EP1466036B1 - Systeme de couches comprenant une couche poreuse - Google Patents

Systeme de couches comprenant une couche poreuse Download PDF

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Publication number
EP1466036B1
EP1466036B1 EP02787907A EP02787907A EP1466036B1 EP 1466036 B1 EP1466036 B1 EP 1466036B1 EP 02787907 A EP02787907 A EP 02787907A EP 02787907 A EP02787907 A EP 02787907A EP 1466036 B1 EP1466036 B1 EP 1466036B1
Authority
EP
European Patent Office
Prior art keywords
ceramic
layer
porous layer
porous
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02787907A
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German (de)
English (en)
Other versions
EP1466036A1 (fr
Inventor
Uwe Paul
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
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Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Priority to EP02787907A priority Critical patent/EP1466036B1/fr
Publication of EP1466036A1 publication Critical patent/EP1466036A1/fr
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Publication of EP1466036B1 publication Critical patent/EP1466036B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/324—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal matrix material layer comprising a mixture of at least two metals or metal phases or a metal-matrix material with hard embedded particles, e.g. WC-Me
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/325—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with layers graded in composition or in physical properties
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12479—Porous [e.g., foamed, spongy, cracked, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149—Honeycomb-like
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149—Honeycomb-like
    • Y10T428/24157—Filled honeycomb cells [e.g., solid substance in cavities, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y10T428/249956—Void-containing component is inorganic
    • Y10T428/249957—Inorganic impregnant

Definitions

  • the invention relates to a layer system with a ceramic content in the layer.
  • Layer systems consist of a substrate and at least one layer lying on the substrate. Substrates must be protected, for example, in gas turbine construction from excessive temperatures and / or corrosive attacks. This can be done, for example, by applying to the substrate a sheet with a honeycomb structure, the honeycombs being filled with a ceramic. The ceramic essentially assumes the protective function. The sheet of the honeycomb structure serves to mechanically stabilize the ceramic. However, the mechanical bond between the ceramic and the inner surfaces of the honeycomb structure is not good, so it always comes to detachment of the ceramic.
  • US Pat. No. 5,720,597 shows a blade for a gas turbine, which at least partially has a foam-like region in the interior.
  • US Pat. No. 6,299,935 discloses a method for producing a layer in which the surface of a substrate a suspension of foam and a metallic powder is applied.
  • EP 0 609 795 A shows a ceramic thermal barrier coating having a partially open structure, with the inner open surfaces being covered with passivating ceramic layers or metal deposits.
  • the object of the invention is therefore to show a layer system which improves the mechanical strength between metal and ceramic.
  • the object is achieved by a layer system consisting of a substrate on which follows a porous layer with a pore content of at least 30 percent by volume, wherein a ceramic in the form of a coating or as ceramic particles is at least partially introduced into the porous layer, so the porous layer is at least partially densely filled with the ceramic.
  • the ceramic which is applied to the porous layer and at least partially introduced into this, can also form a mixture of different ceramic materials in order to set desired properties targeted.
  • the porous layer may be at least partially filled with ceramic so that it is almost dense in these areas, so that a nearly dense ceramic layer in the porous layer is achieved in order to exploit the advantages of the ceramic with respect to heat resistance.
  • a further ceramic protective layer such as is known from the thermal barrier coatings of gas turbine blades, be applied to protect by a further coating the ceramic in the porous layer from oxidation.
  • FIG. 1a shows a substrate 1, for example of metal, in particular of a superalloy for a gas turbine blade, on which a porous layer 4 is applied.
  • the porous layer 4 may be made of metal or ceramic.
  • the porous structure is schematically represented by the bars which are intended to represent the individual walls surrounding the pores in the porous layer 4.
  • the pore content is at least thirty (30) percent by volume.
  • an open pore structure of advantage ie there are connecting paths from the outer surface of the porous layer 4 to its underside, which faces the substrate 1, as z. B. in the application of filter systems is known.
  • a ceramic can be introduced particularly well in the porous layer.
  • FIG. 1 b shows a layer system in which a ceramic 7 is present in the porous layer 4.
  • the ceramic 7 may consist of a single ceramic material or of a mixture of different ceramic materials, for example in the form of ceramic particles. Metallic admixtures or coatings are also possible.
  • FIG. 2 a shows a further exemplary embodiment of a layer system 20 in which no individual ceramic particles 7 can be seen (FIG. 2 a), because the pore walls 13 of the porous layer 4 are coated with a ceramic layer 16 (FIG. 2 b). For example, the inner surfaces of the pores of the porous layer 4 are completely covered with a ceramic 16.
  • FIG. 3 shows an exemplary embodiment of a layer system 20 designed according to the invention.
  • a porous layer 4 is applied, the pores of which are filled with the ceramic 7, so that a dense layer is achieved.
  • FIG. 4 shows that at least one further intermediate layer 10 can be present between the substrate 1 and the porous layer 4.
  • FIG. 5 shows a further example of application for a layer system 20 according to the invention.
  • the layer system 20 forms part of a gas turbine housing 23, which surrounds turbine blades 26, for example, which are connected downstream of a burner in a gas turbine.
  • the axis of rotation of the turbine blade 26 is indicated at 29.
  • the layer system 20 according to the invention forms a seal between the gas turbine casing 23 and the turbine blade 26 and replaces the honeycomb structure described above. Further application examples can be found for gas turbine blades and heat shield elements.
  • FIG. 6a, b shows the production steps for producing a layer system 20 according to the invention.
  • the substrate 1 is connected to one another by means of a connection technique with an already prefabricated porous component 4 (FIG. 6b). This can be done for example by welding, diffusion bonding or diffusion soldering. Other connection techniques are possible.
  • FIG. 7 shows a further method for producing a layer system 20 according to the invention.
  • a suspension 32 which, for example, is converted by treatment at a temperature T into a porous layer 4.
  • the suspension 32 contains a metal powder and an activator that gasses in the heat treatment and the suspension foams with the metal, then at elevated temperature, the metal particles sintered together, for example, and thus form the porous layer 4, wherein simultaneously a good connection to the substrate 1 takes place.
  • Other methods of preparation for producing porous, in particular foam-like, structures may be used here, e.g. the investment casting process.
  • FIG. 8 shows a further exemplary embodiment for producing a layer system 20 according to the invention. This can be done, for example, by first casting the material for the substrate 1 in a casting process and then casting continuously or without interruption a metal or an alloy having a porous structure or a mixture of metal and ceramic, so that a porous metallic layer 4 is formed on the substrate 1, which may is densely filled with ceramics. From a blank 38, a substrate 1 and a porous layer 4 can also be formed by an intermediate treatment.
  • the ceramic 7 into the porous layer 4.
  • a coating device 35 for example by plasma spraying, so that a ceramic coating 16 is produced in the porous layer 4.
  • the coating process can be continued so that not only are the walls 13 of the porous layer coated, but also the pore structure is at least partially closed in order to achieve a dense layer.
  • a ceramic suspension with ceramic particles can also be introduced into the porous layer 4, in particular injected.
  • the carrier of the suspension is evaporated, so that the ceramic particles 7 remain behind and after a heat treatment with the metallic walls 13 of the porous layer 4 connect.
  • the porous layer 4 can also be completely filled with the ceramic 7 only in an upper region 11, the pores (FIG. 9b).
  • the porous layer 4 is advantageously filled with a ceramic 7, which has good mechanical properties at high temperatures and serves as a thermal barrier.
  • a ceramic 7 which has good mechanical properties at high temperatures and serves as a thermal barrier.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

