EP1546014B1 - Improved high-speed fiber feed assembly - Google Patents

Improved high-speed fiber feed assembly Download PDF

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Publication number
EP1546014B1
EP1546014B1 EP03764365A EP03764365A EP1546014B1 EP 1546014 B1 EP1546014 B1 EP 1546014B1 EP 03764365 A EP03764365 A EP 03764365A EP 03764365 A EP03764365 A EP 03764365A EP 1546014 B1 EP1546014 B1 EP 1546014B1
Authority
EP
European Patent Office
Prior art keywords
fibre
dampening
feed system
dampening bar
intake housing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03764365A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1546014A1 (en
Inventor
James R. Priest
Frederick R. Vees
Christopher S. Garrett
David V. Stotler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Neptco JV LLC
Original Assignee
Neptco JV LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neptco JV LLC filed Critical Neptco JV LLC
Priority to EP08014557A priority Critical patent/EP2019070A3/en
Publication of EP1546014A1 publication Critical patent/EP1546014A1/en
Application granted granted Critical
Publication of EP1546014B1 publication Critical patent/EP1546014B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • D06B3/06—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments individually handled
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H49/00—Unwinding or paying-out filamentary material; Supporting, storing or transporting packages from which filamentary material is to be withdrawn or paid-out
    • B65H49/02—Methods or apparatus in which packages do not rotate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H57/00—Guides for filamentary materials; Supports therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H57/00—Guides for filamentary materials; Supports therefor
    • B65H57/22—Guides for filamentary materials; Supports therefor adapted to prevent excessive ballooning of material
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J3/00—Modifying the surface
    • D02J3/02—Modifying the surface by abrading, scraping, scuffing, cutting, or nicking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2701/00—Handled material; Storage means
    • B65H2701/30—Handled filamentary material
    • B65H2701/31—Textiles threads or artificial strands of filaments
    • B65H2701/312—Fibreglass strands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H2701/00—Handled material; Storage means
    • B65H2701/30—Handled filamentary material
    • B65H2701/31—Textiles threads or artificial strands of filaments
    • B65H2701/313—Synthetic polymer threads

