EP1627144A1 - Cylinder liner, method for the production thereof and a combined - Google Patents
Cylinder liner, method for the production thereof and a combinedInfo
- Publication number
- EP1627144A1 EP1627144A1 EP04729862A EP04729862A EP1627144A1 EP 1627144 A1 EP1627144 A1 EP 1627144A1 EP 04729862 A EP04729862 A EP 04729862A EP 04729862 A EP04729862 A EP 04729862A EP 1627144 A1 EP1627144 A1 EP 1627144A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cylinder liner
- layer
- alloy
- tread
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
- F02F1/02—Cylinders; Cylinder heads having cooling means
- F02F1/10—Cylinders; Cylinder heads having cooling means for liquid cooling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
- F02F1/18—Other cylinders
- F02F1/20—Other cylinders characterised by constructional features providing for lubrication
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/131—Wire arc spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/14—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying for coating elongate material
- C23C4/16—Wires; Tubes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B77/00—Component parts, details or accessories, not otherwise provided for
- F02B77/02—Surface coverings of combustion-gas-swept parts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
- F02F1/02—Cylinders; Cylinder heads having cooling means
- F02F1/10—Cylinders; Cylinder heads having cooling means for liquid cooling
- F02F1/16—Cylinder liners of wet type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49229—Prime mover or fluid pump making
- Y10T29/49231—I.C. [internal combustion] engine making
- Y10T29/49233—Repairing, converting, servicing or salvaging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49229—Prime mover or fluid pump making
- Y10T29/4927—Cylinder, cylinder head or engine valve sleeve making
- Y10T29/49272—Cylinder, cylinder head or engine valve sleeve making with liner, coating, or sleeve
Definitions
- the present invention relates to a liner for a crankcase according to the preamble of claim 1 and a method for its production according to the preamble of claims 18 and 20 respectively.
- Generic liners are known. They are located in the cylinder bores of the crankcase of internal combustion engines and serve to provide suitable tribological running surfaces for the pistons accommodated in the cylinder bores. Light-alloy die-cast crankcases with cast-in liners made of aluminum materials (Silitec 5, Alusil, Locasil, etc.) are usually used. The liners can also be made of gray cast iron or ceramic materials and, especially in gray cast iron housings, can also be pressed in instead of cast in.
- Such liners or their tribological running surfaces are subject to wear over time. If there is a certain wear rate, the liner must be repaired. To do this, the worn bushing is turned down to a certain dimension (e.g. 0.3 mm), honed and then exposed. This creates a new tribological tread. Then new pistons with rings are attached to the new diameter of the liners. fits. These pistons are about a factor of 3 to 4 more expensive than series pistons because they are made to order.
- the ÜS-4,918,805 A describes a welding process for repairing cylinder heads for diesel engines, in which cracks in the cylinder head are welded with various metal alloys.
- welding processes are not suitable for the repair of tribological treads, since the desired friction or Running properties can not be achieved.
- DE 28 41 446 C2 discloses a method for producing a composite body from a metal part and a light metal casting layer, in which an intermediate layer made of aluminum or an aluminum alloy is applied to the metal part by high-temperature spraying and the casting layer is then cast from an aluminum alloy.
- DE 38 16 348 AI discloses a method for producing composite metal workpieces, in which the surface of a workpiece to be coated is roughened and provided with a coupling layer, for example in the form of a low-melting metal alloy such as a nickel-based alloy. The workpiece is then heated to the flow temperature of the coupling layer and cast.
- the object of the present invention is therefore to provide a liner and a method of the type mentioned above, which enable simple and inexpensive repair of tribological treads of liners.
- the solution consists in a liner with the features of claim 1, a composite part with the features of claim 10 and a method with the features of claims 18 and 20.
- the cylinder liner has at least one thermally sprayed layer on its worn tread.
- the surprising advantage of the present invention is that cylinder liners made of different materials, namely gray cast iron, an aluminum material or a ceramic material, can be repaired or replaced in the same way.
- the direct application of at least one thermally sprayed layer, at least the uppermost exposed layer having tribological properties, makes it possible to adapt the inside diameter of the cylinder liner again to the dimensions of the pistons (with rings) produced in series.
- an effective and inexpensive repair of worn treads can be carried out without having to adapt new pistons (with new rings). In the best case scenario, the costs can be reduced by a factor of 3 to 4.
- One of the two particularly preferred variants of the present invention provides that exactly one is thermally sprayed Layer is provided, namely a layer of a low-alloy Fe-base alloy, preferably a low-alloy Fe-C alloy, thermally sprayed onto the worn tread.
- this alloy is suitable for cylinder pistons or running surfaces made of any material and has suitable adhesive properties on the worn running surface.
- Such an alloy is preferably applied by means of arc wire spraying, it being possible for one or two wires made of the alloy used in each case to be used as the spray material.
