EP1500499B1 - Method and means for measuring and controlling the concentration of chemical substances in process liquids for offset printing - Google Patents
Method and means for measuring and controlling the concentration of chemical substances in process liquids for offset printing Download PDFInfo
- Publication number
- EP1500499B1 EP1500499B1 EP04017479.9A EP04017479A EP1500499B1 EP 1500499 B1 EP1500499 B1 EP 1500499B1 EP 04017479 A EP04017479 A EP 04017479A EP 1500499 B1 EP1500499 B1 EP 1500499B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- individual
- accordance
- fountain solution
- components
- chemical components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 63
- 239000000126 substance Substances 0.000 title claims description 52
- 239000007788 liquid Substances 0.000 title claims description 18
- 238000007645 offset printing Methods 0.000 title claims description 14
- 230000008569 process Effects 0.000 title description 41
- 239000000654 additive Substances 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 238000005259 measurement Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 8
- 230000003068 static effect Effects 0.000 claims description 6
- 230000005670 electromagnetic radiation Effects 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims 3
- 238000012544 monitoring process Methods 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 238000007639 printing Methods 0.000 description 39
- 230000000996 additive effect Effects 0.000 description 25
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- 239000002904 solvent Substances 0.000 description 6
- 239000012530 fluid Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F7/00—Rotary lithographic machines
- B41F7/20—Details
- B41F7/24—Damping devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F33/00—Indicating, counting, warning, control or safety devices
- B41F33/0054—Devices for controlling dampening
Definitions
- the respective printing plate is wetted by a so-called dampening unit with an aqueous liquid in order to achieve that in a subsequent process step, the image areas assume the color, while the non-image areas behave ink repellent.
- the aqueous liquid often consists of a mixture with alcohol, usually isopropanol, and a chemical mixture of up to about twenty substances, which is referred to below as an additive.
- the additive is used in concentrations of 1 to 8% vol., The alcohol of 0.5 to 20% vol. added. The concentration of water is therefore between 72% and 98.5% - Vol.
- Using optimized additives is the Part completely renounced the alcohol. In this case, the additive is also referred to as an alcohol substitute.
- the optimized additive then takes full or at least partially the function of isopropanol.
- a major problem of offset printing is the insufficient availability of the process, which is typically around 80% and therefore characterized by high downtime of very investment intensive printing presses. For example, with a so-called 64-page offset rotary printing line, you would save around 35,000 EUR per year if the. pure production time per day could be extended on average by just two minutes. Recent, intensive practical investigations have clearly shown that the too low availability of offset printing presses is due in large part to an undefined, unknown and so far not measurable in the process and therefore in particular not controllable physical and chemical composition of the process liquid.
- the concentrations of alcohol in the fountain solution are currently usually between 6% and 20% and facilitate in the case of roll and sheet offset the use of so-called film dampening.
- the latter consist of several rollers coated with rubber mixtures and / or metals, which rotate with a certain pressure in contact with each other and the fountain solution in the form of a film adjustable Transport the layer thickness to the printing plate. This transport process is promoted by the addition of isopropanol due to the resulting reduction in the surface tension of the liquid film.
- contactless systems in particular jet-operated spray dampening units or dampening units, which have rolls with covers made of plush.
- the new method according to the invention is of utmost importance, since it allows an optimal composition of the chemicals of the fountain solution.
- surfactants are not VOCs.
- surfactants lead to undesirable foaming and to quality-reducing emulsification of paint and fountain solution, so that In many practical cases, the non-alcoholic printing fails and must be replaced again by printing with alcohol.
- the difficulty arises that surfactants are very often difficult to dissolve in a chemical multicomponent mixture, so that in addition substances must be introduced as solvent mediators in the additive concentrate to a separation, ie settling on the bottom of the additive - barrel of the supplier to prevent.
- This difficulty is also easily solved by the method according to the invention. It offers the possibility of using only those chemical components that are absolutely necessary for the printing process. Since the web speeds of modern printing presses are constantly being increased and the latter requires increasingly precise measurement and metering of the individual chemical components, the new process for printing without alcohol is indispensable.
- the composition of the individual components of the additive depends on the print job, ie on the currently used paper, on the special colors required by the specific customer, on the specially used blanket, roll coating, etc.
- the aim of the present invention is therefore, by continuous measurement and control of the composition of the fountain solution, ie by continuous subsequent addition of the individual differently depleted chemical components or selected groups of components to readjust the respective setpoints to the availability of the offset printing process on values of competing Low pressure, ie to increase to about 90 to 95%.
- JP-A-4327940 is provided to carry out the control of the concentrations of individual components in the fountain solution of offset printing machines by measuring the pH, conductance, refractive index, specific gravity and gas concentration and make a re-dosing of the respective component via pumps over a specific period, if the concentration value is not within a range between an upper and lower limit.
- the stated measuring principles are not selective or a significant number of substances are not sufficient.
- a method and a device are used for the first time in printing technology, which continuously measure the concentrations of the individual components of the additive on the basis of selective weakening of electromagnetic radiation and regulate them to predetermined optimal values. In this case, it is prevented that the process fluid suffers in particular a depletion but also an overdose of individual components of the additive, so that the printing process can be continued continuously with high stability and availability at the optimum operating point.
- the method not only works in alcohol-free printing, ie substitutes, but that the selectivity of the measurement and control of the additive can be maintained even when printing with additional admixture of alcohol, ie the alcohol no falsification of the measurement of the concentrations of the individual components of the additive caused.
- the selective measurement of the concentrations of the individual components or of groups of different chemical compounds is coupled to a dosing system which removes the various components from different containers via a system consisting of cycled valves and pumps and feeds them to the dampening water.
- the pressure without alcohol is thereby placed for the first time on a basis, which allows a long-term process while fulfilling the boundary conditions of economy.
- the too narrow window of the variations of the concentrations of the chemical components of ready-to-use additives supplied by the new method is arbitrarily extended, so that constant fountain solution , Especially by the already mentioned search for better fountain solution - additives in several hours of shutdowns of the printing process and corresponding negative consequences for the disposal of previously operated fountain solution and thus also for the efficiency of the printing process, omitted by the new process.
- dosing devices are used to volumetrically mix the two or three components under fixed conditions as part of a control and into the fluid circuit of the printing press according to the respective consumption, ie according to the removal of the liquid through the paper to be printed, feed.
- systems with conventional metering pumps are currently being used in particular.
