EP1511886B1 - Benetzungseinrichtung und spinnanlage mit benetzungseinrichtung - Google Patents

Benetzungseinrichtung und spinnanlage mit benetzungseinrichtung Download PDF

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Publication number
EP1511886B1
EP1511886B1 EP03755084A EP03755084A EP1511886B1 EP 1511886 B1 EP1511886 B1 EP 1511886B1 EP 03755084 A EP03755084 A EP 03755084A EP 03755084 A EP03755084 A EP 03755084A EP 1511886 B1 EP1511886 B1 EP 1511886B1
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EP
European Patent Office
Prior art keywords
wetting
spinning
treatment medium
threads
wetting device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03755084A
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German (de)
English (en)
French (fr)
Other versions
EP1511886A1 (de
Inventor
Stefan Zikeli
Friedrich Ecker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LL Plant Engineering AG
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ZiAG Plant Engineering GmbH
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Publication of EP1511886A1 publication Critical patent/EP1511886A1/de
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/06Wet spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/12Stretch-spinning methods
    • D01D5/14Stretch-spinning methods with flowing liquid or gaseous stretching media, e.g. solution-blowing
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof

Definitions

  • the invention relates to a wetting device for installation in a spinning plant for the production of spun yarns, for example for spun yarns from a spinning solution containing water, cellulose and tertiary amine oxide, with a supply line for a treatment medium, with a built-in state between the spun yarns and the supply line to a Guide wall arranged for the treatment medium at least partially permeable wetting area along which the filaments in the installed state feasible and through which the filaments are wetted with the treatment medium
  • the spinning solution is passed through a field of extrusion orifices and extruded into the filaments.
  • a gas line usually in the form of an air gap, in which the freshly extruded filaments are drawn, which leads to alignment of the molecules and solidification of the filaments and to a desired filament diameter.
  • the filaments in the air gap are blown with a gas to cool and solidify their surface to reduce surface tackiness. Due to the reduced surface tackiness, the spun yarns no longer tend to form clumps and the susceptibility to failure of the spinning process is reduced. Accordingly, the spinning security increases.
  • the extruded spinning solution - already in the form of filaments - passed through a cellulose precipitating treatment medium such as water. Under the action of the treatment medium, the filaments coagulate and harden.
  • the treatment medium is accommodated in a spinning bath container through which the spun yarns pass be directed.
  • a spinning bath container through which the spun yarns pass be directed.
  • Such devices are for example from the WO 96/20300 and the DE 100 37 923 known. If the extrusion openings are arranged on a circular ring surface or a circular surface, then the spin bath containers can also be used as funnels be designed as the devices of the WO 94/28218 , of the DE 44 09 609 and the WO 01/68958 ,
  • the filaments are passed through a funnel filled with a treatment medium.
  • the filaments come through an outlet opening, wherein inevitably a part of the treatment medium flows out with.
  • the spinning performance is also narrow limits: To make the spinning process more economical, the number of spun yarns passed through the spinning funnel must be increased. This has the consequence that the spinning funnel extended and the outlet opening must be increased. Due to the extended spin funnel, the static pressure in the treatment medium at the outlet opening increases, which leads to high outflow rates at the outlet opening. Due to the additionally enlarged diameter of the outlet opening disproportionately more treatment medium flows out, the turbulence in the spinning cone becomes stronger and more treatment medium has to be circulated.
  • the filaments are passed through a film of treatment medium, which runs down along an inclined surface of a spin bath container formed as an overflow container.
  • a spinning guide in which a liquid flows out of peripheral discharge openings.
  • the spin guide serves to deflect a gel fiber.
  • the liquid passes between the gel fiber and the surface of the spinning guide, so that each filament is carried by the flow from the openings.
  • the spinline is completely immersed in a precipitation bath.
  • the invention is therefore based on the object to improve the known spinning plants so that the efficiency of the process is increased by increasing the spinning speed and a reduced need for treatment medium while improving the control of the precipitation process.
  • This object is achieved for a wetting device described above in that the wetting area is made of a porous material.
