EP1598118A1 - Pump for fluid dispensers - Google Patents

Pump for fluid dispensers Download PDF

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Publication number
EP1598118A1
EP1598118A1 EP04253005A EP04253005A EP1598118A1 EP 1598118 A1 EP1598118 A1 EP 1598118A1 EP 04253005 A EP04253005 A EP 04253005A EP 04253005 A EP04253005 A EP 04253005A EP 1598118 A1 EP1598118 A1 EP 1598118A1
Authority
EP
European Patent Office
Prior art keywords
pump
fluid
outlet
inlet
wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04253005A
Other languages
German (de)
English (en)
French (fr)
Inventor
Roland Nmn Stark
Mark Andrew Jarvis
William John Connolly
Arne Benjamin Colman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP04253005A priority Critical patent/EP1598118A1/en
Priority to US11/134,986 priority patent/US20050260090A1/en
Priority to JP2007527547A priority patent/JP4354508B2/ja
Priority to AU2005245497A priority patent/AU2005245497A1/en
Priority to CA002565123A priority patent/CA2565123A1/en
Priority to CNA2005800157897A priority patent/CN1953819A/zh
Priority to BRPI0510138-7A priority patent/BRPI0510138A/pt
Priority to PCT/US2005/018071 priority patent/WO2005113158A1/en
Priority to MXPA06013447A priority patent/MXPA06013447A/es
Priority to EP05755106A priority patent/EP1765512A1/en
Publication of EP1598118A1 publication Critical patent/EP1598118A1/en
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005—Components or details
    • B05B11/0037—Containers
    • B05B11/0039—Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means
    • B05B11/0044—Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means compensating underpressure by ingress of atmospheric air into the container, i.e. with venting means
    • B05B11/00444—Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means compensating underpressure by ingress of atmospheric air into the container, i.e. with venting means with provision for filtering or cleaning the air flow drawn into the container
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1028—Pumps having a pumping chamber with a deformable wall
    • B05B11/1032—Pumps having a pumping chamber with a deformable wall actuated without substantial movement of the nozzle in the direction of the pressure stroke
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1028—Pumps having a pumping chamber with a deformable wall
    • B05B11/1033—Pumps having a pumping chamber with a deformable wall the deformable wall, the inlet and outlet valve elements being integrally formed, e.g. moulded

