EP1513426A1 - Dispenser head with a check valve - Google Patents
Dispenser head with a check valveInfo
- Publication number
- EP1513426A1 EP1513426A1 EP03760629A EP03760629A EP1513426A1 EP 1513426 A1 EP1513426 A1 EP 1513426A1 EP 03760629 A EP03760629 A EP 03760629A EP 03760629 A EP03760629 A EP 03760629A EP 1513426 A1 EP1513426 A1 EP 1513426A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- valve body
- head
- valve
- dispenser head
- dispenser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/16—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means
- B65D83/20—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means operated by manual action, e.g. button-type actuator or actuator caps
- B65D83/205—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container
- B65D83/206—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container comprising a cantilevered actuator element, e.g. a lever pivoting about a living hinge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
- B65D83/753—Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by details or accessories associated with outlets
- B65D83/7535—Outlet valves opened by the product to be delivered
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D27/00—Shaving accessories
- A45D27/02—Lathering the body; Producing lather
- A45D27/10—Lather-producing devices operated by compressed air or by swirling water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1042—Components or details
- B05B11/1052—Actuation means
- B05B11/1053—Actuation means combined with means, other than pressure, for automatically opening a valve during actuation; combined with means for automatically removing closures or covers from the discharge nozzle during actuation
Definitions
- the invention relates to a dispenser head with a discharge channel for the discharge of products such as foams, for example shaving foam or gel, self-foaming products and other products which can be applied with a pressurized system, from a conventional dispenser container which is under pressure and which can be plugged onto the discharge valve of the dispenser container and through which An external mechanical pressure exerted on him and a resulting tilting movement of his upper part about a pivot point opens the discharge valve of the dispenser container, so that the product flows with overpressure from the discharge valve into the discharge channel and exits the dispenser head through its discharge opening.
- products such as foams, for example shaving foam or gel, self-foaming products and other products which can be applied with a pressurized system
- a disadvantage of such known dispensers or dispenser heads is that after the application and the reset of the tilted upper part, despite the discharge valve having already been closed, the product still under pressure in the discharge channel emerges in a small amount from the discharge opening of the dispenser head. This undesirable and uncontrolled pressing of the product then contaminates the dispenser head and, if present, the protective cap.
- the object of the invention is to design a dispenser head for pressurized dispenser containers in such a way that the described pressing of the product is prevented after use.
- the stated object is achieved for a dispenser head of the type mentioned at the outset with the characterizing features of claim 1 in that the dispenser head is designed with an additional closure device which automatically opens the discharge opening of the discharge channel and closes automatically after the dispensing process has ended.
- the inventive design of the dispenser head with its own closure for the discharge opening reliably prevents the product from escaping after use.
- the closure device of the dispenser head which can be placed on any conventional aerosol valve, consists in particular of a valve housing which forms part of the discharge channel arranged in the upper part of the dispenser head, a pin-shaped valve body with a valve head for closing the discharge opening and a reset element.
- the restoring element is formed from an elastic dome, in the semicircular rear wall of which an inner sleeve is arranged, into which the end of the valve body opposite the valve head is inserted.
- the elastic dome pulls the valve head of the valve body from the outside against the discharge opening of the discharge channel and closes it due to its inherent tension.
- the position of the elastic dome with respect to the usual pivot point for the tilting movement of the upper part of the dispenser head is selected so that its elastic rear wall during the tilting movement is guided on a circular path against a fixed web of the lower part of the dispenser head and deforms it in the process and by a certain amount is moved towards the discharge opening.
- valve body In a second embodiment of the invention, the valve body, the valve head of which closes the discharge opening from the front, is anchored in a valve body sleeve.
- the rear part of the valve body sleeve is made as a restoring element from an elastic double wall and is connected in a stationary manner to the upper part and / or the lower part of the dispenser head.
- this elastically designed rear part of the double wall is guided in a circular path against a fixed web of the lower part, deformed and moved with the valve body in the direction of the discharge opening.
- the valve head releases the discharge opening that it previously closed to the outside.
- the rear part of the valve body closing the discharge opening from the inside is double-walled and can be filled with the product to be discharged.
- the outer valve body wall is made of an elastic material and serves as a restoring element, for which purpose the front part of the elastic valve body wall is fixedly connected to the upper part and / or to the lower part of the dispenser head. With this connection, the elastic valve body wall is placed under tension in the starting position in such a way that the conical or round tip of the valve head is pulled from the inside against the appropriately designed nozzle mouth of the discharge opening and seals it tightly.
