EP1636110B1 - Verschlussvorrichtung für behälter für flüssigkeiten, insbesondere flaschen für spirituosen - Google Patents

Verschlussvorrichtung für behälter für flüssigkeiten, insbesondere flaschen für spirituosen Download PDF

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Publication number
EP1636110B1
EP1636110B1 EP04736514A EP04736514A EP1636110B1 EP 1636110 B1 EP1636110 B1 EP 1636110B1 EP 04736514 A EP04736514 A EP 04736514A EP 04736514 A EP04736514 A EP 04736514A EP 1636110 B1 EP1636110 B1 EP 1636110B1
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EP
European Patent Office
Prior art keywords
stopper
cap
closure device
weakening line
annular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP04736514A
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English (en)
French (fr)
Other versions
EP1636110A1 (de
Inventor
Piero Battegazzore
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guala Closures Patents BV
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Guala Closures Patents BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Guala Closures Patents BV filed Critical Guala Closures Patents BV
Priority to PL04736514T priority Critical patent/PL1636110T3/pl
Publication of EP1636110A1 publication Critical patent/EP1636110A1/de
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D55/00—Accessories for container closures not otherwise provided for
    • B65D55/02—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure
    • B65D55/06—Deformable or tearable wires, strings, or strips; Use of seals, e.g. destructible locking pins
    • B65D55/08—Annular elements encircling container necks
    • B65D55/0863—Plastic snap-on cap-like collars having frangible parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/32—Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
    • B65D41/34—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
    • B65D41/3495—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt the tamper element being bonded or adhered to the container wall
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D49/00—Arrangements or devices for preventing refilling of containers
    • B65D49/02—One-way valves

