EP1731304A1 - Wärmeschrumpfbare Verpackungsfolie mit barriere Eigenschaften - Google Patents

Wärmeschrumpfbare Verpackungsfolie mit barriere Eigenschaften Download PDF

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Publication number
EP1731304A1
EP1731304A1 EP20060252647 EP06252647A EP1731304A1 EP 1731304 A1 EP1731304 A1 EP 1731304A1 EP 20060252647 EP20060252647 EP 20060252647 EP 06252647 A EP06252647 A EP 06252647A EP 1731304 A1 EP1731304 A1 EP 1731304A1
Authority
EP
European Patent Office
Prior art keywords
film
ethylene
copolymer
layer
intermediate layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20060252647
Other languages
English (en)
French (fr)
Inventor
Stephanie G. Kreitman
Mendy J. Mossbrook
Michael Broadus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cryovac LLC
Original Assignee
Cryovac LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cryovac LLC filed Critical Cryovac LLC
Publication of EP1731304A1 publication Critical patent/EP1731304A1/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/406—Bright, glossy, shiny surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/40—Closed containers
    • B32B2439/46—Bags
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1328—Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
    • Y10T428/1341—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
    • Y10T428/1383—Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer
    • Y10T428/3192—Next to vinyl or vinylidene chloride polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Definitions