- the product to be discharged flows into the double wall of the valve body with overpressure.
- the pressure exerted on the inner rear wall of the double wall is greater than the tensile stress in the elastic region of the valve body wall, so that the valve body is pulled inwards and releases the discharge opening towards the inside.
- the tensile stress already present in the starting position is increased by stretching the elastic region of the valve body wall. After the dispensing process has ended, the tension in the elastic valve body wall is sufficient to automatically reset the valve body and to close the discharge opening again.
- the elastic part of the valve body sleeve (second embodiment) or the valve body wall (third embodiment) is connected in a special injection molding process (2-component injection molding) in one piece by injection molding to the rest of the inelastic part of the valve body sleeve or the valve body wall.
- the internal stress of these elastic restoring elements is selected so large by using an appropriate elastic material, for example TPE (thermoplastic elastomers), that it is sufficient to pull the valve body back into its original position after the dispensing process has ended and the tilted upper part has been reset and the Close the discharge opening again tightly with the valve head.
- TPE thermoplastic elastomers
- the valve body is designed in a manner similar to that in the third embodiment with a double wall which can be filled with the product to be discharged.
- the double-walled rear part of the valve body is pressed against a projecting rib of a stationary web, and the valve head lies against the discharge opening in a sealing manner, the rear elastic region of the double wall being compressed.
- the web and its rib are arranged so that the circular Tilting movement of the upper part is turned out of the lock during the dispensing process.
- the excess pressure of the product in the double wall which initially only acts on the rear wall of the double wall, is supported by the restoring force of the compressed elastic area of the double wall, pulling the valve body inwards, whereby the valve head releases the discharge opening.
- the projecting rib pushes the valve body back manually against the discharge opening and thereby closes it, the elastic region of the double wall of the valve body being compressed again.
- FIG. 3 shows the dispenser head of FIG. 1 in a front view
- FIGS. 1, 2 and 3 shows the closure device of FIGS. 1, 2 and 3,
- FIG. 6 shows the valve body of FIG. 5
- FIG. 10 is an enlarged partial section of FIG. 9 in the dispensing position, 11a, b two alternative designs of the outlet opening closure of the second dispenser head,
- FIG. 13 is an enlarged partial section of FIG. 12 in the dispensing position
- FIG. 1 shows a vertical section of a dispenser head 1 with a closure device V according to the invention in the starting position.
- This closure device V is located in the upper part 10 of the dispenser head 1, which can be tilted to open the discharge valve of the dispenser container. It consists of a valve housing 4, which is also part of the upper (in the drawing horizontal) discharge channel 2 and is arranged at right angles to the container axis 15 , a pin-shaped valve body 5 with a valve head 7 and an elastic return element or dome 6 (see also Figures 5 to 8).
- the front part of the valve housing 4 ends at a distance from the front edge 16 of the upper discharge channel 2 with the discharge opening 3 and the rear part of the valve housing 4 (on the right in the drawing) is formed by the elastic dome 6 which is put on.
- the semicircular rear wall 12 of the dome 6 has a sleeve 8 inside, into which the tapered end 18 of the pin-shaped valve body 5 opposite the valve head 7 is inserted.
- the length of the pin-shaped valve body 5 is dimensioned such that, in the starting position of the dispenser head 1, the valve head 7 is pulled against the discharge opening 3 from the front by the internal tension of the elastic dome 6 and closes it.
- the non-tiltable lower part 11 of the dispenser head 1, which is connected to the dispenser container (the dispenser container is not shown) by pushing it on, has a web 9 on the side which touches the semicircular rear wall 12 of the dome 6.
- the dispenser head 1 of Fig. 1 is shown in the dispensing position.
- the upper part 10 of the dispenser head 1 has been tilted by an external mechanical pressure on the button 17 of the dispenser head 1 about a pivot point (the pivot point is not shown), whereby the discharge valve (not shown) of the dispenser container has been opened and the product into the discharge channel 2 and in flows into the valve housing 4.
- the dome 6 was guided on a circular path with its semicircular rear wall 12 downwards against the stationary web 9 in the direction of the dispenser container, as a result of which the rear wall 12 was deformed and shifted in the direction of the discharge opening.
