EP1626122B1 - Method and device for producing a fibre strip provided with a three-dimensional surface structure - Google Patents

Method and device for producing a fibre strip provided with a three-dimensional surface structure Download PDF

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Publication number
EP1626122B1
EP1626122B1 EP05109471A EP05109471A EP1626122B1 EP 1626122 B1 EP1626122 B1 EP 1626122B1 EP 05109471 A EP05109471 A EP 05109471A EP 05109471 A EP05109471 A EP 05109471A EP 1626122 B1 EP1626122 B1 EP 1626122B1
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EP
European Patent Office
Prior art keywords
embossing
belt
fibrous web
embossing belt
suction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP05109471A
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German (de)
French (fr)
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EP1626122A1 (en
Inventor
Thomas Scherb
Jeffrey Herman
Harald Schmidt-Hebbel
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Voith Patent GmbH
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Voith Patent GmbH
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Publication of EP1626122A1 publication Critical patent/EP1626122A1/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00Press section of machines for making continuous webs of paper
    • D21F3/02Wet presses
    • D21F3/0209Wet presses with extended press nip
    • D21F3/0254Cluster presses, i.e. presses comprising a press chamber defined by at least three rollers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/006Making patterned paper

Definitions

  • the invention relates to a method and an apparatus for producing a provided with a three-dimensional surface structure fibrous web, in particular tissue or sanitary membrane.
  • TAD Through Air Drying
  • the aim of the invention is to provide an improved method and an improved device of the type mentioned, with which, in particular, even without the use of a larger TAD-drying device in an economical and correspondingly cost-effective manner, a high quality of the final product can be achieved.
  • a corresponding quality can be achieved.
  • the WO 93/00475 and the WO 00/19014 describe a process for the production of tissue paper in which the tissue web is pressed onto an embossing sieve and then dried by means of air flow in the direction of the embossing sieve in a TAD process.
  • the US 6,103,062 describes a process for the production of tissue paper in which the tissue paper is pressed onto a stamping belt in front of the Yankee drying cylinder by means of a shoe press. According to this publication, the tissue web is further dehydrated in the shoe press, with a press felt with capillary action being arranged on both sides of the tissue web.
  • the WO 99/47749 shows a process for the production of tissue paper, in which the tissue web is guided on an embossing belt together with a felt through a press nip formed between a roller and a Yankee cylinder.
  • the US 4,102,737 teaches a machine for the production of tissue paper, in which the tissue web is dried on a stamping tape by means of a TAD process.
  • this object is achieved by a method for producing a fibrous web provided with a three-dimensional surface structure, in particular tissue or hygiene web, in which the fibrous web is pressed at a dry content ⁇ 35% by means of a first pressure field on an embossing belt, e.g.
  • embossing fabric As an embossing or structured band ("imprinting fabric”, “structured fabric”), preferably an embossing screen or an embossing membrane is used.
  • the fibrous web is pre-stamped after the forming area.
  • At least the first pressure field is generated by means of a arranged on the side facing away from the fibrous web side of the embossing belt Saugelements to suck the fibrous web in the surface structure of the embossing belt.
  • a so-called wet vacuum can be used as a suction element.
  • the fibrous web in the further pressure field is gentle, i. preferably over a lengthened in the web running direction distance, is pressed.
  • the further pressure field is preferably generated by means of a press nip.
  • this Preßnip can be generated for example between a drying cylinder and a counter element, wherein the guided through the press nip fibrous web is in contact with the surface of the drying cylinder and rests with its other side on the embossing belt.
  • a drying cylinder in particular a so-called Yankee cylinder can be used.
  • a counteracting element cooperating with the drying cylinder it is possible in particular to use a shoe press unit which comprises a flexible band guided in the region of the press nip via a press shoe.
  • a shoe press roll provided with a flexible roll shell is preferably used as the shoe press unit.
  • a provided within the loop of the embossing belt preferably soft band, in particular felt, is guided by the Preßnip generating the further pressure field.
  • the soft felt may, for example, be a felt with a foamed layer, which, as will be explained in more detail below, contributes to drainage of the fibrous web due to its capillary action (capillary fabric).
  • a preferred practical embodiment of the method according to the invention is characterized in that the pre-embossed fibrous web is dried on the drying cylinder or Yankee cylinder, the fibrous web is creped and / or the fibrous web is subsequently wound up.
  • the dry content at which the fibrous web is pre-embossed, and / or the dry content at which the three-dimensional surface structure is fixed in each case ⁇ 35%, in particular ⁇ 30% and preferably ⁇ 25%.
  • the water retention capacity and the volume increased sustainably which means that even with the use of the final product, such as a respective tissue or tissue web, the desired embossment is still present.
  • the advantage of a higher water retention capacity for towel tissue (towel paper) also comes into play when using the end product in question.
  • an evacuated device is used between the suction pad producing the first pressure field and the press pad generating the further pressure field and the fibrous web is guided together with an embossing belt both via the evacuated device and through the press nip. It is advantageous if the evacuated device has a curved surface and the fibrous web and the embossing belt are guided over this curved surface.
  • a suctioned device for example, a suction roll can be used.
  • the felt is conveniently passed between the embossing belt and the flexible belt of the shoe press unit through the press nip.
  • the particular soft felt is also passed over the evacuated device.
  • this is preferably associated with a standing under pressure hood to support the negative pressure effect of the evacuated device.
  • the felt can be conditioned, for example, by means of a suction device, in particular by means of a suction box, before it is brought together with the embossing belt carrying the fibrous web.
  • a suction device in particular by means of a suction box
  • the dry content of the felt can be increased and the felt can be cleaned.
  • the embossing band can be placed in front of the evacuated device, i.
  • the suction roller are guided over the suction element or the Najisauger to suck the fibrous web in the three-dimensional surface structure of the embossing belt and thus impart this structure to the band.
  • the relevant suction element brings a corresponding increase in dry content with it.
  • the felt is brought together only after the evacuated device with the embossing belt carrying the fibrous web.
  • the evacuated device is therefore not wrapped in this case of the felt, whereby the suction effect of this device is increased and increased according to the dry content.
  • the wet molding effect is maintained by the gentler dewatering by the so-called TissueFlex, which operates at a lower pressure and longer residence time compared to a shoe press roll.
  • the length of the press nip of the drying cylinder and the shoe press unit considered in the web running direction greater than a value of about 80 mm selected and the shoe press is designed so that over the Preßnipin results in a pressure profile with a maximum pressure, which is less than or equal to a value of about 2.5 MPa. This ensures a gentle pressing, with which it is avoided that the structure produced in the fibrous web, such as tissue or sanitary membrane, is flattened out again.
  • suction roll between the suction element producing the first pressure field and the press nip, which is preferably associated with a pressure hood.
  • At least one dewatering screen with zonal different screen permeability is used in the forming area.
  • the relevant drainage sieve can be provided in particular as an outer sieve.
  • a corresponding embodiment of the method is particularly advantageous in the production of towel tissue.
  • the screen produces a fine structure which increases the rate of water absorption and, in conjunction with the embossing of the present invention, brings with it increased water retention.
  • a former with two circulating dewatering belts which converge to form a Stoffeinlaufspaltes and are passed over a forming element such as in particular a forming roller, and as not coming into contact with the forming element in contact Outside belt and / or as inner band a drainage sieve with zonal different Sieb trim is used.
  • a forming element such as in particular a forming roller
  • an embossing belt and preferably as an outer belt, a dewatering screen with zonal different Sieb prepare be used as an inner band.
  • the fibrous web is preferably taken over by an embossing belt from the inner band.
  • the web can be wet embossed by means of the embossing belt, for example by means of a suction box in front of the press.
  • an embossing belt eg embossing screen or embossing membrane, led, which is structured so that results for this embossing belt compared to the area ratio of recessed zones or holes smaller area ratio of raised or closed zones and Accordingly, in the Preßnip a smaller area fraction of the fibrous web is pressed.
  • the smaller areal proportion of raised or closed zones provides the high density web areas for strength, while the larger areal fraction of recessed zones or holes remaining at least substantially unpressed will provide the desired water absorbency and volume as previously limited a complex and expensive fürströmungs- or TAD drying were achieved.
  • an embossing belt can advantageously be used in which the areal proportion of raised or closed zones is ⁇ 40% and is preferably in a range from about 25 to about 30%.
  • an embossing belt is used in which the raised zones and recessed zones are offset by cranks, i. result from crossing points of weft and warp threads, a screen mesh.
  • an embossing membrane can also be used, with which the raised and recessed zones result through the holes. In this case, it is advantageous that 100% of the surface is pressed around the holes and results in a higher strength.
  • the embossing belt in question can be guided together with the fibrous web, for example, again over a drying cylinder, in particular Yankee cylinder.
  • a shoe press unit can in particular be used again.
  • the length of the press nip considered in the web running direction as well as the pressure profile resulting over the press nip length can in particular be selected again as stated above.
  • Creping the web can improve the water absorbency by 50%, and taking this into account, TAD towel quality water absorption can be achieved.
  • the WO 93/00475 and the WO 00/19014 describe a process for the production of tissue paper in which the tissue web is pressed onto an embossing sieve and then dried by means of air flow in the direction of the embossing sieve in a TAD process.
  • the US 6,103,062 describes a process for the production of tissue paper in which the tissue paper is pressed onto a stamping belt in front of the Yankee drying cylinder by means of a shoe press. According to this publication, the tissue web is further dehydrated in the shoe press, with a press felt with capillary action being arranged on both sides of the tissue web.
  • the WO 99/47749 shows a process for the production of tissue paper, in which the tissue web is guided on an embossing belt together with a felt through a press nip formed between a roller and a Yankee cylinder.
  • the US 4,102,737 teaches a machine for the production of tissue paper, in which the tissue web is dried on a stamping tape by means of a TAD process.
  • the foamed layer fabric may comprise a suction roll having a diameter of e.g. about 2 to 3 m or more suction rolls of smaller diameter, preferably two suction rolls with a diameter of, for example, in each case about 2 m, loop.
  • the residence time of the web in the area of the suction roll or the suction rolls should expediently be greater than about 0.15 s and less than about 0.40 s.
  • the respective suction roll can be placed on its underside, e.g. be applied with vacuum, or it can be used a Saugsalze with associated Siphonabzug.
  • the water can be thrown off, for example by centrifugal force in a gutter.
  • the suctioned device can, in particular, again be associated with a hood under overpressure in order to support the negative pressure effect of the evacuated device.
  • the fibrous web is preferably guided together with the embossing belt and a membrane through the pressure chamber.
  • the basic principle of such a displacement press, at the water in the fibrous web is displaced by air, for example, in the DE 19946972 described.
  • the invention is particularly applicable to Crescent Formers, Duo Formers, C-Wrap Formers, S-Wrap Formers and to the manufacture of multi-layer and multi-ply tissue.
  • Fig. 1 shows a schematic partial representation of an apparatus 10 for producing a provided with a three-dimensional surface structure fibrous web 12 (see also Fig. 7 ), which may in particular be a paper web and preferably a tissue or hygiene web.
  • the fibrous web 12 is pressed at a dry content ⁇ 35% by means of a first pressure pad I on a stamping or structural band 14, e.g. sucked, and thereby pre-embossed and then pressed for further drainage and drying by means of another pressure pad II a further time on the embossing belt 14 to fix the three-dimensional surface structure and strength.
  • a stamping or structural band 14 e.g. sucked, and thereby pre-embossed and then pressed for further drainage and drying by means of another pressure pad II a further time on the embossing belt 14 to fix the three-dimensional surface structure and strength.
  • another pressure pad II a further time on the embossing belt 14 to fix the three-dimensional surface structure and strength.
  • embossing belt 14 in particular an embossing screen.
  • the same embossing belt 14 is provided for embossing and fixing the surface structure.
  • the first pressure field I is produced by means of a suction element 16 arranged on the side of the embossing belt 14 facing away from the fibrous web 12, whereby the fibrous web 12 is sucked into the surface structure of the embossing belt 14.
  • the suction element 16 may be provided in particular as a suction box or wet vacuum.
  • the fibrous web 12 is preferably gently, ie in particular over a lengthened in the direction of web travel L distance pressed.
  • the further pressure field II can be generated in particular by means of a Preßnips 18, between a drying cylinder 20 and a counter-element 22 is formed.
  • the guided through the press nip 18 fibrous web 12 is in this case in contact with the surface 20 'of the drying cylinder 20. With its other side it lies against the embossing belt 14.
  • drying cylinder 20 may be provided in particular a Yankee cylinder.
  • a Schuhpreßaku 22 is provided which comprises a guided in the region of the press nips 18 via a press shoe 24 flexible belt 26.
  • Schuhpreßaku 22 provided with a flexible roll shell 26 shoe press roll.
  • a preferably soft band 28 (capillary fabric), in particular a soft felt or a soft foam felt, may be guided through the press nip 18. This soft band 28 thus runs between the embossing belt 14 and the flexible belt 26 of the shoe press unit 22.
  • the fibrous web 12 may be placed on the drying cylinder 20, i. For example, on a Yankee cylinder, dried.
  • the fibrous web 12 can be creped.
  • the web 12 can be wound up by appropriate means.
  • the dry content at which the fibrous web 12 is pre-stamped and / or the dry content at which the three-dimensional surface structure is fixed is as already mentioned, ⁇ 35%, and may in particular be ⁇ 30% and preferably ⁇ 25%.
  • a suctioned device 30 is provided, which may in particular be a suction roll.
  • the fibrous web 12 is guided together with the embossing belt 14 both via the evacuated device 30 and through the press nip 18.
  • the felt 28 is guided between the embossing belt 14 and the flexible belt 26 of the shoe press unit 22 through the press nip 18.
  • the felt 28 is guided not only by the Preßnip 18, but also on the evacuated device 30. Since the Saugwi kung of the device 30 is reduced by the resistance of the felt 28, the evacuated means 30 may be associated with an over-standing hood to support the vacuum effect of the evacuated device 30.
  • a suction device 32 for conditioning the felt 28, a suction device 32, in particular a suction box or the like, may be provided.
  • this felt conditioning device serving suction device 32 is disposed in front of the evacuated device 30, in the region of the felt 28 is merged with the embossing belt 14 carrying the fibrous web 12.
  • the suction device 32 is preferably arranged in front of (shown in solid lines) a lower deflection roller 72. In principle, however, an arrangement behind this lower guide roller 72 is possible (dashed line 32 ').
  • the embossing belt 14 In front of the evacuated device 30, the embossing belt 14 is guided over the suction element 16, which causes a pre-embossing of the fibrous web 12 in addition to a dry content increase. This is sucked into the three-dimensional surface structure of the embossing belt or sieve 14, whereby the structure of the web is impressed.
  • the in the Fig. 2 illustrated embodiment differs from that according to Fig. 1 essentially only in that the felt 28 is brought together after the suctioned egg n-direction 30 with the fibrous web 12 carrying embossing belt 14.
  • the evacuated device 30 is thus not wrapped in this case by the felt 28, whereby their suction effect is increased and the dry content is increased accordingly.
  • the wet embossing effect is maintained by the relatively gentle dewatering of the TissueFlex, where the pressure is lower than that of a conventional shoe press.
  • the suction device 32 is preferably arranged again before (representation in solid lines) of the lower deflection roller 72, wherein in principle, however, an arrangement behind this lower deflection roller 72 is again possible (dashed representation 32 ').
  • Fig. 3 shows a schematic partial representation of an embodiment in which a drainage device 34 is additionally provided, in which the capillary action of a felt 36 with foamed layer is used for dewatering.
  • the foam coating may in particular be selected so that pores in a range of about 3 to about 6 microns.
  • the foamed layer felt 36 together with an embossing belt 14 and intermediate fibrous web 12 is guided around a larger suction roll 38, the felt 36 preferably being in contact with the suction roll 38.
  • the suction roll 38 wrapped around the felt 36 may have a diameter of about 2 to about 3 meters.
  • the suction roller 38 may be acted upon by vacuum on its underside.
  • the suction roll 38 can also be assigned a siphon outlet.
  • the funds in question are in the Figure 3 denoted by "40".
  • At least one drainage sieve with zonal different sieve permeability can be provided.
  • a former with two circumferential dewatering belts 14, 42 is provided, the inner belt 14 also serving as an embossing belt.
  • the two dewatering belts 14, 42 converge to form a material inlet gap 44 and are guided over a shaping element 46 such as in particular a forming roller.
  • the embossing belt 14 is formed by the element 46 coming into contact with the inner band of the former.
  • the outer band 42 which does not come into contact with the forming element 46, can be provided in particular as a dewatering screen with zonal different screen permeability.
  • a headbox 48 By means of a headbox 48, the pulp suspension is introduced into the stock inlet gap 44. Behind the forming element 46, a pickup or separating element 50 is provided, through which the web is held on the embossing belt 14 during the separation from the dewatering belt 42. Preferably in front of the egg n-direction 34 with capillary action is again a suction element 16 (solid Representation) provided by the fibrous web 12 is pressed onto the embossing belt 14. However, this suction element can also be arranged between the device 34 with capillary action and the evacuated device or suction roller 30 (dashed representation 16 ').
  • a soft belt or felt 28 is again guided through the press nip 18 formed between a drying cylinder 20 and a shoe press unit 22.
  • the soft band is according to the embodiment according to Fig. 1 again guided around the evacuated device 30.
  • this soft band 28 may again be a capillary felt.
  • the felt 28 can be conditioned again via a suction device or a so-called UHLE box.
  • the drying cylinder 20 may in particular be a Yankee cylinder again. In this case, this drying cylinder 20 may be associated with a drying hood 52.
  • the dry content of the fibrous web before the capillary drainage device 34 is about 10 to about 25%, in the area downstream of this device 34 e.g. about 30 to about 40%.
  • the in the Fig. 4 illustrated embodiment differs from that according to Fig. 3 initially by the fact that the fibrous web 12 is taken over by the embossing belt 14 of an inner band 54 of the former.
  • this inner band 54 or the outer band 42 of the former can again be provided as a dewatering screen with zonal different Sieb trim engineer.
  • the two circulating dewatering belts 42, 54 converge again to form a material inlet gap 44, wherein they are guided again over a forming element 46 such as in particular a forming roller.
  • a headbox 48 of the material inlet gap 44 is again with pulp suspension fed.
  • the pulp suspension is supplied in the present case from below.
  • a pickup or separating element is again provided, through which the fibrous web 12 is held on the embossing belt during the separation from the inner band 54 of the former.
  • suction member 16 is arranged in front of the dewatering device 34 with capillary action, in principle, however, an arrangement according to this device 34 is possible.
  • the felt 28 is missing.
  • the dry content of the fibrous web in the present embodiment is about 10 to about 25% in the region of the pickup element 50, about 15 to about 30% in the region upstream of the dewatering device 34 and about 35 to about 45% downstream of the device 34.
  • this embodiment may have at least substantially the same structure as that according to Fig. 3 , Corresponding elements are assigned the same reference numerals.
  • Fig. 5 shows a schematic partial view of an embodiment of the device 10, in which a displacement press 56 is provided.
  • the fibrous web 12 is guided to expel water by means of gas pressure with the embossing belt 14 at least once through a pressure chamber 58 which is bounded by at least four parallel rollers 60 - 66 and in which a compressed gas can be introduced.
  • the fibrous web 12 is preferably guided together with the embossing belt 14 and a membrane 68 through the pressure chamber 58.
  • the membrane 68 forms the inner band of the former, which again comprises a forming member 46, in particular a forming roller, in the region of which provided as a membrane inner band 48 and the outer band 42 converge to form a Stoffeinlaufspaltes 44 which feeds by means of a headbox 48 with pulp suspension becomes.
  • the fibrous web 12 together with the embossing belt 14 again via an evacuated device 30, in particular a suction roll, and passed through the formed between a drying cylinder 20, in particular Yankee cylinder, and a shoe press 22 Preßnip 18.
  • the drying cylinder or Yankee cylinder 20 is again associated with a drying hood 52.
  • the first pressure field I by which the fibrous web 12 is pressed at a dry content of ⁇ 50% on the embossing belt 14 and pre-embossed, for example, be generated by the air press 56.
  • the area fraction of raised or closed zones 68 can be in particular ⁇ 40% and preferably in a range of about 25 to about 30%.
  • the raised zones 68 and the recessed zones may result, for example, by offsets, ie by intersections of weft and warp threads, of a mesh fabric.
  • Preßmembran results in a corresponding structuring through the holes 74th
  • Fig. 6 shows a schematic partial view of a corresponding embossing belt 14, for example, embossing felt or embossing membrane, with a smaller compared to the area ratio of recessed zones or holes 74 surface portion of raised or closed areas 68th
  • the thickness d of the right part of the Fig. 6 may be about 1 to about 3 mm.
  • the open area may be greater than 50%, and more preferably greater than 60%, and preferably within a range of from about 70% to about 75%.
  • the membrane expediently i-wise of a resistant to the pulp chemistry material. It can for example consist of polyester.
  • Fig. 7 shows a schematic section through a Preßnip 18, through which in the Fig. 6 shown embossing belt 14 is passed together with the fibrous web 12 and a preferably soft belt or felt 28.
  • this soft band 28 is in contact with the flexible band 26 of the shoe press unit, which is guided in the region of the press nips 18 via a press shoe 24, via which the desired contact pressure can be applied.
  • the fibrous web 12 is applied to the drying cylinder 20, preferably a Yankee cylinder.
  • the fibrous web 12 is already marked before the nip. As based on the Fig. 7 can be seen, is already on the embossing belt before the nip.