- a major disadvantage of these systems is that neither malfunctions of the mixing devices Changes in the physical and / or chemical composition, for example as a result of chemical reactions or of absorption or desorption processes by the printing ink, the paper, through the pipeline or the machine modules, can be detected.
- evaporation processes in these classic dosing methods lead to considerable concentration errors.
- the aim of the present invention is therefore a method and an apparatus for implementing the method, which comprises a quantitative, continuous measurement and control of the concentrations of the individual components of the respective additive or the substitute in a matrix of up to 20 chemical components without faulty influence by other substances , as in particular by alcohols, dirt, color and paper particles, gas bubbles, salts from the paper coating and other impurities typical for offset printing, allow.
- the This problem has not yet been solved in all practical cases.
- our scientific studies have shown above all that the various chemical ingredients of a statically predetermined additive mixture are not consumed in proportion to the concentration
- the mixture changes in the course of the printing process, since both the colors, as well as the paper, as well as other effects cause a more or less selective depletion of the individual components.
- the present invention solves the tasks set, inter alia, that the chemical components are continuously measured and the dampening solution controlled as pure raw materials and / or as partial mixtures of several components usually in mixtures with water, fed so that they are simply in the fountain solve and in particular do not form separate phases.
- chemical formulations can be realized which separate in a prefabricated additive concentrate and therefore would not lead to a homogeneous solution.
- concentration the weakening of electromagnetic radiation is used in the passage through the dampening water according to the invention.
- the according to Fig. 1 in a tank (1) located process fluid (2) is circulated by circulation pumps (3) to the printing machine (4) and back to the tank (1) via pipes (5).
- the respective concentrations of the individual chemical components of the additive are continuously measured by a measuring system (6).
- the predetermined chemical components K1, K2, K3, .... to Kn are fed into the process liquid (2) via pumps (7) and via valves (8).
- the respective different desired concentrations of the chemical components K1 to Kn are required guaranteed by the fact that the measuring system (6) continuously measures the actual concentrations and, in the context of a regulation, replenishes so much of the respective component, that the actual value is equal to the predetermined target value.
- the concentration of the alcohol is continuously measured, unless it is not alcohol-free, in the process liquid (2) and the Substantially alcohol lost by evaporation from a reservoir (13) via a unit consisting of valve and metering pump (14) fed so that even in the case of printing with alcohol target and actual value consistently match and ensures the availability and quality of the printing process are.
- an agitator (15) is used to homogenize the process liquid.
- Fig. 2 outlines the arrangement according to the invention consisting of printing press (16), fountain tank (17), fountain solution (18) with circulation (19) and the chemical components K1 to Kn (20), which via a venturi nozzle (21), and via a pump (22) is operated, the chemical components K1 to Kn via valves (23) sucks and fed into the dampening water (18), wherein the measurement of the concentrations of the chemical components via the measuring and control system (24).
- the make-up (25) of water with automatic level control and the agitator (26) correspond to the arrangements of Fig. 1 ,
- Fig. 3 is in the overall arrangement consisting of printing press (27), dampening water tank (28), fountain solution (29), measuring and control system (30), agitator (31), water feed (32) with Brown Bangnkontrolle (33) and dampening water circulation (34), as additional component realized a static mixer (35).
- the fountain solution (29) circulated via the pump (36) is mixed with the chemical components K1 to Kn (37), which are fed into the circuit (39) via the valves (38) in the static mixer (35) that both the measuring system (30) and the circuit (34) have homogeneous liquid mixtures with the aim that the overall system in Figure 3 works optimally.
- FIG. 12 illustrates a modified version of the invention compared to the preceding figures, characterized by a pre-mixing of the chemical components K1 to Kn (42) via pumps (50a) with a water supply (41) in a mixing vessel (40).
- a homogenizing device (39) is also used in the pre-mixing tank (40) analogously to the agitator (46) in the fountain solution tank.
- the latter can also according to Fig. 3 be a static mixer.
- Fig. 5 shows the simplest variant according to the invention, in which the chemical components K1 to Kn (51) via the measuring system (52) controlled, calibrated metering pumps (53) according to the respective target value of the individual component via a valve (54) are metered.
- the level measurement (55) and the stirrer (56), in combination with the water supply (57), permit a homogeneous mixture of the moist water (58), which is circulated through the circulating pump (59) in the circuit (60) between the printing machine (61) and dampening water cooling unit (62) circulates.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Inking, Control Or Cleaning Of Printing Machines (AREA)
- Printing Plates And Materials Therefor (AREA)
- Rotary Presses (AREA)
Description
Bei Offset-Druckmaschinen wird die jeweilige Druckplatte durch ein sogenanntes Feuchtwerk mit einer wässrigen Flüssigkeit benetzt, um zu erreichen, dass in einem nachfolgenden Prozeßschritt die Bildbereiche die Farbe annehmen, während die bildfreien Bereiche farbabweisend sich verhalten. Die wässrige Flüssigkeit besteht neben Wasser häufig aus einem Gemisch mit Alkohol, meist wird-Isopropanol verwendet, sowie einem chemischen Gemisch aus bis zu ca. zwanzig Substanzen, das im folgenden als Additiv bezeichnet wird. Das Additiv wird in Konzentrationen von 1 bis 8 % -Vol., der Alkohol von 0,5 bis 20 % -Vol. zugesetzt. Die Konzentration des Wassers liegt demnach zwischen 72% und 98,5 % - Vol. Unter Verwendung von optimierten Additiven wird zum Teil gänzlich auf den Alkohol verzichtet. In diesem Fall wird das Additiv auch als Alkohol-Ersatzstoff bezeichnet. Das optimierte Additiv übernimmt dann voll oder zumindest teilweise die Funktion von Isopropanol.In offset printing presses, the respective printing plate is wetted by a so-called dampening unit with an aqueous liquid in order to achieve that in a subsequent process step, the image areas assume the color, while the non-image areas behave ink repellent. In addition to water, the aqueous liquid often consists of a mixture with alcohol, usually isopropanol, and a chemical mixture of up to about twenty substances, which is referred to below as an additive. The additive is used in concentrations of 1 to 8% vol., The alcohol of 0.5 to 20% vol. added. The concentration of water is therefore between 72% and 98.5% - Vol. Using optimized additives is the Part completely renounced the alcohol. In this case, the additive is also referred to as an alcohol substitute. The optimized additive then takes full or at least partially the function of isopropanol.
