EP1542947B8 - Alkylaromatics production - Google Patents

Alkylaromatics production Download PDF

Info

Publication number
EP1542947B8
EP1542947B8 EP03754437A EP03754437A EP1542947B8 EP 1542947 B8 EP1542947 B8 EP 1542947B8 EP 03754437 A EP03754437 A EP 03754437A EP 03754437 A EP03754437 A EP 03754437A EP 1542947 B8 EP1542947 B8 EP 1542947B8
Authority
EP
European Patent Office
Prior art keywords
alkane
alkylation
aromatic compound
effluent
alkene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03754437A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1542947B1 (en
EP1542947A2 (en
Inventor
Michael C. Clark
Charles M. Smith
Ronald J. Cimini
Brian Maerz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Washington Group International Inc
ExxonMobil Chemical Patents Inc
Original Assignee
Washington Group International Inc
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Washington Group International Inc, ExxonMobil Chemical Patents Inc filed Critical Washington Group International Inc
Publication of EP1542947A2 publication Critical patent/EP1542947A2/en
Application granted granted Critical
Publication of EP1542947B1 publication Critical patent/EP1542947B1/en
Publication of EP1542947B8 publication Critical patent/EP1542947B8/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
EP03754437A 2002-09-23 2003-09-04 Alkylaromatics production Expired - Lifetime EP1542947B8 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/252,767 US6995295B2 (en) 2002-09-23 2002-09-23 Alkylaromatics production
US252767 2002-09-23
PCT/US2003/027581 WO2004026797A2 (en) 2002-09-23 2003-09-04 Alkylaromatics production

Publications (3)

Publication Number Publication Date
EP1542947A2 EP1542947A2 (en) 2005-06-22
EP1542947B1 EP1542947B1 (en) 2010-01-13
EP1542947B8 true EP1542947B8 (en) 2010-05-19

Family

ID=31993013

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03754437A Expired - Lifetime EP1542947B8 (en) 2002-09-23 2003-09-04 Alkylaromatics production

Country Status (12)