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  • Paper (AREA)
  • Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Preliminary Treatment Of Fibers (AREA)

Abstract

In a process to manufacture a tissue web with a three-dimensional embossed surface, the wet web (less than 35% dry matter content) is pressed by suction to the surface of a pre-embossing belt. The pre-dried web is then transferred to and pressed onto a second embossing belt where the three-dimensional structure is fixed. Also claimed is a commensurate tissue or hygiene material (12) drying and embossing assembly (10) with first (I) and second (II) de-watering and embossing zones. The web is embossed by an embossing sieve belt (14) moving around first (30) and second (24) embossing drums. The second embossing drum (22) squeezes the web (12) and embossing belt (14) against a drying cylinder (20).

Description

Die Erfindung betrifft ein Verfahren sowie eine Vorrichtung zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn, insbesondere Tissue- oder Hygienebahn.The invention relates to a method and an apparatus for producing a provided with a three-dimensional surface structure fibrous web, in particular tissue or sanitary membrane.

Das Einprägen einer dreidimensionalen Struktur in die Oberfläche einer Papierbahn, insbesondere einer Tissuebahn insbesondere von Hand-Tissue, ist bekannt (siehe beispielsweise WO 99/47749 , WO 01/18307 ). Ferner ist bekannt, daß durch eine sogenannte Durchströmungstrocknung (TAD = Through Air Drying) eine sehr gute Papierqualität erreichbar ist. Von Nachteil ist jedoch, daß der Einsatz von TAD-Trocknern sehr aufwendig und entsprechend teuer ist.The embossing of a three-dimensional structure in the surface of a paper web, in particular a tissue web, in particular of hand-tissue, is known (see, for example WO 99/47749 . WO 01/18307 ). Furthermore, it is known that a very good paper quality can be achieved by a so-called through-air drying (TAD = Through Air Drying). The disadvantage, however, is that the use of TAD dryers is very expensive and correspondingly expensive.

Ziel der Erfindung ist es, ein verbessertes Verfahren sowie eine verbesserte Vorrichtung der eingangs genannten Art anzugeben, mit denen insbesondere auch ohne den Einsatz einer größeren TAD-Trocknungseinrichtung auf wirtschaftliche und entsprechend kostengünstige Weise eine hohe Qualität des Endproduktes erreichbar ist. Dabei soll insbesondere hinsichtlich des Wasserrückhaltevermögens, der Wassraufnahmegeschwindigkeit, des Volumens (bulk) usw. eine entsprechende Qualität erreicht werden.The aim of the invention is to provide an improved method and an improved device of the type mentioned, with which, in particular, even without the use of a larger TAD-drying device in an economical and correspondingly cost-effective manner, a high quality of the final product can be achieved. In this case, in particular with regard to the water retention capacity, the water absorption rate, the volume (bulk), etc., a corresponding quality can be achieved.

Die WO 93/00475 und die WO 00/19014 beschreiben ein Verfahren zur Herstellung von Tissuepapier, bei dem die Tissuebahn auf ein Prägesieb gepresst wird und anschließend mittels Luftströmung in Richtung des Prägesiebs in einem TAD Prozess getrocknet wird.The WO 93/00475 and the WO 00/19014 describe a process for the production of tissue paper in which the tissue web is pressed onto an embossing sieve and then dried by means of air flow in the direction of the embossing sieve in a TAD process.