  • the wetting device according to the invention can also be used as a retrofit kit of existing spinning plants.
  • the solution according to the invention is therefore to guide the wetting medium through the guide wall to the filaments.
  • This solution which is quite simple in itself, surprisingly results in not only a good wetting of the filaments with the treatment medium, but also a considerably reduced friction between the filaments and the guide wall compared with the known wetting devices, since the treatment medium is pressed between the filaments and the guide wall and a friction-reducing effect Slip layer between the spun threads and the guide wall is formed. This sliding layer reduces the mechanical stress on the filaments and the susceptibility to failure of the spinning process. Due to the reduced friction, the transport speed of the spun yarns can be increased without affecting the spinning safety.
  • Suitable materials for the guide wall porous materials can be considered, which are constructed in developments of several layers of materials of different porosity.
  • Such porous materials may be sintered materials or materials constructed of woven or knitted or nonwoven fabrics.
  • the guide wall at least in the wetting region micro-pockets form, where the entrained with the spun yarns treatment medium is aufstaubar in operation between the spun yarns and the wetting area, so that the sliding layer gets thicker.
  • micro-pockets may be configured in the form of longitudinal grooves which extend transversely to the transport speed of the spun threads, or in the form of regularly or irregularly arranged recesses, similar to the surface of a golf ball.
  • a mesh or lattice-like surface structure also facilitates the formation of a sliding layer.
  • the supply of the treatment medium to the wetting area is particularly simple in construction if the guide wall is formed on a substantially hollow cylindrical body, through which the treatment medium can be supplied to the wetting area during operation.
  • the guide wall is thus part of the supply line of the treatment medium in this advantageous embodiment.
  • the hollow cylindrical body can be configured essentially cylindrical.
  • the wetting device can have at least one bearing, by means of which the body forming the guide wall can be attached rotatably to the spinning system.
  • the guide wall is formed along a substantially rotationally symmetrical body.
  • the permeable areas for the treatment medium may extend over the entire circumference or be divided into individual, circumferentially spaced areas.
  • the wetting device may have a rotation means by which the rotational movement of the guide wall can be influenced.
  • a rotation means may for example be a motor, for example an electric motor, or a brake.
  • the guide wall can be driven in the direction of the spun yarns or against the direction of the spun yarns, so that the wetting device additionally serves as a drawing means, through which a tensile force in the spun yarns upstream - for example, with a rotation of the guide wall at a speed greater than that Transport speed of the filaments - or downstream - for example, in a rotation at a speed less than or opposite to the transport speed of the filaments - in the filaments can be introduced.
  • the wetting device according to the invention can also be used simultaneously as a deflecting member, by means of which the transport direction of the filaments is changed.
  • the wetting surface can be designed to be curved, in particular in the transport direction of the filaments.
  • a plurality of wetting devices, at least two, in the transport direction of the spun yarns can be designed one behind the other.
  • each treatment device By connecting several wetting stages in series, a targeted and gentle coagulation of the filaments can be achieved over several stages.
  • This partial precipitation at each treatment device can be positively influenced once again by the fact that each wetting device is supplied with a different treatment medium, for example treatment media having different concentrations.
  • the successive wetting devices can be supplied in an advantageous development in series with the treatment medium.
  • a plurality of wetting devices with rotatably mounted bodies forming the guide wall can be arranged one behind the other. In this way, not only a multi-stage precipitation, but also a multi-stage stretching can be achieved.
  • a wetting device with a rotatably mounted body and a wetting device with a fixed guide wall can alternate.
  • the tensile stress in the spun yarns and thus the degree of stretching is generated by the rotational speed of the rotatably mounted body and by the frictional resistance of the spun yarns on the stationary guide wall.
  • the mechanical properties of the filaments can be decisively improved in this way compared to conventional wetting devices, without the spinning speed having to be reduced and thus the cost-effectiveness of producing the filaments suffers.