Ein großes Problem des Offsetdrucks liegt in der unzureichenden Verfügbarkeit des Prozesses, die typisch bei ca. nur 80 % liegt und daher durch hohe Stillstandszeiten sehr investitionsintensiver Druckmaschinen gekennzeichnet ist. Beispielsweise würde man bei einer sog. 64-Seiten Offset-Rotationsdrucklinie pro Jahr ca. 35.000,-- EUR einsparen, wenn die. reine Produktionszeit pro Tag durchschnittlich um nur zwei Minuten verlängert werden könnte. Neue, intensive praktische Untersuchungen haben klar gezeigt, dass die zu niedrige Verfügbarkeit von Offset-Druckmaschinen zu einem wesentlichen Teil auf eine undefinierte, unbekannte und bisher nicht im Prozeß meßbare und daher insbesondere nicht regelbare physikalische und chemische Zusammensetzung der Prozeßflüssigkeit zurückzuführen ist. Im Rahmen dieser Untersuchungen wurde insbesondere und paradoxerweise festgestellt, dass selbst bei exakter Realisierung einer vorgegebenen volumetrischen Mischung der Komponenten Wasser und Additiv, z.B. durch eine exakte Steuerung von zwei Dosierpumpen, welche z.B. die Volumina 97 % - Vol. Wasser und 3 % - Vol. Additiv in die Prozeßflüssigkeit injizieren, im Kreislauf der Prozeßflüssigkeit ein viel niedrigerer Wert, z. B. 0,8 % - Vol. an Additiv, vorhanden ist. Noch viel erstaunlicher ist die Tatsache, dass Analysen ergaben, dass die ursprüngliche prozentuale Zusammensetzung der Einzelkomponenten des Additives im Feuchtwasserkreislauf nicht mit der ursprünglich beabsichtigten und von den Dosierpumpen durch eine Steuerung bei der Einspeisung realisierten Zusammensetzung übereinstimmen. Vielmehr treten von uns als "kannibalistische Effekte" bezeichnete Vorgänge auf, die darin bestehen, dass im Druckprozess die Bestandteile des Additivs mehr oder weniger stark verschwinden, obwohl in den beabsichtigten Konzentrationsverhältnissen periodisch zudosiert wird. Die derzeit standarmäßig im Offsetdruck eingeführte Technik, das Additiv-Konzentrat als eine einzige chemische Formulation, die aus allen notwendigen chemischen Bestandteilen mit definiert vorgegebenen Konzentrationen besteht und deren Zusammensetzung von der Druckapplikation, d.h. Rollenoffset, Bogenoffset oder Zeitungsdruck sowie vom Maschinentyp, Papiertyp, Farbtyp, abhängt, in den Feuchtwasserkreislauf einer Druckmaschine einzuspeisen, ist eine Notlösung, die den modernen Anforderungen an hohe Verfügbarkeit des Offsetproesses nicht gerecht wird. Auch wenn diese Nachteile beim Drucken mit Alkohol durch Zudosierung erhöhter Konzentrationen von Isopropanol zu einem gewissen Teil ausgeglichen werden können, was in der Praxis derzeit so gehandhabt wird, ist diese Vorgehensweise nicht als eine zukünftige technische Lösung zu betrachten, da Isopropanaol als Lösemittel und leicht flüchtiger Stoff (VOC = Volatile Organic Compound) im Offsetdruck in vielen Staaten der USA verboten, in Europa mit strengen Gesetzen zur Emissionbegrenzung und in der Schweiz sogar mit einer für die Wirtschaftlichkeit des Druckprozesses schädlichen Strafsteuer, der sog. "Lenkungsabgabe", belegt ist. Aus umweltpolitischen Gesichtspunkten und insbesondere auch zum Schutze der Gesundheit der Drucker am Arbeitsplatz, müssen daher Isopropanol oder andere Lösemittel in der Zukunft massiv reduziert bzw. letztendlich vollständig aus dem Druckprozess verschwinden. Die Konzentrationen von Alkohol im Feuchtwasser liegen in der Regel derzeit zwischen 6% und 20 % und erleichtern im Falle des Rollen- und des Bogen-Offset den Einsatz von sogenannten Filmfeuchtwerken. Gemäß dem Stand der Technik bestehen letztere aus mehreren mit Gummimischungen und/oder Metallen beschichteten Walzen, die mit einem gewissen Anpressdruck in Kontakt miteinander rotieren und das Feuchtwasser in Form eines Filmes einstellbarer Schichtdicke zur Druckplatte transportieren. Dieser Transportvorgang wird durch die Zugabe von Isopropanol infolge der dadurch bewirkten Reduktion der Oberflächenspannung des Flüssigkeitsfilmes begünstigt. Neben Filmfeuchtwerken gemäß dem Stand der Technik werden auch kontaktlos arbeitende Systeme, insbesondere mit Düsen betriebene Sprühfeuchtwerke oder Feuchtwerke, die Walzen mit Bezügen aus Plüsch aufweisen, eingesetzt. Da in diesen Fällen das Feuchtmittel ohne kontinuierlichen Flüssigkeitsfilm transportiert wird, kann der Einsatz von Alkohol entfallen. Auch bei diesen Ausführungen gemäß dem Stand der Technik ist das erfindungsgemäße neue Verfahren von größter Wichtigkeit, da es eine optimale Zusammensetzung der Chemikalien des Feuchtwassers ermöglicht.A major problem of offset printing is the insufficient availability of the process, which is typically around 80% and therefore characterized by high downtime of very investment intensive printing presses. For example, with a so-called 64-page offset rotary printing line, you would save around 35,000 EUR per year if the. pure production time per day could be extended on average by just two minutes. Recent, intensive practical investigations have clearly shown that the too low availability of offset printing presses is due in large part to an undefined, unknown and so far not measurable in the process and therefore in particular not controllable physical and chemical composition of the process liquid. In the context of these investigations, it was found, in particular and paradoxically, that even with exact realization of a given volumetric mixture of the components water and additive, eg by an exact control of two metering pumps, which eg the volumes 97% - Vol. Water and 3% - Vol. Inject additive into the process liquid, in the circulation of the process liquid a much lower value, eg. B. 0.8% - Vol. Of additive, is present. Even more surprising is the fact that analyzes have shown that the original percentage composition of the individual components of the additive in the fountain solution cycle does not match the composition originally intended and realized by the metering pumps by a feed control. Rather, what we call "cannibalistic effects" are processes that consist in the fact that in the printing process the constituents of the Additive more or less disappear, although in the intended concentration ratios is periodically added. The currently standard in offset printing technology, the additive concentrate as a single chemical formulation consisting of all the necessary chemical ingredients with defined concentrations specified and their composition of the print application, ie web offset, sheetfed offset or newsprint and machine type, paper type, color type, depends on feeding into the fountain solution circulation of a printing press, is an emergency solution that does not meet the modern requirements for high availability of the offset process. Although these disadvantages in printing with alcohol can be compensated to a certain extent by adding increased concentrations of isopropanol, which is currently the case in practice, this procedure should not be regarded as a future technical solution since isopropanol is a solvent and more volatile Offset printing is prohibited in many states in the USA, is subject to stringent emissions legislation in Europe, and is even punishable in Switzerland by a punitive tax, the so-called "steering levy", which is detrimental to the economic efficiency of the printing process. From an environmental point of view and especially to protect the health of the printer at the workplace, therefore, isopropanol or other solvents in the future massively reduced or ultimately disappear completely from the printing process. The concentrations of alcohol in the fountain solution are currently usually between 6% and 20% and facilitate in the case of roll and sheet offset the use of so-called film dampening. According to the prior art, the latter consist of several rollers coated with rubber mixtures and / or metals, which rotate with a certain pressure in contact with each other and the fountain solution in the form of a film adjustable Transport the layer thickness to the printing plate. This transport process is promoted by the addition of isopropanol due to the resulting reduction in the surface tension of the liquid film. In addition to state-of-the-art film dampening systems, it is also possible to use contactless systems, in particular jet-operated spray dampening units or dampening units, which have rolls with covers made of plush. Since in these cases the dampening solution is transported without a continuous liquid film, the use of alcohol can be omitted. Also in these embodiments according to the prior art, the new method according to the invention is of utmost importance, since it allows an optimal composition of the chemicals of the fountain solution.