Definitions

  • the present invention relates to a pump which can be easily made and assembled from a small number of moulded parts, particularly from injection moulded parts.
  • the invention further relates to a dispenser comprising the pump and to valving arrangements for pumps and dispensers.
  • the pump and device are useful for dispensing fluids such as medicines, including nasal and throat sprays, perfumes, cosmetics, cleaning products and the like.
  • WO 98/08661 discloses a readily manufactured pump having a small number of stackable parts. However, it still requires four parts which need to be separately manufactured and assembled.
  • WO 02/16047 discloses another simple diaphragm pump, incorporated into the inside of a dispensing flexible reservoir; it too comprises four parts.
  • a related problem is that of enabling a simple method of modular construction of dispensers whereby differently functioning pumps, e.g. delivering different size doses, can be fitted to a common dispenser, enabling a flexible method of adapting a production line to provide different products.
  • a pump of simple construction has now been developed which can be manufactured from as few as two separate parts and, in particular, each part can be formed by mass production techniques such as injection moulding, compression moulding or thermoforming.
  • the pump can be employed as a separate part in a more complex dispenser or indeed can be integrally moulded into a simple dispenser.
  • the construction of the pump provides for much greater design freedom in the way that the pump is employed in dispensers and, as a result, in the dispenser design.
  • the invention herein relates to pumps and valving arrangements for fluid dispensers.
  • the invention further relates to dispensers incorporating a pump.
  • the pumps herein comprise a dose chamber, a resilient actuator and valves for controlling the flow of fluid into and out of the dose chamber.
  • Combination of the pump with a fluid reservoir provides a fluid dispenser which may further comprise an atomiser for forming a spray as fluid is ejected from a dispenser outlet.
  • a pump for a fluid dispenser comprising:
  • a pump for a fluid dispenser comprising an upper pump half comprising a semirigid, thermoplastic material, a lower pump half, a dose chamber, a resilient actuator, a pump inlet port, a pump outlet port, an inlet valve and an outlet valve, the method comprising the steps of:
  • a pump for a fluid dispenser comprising an upper pump half comprising a semirigid, thermoplastic material, a lower pump half, a dose chamber, a resilient actuator, a pump inlet port, a pump outlet port, an inlet valve and an outlet valve, the method comprising the steps of:
  • valve module for a pump for a fluid dispenser comprising:
  • a valving arrangement suitable for use in a pump dispenser, comprising a flow channel having semirigid upper and lower walls, a fluid inlet through which fluid enters the arrangement from a fluid supply and a fluid outlet through which the fluid exits the valving arrangement, the flow channel further comprising inlet and outlet elastomeric, flap valves, mounted inside the flow channel, each valve having a surface immovably fixed to the upper flow channel wall and a flap sealingly compressed against the lower flow channel wall, whereby each valve prevents flow of fluid along the flow channel until a positive fluid pressure differential on an upstream side of the flap of the valve causes the flap to lift thereby allowing fluid to flow past the valve, the valves permitting fluid flow in the same direction along the flow channel whereby an increase in fluid pressure in a section of flow channel between the two valves causes the outlet valve to open and the inlet valve to remain closed and a reduction in fluid pressure in the section of flow channel between the two valves causes the inlet valve to open
  • the pump is incorporated into a dispenser further comprising a fluid reservoir in fluid communication with the pump inlet port.
  • the reservoir is co-moulded with the pump.
  • the resilient actuator of the pumps preferably has a threshold force for actuation which facilitates consistent unit dosing.
  • the pumps, valving arrangements, dispensers and actuators herein are amenable to a modular approach to construction which provides substantial flexibility in a mass manufacturing environment.
  • the pumps and dispensers comprise upper and lower halves.
  • the terms "half” and “halves” herein are intended only to indicate corresponding parts and are not intended to imply any equality in size, construction or function.
  • the terms “upper” and “lower” in respect of the pump or dispenser are used only to distinguish the two halves and are not intended to imply any particular orientation of the parts in use.
  • a “semirigid” refers to a material having a flexural modulus of at least about 300, preferably at least about 500 MPa, measured using ASTM D790.
  • Pump and dispenser parts herein made from a semirigid material are generally moulded with sufficient wall thicknesses that they are self-supporting, by which is meant that they will not substantially bend under their own weight.
  • certain embodiments of reservoirs herein, such as flexible sachets are non-self supporting structures through being made of thin laminates, even though the laminates may comprise semirigid materials.
  • unitary moulding is meant a moulding formed in a single piece or completely formed within a single mould. It may comprise only one material but the term “unitary moulding” also comprises workpieces formed from two or more materials in a common moulding operation such as a two-shot injection moulding where different materials are co-injected or sequentially injected into a common mould.
  • a "fluid” herein refers to a flowable liquid or gel.
  • “Monostable” as used herein in respect of an actuator or an element thereof means having a force-deflection curve including a priming region wherein the force initially increases for increasing deflection, in the manner of, say, a conventional spring, and then at some threshold force there is at least one inflection point such that further deflection of the element occurs with a reduction in the applied force. Such a curve is shown in Figure 26.
  • Bi-stable in respect of an actuator or an element thereof, refers to an actuator or an element thereof that behaves like a monostable actuator or element until the defined force threshhold is overcome but then "flips" to stay permanently in a depressed position.
  • the pumps according to the invention comprise a dose chamber.
  • the dose chamber is formed by the co-operation of the upper and lower pump halves when the pump is assembled.
  • the dose chamber holds a single dose of the fluid to be dispensed which, in preferred embodiments, can be replenished from a reservoir in fluid communication with the dose chamber.
  • the dose chamber is in fluid communication with a pump inlet port, through which fluid can be received from the reservoir, and a pump outlet port from which fluid can be dispensed.
  • the pump inlet and outlet ports are at opposite sides of the dose chamber and for many applications this will be the most appropriate geometry however the invention is not so limited.
  • the inlet and outlet ports can be adjacent to each other or placed in any other position relative to each other and the dose chamber provided they perform their intended function of permitting fluid flow into and out of the pump. Fluid flow into and out of the dose chamber is controlled by inlet and outlet valves described in more detail below.
  • the pumps further comprise a resilient actuator, also described further below whose actuation results in the dispensing of a dose of fluid from the dose chamber.
  • the volume of the dose dispensed by the pump will generally be less than the pump volume since actuation of the pump via the resilient actuator will generally not result in all of the fluid contained within the pump being dispensed.
  • Dose volumes herein may vary from a few microlitres to several millilitres depending upon the pump dimensions and construction.
  • the dose volume is preferably a metered dose substantially pre-determined by the dimensions of the dose chamber. Means for achieving this, comprising restricting a user's ability to modify the dose volume are described further below in the section on resilient actuators.
  • the dose chamber may require priming with the fluid to be dispensed.
  • the preferred number of priming strokes is three or fewer.
  • the dose chamber has a lower wall which creates an endpoint for the deflection of the resilient actuator and stops its movement when the actuator abuts it.