Country Link
US (1) US6995295B2 (ko)
EP (1) EP1542947B8 (ko)
JP (1) JP4362107B2 (ko)
KR (1) KR101120186B1 (ko)
CN (1) CN1323990C (ko)
AT (1) ATE455085T1 (ko)
AU (1) AU2003272263A1 (ko)
CA (1) CA2495742C (ko)
DE (1) DE60330973D1 (ko)
ES (1) ES2339651T3 (ko)
TW (1) TWI315302B (ko)
WO (1) WO2004026797A2 (ko)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7074978B2 (en) * 2003-02-25 2006-07-11 Abb Lummus Global Inc. Process for the production of alkylbenzene
US7071369B2 (en) * 2003-06-10 2006-07-04 Abb Lummus Global Inc. Process for the production of alkylbenzene with ethane stripping
EP1868970B1 (en) * 2005-03-31 2014-11-26 Badger Licensing LLC A process of using a high activity catalyst for the transalkylation of aromatics
EP1866267B1 (en) * 2005-03-31 2014-11-05 Badger Licensing LLC Alkylaromatics production using dilute alkene
KR101177220B1 (ko) * 2005-03-31 2012-08-24 바져 라이센싱 엘엘씨 다중상 알킬방향족의 제조방법
EP1866271B1 (en) * 2005-03-31 2016-09-21 ExxonMobil Chemical Patents Inc. Process and catalyst for the transalkylation of aromatics
US7495139B2 (en) * 2006-01-07 2009-02-24 Fina Technology, Inc. Use of modified zeolite catalysts in alkylation systems
EP1968919A4 (en) * 2006-01-07 2009-01-21 Fina Technology LIQUID PHASE ALKYLATION DILUTED
TW200744985A (en) * 2006-02-14 2007-12-16 Exxonmobil Chemical Patents Inc Process for producing sec-butylbenzene
AU2007245193B2 (en) * 2006-04-21 2010-12-02 Exxonmobil Chemical Patents Inc. Process for methane conversion
US7501547B2 (en) * 2006-05-10 2009-03-10 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7692054B2 (en) * 2006-10-30 2010-04-06 Uop Llc Process and apparatus for alkylation of aromatic compound with aliphatic mono-olefin compound of 8 to 18 carbon atoms
US7919421B2 (en) * 2006-12-21 2011-04-05 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation
US7420098B2 (en) * 2007-01-12 2008-09-02 Uop Llc Dual zone aromatic alkylation process
US7381676B1 (en) * 2007-01-16 2008-06-03 Exxonmobil Chemical Patents Inc. Catalyst composition and its use thereof in aromatics alkylation
US7645913B2 (en) 2007-01-19 2010-01-12 Exxonmobil Chemical Patents Inc. Liquid phase alkylation with multiple catalysts
US7737314B2 (en) * 2007-02-12 2010-06-15 Exxonmobil Chemical Patents Inc. Production of high purity ethylbenzene from non-extracted feed and non-extracted reformate useful therein
US7745676B2 (en) 2007-07-30 2010-06-29 Exxonmobil Chemical Patents Inc. Alkylaromatics production
DE602008005752D1 (de) * 2007-08-22 2011-05-05 Exxonmobil Chem Patents Inc Verfahren zur herstellung von sec.-butylbenzol
US7795485B2 (en) * 2007-10-26 2010-09-14 Uop Llc Integrated production of FCC-produced C2 and ethyl benzene
CA2716150A1 (en) * 2008-02-28 2009-09-03 Andre Petitjean Process for the manufacture of at least one ethylene derivative compound
FR2934599B1 (fr) * 2008-07-29 2012-12-21 Arkema France Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations
US8865958B2 (en) 2008-09-30 2014-10-21 Fina Technology, Inc. Process for ethylbenzene production
BRPI0920705B1 (pt) * 2008-10-10 2018-02-06 Exxonmobil Chemical Patents Inc. Processo para a produção de compostos alquilaromáticos
RU2515979C2 (ru) * 2008-10-10 2014-05-20 Бэджер Лайсенсинг ЛЛК Способ получения алкилароматических соединений
WO2010042269A1 (en) 2008-10-10 2010-04-15 Exxonmobil Chemical Patents Inc. Process for producing phenol and methyl ethyl ketone
SG183322A1 (en) * 2010-03-10 2012-09-27 Exxonmobil Chem Patents Inc Alkylated aromatics production
US8629311B2 (en) * 2010-03-10 2014-01-14 Stone & Webster, Inc. Alkylated aromatics production
WO2011123413A2 (en) * 2010-03-31 2011-10-06 Uop Llc Process and apparatus for increasing weight of olefins
US8895793B2 (en) 2010-06-11 2014-11-25 Uop Llc Process for the reduction of gasoline benzene content by alkylation with dilute ethylene
US8414851B2 (en) 2010-06-11 2013-04-09 Uop Llc Apparatus for the reduction of gasoline benzene content by alkylation with dilute ethylene
RU2563461C2 (ru) 2010-08-30 2015-09-20 Эксонмобил Кемикэл Пейтентс Инк. Улучшенный способ алкилирования
US9902664B2 (en) 2012-02-08 2018-02-27 Exxonmobil Chemical Patents Inc. Production of monoalkyl aromatic compounds
JP5736360B2 (ja) * 2012-10-26 2015-06-17 エクソンモービル・ケミカル・パテンツ・インク 有機化合物変換方法
KR20160076320A (ko) * 2014-12-22 2016-06-30 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법 및 장치
WO2017065771A1 (en) * 2015-10-15 2017-04-20 Badger Licensing Llc Production of alkylaromatic compounds
CN107513001B (zh) * 2016-06-17 2020-09-01 中国科学院大连化学物理研究所 一种提高稀乙烯制乙苯装置产能的方法
CN106478331A (zh) * 2016-08-31 2017-03-08 苏州乔发环保科技股份有限公司 一种苯与长链烯烃烷基反应处理系统
CN111589406B (zh) 2019-02-21 2022-04-12 中国石油化工股份有限公司 烷基化反应装置、反应系统和液体酸催化的烷基化反应方法
CN111574318B (zh) * 2020-06-04 2022-09-30 常州瑞华化工工程技术股份有限公司 一种纯乙烯生产乙苯的节能反应工艺