- the closure device 1 'with the upper part 10 of the dispenser head 1 is rotated back into the starting position by the existing tension in the pivot point of the dispenser head 1 and the force of the dispenser valve still open the dispensing container discharge valve closes again.
- the rear wall 12 of the elastic dome 6 is released again from the web 9 and its deformation is reduced by its internal stress and the excess pressure of the product still in the valve housing 4.
- the valve body 5 fastened to the rear wall 12 is also pulled back into its starting position in the same direction and the valve head 7 is firmly pulled from the front onto the discharge opening 3 and thereby closed.
- Another advantage of the closure device 1 'according to the invention is that the pressure of the valve head 7 on the discharge opening 3 is not only due to the internal stress of the elastic dome 6, but also due to the differently sized effective surfaces 13, 14 of the rear wall which are subjected to excess pressure by the product 12 and valve head 7 is effected. Since the effective area 14 of the rear wall 12 of the dome 6 is substantially larger than the effective area 13 of the valve head 7, there is a resultant force which only acts on the rear wall 12, with the result that the greater the overpressure, the higher also is the force with which the valve head 7 is pulled against the discharge opening 3, and the higher the tightness of the system.
- the object of the invention is to prevent the product from being pressed after the dispensing process has ended.
- FIG. 3 shows the dispenser head 1 of FIG. 1 with the closure device 1 ′ designed according to the invention in a front view.
- FIG. 4 shows the dispenser head 1 without the closure device V
- the size of the closure device 1 'in relation to the size of the dispenser head 1 and its adaptation to it are particularly clearly emphasized.
- 5 shows the complete closure device 1 'individually in the starting position with the discharge opening 3 closed and the undeformed rear wall 12 of the dome 6. 6 to 8, the individual components of this closure device 1 'are then listed separately.
- valve body 5 shows the valve body 5 with valve head 7 at one end and the tapered other end 18 for insertion into the sleeve 8 of the dome 6.
- Fig. 7 shows the valve body 4, and 8 the elastic dome 6 with its rear wall 12 and the sleeve 8 arranged thereon.
- FIGS. 9 and 10 show a second embodiment of the dispenser head according to the invention; 9 shows the entire dispenser head 20 in the starting position; 10 shows an enlarged partial section of the dispenser head 20 in the dispensing position.
- the dispenser head 20 consists of an upper part 30 and a lower part 31 with an integrated closing device 21.
- a valve body sleeve 28 is arranged with inserted and latching from the front anchored valve body 25.
- the front part of the valve body sleeve 28 is formed with a nozzle body 36 with alternately arranged passage channels 36 'in a guide region 34 in order to enable the product to be discharged between the valve body 25 and the valve body sleeve 28.
- valve body 25 in the valve body sleeve 28 is such that the valve head 27 closes the discharge opening 23 from the front.
- the valve body sleeve 28 is formed as part of the discharge channel 22 with a double wall 32 which can be filled with the product through a lower opening 33.
- the seal between the dispenser head 20 and the closure device 21 takes place via two elastic ring beads 32 ′ and 32 ′′. Between these two ring beads 32 ′ and 32 ′′ an annular space is formed, through which the product can flow and thus a positioning of the lower opening 33 Closure device 21 to the product channel 19 of the dispenser head 20 is unnecessary. The consequence of this measure is an easier assembly.
- valve body sleeve 28 is guided with its restoring element or rear end 26 on a circular path against the fixed web 29 of the lower part 31 and pushed forward together with the valve body 25 , whereby the valve head 27 releases the discharge opening 23 to the front and the product emerges from the valve head 27 in the direction of arrow 39.
- the elastic rear end 26 is deformed (compressed) by the stop on the web 29.
- the rear end 26 of the valve body sleeve 28 is released again from the web 29 and the restoring force of the compressed rear end 26 and the pressure exerted on its rear wall 26 'by the product still under pressure in the double wall 32 pull the valve body sleeve 28 along with it the valve body 25 back to the starting position.
- the conical front part of the valve head 27 seals the nozzle body 36 of the discharge opening 23, which is designed with a recessed corner, with point contact.
- FIGS. 11a and 11b show alternative designs of the outlet opening closure with nozzle body 36 and valve head 27.
- the nozzle body 36 a is likewise designed with a cone corresponding to the cone of the valve head 27 a of the valve body 25 a, so that a flat sealing contact is produced.
- the valve head 27b of the valve body 25b is additionally formed with an outwardly projecting central mandrel 35, which better distributes the product during its out - guaranteed sluggish from the dispenser head.