Die US 6,103,062 beschreibt ein Verfahren zur Herstellung von Tissuepapier, bei dem das Tissuepapier vor dem Yankee Trockenzylinder mittels einer Schuhpresse auf ein Prägeband gepresst wird. Gemäß dieser Druckschrift wird die Tissuebahn in der Schuhpresse ferner entwässert, wobei beidseitig der Tissuebahn ein Pressfilz mit Kapillarwirkung angeordnet ist.The US 6,103,062 describes a process for the production of tissue paper in which the tissue paper is pressed onto a stamping belt in front of the Yankee drying cylinder by means of a shoe press. According to this publication, the tissue web is further dehydrated in the shoe press, with a press felt with capillary action being arranged on both sides of the tissue web.

Die WO 99/47749 zeigt ein Verfahren zur Herstellung von Tissuepapier, bei dem die Tissuebahn auf einem Prägeband zusammen mit einem Filz durch einen zwischen einer Walze und einem Yankee-Zylinder gebildeten Pressnip geführt wird.The WO 99/47749 shows a process for the production of tissue paper, in which the tissue web is guided on an embossing belt together with a felt through a press nip formed between a roller and a Yankee cylinder.

Die US 4,102,737 lehrt eine Maschine zur Herstellung von Tissuepapier, bei der die Tissuebahn auf einem Prägeband mittels eines TAD-Prozesses getrocknet wird.The US 4,102,737 teaches a machine for the production of tissue paper, in which the tissue web is dried on a stamping tape by means of a TAD process.

Erfindungsgemäß wird diese Aufgabe gelöst durch ein Verfahren zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn, insbesondere Tissue- oder Hygienebahn, bei dem die Faserstoffbahn bei einem Trockengehalt < 35 % mittels eines ersten Druckfeldes auf ein Prägeband gedrückt, z.B. gesaugt, und dadurch vorgeprägt und anschließend zur weiteren Entwässerung und Trocknung mittels eines weiteren Druckfeldes ein weiteres Mal auf ein Prägeband gedrückt wird, um die dreidimensionale Oberflächenstruktur und Festigkeit zu fixieren und zur Entwässerung der Bahn wenigstens eine feinporige Bespannung mit Kapillar-Effekt verwendet wird, die eine Bespannung mit geschäumter Schicht ist, wobei die Bespannung mit geschäumter Schicht zusammen mit einem Prägeband und dazwischen liegender Faserstoffbahn um eine Saugwalze geführt und die Bespannung mit einer Saugwalze in Kontakt ist.According to the invention, this object is achieved by a method for producing a fibrous web provided with a three-dimensional surface structure, in particular tissue or hygiene web, in which the fibrous web is pressed at a dry content <35% by means of a first pressure field on an embossing belt, e.g. sucked, and thereby pre-embossed and then for further dewatering and drying by means of another pressure field is pressed once more on an embossing belt to fix the three-dimensional surface structure and strength and at least one fine-pored fabric with capillary effect is used to drain the web a covering with a foamed layer, wherein the fabric with foamed layer is guided together with an embossing belt and fibrous web lying therebetween around a suction roller and the clothing is in contact with a suction roller.

Aufgrund dieser Ausgestaltung wird in der betreffenden Faserstoffbahn, d.h. insbesondere der betreffenden Papier-, Tissue- oder Hygienebahn, eine nachhaltige dreidimensionale Oberflächenstruktur erzeugt, die auch noch nach dem Trocknungsprozeß in der gewünschten Weise in der Bahn, d.h. beispielsweise in dem Papier, vorhanden ist. Des weiteren wird zur Entwässerung die Kapillarwirkung ausgenutzt um den gewünschten Trockengehalt zu erhalten. Der Einsatz eines aufwendigen und entsprechend teuren TAD-Verfahrens ist nicht mehr erforderlich. Auch ohne eine solche TAD-Trocknungseinrichtung kann nunmehr insbesondere eine nachhaltige Oberflächenstruktur beispielsweise einer Tissue- oder Hygienebahn nach dem Formierbereich oder Formierzone erzeugt werden.Due to this configuration, in the relevant fibrous web, i. in particular the paper, tissue or hygiene web in question, produces a sustainable three-dimensional surface structure which, even after the drying process in the desired manner in the web, i. in the paper, for example. Furthermore, the capillary action is used for dewatering to obtain the desired dry content. The use of a complex and correspondingly expensive TAD method is no longer necessary. Even without such a TAD drying device, it is now possible in particular to produce a sustainable surface structure, for example a tissue or hygiene web, after the forming area or forming zone.

Als Präge- oder Strukturband ("imprinting fabric", "structured fabric") wird vorzugsweise ein Prägesieb oder eine Prägemembran verwendet.As an embossing or structured band ("imprinting fabric", "structured fabric"), preferably an embossing screen or an embossing membrane is used.

Im allgemeinen wird die Faserstoffbahn nach dem Formierbereich vorgeprägt.In general, the fibrous web is pre-stamped after the forming area.

Gemäß einer bevorzugten Ausgestaltung wird zumindest das erste Druckfeld mittels eines auf der von der Faserstoffbahn abgewandten Seite des Prägebandes angeordneten Saugelements erzeugt, um die Faserstoffbahn in die Oberflächenstruktur des Prägebandes zu saugen. Dabei kann als Saugelement insbesondere ein sogenannter Naßsauger verwendet werden.According to a preferred embodiment, at least the first pressure field is generated by means of a arranged on the side facing away from the fibrous web side of the embossing belt Saugelements to suck the fibrous web in the surface structure of the embossing belt. In this case, in particular a so-called wet vacuum can be used as a suction element.

Von Vorteil ist auch, wenn die Faserstoffbahn in dem weiteren Druckfeld sanft, d.h. vorzugsweise über eine in Bahnlaufrichtung verlängerte Strecke hinweg, gepreßt wird.It is also advantageous if the fibrous web in the further pressure field is gentle, i. preferably over a lengthened in the web running direction distance, is pressed.

Das weitere Druckfeld wird vorzugsweise mittels eines Preßnips erzeugt. Um ein möglichst sanftes Pressen der Bahn zu bewerkstelligen, kann dieser Preßnip beispielsweise zwischen einem Trockenzylinder und einem Gegenelement erzeugt werden, wobei die durch den Preßnip geführte Faserstoffbahn in Kontakt mit der Oberfläche des Trockenzylinders ist und mit ihrer anderen Seite am Prägeband anliegt. Als Trockenzylinder kann insbesondere ein sogenannter Yankee-Zylinder verwendet werden. Als mit dem Trockenzylinder zusammenwirkendes Gegenelement kann insbesondere eine Schuhpreßeinheit verwendet werden, die ein im Bereich des Preßnips über einen Preßschuh geführtes flexibles Band umfaßt. Dabei wird als Schuhpreßeinheit vorzugsweise eine mit einem flexiblen Walzenmantel versehene Schuhpreßwalze verwendet.The further pressure field is preferably generated by means of a press nip. In order to accomplish the most gentle pressing of the web, this Preßnip can be generated for example between a drying cylinder and a counter element, wherein the guided through the press nip fibrous web is in contact with the surface of the drying cylinder and rests with its other side on the embossing belt. As a drying cylinder, in particular a so-called Yankee cylinder can be used. As a counteracting element cooperating with the drying cylinder, it is possible in particular to use a shoe press unit which comprises a flexible band guided in the region of the press nip via a press shoe. In this case, a shoe press roll provided with a flexible roll shell is preferably used as the shoe press unit.

Vorteilhafterweise wird ein innerhalb der Schlaufe des Prägebandes vorgesehenes, vorzugsweise weiches Band, insbesondere Filz, durch den das weitere Druckfeld erzeugenden Preßnip geführt. Bei dem weichen Filz kann es sich beispielsweise um einen Filz mit geschäumter Schicht handeln, die, wie weiter unten noch näher erläutert wird, aufgrund ihrer Kapillarwirkung zur Entwässerung der Faserstoffbahn beiträgt (capillary fabric).Advantageously, a provided within the loop of the embossing belt, preferably soft band, in particular felt, is guided by the Preßnip generating the further pressure field. The soft felt may, for example, be a felt with a foamed layer, which, as will be explained in more detail below, contributes to drainage of the fibrous web due to its capillary action (capillary fabric).

Eine bevorzugte praktische Ausgestaltung des erfindungsgemäßen Verfahrens zeichnet sich dadurch aus, daß die vorgeprägte Faserstoffbahn auf dem Trockenzylinder bzw. Yankee-Zylinder getrocknet, die Faserstoffbahn gekreppt und/oder die Faserstoffbahn anschließend aufgewickelt wird.A preferred practical embodiment of the method according to the invention is characterized in that the pre-embossed fibrous web is dried on the drying cylinder or Yankee cylinder, the fibrous web is creped and / or the fibrous web is subsequently wound up.

Gemäß einer bevorzugten Ausgestaltung des erfindungsgemäßen Verfahrens wird der Trockengehalt, bei dem die Faserstoffbahn vorgeprägt wird, und/oder der Trockengehalt, bei dem die dreidimensionale Oberflächenstruktur fixiert wird, jeweils < 35 %, insbesondere < 30 % und vorzugsweise < 25 % gewählt. Damit wird u.a. das Wasserrückhaltevermögen und das Volumen nachhaltig erhöht, was bedeutet, daß auch beim Gebrauch des Endproduktes, beispielsweise einer betreffenden Tissue- oder Hygienebahn, die gewünschte Prägung noch vorhanden ist. Insbesondere der Vorteil eines höheren Wasserrückhaltevermögens für Handtuch-Tissue (towel paper) kommt also auch noch beim Gebrauch des betreffenden Endproduktes zur Geltung.According to a preferred embodiment of the method according to the invention, the dry content at which the fibrous web is pre-embossed, and / or the dry content at which the three-dimensional surface structure is fixed, in each case <35%, in particular <30% and preferably <25%. This will u.a. the water retention capacity and the volume increased sustainably, which means that even with the use of the final product, such as a respective tissue or tissue web, the desired embossment is still present. In particular, the advantage of a higher water retention capacity for towel tissue (towel paper) also comes into play when using the end product in question.

Gemäß einer bevorzugten praktischen Ausgestaltung des erfindungsgemäßen Verfahrens wird zwischen dem das erste Druckfeld erzeugenden Saugelement und dem das weitere Druckfeld erzeugenden Preßnip eine besaugte Einrichtung verwendet und die Faserstoffbahn zusammen mit einem Prägeband sowohl über die besaugte Einrichtung als auch durch den Preßnip geführt. Dabei ist es von Vorteil, wenn die besaugte Einrichtung eine gekrümmte Fläche besitzt und die Faserstoffbahn und das Prägeband über diese gekrümmte Fläche geführt werden. Als besaugte Einrichtung kann beispielsweise eine Saugwalze verwendet werden.According to a preferred practical embodiment of the method according to the invention, an evacuated device is used between the suction pad producing the first pressure field and the press pad generating the further pressure field and the fibrous web is guided together with an embossing belt both via the evacuated device and through the press nip. It is advantageous if the evacuated device has a curved surface and the fibrous web and the embossing belt are guided over this curved surface. As a suctioned device, for example, a suction roll can be used.

Der Filz wird zweckmäßigerweise zwischen dem Prägeband und dem flexiblen Band der Schuhpreßeinheit durch den Preßnip geführt.The felt is conveniently passed between the embossing belt and the flexible belt of the shoe press unit through the press nip.

In bestimmten Fällen ist es von Vorteil, wenn der insbesondere weiche Filz auch über die besaugte Einrichtung geführt wird. Da hier die Saugwirkung der besaugten Einrichtung entsprechend reduziert wird, wird dieser vorzugsweise eine unter Überdruck stehende Haube zugeordnet, um die Unterdruckwirkung der besaugten Einrichtung zu unterstützen.In certain cases, it is advantageous if the particular soft felt is also passed over the evacuated device. Here, since the suction of the evacuated device is reduced accordingly, this is preferably associated with a standing under pressure hood to support the negative pressure effect of the evacuated device.

Weitere Vorteile ergeben sich aus der relativ langen gemeinsamen Führung von Filz und Prägeband, da über eine längere Strecke hinweg die Kapillarwirkung des Filzes zur Entwässerung der Faserstoffbahn ausgenutzt wird.Further advantages result from the relatively long common leadership of felt and embossing belt, as over a longer distance, the capillary action of the felt is used for dewatering the fibrous web.