Family Cites Families (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6503410A (ko) * 1963-02-21 1965-09-20
US3442795A (en) * 1963-02-27 1969-05-06 Mobil Oil Corp Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom
USRE28341E (en) 1964-05-01 1975-02-18 Marshall dann
US3308069A (en) * 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US3293192A (en) * 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3494971A (en) * 1969-04-18 1970-02-10 Universal Oil Prod Co Process for the production of a monoalkylated aromatic hydrocarbon
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) * 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
US3832449A (en) * 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US3766093A (en) * 1972-01-07 1973-10-16 Mobil Oil Corp Treatment of organic cationcontaining zeolites
US3755483A (en) * 1972-04-28 1973-08-28 Mobil Oil Vapor phase alkylation in presence of crystalline aluminosilicate catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US3751506A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst
US3894104A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US3923636A (en) * 1974-06-03 1975-12-02 Texaco Inc Production of lubricating oils
US3972983A (en) * 1974-11-25 1976-08-03 Mobil Oil Corporation Crystalline zeolite ZSM-20 and method of preparing same
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
CA1064890A (en) * 1975-06-10 1979-10-23 Mae K. Rubin Crystalline zeolite, synthesis and use thereof
US4107224A (en) * 1977-02-11 1978-08-15 Mobil Oil Corporation Manufacture of ethyl benzene
US4234231A (en) * 1978-12-06 1980-11-18 Mobil Oil Corporation Method for restoring a leached formation
DE3117135A1 (de) * 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US4956122A (en) 1982-03-10 1990-09-11 Uniroyal Chemical Company, Inc. Lubricating composition
CA1208196A (en) 1982-03-10 1986-07-22 Raymond F. Watts Lubricating composition
US4556477A (en) * 1984-03-07 1985-12-03 Mobil Oil Corporation Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks
US5149894A (en) * 1986-01-29 1992-09-22 Chevron Research And Technology Company Alkylation using zeolite SSZ-25
IT1205681B (it) 1987-05-26 1989-03-31 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio e boro
EP0339088B1 (en) 1987-09-25 1993-04-21 Tonen Corporation Improved traction fuid
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
GB8729555D0 (en) 1987-12-18 1988-02-03 Shell Int Research Alkylation process
US5003119A (en) * 1988-05-09 1991-03-26 Lummus Crest, Inc. Manufacture of alkylbenzenes
US4912272A (en) 1988-06-23 1990-03-27 Mobil Oil Corporation Lubricant blends having high viscosity indices
US4990711A (en) 1988-06-23 1991-02-05 Mobil Oil Corporation Synthetic polyolefin lubricant blends having high viscosity indices
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5073653A (en) * 1989-06-23 1991-12-17 Fina Technology, Inc. Aromatic alkylation processes
US5476978A (en) * 1989-09-05 1995-12-19 Chemical Research & Licensing Company Process for the preparation of ethyl benzene
IT1237198B (it) 1989-11-16 1993-05-26 Eniricerche Spa Processo per l'alchilazione di composti aromatici.
DE69026613T2 (de) 1990-07-18 1996-10-24 Fina Technology Transalkylierungsverfahren