  • ethylene/unsaturated ester copolymer is the copolymer of ethylene and one or more unsaturated ester monomers.
  • Useful unsaturated esters include: 1) vinyl esters of aliphatic carboxylic acids, where the esters have from 4 to 12 carbon atoms, and 2) alkyl esters of acrylic or methacrylic acid (collectively, "alkyl (meth)acrylate”), where the esters have from 4 to 12 carbon atoms.
  • Another useful ethylene copolymer includes ethylene/(meth)acrylic acid copolymer, which is the copolymer of ethylene and acrylic acid, methacrylic acid, or both.
  • polyamides of the type that may be formed by the polycondensation of one or more diamines with one or more diacids include aliphatic polyamides such as poly(hexamethylene adipamide) ("nylon-6,6"), poly(hexamethylene sebacamide) (“nylon-6,10”), poly(heptamethylene pimelamide) ("nylon-7,7"), poly(octamethylene suberamide) ("nylon-8,8”), poly(hexamethylene azelamide) (“nylon-6,9”), poly(nonamethylene azelamide) (“nylon-9,9”), poly(decamethylene azelamide) (“nylon-10,9”), poly(tetramethylenediamine-co-oxalic acid) (“nylon-4,2”), the polyamide of n-dodecanedioic acid and hexamethylenediamine (“nylon-6,12”), the polyamide of dodecamethylenediamine and n-dodecanedi
  • Representative aliphatic/aromatic polyamides include poly(tetramethylenediamine-co-isophthalic acid) ("nylon-4,I”), polyhexamethylene isophthalamide (“nylon-6,I”), polyhexamethylene terephthalamide (“nylon-6,T”), poly (2,2,2-trimethyl hexamethylene terephthalamide), poly(m-xylylene adipamide) (“nylon-MXD,6”), poly(p-xylylene adipamide), poly(hexamethylene terephthalamide), poly(dodecamethylene terephthalamide), and polyamide-MXD,I.
  • any of the layers of the film may have a thickness of at least about, and/or at most about, any of the following: 0.05, 0.1, 0.5, 1, 1.3, 1.5, 2, 2.5, 3, 4, 5, and 6 mils. Any of the layers of the film may have a thickness as a percentage of the total thickness of the film of at least about, and/or at most about, any of the following: 1, 3, 5, 7, 10, 15, 20, 25, 30, 35, 40, 45, and 50 percent.
  • the minimum bond strength between the intermediate layer and each of the layers directly adjacent the intermediate layer may be at least about any of the following: 1, 1.5, 2, 2.5, 2.6, 2.8, 3, 3.5, 4, and 4.5 pounds/inch measured according to ASTM F904.
  • the film may be oriented in either the machine (i.e., longitudinal), the transverse direction, or in both directions (i.e., biaxially oriented), for example, to enhance the strength, optics, and durability of the film.
  • a web or tube of the film may be uniaxially or biaxially oriented by imposing a draw force at a temperature where the film is softened (e.g., above the vicat softening point; see ASTM 1525) but at a temperature below the film's melting point.
  • the film may then be quickly cooled to retain the physical properties generated during orientation and to provide a heat-shrink characteristic to the film.
  • the film may be oriented using, for example, a tenter-frame process or a bubble process.
  • One or more of the layers of the film -- or at least a portion of the entire film may be cross-linked, for example, to improve the strength of the film.
  • Cross-linking may be achieved by using chemical additives or by subjecting one or more film layers to one or more energetic radiation treatments -- such as ultraviolet, or ionizing radiation such as X-ray, gamma ray, beta ray, and high energy electron beam treatment -- to induce cross-linking between molecules of the irradiated material.
  • one or more film layers may be extruded and irradiated, and any of the PVdC-containing layer, the intermediate layer, and subsequent layers may then be applied to the irradiated substrate, for example, by an extrusion coating process. This will produce an extrusion coating interface, as referenced in the Additional Film Layers section above. Further, the PEC of the intermediate layer may be substantially devoid of crosslinks.
  • the product may be inserted into the bag, and the open end of the bag sealed to enclose the product.
  • the film may also be wrapped around a product and heat sealed to form a package enclosing the product.
  • the film may be used as a wrap to cover and secure a product (e.g., a food product) that rests on a tray.
  • the film may be used as a lid adapted to be sealed to a support (e.g., a tray) for the packaged product.
  • Example 1 Longitudinal** Modulus (kpsi) Transverse** Modulus (psi) Haze (%) Gloss (%) Total Free*** Shrink (%)
  • Example 1 (NBX0197) 27,700 29,900 3.9 92 82.5
  • Example 2 (NBX0200) 29,100 35,900 3.7 92 85.0
  • Example 3 (NBX0268) 30,100 31,700 4.1 88 81.0
  • Example 4 (NBX0282) 33,900 35,900 3.6 90 78.5
  • Example 5 (NBX0288) 36,000 38,500 4.8 88 81.5
  • Example 6 (NBX0317) 23,800 29,100 2.6 89 80.0 Compare 1* (B255A) 19,000 21,700 3.4 86 88.0 Compare 1 * (B255A) 18,700 18,900 4.9 81 87.0 Compare 2 (NBX0229) 25,100 26,400 4.3 87 72.0 Compare 3 (NBX0235) 23,600 21,800 4.6 84 82.5 Compare 4 (NBX0375
  • any numerical value ranges recited herein include all values from the lower value to the upper value in increments of one unit provided that there is a separation of at least 2 units between any lower value and any higher value.
  • the amount of a component or a value of a process variable e.g., temperature, pressure, time
  • the amount of a component or a value of a process variable may range from any of 1 to 90, 20 to 80, or 30 to 70, or be any of at least 1, 20, or 30 and/or at most 90, 80, or 70, then it is intended that values such as 15 to 85, 22 to 68, 43 to 51, and 30 to 32, as well as at least 15, at least 22, and at most 32, are expressly enumerated in this specification.

Landscapes

  • Laminated Bodies (AREA)
  • Wrappers (AREA)
EP20060252647 2005-06-06 2006-05-19 Wärmeschrumpfbare Verpackungsfolie mit barriere Eigenschaften Withdrawn EP1731304A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/145,607 US7517569B2 (en) 2005-06-06 2005-06-06 Shrink packaging barrier film

Publications (1)

Publication Number Publication Date
EP1731304A1 true EP1731304A1 (de) 2006-12-13

Family

ID=36933486

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20060252647 Withdrawn EP1731304A1 (de) 2005-06-06 2006-05-19 Wärmeschrumpfbare Verpackungsfolie mit barriere Eigenschaften

Country Status (5)

Country Link
US (1) US7517569B2 (de)
EP (1) EP1731304A1 (de)
AU (1) AU2006202193B2 (de)
CA (1) CA2548840C (de)
NZ (1) NZ547159A (de)

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US8043680B2 (en) 2007-05-09 2011-10-25 Baxter International Inc. Multiple layer structures comprising a poly (vinylidene chloride) layer
WO2018191506A1 (en) * 2017-04-13 2018-10-18 Cryovac, Inc. High-shrink, high-strength packaging article exhibiting directional tear
CN109851956A (zh) * 2017-11-30 2019-06-07 株式会社吴羽 偏氯乙烯系树脂膜、使用其的填充包装体及其制造方法