  • Changing the distance between the actuator in its resting position and the lower dose chamber wall can provide a method for fine adjustment of the dose volume of the pump, thereby at least partially defining a metered dose. This is advantageous in a commercial production environment when different dose volumes need to be produced in a cost effective way.
  • the dose volume can also be adjusted by changing other parameters such as the actuator shape and size.
  • the actuator is preferably resilient. It can be a separately manufactured piece fitted to the upper pump half but is preferably an integral, resilient wall section of the upper pump half bounding the dose chamber. Resilience is provided by selection of the material from which the actuator is made and by control over its thickness and shape. Suitable materials for the actuator are thermoplastic elastomers, silicones, rubbers or soft grades of polyolefins (e.g. polyethylene or polypropylene). A suitable thickness for the actuator is from about 0.1 to 0.8 mm, preferably from about 0.3 to 0.7 mm, more preferably from about 0.4 to 0.6 mm.
  • the actuator is depressed by a user in order to decrease the volume of the dose chamber and thus dispense a dose of fluid from the pump.
  • a resilient actuator when the depressing force is removed, its resilience causes the actuator to spring back to its original shape causing a pressure reduction in the dose chamber to draw fluid into the dose chamber from a reservoir.
  • the design of the actuator influences the dose size and accuracy of the overall system. For many applications the precise requirement for the delivered dose is not so critical and dose tolerances of +/- 20% are acceptable. Simple resilient actuators in form of buttons are well known in the art.
  • the actuator can be integrally moulded with the upper pump half (in a manner similar to the gas bellows shown in US patent application 2002/074359), co-moulded, overmoulded, or moulded separately and assembled via a mechanical snap or friction fit, such as in the pump of WO 98/08661, or attached via a welding operation.
  • Simple actuators can have the disadvantage that the user can choose the force applied whilst dispensing a fluid, which can lead to a big variation in dose quantity and quality.
  • the relationship between the applied force and the degree of deflection of the actuator may approximate to linear, or at least require continuously increasing force for ever greater deflections. If a user only presses gently then the dispensed volume and pressure of the fluid may be suboptimal, resulting, for example, in incomplete or variable dosing, an undesirable spray pattern or poor particle size distribution. Although this may be acceptable for certain applications or products, applications in the area of medical devices typically require more rigorous dose tolerances, especially when delivering active pharmaceutical ingredients.
  • the actuator herein preferably includes monostable or bi-stable elements. These elements are characterised in that they do not have a linear force-deflection relationship. The use of monostable or bi-stable elements in an actuator for a delivery system provides added control to a user's operation of the device.
  • buttons or snap-domes are known in the electronics industry in form of input devices (keypads for mobile phones, calculators, etc) and circuit board switches. Snaptron Inc. of Loveland, Colorado 80537, USA distributes metal snap domes in various sizes and geometries. Monostable elements, in the form of "snap-domes" are known, for example, in switches from e.g., US patent nos. 4,933,522; and 5,510,584. The principle has also been disclosed for use in a sample type spray dispenser in US 6,460,781. WO 02/016796, assigned to Valois SA, describes a two-leaved spring which acts a monostable element and can be used inside a dispensing reservoir.
  • the typical force-deflection curve is like that shown in Figure 26.
  • Initial deflection requires a continuously increasing force. If only a low force is applied by a user's finger to an actuator fitted to a pump primed with fluid, there will typically be no delivery of fluid at all since the force applied generates insufficient pressure in the fluid to open the outlet valve of the pump.
  • the actuator has a threshold point though at which further deflection of the element occurs with a reduction in the applied force, this threshold point should be a little greater than that required to create sufficient fluid pressure to open the outlet valve. The practical effect of this is that the momentum of the user's finger depression results in a rapidly increasing deflection making it difficult to prevent full actuation once the pre-defined threshold point has been passed.
  • This process of passing the threshold point is preferably accompanied by an audible 'click' or tactile feedback to signal correct operation of the element to the user.
  • the deflection D axis graduated in mm
  • the deflection D increases by at least 50% even though the force F (axis graduated in Newtons) is reduced by at least 10%, more preferably the deflection increases by at least 75% even though the force is reduced by at least 25%.
  • the slope of the curve from the origin to the first threshold point is at least 5 Nmm -1 , more preferably at least 10 Nmm -1 .
  • an actuator for use with a dispensing pump, the actuator comprising a shaped, preferably disc-like, plate comprising an outer flange lying in a first plane and a central resiliently deflectable dome, the dome comprising an apex and at least one annular trough whereby, when the actuator is fixed at its outer flange, the actuator has, for forces applied perpendicularly to the first plane, a force-deflection curve that includes a priming region wherein the force initially increases for increasing deflection of the dome, and at least one inflection point such that further deflection of the dome occurs with a reduction in the applied force.
  • the applied force required to achieve further deflection increases again, usually as some material limit of the actuator is reached.
  • a predefined endpoint for the deflection may also be achieved due to the actuator abutting some stopping element, in which case of course the applied force will increase very rapidly for slight or no further deflection.
  • the deflection endpoint may be defined by the physical dimensions of the actuator or a further stop element can be introduced, such as the lower dose chamber wall.
  • a reservoir containing a fluid to be dispensed comprising boundary walls and a fluid outlet, wherein the boundary walls of the reservoir comprise a plurality of bi-stable actuators such that each depression of a bi-stable actuator results in a substantially identical dose of fluid being dispensed from the fluid outlet.
  • a preferred bi-stable actuator will present a convex dome to the exterior of the reservoir and, when depressed past its threshold, will permanently deform to present a concave depression to the exterior of the reservoir.
  • the preferred embodiment of this further aspect of the invention comprises a reservoir having a plurality of externally convex deformable bi-stable actuators arranged in a regular array on one face of the reservoir, to give the appearance of a blister pack.
  • the inlet valve is associated with the pump inlet port for controlling fluid flow through the inlet port and the outlet valve is associated with the pump outlet port for controlling fluid flow through the inlet port.
  • each valve is located in the respective port or in a flow channel directly connected to the port. If not located in the port then the valve can be upstream or downstream of the port provided it is able to perform its intended function of controlling fluid flow through the port.
  • both the inlet and outlet valves are of the non-return type, allowing movement of fluid in one direction along a conduit or flow channel but preventing the flow of fluid in the reverse direction.
  • Suitable valves include flap valves, duckbill valves and slit valves. Flap valves are preferred for ease of in-situ moulding.
  • the inlet and outlet valves are made from an elastomeric material having a Shore A hardness of from about 5 to about 90, more preferably from about 20 to about 70. Suitable elastomeric materials include thermoplastic elastomers and silicone rubbers.
  • the flap and slit valves can be various shapes such as rectangular or triangular or more complex shapes as described in more detail below.
  • the valves can be co-injected, overmoulded, insert moulded as an extra part or separately assembled such as by welding or snap fitting.
  • the inlet and outlet valves are integrally moulded with either the upper or lower pump half from the same semirigid, thermoplastic material as the pump half with which they are integrally moulded.
