EP1677928A1 - Electromagnetic agitation method for continuous casting of metal products having an elongate section - Google Patents
Electromagnetic agitation method for continuous casting of metal products having an elongate sectionInfo
- Publication number
- EP1677928A1 EP1677928A1 EP04805290A EP04805290A EP1677928A1 EP 1677928 A1 EP1677928 A1 EP 1677928A1 EP 04805290 A EP04805290 A EP 04805290A EP 04805290 A EP04805290 A EP 04805290A EP 1677928 A1 EP1677928 A1 EP 1677928A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal
- mold
- product
- collinear
- cast product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002184 metal Substances 0.000 title claims abstract description 55
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 55
- 238000009749 continuous casting Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000013019 agitation Methods 0.000 title description 2
- 238000005266 casting Methods 0.000 claims abstract description 39
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 229910001338 liquidmetal Inorganic materials 0.000 claims abstract description 19
- 238000007711 solidification Methods 0.000 claims abstract description 17
- 230000008023 solidification Effects 0.000 claims abstract description 17
- 208000029152 Small face Diseases 0.000 claims abstract description 11
- 238000009434 installation Methods 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims description 23
- 230000003042 antagnostic effect Effects 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 4
- 241000736305 Marsilea quadrifolia Species 0.000 claims description 3
- 230000006698 induction Effects 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 12
- 238000002156 mixing Methods 0.000 description 12
- 230000005499 meniscus Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 230000009471 action Effects 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 230000000630 rising effect Effects 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 244000241796 Christia obcordata Species 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 210000002816 gill Anatomy 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000219793 Trifolium Species 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000001174 ascending effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000013598 vector Substances 0.000 description 2
- SIPNIVSCAYGONU-UHFFFAOYSA-N 4-[(7-oxo-6,8-dihydropyrrolo[2,3-g][1,3]benzothiazol-8-yl)methylideneamino]-N-pyridin-2-ylbenzenesulfonamide Chemical compound O=C1NC2=CC=C3N=CSC3=C2C1C=NC(C=C1)=CC=C1S(=O)(=O)NC1=CC=CC=N1 SIPNIVSCAYGONU-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000013124 brewing process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 230000008093 supporting effect Effects 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
- B22D11/11—Treating the molten metal
- B22D11/114—Treating the molten metal by using agitating or vibrating means
- B22D11/115—Treating the molten metal by using agitating or vibrating means by using magnetic fields
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/45—Magnetic mixers; Mixers with magnetically driven stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/16—Controlling or regulating processes or operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/02—Use of electric or magnetic effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
Definitions
- the movements imparted to molten metal during continuous casting can schematically be classified into two distinct categories, depending on whether one considers the ingot mold or, below, the stages of the secondary cooling of the casting machine.
- loops 42, 43 are established parallel to the large faces and are staggered according to the height of the product poured on either side of a common transverse motor action area of the magnetic field, the currents of each loop going up along of a small face and descending along the small opposite face.
- Such a configuration of movements is conventionally referred to as a "butterfly wing configuration”. It is possible, as shown in the attached figure 4 extracted from the document FR 82.10844, to multiply the transverse motor action zones 51, 52 ... of the magnetic fields according to the height of the casting machine. In this case, they are given opposite directions of rotation two by two between the nearest neighboring loops, in order for example to concern a volume stirred as large as possible for a given available stirring power.
- horizontally movable magnetic fields are produced by polyphase linear inductors 30a, 30b and 30a ', 30b' arranged on the large walls of the mold 32 opposite the exit path of the metal jets on either side of the nozzle 31.
- polyphase linear inductors 30a, 30b and 30a ', 30b' arranged on the large walls of the mold 32 opposite the exit path of the metal jets on either side of the nozzle 31.
- it is then possible to slow the current of the jet concerned sliding of the fields against current, going from the small wall to the nozzle -fig 3b j
- accelerate it sliding in co-current in the direction going from the nozzle to the small wall-fig 3b 2 ).
- the invention aims, via an overall mixing movement studied of the molten metal according to the metallurgical height, to provide a good exchange of the metal still liquid in both directions between the secondary cooling zone and the mold. Therefore, both thermal and chemical homogeneity will be achieved between the top and bottom of the poured liquid metal well without disturbing the flow mode in the ingot mold and, if necessary, without depriving itself of the cumulative beneficial effects proper mixing in an ingot mold and mixing in secondary cooling respectively.