Um den gesetzlichen Zwängen bezüglich der Vermeidung von Isopropanol nachzukommen, wurden inbesondere in den USA andere Lösemittel auf den Markt gebracht. Dieser Weg wurde jedoch in Europa nicht nachvollzogen, da dadurch keine Elemenierung von Lösemitteln erzielt wurde. Ferner gelten die anderen Lösemittel zum Teil als krebserregend bzw. als gesundheitsschädlich und stellen daher keine Alternative zum Alkohol dar.In order to comply with the legal requirements regarding the avoidance of isopropanol, other solvents have been brought to market, especially in the USA. However, this approach was not followed in Europe, as it did not result in the elimination of solvents. Furthermore, the other solvents are partly considered to be carcinogenic or detrimental to health and therefore do not represent an alternative to alcohol.
Eine echte Alternative zum Alkohol sind die sog. Tenside, welche vergleichbare Vorteile bezüglich den Benetzungseigenschaften des Feuchtwassers an den Walzen des Feuchtwerkes bewirken. Insbesondere ist festzustellen. dass Tenside keine VOC' s sind .Diese positiven Eigenschaften der Tenside können jedoch erfahrungsgemäß nur dann zum Tragen kommen, wenn die erforderlichen Soll Konzentrationen exakt eingehalten werden können. Bei den derzeit eingesetzten alkoholfreien Verfahren gemäß dem Stand der Technik, führen daher Tenside zu unerwünschtem Schäumen sowie zu qualitätsminderndem Emulgieren von Farbe und Feuchtwasser, so dass in vielen praktischen Fällen der alkoholfreie Druck versagt und wieder durch das Drucken mit Alkohol abgelöst werden muss. Hinzu kommt die Schwierigkeit, dass Tenside sich in einem chemischen Multikomponentengemisch sehr oft schwierig zu lösen sind, so dass zusätzlich Stoffe als Lösemittelvermittler in das Additiv - Konzentrat eingebracht werden müssen, um eine Entmischung, d.h. ein Absetzen auf dem Boden des Additiv - Fasses des Lieferanten zu verhindern. Auch diese Schwierigkeit wird durch das erfindungsgemäße Verfahren leicht gelöst. Es bietet nämlich die Möglichkeit, nur diejenigen chemischen Stoffkomponenten anzuwenden, die für den Druckprozess absolut notwendig sind. Da die Bahngeschwindigkeiten moderner Druckmaschinen laufend gesteigert werden und letzteres eine zunehmend präzisere Messung und Dosierung der chemischen Einzelkomponenten erfordert, ist das neue Verfahren für den Druck ohne Alkohol unverzichtbar. Unterstützend hinzu kommt, dass bei ein und derselben Druckmaschine , abhängig vom Druckauftrag, d.h. von dem aktuell verwendeten Papier, von den vom spezifischen Kunden verlangten Sonderfarben, von dem speziell verwendeten Gummituch, der Walzenbeschichtung, etc.,die Zusammen - setzung der Einzelkomponenten des Additivs veränderbar sein muss. Auch letzteres ist nur mit dem hier beschriebenen neuen Verfahren möglich. Dies wird insbesondere auch dadurch bewiesen, dass es bis heute kein einziges Additiv auf der Welt gibt, welches Drucken ohne Alkohol unter allen in einer Druckmaschine auftretenden Bedingungen ermöglicht. Letzteres erklärt, weshalb Druckereileiter immer wieder andere Additivformulationen testen wollen, um ihre Druckaufträge durchzuführen. Trotzdem muss festgestellt werden, dass jede chemische Formulierung einen Kompromiss darstellt und daher nur für eine beschränkte Skala von Druckaufträgen optimal ist. Insgesamt ist die derzeitige Vorgehensweise notgedrungen mit einem hohen finanziellen Aufwand verbunden, der trotz der oben genannten gesetzlichen Vorschriften in Europa, den Druck ohne Alkohol de facto unmöglich macht.A real alternative to alcohol are the so-called surfactants, which bring about comparable advantages with regard to the wetting properties of the dampening solution on the rollers of the dampening unit. In particular, it should be noted. surfactants are not VOCs. However, experience has shown that these positive properties of the surfactants can only be used if the required target concentrations can be exactly met. In the currently used alcohol-free processes according to the prior art, therefore, surfactants lead to undesirable foaming and to quality-reducing emulsification of paint and fountain solution, so that In many practical cases, the non-alcoholic printing fails and must be replaced again by printing with alcohol. In addition, the difficulty arises that surfactants are very often difficult to dissolve in a chemical multicomponent mixture, so that in addition substances must be introduced as solvent mediators in the additive concentrate to a separation, ie settling on the bottom of the additive - barrel of the supplier to prevent. This difficulty is also easily solved by the method according to the invention. It offers the possibility of using only those chemical components that are absolutely necessary for the printing process. Since the web speeds of modern printing presses are constantly being increased and the latter requires increasingly precise measurement and metering of the individual chemical components, the new process for printing without alcohol is indispensable. In addition, the composition of the individual components of the additive depends on the print job, ie on the currently used paper, on the special colors required by the specific customer, on the specially used blanket, roll coating, etc. must be changeable. The latter is possible only with the new method described here. This is especially proven by the fact that to date there is not a single additive in the world which allows printing without alcohol under all conditions encountered in a printing press. The latter explains why print shop managers always want to test other additive formulations to run their print jobs. Nevertheless, it has to be stated that every chemical formulation is a compromise and therefore only optimal for a limited range of print jobs. Overall, the current approach is inevitably associated with a high financial outlay, despite the above-mentioned legal requirements in Europe, which makes pressure without alcohol de facto impossible.