  • the wetting device according to the invention which can be used instead of a spinning bath container, can be used in a more versatile manner and at the same time can serve as a deflecting element and / or drawing agent.
  • the filaments 6 are produced by the Lyocell process from a spinning solution containing water, cellulose and tertiary amine oxide.
  • the three process steps typical of the lyocell process are carried out, namely the extrusion of spinning solution 5 into filaments 6, the subsequent stretching of the extruded filaments 6 in a gas line 7 and the wetting of the drawn filaments 6 with a treatment medium, such as Water, to precipitate and solidify the filaments.
  • a treatment medium such as Water
  • the hiding of the spun yarns 6 in the gas line 7 can be done in a non-mechanical manner, for example, by the air flowing axially through the spun yarns whose speed is greater than the transport speed T of the spun yarns 6, or mechanically by a deduction mechanism 10, through which the spun yarns 6 deducted become.
  • the take-off unit 10 may have motor-driven rollers.
  • a blowing of the filaments 6 take place substantially transversely to the transport direction T of the filaments.
  • a blowing device 11 is used which directs a preferably turbulent gas flow onto the spun yarns 6.
  • the wetting of the drawn filaments 6 with treatment fluid 8 can, as shown in FIG. 1, be effected by a wetting device 9 according to the invention, in which a guide wall 12 between a supply line 13, through which the treatment medium 8 is fed to the wetting device 9, and the filaments 6 is arranged.
  • a wetting region 14 is provided, which is shown in Fig. 1 with a double-dot chain line.
  • the wetting area 14 is at least partially permeable to the treatment medium, such that the treatment medium 8 led through the supply line 13 emerges from the guide wall 12 in the wetting area 14 and wets the spun yarns 6 conducted along the guide wall.
  • the treatment medium 8 is pressed from the filaments 8, so that it drips or flows into a collecting device 15.
  • the treatment medium 8 is supplied via discharges 16 reprocessing steps, which are not shown in Fig. 1. After the reprocessing, the spent treatment medium 8 can be returned to the wetting device 9.
  • the embodiment of a wetting device 9 according to the invention shown by way of example in FIG. 1 is used instead of the spinning bath container and completely replaces it.
  • the spun yarns 6 are in the wetting region 14 on the guide wall 12, preferably between the spun yarns and the wetting region 14 is a sliding film of treatment medium 8.
  • FIGS. 2 to 5 further embodiments of the guide wall 12 comprising the body will be described.
  • the embodiments of FIGS. 2 to 5 are shown in a cross section along the plane E of FIG. 1.
  • the guide wall 12 forming the wetting area 14 is formed as a substantially planar and / or as a wall slightly curving perpendicular to the plane of the drawing. A deflection of the transport direction T of the spun yarns 6 therefore takes place in the wetting devices 9 of FIGS. 2 and 3 by means of a subsequently arranged deflecting member 17 or by the take-off mechanism 10 known from FIG.
  • the guide wall 12 forming body 18 is formed as a filled with treatment fluid, open channel. Solely by the static pressure of the treatment medium 8, this is pressed by a permeable for the treatment medium portion 19 of the wetting region 14 on the side of the filaments 6, where they are wetted by the treatment medium.
  • the region 19 may comprise the entire wetting region 14 or only parts thereof.
  • the body 18 of the wetting device 9 is configured substantially hollow-cylindrical, wherein the treatment medium 8 is guided in the interior of the hollow cylindrical body 18. In this closed embodiment of the body 18, the treatment medium 8 can be pressurized, so that a pressure-controllable amount of treatment medium 8 is forced through the porous area of the wetting area 14.
  • the entire wetting region 14 is designed to be permeable to the treatment medium. Since in the exemplary embodiment of FIG. 3 the guide wall 12 is also essentially straight in the transport direction T of the spun yarns, a deflection of the spun yarns must be effected by a downstream deflecting element 17 or a downstream take-off unit 10.
  • a downstream deflection member 17 can be omitted if the guide wall 12 is curved in the transport direction T of the spun yarns 6.
  • any desired deflection angle ⁇ can be achieved.
  • the deflection angle ⁇ results essentially from the degree of wrap of the body 18 through the filaments 6.
  • the straight guide wall 12 is replaced according to the embodiment of FIG. 3 by a curved in the transport direction T guide wall 12.
  • a plurality of separate regions 19 permeable to the treatment medium are provided in the wetting region 14, preferably at the points where, owing to the deflection of the spun threads 6 about the deflection angle ⁇ , a high contact pressure of the spun threads against the guide wall 12 prevails. Due to the treatment medium emerging under pressure in these areas, a strong friction between the spun yarns 6 and the guide wall 12 is avoided in these embodiments in these critical areas.