- a further aim of the invention is to contribute to the improvement of the metallurgical quality of steel grades for which good internal health is sought, such as grades for heavy plates or for large welded tubes, ferritic stainless steels, or electrical steels with silicon.
- Another additional aim is to be able to act on the flows in the secondary to use them at the level of the casting jets coming from the nozzle either as an accelerating agent, or on the contrary as a braking agent for the metal arriving in the ingot mold, or even as a means to counteract the inclinations of "left-right" asymmetry of the movements of the metal within the ingot mold.
- the invention relates to an electromagnetic stirring process in the secondary cooling zone of an installation for continuous casting of slabs, or other similar products with an elongated straight section, the ingot mold of which has a immersed pouring nozzle with lateral outlet openings directed towards the small faces, stirring process implemented using sliding magnetic fields generated by polyphase inductors placed near the cast metal, characterized in that one forces, in said secondary cooling zone, the establishment of a longitudinal flow of the liquid metal located in the middle region of the product poured according to two antagonistic collinear currents.
- these two longitudinal antagonistic collinear currents are created in the middle part of the product which converge towards one another so that the two upper lobes which extend in the mold up to the level of the jets coming from the Outlets of the pouring nozzle are superimposed on them against the current to brake them.
- the location of the longitudinal flow in the secondary is shifted laterally towards one or the other of the small walls of the cast product in order to counteract the tendencies to the "left-right" asymmetry of the movements of metal within the mold.
- the longitudinal metal flow is created in the middle region of the product poured according to two antagonistic collinear currents using collinear mobile magnetic fields sliding longitudinally in said median region, or by approaching the from each other, either by moving away.
- the longitudinal metal flow is created in the middle region of the cast product according to two antagonistic collinear currents using mobile collinear magnetic fields sliding transversely along the width of the cast product, ie by approaching the 'from each other from the edge towards the center of the cast product, or by moving away from each other from the center towards the edge of the cast product.
- the sliding magnetic fields are generated using polyphase linear inductors which are placed opposite the large faces of the cast product.
- the inductors are supplied with electric currents of different intensities, in order to regulate differently the action on the two antagonistic collinear metallic currents created by the sliding magnetic fields which they generate.
- colllinear sliding of the metal fields or flows it should be understood that the magnetic fields, respectively the currents of metal, slide not in parallel with each other but in the same line, like two collinear vectors with respect to two parallel vectors.
- the invention consists, in its main foundations, in creating in the secondary cooling zone a cross-stitch with two transverse branches and two longitudinal branches.
- This zone is provided with a pair of linear inductors arranged opposite one on the other on each side of the product along the width thereof and generating a horizontally sliding magnetic field so as to achieve an electromagnetic mixing mode in the form of "butterfly wings" known is for example from the document FR 72.20546 cited above
- Figure 4 is a diagram similar to the previous one in Fig. 3, but showing a mode of electromagnetic mixing in "triple loop", as achieved for example by implementing the teaching of the document FR 82.10844 pre- - the other figures, numbered from 5 to 9 are specific to the invention.
- FIGS. 1 to 4 served as a support for the presentation of the prior art already made at the start of this thesis. We will not come back to this in the following.
- FIGS. 5 to 9 representative of the mode of mixing in the secondary proper to the invention in these two variants (divergent or convergent in the center), the sliding magnetic fields, just like the linear inductors which produce them, are represented by thick vertical or horizontal arrows.
- the convection movements produced are themselves represented by their main trajectories in the form of lines carrying arrowheads indicating the direction of movement movement on the carrier path.
- the solid lines represent active convection zones, therefore of circulation subjected to the action of sliding magnetic fields.
- a submerged nozzle 4 centered on the casting axis A feeds the ingot mold in molten metal from a distributor not shown located above.
- This nozzle is provided with gills of lateral outlets 5 and 5 ′ each turned opposite one and the other of the small walls 3 and 3 ′ respectively.
- the form of the cast product is determined by the internal dimensions of the mold defining the casting space into which the molten metal arrives in the form of jets 7, 7 ′ emerging from the openings of the nozzle 4 conventionally in a more or less average direction. horizontal, or slightly tilted downwards.