Der Filz kann beispielsweise mittels einer Saugeinrichtung, insbesondere mittels eines Saugkastens, konditioniert werden, bevor er mit dem die Faserstoffbahn tragenden Prägeband zusammengeführt wird. Durch eine entsprechende Konditionierung kann insbesondere der Trockengehalt des Filzes erhöht und der Filz gereinigt werden.The felt can be conditioned, for example, by means of a suction device, in particular by means of a suction box, before it is brought together with the embossing belt carrying the fibrous web. By appropriate conditioning, in particular, the dry content of the felt can be increased and the felt can be cleaned.

Das Prägeband kann insbesondere vor der besaugten Einrichtung, d.h. beispielsweise der Saugwalze, über das Saugelement bzw. den Naßsauger geführt werden, um die Faserstoffbahn in die dreidimensionale Oberflächenstruktur des Prägebandes zu saugen und damit dem Band diese Struktur aufzuprägen. Gleichzeitig bringt das betreffende Saugelement eine entsprechende Trockengehaltssteigerung mit sich.In particular, the embossing band can be placed in front of the evacuated device, i. For example, the suction roller, are guided over the suction element or the Naßsauger to suck the fibrous web in the three-dimensional surface structure of the embossing belt and thus impart this structure to the band. At the same time the relevant suction element brings a corresponding increase in dry content with it.

Gemäß einer anderen zweckmäßigen Ausgestaltung des erfindungsgemäßen Verfahrens wird der Filz erst nach der besaugten Einrichtung mit dem die Faserstoffbahn tragenden Prägeband zusammengeführt. Die besaugte Einrichtung ist in diesem Fall also nicht vom Filz umschlungen, wodurch der Saugeffekt dieser Einrichtung erhöht und entsprechend der Trockengehalt gesteigert wird. Der Naßprägeeffekt (wet molding effect) bleibt durch die schonendere Entwässerung durch die sogenannte TissueFlex erhalten, die im Vergleich zu einer Schuhpreßwalze bei kleinerem Druck und längerer Verweilzeit arbeitet.According to another advantageous embodiment of the method according to the invention, the felt is brought together only after the evacuated device with the embossing belt carrying the fibrous web. The evacuated device is therefore not wrapped in this case of the felt, whereby the suction effect of this device is increased and increased according to the dry content. The wet molding effect is maintained by the gentler dewatering by the so-called TissueFlex, which operates at a lower pressure and longer residence time compared to a shoe press roll.

Von Vorteil ist auch, wenn die in Bahnlaufrichtung betrachtete Länge des Preßnips der den Trockenzylinder und die Schuhpreßeinheit umfassenden Schuhpresse größer als ein Wert von etwa 80 mm gewählt und die Schuhpresse so ausgelegt wird, daß sich über die Preßniplänge ein Druckprofil mit einem maximalen Preßdruck ergibt, der kleiner oder gleich einem Wert von etwa 2,5 MPa ist. Damit ist ein sanftes Pressen gewährleistet, mit dem vermieden wird, daß die erzeugte Struktur in der Faserstoffbahn, z.B. Tissue- oder Hygienebahn, wieder herausgeplättet wird.It is also advantageous if the length of the press nip of the drying cylinder and the shoe press unit considered in the web running direction greater than a value of about 80 mm selected and the shoe press is designed so that over the Preßniplänge results in a pressure profile with a maximum pressure, which is less than or equal to a value of about 2.5 MPa. This ensures a gentle pressing, with which it is avoided that the structure produced in the fibrous web, such as tissue or sanitary membrane, is flattened out again.

Wie bereits erwähnt, kann zwischen dem das erste Druckfeld erzeugenden Saugelement und dem Preßnip beispielsweise eine Saugwalze eingesetzt werden, der vorzugsweise eine Druckhaube zugeordnet ist.As already mentioned, it is possible, for example, to insert a suction roll between the suction element producing the first pressure field and the press nip, which is preferably associated with a pressure hood.

Gemäß einer bevorzugten praktischen Ausgestaltung des erfindungsgemäßen Verfahrens wird im Formierbereich wenigstens ein Entwässerungssieb mit zonal unterschiedlicher Siebdurchlässigkeit verwendet. Das betreffende Entwässerungssieb kann insbesondere als Außensieb vorgesehen sein. Eine entsprechende Ausgestaltung des Verfahrens ist insbesondere bei der Herstellung von Handtuch-Tissue (towel tissue) von Vorteil. Das Sieb erzeugt eine feine Struktur, die die Wasseraufnahmegeschwindigkeit erhöht und in Verbindung mit der erfindungsgemäßen Prägung ein erhöhtes Wasserrückhaltevermögen mit sich bringt.According to a preferred practical embodiment of the method according to the invention, at least one dewatering screen with zonal different screen permeability is used in the forming area. The relevant drainage sieve can be provided in particular as an outer sieve. A corresponding embodiment of the method is particularly advantageous in the production of towel tissue. The screen produces a fine structure which increases the rate of water absorption and, in conjunction with the embossing of the present invention, brings with it increased water retention.

In bestimmten Fällen ist es von Vorteil, wenn ein Former mit zwei umlaufenden Entwässerungsbändern verwendet wird, die unter Bildung eines Stoffeinlaufspaltes zusammenlaufen und über ein Formierelement wie insbesondere eine Formierwalze geführt sind, und als nicht mit dem Formierelement in Kontakt tretendes Außenband und/oder als Innenband ein Entwässerungssieb mit zonal unterschiedlicher Siebdurchlässigkeit verwendet wird. Dabei kann beispielsweise als Innenband ein Prägeband und vorzugsweise als Außenband ein Entwässerungssieb mit zonal unterschiedlicher Siebdurchlässigkeit verwendet werden. Es ist beispielsweise auch möglich, daß die Faserstoffbahn durch ein Prägeband vorzugsweise von dem Innenband übernommen wird.In certain cases, it is advantageous if a former with two circulating dewatering belts is used, which converge to form a Stoffeinlaufspaltes and are passed over a forming element such as in particular a forming roller, and as not coming into contact with the forming element in contact Outside belt and / or as inner band a drainage sieve with zonal different Siebdurchlässigkeit is used. In this case, for example, an embossing belt and preferably as an outer belt, a dewatering screen with zonal different Siebdurchlässigkeit be used as an inner band. It is also possible, for example, that the fibrous web is preferably taken over by an embossing belt from the inner band.

Beim Naßprägen in einer mit einem Prägeband versehenen Tissue-Maschine geht es insbesondere auch darum, den gewünschten Trockengehalt zu erzielen. Die Bahn kann mittels des Prägebandes beispielsweise mittels eines Saugkastens vor der Presse naßgeprägt werden. Um nun zu vermeiden, daß die dreidimensionale Oberflächenstruktur, die durch die Naßprägung im Bereich des Naßsaugers (wet suction box) vorgeprägt wurde, durch einen kurzzeitigen hohen Druck im Preßnip wieder zerstört wird, wie dies bei einer herkömmlichen Saugpreßwalze der Fall ist, wird gemäß einer vorteilhaften praktischen Ausgestaltung des erfindungsgemäßen Verfahrens durch den Preßnip ein Prägeband, z.B. Prägesieb oder Prägemembran, geführt, das so strukturiert ist, daß sich für dieses Prägeband ein im Vergleich zum Flächenanteil an zurückgesetzten Zonen bzw. Löchern kleinerer Flächenanteil an erhabenen bzw. geschlossenen Zonen ergibt und entsprechend in dem Preßnip ein kleinerer Flächenanteil der Faserstoffbahn gepreßt wird. Der kleinere Flächenanteil an erhabenen bzw. geschlossenen Zonen ergibt die Bahnbereiche hoher Dichte für die Festigkeit, während der größere Flächenanteil an zurückgesetzten Zonen bzw. Löchern, der zumindest im wesentlichen ungepreßt bleibt, die gewünschte Wasseraufnahmefähigkeit und das gewünschte Volumen erbringt, wie sie bisher nur durch eine aufwendige und teure Durchströmungs- oder TAD-Trocknung erreicht wurden.In wet embossing in a tissue machine provided with an embossing belt, it is particularly important to achieve the desired dry content. The web can be wet embossed by means of the embossing belt, for example by means of a suction box in front of the press. In order to avoid that the three-dimensional surface structure, which was pre-stamped by the wet embossing in the wet suction box, is again destroyed by a brief high pressure in the press nip, as is the case with a conventional suction press roll, according to advantageous practical embodiment of the method according to the invention by the Preßnip an embossing belt, eg embossing screen or embossing membrane, led, which is structured so that results for this embossing belt compared to the area ratio of recessed zones or holes smaller area ratio of raised or closed zones and Accordingly, in the Preßnip a smaller area fraction of the fibrous web is pressed. The smaller areal proportion of raised or closed zones provides the high density web areas for strength, while the larger areal fraction of recessed zones or holes remaining at least substantially unpressed will provide the desired water absorbency and volume as previously limited a complex and expensive Durchströmungs- or TAD drying were achieved.

Dabei kann vorteilhafterweise ein Prägeband verwendet werden, bei dem der Flächenanteil an erhabenen bzw. geschlossenen Zonen ≤ 40 % ist und vorzugsweise in einem Bereich von etwa 25 bis etwa 30 % liegt.In this case, an embossing belt can advantageously be used in which the areal proportion of raised or closed zones is ≦ 40% and is preferably in a range from about 25 to about 30%.

Zweckmäßigerweise wird ein Prägeband verwendet, bei dem sich die erhabenen Zonen und die zurückgesetzten Zonen durch Kröpfungen, d.h. durch Kreuzungspunkte aus Schuß- und Kettfäden, eines Siebgewebes ergeben. Wie bereits erwähnt kann beispielsweise auch eine Prägemembran verwendet werden, bei sich die erhabenen und zurückgesetzten Zonen durch die Löcher ergeben. In diesem Fall ist von Vorteil, daß 100 % von der Fläche um die Löcher gepreßt wird und sich eine höhere Festigkeit ergibt.Conveniently, an embossing belt is used in which the raised zones and recessed zones are offset by cranks, i. result from crossing points of weft and warp threads, a screen mesh. As already mentioned, for example, an embossing membrane can also be used, with which the raised and recessed zones result through the holes. In this case, it is advantageous that 100% of the surface is pressed around the holes and results in a higher strength.

Das betreffende Prägeband kann zusammen mit der Faserstoffbahn beispielsweise wieder über einen Trockenzylinder, insbesondere Yankee-Zylinder geführt werden. Als mit dem Trockenzylinder zusammenwirkendes Gegenelement kann insbesondere wieder eine Schuhpreßeinheit eingesetzt werden. Auch die in Bahnlaufrichtung betrachtete Länge des Preßnips sowie das sich über die Preßniplänge ergebende Druckprofil können insbesondere wieder so gewählt werden, wie dies zuvor angegeben wurde.The embossing belt in question can be guided together with the fibrous web, for example, again over a drying cylinder, in particular Yankee cylinder. As a counter-element cooperating with the drying cylinder, a shoe press unit can in particular be used again. The length of the press nip considered in the web running direction as well as the pressure profile resulting over the press nip length can in particular be selected again as stated above.

Es hat sich gezeigt, daß mit dem erfindungsgemäßen Verfahren eine um 50% höhere Wasseraufnahmefähigkeit (g H20/g Fasern) und ein um 100% höheres Volumen (cm3/g) bei gleicher Zugfestigkeit bei einem Einsatz eines Prägebandes anstelle eines herkömmlichen Filzes im Preßnip vor der Kreppung erreicht werden kann.It has been shown that with the inventive method, a 50% higher water absorption capacity (g H20 / g fibers) and a 100% higher volume (cm 3 / g) at the same tensile strength when using an embossing belt instead of a conventional felt in Preßnip can be achieved before creping.

Durch Kreppen der Bahn kann die Wasseraufnahmefähigkeit um 50% verbessert werden, und unter Berücksichtigung dieses Umstandes kann eine Wasseraufnahmefähigkeit von TAD-Handtuch-Qualität erreicht werden.Creping the web can improve the water absorbency by 50%, and taking this into account, TAD towel quality water absorption can be achieved.

Die WO 93/00475 und die WO 00/19014 beschreiben ein Verfahren zur Herstellung von Tissuepapier, bei dem die Tissuebahn auf ein Prägesieb gepresst wird und anschließend mittels Luftströmung in Richtung des Prägesiebs in einem TAD Prozess getrocknet wird.The WO 93/00475 and the WO 00/19014 describe a process for the production of tissue paper in which the tissue web is pressed onto an embossing sieve and then dried by means of air flow in the direction of the embossing sieve in a TAD process.