Les systèmes de couches de l'état de la technique, dans lesquels une couche céramique est appliquée sur une couche métallique du système de couches, se caractérisent souvent par une mauvaise liaison entre métal et céramique. Le système de couches (20) de l'invention présente une couche poreuse (4) dans laquelle se trouve au moins partiellement une céramique (7) de sorte que la liaison entre la céramique (7) et le métal de la couche poreuse (4) est de meilleure qualité.

Claims (7)

  1. Système (20) stratifié
    constitué
    d'un substrat (1),
    d'une couche (2) extérieure poreuse ayant une proportion de pores d'au moins 30 pourcent en volume,
    qui est disposée sur un substrat (1),
    et d'une céramique (7, 16),
    la couche (4) poreuse étant remplie au moins par endroits d'une manière étanche de la céramique (7).
  2. Système stratifié suivant la revendication 1,
    caractérisé en ce que
    la couche (4) poreuse a une structure à pores ouverts.
  3. Système stratifié suivant la revendication 1,
    caractérisé en ce que la céramique (16) est un mélange de divers matériaux céramiques.
  4. Système stratifié suivant la revendication 1,
    caractérisé en ce qu'une autre couche (41) en céramique est déposée sur la céramique (7) de la couche (4) poreuse.
  5. Système stratifié suivant la revendication 1,
    caractérisé en ce que la couche (4) poreuse est du type alvéolaire.
  6. Système stratifié suivant la revendication 1,
    caractérisé en ce que le substrat (1) est métallique, notamment est un superalliage de cobalt/nickel.
  7. Système stratifié suivant la revendication 1,
    caractérisé en ce que la couche (4) poreuse est en métal.
EP02787907A 2002-01-15 2002-12-04 Systeme de couches comprenant une couche poreuse Expired - Lifetime EP1466036B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP02787907A EP1466036B1 (fr) 2002-01-15 2002-12-04 Systeme de couches comprenant une couche poreuse