- This layer has tribological properties and can be honed in the usual way and exposed if necessary, so that a new tread is created.
- the inside diameter of the cylinder liner provided with this new tread can again be adapted to the dimensions of the series-produced pistons (with rings). Therefore, the thickness of the newly applied layer also depends on the degree of adjustment of the inner diameter.
- the second particularly preferred variant of the present invention provides that the cylinder liner has an adhesion promoter layer on the worn tread which consists of a nickel-aluminum alloy made of 80 to 95% by weight of nickel and 5 to 20% by weight of aluminum, wherein a new layer serving as a tribological tread is applied to the adhesion promoter layer.
- an adhesion promoter layer on the worn tread which consists of a nickel-aluminum alloy made of 80 to 95% by weight of nickel and 5 to 20% by weight of aluminum, wherein a new layer serving as a tribological tread is applied to the adhesion promoter layer. It is surprising to the person skilled in the art that the composition of the nickel-aluminum alloy also ensures a firm and uniformly good connection between the material of the cylinder liner or the worn tread and the newly applied layer. In addition, there are no gaps or separations in the area of the connection.
- the adhesion promoter layer in particular has a thickness of 50 to 200 ⁇ m, preferably 100 ⁇ m, and is preferably applied to the inner surface of the cylinder liner by means of plasma spraying.
- a powder of the same material as the adhesion promoter layer that is to say a nickel-aluminum alloy composed of 80 to 95% by weight of nickel and 5 to 20% by weight of aluminum, is preferably used for plasma spraying.
- the new layer serving as a tribological tread preferably consists of the same material as the cylinder liner or the old, worn tread. This also eliminates the need to adapt the pistons to new tread materials and the previous running properties of the engine can be restored.
- the cylinder liner can be manufactured in a manner known per se from gray cast iron or an aluminum material, preferably an Al-Si alloy which is hypereutectic to Si, as are known, for example, under the trade names Silitec 5, Aluil etc.
- the cylinder liner can also be made from ceramic materials, for example oxide ceramics, ceramic-metal composite materials, silicon carbide ceramics or fiber-reinforced SiC / SiC or C / SiC ceramics.
- pretreat, especially roughen, the worn tread before applying the first thermally sprayed layer for example by means of high-pressure water jets or corundum jets, in order to further improve the adhesion between the worn tread and the first thermally sprayed layer.
- high-pressure water jets or corundum jets for example by means of high-pressure water jets or corundum jets, in order to further improve the adhesion between the worn tread and the first thermally sprayed layer.
- the method according to the invention can be used to machine liners made from a wide variety of materials, as has already been explained above.
- DE 197 17 825 AI describes, for example, a crankcase made of an aluminum-based alloy (such as AlSi8Cu, AlSi9Cu, AlSilOCu as near-eutectic alloys) with a layer of aluminum nitride which is firmly anchored in the base material and is homogeneous in terms of structure as a tread.
- an aluminum-based alloy such as AlSi8Cu, AlSi9Cu, AlSilOCu as near-eutectic alloys
- a cylinder liner made of a hypereutectic aluminum-silicon alloy which has fine silicon primary crystals and intermetallic phases in the form of hard particles.
- a material of this type is surface-treated by making a fine bore in a first step. The surface is then smoothed by honing. In series production, this takes place in at least two work steps, which are referred to as pre-honing and finishing honing.
- pre-honing and finishing honing In a final step, the silicon particles contained in the alloy, which form the actual running surface, are exposed by etching aluminum out with the aid of an aqueous solution of an acid.
- % Manganese, copper, nickel and zinc, the rest aluminum, is cleaned for pretreating the worn tribological surface, e.g. sandblasted and if necessary roughened, e.g. by high pressure water jets or corundum jets.
- the surface pretreated in this way is provided with an adhesive layer made of an adhesive layer material with 80-95% by weight of nickel and 20-5% by weight of aluminum.
- the adhesive layer material is in the form of an alloy in powder form and is applied by means of plasma spraying methods known per se, as described, for example, in DE 195 08 687 C2.
- the thickness of the adhesive layer is such that the worn tread including all roughness and depressions is completely covered by the adhesive layer. At the thinnest points, the thickness of the adhesive layer should be about 0.05 to 0.1 mm.
- a new tribological layer made of the same material as the liner is applied to the adhesive layer. In this case too, this is done using pias maspritzvon as described in DE 197 33 204 AI and DE 197 33 205 AI. This new layer in turn serves as the tread of the repaired liner.
- the thickness of the tribological layer is dimensioned so that the usual diameter of the liner is restored during the usual reworking (honing, exposing), so that the piston (with rings) manufactured in series can be fitted.
- the adhesive layer binds to the worn surface of the liner before it solidifies, the two layers penetrating into one another about 0.01 to 0.1 mm deep. The same applies to the connection of the adhesive layer with the newly applied tribological layer.