Die US 6,103,062 beschreibt ein Verfahren zur Herstellung von Tissuepapier, bei dem das Tissuepapier vor dem Yankee Trockenzylinder mittels einer Schuhpresse auf ein Prägeband gepresst wird. Gemäß dieser Druckschrift wird die Tissuebahn in der Schuhpresse ferner entwässert, wobei beidseitig der Tissuebahn ein Pressfilz mit Kapillarwirkung angeordnet ist.The US 6,103,062 describes a process for the production of tissue paper in which the tissue paper is pressed onto a stamping belt in front of the Yankee drying cylinder by means of a shoe press. According to this publication, the tissue web is further dehydrated in the shoe press, with a press felt with capillary action being arranged on both sides of the tissue web.

Die WO 99/47749 zeigt ein Verfahren zur Herstellung von Tissuepapier, bei dem die Tissuebahn auf einem Prägeband zusammen mit einem Filz durch einen zwischen einer Walze und einem Yankee-Zylinder gebildeten Pressnip geführt wird.The WO 99/47749 shows a process for the production of tissue paper, in which the tissue web is guided on an embossing belt together with a felt through a press nip formed between a roller and a Yankee cylinder.

Die US 4,102,737 lehrt eine Maschine zur Herstellung von Tissuepapier, bei der die Tissuebahn auf einem Prägeband mittels eines TAD-Prozesses getrocknet wird.The US 4,102,737 teaches a machine for the production of tissue paper, in which the tissue web is dried on a stamping tape by means of a TAD process.

Die Bespannung mit geschäumter Schicht kann beispielsweise eine Saugwalze mit einem Durchmesser von z.B. etwa 2 bis 3 m oder mehrere Saugwalzen mit kleinerem Durchmesser, vorzugsweise zwei Saugwalzen mit einem Durchmesser von beispielsweise jeweils etwa 2 m, umschlingen. Die Verweilzeit der Bahn im Bereich der Saugwalze bzw. den Saugwalzen soll zweckmäßigerweise größer als etwa 0,15 s und kleiner als etwa 0,40 s sein.For example, the foamed layer fabric may comprise a suction roll having a diameter of e.g. about 2 to 3 m or more suction rolls of smaller diameter, preferably two suction rolls with a diameter of, for example, in each case about 2 m, loop. The residence time of the web in the area of the suction roll or the suction rolls should expediently be greater than about 0.15 s and less than about 0.40 s.

Die betreffende Saugwalze kann auf deren Unterseite z.B. mit Vakuum beaufschlagt werden, oder es kann eine Saugsalze mit zugeordnetem Siphonabzug verwendet werden. Insbesondere bei einem geringeren Durchmesser kann das Wasser beispielsweise auch durch Zentrifugalkraft in eine Rinne abgeschleudert werden.The respective suction roll can be placed on its underside, e.g. be applied with vacuum, or it can be used a Saugsalze with associated Siphonabzug. In particular, with a smaller diameter, the water can be thrown off, for example by centrifugal force in a gutter.

Eine Entwässerung unter Ausnutzung der Kapillarwirkung ist zwar bereits in der US 5 701 682 beschrieben. Das betreffende Kapillarelement ist hier jedoch Teil der Saugwalze.A drainage taking advantage of the capillary action is already in the US 5,701,682 described. However, the capillary element in question is part of the suction roll here.

Trotz der Ausnutzung der Kapillarwirkung zur Entwässerung kann der besaugten Einrichtung insbesondere wieder eine unter Überdruck stehende Haube zugeordnet werden, um die Unterdruckwirkung der besaugten Einrichtung zu unterstützen.Despite the utilization of the capillary action for dehydration, the suctioned device can, in particular, again be associated with a hood under overpressure in order to support the negative pressure effect of the evacuated device.

Gemäß einer weiteren bevorzugten Ausgestaltung des erfindungsgemäßen Verfahrens wird die Faserstoffbahn zum Austreiben von Wasser mittels Gasdruck zusammen mit einem Prägeband wenigstens einmal, vorzugsweise zweimal, durch einen Druckraum geführt, der von wenigstens vier parallel angeordneten Walzen begrenzt und in den ein Druckgas eingeleitet wird. Dabei wird die Faserstoffbahn vorzugsweise zusammen mit dem Prägeband und einer Membran durch den Druckraum geführt. Das Grundprinzip einer solchen Verdrängungspresse, bei der das Wasser in der Faserstoffbahn durch Luft verdrängt wird, ist beispielsweise in der DE 19946972 beschrieben.According to a further preferred embodiment of the method according to the invention, the fibrous web for expelling water by gas pressure together with an embossing belt at least once, preferably twice, passed through a pressure chamber bounded by at least four parallel rollers and into which a compressed gas is introduced. The fibrous web is preferably guided together with the embossing belt and a membrane through the pressure chamber. The basic principle of such a displacement press, at the water in the fibrous web is displaced by air, for example, in the DE 19946972 described.

Bevorzugte Ausführungsformen der erfindungsgemäßen Vorrichtung sind in den Unteransprüchen angegeben.Preferred embodiments of the device according to the invention are specified in the subclaims.

Die Erfindung kann insbesondere bei Crescent-Formern, DuoFormern, C-Wrap-Formern, S-Wrap-Formern sowie bei der Herstellung von mehrschichtigem und mehrlagigem Tissue angewendet werden.The invention is particularly applicable to Crescent Formers, Duo Formers, C-Wrap Formers, S-Wrap Formers and to the manufacture of multi-layer and multi-ply tissue.

Die Erfindung wird im folgenden anhand von Ausführungsbeispielen unter Bezugnahme auf die Zeichnung näher erläutert; in dieser zeigen:

Fig. 1
eine schematische Teildarstellung einer Vorrichtung zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn,
Fig. 2
eine schematische Teildarstellung einer abgewandelten Ausführungsform der Vorrichtung, bei der der Filz nicht über die besaugte Einrichtung geführt ist,
Fig. 3
eine schematische Teildarstellung einer Ausführungsform einer Vorrichtung zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn, bei der zusätzlich eine Entwässerungsvorrichtung vorgesehen ist, in der zur Entwässerung die Kapillarwirkung eines Filzes mit geschäumter Schicht ausgenutzt wird,
Fig. 4
eine schematische Teildarstellung einer weiteren Ausführungsform einer Vorrichtung zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn, bei der zusätzlich eine Entwässerungsvorrichtung vorgesehen ist, in der zur Entwässerung die Kapillarwirkung eines Filzes mit geschäumter Schicht ausgenutzt wird,
Fig. 5
eine schematische Teildarstellung einer Ausführungsform einer Vorrichtung zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn, bei der zusätzlich eine Verdrängungspresse vorgesehen ist,
Fig. 6
eine schematische Teildarstellung eines Prägebandes mit einem im Vergleich zum Flächenanteil an zurückgesetzten Zonen kleineren Flächenanteil an erhabenen Zonen und
Fig. 7
einen schematischen Schnitt durch einen Preßnip, durch den das in der Fig. 6 dargestellte Prägeband zusammen mit der Faserstoffbahn und einem vorzugsweise weichen Filz hindurchgeführt ist.
The invention is explained in more detail below with reference to embodiments with reference to the drawing; in this show:
Fig. 1
FIG. 2 a schematic partial representation of a device for producing a fibrous web provided with a three-dimensional surface structure; FIG.
Fig. 2
a schematic partial view of a modified embodiment of the device in which the felt is not passed over the evacuated device,
Fig. 3
1 is a schematic partial representation of an embodiment of an apparatus for producing a fibrous web provided with a three-dimensional surface structure, in which a dewatering device is additionally provided, in which the capillary action of a foamed-layer felt is utilized for dewatering;
Fig. 4
a schematic partial view of another embodiment of an apparatus for producing a provided with a three-dimensional surface structure fibrous web, in which a drainage device is additionally provided in which the capillary action of a felt with foamed layer is used for dewatering,
Fig. 5
FIG. 2 a schematic partial representation of an embodiment of an apparatus for producing a fibrous web provided with a three-dimensional surface structure, in which a displacement press is additionally provided, FIG.
Fig. 6
a schematic partial view of an embossing belt with a smaller compared to the area ratio of recessed zones area ratio of raised zones and
Fig. 7
a schematic section through a Preßnip, through which in the Fig. 6 shown embossing belt is passed together with the fibrous web and a preferably soft felt.

Fig. 1 zeigt in schematischer Teildarstellung eine Vorrichtung 10 zur Herstellung einer mit einer dreidimensionalen Oberflächenstruktur versehenen Faserstoffbahn 12 (vgl. auch Fig. 7), bei der es sich insbesondere um eine Papierbahn und vorzugsweise um eine Tissue- oder Hygienebahn handeln kann. Fig. 1 shows a schematic partial representation of an apparatus 10 for producing a provided with a three-dimensional surface structure fibrous web 12 (see also Fig. 7 ), which may in particular be a paper web and preferably a tissue or hygiene web.

Die Faserstoffbahn 12 wird bei einem Trockengehalt < 35 % mittels eines ersten Druckfeldes I auf ein Präge- oder Strukturband 14 gedrückt, z.B. gesaugt, und dadurch vorgeprägt und anschließend zur weiteren Entwässerung und Trocknung mittels eines weiteren Druckfeldes II ein weiteres Mal auf das Prägeband 14 gedrückt, um die dreidimensionale Oberflächenstruktur und Festigkeit zu fixieren. Dabei kann als Prägeband 14 insbesondere ein Prägesieb vorgesehen sein.The fibrous web 12 is pressed at a dry content <35% by means of a first pressure pad I on a stamping or structural band 14, e.g. sucked, and thereby pre-embossed and then pressed for further drainage and drying by means of another pressure pad II a further time on the embossing belt 14 to fix the three-dimensional surface structure and strength. In this case can be provided as embossing belt 14, in particular an embossing screen.

Bei dem vorliegenden Ausführungsbeispiel ist zum Prägen und zum Fixieren der Oberflächenstruktur dasselbe Prägeband 14 vorgesehen.In the present embodiment, the same embossing belt 14 is provided for embossing and fixing the surface structure.

Das erste Druckfeld I wird mittels eines auf der von der Faserstoffbahn 12 abgewandten Seite des Prägebandes 14 angeordneten Saugelements 16 erzeugt, wodurch die Faserstoffbahn 12 in die Oberflächenstruktur des Prägebandes 14 gesaugt wird. Das Saugelement 16 kann insbesondere als Saugkasten oder Naßsauger vorgesehen sein.The first pressure field I is produced by means of a suction element 16 arranged on the side of the embossing belt 14 facing away from the fibrous web 12, whereby the fibrous web 12 is sucked into the surface structure of the embossing belt 14. The suction element 16 may be provided in particular as a suction box or wet vacuum.

In dem weiteren Druckfeld II wird die Faserstoffbahn 12 vorzugsweise sanft, d.h. insbesondere über eine in Bahnlaufrichtung L verlängerte Strecke hinweg, gepreßt. Dabei kann das weitere Druckfeld II insbesondere mittels eines Preßnips 18 erzeugt werden, der zwischen einem Trockenzylinder 20 und einem Gegenelement 22 gebildet ist. Die durch den Preßnip 18 geführte Faserstoffbahn 12 ist hierbei in Kontakt mit der Oberfläche 20' des Trockenzylinders 20. Mit ihrer anderen Seite liegt sie am Prägeband 14 an.In the further pressure field II, the fibrous web 12 is preferably gently, ie in particular over a lengthened in the direction of web travel L distance pressed. In this case, the further pressure field II can be generated in particular by means of a Preßnips 18, between a drying cylinder 20 and a counter-element 22 is formed. The guided through the press nip 18 fibrous web 12 is in this case in contact with the surface 20 'of the drying cylinder 20. With its other side it lies against the embossing belt 14.

Als Trockenzylinder 20 kann insbesondere ein Yankee-Zylinder vorgesehen sein.As a drying cylinder 20 may be provided in particular a Yankee cylinder.

Als mit dem Trockenzylinder 20 zusammenwirkendes Gegenelement ist vorzugsweise eine Schuhpreßeinheit 22 vorgesehen, die ein im Bereich des Preßnips 18 über einen Preßschuh 24 geführtes flexibles Band 26 umfaßt. Beim vorliegenden Ausführungsbeispiel ist als Schuhpreßeinheit 22 eine mit einem flexiblen Walzenmantel 26 versehene Schuhpreßwalze vorgesehen.As a cooperating with the drying cylinder 20 counter element is preferably a Schuhpreßeinheit 22 is provided which comprises a guided in the region of the press nips 18 via a press shoe 24 flexible belt 26. In the present embodiment is provided as Schuhpreßeinheit 22 provided with a flexible roll shell 26 shoe press roll.