Definitions

  • the present invention relates to a closure device for containers of liquids, particularly bottles for liquors, with an opening located at the end of a neck which extends axially from the body of the container along a longitudinal axis (X-X), comprising a pouring body provided with an internal cavity and a pouring aperture, positioned on the said opening and extending coaxially with, and outside, the neck, in the opposite direction to the body of the container, a valve member located between the said cavity of the said pouring body and movable axially with respect to an annular stop to allow the outflow of the liquid and prevent its fraudulent introduction, a tubular element comprising a first stopper-like portion and a second sleeve-like portion which extends axially along the outer wall of the neck, the said first stopper-like portion and the said second sleeve-like portion forming a so called tube-stopper element and being interconnected axially by a circumferential weakening line, the said first stopper-like portion being engaged with the pouring
  • Closures are known in the prior art and are used for closing bottles of valuable liquors, providing them with a seal which guarantees the integrity of the closure by making any previous opening visible and providing evidence as far as possible of any attempt to tamper with the seal.
  • the sealing function is provided by a stopper-like element which is placed on top of the stopper portion of the tubular element and which is extended axially by an annular strip connected by means of a circumferential weakened line consisting, for example, of cuts separated by breakable links.
  • the outer stopper is fixed to the underlying stopper portion both axially and rotationally, while the annular strip is connected to the sleeve-like portion of the tubular element by means of corresponding radial teeth, in a position below the weakening line which connects the aforesaid two portions.
  • the outer stopper or over stopper may be made of adequate plastic material or, in view of specific needs, may be made in form of a metallic sheet capsule.
  • a tube-stopper element provided with means capable to match with an outer stopper or over stopper made either of plastic material, with or without conventional security breakable strips, or in the form of a metallic sheet capsule, with or without weakening line.
  • a further object of the present invention is to devise a closure of the aforementioned type which has sealing characteristics such that the above mentioned drawback can be overcome.
  • the closure comprises a pouring body 1 provided with an inner cavity 2 and a pouring aperture 3.
  • This pouring body 1 is positioned on the rim 4 of the opening 5 of the neck 6 of a container, particularly a bottle, whose body is indicated schematically at 7.
  • the bottle is intended particularly, but not exclusively, to contain valuable liquors whose originality and genuineness is to be guaranteed by means of the security imparted by the closure according to the invention.
  • the pouring body 1 is positioned on the rim 4 by means of the interposition of a fixing and sealing collar 8, or directly by other conventional means.
  • valve member 9 allows the outflow of the liquid from the pouring aperture 3 but prevents its fraudulent introduction.
  • the closure also comprises a tubular element, indicated as a whole by 11, consisting of a first stopper-like portion 12, the outer surface of which is preferably knurled, and a second sleeve-like portion 13.
  • the two portions 12 and 13 are interconnected axially by a weakening line 14 formed in a conventional way by circumferential cuts separated by breakable links, not shown in the drawings.
  • the stopper-like portion 12 comprises a wall 15 transverse with respect to the axis X-X, which closes the upper end of the tubular element 11.
  • the said wall 15 has a collar 16 which projects towards the cavity 2 of the pouring body 1 and is designed to engage axially with the pouring aperture 3 in order to close it.
  • the said portion 12 is superimposed on the underlying pouring body 1 with which it is engaged by screw means consisting of the threads 17 and 18 which allow the pouring aperture 3 to be opened and closed when the container is in use.
  • the sleeve-like portion 13 is provided with conventional means, indicated schematically at 19 and 20, for its axial and circumferential engagement with the underlying part of the pouring body in such a way that axial and rotary displacements between these parts are prevented and consequently the unscrewing and re-screwing of the stopper portion 12 is permitted by the breaking of the links of the weakening line 14 when the closure is opened for the first time.
  • the closure according to the invention comprises a cap-like seal, indicated as a whole by 21, which is fitted on top of the said stopper-like portion 12.
  • the cap 21 consists of a top wall 22, transverse with respect to the axis X-X, and an annular strip 23 which extends axially over the stopper-like portion 12 to a point beyond the said weakening line 14.
  • the first annular rib 25 is positioned axially above the weakening line 14 whereas the second annular rib 27 is positioned axially below the weakening line 14.
  • each embossed sector 24 and 26 is essentially triangular with the vertex pointing towards the axis X-X of the neck.
  • the respective lower sides 24a and 26a are inclined, but the respective upper sides 24b and 26b are positioned essentially perpendicularly to the axis X-X of the neck.
  • annular ribs 25 and 27 are provided with planes inclined downwards with respect to the container on their upper faces 25a and 27a to assist the axial movement of the sectors 24 and 26 during the application of the cap 21, but are provided with planes which are practically perpendicular to the axis X-X on their opposite faces.
  • the said upper faces 25a and 27a of the ribs 25 and 27 may also be perpendicular to the axis X-X as theirs opposite faces.
  • the inclined planes are provided on the sectors 24 and 26 to assist the axial movement during the application of the cap 21.
  • the configuration of the ribs 25 and 27 with lower planes perpendicular to the axis X-X, against which the corresponding upper sides 24b and 26b of the sectors 24 and 26 are positioned, is such that the sectors 24 and 26 can pass over these steps solely and exclusively as a result of a substantial radial deformation of the wall forming the strip 23 of the cap, causing the formation of irreversible bends, cracks and color variations which provide evidence of an attempt to tamper with the cap.
  • ABS acrylonitrile butadiene styrene
  • the end wall 22 of the capsule 21 is provided with at least one tab or tag 29 formed in the said wall by a circular cut 30 which leaves an intact portion 31 about which the tag can be bent when raised from the plane of the wall.
  • the circular cut 30 is extended at the sides of the portion 31 with continuations 32 and 33 in line with which the axial weakening lines 34 and 35 respectively are formed on the inner surface 23a.
  • the aforesaid weakening lines preferably extend from the level of the aperture 3 of the pouring body 1 substantially as far as the area where the embossed sectors 26 are formed.
  • the cap 21 For the first authorized opening of the closure, the cap 21 must first be removed by raising the tab 29 and pulling it so that it rotate about the portion 31, continuing by tearing the area "S" of the wall 23 lying between the axial weakening lines 34 and 35.
  • the tearing causes the breakage of the cap 21 which can no longer be reconstituted, even in a fraudulent way.
  • the said cap is provided with further axial cuts 36 and 37 which extend partially across the strip 23 in the proximity of the transverse wall 22.
  • the aforesaid cuts 36 and 37 allow the cap to be bent about at least one of the generatrices of the tubular strip 23 and consequently allow the removal and practical destruction of the cap.
  • the cap 21 can alternatively be broken and removed by means of a single weakening line with the tear tab positioned at the side of this weakening.
  • the second embodiment of the closure according to the invention principally differs from the first, illustrated in Figure 1 , in that the tubular strip 23 of the cap 21 is provided with an annular terminal area 38 connected to the tubular strip 23 by a circumferential weakening line 39 consisting of cuts 40 separated by breakable links 41.
  • the set of embossed sectors 26 is positioned in the terminal area 38 and that the pair of axial weakening lines 34 and 35 stop at the position of the said circumferential weakening line 39.
  • tab 29 for tearing the cap is replaced by a corresponding pair of tabs 42 and 43 formed by cutting in the wall 22 of the cap.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Beverage Vending Machines With Cups, And Gas Or Electricity Vending Machines (AREA)