Definitions

  • This invention relates to an improved apparatus for the high-speed feeding of fiber materials from balls, doffs, cakes or other windings into one or more machines for further processing, and particularly for the high-speed feeding of continuous fibers of glass or synthetic materials.
  • a common practice during the production of fiber products is to collect and wind strands of filaments onto a carrier to produce a fiber bundle that may be referred to as a ball, winding, package, cake or doff. These fiber bundles are then used to store, transport and supply fiber linearly into processes such as roving, rewinding, braiding, twisting, weaving. plying, knitting, chopping, pultrusion, filament winding, prepregging, wire coating or cabling for the production of products such as chopped strand mat, yarn wound onto bobbins, multi-end rovings or fabrics or other materials. Typically, a number of these fiber bundles are arranged in a creel or other assembly with individual fibers then being drawn from the separate bundles and passed either singly or in combination into one or more subsequent processes.
  • tensioner designs are available, a spring tensioner capable of applying a uniform tension as the fiber passes at high speed and does not damage the strand even at high tension levels is preferred.
  • other types of tensioners including post and disc, breaker bars/alligator clips, electromagnetic breaking/tensioning devices and ball-in-tube tensioners, could also be used in conjunction with the basic feed assembly to perform the desired tensioning.
  • the rate at which the final product may be produced is limited, at least in part, by the rate at which the fiber can be drawn from the creel and supplied to the desired manufacturing operation in a safe and sustainable manner.
  • Prior art techniques that have been employed to control and guide the fiber as it is withdrawn from the creel include ring-shaped guides, eyelets and rollers manufactured from various ceramic and metallic materials. Guides fashioned from metals, such as steel, that are subject to corrosion are frequently coated with a layer of polished nickel or chrome to reduce or prevent corrosion of the guide surface and reduce the damage to the fiber as it is drawn through or across the guide.
  • U. S. Pat. No. 4,944, 077 to Bollen provides a method of reducing the air friction of yarns drawn from a bobbin at high speed in which a region of accelerated air surrounds the yarn.
  • U. S. Pat. No.6, 182,475 to Lee provides yet another yarn guiding device for feeding yarn from a creel to a knitting needle utilizing a yarn guiding assembly constructed from a combination of zirconium oxide and yttrium oxide.
  • an anti-ballooning apparatus for a bobbin creel arranged between a bobbin mounted upon a bobbin holder of the creel and the thread guide and thread monitoring device operatively associated with such bobbin.
  • the anti-ballooning device comprises two parallel rods located at the central region between the thread guide and monitoring devicea and the bobbin and extend in a plane perpendicular to the thread withdrawal direction to prevent contact and/or entanglement of the thread balloon formed during withdrawal of the thread from the bobbins of the creel.
  • U. S. Pat. No. 5,639, 036 to Flamm provides a textile machine in which the creel is pivotably supported on a pivot shaft with the motion of the shaft and the creel being controlled with an electric motor and a transmission belt unit.
  • GB-A-1192705 discloses a fibre feed system comprising: a fibre source from which a fibre is drawn; an intake housing arranged to receive the fibre, the intake housing providing a large front opening through which the fibre enters the intake housing and a small rear opening through which the fibre exits the intake housing; a feed tube having an inlet arranged adjacent the rear opening of the intake housing to receive the exiting fibre and an outlet; and a fibre processing apparatus arranged to receive and process the fibre exiting from the feed tube outlet.
  • a fibre feed system characterised by a dampening bar assembly for receiving and contacting the fibre being drawn from the fibre source, said intake housing being arranged to receive the fibre from said dampening bar assembly, wherein the dampening bar assembly comprises a first dampening bar and a second dampening bar, each of the dampening bars being generally cylindrical and having a longitudinal axis and a diameter, the first and second dampening bars being arranged so that their longitudinal axes are both substantially parallel to one another and perpendicular to the fibre being drawn from the fibre source and defining a serpentine path for said fibre, the fibre making contact with both a first rounded outer surface on the first dampening bar and with a second rounded outer surface on the second dampening bar before entering the intake housing.
  • the fibre exiting the feed tube outlet may be processed by operations such as roving, rewinding, braiding, twisting, weaving. plying, knitting, chopping, pultrusion, filament winding, prepregging, wire coating, cabling, tensioning or beaming.
  • the configuration of the claimed assembly allows the fiber to be consumed at draw speeds in excess of 1500 meters/minute while reducing the tendency of the fiber to wrap around feed assembly components.
  • the present invention allows increased run speed, reduced downtime resulting from fiber breaks and improved operator safety.
  • the present invention is suitable for use with a wide number of fibers including polymer fibers such as aramids, polyesters, nylons, polycarbonates (PC), polyethylenes (PE), polypropylenes (PP), polybutylene terephthalate (PBT), polyethylene terephthalate (PET) and polyphenylenebenzobisoxazole, carbon and metal fibers including steel and copper, various types of glass fibers such as E, ECR, S, C and D type glass fibers, and natural fibers such as jute, hemp, cotton and flax.
  • polymer fibers such as aramids, polyesters, nylons, polycarbonates (PC), polyethylenes (PE), polypropylenes (PP), polybutylene terephthalate (PBT), polyethylene terephthalate (PET) and polyphenylenebenzobisoxazole
  • carbon and metal fibers including steel and copper
  • various types of glass fibers such as E, ECR, S, C and D type glass fibers
  • the present invention comprises an improved high-speed fiber assembly that includes a dampening assembly comprising one or more dampening bars, an intake assembly, and feed tubes for transferring one or more fibers from an initial winding into an assembly for conducting additional processing such as roving, rewinding, braiding, twisting, weaving. plying, knitting, chopping, pultrusion, filament winding, prepregging, wire coating, cabling, tensioning or beaming..