- the cast product thus progresses from the top, from the level of the meniscus 8, downwards, in the direction of extraction of the casting machine, vertically or along a curved path in a plane orthogonal to that of the figure, with an extraction speed (casting speed) usually of the order of one meter per minute.
- these branches Due to the necessarily “finished” dimensional nature of the cast product, these branches, as can be seen, are connected in a way with each other by recirculation loops to form an overall flow developing in the plane of the large faces of the product cast in the shape of a four-leaf clover, the leaves constituting lobes L1, L2, L3, L4, the upper two of which, L1 and L4, extend to the mold at the outlet jets 7 and 7 '.
- the pair of vertical branches is in "divergent" type convection. The metal streams move away from each other from the center P.
- the convection of the metal is then of the "convergent" type: the metallic currents converge towards each other in the direction of the center of confluence P by flowing from the small lateral faces of the product towards the longitudinal axis A.
- the metal currents which form these branches are created by sliding magnetic fields, themselves generated by linear inductors arranged in the immediate vicinity of the product cast opposite these large faces (preferably the two faces) .
- the implementation of the invention maximizes the exchanges of metallic material between the bottom and the top of the liquid well.
- the looping circulation of the metal in any lobe takes place in a direction of rotation opposite to that which is established in the two closest neighboring lobes.
- the strength of the casting jets 7 and 7 ′ then being systematically reinforced by the central flow 10a rising co-current, the recirculation loops L5 and L6 in the mold towards the meniscus 8 will be reinforced in their turn. Consequently, the "double loop" mode L5, L1, L4 and L6 present within the mold is thus moreover stabilized.
- FIG. 9 similar to FIG. 5, is essentially distinguished from it by the fact that the directions of circulation of the metal in each of the four " branches of the cross 9 are reversed. This FIG.
- FIG. 9 thus illustrates the second main variant for implementing the invention which consists in creating longitudinal antagonistic collinear currents 20a, 20b in the middle part of the cast product 6 which this time converge towards each other in the direction of point P so as to provide circulation of the liquid metal which extends into the mold 1 by currents rising along the small faces 18, 18 'up to the level of the metal jets 7, 7' coming from the outlet gills 5, 5 'of the nozzle with which they oppose against the current to slow them down.
- the invention consists, in short, in judiciously using the electromagnetic stirring means currently available to carry out in the secondary a cutting in the long direction of the product into two strands juxtaposed and, in each strand, to install a butterfly wing type brewing configuration. In doing so, an overall flow system is created in the secondary with four lobes, the heart of which is the cross cross 9 with its center P.
- this division into two strands will be made half-width of the cast product, that is to say along the longitudinal axis thereof, since this axis generally merges with the casting axis. That said, it will suffice to unbalance the stirring forces between the two transverse branches 11 a, 11 b, for example via a differentiated adjustment of the intensities of the electric currents supplying the inductors 12, 13, to laterally move the middle position from the center P towards a small face 5 or towards the other 5 ′ and thus obtain a more selective effect on one side of the nozzle on the mold movements than on the other.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Continuous Casting (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Alcoholic Beverages (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0312555A FR2861324B1 (en) | 2003-10-27 | 2003-10-27 | ELECTROMAGNETIC BREWING PROCESS FOR CONTINUOUS CASTING OF EXTENDED SECTION METAL PRODUCTS |