Claims (13)

  1. Verschlussvorrichtung für Behälter für Flüssigkeiten, im Besonderen Flaschen für Spirituosen, die eine Öffnung (5) aufweisen, die sich am Ende eines Halses (6) befindet, der axial vom Körper (7) des Behälters entlang der Längsachse (X-X) verläuft, einen Ausgießkörper (1) aufweisend, der mit einem Innenhohlraum (2) und einer Ausgießöffnung (3) vorgesehen ist, die an der Öffnung (5) angeordnet ist und sich koaxial zum Hals (6) und außerhalb davon in der Richtung abgewandt zum Körper (7) des Behälters erstreckt, wobei ein Ventil (9) sich in dem Hohlraum (2) des Ausgießkörpers (1) befindet und axial bezüglich eines ringförmigen Stopps (10) bewegbar ist, um das Hinausfliessen der Flüssigkeit zu erlauben und betrügerisches Einfüllen zu verhindern, wobei ein röhrenförmiges Element (11), das einen ersten verschlussartigen Bereich (12) und einen zweiten hülsenartigen Bereich (13) aufweist, der axial entlang der Außenwand des Halses (6) verläuft, wobei der erste verschlussartige Bereich (12) und der zweite hülsenartige Bereich (13) ein so genanntes Röhren-Verschluss-Element bilden und miteinander durch eine axial umlaufende Schwächungslinie (14) verbunden sind, wobei der erste verschlussartige Bereich (12) in das Ausgießelement (1) durch Verschrauben (17, 18) zum Öffnen und Schließen der Ausgießöffnung (3) eingreift, und die entfernbaren Dichtmittel das erste Öffnen des Verschlusses erlauben, wobei das Röhren-Verschluss-Element mit wenigstens einer ringförmigen Rippe (25) vorgesehen ist, die radial von der Außenfläche davon hervorsteht und axial über der Abschwächungslinie (14) positioniert ist,
    dadurch gekennzeichnet, dass
    das Röhren-Verschluss-Element weiterhin mit wenigstens einer zweiten ringförmigen Rippe (27) vorgesehen ist, die von der Außenseite davon hervorsteht und axial unterhalb der Abschwächungslinie (14) positioniert ist, wobei die erste und zweite Rippe Verbindungsmittel zwischen den entfernbaren Dichtmitteln und dem Röhren-Verschluss-Element bilden.
  2. verschlussvorrichtung gemäß Anspruch 1,
    dadurch gekennzeichnet, dass
    die Dichtmittel eine Kappe (21) aufweisen, die an der Oberseite des verschlussartigen Bereichs (12) befestigt ist und axial mit einem ringförmigen Streifen (23) von der Oberseite (15) des verschlussartigen Bereichs zu einem Punkt über die umlaufende Abschwächungslinie (14), die den ersten und zweiten Bereich des röhrenförmigen Elements (11) verbindet, hinaus verläuft, wobei die Kappe (21) mit wenigstens einer Abschwächungslinie (34, 35) bereitgestellt ist, die axial entlang dem ringförmigen Streifen (23) davon wenigstens von der Ebene der Ausgießöffnung (3) im Wesentlichen so weit bis zu einer Zone unter der umlaufenden Abschwächungslinie (14) des röhrenförmigen Elements (11) verläuft, wobei wenigstens eine Nase (29) an der Oberseite (22) der Kappe (21) nahe dem Verschluss zum Ziehen der "S"-Zone des ringförmigen Streifens (23), der an der Seite der axialen Abschwächungslinie (34, 35) angeordnet ist, vorgesehen ist, was bewirkt, dass die Kappe (21) abreißt.
  3. Verschlussvorrichtung gemäß den Ansprüchen 1 und 2, dadurch gekennzeichnet, dass die Kappe (21) ein Paar axialer Schwächungslinien (34, 35) aufweist, die von einander beabstandet sind, wobei die "S"-Zone des Streifens zwischen den Linien liegt und durch Abreißen entfernbar ist.
  4. Verschlussvorrichtung gemäß den Ansprüchen 1 bis 3,
    dadurch gekennzeichnet, dass
    die Schwächungslinien (34, 35) aus Einschnitten bestehen, die an der Innenseite (23a) der Kappe (21) vorgenommen wurden, die nicht durch die Dicke der Kappe durchgehen.
  5. Verschlussvorrichtung gemäß den Ansprüchen 1 bis 4,
    dadurch gekennzeichnet, dass