EP0485683B1 (en) 1990-11-13 2001-01-10 Fina Technology, Inc. Preparation of alkylated aromatics
CN1020041C (zh) * 1990-12-18 1993-03-10 中国石油化工总公司 稀乙烯与苯反应制取乙苯工艺过程
US5300722A (en) * 1990-12-27 1994-04-05 Amoco Corporation Oxygen-free aromatic alkylation process
US5250277A (en) * 1991-01-11 1993-10-05 Mobil Oil Corp. Crystalline oxide material
US5077445A (en) * 1991-02-06 1991-12-31 Mobil Oil Corp. Liquid-phase alkylbenzene synthesis using hydrated catalyst
US5191135A (en) * 1991-03-25 1993-03-02 Mobil Oil Corporation Aromatics alkylation process
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5258565A (en) * 1992-05-04 1993-11-02 Mobil Oil Corp. Process for preparing short chain alkylaromatic compounds
US5362697A (en) * 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
CA2125378A1 (en) 1993-06-09 1994-12-10 James A. E. Bell Composition for lightning strike protection and improved electrical conductivity
EP0703887A1 (en) * 1993-06-16 1996-04-03 Mobil Oil Corporation Liquid phase ethylbenzene synthesis
FR2706888A1 (en) 1993-06-25 1994-12-30 Inst Francais Du Petrole Process for the alkylation of aromatic compounds
US5430211A (en) * 1993-10-29 1995-07-04 The Dow Chemical Company Process of preparing ethylbenzene or substituted derivatives thereof
US5491277A (en) * 1993-12-28 1996-02-13 Uop Mixed-phase solid bed hydrocarbon alkylation process
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
ES2124154B1 (es) 1995-11-08 1999-12-01 Univ Politecnica De Valencia C Metodo de preparaciion y propiedades cataliticas de un solido microporoso con alta superficie externa.
ES2105982B1 (es) * 1995-11-23 1998-07-01 Consejo Superior Investigacion Zeolita itq-1
US5856607A (en) * 1996-05-03 1999-01-05 Amoco Corporation Process for production of ethylbenzene frome dilute ethylene streams
US5858934A (en) 1996-05-08 1999-01-12 The Lubrizol Corporation Enhanced biodegradable vegetable oil grease
CN1105093C (zh) 1996-08-20 2003-04-09 陶氏化学公司 制备烷基化苯的方法
US5880320A (en) * 1997-08-05 1999-03-09 Netzer; David Combination process for manufacturing ethylene ethylbenzene and styrene
US6252126B1 (en) * 1998-06-19 2001-06-26 David Netzer Method for producing ethylbenzene
US6057485A (en) * 1998-11-17 2000-05-02 Fina Technology, Inc. Gas phase alkylation with split load of catalyst
DE60011814T2 (de) 1999-09-20 2005-07-07 Consejo Superior de Investigaciónes Científicas Alkylierung von aromaten
US6372696B1 (en) 1999-11-09 2002-04-16 The Lubrizol Corporation Traction fluid formulation

Also Published As

Publication number Publication date
CN1323990C (zh) 2007-07-04
AU2003272263A1 (en) 2004-04-08
ATE455085T1 (de) 2010-01-15
CA2495742A1 (en) 2004-04-01
KR101120186B1 (ko) 2012-03-16
WO2004026797A3 (en) 2004-05-27
TW200413277A (en) 2004-08-01
JP2006500406A (ja) 2006-01-05
CN1732138A (zh) 2006-02-08
AU2003272263A8 (en) 2004-04-08
CA2495742C (en) 2011-05-03
WO2004026797A2 (en) 2004-04-01
JP4362107B2 (ja) 2009-11-11
US20040059167A1 (en) 2004-03-25
EP1542947B1 (en) 2010-01-13
TWI315302B (en) 2009-10-01
DE60330973D1 (de) 2010-03-04
US6995295B2 (en) 2006-02-07
EP1542947A2 (en) 2005-06-22
KR20050069997A (ko) 2005-07-05
ES2339651T3 (es) 2010-05-24

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