  • FIG. 1 A further embodiment of a wetting device 9 according to the invention, which additionally serves as a deflecting element at the same time, is shown in FIG.
  • the body 18 of this embodiment is also hollow cylindrical, in particular as a tube formed with at least in the wetting area 14 throughout for the treatment medium permeable wall.
  • the interior of the tubular body 18 is acted upon with treatment medium 8.
  • the treatment medium emerges over the entire circumference of the body 18.
  • a sliding layer 20 between the spun yarns 6 and the guide wall 12 is shown schematically in Fig. 6A, which shows the detail VI of Fig. 5 enlarged.
  • the pressurized treatment medium 8 is pressed along the arrows 21 through the treatment medium permeable areas 18 of the guide wall 12 into the wetting area 14 between the spun yarns 6 and the guide wall 12. Because the filaments are transported past the guide wall 12 as a dense, planar curtain, they provide great resistance to flow through the treatment medium. Consequently, only a small part of the treatment medium 8 passes through the filaments 6, the greater part of the filaments is entrained with the formation of the sliding layer 20 with the filaments 6.
  • FIG. 6A shows, by way of example only, that the area 19 of the guide wall 12 that is permeable to the treatment medium has a uniform structure over the entire thickness of the material.
  • the guide wall 12 can also have a multi-layered construction.
  • the area 19 which is permeable to the treatment medium can be constructed from a plurality of permeable layers 19 ', 19 ", 19"',.... These individual layers can be constructed differently, for example once as a woven or knitted fabric layer other than a nonwoven layer, and provided with different permeabilities.
  • various sintered layers or a one-piece construction of a sintered guide wall 12 is possible.
  • the formation of the sliding layer 20 can be facilitated by various measures. Examples of such measures are shown in Figures 7A and 7B, in which the detail VII of Fig. 6A is shown enlarged.
  • micro-pockets 22 are designated areas in which the surface increases in relation to the environment in the transport direction T, so that a kind of depression or "pocket" is formed in front of this elevated area. At these pockets, the pressure in the treatment medium increases due to the backlog.
  • the micro-pockets may be arranged randomly or regularly distributed on the surface of the guide wall 12 and may have heights of the micro-pockets between 20 and 150 microns.
  • the micro-pockets 22 can also be formed by a net-like surface structure, or, as shown in FIG. 7B, by longitudinal grooves which extend substantially transversely to the transport direction T of the spun yarns 6.
  • Fig. 8 is a schematic representation similar to the representation of Fig. 1, wherein, however, the wetting device 9 has a substantially cylindrical or tubular body 18, which also serves as a deflecting member 10.
  • the body 18 is rotatably supported by schematically illustrated bearings 24 on the spinning unit 1, so that the guide wall 12 may have a rotational speed. If the body 18 can rotate freely, then the friction can be minimized by the rotatable mounting again.
  • the body 18 of the embodiment of FIG. 8 can be influenced in its rotation by an optional drive means 25, for example braked or accelerated with respect to the transport speed of the spun yarns. Via the drive means 25, a tensile force can be introduced into the spun yarns 6 in the region upstream or downstream of the wetting device 9 in this way.
  • the wetting device 9 can be used in a dual function as delay means.
  • the guide wall 12 is provided in the wetting region 14 with circumferentially spaced, over the wetting region 14 axially extending portions 19 which are permeable to the treatment medium 8.
  • FIG. 9 shows a spinning system 1 in which a wetting device 9 according to the invention is rotationally driven in the direction indicated by the arrow 26.
  • the wetting device 9 serves at this point both for wetting the filaments and for drawing the filaments in the gas line 7 immediately after the extrusion.
  • the filaments 6 are deflected by the wetting device 9.
  • the spun yarns 6 are kept largely tension-free in a region 28 for through coagulation by a roller work 27 rotating counter to the transport direction T of the spun yarns 6.
  • the region 28 is followed by a region 29 with greater delay.
  • a further wetting device 9 according to the invention is arranged, which rotates passively with the spun yarns 6 or is rotatably driven in their direction.
  • the delay is determined by the speed difference between the roller mechanism 27 and a take-off unit 10 arranged behind the second wetting device 9.