  • a preferred valve arrangement comprises an elastomeric valve mounted inside a flow channel, the valve comprising an upper surface, the upper surface being immovably fixed, preferably by injection moulding, to an upper flow channel wall, the valve further comprising a flap having a lower surface which is sealingly compressed against a lower flow channel wall in the absence of a differential in fluid pressure across the valve flap, wherein an increase in fluid pressure on against the lower surface of the flap lifts the flap from the lower flow channel wall and permits fluid to flow past the valve.
  • the one of the upper or lower pump halves comprises the upper flow channel wall of the valve arrangement and the other of the upper or lower pump halves comprises the lower flow channel wall against which the lower surface of the valve flap is sealingly compressed.
  • the lower surface of the valve flap is generally coplanar with the lower flow channel wall and the valve flap is oriented in the direction of fluid flow along the flow channel. If back pressure in the fluid should urge it to flow in the reverse direction, the fluid presses against an upper surface of the valve flap, sealingly compressing the flap against the lower flow channel wall and thereby preventing reverse fluid flow.
  • a desired threshold pressure for valve actuation can be set. Only when the pressure differential across the valve exceeds the threshold pressure is the valve opened.
  • a normally closed valve system is beneficial, as it ensures that the pump only has to be primed once and it reduces the risk of contamination from outside.
  • the threshold pressure for the valve is such that the outlet valve opens when the force applied to the resilient actuator is in the range from about 70% to about 100%, preferably from about 90% to about 100%, of the threshold actuation force for the resilient actuator.
  • the flow channel is restricted at the point where fluid flowing along it would first encounter the valve and the valve comprises a foot portion which is permanently compressed against the lower flow channel wall such that the only fluid passage past it is along a groove in the lower flow channel wall, the groove being flanked by side walls.
  • the groove is bridged by a sealing ridge rising to the height of the side walls and the valve flap sits across the sealing ridge and the side walls preventing fluid flow until the fluid pressure rises sufficiently to lift the valve flap away from the sealing ridge and the adjacent side walls.
  • More particularly two such valve arrangements are preferably used in tandem with the valves in each arrangement being separated from each other and a dose chamber being arranged on a fluid flow path intermediate the two valves such that the valves act as inlet and outlet valves for the dose chamber.
  • the pump herein without its resilient actuator can be used as a valve module and is useful in its own right since it can be combined with differently sized or shaped actuators to provide pumps with different characteristics, such as different dose volumes.
  • the pumps and valving modules herein can of course be designed so that the valves are fixed to either the upper or lower pump halves.
  • the pump or dispenser includes an atomiser associated with an outlet flow channel to break up dispensed fluid into a spray.
  • the outlet flow channel can be formed from upper and lower outlet flow channel halves which are preferably integrally moulded with the upper and lower pump halves.
  • US 6,059,150 illustrates a typical atomiser for a nasal spray application using a hollow nozzle adaptor which includes a spray orifice incorporating a swirl chamber geometry.
  • atomisers are known wherein a cup shaped component, including a spray orifice and swirl chamber geometry, is separately assembled to a nozzle adaptor, an example of such a component is the nozzle cap disclosed in US 5,738,282.
  • a plain dispensing orifice is sufficient for highly viscous fluids that cannot be broken up into small particles to form a spray.
  • the orifice can be formed entirely within either of the upper or lower outlet flow channel halves or from a combination of part mouldings in both halves. Where a circular orifice is required then this can be done by moulding a semicircular channel in each of the upper or lower outlet flow channel halves. Due to the small dimensions and tolerances it can be difficult to exactly match the edges of top and bottom half. In order to eliminate this particular issue the orifice can be formed with one side being flat, therefore small variations in assembly positioning will not matter. This principle is illustrated in WO 01/32317.
  • a dispensing orifice can also be formed entirely within either of the upper and lower outlet flow channel halves.
  • the dispensing orifice can also comprise a movable plug to seal the orifice when it is not in use. This can help avoid clogging of the orifice and also provides better protection from contaminants for fluid remaining in the dispenser.
  • WO 03/078073 discloses an arrangement whereby a plugging element is movable between a sealing and non-sealing position upon operation of the device without other intervention by the user.
  • the purpose of the pump is to enable dispensing of a fluid from a fluid source or reservoir.
  • the fluid can be any that is compatible with components of the pump and that is not too viscous to be pumped including, without limitation, cosmetic products such as perfumes and lotions; medicines; veterinary products, liquid foods or sauces and other household products such as cleaning fluids.
  • the pump can be permanently or detachably connected to a reservoir and, optionally, an atomising nozzle or applicator, to form a complete dispenser and/or it can form part of a more complex product comprising other parts such as a housing and a handle.
  • An atomising nozzle is preferred for certain medicinal applications, such as nasal or throat treatment.
  • An applicator suitable for spreading the fluid onto a substrate may be preferred for other treatments.
  • Useful applicators comprise spreading means selected from brush heads, elastomeric wiping blades and disposable cloths.
  • the pump can be directly connected to a reservoir or connection can be made, for example by means of intermediate tubing if it is desirable for the pump and reservoir to be remote from each other. Provision for permanent attachment to a reservoir can be made, for example by co-moulding a weld spout with the pump inlet port so that the pump can be sealed in a fluid tight manner to a flexible sachet.
  • the pumps provided herein can be manufactured at low cost and are economically suited to applications where a pump is provided with each reservoir.
  • the reservoir and pump are preferably permanently connected via a heat-sealing, welding, in-mould or snap fit operation.
  • the pump is associated with a more complex device, where it can be beneficial for the reservoir to be detachably connected to the pump such that replacement reservoirs can be fitted to the same pump.
  • a detachable connection avoids throwing away the pump if the reservoir must be replaced, it introduces further complexity in order to provide a reliable, fluid tight, re-usable connection.
  • suitable fitments for this purpose are known in the art. Exemplary fitments are disclosed in WO 99/05446, WO 00/66448 and WO 03/095322.
  • the reservoir itself can be semirigid or flexible. If it is semirigid then it may be necessary to provide means for venting the reservoir, for example by means of a one-way valve allowing air ingress, in order to avoid the development of a vacuum in the reservoir which could inhibit further dispensing or cause suck-back past the pump outlet valve requiring the pump to be reprimed.
  • the venting means can also comprise a narrow mesh biofilter that filters out bacteria, spores and the like from the in-drawn air, thus enabling the fluid in the reservoir to be preservative free.
  • a biofilter capable of maintaining a sterile filtration barrier can be made from GORE-TEX® expanded PTFE laminate, available from W. L. Gore & Associates, Inc.
  • a dispenser herein the pump is combined with a reservoir in the form of a flexible sachet containing a fluid, the sachet collapsing as fluid is withdrawn from it by the pump.
  • a reservoir made of a flexible laminate offers the benefit of improved barrier properties.
  • Flexible reservoirs are preferably charged with fluid via an airless filling operation so that the charged reservoir contains no air.