Ziel der vorliegenden Erfindung ist daher, durch kontinuierliche Messung und Regelung der Zusammensetzung des Feuchtwassers, d.h. durch kontinuierliche Nachdosierung der einzelnen unterschiedlich verarmenden chemischen Komponenten bzw. ausgewählter Gruppen von Komponenten auf die jeweiligen Sollwerte nachzuregeln, um die Verfügbarkeit des Offset-Druckprozesses auf Werte des konkurrierenden Tiefdrucks, d.h. auf etwa 90 bis 95 %, zu erhöhen. Gemäß dem Stand der Technik aus
Gemäß dem derzeitigen Stand der Technik werden zur Herstellung der Prozeßflüssigkeit Dosiereinrichtungen verwendet, die volumetrisch im Rahmen einer Steuerung die zwei bzw. drei Komponenten unter fest vorgegebenen Verhältnissen mischen und in den Flüssigkeitskreislauf der Druckmaschine entsprechend dem jeweiligen Verbrauch, d.h. gemäß dem Abtransport der Flüssigkeit durch das zu bedruckende Papier, einspeisen. Neben Mischstationen, die von Hand bedient werden, sind derzeit insbesondere Systeme mit herkömmlichen Dosierpumpen im Einsatz. Ein großer Nachteil dieser Systeme besteht darin, dass weder Fehlfunktionen der Mischeinrichtungen noch Änderungen der physikalischen und / oder der chemischen Zusammensetzung , z.B. infolge von chemischen Reaktionen oder von Absorptions- oder Desorptionsprozessen durch die Druckfarbe, das Papier, durch die Rohrleitung oder die Maschinenmodule, festgestellt werden können. Insbesondere führen Verdunstungsprozesse bei diesen klassischen Dosierungsverfahren zu erheblichen Konzentrationsfehlern. Die im Moment als einzige Kontrollinstrumente bereits im Einsatz befindlichen Sensoren zur Erfassung der elektrischen Leitfähigkeit sind wegen der starken und schwankenden Verschmutzung der Prozeßflüssigkeit für eine quantitative Messung der Konzentration des jeweiligen Additivs bzw. des Ersatzstoffes nicht geeignet. Ferner sind die wichtigen chemischen Leitkomponenten der Additive, welche den Druckprozeß ermöglichen, durch eine Leitfähigkeitsmessung nicht erfassbar, da diese Substanzen im Wasser nicht disssoziierbar sind. Auch die mehr oder weniger als Standard im Offsetdruck bereits eingeführte pH - Sonde kann allenfalls als Indikator kurz vor dem Zusammenbruch der Funktion des Druckprozesses herangezogen werden, da die erforderliche starke chemische Pufferung der Prozeßflüssigkeit, z.B. durch Zitronensäure, eine Veränderung des pH-Wertes auch bei starker Veränderung der chemischen Zusammensetzung, verhindert.According to the current state of the art, dosing devices are used to volumetrically mix the two or three components under fixed conditions as part of a control and into the fluid circuit of the printing press according to the respective consumption, ie according to the removal of the liquid through the paper to be printed, feed. In addition to mixing stations that are operated by hand, systems with conventional metering pumps are currently being used in particular. A major disadvantage of these systems is that neither malfunctions of the mixing devices Changes in the physical and / or chemical composition, for example as a result of chemical reactions or of absorption or desorption processes by the printing ink, the paper, through the pipeline or the machine modules, can be detected. In particular, evaporation processes in these classic dosing methods lead to considerable concentration errors. The present as the only control instruments already in use sensors for detecting the electrical conductivity are not suitable because of the strong and fluctuating contamination of the process liquid for a quantitative measurement of the concentration of the respective additive or the substitute. Furthermore, the important chemical control components of the additives which make the printing process possible can not be detected by a conductivity measurement, since these substances are not dissociable in the water. The more or less introduced as standard in offset printing pH probe can be used as an indicator just before the collapse of the function of the printing process, since the required strong chemical buffering of the process fluid, eg by citric acid, a change in pH even at strong change in chemical composition, prevented.
