP1760086 A3 EP 1760086A3 EP 06254433 A EP06254433 A EP 06254433A EP 06254433 A EP06254433 A EP 06254433A EP 1760086 A3 EP1760086 A3 EP 1760086A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- palladium catalyst
- single site
- catalyst complexes
- site palladium
- catalyst structures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229910052763 palladium Inorganic materials 0.000 title abstract 2
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
- C07F15/0066—Palladium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2247—At least one oxygen and one phosphorous atom present as complexing atoms in an at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
- B01J2231/4261—Heck-type, i.e. RY + C=C, in which R is aryl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
- B01J2540/30—Non-coordinating groups comprising sulfur
- B01J2540/34—Sulfonyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerization Catalysts (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08164039A EP2014668B1 (en) | 2005-08-31 | 2006-08-24 | Single site palladium catalyst complexes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US71304405P | 2005-08-31 | 2005-08-31 | |
US11/457,969 US7833927B2 (en) | 2005-08-31 | 2006-07-17 | Single site palladium catalyst complexes |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08164039A Division EP2014668B1 (en) | 2005-08-31 | 2006-08-24 | Single site palladium catalyst complexes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1760086A2 EP1760086A2 (en) | 2007-03-07 |
EP1760086A3 true EP1760086A3 (en) | 2007-08-01 |
Family
ID=37576586
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06254433A Withdrawn EP1760086A3 (en) | 2005-08-31 | 2006-08-24 | Single site palladium catalyst complexes |
EP08164039A Expired - Fee Related EP2014668B1 (en) | 2005-08-31 | 2006-08-24 | Single site palladium catalyst complexes |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08164039A Expired - Fee Related EP2014668B1 (en) | 2005-08-31 | 2006-08-24 | Single site palladium catalyst complexes |
Country Status (8)
Country | Link |
---|---|
US (1) | US7833927B2 (zh) |
EP (2) | EP1760086A3 (zh) |
JP (1) | JP4671358B2 (zh) |
KR (1) | KR100827555B1 (zh) |
CN (1) | CN100567335C (zh) |
CA (1) | CA2556354C (zh) |
DE (1) | DE602006015106D1 (zh) |
TW (1) | TWI328014B (zh) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7635739B2 (en) * | 2005-08-31 | 2009-12-22 | Rohm And Haas Company | Substantially linear polymers and methods of making and using same |
CA2620852A1 (en) | 2007-02-28 | 2008-08-28 | Rohm And Haas Company | A porous linear polymer composition and method of making same |
JP5047832B2 (ja) * | 2007-02-28 | 2012-10-10 | ローム アンド ハース カンパニー | フリーラジカル開始ポリマーを実質的に含まない、極性および非極性オレフィンのコポリマーを製造するための組成物および方法 |
CA2708369C (en) * | 2007-12-12 | 2017-04-04 | Massachusetts Institute Of Technology | Ligands for transition-metal-catalyzed cross-couplings, and methods of use thereof |
US8268946B2 (en) | 2008-06-19 | 2012-09-18 | The Regents Of The University Of California | Clay activation of PD(II) and NI(II) complexes |
JP5649812B2 (ja) * | 2008-11-20 | 2015-01-07 | 日本ポリプロ株式会社 | 新規なトリアリールホスフィン又はトリアリールアルシン化合物及びそれらを用いたα−オレフィン系重合触媒並びにα−オレフィン系共重合体の製造方法。 |
CN102292344B (zh) * | 2008-11-20 | 2014-12-10 | 日本聚乙烯株式会社 | 新三芳基膦或三芳基胂化合物及α-烯烃聚合催化剂、三元共聚物和α-烯烃/(甲基)丙烯酸系共聚物的制法 |
JP5666808B2 (ja) * | 2009-02-05 | 2015-02-12 | 日本ポリエチレン株式会社 | 新規なトリアリールホスフィン又はトリアリールアルシン化合物及びそれらを使用するα−オレフィン系重合触媒並びにα−オレフィン系共重合体の製造方法。 |
JP5225973B2 (ja) * | 2009-12-31 | 2013-07-03 | 日本ポリエチレン株式会社 | 新規なトリアリールホスフィン又はトリアリールアルシン化合物及びそれらを用いたα−オレフィン重合触媒、並びにその重合触媒によるα−オレフィン・(メタ)アクリル酸系共重合体の製造方法。 |
JP5694846B2 (ja) * | 2010-05-13 | 2015-04-01 | 日本ポリエチレン株式会社 | 新規なトリアリールホスフィン又はトリアリールアルシン化合物及びそれらによるα−オレフィン系重合触媒並びにα−オレフィン系重合体の製造方法 |
JP5945449B2 (ja) * | 2011-04-27 | 2016-07-05 | 日本ポリエチレン株式会社 | 新規なトリアリールホスフィン又はトリアリールアルシン化合物及びそれらによるオレフィン系重合触媒並びにオレフィン系共重合体の製法 |