- FIGS. 12 and 13 A third variant of the dispenser head according to the invention is shown in FIGS. 12 and 13 in an enlarged detail, in FIG. 12 in the starting position and in FIG. 13 in the dispensing position.
- the dispenser head 40 consists of an upper part 50 with a closure device 41 arranged therein and a lower part 51.
- the closure device 41 is formed from a valve housing 44 with a nozzle body 56 and a valve body 45, the valve head 47 of which closes the discharge opening 43 of the nozzle body 56 from the inside.
- the rear part of the valve body 45 is formed by a double wall 52 which is open towards the valve head 47 and closed in the opposite direction by a rear wall 52 '.
- the double wall 52 thereby forms part of the discharge channel 42 and can be filled with the product to be discharged via a lower opening 53.
- the outer valve body wall 46 as a restoring element, consists of an elastic material molded onto the remaining wall and is connected in a fixed manner to the upper part 50 and the lower part 51 via a snap connection via elastic ring beads 46 ', 46 ".
- These ring beads 46', 46" lead in the same way 10 as a seal between the dispenser head 40 and the closure device 41 and in the same way as described there lead to an easier assembly by forming an annular space through which the product can flow.
- the elastic valve body wall 46 is under tension as a restoring element and pulls the valve body 45 with its valve head 47 in a sealing manner against the discharge opening 43 of the nozzle body 56.
- This tension in the elastic valve body wall 46 is generated in that the nozzle body 56 during assembly of is inserted into the front of the valve housing 44 and thereby moves the valve body 45 to the rear.
- the elastic valve body wall 46 acts as an automatic restoring element during the dispensing process in the following manner: During the dispensing process, flows through Pressing the button 57 the product to be discharged from below through the lower opening 53 into the cavity formed by the double wall 52. Here, the product presses with its pressure, which is greater than the preset tensile force, against the rear wall 52 'of the double wall 52 and, since the discharge opening 43 is initially still closed, moves while stretching the elastic outer valve body wall 46 and enlarging the original one Tension the valve body 45 towards the rear wall 52 '. As a result of this displacement, the valve head 47 of the valve body 45 releases the discharge opening 43 inwards and the product can emerge from the dispenser head 40 in the direction of arrow 59.
- the restoring force of the elastic outer valve body wall 46 automatically pulls the valve body 45 back into its starting position and the valve head 47 closes the discharge opening 43.
- the discharge opening 43 is thereby closed by the conically tapered valve head 47, which is attached to the conical
- the course of the discharge opening 43 of the nozzle body 56 is adapted.
- FIGS. 14a to 14c show further training options for the front closure.
- the front part of the valve head 47a is formed with a central cylindrical mandrel 55.
- the valve body 45a is guided here via guide webs 58a with a conical centering which are arranged in the discharge opening 43a of the nozzle body 56a and which grip around the cylindrical mandrel 55.
- the discharge opening 43a is sealed in a plane seal with the peripheral edge 48 of the valve head 47a with the rear part of the nozzle body 56a.
- FIG. 14b with otherwise identical design to FIG.
- the discharge opening 43a is sealed between the rear part of the nozzle body 56b, which has just been formed in the radial direction, and the peripheral edge 48 of the end face of the valve head 47b.
- the guidance of the valve body 45c is increased in that, in addition to the guidance of the dome 55, an extended The front part 45c 'of the valve body 45c is supported by the correspondingly designed nozzle body 56c'.
- FIGS. 15a In the starting position
- 15b In the closed position
- the closure device 61 of the dispenser head 60 consisting of an upper part 70 and a lower part 71 has, just like the dispenser head 40 of FIG. 12, in a valve housing 64 a valve body 65 with a double wall 72 which is elastic in its rear region 66 as a reset body Double wall 72, which is open towards and oppositely closed, can be filled with the product to be discharged through a lower opening 73 and forms part of the discharge channel 62.
- valve body 65 In the starting position of the dispenser head 60, the valve body 65 is manually guided and locked with its rear end 72 ′ against a projecting rib 69 ′ of a fixed web 69 of the lower part 71, the valve head 67 being pressed against the discharge opening 63 from the inside and at the same time being elastic trained area 66 is compressed.
- the web 69 with its projecting rib 69 ' is arranged in such a way that the valve body 65 is rotated out of this lock by the circular tilting movement of the upper part 70 by the manual actuation of the button 77 during the dispensing process.