Ziel der vorliegenden Erfindung sind daher ein Verfahren sowie eine Vorrichtung zur Realisierung des Verfahrens, welche eine quantitative, kontinuierliche Messung und Regelung der Konzentrationen der Einzelkomponenten des jeweiligen Additivs bzw. des Ersatzstoffes in einer Matrix von bis zu 20 chemischen Komponenten ohne fehlerhafte Beeinflussung durch andere Stoffe, wie z.B. insbesondere durch Alkohole, Schmutz-, Farb- und Papier- Partikel, Gasblasen, Salze aus dem Papierstrich und andere für den Offsetdruck typische Verunreinigungen, ermöglichen. Darüber hinaus müssen die Einzelkomponenten mit einer stoffabhängigen Genauigkeit zwischen 10 ppm und 3.0 % gemessen und geregelt werden.Dieses Problem wurde bisher in keinem aller praktischen Fälle gelöst Da unsere wissenschaftlichen Untersuchungen vor allem gezeigt haben, dass die verschiedenen chemischen Inhaltsstoffe einer statisch vorgegebenen Additiv-Mischung nicht konzentrationsproportional verbraucht werden, sich die Mischung im Laufe des Druckprosesses also verändert, da sowohl die Farben, als auch das Papier, als auch andere Effekte eine mehr oder weniger selektive Abreicherung der Einzelkomponenten hervorrufen.Diese besondere Situation im Offsetdruck macht die vorliegende Erfindung in höchstem Maße wertvoll, da Abreicherungseffekte vollständig ausgeglichen werden, unabhängig von dem jeweils in der Druckmaschine befindlichen Kundenauftrag. Die vorliegende Erfindung löst die gestellten Aufgaben unter anderem dadurch, dass die chemischen Einzelkomponenten kontinuierlich gemessen und dem Feuchtmittelkreislauf geregelt als reine Rohstoffe oder / und als Teilmischungen aus mehreren Komponenten in der Regel in Mischungen mit Wasser, so zugeführt werden, dass sie sich einfach im Feuchtwasser lösen und insbesondere keine getrennten Phasen bilden. Auf diese Weise können insbesondere auch chemische Formulierungen realisiert werden, die in einem vorgefertigten Additiv - Konzentrat sich abtrennen und daher nicht zu einer homogenen Lösung führen würden. Für die Konzentrationsbestimmungen wird erfindungsgemäß die Schwächung elektromagnetischer Strahlung beim Durchgang durch das Feuchtwasser ausgenutzt.The aim of the present invention is therefore a method and an apparatus for implementing the method, which comprises a quantitative, continuous measurement and control of the concentrations of the individual components of the respective additive or the substitute in a matrix of up to 20 chemical components without faulty influence by other substances , as in particular by alcohols, dirt, color and paper particles, gas bubbles, salts from the paper coating and other impurities typical for offset printing, allow. In addition, the This problem has not yet been solved in all practical cases. As our scientific studies have shown above all that the various chemical ingredients of a statically predetermined additive mixture are not consumed in proportion to the concentration Thus, the mixture changes in the course of the printing process, since both the colors, as well as the paper, as well as other effects cause a more or less selective depletion of the individual components. This particular situation in offset printing makes the present invention highly valuable in that Depletion effects are fully compensated, regardless of the customer's order in the printing press. The present invention solves the tasks set, inter alia, that the chemical components are continuously measured and the dampening solution controlled as pure raw materials and / or as partial mixtures of several components usually in mixtures with water, fed so that they are simply in the fountain solve and in particular do not form separate phases. In this way, in particular, chemical formulations can be realized which separate in a prefabricated additive concentrate and therefore would not lead to a homogeneous solution. For the determination of concentration, the weakening of electromagnetic radiation is used in the passage through the dampening water according to the invention.
Die Erfindung wird im folgenden detailliert mittels Figuren beschrieben. Dabei zeigen im einzelnen:
- Fig.1:
- Das Gesamtsystem bestehend aus Meß- und Regelsystemen, Druckmaschine und Prozeßflüssigkeitskreislauf, wobei die Dosierung der verschiedenen chemischen Komponenten / Komponentengruppen direkt durch das Mess- und Regelgerät erfolgt.
- Fig. 2:
- Eine alternative Ausbildung der Erfindung, wobei die Dosierung über eine Venturi - Düse stattfindet.
- Fig. 3:
- Eine alternative Ausbildung der Erfindung, die dadurch gekennzeichnet ist, dass die chemischen Einzelkomponenten über einen statischen Mischer geführt werden.
- Fig. 4:
- Eine weitere Systemvariante, bei welcher eine Voranmischung in einem separaten Behälter stattfindet, welcher mit dem Gesamtsystem verbunden ist, wobei die Zusammensetzung dem optimalen Mischungsverhältnis entspricht.
- Fig. 5:
- System, bei welchem die optimale Zusammensetzung über kalibrierte Dosierpumpen erfolgt.
- Fig.1:
- The complete system consisting of measuring and control systems, printing machine and process fluid circuit, wherein the dosage of the various chemical components / groups of components is carried out directly by the measuring and control device.
- Fig. 2:
- An alternative embodiment of the invention wherein the metering takes place via a Venturi nozzle.
- 3:
- An alternative embodiment of the invention, which is characterized in that the individual chemical components are passed through a static mixer.
- 4:
- Another system variant, in which a pre-mixing takes place in a separate container, which is connected to the entire system, wherein the composition corresponds to the optimum mixing ratio.
- Fig. 5:
- System in which the optimum composition is carried out via calibrated metering pumps.
Die gemäß
In
Claims (16)
- Method for direct, selective measurement and control of the concentrations of individual chemical components of chemical additives or of chemical alcohol substitutes in fountain solution for offset printing, characterised in that the concentrations of the individual chemical components or groups thereof are continuously determined by detecting the attenuation of electromagnetic radiation as it passes through the fountain solution and that the individual components or groups of individual components are topped up to their respective reference values.
- Method in accordance with Claim 1, characterised in that the various chemical components are located in individual tanks and topping up is carried out by means of a measuring system that continuously measures the concentrations of the individual components or groups thereof and tops up the individual components via a control loop.
- Method in accordance with Claims 1 and 2, characterised in that the individual chemical components/groups are topped up from the individual tanks via pumps that are each fitted with a valve and are connected in series.
- Method in accordance with Claims 1 and 2, characterised in that the individual components/groups are drawn into the fountain solution circuit by a Bernoulli nozzle.
- Method in accordance with Claims 1 to 4, characterised in that the mixing of fountain solution and individual components/groups is optimised by means of a static mixer.
- Method in accordance with Claims 1 to 3, characterised in that the individual chemical components/groups are premixed with water in a premixing tank and that the liquid content of the premixing tanks is transferred to the fountain solution tank.
- Method in accordance with Claims 1 and 2, characterised in that in each case the individual chemical components/groups are metered out of each tank via a separate pump for each tank, upstream of which a common valve is connected.
- Apparatus for measuring and controlling the concentrations of individual chemical components or groups thereof in the fountain solution during offset printing, wherein the apparatus comprises both pumps and a measuring system for continuously monitoring the concentrations of the individual components in the fountain solution, characterised in that the apparatus is equipped with a measuring and control system (6, 24, 30, 43, 52) that measures the concentrations of the individual components based on selective attenuation of electromagnetic radiation through said fountain solution in the operating state and tops up the individual chemical components K1 to Kn via pumps (7, 21, 36, 50, 55) so as to ensure that the concentrations of the individual chemical components are identical to the reference concentrations at all times.
- Apparatus in accordance with claim 8, characterised in that a Bernoulli nozzle (21) that is operated by a partial flow of the fountain solution (18) which is circulated by a pump (22) is used as the pump.
- Apparatus in accordance with Claims 8 and 9, characterised in that the chemical components K1 to Kn are homogeneously mixed together with the fountain solution (29) by a static mixer (35) in a circuit (39) that is driven by a pump (38).
- Apparatus in accordance with Claims 8 and 9, characterised in that the individual chemical components K1 to Kn are prepared in a premixing tank (40) with water from a water pipe (41) via pumps (50a) and the mixture (47) is subsequently routed to the main tank (44).