    die Kappe (21) auf der Innenseite (23a) des Bereichs des ringförmigen Streifens, in dem die axialen Abschwächungslinien ausgebildet sind, mit wenigstens einer ersten Gruppe von eingeprägten umlaufenden Sektoren (24) zum Eingriff unter eine entsprechende ringförmige Rippe (25), die von der Außenseite des ersten verschlussartigen Bereichs (12) des röhrenförmigen Elements (11) gestützt wird, vorgesehen ist.
  6. Verschlussvorichtung gemäß den Ansprüchen 1 bis 5,
    dadurch gekennzeichnet, dass
    die Kappe (21) auf der Innenseite (23a) des Bereichs des ringförmigen Streifens, in dem die axiale Schwächungslinien ausgebildet sind, mit einer zweiten Gruppe von eingeprägten umlaufenden Sektoren (26) zum Eingriff unter eine entsprechende ringförmige Rippe (27), die von dem hülsenartigen Bereich (13) des röhrenförmigen Elements (11) gestützt wird, vorgesehen ist.
  7. Verschtussvorrichtung gemäß Anspruch 1 bis 6,
    dadurch gekennzeichnet, dass
    jeder geprägte umlaufende Sektor der ersten (24) und zweiten (26) Gruppe von Sektoren einen im Wesentlichen dreieckigen Querschnitt aufweist, bei dem der Scheitel in Richtung der Längsachse (X-X) des Halses (6) des Behälters zeigt und wobei die Oberseite (24b, 26b) zum Eingriff in die entsprechende Unterseite der ringförmigen Rippen (25, 27) des röhrenförmigen Elements (11) im Wesentlichen senkrecht zur Längsachse (X-X) angeordnet ist,
  8. Verschlussvorrichtung gemäß den Ansprüchen 1 bis 7,
    dadurch gekennzeichnet, dass
    die Kappe (21) einen ringförmigen Abschlussbereich (38) aufweist, der axial mit dem ringförmigen Streifen (23) durch eine umlaufende Schwächungslinie (39) verbunden ist.
  9. Verschlussvorrichtung gemäß Anspruch 8,
    dadurch gekennzeichnet, dass die axialen Schwächungslinien (34, 35) an der Position der umlaufenden Schwächungslinie (39) aufhören.
  10. Verschlussvorrichtung gemäß den Ansprüchen 1 bis 9,
    dadurch gekennzeichnet, dass die umlaufende Schwächungslinie (39) aus einer Vielzahl von Schnitten (40) besteht, die sich mit abreißbaren Verbindungen (41) abwechseln, und zwischen der ersten (24) und der zweiten (26) Gruppe an geprägten umlaufenden Sektoren angeordnet ist.
  11. Verschlussvorrichtung gemäß den Ansprüchen 1 bis 10,
    dadurch gekennzeichnet, dass die Oberseite der Kappe (21) aus einer Wand (22) besteht, die quer zur Längsachse (X-X) des Halses (6) verläuft, die zwei Nasen (42, 43) aufweist, die zum Aufreißen der "S"-Zone, die zwischen den Paaren axialer Schwächungslinien (34, 35) liegt, nebeneinander angeordnet sind.
  12. Verschlussvorrichtung gemäß den Ansprüchen 1 bis 11,
    dadurch gekennzeichnet, dass
    die Kappe (21) axiale Einschnitte (36, 37) aufweist, die nahe der oberen Wand (22) ausgebildet sind, damit der röhrenförmige Streifen (23) entlang wenigstens einer der axialen Erzeugenden, die durch wenigstens eine der Einschnitte (36, 37) durchgehen, davon gebogen werden kann, und um das vollständige Entfernen der Kappe (21) von dem verschlussartigen Bereich (12) zu erleichtern, was auf das Abreißen der "S"-Zone folgt, die zwischen den axialen Abschwächungslinien (34, 35) liegt.
  13. Verschlussvorrichtung gemäß Anspruch 1,
    dadurch gekennzeichnet, dass die entfernbaren Dichtmittel ein Überverschluss in Form einer aus einem Metallblech hergestellten Kapsel sind, die mit dem Röhren-Verschluss-Element durch eine Einrollung verbunden ist, die unter der ersten ringförmigen Rippe (25) des Röhren-Verschluss-Elements vorgesehen ist.
EP04736514A 2003-06-24 2004-06-10 Verschlussvorrichtung für behälter für flüssigkeiten, insbesondere flaschen für spirituosen Expired - Lifetime EP1636110B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL04736514T PL1636110T3 (pl) 2003-06-24 2004-06-10 Urządzenie zamykające do pojemników na ciecze, w szczególności butelek na alkohole