  • the wetting device 9, which immediately adjoins the gas line 7, serves at the same time again as a deflecting element and drafting means and as a replacement for the spinning bath container.
  • the wetting device 9 is provided with a further roller 30, the structure of which may correspond to one of the embodiments described above, but which may also be configured only as a conventional pressure roller.
  • the filaments 6 are subjected to a first treatment medium 8.
  • a second treatment medium is supplied from the treatment medium supplied in the first wetting device 9.
  • further wetting devices 9, to which different treatment media are supplied may be provided. Adapted to the different treatment media can also be adjusted between the individual wetting devices of the respective delay, as already explained in FIG. 9.
  • a plurality of wetting devices 9 connected in series can also be supplied via a line system 31 in series with the same treatment fluid.
  • the bodies 18 of the wetting device 9 are each successively flowed through by the treatment medium 8.
  • the spinning process was carried out using the process steps known from the prior art.
  • the spinning plant used here comprised an extrusion head with extrusion openings arranged on a rectangular area in five rows of perforations with a hole density of 0.25 / mm 2 .
  • the zero shear viscosity of the spinning solution was 17,000 Pas with a cellulose DP of 700 and a concentration of 13.5% cellulose, 10.5% water, 76% amine oxide.
  • the essentially alkaline spinning solution was added to the stabilizer propyl gallate for thermal stabilization of the cellulose and the solvent.
  • the spun filament tow was 1.42 dtex.
  • the spun yarns, after extrusion, were passed through a gas gap (air gap) of 60 mm length where they were blown.
  • the filaments were passed into a bath of treatment medium and was deflected there by a deflection.
  • the deflection angle ⁇ was 55 °.
  • the filaments were drawn off at a take-off speed of 200 m / min.
  • Comparative Example 2 the bath of treatment medium by a wetting device according to the invention, which also served as a deflecting replaced.
  • the body 18 of the wetting device consisted of a tube filter made of stainless steel with a porosity, i. an average pore or opening size of 2 ⁇ m.
  • Comparative Example 3 an extrusion head with only one row of holes was used. Further, in contrast to Comparative Examples 1 and 2, blowing off in the gas train was omitted, and the gas train was shortened to 50 mm, and the spinning speed was set to 350 m / min.
  • a wetting device according to the invention was used, which also served as a deflecting member with a deflection angle of 65 °.
  • the body of the wetting device was a polyethylene tube filter having a porosity of 20 ⁇ m.
  • Comparative Example 4 a wetting device according to the invention was again used, wherein the body 18 of the wetting device from a tubular membrane with a porosity of 0.2 microns was used.
  • Comparative Example 5 a spinning system known from the prior art was used with a 10 times increased hole density and 32 rows of holes compared to Comparative Examples 1 to 4.
  • the length of the air gap traversed by the filaments after extrusion was reduced to 22 mm, with blowing in the air gap.
  • the take-off speed was reduced to 60 m / min because of the high spinning density.
  • Comparative Example 6 the bath of treatment medium by a wetting device according to the invention, which also served as a deflecting replaced.
  • a stainless steel tube filter having a porosity of 2 ⁇ m was used as the body 18 of the wetting device.
  • the take-off speed was increased compared to Experimental Example 5 to 70 m / min.
  • a two-stage precipitation is carried out by means of two wetting devices according to the invention arranged one behind the other in the transport direction of the spun yarns.
  • the treatment medium fed in Experiment Examples 7 and 8 in the first wetting device had a spinning bath concentration of 50%, in the subsequent second wetting device the spinning bath concentration in the treatment medium supplied there was reduced to 20%.
  • the deflection angle in the first wetting device was 55 ° in the experimental examples 7 and 8 and 170 ° in the second wetting device.
  • the wetting device according to the invention allows a significantly improved variability of the process control than the devices known from the prior art.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Spinning Or Twisting Of Yarns (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Inorganic Fibers (AREA)
  • Manufacturing Of Printed Wiring (AREA)
EP03755084A 2002-05-24 2003-03-20 Benetzungseinrichtung und spinnanlage mit benetzungseinrichtung Expired - Lifetime EP1511886B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10223268A DE10223268B4 (de) 2002-05-24 2002-05-24 Benetzungseinrichtung und Spinnanlage mit Benetzungseinrichtung
DE10223268 2002-05-24
PCT/EP2003/002946 WO2003100140A1 (de) 2002-05-24 2003-03-20 Benetzungseinrichtung und spinnanlage mit benetzungseinrichtung