Es ergibt sich somit ein in Bahnlaufrichtung L verlängerter Preßnip 18, wodurch eine relativ sanfte Pressung der Faserstoffbahn 12 erreicht wird.This results in a lengthened in the web running direction L Preßnip 18, whereby a relatively gentle pressure of the fibrous web 12 is achieved.

Innerhalb der Schlaufe des Prägebandes 14 kann ein vorzugsweise weiches Band 28 (capillary fabric), insbesondere ein weicher Filz oder ein weicher Schaumfilz, durch den Preßnip 18 geführt sein. Dieses weiche Band 28 läuft also zwischen dem Prägeband 14 und dem flexiblen Band 26 der Schuhpreßeinheit 22.Within the loop of the embossing belt 14, a preferably soft band 28 (capillary fabric), in particular a soft felt or a soft foam felt, may be guided through the press nip 18. This soft band 28 thus runs between the embossing belt 14 and the flexible belt 26 of the shoe press unit 22.

Die Faserstoffbahn 12 kann auf dem Trockenzylinder 20, d.h. beispielsweise auf einem Yankee-Zylinder, getrocknet werden. Zudem kann die Faserstoffbahn 12 gekreppt werden. Schließlich kann die Bahn 12 durch entsprechende Mittel aufgewickelt werden.The fibrous web 12 may be placed on the drying cylinder 20, i. For example, on a Yankee cylinder, dried. In addition, the fibrous web 12 can be creped. Finally, the web 12 can be wound up by appropriate means.

Der Trockengehalt, bei dem die Faserstoffbahn 12 vorgeprägt wird, und/oder der Trockengehalt, bei dem die dreidimensionale Oberflächenstruktur fixiert wird, ist, wie bereits erwähnt, < 35 %, und kann insbesondere < 30 % und vorzugsweise < 25 % sein.The dry content at which the fibrous web 12 is pre-stamped and / or the dry content at which the three-dimensional surface structure is fixed is as already mentioned, <35%, and may in particular be <30% and preferably <25%.

Zwischen dem Saugelement 16 und dem Preßnip 18 ist eine besaugte Einrichtung 30 vorgesehen, bei der es sich insbesondere um eine Saugwalze handeln kann. Die Faserstoffbahn 12 ist zusammen mit dem Prägeband 14 sowohl über die besaugte Einrichtung 30 als auch durch den Preßnip 18 geführt. Der Filz 28 ist zwischen dem Prägeband 14 und dem flexiblen Band 26 der Schuhpreßeinheit 22 durch den Preßnip 18 geführt.Between the suction element 16 and the press nip 18, a suctioned device 30 is provided, which may in particular be a suction roll. The fibrous web 12 is guided together with the embossing belt 14 both via the evacuated device 30 and through the press nip 18. The felt 28 is guided between the embossing belt 14 and the flexible belt 26 of the shoe press unit 22 through the press nip 18.

Beim vorliegenden Ausführungsbeispiel ist der Filz 28 nicht nur durch den Preßnip 18, sondern auch über die besaugte Einrichtung 30 geführt. Da die Saugwi r-kung der Einrichtung 30 durch den Widerstand des Filzes 28 reduziert wird, kann der besaugten Einrichtung 30 eine unter Überdruck stehende Haube zugeordnet sein, um die Unterdruckwirkung der besaugten Einrichtung 30 zu unterstützen.In the present embodiment, the felt 28 is guided not only by the Preßnip 18, but also on the evacuated device 30. Since the Saugwi kung of the device 30 is reduced by the resistance of the felt 28, the evacuated means 30 may be associated with an over-standing hood to support the vacuum effect of the evacuated device 30.

Zur Konditionierung des Filzes 28 kann eine Saugeinrichtung 32 wie insbesondere ein Saugkasten oder dergleichen vorgesehen sein. Wie anhand der Fig. 1 zu erkennen ist, ist diese der Filzkonditionierung dienende Saugeinrichtung 32 vor der besaugten Einrichtung 30 angeordnet, in deren Bereich der Filz 28 mit dem die Faserstoffbahn 12 tragenden Prägeband 14 zusammengeführt wird. Dabei ist die Saugeinrichtung 32 vorzugsweise vor (Darstellung in durchgezogenen Linien) einer unteren Umlenkwalze 72 angeordnet. Grundsätzlich ist jedoch auch eine Anordnung hinter dieser unteren Umlenkwalze 72 möglich (gestrichelte Darstellung 32').For conditioning the felt 28, a suction device 32, in particular a suction box or the like, may be provided. As based on the Fig. 1 can be seen, this felt conditioning device serving suction device 32 is disposed in front of the evacuated device 30, in the region of the felt 28 is merged with the embossing belt 14 carrying the fibrous web 12. In this case, the suction device 32 is preferably arranged in front of (shown in solid lines) a lower deflection roller 72. In principle, however, an arrangement behind this lower guide roller 72 is possible (dashed line 32 ').

Durch die relativ lange gemeinsame Führung von Filz 28 und Prägeband 14 wird durch die Kapillarwirkung des Filzes 28 der Faserstoffbahn 12 über eine längere Strecke hinweg Wasser entzogen. Zuvor wird der Filz 28 über die Saugeinrichtung 32 konditioniert, wodurch dessen Trockengehalt erhöht und der Filz gereinigt wird.Due to the relatively long joint leadership of felt 28 and embossing belt 14 water is removed by the capillary action of the felt 28 of the fibrous web 12 over a longer distance. Previously, the felt 28 is over the suction device 32 conditioned, which increases its dry content and the felt is cleaned.

Vor der besaugten Einrichtung 30 wird das Prägeband 14 über das Saugelement 16 geführt, was außer einer Trockengehaltssteigerung eine Vorprägung der Faserstoffbahn 12 bewirkt. Diese wird in die dreidimensionale Oberflächenstruktur des Prägebandes bzw. -siebes 14 gesaugt, wodurch der Bahn die Struktur aufgeprägt wird.In front of the evacuated device 30, the embossing belt 14 is guided over the suction element 16, which causes a pre-embossing of the fibrous web 12 in addition to a dry content increase. This is sucked into the three-dimensional surface structure of the embossing belt or sieve 14, whereby the structure of the web is impressed.

Die in der Fig. 2 dargestellte Ausführungsform unterscheidet sich von der gemäß Fig. 1 im wesentlichen nur dadurch, daß der Filz 28 erst nach der besaugten Ei n-richtung 30 mit dem die Faserstoffbahn 12 tragenden Prägeband 14 zusammengeführt wird. Die besaugte Einrichtung 30 wird also in diesem Fall nicht vom Filz 28 umschlungen, wodurch deren Saugeffekt erhöht und entsprechend der Trockengehalt gesteigert wird. Der Naßprägeeffekt bleibt durch die relativ schonende Entwässerung der TissueFlex erhalten, bei der der Druck im Gegensatz zu einer herkömmlichen Schuhpresse geringer ist.The in the Fig. 2 illustrated embodiment differs from that according to Fig. 1 essentially only in that the felt 28 is brought together after the suctioned egg n-direction 30 with the fibrous web 12 carrying embossing belt 14. The evacuated device 30 is thus not wrapped in this case by the felt 28, whereby their suction effect is increased and the dry content is increased accordingly. The wet embossing effect is maintained by the relatively gentle dewatering of the TissueFlex, where the pressure is lower than that of a conventional shoe press.

Im übrigen kann diese Ausführungsform zumindest im wesentlichen so wie die gemäß Fig. 1 ausgelegt sein. So ist auch hier die Saugeinrichtung 32 vorzugsweise wieder vor (Darstellung in durchgezogenen Linien) der unteren Umlenkwalze 72 angeordnet, wobei grundsätzlich jedoch auch wieder eine Anordnung hinter dieser unteren Umlenkwalze 72 möglich ist (gestrichelte Darstellung 32').Moreover, this embodiment, at least substantially as the according to Fig. 1 be designed. Thus, here too, the suction device 32 is preferably arranged again before (representation in solid lines) of the lower deflection roller 72, wherein in principle, however, an arrangement behind this lower deflection roller 72 is again possible (dashed representation 32 ').

Fig. 3 zeigt in schematischer Teildarstellung eine Ausführungsform, bei der zusätzlich eine Entwässerungsvorrichtung 34 vorgesehen ist, in der zur Entwässerung die Kapillarwirkung eines Filzes 36 mit geschäumter Schicht ausgenutzt wird. Dabei kann die Schaumstoffbeschichtung insbesondere so gewählt sein, daß sich Poren in einem Bereich von etwa 3 bis etwa 6 µm ergeben. Fig. 3 shows a schematic partial representation of an embodiment in which a drainage device 34 is additionally provided, in which the capillary action of a felt 36 with foamed layer is used for dewatering. In this case, the foam coating may in particular be selected so that pores in a range of about 3 to about 6 microns.

Im vorliegenden Fall ist der Filz 36 mit geschäumter Schicht zusammen mit einem Prägeband 14 und dazwischen liegender Faserstoffbahn 12 um eine größere Saugwalze 38 geführt, wobei der Filz 36 vorzugsweise mit der Saugwalze 38 in Kontakt ist. Die von dem Filz 36 geschäumte Schicht umschlungene Saugwalze 38 kann beispielsweise einen Durchmesser von etwa 2 bis etwa 3 m besitzen. Die Saugwalze 38 kann auf deren Unterseite mit Vakuum beaufschlagbar sein. Grundsätzlich kann der Saugwalze 38 auch ein Siphonabzug zugeordnet sein. Die betreffenden Mittel sind in der Fig.3 mit "40" bezeichnet.In the present case, the foamed layer felt 36 together with an embossing belt 14 and intermediate fibrous web 12 is guided around a larger suction roll 38, the felt 36 preferably being in contact with the suction roll 38. For example, the suction roll 38 wrapped around the felt 36 may have a diameter of about 2 to about 3 meters. The suction roller 38 may be acted upon by vacuum on its underside. In principle, the suction roll 38 can also be assigned a siphon outlet. The funds in question are in the Figure 3 denoted by "40".

Im Formierbereich kann wenigstens ein Entwässerungssieb mit zonal unterschiedlicher Siebdurchlässigkeit vorgesehen sein.In the forming region, at least one drainage sieve with zonal different sieve permeability can be provided.

Im vorliegenden Fall ist ein Former mit zwei umlaufenden Entwässerungsbändern 14, 42 vorgesehen, wobei das Innenband 14 gleichzeitig als Prägeband dient. Die beiden Entwässerungsbänder 14, 42 laufen unter Bildung eines Stoffeinlaufspaltes 44 zusammen und sind über ein For- mi erelement 46 wie insbesondere eine Formierwalze geführt.In the present case, a former with two circumferential dewatering belts 14, 42 is provided, the inner belt 14 also serving as an embossing belt. The two dewatering belts 14, 42 converge to form a material inlet gap 44 and are guided over a shaping element 46 such as in particular a forming roller.

Im vorliegenden Fall wird das Prägeband 14 durch das mit dem Formier- element 46 in Kontakt tretende Innenband des Formers gebildet. Das nicht mit dem Formierelement 46 in Kontakt tretende Außenband 42 kann insbesondere als Entwässerungssieb mit zonal unterschiedlicher Siebdurchlässigkeit vorgesehen sein.In the present case, the embossing belt 14 is formed by the element 46 coming into contact with the inner band of the former. The outer band 42, which does not come into contact with the forming element 46, can be provided in particular as a dewatering screen with zonal different screen permeability.

Mittels eines Stoffauflaufs 48 wird die Faserstoffsuspension in den Stoffeinlaufspalt 44 eingebracht. Hinter dem Formierelement 46 ist ein Pickup- oder Trennelement 50 vorgesehen, durch das die Bahn bei der Trennung vom Entwässerungsband 42 auf dem Prägeband 14 gehalten wird. Vorzugsweise vor der Ei n-richtung 34 mit Kapillarwirkung ist wieder ein Saugelement 16 (durchgezogene Darstellung) vorgesehen, durch das die Faserstoffbahn 12 auf das Prägeband 14 gedrückt wird. Dieses Saugelement kann jedoch auch zwischen der Einrichtung 34 mit Kapillarwirkung und der besaugten Einrichtung bzw. Saugwalze 30 angeordnet sein (gestrichelte Darstellung 16').By means of a headbox 48, the pulp suspension is introduced into the stock inlet gap 44. Behind the forming element 46, a pickup or separating element 50 is provided, through which the web is held on the embossing belt 14 during the separation from the dewatering belt 42. Preferably in front of the egg n-direction 34 with capillary action is again a suction element 16 (solid Representation) provided by the fibrous web 12 is pressed onto the embossing belt 14. However, this suction element can also be arranged between the device 34 with capillary action and the evacuated device or suction roller 30 (dashed representation 16 ').