- Apparatus in accordance with Claim 8, characterised in that the individual chemical components K1 to Kn are metered into the fountain solution (58) in each case via a pump (53), upstream of which a valve (54) is connected.
- Apparatus in accordance with Claims 8 to 12, characterised in that a second measuring and control unit (12) is provided that continuously measures the concentration of alcohol in the fountain solution (2, 18, 29, 44, 58) and tops up the depleted alcohol from an alcohol reservoir (13) via a pump (14) with an upstream valve.
- Apparatus in accordance with Claims 8 to 14, characterised in that the level (10, 27) is detected by a sensor (11, 28, 33, 48, 55) and that the fill level is kept constant by means of a control loop.
- Apparatus in accordance with Claim 14, characterised in that an ultrasound unit that works according to the depth sounding principle is used as the level sensor (11, 28, 33, 48, 55).
- Apparatus in accordance with Claims 8 to 15, characterised in that the fountain solution (2, 18, 29, 44, 58) is homogenised by means of stirrers (15, 26, 31, 39, 46, 58).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10333625A DE10333625B4 (en) | 2003-07-24 | 2003-07-24 | Method and device for measuring and controlling the concentration of chemical compounds in fountain solution during offset printing |
DE10333625 | 2003-07-24 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1500499A1 EP1500499A1 (en) | 2005-01-26 |
EP1500499B1 true EP1500499B1 (en) | 2016-01-20 |
EP1500499B2 EP1500499B2 (en) | 2023-11-22 |
Family
ID=33483038
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04017479.9A Expired - Lifetime EP1500499B2 (en) | 2003-07-24 | 2004-07-23 | Method and means for measuring and controlling the concentration of chemical substances in process liquids for offset printing |
Country Status (3)
Country | Link |
---|---|
US (1) | US20050061188A1 (en) |
EP (1) | EP1500499B2 (en) |
DE (1) | DE10333625B4 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005003372B4 (en) | 2005-01-24 | 2024-04-18 | Gunther Krieg | Method and device for controlling the concentration of components of additives in a pressure process fluid |
DE102005042299A1 (en) * | 2005-09-06 | 2007-03-08 | Baldwin Germany Gmbh | Printing machine`s e.g. offset printing machine, cylinders and rollers cleaning device, has chambers connected/combinable by fluid communication flow path for receiving fluid in chambers, so that equal fluid levels are produced in chambers |
DE102005042298A1 (en) * | 2005-09-06 | 2007-03-08 | Baldwin Germany Gmbh | Cleaning liquid e.g. fresh water, supplying device for cleaning device of offset-printing machine, has measuring and control devices that are provided for detecting measuring value depending on viscosity of liquid |
DE102006024789A1 (en) * | 2006-05-27 | 2007-11-29 | Man Roland Druckmaschinen Ag | Printing machine, especially roller rotary printing press, includes cavitation mixer for pressurizing and/or heating circulating wetting agent to counteract germ growth and/or eliminate germs |
DE102006042091B4 (en) * | 2006-09-07 | 2008-04-30 | Technotrans Ag | System for dampening solution preparation for offset printing |
DE102007034973A1 (en) * | 2007-07-26 | 2009-01-29 | Technotrans Ag | Fluid supply for e.g. offset printing machine, has fluid tank with level sensor supplying output signals continuously changed with levels such that associated levels are clearly determined based on respective signals |
CN105690978A (en) * | 2016-01-24 | 2016-06-22 | 东莞华南印刷有限公司 | Full-automatic eco-friendly fountain solution batching system |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4403866A (en) | 1982-05-07 | 1983-09-13 | E. I. Du Pont De Nemours And Company | Process for making paints |
DE3428909A1 (en) | 1983-11-11 | 1985-05-23 | VEB Kombinat Polygraph "Werner Lamberz" Leipzig, DDR 7050 Leipzig | DEVICE FOR THE AUTOMATIC MANUFACTURING OF MOISTURIZING MATERIAL FROM MULTIPLE COMPONENTS IN A PRE-DETERMINED CONCENTRATION FOR OFFSET PRINTING MACHINES |
JPH04327940A (en) | 1991-04-26 | 1992-11-17 | Toyo Ink Mfg Co Ltd | Concentration control of damping water for lithographic printing |
DE4324141A1 (en) | 1993-07-19 | 1995-03-16 | Krieg Gunther | Method and device for continuous, accurate and reliable determination and control of the isopropanol content in wetting agents in printing machines |
DE19546971A1 (en) | 1995-12-15 | 1997-06-19 | Baldwin Gegenheimer Gmbh | Device of a printing press |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2017867A (en) * | 1930-02-05 | 1935-10-22 | Merle E Nantz | Mixing device |
US4571092A (en) * | 1984-09-06 | 1986-02-18 | Ryco Graphic Manufacturing, Inc. | Liquid mixing system |
US4864925A (en) * | 1987-09-28 | 1989-09-12 | Rockwell International Corporation | Simplified lithography using ink and water admixtures |
US5713062A (en) * | 1996-09-26 | 1998-01-27 | Xerox Corporation | Color mixing and control system for use in an electrostatographic printing machine |
JP3843584B2 (en) * | 1998-03-20 | 2006-11-08 | 大日本インキ化学工業株式会社 | Heat-sensitive composition and planographic printing plate precursor and printing plate making method using the same |
US6947175B1 (en) * | 2000-07-31 | 2005-09-20 | Xerox Corporation | Method and system for adjusting color mixing due to substrate characteristics |
US6917424B2 (en) * | 2001-03-19 | 2005-07-12 | E. I. Du Pont De Nemours And Company | Process for manufacturing pigment dispersions |
US6575096B1 (en) * | 2001-11-07 | 2003-06-10 | Xerox Corporation | Computer controlled mixing of customer-selected color inks for printing machines |
US6682865B2 (en) * | 2001-11-21 | 2004-01-27 | Xerox Corporation | Hybrid electrophotographic apparatus for custom color printing |
DE102005003372B4 (en) * | 2005-01-24 | 2024-04-18 | Gunther Krieg | Method and device for controlling the concentration of components of additives in a pressure process fluid |
-
2003
- 2003-07-24 DE DE10333625A patent/DE10333625B4/en not_active Expired - Lifetime
-
2004
- 2004-07-21 US US10/895,388 patent/US20050061188A1/en not_active Abandoned
- 2004-07-23 EP EP04017479.9A patent/EP1500499B2/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4403866A (en) | 1982-05-07 | 1983-09-13 | E. I. Du Pont De Nemours And Company | Process for making paints |
DE3428909A1 (en) | 1983-11-11 | 1985-05-23 | VEB Kombinat Polygraph "Werner Lamberz" Leipzig, DDR 7050 Leipzig | DEVICE FOR THE AUTOMATIC MANUFACTURING OF MOISTURIZING MATERIAL FROM MULTIPLE COMPONENTS IN A PRE-DETERMINED CONCENTRATION FOR OFFSET PRINTING MACHINES |
JPH04327940A (en) | 1991-04-26 | 1992-11-17 | Toyo Ink Mfg Co Ltd | Concentration control of damping water for lithographic printing |