- a worn cylinder liner of 140 mm high and 93 mm diameter made of the material Silitec 5 was treated in a comparable manner.
- the worn tribological tread was cleaned by sandblasting and then coated with a 100 ⁇ m thick adhesion promoter layer made of 95% by weight of nickel and 5% by weight of aluminum by means of plasma spraying.
- the adhesion promoter layer was also coated with a new layer of Silitec 5, which serves as a tribological tread, by means of plasma spraying. This layer was then honed and exposed as usual, the inner diameter of the cylinder liner being adapted to the dimensions of the desired series pistons (with rings).
- thermal spraying instead of plasma spraying, other thermal spraying methods such as flame spraying and arc wire spraying can also be used.
- the choice of the thermal spraying method depends on the material of the cylinder liner and the adhesive layer and on the type of microstructure desired. These criteria can be matched to one another in a manner known per se by the person skilled in the art.
- Another cylinder liner made of the material described above (Silitec 5) was pretreated in the same way (cleaned by sandblasting and roughened) and then a low-alloy Fe-C alloy was applied by means of arc wire spraying. In the subsequent post-treatment (honing, exposing), the inside diameter of the cylinder liner was adapted to the dimensions of the pistons to be used (with rings).
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10324279A DE10324279B4 (en) | 2003-05-28 | 2003-05-28 | Use of FeC alloy to renew the surface of cylinder liners |
PCT/EP2004/004450 WO2004106721A1 (en) | 2003-05-28 | 2004-04-28 | Cylinder liner, method for the production thereof and a combined |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1627144A1 true EP1627144A1 (en) | 2006-02-22 |
Family
ID=33482256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04729862A Withdrawn EP1627144A1 (en) | 2003-05-28 | 2004-04-28 | Cylinder liner, method for the production thereof and a combined |
Country Status (6)
Country | Link |
---|---|
US (1) | US20070000129A1 (en) |
EP (1) | EP1627144A1 (en) |
JP (1) | JP2007533889A (en) |
KR (1) | KR20060029610A (en) |
DE (1) | DE10324279B4 (en) |
WO (1) | WO2004106721A1 (en) |
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DE19841619C2 (en) * | 1998-09-11 | 2002-11-28 | Daimler Chrysler Ag | Material wire for producing wear-resistant coatings from hypereutectic Al / Si alloys by thermal spraying and its use |
DE19845347C1 (en) * | 1998-10-02 | 2000-03-30 | Federal Mogul Burscheid Gmbh | Cylinder liner |
EP1507020B1 (en) * | 1999-01-19 | 2007-06-27 | Sulzer Metco AG | Plasma sprayed layer on cylinder bores of engine blocks |
DE10002440A1 (en) * | 2000-01-21 | 2001-08-02 | Daimler Chrysler Ag | Cylinder bushing sleeve used for casting in an engine block for an internal combustion engine has an adhesion promoting layer made of a nickel-aluminum alloy or a nickel-titanium alloy on the outer surface facing the engine block |
CH694664A5 (en) * | 2000-06-14 | 2005-05-31 | Sulzer Metco Ag | By plasma spraying a powder spray applied iron-containing layer on a cylinder surface. |
DE10150999C2 (en) * | 2001-10-16 | 2003-08-07 | Peak Werkstoff Gmbh | Method of profiling the outer peripheral surface of cylinder liners |
CH695339A5 (en) * | 2002-02-27 | 2006-04-13 | Sulzer Metco Ag | Cylinder surface layer for internal combustion engines and methods for their preparation. |
US7188416B1 (en) * | 2003-02-05 | 2007-03-13 | Brunswick Corporation | Restoration process for porosity defects in high pressure die cast engine blocks |
-
2003
- 2003-05-28 DE DE10324279A patent/DE10324279B4/en not_active Expired - Fee Related
-
2004
- 2004-04-28 US US10/558,249 patent/US20070000129A1/en not_active Abandoned
- 2004-04-28 KR KR1020057022650A patent/KR20060029610A/en not_active Application Discontinuation
- 2004-04-28 EP EP04729862A patent/EP1627144A1/en not_active Withdrawn
- 2004-04-28 JP JP2006529716A patent/JP2007533889A/en active Pending
- 2004-04-28 WO PCT/EP2004/004450 patent/WO2004106721A1/en active Application Filing
Non-Patent Citations (1)
Title |
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See references of WO2004106721A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE10324279A1 (en) | 2004-12-23 |
US20070000129A1 (en) | 2007-01-04 |
WO2004106721A1 (en) | 2004-12-09 |
KR20060029610A (en) | 2006-04-06 |
JP2007533889A (en) | 2007-11-22 |
DE10324279B4 (en) | 2006-04-06 |
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