EP1406052A3 - Procédé intégré de séparation d'air et installation pour la mise en oeuvre d'un tel procédé - Google Patents

Procédé intégré de séparation d'air et installation pour la mise en oeuvre d'un tel procédé Download PDF

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Publication number
EP1406052A3
EP1406052A3 EP03300172A EP03300172A EP1406052A3 EP 1406052 A3 EP1406052 A3 EP 1406052A3 EP 03300172 A EP03300172 A EP 03300172A EP 03300172 A EP03300172 A EP 03300172A EP 1406052 A3 EP1406052 A3 EP 1406052A3
Authority
EP
European Patent Office
Prior art keywords
separator
air
carrying
turbine
plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP03300172A
Other languages
German (de)
English (en)
Other versions
EP1406052B1 (fr
EP1406052A2 (fr
Inventor
Alain l'Air Liquide SA Guillard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA a Directoire et Conseil de Surveillance pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8858754&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1406052(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Liquide SA, LAir Liquide SA a Directoire et Conseil de Surveillance pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of EP1406052A2 publication Critical patent/EP1406052A2/fr
Publication of EP1406052A3 publication Critical patent/EP1406052A3/fr
Application granted granted Critical
Publication of EP1406052B1 publication Critical patent/EP1406052B1/fr
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763—Start-up or control of the process; Details of the apparatus used
    • F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812—Different modes, i.e. "runs" of operation
    • F25J3/04818—Start-up of the process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04163—Hot end purification of the feed air
    • F25J3/04169—Hot end purification of the feed air by adsorption of the impurities
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
    • F25J3/04539—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels
    • F25J3/04545—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels for the gasification of solid or heavy liquid fuels, e.g. integrated gasification combined cycle [IGCC]
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04563—Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating
    • F25J3/04575—Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating for a gas expansion plant, e.g. dilution of the combustion gas in a gas turbine
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04593—The air gas consuming unit is also fed by an air stream
    • F25J3/04606—Partially integrated air feed compression, i.e. independent MAC for the air fractionation unit plus additional air feed from the air gas consuming unit
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763—Start-up or control of the process; Details of the apparatus used
    • F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04951—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763—Start-up or control of the process; Details of the apparatus used
    • F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04951—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
    • F25J3/04957—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network and inter-connecting equipments upstream of the fractionation unit (s), i.e. at the "front-end"
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/80—Hot exhaust gas turbine combustion engine

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Power Engineering (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Dans un procédé intégré de séparation d'air produisant un fluide enrichi en oxygène et éventuellement un fluide enrichi en azote dans une installation comprenant au moins deux appareils de séparation d'air (1, 101), chaque appareil comprend au moins deux colonnes de distillation, un premier compresseur d'air (13), une première chambre de combustion (17), et une première turbine de détente (19), dans lequel de l'air comprimé est fourni au premier appareil de séparation d'air (1) au moins par le premier compresseur d'air qui fournit également de l'air comprimé à la première chambre de combustion, de l'air comprimé est fourni au deuxième appareil de séparation d'air (101) au moins par un compresseur auxiliaire (21, 121) qui n'alimente pas de chambre de combustion mais qui alimente également le premier appareil de séparation d'air.
EP03300172A 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et installation pour la mise en oeuvre d'un tel procédé Revoked EP1406052B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0100403 2001-01-12
FR0100403A FR2819584B1 (fr) 2001-01-12 2001-01-12 Procede integre de separation d'air et de generation d'energie et installation pour la mise en oeuvre d'un tel procede
EP01403286.6A EP1223395B2 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et de génération d'énergie

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP01403286.6A Division EP1223395B2 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et de génération d'énergie
EP01403286.6 Division 2001-12-18

Publications (3)

Publication Number Publication Date
EP1406052A2 EP1406052A2 (fr) 2004-04-07
EP1406052A3 true EP1406052A3 (fr) 2005-01-05
EP1406052B1 EP1406052B1 (fr) 2006-07-26