  • the basic assembly comprises a fiber source 1, typically a winding or a doff provided in a creel or on a pallet, from which a fiber 2 is unwound for use in another process.
  • the term fiber is also intended to encompass tows and rovings that are configured to be unwound from an intermediate source for use in an additional operation.
  • the fiber 2 is drawn over a dampening bar assembly comprising a first dampening bar 3 where it contacts a portion of the surface 4 of the dampening bar, the contacted portion preferably providing a smooth, durable surface that does not tend to damage or fuzz the fiber and does not suffer undue damage as the fiber is drawn across it at high speeds.
  • the fiber After passing over the first dampening bar 3, the fiber is drawn over a second dampening bar 5 where it contacts a portion of the surface 6 of the second dampening bar, the contacted portion preferably providing a smooth, durable surface that does not tend to damage or fuzz the fiber and does not suffer undue damage as the fiber is drawn across it at high speeds.
  • the fiber 2 After passing over dampening bar 5, the fiber 2 is drawn into an intake housing 7 which provides a large opening 8 defined by a peripheral edge 9 into a cavity that contains and guides the fiber 2 until it exits the intake housing 7 through a small rear opening 11 and enters the feed tube 12.
  • the fiber continues through the feed tube 12 to the feed tube exit 13 where it is fed into another assembly 14 for additional processing such as a tensioner 15 coupled with winder 16.
  • additional processing such as a tensioner and winder are illustrated here for the purposes of discussion, the type of additional processing is not generally limited in scope and may include one or more operations such as roving, rewinding, braiding, twisting, weaving. plying, knitting, chopping, pultrusion, filament winding, prepregging, wire coating or cabling, tensioning or beaming or other processes requiring or benefiting from a linear high-speed fiber feed.
  • the intake housing 7 preferably provides a solid, smooth and durable surface that does not tend to damage or fuzz the fiber and does not suffer undue damage as the fiber is drawn across it at high speeds.
  • Materials such as polished stainless steel, copper and brass have been found to be acceptable for constructing the dampening bars, intake housing and feed tubes for use with glass fibers.
  • Other materials including metals such as chromed or nickeled steel, alloys, composite materials, ceramics, Teflon ® or other high molecular weight polymers could also be used singly or in combination in constructing these elements.
  • the key consideration in the selection of an appropriate material is that they wear smoothly and consistently without producing sharp or rough areas that could tend to damage the fiber as it is drawn across the worn surface. For this reason, black iron, uncoated steel and ceramics having a high iron content are generally not preferred for use in combination with glass fibers.
  • the selection of the materials and the sizing of the elements will be selected with regard to the type and size of the fiber being fed through the assembly and the rate at which the fiber will be fed to provide fiber/surface contact conditions that do not result in damage to the fiber or the surface.
  • a preferred embodiment of the present invention comprises a pair of generally parallel and closely spaced cylindrical dampening bars 3, 5 through which the fiber 2 is drawn in a serpentine pattern.
  • the present invention may employ various configurations of the basic mechanical elements.
  • the centers of the dampening bars are generally aligned along a fiber axis 2' defined between the fiber source 1 and the center of the rear opening 11 into feed tube 12.
  • This fiber axis does not necessarily reflect the actual path of the fiber 2 between the fiber source 1 and the feed tube 12, but rather provides a reference point for the relative positioning of certain elements of the present invention.
  • a third dampening bar 17 having a bearing surface 18 is provided below dampening bars 3, 5 is increase the length of the serpentine path taken by fiber 2 between the fiber source and the intake housing 7.
  • the spacing between adjacent dampening bars can be the same or the spacing between the lower dampening bars 3, 17 can be somewhat larger for knocking down large loops without binding.
  • one of the dampening bars 5a is fixed in a position offset from the fiber axis 2' by an offset distance 19 to modify the path taken by the path taken by the fiber 2, the length and location of the surface portions of the dampening bars contacted by the fiber and the tension exerted on or applied to the fiber.
  • dampening bars present in a particular embodiment could be offset from the fiber axis 2'.
  • the offset distances may be to either side of the fiber axis and may, if more than one dampening bar is offset, have different magnitudes to adapt the assembly to the particular application.
  • One measure of the dampening bar is the offset angle ⁇ measured between the fiber axis 2' and a line projected through the center of the dampening bar and a point on the fiber axis 2'perpendicular to the lowest surface of the dampening bar.
  • At least one of the dampening bars (dampening bar 5 used for convenience only) in the fiber feed assembly may be mounted so as to be moveable between at least a first position 5 and a second position 5a to provide additional control over the path tension of the fiber 2 entering the intake housing 7.
  • the movement of the moveable dampening bar (s) can be generally linear (generally horizontal linear motion illustrated), arcuate or, in the case of non-cylindrical dampening bars, rotational, or a combination of two or more types of motion. Further, the movements of the respective moveable dampening bars may be coordinated or independent using a variety of known mechanisms.
  • dampening bars 20,21 may be employed including oval shapes or even more irregular shapes (not illustrated) in which only the portion of the dampening bars actually contacted by the fiber 2 are smooth and durable.
  • one or more of the dampening bars may be hollow, either simply to reduce the overall weight of the system or to provide a passage 22,23 through which a fluid could be passed to heat or cool the dampening bar as desired.
  • a plurality of fiber feed assemblies may be arranged adjacent one another to draw a plurality of fibers 2 from a plurality of fiber sources 1 arranged on a pallet or creel 24.
  • each feed assembly draws fiber from only one fiber source at a time, for certain applications it may be desirable to feed a plurality of fibers through a single fiber feed assembly.
  • the middle of the three fiber feed assemblies simultaneously draws two fibers 2,2a from corresponding fiber sources 1, la and delivers them together to a single additional processing assembly 14.