  • the reservoir can be built around the pump so that the pump is internal to, or contained within, the reservoir, by which is meant that walls of the reservoir substantially enclose the pump even though parts of the pump, such as, in particular its actuator and a lower pump surface opposed to the actuator may be contiguous with upper and lower outside walls of the reservoir.
  • Preferred embodiments herein include a dispenser comprising a reservoir with an integral pump contained within the reservoir.
  • the pump can be contained within a flexible sachet so that the actuator of the pump can be actuated by pressing against that portion of the sachet wall which overlies the actuator, as shown for example in the device of WO 02/16047.
  • the pump upper and lower halves are integrally moulded with upper and lower halves of the reservoir.
  • the reservoir is semirigid or flexible it may be preferable to include a dip tube inside the reservoir to assist the removal of all of the fluid in the reservoir in certain orientations.
  • a dip tube will generally be used when the reservoir is semirigid and can also be useful in a flexible sachet.
  • the method of construction of pumps, reservoirs and dispensers herein, from upper and lower moulded halves, can also be applied to the construction of dispensing devices and reservoirs with dip tubes, even if a pump is not incorporated.
  • a dispensing device comprising upper and lower halves, the upper and lower halves co-operating to form a fluid reservoir and a dispensing outlet at a first end of the reservoir characterized in that the upper and lower halves each comprise sections of an integrally moulded channel, the sections co-operating to form a dip tube, or flow channel, in fluid communication with the dispensing outlet and terminating at an inlet end close to a second end of the reservoir remote from the first.
  • the dip tube preferably has a length from the dispensing outlet end to its inlet end of at least 90%, preferably at least 95% of the length of the reservoir.
  • this dispensing device at least one of its upper and lower halves comprises a resiliently deformable region enabling fluid to be pumped from the reservoir through the dispensing outlet.
  • This resiliently deformable region may comprise a substantial proportion, say at least 30%, more preferably at least 50%, of the external area of the pump half comprising it.
  • the deformable region may be relatively small and be in the form of a resilient actuator as herein described, preferably comprising a monostable element.
  • a further mechanism for dispensing fluid from the device comprises providing a plurality of bi-stable actuators, as described further above, such that compression of each actuator delivers a unit dose of the fluid.
  • this dispensing device can also comprise an atomising nozzle in fluid communication with the dispensing outlet and, if necessary an outlet valve and a vent valve.
  • the pumps, dispensers, valves, valve modules and actuators herein can be made by low cost making moulding techniques such as injection moulding, compression moulding and thermoforming. Injection moulding is preferred.
  • at least one of the upper and lower pump halves to be compression moulded or thermoformed, and the present invention comprises pumps with compression moulded or thermoformed upper and/or lower pump halves comprising valves as herein described.
  • Assembly of the component parts assembly can be by snap or friction fit or by welding. Further sealing, where necessary, can be provided by additional injection moulded seals or by other techniques known in the art, such as ultrasonic sealing.
  • each of the upper and lower pump or dispenser halves is formed in one single shot injection moulding operation from a suitable, semirigid thermoplastic resin material.
  • suitable resins include thermoplastics having a flexural modulus of at least 300, preferably at least 500 MPa, preferably at least 1000 MPa, measured using ASTM D790 and include polypropylene, polyethylene, polyethylene terephthalate (PET), polyesters, polycarbonates, polyamides, polystyrenes and blends thereof.
  • Preferred materials include polypropylene, polyethylene and polyethylene terephthalate, most preferred is polypropylene.
  • flap valves can be integrally moulded with the upper or lower pump half in a single shot injection moulding process. Alternately, the valves can be co-moulded from a softer material in a two-shot injection moulding.
  • an upper pump half may be substantially composed of a semirigid material with its resilient actuator being formed from a thermoplastic elastomer in a two shot injection moulding operation.
  • the inlet and outlet valves can be and preferably are formed from a second resin material co-moulded with either of the upper and lower pump halves in a two-shot injection moulding operation. Conveniently this can be done within the same mould or tool as that employed for the first step.
  • the second resin material is preferably an elastomeric material having a Shore A hardness, measured using ASTM D2240, of from 5 to 90, preferably from 20 to 70.
  • a sealing element can be formed by injecting an additional resin, bonding the sealing element to the upper and lower halves, thus holding them together and creating a fluid tight seal.
  • An alternative option for sealing the upper and lower half together is the use of a welding operation, such as by high frequency sealing.
  • a third option for assembly of upper and lower halves is to integrate a snap feature into one or both halves which enables the upper and lower halves to maintain the assembled position once brought together. In this case it may be necessary to use an O-ring or gasket to provide adequate sealing.
  • the resilient actuator has not been integrally moulded with the pump upper half then it can be made in a separate operation and assembled to form the completed pump via e.g., an in-mould sealing operation.
  • Figures 1 to 11 show a first embodiment of a pump according to the invention and its mode of operation.
  • Figure 1 shows the assembled pump 101 in perspective view.
  • Pump 1 comprises an extended nozzle and a connector 125 in the form of a weld spout by which the pump can be connected to a fluid reservoir (not shown).
  • the pump comprises an upper pump half 102 and a lower pump half 103 sealed together via a joining element 104.
  • Figures 2 and 3 respectively show the lower and upper pump halves in more detail.
  • the connector 125 is not shown in these figures.
  • the upper and lower pump halves co-operate to form a dose chamber 114, an inlet flow channel 116 and outlet flow channel 117, the dose chamber and flow channels being in fluid communication with each other and the reservoir.
  • the joining element 104 is added by a moulding shot and seals the upper half and the lower half of the pump together, securing both parts against further movement and creating a fluid tight path for the fluid as it passes through the pump.
  • the upper and lower pump halves can be fitted directly together by snap fit, welding or gluing operations.
  • lower pump half 103 has a geometry corresponding to that of the upper pump half 102 which comprises opposed sealing ridges 129 for receiving the lower pump half 103.
  • Sealing ridges 129 comprise upper inlet port walls 115a, upper dose chamber walls 130 and upper outlet port walls 115b.
  • Lower inlet port walls 110a are received inside upper inlet port walls 115a to define inlet flow channel 116 and pump inlet port 112.
  • An inlet sealing ridge 108 bridges the lower inlet port walls.
  • Lower dose chamber wall 122 is received inside upper dose chamber walls 130 to bound a dose chamber 114 which is closed by resilient actuator 105.
  • the lower dose chamber wall in this embodiment is a substantially solid block, divided by a flow channel, extending across the width of the dose chamber. This enables it to limit the travel of resilient actuator 105 and thereby help define the dose volume. It also has the effect of reducing the pump volume so that fewer priming strokes are needed.
  • Lower outlet port walls 110b on the lower pump half are received inside upper outlet port walls 115b on the upper pump half to define pump outlet port 113.
  • An outlet sealing ridge 109 bridges the lower outlet port walls.
  • Outlet flow channel walls 111 on lower pump half 103 are received inside upper pump half sealing ridges 129 to form outlet flow channel 117 leading from pump outlet port 113 to exit orifice 118.
  • Outlet flow channel 117 is further bounded by the outlet flow channel upper wall 121 on upper pump half 102.
  • Outlet flow channel walls 111 converge at one end of flow channel 117 to form exit orifice 118 in conjunction with outlet flow channel upper wall 121, as shown more clearly in Figures 7 and 8.