DE4324141A1 (en) | 1993-07-19 | 1995-03-16 | Krieg Gunther | Method and device for continuous, accurate and reliable determination and control of the isopropanol content in wetting agents in printing machines |
DE19546971A1 (en) | 1995-12-15 | 1997-06-19 | Baldwin Gegenheimer Gmbh | Device of a printing press |
Non-Patent Citations (3)
Title |
---|
"Alkoholkonstanthalter", ALCOSMART BROSCHURE, November 1998 (1998-11-01), XP055318015 |
KRIEG G.: "Die richtige Antwort auf die Lenkungsabgabe: Alkoholreduktion im Offsetdruck bis unter 3,0% mit dem Mess- und Regelsystem ALCOPRINT 2000 von UNISENSOR", GRAPHIA, vol. 79, January 2000 (2000-01-01), XP055318004 |
KRIEG G.: "OFFSETDRUCK DURCH ALKOHOL-REDUKTION NOCH WIRTSCHAFTLICHER", DEUTSCHER DRUCKER, no. 33, 2 September 1999 (1999-09-02), XP000848954 |
Also Published As
Publication number | Publication date |
---|---|
DE10333625B4 (en) | 2009-04-02 |
DE10333625A1 (en) | 2005-02-24 |
EP1500499B2 (en) | 2023-11-22 |
US20050061188A1 (en) | 2005-03-24 |
EP1500499A1 (en) | 2005-01-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3888270T2 (en) | Simplified planographic printing system using mixtures of ink and water. | |
EP0049887B1 (en) | Method and apparatus for determining toxic biological consumable substances in aqueous solutions, for instance in sewage | |
DE2745741B2 (en) | Method and device for regulating the fountain solution used in printing machines operating according to the lithographic process | |
EP1500499B1 (en) | Method and means for measuring and controlling the concentration of chemical substances in process liquids for offset printing | |
DD253679A1 (en) | PROCESS FOR REGULATING COLOR DENSITY | |
EP2335941B1 (en) | Dampening solution hardness regulation | |
DE102005003372B4 (en) | Method and device for controlling the concentration of components of additives in a pressure process fluid | |
DE3828325C2 (en) | ||
DE102012024806B4 (en) | Plant and method for producing a mixed product of at least one main liquid component and at least one additional component | |
DE69406736T2 (en) | Stencil printing device | |
DE69327749T2 (en) | Process for adjusting the concentration of a developer | |
DE68904381T2 (en) | PRINTING MACHINE WITHOUT COLOR KNIFE. | |
DE102009053087B4 (en) | Method and apparatus for dye batch production, computer program product and use | |
DE932491C (en) | Dampening system for lithographic printing machines | |
EP0009580A1 (en) | Process and apparatus for the regulation and/or the control of a biological waste water purification plant | |
EP0932502A1 (en) | Process and plant for preparing printing paste or the like, in particular for printing textile or carpet webs | |
DE10393224T5 (en) | Dampening agent supply method and apparatus for an offset printing machine | |
DE10159159B4 (en) | Dosing device for dampening solution preparation on printing machines | |
DE2807733A1 (en) | METHOD AND DEVICE FOR MEASURING BIOLOGICAL OXYGEN CONSUMPTION | |
DE3433618A1 (en) | Process and apparatus for regulating the feed of precipitant in heavy metal precipitation | |
DE10208655A1 (en) | Water filtered within pump-driven reverse osmosis module discharges filtered water to water hardening assembly | |
EP2202357B1 (en) | Method and device for coating printed sheets of paper | |
CH718648B1 (en) | Device for producing disinfectants and cleaning agents and method for supplying brine in a controlled amount and concentration to an electrolyzer. | |
DE102008010036B3 (en) | Damping solution cleaning device arrangement for use in printing machine, has additive dosing device arranged such that dosing of dampening solution additive is controlled based on parameters of damping solution cleaning device | |
DE2207102A1 (en) | DEVICE FOR SUPPLYING THE PRINTING UNITS OF ONE OR MORE OFFSET PRINTING MACHINES WITH WASHING WATER |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL HR LT LV MK |
|
17P | Request for examination filed |
Effective date: 20050722 |
|
AKX | Designation fees paid |
Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR |
|
17Q | First examination report despatched |
Effective date: 20080227 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20150729 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 771511 Country of ref document: AT Kind code of ref document: T Effective date: 20160215 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502004015109 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20160120 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160421 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160520 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R026 Ref document number: 502004015109 Country of ref document: DE |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
26 | Opposition filed |
Opponent name: TECHNOTRANS AG Effective date: 20161019 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160731 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 13 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160420 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160731 |
|
PGRI | Patent reinstated in contracting state [announced from national office to epo] |
Ref country code: BE Effective date: 20170124 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160723 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 14 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20160723 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20040723 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160120 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 15 |
|
PLAB | Opposition data, opponent's data or that of the opponent's representative modified |
Free format text: ORIGINAL CODE: 0009299OPPO |
|
R26 | Opposition filed (corrected) |
Opponent name: TECHNOTRANS SE Effective date: 20161019 |
|
PUAH | Patent maintained in amended form |
Free format text: ORIGINAL CODE: 0009272 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT MAINTAINED AS AMENDED |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20230711 Year of fee payment: 20 Ref country code: CH Payment date: 20230801 Year of fee payment: 20 Ref country code: AT Payment date: 20230710 Year of fee payment: 20 |
|
27A | Patent maintained in amended form |
Effective date: 20231122 |
|
AK | Designated contracting states |
Kind code of ref document: B2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R102 Ref document number: 502004015109 Country of ref document: DE |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230724 Year of fee payment: 20 Ref country code: DE Payment date: 20230710 Year of fee payment: 20 Ref country code: BE Payment date: 20230710 Year of fee payment: 20 |