Publications (2)

Publication Number Publication Date
EP1511886A1 EP1511886A1 (de) 2005-03-09
EP1511886B1 true EP1511886B1 (de) 2007-07-25

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Country Status (11)

Country Link
US (1) US20060055078A1 (ko)
EP (1) EP1511886B1 (ko)
KR (1) KR100686322B1 (ko)
CN (1) CN1329564C (ko)
AT (1) ATE368139T1 (ko)
AU (1) AU2003226683A1 (ko)
BR (1) BR0311294A (ko)
DE (2) DE10223268B4 (ko)
TW (1) TWI237071B (ko)
WO (1) WO2003100140A1 (ko)
ZA (1) ZA200409443B (ko)

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DE10204381A1 (de) 2002-01-28 2003-08-07 Zimmer Ag Ergonomische Spinnanlage
DE10206089A1 (de) 2002-02-13 2002-08-14 Zimmer Ag Bersteinsatz
DE10213007A1 (de) * 2002-03-22 2003-10-09 Zimmer Ag Verfahren und Vorrichtung zur Regelung des Raumklimas bei einem Spinnprozess
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DE102004024028B4 (de) * 2004-05-13 2010-04-08 Lenzing Ag Lyocell-Verfahren und -Vorrichtung mit Presswasserrückführung
DE102004024030A1 (de) 2004-05-13 2005-12-08 Zimmer Ag Lyocell-Verfahren mit polymerisationsgradabhängiger Einstellung der Verarbeitungsdauer
KR20070061826A (ko) * 2004-09-17 2007-06-14 빌라 리서어치 인스티튜트 포어 어플라이드 사이언시즈 부직 셀룰로즈 구조물을 제조하는 방법 및 이 방법으로제조한 부직 셀룰로즈 구조물
DE102005040000B4 (de) * 2005-08-23 2010-04-01 Lenzing Ag Mehrfachspinndüsenanordnung und Verfahren mit Absaugung und Beblasung
EP2405047A1 (en) * 2010-07-09 2012-01-11 Siemens Aktiengesellschaft Arrangement and method for wetting fibers with a fluid
CN103225188B (zh) * 2013-03-22 2015-05-06 诚瑞琛泵厂 纺织品的湿润装置
EP3505659A1 (de) * 2018-08-30 2019-07-03 Aurotec GmbH Verfahren und vorrichtung zum filamentspinnen mit umlenkung

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DE10223268A1 (de) 2003-01-16
CN1329564C (zh) 2007-08-01
ZA200409443B (en) 2006-06-28
TWI237071B (en) 2005-08-01
AU2003226683A1 (en) 2003-12-12
KR20050016433A (ko) 2005-02-21
EP1511886A1 (de) 2005-03-09
KR100686322B1 (ko) 2007-02-22
DE50307771D1 (de) 2007-09-06
DE10223268B4 (de) 2006-06-01
TW200404925A (en) 2004-04-01
WO2003100140A1 (de) 2003-12-04
BR0311294A (pt) 2005-02-22
ATE368139T1 (de) 2007-08-15
CN1656259A (zh) 2005-08-17
US20060055078A1 (en) 2006-03-16

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