  • Inlet and outlet positioning lugs 123 and 124 are provided on upper pump half 102 and are received in corresponding recesses in an outer rim of the dose chamber wall 122 to assist in positioning and sealing during pump assembly.
  • Upper pump half 102 is shown fitted with inlet and outlet flap valves 106 and 107, shown separately in Figure 6.
  • the valves are co-moulded onto upper pump half 102 either in the same moulding operation or in a separate moulding operation ("over moulding").
  • the valves can be moulded independently and assembled to the upper pump half by e.g., friction fit and/or by thermal sealing or gluing.
  • the inlet valve prevents backflow of a fluid from the dose chamber 114 into the reservoir.
  • the flap of outlet valve 107 co-operates with outlet sealing ridge 109 and lower outlet port walls 110b to form a non return outlet valve at pump outlet port 113.
  • the outlet valve prevents backflow of fluid from outlet flow channel 117 into the dose chamber.
  • the outlet valve can also prevent contamination of fluid in the dose chamber from the air or other potential external contaminant sources. Moving outlet valve 107 and corresponding outlet sealing ridge 109 closer to the exit orifice 118 of the pump can help prevent drying out of the fluid in the outlet flow channel and avoid potential clogging of certain products, as well as helping to avoid contamination. This will have the effect, however, of increasing the pump volume.
  • the upper pump half comprises resilient actuator 105 which is a thin wall section of the upper pump half where it bounds dose chamber 114.
  • Figure 5 shows more clearly, by cross-sections, the formation of dose chamber 114 between resilient actuator 105 and lower dose chamber wall 122.
  • Joining element 104 helps seal the upper and lower pump halves together.
  • Pressure by a user's finger on actuator 105 reduces the volume of dose chamber 114, forcing fluid to exit the dose chamber through the pump outlet port 113 and along outlet flow channel 117 towards exit orifice 118.
  • the actuator can be made from a different material to that of the upper pump half which can be co-injected in the same process step as when the valves are formed. It will be appreciated that the actuator can also be formed by a combination of materials when this is of advantage for the specific application.
  • FIG. 9 shows the situation as a user initially applies a force F 1 to resilient actuator 105.
  • the pump is primed and dose chamber 114 contains a dose of fluid to be dispensed.
  • the actuator has not appreciably deformed and inlet and outlet valves 106 and 107 are still in their normal mode of being compressed against inlet and outlet sealing ridges 108 and 109 so that the pump inlet and outlet ports, 112 and 113, are closed.
  • the actuator deforms rapidly, significantly decreasing the volume inside the dose chamber 114 and increasing the pressure of its contained fluid.
  • the increase in pressure has the effect of applying further pressure to the upper surface of inlet valve 106 thereby keep inlet port 112 closed.
  • pressure on the underside of the flap of outlet valve 107 is increased, causing it to lift, opening pump outlet port 113 and thereby allowing fluid to flow out of the dose chamber, along outlet flow channel 117 and ultimately to be dispensed through exit orifice 118, as shown by the arrows.
  • Figure 11 shows the situation after the dose of fluid has been dispensed and the user removes the force applied to the actuator.
  • the resilience of the actuator now causes it to return to its starting position with force F 3 .
  • the effect of this is to increase the volume inside the dose chamber 114, reducing its internal pressure.
  • the reduction in pressure results in outlet valve 107 closing once more through its natural resilience combined with atmospheric pressure on the upper surface of its flap.
  • the pressure on the flap of inlet valve 106 is reduced so that fluid pressure from the reservoir lifts it away from the sealing ridge 108 thereby opening pump inlet port 112 and allowing the dose chamber to be recharged from the reservoir. It will be understood that for this process to work efficiently either the reservoir needs to be collapsible or it needs to be vented.
  • Figures 12 and 13 show cross sectional views of an atomising outlet 119 which can be moulded in two halves and integrally moulded into the design of the nozzle of the first embodiment according to the invention.
  • a swirl chamber geometry has been integrated into the upper and lower halves around exit orifice 118, without need for side action on the moulding tool. This geometry will be coupled to a baffle (not shown) also moulded into each of the upper and lower halves of the nozzle to force fluid to exit through the swirl chamber.
  • Figures 14 to 16 show a second embodiment according to the invention which is a dispenser 250 comprising a pump having essentially the same construction as that of Figure 1 but with modifications to the nozzle.
  • a flexible laminate reservoir 220 is bonded to the weld spout connector 225.
  • a sleeve 260 which can be made of, say, folding boxboard or plastic, encloses the reservoir.
  • a hole in the sleeve provides access to resilient actuator 205. If the sleeve is flexible then it can of course be provided without a hole and the actuator can be depressed through the sleeve. In this case indicia can be provided on the sleeve to indicate where the user needs to press.
  • nozzle 266 The modifications to the nozzle 266 include the provision of a shoulder 265 which provides support to sleeve 260 and cap 255 which is provided to cover the nozzle and keep it clean.
  • Shoulder 265 can be integrally moulded in two halves with the pump and nozzle or alternatively, as here, it can be a separate part assembled by a clip or friction fit.
  • FIG. 17 to 20 A very different solution for a dispenser according to the invention is shown in Figures 17 to 20 which represent a third embodiment of the invention.
  • the whole dispenser 350 including reservoir 320, is integrally moulded with pump 301 in two halves.
  • the advantage of following this approach is that an entire multiple controlled-dose dispenser can be obtained with a minimum of parts and moulding / assembly operations.
  • this solution provides a more compact dispenser for the same amount of contained fluid as it utilises the otherwise unused space by building the reservoir around the pump so that the pump is internal to the reservoir.
  • the need for the reservoir to be moulded imposes some restrictions on the materials that can be used for the reservoir, for example laminates will generally be unsuitable, but this may not be critical for many applications.
  • This design also requires a process for sealing two areas: a first, inner, seal which isolates the pump components, including outlet flow channel 317, from the reservoir 320 and a second, outer, seal at the outer perimeter which seals the reservoir 320 from the outside air.
  • the inner seal can no longer be created via an injection moulded joining element as in the pump of Figure 1.
  • the seal is instead created by a snap fit, welding or gluing process when upper pump / dispenser half 302 is assembled to lower half 303.
  • the outer seal can be formed using other processes such as the afore-mentioned joining element or by using in-mould sealing.
  • the dispenser further comprises an atomiser 319 to generate a spray from dispensed fluid as the fluid exits outlet flow channel 317.
  • Inlet flow channel 316 is open to the reservoir 320 at a point close to an end of the dispenser disposed opposite to the atomiser 319, providing an inlet point whereby fluid can be drawn from the reservoir into the flow channel. Having the inlet point close to the end of the dispenser ensure that, in normal use, most of the fluid can be dispensed from the reservoir.
  • the inlet and outlet flow channels and the pump 301 form a continuous reservoir flow path, acting like a dip tube, having an outlet end through which fluid is dispensed from the dispenser and an inlet end through which fluid is drawn from the reservoir, the flow path being isolated from the reservoir along its length except at its inlet end.
  • the reservoir flow path preferably has a length from its outlet end to its inlet end of at least 90%, preferably at least 95% of the length of the dispenser.
  • Reservoir 320 is in the form of compartments symmetrically disposed about pump 301 and inlet and outlet flow channels 316 and 317.