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP02000874A EP1327703A1 (fr) 2002-01-15 2002-01-15 Système de revêtement avec une couche poreuse
EP02000874 2002-01-15
PCT/EP2002/013752 WO2003060195A1 (fr) 2002-01-15 2002-12-04 Systeme de couches comprenant une couche poreuse
EP02787907A EP1466036B1 (fr) 2002-01-15 2002-12-04 Systeme de couches comprenant une couche poreuse

Publications (2)

Publication Number Publication Date
EP1466036A1 EP1466036A1 (fr) 2004-10-13
EP1466036B1 true EP1466036B1 (fr) 2007-05-30

Family

ID=8185262

Family Applications (2)

Application Number Title Priority Date Filing Date
EP02000874A Withdrawn EP1327703A1 (fr) 2002-01-15 2002-01-15 Système de revêtement avec une couche poreuse
EP02787907A Expired - Lifetime EP1466036B1 (fr) 2002-01-15 2002-12-04 Systeme de couches comprenant une couche poreuse

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP02000874A Withdrawn EP1327703A1 (fr) 2002-01-15 2002-01-15 Système de revêtement avec une couche poreuse

Country Status (5)

Country Link
US (1) US7070853B2 (fr)
EP (2) EP1327703A1 (fr)
JP (1) JP2005514526A (fr)
DE (1) DE50210249D1 (fr)
WO (1) WO2003060195A1 (fr)

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EP1496140A1 (fr) * 2003-07-09 2005-01-12 Siemens Aktiengesellschaft Structure stratifiée et procédé pour sa production
US7579087B2 (en) * 2006-01-10 2009-08-25 United Technologies Corporation Thermal barrier coating compositions, processes for applying same and articles coated with same
US7968144B2 (en) * 2007-04-10 2011-06-28 Siemens Energy, Inc. System for applying a continuous surface layer on porous substructures of turbine airfoils
US20080290138A1 (en) * 2007-05-22 2008-11-27 David Myron Lineman Method for bonding refractory ceramic and metal
EP2938828A4 (fr) 2012-12-28 2016-08-17 United Technologies Corp Composant de moteur à turbine à gaz à structure maillée vasculaire artificielle
US10018052B2 (en) 2012-12-28 2018-07-10 United Technologies Corporation Gas turbine engine component having engineered vascular structure
US10094287B2 (en) 2015-02-10 2018-10-09 United Technologies Corporation Gas turbine engine component with vascular cooling scheme
US20160312633A1 (en) * 2015-04-24 2016-10-27 General Electric Company Composite seals for turbomachinery
US10221694B2 (en) 2016-02-17 2019-03-05 United Technologies Corporation Gas turbine engine component having vascular engineered lattice structure
US10774653B2 (en) 2018-12-11 2020-09-15 Raytheon Technologies Corporation Composite gas turbine engine component with lattice structure

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DE3579684D1 (de) * 1984-12-24 1990-10-18 United Technologies Corp Abschleifbare dichtung mit besonderem erosionswiderstand.
US4639388A (en) * 1985-02-12 1987-01-27 Chromalloy American Corporation Ceramic-metal composites
DE4303135C2 (de) * 1993-02-04 1997-06-05 Mtu Muenchen Gmbh Wärmedämmschicht aus Keramik auf Metallbauteilen und Verfahren zu ihrer Herstellung
DE4338457C2 (de) 1993-11-11 1998-09-03 Mtu Muenchen Gmbh Bauteil aus Metall oder Keramik mit dichter Außenschale und porösem Kern und Herstellungsverfahren
US5720597A (en) * 1996-01-29 1998-02-24 General Electric Company Multi-component blade for a gas turbine
US6235370B1 (en) * 1999-03-03 2001-05-22 Siemens Westinghouse Power Corporation High temperature erosion resistant, abradable thermal barrier composite coating
US6165628A (en) * 1999-08-30 2000-12-26 General Electric Company Protective coatings for metal-based substrates and related processes
US6294260B1 (en) * 1999-09-10 2001-09-25 Siemens Westinghouse Power Corporation In-situ formation of multiphase air plasma sprayed barrier coatings for turbine components
US6299935B1 (en) * 1999-10-04 2001-10-09 General Electric Company Method for forming a coating by use of an activated foam technique
CN1443147A (zh) * 2000-05-19 2003-09-17 英属哥伦比亚大学 化学制备粘接复合氢氧化物陶瓷的方法
US6670046B1 (en) * 2000-08-31 2003-12-30 Siemens Westinghouse Power Corporation Thermal barrier coating system for turbine components

Non-Patent Citations (1)

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Title
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Also Published As

Publication number Publication date
EP1327703A1 (fr) 2003-07-16
WO2003060195A1 (fr) 2003-07-24
EP1466036A1 (fr) 2004-10-13
US7070853B2 (en) 2006-07-04
US20040058185A1 (en) 2004-03-25
DE50210249D1 (de) 2007-07-12
JP2005514526A (ja) 2005-05-19

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