- valve body 65 which is released towards the rear, is pulled in the direction of the web 69 (to the right in the drawing) by the pressure exerted by the product on the rear wall of the double wall 72 and by the elastic springback of the compressed area 66, and the product can move in the direction of the arrow 79 emerge from the dispenser head 60.
- the re-opening of the discharge opening 63 by the valve head 67 after the dispensing process has ended is then accomplished by the upper part 70 being rotated backwards, through which the rear end 72 'of the valve body 65 goes upwards and at the same time forwards (in the Drawing to the left) is pushed and thereby presses the valve head 67 from the inside against the discharge opening 63.
- the elastic region 66 of the double wall 72 is compressed again.
- the restoring force of the upper part for producing the starting position is sufficiently large to be able to pull the end 72 'of the valve body 65 over the oblique shoulder 74 of the rib 69'.
- annular beads 66 ′, 66 ′′ are arranged on the elastic region 66 of the double wall 72, which, in the same way as described for FIGS. 10 and 13, provide a seal between the Dispenser head 60 and the closure device 61 and lead to easier assembly.
- the invention is not only limited to the described exemplary embodiments with the dispenser heads shown there, but an identical or functionally identical closure device according to the invention can also be used in other commercially available dispenser heads for pressurized dispenser containers after a possibly necessary design adjustment.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Closures For Containers (AREA)
- Vacuum Packaging (AREA)
- Reciprocating Pumps (AREA)
- Nozzles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE20209616U | 2002-06-20 | ||
DE20209616U DE20209616U1 (en) | 2002-06-20 | 2002-06-20 | Dispenser head with shut-off valve |
PCT/EP2003/006373 WO2004000066A1 (en) | 2002-06-20 | 2003-06-17 | Dispenser head with a check valve |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1513426A1 true EP1513426A1 (en) | 2005-03-16 |
EP1513426B1 EP1513426B1 (en) | 2006-06-14 |
Family
ID=27675263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03760629A Revoked EP1513426B1 (en) | 2002-06-20 | 2003-06-17 | Dispenser head with a check valve |
Country Status (9)
Country | Link |
---|---|
US (1) | US7464839B2 (en) |
EP (1) | EP1513426B1 (en) |
JP (1) | JP4338635B2 (en) |
CN (1) | CN100464866C (en) |
AT (1) | ATE329504T1 (en) |
DE (2) | DE20209616U1 (en) |
EA (1) | EA005752B1 (en) |
ES (1) | ES2264004T3 (en) |
WO (1) | WO2004000066A1 (en) |
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2002
- 2002-06-20 DE DE20209616U patent/DE20209616U1/en not_active Expired - Lifetime
-
2003
- 2003-06-17 WO PCT/EP2003/006373 patent/WO2004000066A1/en active IP Right Grant
- 2003-06-17 EP EP03760629A patent/EP1513426B1/en not_active Revoked
- 2003-06-17 CN CNB038143143A patent/CN100464866C/en not_active Expired - Fee Related
- 2003-06-17 AT AT03760629T patent/ATE329504T1/en not_active IP Right Cessation
- 2003-06-17 DE DE50303849T patent/DE50303849D1/en not_active Revoked
- 2003-06-17 US US10/509,864 patent/US7464839B2/en not_active Expired - Fee Related
- 2003-06-17 JP JP2004514746A patent/JP4338635B2/en not_active Expired - Fee Related
- 2003-06-17 EA EA200401320A patent/EA005752B1/en not_active IP Right Cessation
- 2003-06-17 ES ES03760629T patent/ES2264004T3/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO2004000066A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2004000066A1 (en) | 2003-12-31 |
EA005752B1 (en) | 2005-06-30 |
ES2264004T3 (en) | 2006-12-16 |
US20050103811A1 (en) | 2005-05-19 |
DE20209616U1 (en) | 2003-07-31 |
ATE329504T1 (en) | 2006-07-15 |
JP4338635B2 (en) | 2009-10-07 |
US7464839B2 (en) | 2008-12-16 |
DE50303849D1 (en) | 2006-07-27 |
EP1513426B1 (en) | 2006-06-14 |
EA200401320A1 (en) | 2005-02-24 |
CN1662163A (en) | 2005-08-31 |
JP2005529741A (en) | 2005-10-06 |
CN100464866C (en) | 2009-03-04 |
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