  • Fig. 5 shows the use of common dampening bars 3,5, each of the individual feed assemblies could be configured with dedicated dampening bars. In instances where one or more of the dampening bars is moveable, as illustrated in Fig. 3C , independent dampening bars would be preferred.
  • feed assemblies according to the present invention are characterized by certain spacings between and sizings of the various components that are indicated on a portion of the embodiment illustrated in Fig. 1 .
  • the indicated dimensions include a distance 25 between the upper dampening bar 5 and the intake housing 7, a distance 27 between the upper dampening bar 5 and a lower dampening bar 3, and, in the illustrated twin dampening bar configuration, a distance 29 between the lower dampening bar 3 and the fiber source 1.
  • sizings such as the diameter of the upper dampening bar 26, the diameter of the lower dampening bar 28, the diameter and depth of the intake housing, the dimensions of the fiber, and the diameter of the feed tube also require consideration in the construction of a fiber feed assembly for a particular application.
  • sizings such as the diameter of the upper dampening bar 26, the diameter of the lower dampening bar 28, the diameter and depth of the intake housing, the dimensions of the fiber, and the diameter of the feed tube also require consideration in the construction of a fiber feed assembly for a particular application.
  • other embodiments such as illustrated in Fig. 3A may have additional spacings and sizings.
  • the spacing 27 between at least the first two dampening bars contacted by the fiber be maintained at some low multiple of the maximum fiber dimension, typically less than 5, to assist in knocking down and removing loops that may be drawn from the fiber package before the fiber enters the intake housing.
  • distance 25 between the upper dampening bar 5 and the intake housing 7 also be maintained at some low multiple of the maximum fiber diameter, typically less than 15, to provide good control of the fiber entering the intake housing.
  • this distance be considerably larger, typically at least 50 times and preferably at least about 100 times the spacing between the dampening bars so that variations in the point on the fiber source 1 from which the fiber is being drawn have a reduced impact on the angle of the fiber as it contacts the first dampening bar.
  • the wider opening 8 be at least about 50 larger, and preferably at least about 100 times larger, than the largest fiber dimension.
  • the sizing of the feed tube 12 it is preferred that its diameter be at least about 5 times larger, and preferably at least about 10 times larger, than the largest fiber dimension.
  • D SDB is preferred in situations where minimizing the potential for damaging the fiber is the goal. If space constraints make increasing the D SDB difficult and/or if some damage to the fiber can be tolerated, increasing the degree of contact between the fiber and the dampening bars can be used to improve the linearity of the fiber feed.
  • the surface of the dampening bars 30, 32 may be provided with concave surface portions 31, 33 to assist in centering and guiding the fiber 2 across the surfaces of the dampening bars.
  • the contacted surface or a portion of the contacted surfaces 3 3 a on one or more of the dampening bars may be textured so that the condition of the fiber 2 will be altered, typically roughened or frayed in some manner, as it is drawn across the surface of the dampening bar.
  • an alternative embodiment of the present invention incorporates one or more gas inlets 34 through which a gas, such as air, steam, oxygen, helium or nitrogen, could be introduced into one or more passages 35 and through a plurality of perforations 36 or other openings, nozzles, or inlets through the intake housing 7a.
  • a gas such as air, steam, oxygen, helium or nitrogen
  • this embodiment can help control temperature, humidity, moisture content or accumulation of static charges as the fiber 2 is drawn though the intake housing 7a and feed tube 12.
  • this embodiment may be used to at least partially pre-condition the fiber 2 for subsequent processing as the fiber is drawn through the intake housing 7a and feed tube 12.
  • both fluted intake housings 7b, Fig. 9A , and conical intake housings 7c, Fig. 9B could be incorporated into a fiber feed assembly according to the present invention.
  • any of the solid intake housings 7, 7b, 7c could be modified along the lines illustrated in Fig. 8 to permit the introduction of one or more gases through the sides of the intake housing.
  • the intake housing configuration selected it must be sized and configured to provide sufficient control of the fiber by constricting its range of motion while minimizing unnecessary contact with the interior surface of the intake housing.
  • both hemispherical (domed) and conical (tapered) intake housings of sufficient size performed well.
  • the original fiber feed apparatus was configured to draw a series of 600-1470 tex (grams/kilometer) glass fibers (generally oval with approximate dimensions of 0.26 mm x 2.18 mm) from a collection of windings arranged on a pallet and pass the fibers through a series of open ring guides and into a feed tube inlet of a feed tube constructed from 3 ⁇ 4 inch (1.9 cm) copper tubing.
  • a spring tensioning device was positioned adjacent the outlet of the feed tube to apply a uniform tension to the fiber exiting the feed tube before passing the fiber to a winding operation.
  • the original fiber feed apparatus was modified so that the identical glass fiber was drawn from an identical arrangement of windings again arranged on a pallet.
  • the glass fiber first passed along a serpentine path through a twobar dampening bar assembly of1 1/2 inch(38. 1 mm) diameter copper pipes spaced approximately 1/4 inch (6.3mm) apart.
  • the lower dampening bar was positioned at least about 24 inches (61 cm) above the pallet and the upper dampening bar was generally centered approximately 1/4 inch (6.3 mm) below a hemispherical stainless steel funnel with a radius of approximately 71/2 inches (19 cm) and a smooth interior surface.
  • the stainless steel funnel included a small rear exit through which the fiber was fed into a feed tube constructed from 3/4 inch (1.9 cm) copper tubing.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Moulding By Coating Moulds (AREA)
  • Unwinding Of Filamentary Materials (AREA)
  • Guides For Winding Or Rewinding, Or Guides For Filamentary Materials (AREA)
EP03764365A 2002-07-16 2003-07-07 Improved high-speed fiber feed assembly Expired - Lifetime EP1546014B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08014557A EP2019070A3 (en) 2002-07-16 2003-07-07 Improved high-speed fibre feed assembly