PCT/FR2004/002728 WO2005044487A1 (en) | 2003-10-27 | 2004-10-22 | Electromagnetic agitation method for continuous casting of metal products having an elongate section |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1677928A1 true EP1677928A1 (en) | 2006-07-12 |
EP1677928B1 EP1677928B1 (en) | 2007-04-18 |
Family
ID=34400826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04805290A Active EP1677928B1 (en) | 2003-10-27 | 2004-10-22 | Electromagnetic agitation method for continuous casting of metal products having an elongate section |
Country Status (16)
Country | Link |
---|---|
US (1) | US20070074845A1 (en) |
EP (1) | EP1677928B1 (en) |
JP (1) | JP4758903B2 (en) |
KR (1) | KR101089261B1 (en) |
CN (1) | CN100371108C (en) |
AT (1) | ATE359886T1 (en) |
AU (1) | AU2004286877B2 (en) |
BR (1) | BRPI0415903B1 (en) |
CA (1) | CA2543368A1 (en) |
DE (1) | DE602004006010T2 (en) |
ES (1) | ES2285558T3 (en) |
FR (1) | FR2861324B1 (en) |
RU (1) | RU2357833C2 (en) |
TW (1) | TWI324952B (en) |
WO (1) | WO2005044487A1 (en) |
ZA (1) | ZA200604177B (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5159775B2 (en) * | 2006-07-07 | 2013-03-13 | ロテレツク | Method and apparatus for continuous casting of flat metal products with electromagnetic stirring |
FR2957829B1 (en) | 2010-03-23 | 2012-11-09 | Rotelec Sa | BRUSSE ROLLER FOR BRAMES CONTINUOUS CASTING MACHINE |
RU2457064C1 (en) | 2011-03-03 | 2012-07-27 | Федеральное Государственное Автономное Образовательное Учреждение Высшего Профессионального Образования "Сибирский Федеральный Университет" (Сфу) | Method of continuous and semicontinuous casing of aluminium alloys and device to this end |
RU2464123C1 (en) * | 2011-11-25 | 2012-10-20 | Открытое акционерное общество Акционерная холдинговая компания "Всероссийский научно-исследовательский и проектно-конструкторский институт металлургического машиностроения имени академика Целикова" (ОАО АХК "ВНИИМЕТМАШ") | Method of adjusting conditions of electromagnetic mixing of ingot liquid phase in slab continuous casting machine and device to this end |
US20150290703A1 (en) * | 2012-03-27 | 2015-10-15 | Rotelec | Stirring-roll for a continuous cast machine of metallic products of large cross section |
JP6087155B2 (en) * | 2013-01-23 | 2017-03-01 | 株式会社神戸製鋼所 | Continuous casting method of slab made of titanium or titanium alloy |
JP6625065B2 (en) | 2014-05-21 | 2019-12-25 | ノベリス・インコーポレイテッドNovelis Inc. | Non-contact control of molten metal flow |
CN112687419B (en) * | 2020-12-18 | 2022-04-12 | 岭东核电有限公司 | Metal removing well for spent fuel and method for removing liquid metal on spent fuel |
CN112876043B (en) * | 2021-02-24 | 2022-08-02 | 成都贝施美生物科技有限公司 | Glass ceramic preparation mould capable of realizing rapid demoulding |
CN116121610A (en) * | 2022-12-30 | 2023-05-16 | 湖南稀土金属材料研究院有限责任公司 | Magnesium-zirconium intermediate alloy and preparation method thereof |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2358223A1 (en) * | 1976-07-13 | 1978-02-10 | Siderurgie Fse Inst Rech | PROCESS FOR ELECTROMAGNETIC BREWING OF MOLTEN METALS DURING CONTINUOUS CASTING OPERATIONS |
FR2358222A1 (en) * | 1976-07-13 | 1978-02-10 | Siderurgie Fse Inst Rech | NEW PROCESS AND DEVICE FOR THE ELECTROMAGNETIC BREWING OF CONTINUOUS FLOWING METAL PRODUCTS |
JPS5813263B2 (en) * | 1977-01-11 | 1983-03-12 | 住友金属工業株式会社 | Continuous casting method |
US4158380A (en) * | 1978-02-27 | 1979-06-19 | Sumitomo Metal Industries Limited | Continuously casting machine |