Family

ID=8858754

Family Applications (2)

Application Number Title Priority Date Filing Date
EP03300172A Revoked EP1406052B1 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et installation pour la mise en oeuvre d'un tel procédé
EP01403286.6A Expired - Lifetime EP1223395B2 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et de génération d'énergie

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP01403286.6A Expired - Lifetime EP1223395B2 (fr) 2001-01-12 2001-12-18 Procédé intégré de séparation d'air et de génération d'énergie

Country Status (7)

Country Link
US (1) US6550234B2 (fr)
EP (2) EP1406052B1 (fr)
JP (1) JP2002243361A (fr)
AT (2) ATE301272T1 (fr)
DE (2) DE60121830T2 (fr)
ES (2) ES2246301T5 (fr)
FR (1) FR2819584B1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7284362B2 (en) * 2002-02-11 2007-10-23 L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procedes Georges Claude Integrated air separation and oxygen fired power generation system
JP2007507639A (ja) * 2003-09-30 2007-03-29 ビーエイチピー ビリトン イノベーション プロプライアタリー リミテッド 発電
FR2862128B1 (fr) * 2003-11-10 2006-01-06 Air Liquide Procede et installation de fourniture d'oxygene a haute purete par distillation cryogenique d'air
EP1544559A1 (fr) * 2003-12-20 2005-06-22 Linde AG Procédé et dispositif pour la séparation cryogénique d'air
US7197894B2 (en) * 2004-02-13 2007-04-03 L'air Liquide, Societe Anonyme A' Directorie Et Conseil De Survelliance Pour L'etude Et, L'exploltation Des Procedes Georges, Claude Integrated process and air separation process
US20060123844A1 (en) * 2004-12-09 2006-06-15 Patrick Le Bot Integrated process for the separation of air and an integrated installation for the separation of air
US20070101989A1 (en) * 2005-11-08 2007-05-10 Mev Technology, Inc. Apparatus and method for the conversion of thermal energy sources including solar energy
US7617687B2 (en) * 2006-02-28 2009-11-17 General Electric Company Methods and systems of variable extraction for gas turbine control
US7784288B2 (en) * 2006-03-06 2010-08-31 General Electric Company Methods and systems of variable extraction for compressor protection
FR2898645B1 (fr) * 2006-03-14 2008-08-22 L'air Liquide Compresseur a plusieurs etages, appareil de separation d'air comprenant un tel compresseur et installation
ES2733083T3 (es) 2009-02-26 2019-11-27 8 Rivers Capital Llc Aparato y método para quemar un combustible a alta presión y alta temperatura, y sistema y dispositivo asociados
US8596075B2 (en) 2009-02-26 2013-12-03 Palmer Labs, Llc System and method for high efficiency power generation using a carbon dioxide circulating working fluid
US10018115B2 (en) 2009-02-26 2018-07-10 8 Rivers Capital, Llc System and method for high efficiency power generation using a carbon dioxide circulating working fluid
US20120067054A1 (en) 2010-09-21 2012-03-22 Palmer Labs, Llc High efficiency power production methods, assemblies, and systems
US8869889B2 (en) 2010-09-21 2014-10-28 Palmer Labs, Llc Method of using carbon dioxide in recovery of formation deposits
US8752391B2 (en) * 2010-11-08 2014-06-17 General Electric Company Integrated turbomachine oxygen plant
EP2776692B1 (fr) 2011-11-02 2016-05-04 8 Rivers Capital, LLC Système de production d'énergie et procédé correspondant
MX358190B (es) 2012-02-11 2018-08-08 Palmer Labs Llc Reaccion de oxidacion parcial con enfriamiento de ciclo cerrado.
JP6250332B2 (ja) 2013-08-27 2017-12-20 ８ リバーズ キャピタル，エルエルシー ガスタービン設備
TWI657195B (zh) 2014-07-08 2019-04-21 美商八河資本有限公司 加熱再循環氣體流的方法、生成功率的方法及功率產出系統
EP3438049B1 (fr) 2014-09-09 2021-11-03 8 Rivers Capital, LLC Procédé de production de dioxyde de carbone liquide à basse pression à partir d'un système de production d'énergie
US11231224B2 (en) 2014-09-09 2022-01-25 8 Rivers Capital, Llc Production of low pressure liquid carbon dioxide from a power production system and method
MA40950A (fr) 2014-11-12 2017-09-19 8 Rivers Capital Llc Systèmes et procédés de commande appropriés pour une utilisation avec des systèmes et des procédés de production d'énergie
US10961920B2 (en) 2018-10-02 2021-03-30 8 Rivers Capital, Llc Control systems and methods suitable for use with power production systems and methods
US11686258B2 (en) 2014-11-12 2023-06-27 8 Rivers Capital, Llc Control systems and methods suitable for use with power production systems and methods
KR102602774B1 (ko) 2015-06-15 2023-11-15 8 리버스 캐피탈, 엘엘씨 동력 생산 플랜트의 기동을 위한 시스템 및 방법
MX2018010022A (es) 2016-02-18 2018-12-10 8 Rivers Capital Llc Sistema y metodo para la produccion de energia incluyendo metanacion.
JP7001608B2 (ja) 2016-02-26 2022-01-19 ８ リバーズ キャピタル，エルエルシー 電力プラントを制御するためのシステムおよび方法
MX2019002888A (es) 2016-09-13 2019-07-04 8 Rivers Capital Llc Sistema y metodo para la produccion de energia utilizando oxidacion parcial.
BR112020003886A2 (pt) 2017-08-28 2020-09-01 8 Rivers Capital, Llc otimização de calor de baixo grau de ciclos de energia de co2 supercrítico recuperável
PL3759322T3 (pl) 2018-03-02 2024-03-18 8 Rivers Capital, Llc Układy i sposoby wytwarzania energii z wykorzystaniem płynu roboczego z dwutlenku węgla
CA3155211A1 (fr) 2019-10-22 2021-04-29 Brock Alan Forrest Schemas de commande pour la gestion thermique de systemes et procedes de production d'energie
EP4121638A4 (fr) * 2020-03-19 2024-04-03 Kellogg Brown & Root LLC Augmentation de puissance pour turbine à gaz