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT001279A ITMI20031279A1 (it) 2003-06-24 2003-06-24 Dispositivo di chiusura per contenitori di liquidi, particolarmente bottiglie per liquori.
PCT/EP2004/006722 WO2005000701A1 (en) 2003-06-24 2004-06-10 Closure device for containers of liquids, particularly bottles for liquors

Publications (2)

Publication Number Publication Date
EP1636110A1 EP1636110A1 (de) 2006-03-22
EP1636110B1 true EP1636110B1 (de) 2009-12-09

Family

ID=30131278

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04736514A Expired - Lifetime EP1636110B1 (de) 2003-06-24 2004-06-10 Verschlussvorrichtung für behälter für flüssigkeiten, insbesondere flaschen für spirituosen

Country Status (13)

Country Link
EP (1) EP1636110B1 (de)
CN (1) CN100540410C (de)
AT (1) ATE451310T1 (de)
BR (1) BRPI0411879B1 (de)
CO (1) CO5700806A2 (de)
DE (1) DE602004024527D1 (de)
EA (1) EA007245B1 (de)
ES (1) ES2261010B1 (de)
IT (1) ITMI20031279A1 (de)
MX (1) MXPA05013644A (de)
PL (1) PL1636110T3 (de)
UA (1) UA81958C2 (de)
WO (1) WO2005000701A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006085787A1 (en) * 2005-02-10 2006-08-17 Prozumenshchikov Andrey Boriso Bottle closure used in alcoholic beverage industry
EA200500559A1 (ru) * 2005-04-28 2006-04-28 Иностранное Унитарное Производственное Предприятие Компании "Белкапс Бетайлингус Гмбх" Белкэпс Укупорочное устройство для бутылки (варианты)
WO2007059658A1 (fr) * 2005-11-28 2007-05-31 Laixing Zhao Capsule inviolable duale, ouvrable vers le haut, dechirable pour bouteille de vin
ES2333569B1 (es) * 2008-02-08 2011-01-11 Compañia De Tapones Irrellenables S.A. Capsula para un cierre de botellas.
DE102014018155A1 (de) * 2014-12-10 2016-06-16 Hsil Limited Originalitätsverschluss für eine Zugangsöffnung eines Behälters, insbesondere einer Flasche

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2666307A1 (fr) * 1990-09-04 1992-03-06 Grupo Stevi Sa Bouchon inviolable pour bouteilles.
IT1275779B1 (it) * 1995-07-06 1997-10-17 Guala Spa Chiusura di garanzia per bottiglie per liquori di pregio
EP0918700A2 (de) * 1996-07-30 1999-06-02 DANIEL MONTGOMERY & SON LIMITED Nichtdemontierbare verschlussanordnung
NL1004376C2 (nl) * 1996-10-29 1998-05-06 Guala Patents Bv Veiligheidssluiting voor een fles voor waardevolle dranken.
EP0985607A1 (de) * 1998-07-28 2000-03-15 Guala Closures S.P.A. Sicherheitsverschluss
IT1301982B1 (it) * 1998-07-31 2000-07-20 Guala Closures Spa Dispositivo di chiusura con sigillo per contenitori di liquidi.
NL1016994C1 (nl) * 2000-12-27 2002-06-28 Guala Closures Patents Bv Veiligheidssluiting voor vloeistofhouders.

Also Published As

Publication number Publication date
CO5700806A2 (es) 2006-11-30
EP1636110A1 (de) 2006-03-22
ES2261010B1 (es) 2007-10-01
DE602004024527D1 (de) 2010-01-21
ITMI20031279A1 (it) 2004-12-25
ITMI20031279A0 (it) 2003-06-24
EA007245B1 (ru) 2006-08-25
CN100540410C (zh) 2009-09-16
CN1809499A (zh) 2006-07-26
ATE451310T1 (de) 2009-12-15
ES2261010A1 (es) 2006-11-01
WO2005000701A1 (en) 2005-01-06
EA200600094A1 (ru) 2006-06-30
PL1636110T3 (pl) 2010-07-30
UA81958C2 (uk) 2008-02-25
BRPI0411879A (pt) 2006-08-08
BRPI0411879B1 (pt) 2014-11-18
MXPA05013644A (es) 2006-05-25

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