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US196492 2002-07-16
US10/196,492 US6869004B2 (en) 2002-07-16 2002-07-16 High-speed fiber feed assembly
PCT/US2003/021185 WO2004007330A1 (en) 2002-07-16 2003-07-07 Improved high-speed fiber feed assembly

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP08014557A Division EP2019070A3 (en) 2002-07-16 2003-07-07 Improved high-speed fibre feed assembly

Publications (2)

Publication Number Publication Date
EP1546014A1 EP1546014A1 (en) 2005-06-29
EP1546014B1 true EP1546014B1 (en) 2008-10-08

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ID=30115071

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EP08014557A Withdrawn EP2019070A3 (en) 2002-07-16 2003-07-07 Improved high-speed fibre feed assembly
EP03764365A Expired - Lifetime EP1546014B1 (en) 2002-07-16 2003-07-07 Improved high-speed fiber feed assembly

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Application Number Title Priority Date Filing Date
EP08014557A Withdrawn EP2019070A3 (en) 2002-07-16 2003-07-07 Improved high-speed fibre feed assembly

Country Status (10)

Country Link
US (1) US6869004B2 (ja)
EP (2) EP2019070A3 (ja)
JP (3) JP4383344B2 (ja)
CN (1) CN1332866C (ja)
AU (1) AU2003253811A1 (ja)
BR (1) BR0312709A (ja)
CA (1) CA2491197A1 (ja)
DE (1) DE60324001D1 (ja)
DK (1) DK1546014T3 (ja)
WO (1) WO2004007330A1 (ja)

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DE102004048913A1 (de) * 2004-10-06 2006-04-13 Deutsche Institute für Textil- und Faserforschung Verfahren und Vorrichtung zum Umspulen von Fadenzulieferspulen
FR2900651B1 (fr) * 2006-05-02 2012-04-20 Jean Luc Trullier Dispositif ferme permettant de devider une pelote de ficelle pelucheuse avec retenue des fibres volatiles favorisant un environnement de travail propre.
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CN105520204B (zh) * 2015-12-25 2017-07-14 广东宏杰内衣实业有限公司 一种高弹无缝接骨文胸
CN111304797B (zh) * 2018-12-11 2021-12-14 胡梅华 一种棉纱纺织用上蜡装置
CN113279243B (zh) * 2021-05-31 2022-08-26 江苏天华索具有限公司 一种高空作业复合纤维用制备设备及其制备方法

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JP2002220156A (ja) * 2000-11-24 2002-08-06 Toray Ind Inc 糸条パッケージの製造方法及び装置

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JP4383344B2 (ja) 2009-12-16
EP2019070A3 (en) 2009-02-04
WO2004007330A1 (en) 2004-01-22
EP1546014A1 (en) 2005-06-29
JP2009256871A (ja) 2009-11-05
DE60324001D1 (de) 2008-11-20
CN1332866C (zh) 2007-08-22
JP2005533194A (ja) 2005-11-04
CA2491197A1 (en) 2004-01-22
US6869004B2 (en) 2005-03-22
JP2013028893A (ja) 2013-02-07
AU2003253811A1 (en) 2004-02-02
EP2019070A2 (en) 2009-01-28
DK1546014T3 (da) 2009-02-16
JP5261315B2 (ja) 2013-08-14
BR0312709A (pt) 2005-05-10
CN1668520A (zh) 2005-09-14

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