  • the inlet and outlet valves are not shown in the Figures but operate in the same way as already described in relation to Figures 9 to 11 such that, after a dose of fluid has been dispensed from dose chamber 314, fluid is drawn from the reservoir via inlet flow channel 316 to recharge the dose chamber. Though it is not shown in the Figures it is highly preferred that the reservoir is also fitted with a vent valve to keep the reservoir at atmospheric pressure.
  • the reservoir is filled with fluid via fill port 381 after the assembly of the upper and lower halves 302 and 303, the port then being sealed with fill port plug 380.
  • dispenser 350 can be various shapes and thicknesses and sized to suit the particular application. It can also be moulded with a shoulder for receiving a protective cap.
  • the dispenser has a length of from about 20 to about 100 mm, more preferably from about 40 to about 70 mm, a width of from about 15 to about 80 mm, more preferably from about 20 to about 55 mm and a depth of from about 5 to about 10 mm.
  • the reservoir preferably has a volume of from about 0.5 to about 40 mls. Of course for other applications much larger reservoirs may be appropriate.
  • dispenser 350 can incorporate an integrally moulded actuator as part of the upper half 302, as described in the first embodiment, Figures 21 to 23 show in more detail a composite resilient actuator 305 used in the third embodiment.
  • the actuator comprises a separate monostable button 340 covered on top and bottom surfaces by a soft, elastomeric material to form the resilient actuator.
  • the separate monostable element can be made of various materials, in this embodiment it is a commercially available metal snap dome from Snaptron Inc.
  • the actuator is insert-moulded into upper pump half 302 where it is located and fixed by means of positioning lugs 341.
  • Figure 24 shows a fourth embodiment of the invention comprising a dispenser 450 of similar construction to that shown in Figures 17 to 20, including reservoir 420 moulded around an integral pump, the whole being in two halves.
  • Reservoir 420 comprises fill port plug 480 sealing a fill port through which the reservoir can be charged with fluid during manufacture.
  • outlet flow channel 417 in fluid communication with dose chamber 414, runs as far as a cylindrical projection on upper half 402, the projection mating with a corresponding recess formed in a boss in lower half 403, the recess being open to the outside by exit orifice 418.
  • cylindrical projection and exit orifice 418 are shown as passing perpendicularly through lower half 403 they can of course be formed at an oblique angle to it so that, for example, the dispensed fluid emerges at an angle to the plane of the reservoir.
  • the resilient actuator 405 of this embodiment is a thermoformed, polypropylene disc insert-moulded to a corresponding recess on upper half 402.
  • the actuator is shown in section in Figure 25 to give a better appreciation of its shape. It includes a central dome 487, a flange 486 for securing the actuator to a pump and an annular trough 485.
  • the function of the annular trough is to allow the central dome to distort sufficiently to invert without its distortion being inhibited by the flange which will be held fixed.
  • the actuator can also be provided, as in the first embodiment, as an integrally moulded thin wall section of upper half 402.
  • FIG 27 shows a sectional view of a dispenser 550 which is a fifth embodiment according to the invention.
  • This construction of the dispenser affords some advantages in construction and assembly at the expense of an additional part since the dispenser now requires a minimum of three parts.
  • the upper pump half 502 shown separately from above and below in Figures 28 and 29, which comprises the lower dose chamber wall 522.
  • the pump inlet port 512 At the centre of the lower dose chamber wall is the pump inlet port 512 which provides fluid communication between the dose chamber and the inlet flow channel.
  • the resilient actuator 505 is formed as a separate injection moulded piece with two integrally formed strips extending from it, as illustrated in Figure 31.
  • Upper pump half 502 further comprises a recessed portion corresponding in outline shape to the actuator and strip moulding.
  • This recessed portion comprises substantial portions of the lower part of inlet flow channel 516 and outlet flow channel 517 as grooves running longitudinally along the centre of the recessed portion.
  • the outlet flow channel upper wall 521 and an upper portion of the inlet flow channel 516 are provided by the actuator and strip moulding.
  • a reservoir port 526 at one end of the inlet flow channel 516 provides fluid communication between the inlet flow channel and the reservoir 520.
  • inlet valve 506 and outlet valve 507 are pre-formed duckbill valves located in recesses of upper pump half 502, the recesses having holes at the bottom for fluid communication with lower pump half 503. One of these holes serves as pump outlet port 513.
  • Suitable duckbill valves include the DU 027.001 SD valve available from Minivalve International of Jaartsveldstraat 5a, 7575 BP Oldenzaal, The Netherlands. Alternate valves such as slit valves can be co-moulded with upper half 502, lower half 503 or indeed the strip integrally formed with the actuator.
  • lower pump and dispenser half 503 is a simple moulding comprising lower inlet port wall 510a at one end of a dumbbell shaped wall defining a portion of inlet flow channel 516.
  • a further dumbbell shaped wall provides lower outlet port wall 510b which is continuous with outlet flow channel side wall 511, the latter defining a short portion of outlet flow channel 517.
  • a raised lip running around the periphery of the lower pump and dispenser half fits snugly inside an outer side wall of upper pump and dispenser half 502.
  • the two dumbbell shaped walls receive, in their interior spaces, correspondingly shaped projections, shown in Figure 29, on the upper pump and dispenser half 502.
  • the projections include the upper inlet port wall 515a and upper outlet port wall 515b.
  • the strip incorporating the actuator has on its underside two C-shaped projections which locate inside the recesses of upper pump half 502, securing the duckbill valves in place.
  • a portion of the strip comprises an outlet flow channel upper wall 521 which covers the outlet flow channel 517 on its upper side.
  • a portion of the strip on the opposite side of the actuator covers the inlet flow channel 516 on its upper side.
  • the reservoir of this embodiment like that of the dispenser of the fourth embodiment can further comprise a vent valve such that the pressure inside the reservoir is maintained at atmospheric pressure.
  • a microfilter in the vent valve can substantially prevent outside contamination of fluid in the reservoir.
  • a sixth embodiment of the invention is a valve module as illustrated in Figures 32 to 35.
  • the valve module can be manufactured as a separate item for assembly to variously shaped pump or dispenser constructions, thus providing greater manufacturing flexibility.
  • the valve module comprises upper and lower halves 602 and 603.
  • Lower half 603 comprises a flat injection moulded strip having a central groove which forms the basis for inlet and outlet ports 612 and 613.
  • the groove is interrupted by inlet and outlet sealing ridges 608 and 609 against which the flaps of inlet and outlet valves 606 and 607 are compressed, preventing the flow of fluid along the groove until sufficient pressure is exerted by the fluid to lift the valve flaps (during dispensing in the case of outlet valve 607 or during dose chamber recharging in the case of inlet valve 606).
  • An upper surface of the upper half 602 provides lower dose chamber wall 622. A channel passes through the centre of this to provide fluid communication between the dose chamber and the inlet and outlet ports.
  • the lower dose chamber wall is bounded by a raised annular boundary wall 631 for receiving an actuator or interacting with a dispenser, as shown in Figures 34 and 35 which illustrate the assembly of the valve module into a dispenser section (shown only in part), comprising a resilient actuator 605 to provide a completed pump 601.
  • the lower half 603 of the valve module is shaped with a substantially rectangular external wall section which provides a means for ensuring correct alignment of the valve module with other parts of a dispenser with which it is intended to fit.
  • Alternate alignment means which can be used include positioning lugs and indents. More than one type of alignment means can of course be used.
  • An important feature of this embodiment is that the valves are sandwiched between the upper and lower halves 602 and 603, thus enabling the provision of a compact valve module and provides substantial design flexibility.