Zusammen mit der Faserstoffbahn 12 und dem Prägeband 14 wird wieder ein weiches Band bzw. Filz 28 durch den zwischen einem Trockenzylinder 20 und einer Schuhpreßeinheit 22 gebildeten Preßnip 18 geführt. Im vorliegenden Fall ist das weiche Band entsprechend der Ausführung gemäß Fig. 1 auch wieder um die besaugte Einrichtung 30 geführt. Auch bei diesem weichen Band 28 kann es sich beispielsweise wieder um einen eine Kapillarwirkung aufweisenden Filz (capillary felt) handeln. Der Filz 28 kann beispielsweise wieder über eine Saugeinrichtung oder eine sogenannte UHLE-Box konditioniert werden. Bei dem Trockenzylinder 20 kann es sich insbesondere wieder um einen Yankee-Zylinder handeln. Dabei kann diesem Trockenzylinder 20 eine Trockenhaube 52 zugeordnet sein.Together with the fibrous web 12 and the embossing belt 14, a soft belt or felt 28 is again guided through the press nip 18 formed between a drying cylinder 20 and a shoe press unit 22. In the present case, the soft band is according to the embodiment according to Fig. 1 again guided around the evacuated device 30. For example, this soft band 28 may again be a capillary felt. For example, the felt 28 can be conditioned again via a suction device or a so-called UHLE box. The drying cylinder 20 may in particular be a Yankee cylinder again. In this case, this drying cylinder 20 may be associated with a drying hood 52.

Beim vorliegenden Ausführungsbeispiel beträgt der Trockengehalt der Faserstoffbahn vor der Entwässerungseinrichtung 34 mit Kapillarwirkung etwa 10 bis etwa 25 %, im Bereich nach dieser Einrichtung 34 z.B. etwa 30 bis etwa 40%.In the present embodiment, the dry content of the fibrous web before the capillary drainage device 34 is about 10 to about 25%, in the area downstream of this device 34 e.g. about 30 to about 40%.

Die in der Fig. 4 dargestellte Ausführungsform unterscheidet sich von der gemäß Fig. 3 zunächst dadurch, daß die Faserstoffbahn 12 durch das Prägeband 14 von einem Innenband 54 des Formers übernommen wird. Im vorliegenden Fall kann beispielsweise dieses Innenband 54 oder das Außenband 42 des Formers wieder als Entwässerungssieb mit zonal unterschiedlicher Siebdurchlässigkeit vorgesehen sein. Die beiden umlaufenden Entwässerungsbänder 42, 54 laufen wieder unter Bildung eines Stoffeinlaufspaltes 44 zusammen, wobei sie wieder über ein Formierelement 46 wie insbesondere eine Formierwalze geführt sind. Mittels eines Stoffauflaufs 48 wird der Stoffeinlaufspalt 44 wieder mit Faserstoffsuspension beschickt. Anders als bei der Ausführungsform gemäß der Fig. 3 wird die Faserstoffsuspension im vorliegenden Fall jedoch von unten zugeführt.The in the Fig. 4 illustrated embodiment differs from that according to Fig. 3 initially by the fact that the fibrous web 12 is taken over by the embossing belt 14 of an inner band 54 of the former. In the present case, for example, this inner band 54 or the outer band 42 of the former can again be provided as a dewatering screen with zonal different Siebdurchlässigkeit. The two circulating dewatering belts 42, 54 converge again to form a material inlet gap 44, wherein they are guided again over a forming element 46 such as in particular a forming roller. By means of a headbox 48 of the material inlet gap 44 is again with pulp suspension fed. Unlike the embodiment according to the Fig. 3 However, the pulp suspension is supplied in the present case from below.

Innerhalb der Schlaufe des Prägebandes 14 ist wieder ein Pickup- oder Trennelement vorgesehen, durch das die Faserstoffbahn 12 bei der Trennung vom I n-nenband 54 des Formers auf dem Prägeband gehalten wird.Within the loop of the embossing belt 14, a pickup or separating element is again provided, through which the fibrous web 12 is held on the embossing belt during the separation from the inner band 54 of the former.

Das innerhalb der Schlaufe des Prägebandes 14 vorgesehene Saugelement 16 ist vor der Entwässerungseinrichtung 34 mit Kapillarwirkung angeordnet, wobei grundsätzlich jedoch auch eine Anordnung nach dieser Einrichtung 34 möglich ist.The provided within the loop of the embossing belt 14 suction member 16 is arranged in front of the dewatering device 34 with capillary action, in principle, however, an arrangement according to this device 34 is possible.

Im vorliegenden Fall fehlt der Filz 28.In the present case, the felt 28 is missing.

Der Trockengehalt der Faserstoffbahn beträgt beim vorliegenden Ausführungsbeispiel im Bereich des Pickup-Elements 50 etwa 10 bis etwa 25 %, im Bereich vor der Entwässerungseinrichtung 34 etwa 15 bis etwa 30 % und im Bereich nach dieser Einrichtung 34 etwa 35 bis etwa 45 %.The dry content of the fibrous web in the present embodiment is about 10 to about 25% in the region of the pickup element 50, about 15 to about 30% in the region upstream of the dewatering device 34 and about 35 to about 45% downstream of the device 34.

Im übrigen kann diese Ausführungsform zumindest im wesentlichen den gleichen Aufbau besitzen wie die gemäß Fig. 3. Einander entsprechenden Elementen sind gleiche Bezugszeichen zugeordnet.Moreover, this embodiment may have at least substantially the same structure as that according to Fig. 3 , Corresponding elements are assigned the same reference numerals.

Fig. 5 zeigt in schematischer Teildarstellung eine Ausführungsform der Vorrichtung 10, bei der eine Verdrängungspresse 56 vorgesehen ist. Dabei wird die Faserstoffbahn 12 zum Austreiben von Wasser mittels Gasdruck mit dem Prägeband 14 wenigstens einmal durch einen Druckraum 58 geführt, der von wenigstens vier parallel angeordneten Walzen 60 - 66 begrenzt und in den ein Druckgas einleitbar ist. Dabei ist die Faserstoffbahn 12 vorzugsweise zusammen mit dem Prägeband 14 und einer Membran 68 durch den Druckraum 58 geführt. Fig. 5 shows a schematic partial view of an embodiment of the device 10, in which a displacement press 56 is provided. The fibrous web 12 is guided to expel water by means of gas pressure with the embossing belt 14 at least once through a pressure chamber 58 which is bounded by at least four parallel rollers 60 - 66 and in which a compressed gas can be introduced. The fibrous web 12 is preferably guided together with the embossing belt 14 and a membrane 68 through the pressure chamber 58.

Im vorliegenden Fall bildet die Membran 68 das Innenband des Formers, der wieder ein Formierelement 46 insbesondere eine Formierwalze umfaßt, in deren Bereich das als Membran vorgesehene Innenband 48 und das Außenband 42 unter Bildung eines Stoffeinlaufspaltes 44 zusammenlaufen, der mittels eines Stoffauflaufs 48 mit Faserstoffsuspension beschickt wird.In the present case, the membrane 68 forms the inner band of the former, which again comprises a forming member 46, in particular a forming roller, in the region of which provided as a membrane inner band 48 and the outer band 42 converge to form a Stoffeinlaufspaltes 44 which feeds by means of a headbox 48 with pulp suspension becomes.

Im Anschluß an die Luftpresse 56 wird die Faserstoffbahn 12 zusammen mit dem Prägeband 14 wieder über eine besaugte Einrichtung 30, insbesondere eine Saugwalze, und durch den zwischen einem Trockenzylinder 20, insbesondere Yankee-Zylinder, und einer Schuhpreßeinheit 22 gebildeten Preßnip 18 geführt. Beim dargestellten Ausführungsbeispiel ist dem Trockenzylinder bzw. Yankee-Zylinder 20 wieder eine Trockenhaube 52 zugeordnet.Following the air press 56, the fibrous web 12 together with the embossing belt 14 again via an evacuated device 30, in particular a suction roll, and passed through the formed between a drying cylinder 20, in particular Yankee cylinder, and a shoe press 22 Preßnip 18. In the illustrated embodiment, the drying cylinder or Yankee cylinder 20 is again associated with a drying hood 52.

Im vorliegenden Fall kann das erste Druckfeld I, durch das die Faserstoffbahn 12 bei einem Trockengehalt <50% auf das Prägeband 14 gedrückt und entsprechend vorgeprägt wird, beispielsweise durch die Luftpresse 56 erzeugt werden.In the present case, the first pressure field I, by which the fibrous web 12 is pressed at a dry content of <50% on the embossing belt 14 and pre-embossed, for example, be generated by the air press 56.

Wie beispielsweise anhand der Fig. 6 und 7 zu erkennen ist, kann das jeweilige durch den Preßnip 18 geführte Prägeband 14, z.B. Prägesieb (vgl. insbesondere den linken Teil der Fig. 6) oder Prägemembran (vgl. insbesondere den linken Teil der Fig. 6), so strukturiert sein, daß sich für dieses Prägeband 14 ein im Vergleich zum Flächenanteil an zurückgesetzten Zonen bzw. Löchern 74 kleinerer Flächenanteil an erhabenen bzw. geschlossenen Zonen 68 ergibt und entsprechend in dem Preßnip 18 ein kleinerer Flächenanteil der Faserstoffbahn 12 gepreßt wird.For example, based on the 6 and 7 can be seen, the respective guided by the press nip 18 embossing belt 14, for example embossing screen (see, in particular, the left part of Fig. 6 ) or Prägemembran (see in particular the left part of Fig. 6 ), be structured so that there is a smaller area ratio of raised or closed areas 68 compared to the area portion of recessed zones or holes 74 for this embossing belt 14 and accordingly a smaller surface portion of the fibrous web 12 is pressed in the press nip 18.

Dabei kann der Flächenanteil an erhabenen bzw. geschlossenen Zonen 68 insbesondere ≤40% sein und vorzugsweise einem Bereich von etwa 25 bis etwa 30% liegen.In this case, the area fraction of raised or closed zones 68 can be in particular ≦ 40% and preferably in a range of about 25 to about 30%.

Die erhabenen Zonen 68 und die zurückgesetzten Zonen können sich beispielsweise durch Kröpfungen, d.h. durch Kreuzungspunkte aus Schuß- und Kettfäden, eines Siebgewebes ergeben. Im Fall der im rechten Teil der Fig. 6 wiedergegebenen Preßmembran ergibt sich eine entsprechende Strukturierung durch die Löcher 74.The raised zones 68 and the recessed zones may result, for example, by offsets, ie by intersections of weft and warp threads, of a mesh fabric. In the case of the right part of the Fig. 6 reproduced Preßmembran results in a corresponding structuring through the holes 74th

Fig. 6 zeigt eine schematische Teildarstellung eines entsprechenden Prägebandes 14, z.B. Prägefilz oder Prägemembran, mit einem im Vergleich zum Flächenanteil an zurückgesetzten Zonen bzw. Löchern 74 kleineren Flächenanteil an erhabenen bzw. geschlossenen Zonen 68. Fig. 6 shows a schematic partial view of a corresponding embossing belt 14, for example, embossing felt or embossing membrane, with a smaller compared to the area ratio of recessed zones or holes 74 surface portion of raised or closed areas 68th

Die Dicke d der im rechten Teil der Fig. 6 dargestellten Prägemembran kann z.B. etwa 1 bis etwa 3 mm betragen. Die offene Fläche kann insbesondere größer als 50 % und zweckmäßigerweise größer als 60 % sein und vorzugsweise in einem Bereich von etwa 70 % bis etwa 75 % liegen. Die Membran besteht zweckmäß i-gerweise aus einem gegen die Faserstoffchemie resistenten Material. Sie kann beispielsweise aus Polyester bestehen.The thickness d of the right part of the Fig. 6 For example, the embossing membrane shown may be about 1 to about 3 mm. In particular, the open area may be greater than 50%, and more preferably greater than 60%, and preferably within a range of from about 70% to about 75%. The membrane expediently i-wise of a resistant to the pulp chemistry material. It can for example consist of polyester.