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US7258930B2 (en) * 2004-04-28 2007-08-21 Cryovac, Inc. Oxygen scavenging film with cyclic olefin copolymer
US8129006B2 (en) * 2005-09-30 2012-03-06 Flexopack S.A. Stack sealable heat shrinkable film
ATE531515T1 (de) * 2007-04-26 2011-11-15 Flexopack S A Plastics Industry Blockversiegelbare, wärmeschrumpfende folie
EP1985440A3 (de) * 2007-04-26 2011-05-04 Flexopack S.A. Plastics Industry Thermogeformte Folien
US20100297371A1 (en) * 2007-10-29 2010-11-25 Shikoku Kakoh Co., Ltd. Film for food packaging
ATE552304T1 (de) 2008-01-02 2012-04-15 Flexopack Sa Pvdc-formulierung und wärmeschrumpfbare folie
AU2008264215A1 (en) * 2008-01-03 2009-07-23 Flexopack S.A. Thermoforming film
DE202009014170U1 (de) * 2008-01-29 2010-02-25 Flexopack S.A. Dünner Film für Abfallverpackungskassetten
ATE541699T1 (de) * 2008-04-21 2012-02-15 Flexopack S A Plastics Industry Im stapel versiegelbare schrumpffolie
PL2147783T3 (pl) * 2008-07-23 2018-10-31 Flexopack S.A. Folia termokurczliwa do zgrzewania w stosie
US7735926B1 (en) * 2008-12-09 2010-06-15 Combs John A Chair lift
LT3912601T (lt) 2009-11-06 2024-06-10 Hollister Incorporated Daugiasluoksnė plėvelė ir iš jos pagamintas ostomijos gaminys
GB2475961B (en) * 2009-12-02 2015-07-08 Flexopack Sa Thin film for waste packing cassettes
US20120125477A1 (en) 2010-11-19 2012-05-24 Cryovac, Inc. Coiled Valve and Methods of Making and Using the Same
EP2520518B1 (de) 2011-05-03 2020-09-23 Flexopack S.A. Abfallverpackungsvorrichtung
EP2535279B1 (de) 2011-06-16 2016-11-16 Flexopack S.A. Abfallverpackungssystem und Folie
CN103648765B (zh) * 2011-07-27 2017-06-06 纳幕尔杜邦公司 用于可重新闭合的包装的多层膜
US9604430B2 (en) 2012-02-08 2017-03-28 Flexopack S.A. Thin film for waste packing cassettes
US20130272630A1 (en) 2012-04-16 2013-10-17 Cryovac, Inc. Packaging Receptacle For Making Packaging Article Exhibiting Combination of Linear Tear and Directional Curl
US9789669B2 (en) 2013-06-14 2017-10-17 Flexopack S.A. Heat shrinkable film
US20150107762A1 (en) * 2013-10-18 2015-04-23 Avery Dennison Corporation Processes for the Removal of Labels from Materials
EP3063004B1 (de) * 2013-11-01 2018-02-28 Cryovac, Inc. Polyesterhaltige heissschrumpfbare mehrschichtigefolie mit suaerstoffsbarriereeigenschaften und schälfestigkeit
US9624020B2 (en) * 2013-12-27 2017-04-18 Toray Plastics (America), Inc. Citric acid-modified polyvinyl amine film
AU2015258191B2 (en) 2014-11-19 2020-02-27 Flexopack S.A. Oven skin packaging process
WO2016161048A1 (en) 2015-04-02 2016-10-06 Clysar Llc Multilayer shrink film with scission layer
EP3501822A1 (de) 2017-12-22 2019-06-26 Flexopack S.A. Fibc-auskleidungsfolie
EP4045319A2 (de) * 2019-10-15 2022-08-24 Braskem S.A. Eva-zusammensetzungen auf biologischer basis und artikel und verfahren davon
US11618602B1 (en) * 2022-03-10 2023-04-04 Henry G. Schirmer Process for making pouches having strong transverse shrinkage

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US20060272767A1 (en) 2006-12-07
CA2548840C (en) 2011-01-11
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