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US5572861A (en) * 1995-04-12 1996-11-12 Shao; Yulin S cycle electric power system
US5740673A (en) * 1995-11-07 1998-04-21 Air Products And Chemicals, Inc. Operation of integrated gasification combined cycle power generation systems at part load

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US4861369A (en) * 1986-11-25 1989-08-29 Korf Engineering Gmbh Process for gaining electric energy in addition to producing molten pig iron and an arrangement for carrying out the process
US5572861A (en) * 1995-04-12 1996-11-12 Shao; Yulin S cycle electric power system
US5740673A (en) * 1995-11-07 1998-04-21 Air Products And Chemicals, Inc. Operation of integrated gasification combined cycle power generation systems at part load

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Title
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Also Published As

Publication number Publication date
DE60121830D1 (de) 2006-09-07
FR2819584A1 (fr) 2002-07-19
EP1223395A1 (fr) 2002-07-17
ES2246301T5 (es) 2013-10-08
DE60112396T2 (de) 2006-06-01
DE60112396D1 (de) 2005-09-08
EP1406052B1 (fr) 2006-07-26
US6550234B2 (en) 2003-04-22
ES2246301T3 (es) 2006-02-16
ATE334365T1 (de) 2006-08-15
ATE301272T1 (de) 2005-08-15
EP1406052A2 (fr) 2004-04-07
FR2819584B1 (fr) 2003-03-07
ES2269951T3 (es) 2007-04-01
DE60112396T3 (de) 2013-10-10
DE60121830T2 (de) 2007-03-29
EP1223395B1 (fr) 2005-08-03
EP1223395B2 (fr) 2013-05-15
US20020092306A1 (en) 2002-07-18
JP2002243361A (ja) 2002-08-28

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