Fig. 7 zeigt einen schematischen Schnitt durch einen Preßnip 18, durch den das in der Fig. 6 dargestellte Prägeband 14 zusammen mit der Faserstoffbahn 12 und einem vorzugsweise weichen Band bzw. Filz 28 hindurchgeführt ist. Dabei ist dieses weiche Band 28 in Kontakt mit dem flexiblen Band 26 der Schuhpreßeinheit, das im Bereich des Preßnips 18 über einen Preßschuh 24 geführt ist, über den die gewünschte Anpreßkraft aufgebracht werden kann. Fig. 7 shows a schematic section through a Preßnip 18, through which in the Fig. 6 shown embossing belt 14 is passed together with the fibrous web 12 and a preferably soft belt or felt 28. In this case, this soft band 28 is in contact with the flexible band 26 of the shoe press unit, which is guided in the region of the press nips 18 via a press shoe 24, via which the desired contact pressure can be applied.

Die Faserstoffbahn 12 liegt am Trockenzylinder 20, vorzugsweise einem Yankee-Zylinder, an.The fibrous web 12 is applied to the drying cylinder 20, preferably a Yankee cylinder.

In der Fig. 7 sind überdies die sich infolge der erhabenen Zonen 68 ergebenden Preßzonen 70 zu erkennen.In the Fig. 7 Moreover, the pressing zones 70 resulting from the raised zones 68 can be seen.

Die Faserstoffbahn 12 ist schon vor dem Nip geprägt. Wie anhand der Fig. 7 zu erkennen ist, liegt schon vor dem Nip am Prägeband an.The fibrous web 12 is already marked before the nip. As based on the Fig. 7 can be seen, is already on the embossing belt before the nip.

BezugszeichenlisteLIST OF REFERENCE NUMBERS

1010
Vorrichtungcontraption
1212
FaserstoffbahnFibrous web
1414
Prägebandembossing tape
1616
Saugelementsuction
1818
Preßnippress nip
2020
Trockenzylinder, Yankee-ZylinderDrying cylinder, Yankee cylinder
20'20 '
Oberflächesurface
2222
Gegenelement, SchuhpreßeinheitCounter element, shoe press unit
2424
Preßschuhpress shoe
2626
flexibles Band, flexibler Walzenmantelflexible band, flexible roll jacket
2828
weiches Band, weicher Filzsoft band, soft felt
3030
besaugte Einrichtung, Saugwalzevacuumed device, suction roller
3232
Saugeinrichtung, SaugwalzeSuction device, suction roller
3434
Entwässerungseinrichtung mit KapillarwirkungDrainage device with capillary action
3636
Filz mit geschäumter SchichtFelt with foamed layer
3838
große Saugwalzebig suction roll
4040
Vakuum, SiphonabzugVacuum, siphon outlet
4242
Entwässerungsbanddewatering belt
4444
StoffeinlaufspaltStock inlet gap
4646
Formierelement, FormierwalzeForming element, forming roller
4848
Stoffauflaufheadbox
5050
Pickup- oder TrennelementPickup or separating element
5252
TrockenhaubeTrockenhaube
5454
inneres Entwässerungssiebinner drainage sieve
5656
Luftpresseair press
5858
Druckraumpressure chamber
6060
Walzeroller
6262
Walzeroller
6464
Walzeroller
6666
Walzeroller
6868
erhabene Zonenraised zones
7070
Preßzonennips
7272
Umlenkwalzedeflecting
7474
Löcherholes
dd
Dickethickness
LL
BahnlaufrichtungWeb direction
II
erstes Druckfeldfirst pressure field
IIII
weiteres Druckfeldanother pressure field

Claims (39)

  1. Method for producing a fibrous web (12) provided with a three-dimensional surface structure, in particular a tissue or hygiene web, in which the fibrous web (12) at a dryness of < 35% is pressed onto an embossing belt (14) by means of a first pressure area (I) and is pre-embossed as a result and subsequently, for the purpose of further dewatering and drying, is pressed onto an embossing belt (14) a further time by means of a further pressure area (II) in order to fix the three-dimensional surface structure and strength, characterized in that in order to dewater the web, at least one fine-pored fabric (36) having a capillary effect is used, which is a fabric (36) with a foamed layer, the fabric (36) with foamed layer, together with an embossing belt (14) and a fibrous web (12) lying between them, being guided around at least one suction roll (38) and the fabric (36) being in contact with the suction roll (38).
  2. Method according to Claim 1, characterized in that the embossing belt used is an embossing fabric (14).
  3. Method according to Claim 1, characterized in that the embossing belt used is an embossing membrane.
  4. Method according to one of the preceding claims, characterized in that the fibrous web (12) is pre-embossed after the forming region.
  5. Method according to one of the preceding claims, characterized in that the fibrous web (12) is formed on the embossing belt (14) used for the embossing.
  6. Method according to one of the preceding claims, characterized in that the fibrous web (12) is transferred to the embossing belt (14) used for the pre-embossing.
  7. Method according to one of the preceding claims, characterized in that the same embossing belt (14) is used for pre-embossing and for fixing the surface structure.
  8. Method according to one of the preceding claims, characterized in that at least the first pressure area (I) is produced by means of a suction element (16, 16') arranged on the side of the embossing belt (14) facing away from the fibrous web (12), in order to suck the fibrous web (12) into the surface structure of the embossing belt (14).
  9. Method according to Claim 8, characterized in that the suction element used is a wet suction means.
  10. Method according to one of the preceding claims, characterized in that the fibrous web (12) is pressed gently in the further pressure area (II), that is to say over a section which is extended in the web running direction (L).
  11. Method according to one of the preceding claims, characterized in that the further pressure area (II) is produced by means of a press nip (18).
  12. Method according to Claim 11, characterized in that the press nip (18) forming the further pressure area (II) is produced between a drying cylinder (20) and an opposing element (22), the fibrous web (12) guided through the press nip (18) being in contact with the surface of the drying cylinder (20) and resting with its other side on the embossing belt (14).
  13. Method according to Claim 12, characterized in that the drying cylinder used is a Yankee cylinder (20).
  14. Method according to Claim 12 or 13, characterized in that the opposing element interacting with the drying cylinder (20) is a shoe press unit (22) which comprises a flexible belt (26) guided over a press shoe (24) in the region of the press nip (18).
  15. Method according to Claim 14, characterized in that the shoe press unit used is a shoe press roll provided with a flexible roll cover.
  16. Method according to one of the preceding claims, characterized in that a belt (28), preferably a soft belt, provided within the loop of the embossing belt (14), in particular a felt (28), is guided through the press nip (18) producing the further pressure area (II).
  17. Method according to one of the preceding claims, characterized in that the pre-embossed fibrous web (12) is dried on the drying cylinder (20), in that the fibrous web (12) is creped and/or in that the fibrous web (12) is subsequently wound up.
  18. Method according to one of the preceding claims, characterized in that the dryness at which the fibrous web (12) is pre-embossed and/or the dryness at which the three-dimensional surface structure is fixed are in each case chosen to be < 35%, in particular < 30% and preferably < 25%.
  19. Method according to one of the preceding claims, characterized in that, between the suction element (16, 16') producing the first pressure area (I) and the press nip (18) producing the further pressure area (II), an evacuated device (30) is used, and in that the fibrous web (12), together with an embossing belt (14), is guided both over the evacuated device (30) and through the press nip (18).
  20. Method according to Claim 19, characterized in that the evacuated device (30) has a curved surface, and the fibrous web (12) and the embossing belt (14) are guided over this curved surface.
  21. Method according to Claim 20, characterized in that the evacuated device (30) used is a suction roll (30).
  22. Method according to one of Claims 16 to 21, characterized in that the felt (28) is guided through the press nip (18) between the embossing belt (14) and the flexible belt (26) of the shoe press unit (22).
  23. Method according to one of Claims 16 to 22, characterized in that the felt (28) is also guided over the evacuated device (30).
  24. Method according to one of the preceding claims, characterized in that the evacuated device (30) is assigned a hood under a positive pressure in order to assist the negative pressure action of the evacuated device (30).
  25. Method according to one of the preceding claims, characterized in that the felt (28) is conditioned by means of a suction device (32), in particular by means of a suction box, before it is led together with the embossing belt (14) carrying the fibrous web (12).
  26. Method according to one of Claims 16 to 25, characterized in that the felt (28) is led together with the embossing belt (14) carrying the fibrous web (12) only after the evacuated device (30).
  27. Method according to one of Claims 14 to 26, characterized in that the length, viewed in the web running direction (L), of the press nip (18) of the shoe press comprising the drying cylinder (20) and the shoe press unit (22) is chosen to be greater than a value of about 80 mm, and the shoe press is designed in such a way that the result over the press nip length is a pressure profile with a maximum pressing pressure which is less than or equal to a value of about 2.5 mPa.
  28. Method according to one of the preceding claims, characterized in that, in the forming region, at least one dewatering fabric (42, 54) with a zonally different fabric permeability is used.
  29. Method according to Claim 28, characterized in that a former having two circulating dewatering belts (14, 42, 54) is used, which run together, forming a stock inlet gap (44), and are guided over a forming element, such as in particular a forming roll (46), and in that a dewatering fabric with a zonally different fabric permeability is used as the outer belt (42) not coming into contact with the forming element (46) and/or as the inner belt (14).
  30. Method according to Claim 29, characterized in that the inner belt used is an embossing belt (14) and, preferably, the outer belt (42) used is a dewatering fabric with a zonally different fabric permeability.
  31. Method according to Claim 30, characterized in that the fibrous web (12) is preferably picked up from the inner belt (54) by an embossing belt (14).
  32. Method according to one of the preceding claims, characterized in that an embossing belt (14), for example an embossing fabric or embossing membrane, is guided through the press nip (18), which embossing belt (14) is structured in such a way that the result for this embossing belt (14) is a smaller proportion of the area of elevated or closed zones as compared with the proportion of the area of recessed zones or holes and, accordingly, a smaller proportion of the area of the fibrous web (12) is pressed in the press nip (18).
  33. Method according to Claim 32, characterized in that an embossing belt (14) is used in which the proportion of the area of elevated or closed zones is ≤40% and preferably lies in a range from about 25% to about 30%.
  34. Method according to Claim 32 or 33, characterized in that an embossing belt (14) is used in which the elevated zones and the recessed zones result from shoulders, i.e. from crossing points of weft and warp fibres of a fabric weave.
  35. Method according to one of the preceding claims, characterized in that the fine-pored fabric with foamed layer (36) is a felt with a foamed layer.
  36. Method according to Claim 35, characterized in that the foam coating is chosen such that the result is pores in a range from about 3 to about 6 µm.
  37. Method according to one of the preceding claims, characterized in that the fabric with foamed layer (36) wraps around a suction roll (38) with a diameter from about 2 to about 3 m or a plurality of suction rolls with a smaller diameter, preferably two suction rolls with a diameter of, for example, about 2 m in each case.
  38. Method according to one of the preceding claims, characterized in that the suction roll (38) has vacuum applied to its underside.
  39. Method according to one of the preceding claims, characterized in that a suction roll with associated siphon extraction is used or the water is thrown off into a trough by centrifugal force.
EP05109471A 2001-06-20 2002-05-27 Method and device for producing a fibre strip provided with a three-dimensional surface structure Expired - Lifetime EP1626122B1 (en)

Applications Claiming Priority (2)

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DE10129613A DE10129613A1 (en) 2001-06-20 2001-06-20 Method and device for producing a fibrous web provided with a three-dimensional surface structure
EP02758205A EP1397587B1 (en) 2001-06-20 2002-05-27 Method and device for producing a fibre strip provided with a three-dimensional surface structure

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EP1626122B1 true EP1626122B1 (en) 2010-07-14

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US (2) US7291249B2 (en)
EP (3) EP1626121A1 (en)
AT (2) ATE474085T1 (en)
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DE50214542D1 (en) 2010-08-26
ATE317498T1 (en) 2006-02-15
EP1626121A1 (en) 2006-02-15
ATE474085T1 (en) 2010-07-15
US20070289159A1 (en) 2007-12-20
US7662260B2 (en) 2010-02-16
DE10129613A1 (en) 2003-01-02
BR0211023A (en) 2004-07-13
EP1397587B1 (en) 2006-02-08
EP1397587A1 (en) 2004-03-17
EP1626122A1 (en) 2006-02-15
US7291249B2 (en) 2007-11-06
WO2003000002A1 (en) 2003-01-03
US20040237210A1 (en) 2004-12-02
DE50205800D1 (en) 2006-04-20

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