ES2459790B1 (es) * | 2012-11-07 | 2015-04-27 | Universitat Autònoma De Barcelona | Trifenilfosfinas carboxílicas |
JP7175741B2 (ja) * | 2017-12-25 | 2022-11-21 | 日本ポリエチレン株式会社 | 多元系極性基含有オレフィン共重合体 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000006615A1 (en) * | 1998-07-27 | 2000-02-10 | Basell Technology Company B.V. | A polymerization process |
EP1101768A1 (de) * | 1999-11-17 | 2001-05-23 | Basf Aktiengesellschaft | Substituierte Phosphinophenolat-Metall-Komplexe zur Polymerisation von Olefinen |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3694412A (en) * | 1971-03-04 | 1972-09-26 | Shell Oil Co | Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex |
US4698403A (en) | 1985-10-15 | 1987-10-06 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed copolymerization of ethylene |
US4855400A (en) * | 1985-11-26 | 1989-08-08 | Shell Oil Company | Removal of catalyst residues from carbon monoxide/olefin polymers with catalyst complexing agent |
US4689437A (en) | 1986-07-21 | 1987-08-25 | Union Carbide Corporation | Oligomerization to alpha-olefins |
JP3388828B2 (ja) * | 1992-09-21 | 2003-03-24 | モンテル・テクノロジー・カンパニー・ベー・ベー | 重合方法 |
US5766877A (en) * | 1996-05-10 | 1998-06-16 | Amgen Inc. | Genes encoding art, an agouti-related transcript |
JP2001508114A (ja) | 1997-01-14 | 2001-06-19 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | エチレンの重合 |
-
2006
- 2006-07-17 US US11/457,969 patent/US7833927B2/en not_active Expired - Fee Related
- 2006-08-17 CA CA002556354A patent/CA2556354C/en not_active Expired - Fee Related
- 2006-08-21 TW TW095130622A patent/TWI328014B/zh not_active IP Right Cessation
- 2006-08-24 EP EP06254433A patent/EP1760086A3/en not_active Withdrawn
- 2006-08-24 DE DE602006015106T patent/DE602006015106D1/de active Active
- 2006-08-24 EP EP08164039A patent/EP2014668B1/en not_active Expired - Fee Related
- 2006-08-28 KR KR1020060081607A patent/KR100827555B1/ko active IP Right Grant
- 2006-08-30 JP JP2006233740A patent/JP4671358B2/ja not_active Expired - Fee Related
- 2006-08-30 CN CNB2006101285460A patent/CN100567335C/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000006615A1 (en) * | 1998-07-27 | 2000-02-10 | Basell Technology Company B.V. | A polymerization process |
EP1101768A1 (de) * | 1999-11-17 | 2001-05-23 | Basf Aktiengesellschaft | Substituierte Phosphinophenolat-Metall-Komplexe zur Polymerisation von Olefinen |
Non-Patent Citations (8)
Title |
---|
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002423802, retrieved from XFIRE * |
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002423803, retrieved from XFIRE Database accession no. BRN 7952073, BRN 7966377, BRN 7937700 * |
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002423804, retrieved from XFIRE Database accession no. BRN 2800813 * |
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002423805, retrieved from XFIRE Database accession no. BRN 9927941, BRN 9928009, BRN 9928654 * |
GRANOTH, I. ET AL., JACS, vol. 101, 1979, pages 4623 - 4626 * |
HINGST M. ET AL., J. INORG. CHEM., vol. 1, 1998, pages 73 - 82 * |
LIN, F. ET AL., JACS, vol. 127, no. 8, 2005, pages 2686 - 2695 * |
TROST B. ET AL., BULL. SOC. CHIM. FR., vol. 134, no. 3-4, 1997, pages 263 - 274 * |
Also Published As
Publication number | Publication date |
---|---|
TW200718716A (en) | 2007-05-16 |
CA2556354A1 (en) | 2007-02-28 |
DE602006015106D1 (de) | 2010-08-05 |
EP1760086A2 (en) | 2007-03-07 |
EP2014668A3 (en) | 2009-01-21 |
JP2007117991A (ja) | 2007-05-17 |
CA2556354C (en) | 2009-05-19 |
KR20070026055A (ko) | 2007-03-08 |
CN1923859A (zh) | 2007-03-07 |
EP2014668B1 (en) | 2010-06-23 |
EP2014668A2 (en) | 2009-01-14 |
US7833927B2 (en) | 2010-11-16 |
CN100567335C (zh) | 2009-12-09 |
KR100827555B1 (ko) | 2008-05-07 |
JP4671358B2 (ja) | 2011-04-13 |
US20070287627A1 (en) | 2007-12-13 |
TWI328014B (en) | 2010-08-01 |
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