Landscapes

  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Bag Frames (AREA)
  • Nozzles (AREA)
EP04253005A 2004-05-21 2004-05-21 Pump for fluid dispensers Withdrawn EP1598118A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
EP04253005A EP1598118A1 (en) 2004-05-21 2004-05-21 Pump for fluid dispensers
US11/134,986 US20050260090A1 (en) 2004-05-21 2005-05-23 Pumps for fluid dispensers
JP2007527547A JP4354508B2 (ja) 2004-05-21 2005-05-23 流体散布器用ポンプ
AU2005245497A AU2005245497A1 (en) 2004-05-21 2005-05-23 Pump for fluid dispensers
CA002565123A CA2565123A1 (en) 2004-05-21 2005-05-23 Pump for fluid dispensers
CNA2005800157897A CN1953819A (zh) 2004-05-21 2005-05-23 用于流体分配器的泵
BRPI0510138-7A BRPI0510138A (pt) 2004-05-21 2005-05-23 bombas para dispensadores de fluidos
PCT/US2005/018071 WO2005113158A1 (en) 2004-05-21 2005-05-23 Pump for fluid dispensers
MXPA06013447A MXPA06013447A (es) 2004-05-21 2005-05-23 Bomba para despachadores de liquidos.
EP05755106A EP1765512A1 (en) 2004-05-21 2005-05-23 Pump for fluid dispensers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP04253005A EP1598118A1 (en) 2004-05-21 2004-05-21 Pump for fluid dispensers

Publications (1)

Publication Number Publication Date
EP1598118A1 true EP1598118A1 (en) 2005-11-23

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EP04253005A Withdrawn EP1598118A1 (en) 2004-05-21 2004-05-21 Pump for fluid dispensers
EP05755106A Withdrawn EP1765512A1 (en) 2004-05-21 2005-05-23 Pump for fluid dispensers

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EP05755106A Withdrawn EP1765512A1 (en) 2004-05-21 2005-05-23 Pump for fluid dispensers

Country Status (9)

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US (1) US20050260090A1 (es)
EP (2) EP1598118A1 (es)
JP (1) JP4354508B2 (es)
CN (1) CN1953819A (es)
AU (1) AU2005245497A1 (es)
BR (1) BRPI0510138A (es)
CA (1) CA2565123A1 (es)
MX (1) MXPA06013447A (es)
WO (1) WO2005113158A1 (es)

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EP1779933A1 (en) * 2005-10-26 2007-05-02 The Procter and Gamble Company Dispenser for a liquid
DE102006027042A1 (de) * 2006-06-08 2007-12-13 Seaquist Perfect Dispensing Gmbh Abgabevorrichtung
DE102007025387A1 (de) 2007-05-30 2008-12-04 Braun Gmbh Nachfüllpack für ein Gerät des persönlichen Bedarfs
US8534500B2 (en) 2007-05-30 2013-09-17 Braun Gmbh Refill pack for a personal use device
EP2181771A1 (en) * 2008-10-30 2010-05-05 Gojo Industries, Inc. Dome pump spray assembly
CN101725512B (zh) * 2008-10-30 2014-07-30 高爽工业公司 圆顶泵喷雾组件
CN104368463A (zh) * 2014-11-25 2015-02-25 天津大学 一种能够增强射流混合效果的喷嘴
EP3135387A1 (fr) * 2015-08-28 2017-03-01 Albea Lacrost Pompe de distribution de produit cosmetique et dispositif de distribution comprenant une telle pompe
FR3040270A1 (fr) * 2015-08-28 2017-03-03 Albea Lacrost Pompe de distribution de produit cosmetique et dispositif de distribution comprenant une telle pompe

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JP4354508B2 (ja) 2009-10-28
CN1953819A (zh) 2007-04-25
CA2565123A1 (en) 2005-12-01
WO2005113158A1 (en) 2005-12-01
BRPI0510138A (pt) 2007-10-02
EP1765512A1 (en) 2007-03-28
JP2008500173A (ja) 2008-01-10
MXPA06013447A (es) 2007-01-23
AU2005245497A1 (en) 2005-12-01
US20050260090A1 (en) 2005-11-24

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