FR2485411B1 (en) * | 1980-06-27 | 1985-11-08 | Siderurgie Fse Inst Rech | ELECTROMAGNETIC CONTINUOUS CASTING LINGOTIERE OF METAL PRODUCTS WITH EXTENDED RECTANGULAR SECTION |
JPS6037251A (en) * | 1983-08-11 | 1985-02-26 | Kawasaki Steel Corp | Electromagnetic stirring method of molten steel for continuous casting mold |
JPS6333160A (en) * | 1986-07-28 | 1988-02-12 | Nippon Kokan Kk <Nkk> | Continuous casting method |
CA2059030C (en) * | 1992-01-08 | 1998-11-17 | Jun Kubota | Method for continuous casting of slab |
DE19542211B4 (en) * | 1995-11-13 | 2005-09-01 | Sms Demag Ag | Electromagnetic stirring device for a slab casting mold |
CN1139447C (en) * | 1996-05-13 | 2004-02-25 | 株式会社英比寿 | Method and apparatus for continuous casting |
JPH11320054A (en) * | 1998-05-20 | 1999-11-24 | Nippon Steel Corp | Continuous caster and continuous casting method |
JPH11320051A (en) * | 1998-05-20 | 1999-11-24 | Nippon Steel Corp | Continuous casting apparatus and continuous casting method |
JP2000317593A (en) * | 1999-05-12 | 2000-11-21 | Nippon Steel Corp | Method for continuously casting molten steel |
CN1142045C (en) * | 1999-09-22 | 2004-03-17 | 大连理工大学 | Continuous metal casting method with applied composite electromagnetic field |
CN1196548C (en) * | 2000-03-09 | 2005-04-13 | 杰富意钢铁株式会社 | Production method for continuous casting cast billet |
SE519840C2 (en) * | 2000-06-27 | 2003-04-15 | Abb Ab | Method and apparatus for continuous casting of metals |
JP4254576B2 (en) * | 2004-02-27 | 2009-04-15 | Jfeスチール株式会社 | Steel continuous casting apparatus and continuous casting method |
-
2003
- 2003-10-27 FR FR0312555A patent/FR2861324B1/en not_active Expired - Fee Related
-
2004
- 2004-10-22 RU RU2006118350/02A patent/RU2357833C2/en active
- 2004-10-22 EP EP04805290A patent/EP1677928B1/en active Active
- 2004-10-22 WO PCT/FR2004/002728 patent/WO2005044487A1/en active IP Right Grant
- 2004-10-22 JP JP2006536133A patent/JP4758903B2/en active Active
- 2004-10-22 ES ES04805290T patent/ES2285558T3/en active Active
- 2004-10-22 BR BRPI0415903-9A patent/BRPI0415903B1/en active IP Right Grant
- 2004-10-22 DE DE602004006010T patent/DE602004006010T2/en active Active
- 2004-10-22 CN CNB2004800290865A patent/CN100371108C/en active Active
- 2004-10-22 CA CA002543368A patent/CA2543368A1/en not_active Abandoned
- 2004-10-22 AT AT04805290T patent/ATE359886T1/en active
- 2004-10-22 ZA ZA200604177A patent/ZA200604177B/en unknown
- 2004-10-22 US US10/577,461 patent/US20070074845A1/en not_active Abandoned
- 2004-10-22 AU AU2004286877A patent/AU2004286877B2/en not_active Ceased
- 2004-10-22 KR KR1020067008191A patent/KR101089261B1/en active IP Right Grant
- 2004-10-27 TW TW093132533A patent/TWI324952B/en active
Non-Patent Citations (1)
Title |
---|
See references of WO2005044487A1 * |
Also Published As
Publication number | Publication date |
---|---|
TWI324952B (en) | 2010-05-21 |
BRPI0415903B1 (en) | 2012-08-07 |
JP4758903B2 (en) | 2011-08-31 |
RU2006118350A (en) | 2007-12-10 |
CA2543368A1 (en) | 2005-05-19 |
RU2357833C2 (en) | 2009-06-10 |
AU2004286877A1 (en) | 2005-05-19 |
KR101089261B1 (en) | 2011-12-02 |
JP2007509752A (en) | 2007-04-19 |
ES2285558T3 (en) | 2007-11-16 |
DE602004006010T2 (en) | 2007-12-13 |
EP1677928B1 (en) | 2007-04-18 |
US20070074845A1 (en) | 2007-04-05 |
FR2861324B1 (en) | 2007-01-19 |
CN100371108C (en) | 2008-02-27 |
TW200533437A (en) | 2005-10-16 |
BRPI0415903A (en) | 2007-01-16 |
CN1863625A (en) | 2006-11-15 |
AU2004286877B2 (en) | 2009-09-10 |
ZA200604177B (en) | 2007-12-27 |
WO2005044487A1 (en) | 2005-05-19 |
KR20060120054A (en) | 2006-11-24 |
ATE359886T1 (en) | 2007-05-15 |
FR2861324A1 (en) | 2005-04-29 |
DE602004006010D1 (en) | 2007-05-31 |
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