EP1327710B1 - Schnittfestes Garn insbesondere für die Herstellung von Schutzkleidung - Google Patents
Schnittfestes Garn insbesondere für die Herstellung von Schutzkleidung Download PDFInfo
- Publication number
- EP1327710B1 EP1327710B1 EP02356273A EP02356273A EP1327710B1 EP 1327710 B1 EP1327710 B1 EP 1327710B1 EP 02356273 A EP02356273 A EP 02356273A EP 02356273 A EP02356273 A EP 02356273A EP 1327710 B1 EP1327710 B1 EP 1327710B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- glass
- yarn according
- synthetic
- core
- fibre threads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000001681 protective effect Effects 0.000 title description 9
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000011521 glass Substances 0.000 claims abstract description 17
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 7
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 3
- 229920001194 natural rubber Polymers 0.000 claims abstract description 3
- 229920003051 synthetic elastomer Polymers 0.000 claims abstract description 3
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims abstract 2
- 239000003365 glass fiber Substances 0.000 claims abstract 2
- 239000000835 fiber Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 10
- 239000004952 Polyamide Substances 0.000 claims description 9
- 229920002647 polyamide Polymers 0.000 claims description 9
- 239000004705 High-molecular-weight polyethylene Substances 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 229920003235 aromatic polyamide Polymers 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 241001465754 Metazoa Species 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 229920000106 Liquid crystal polymer Polymers 0.000 claims 2
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims 2
- 239000004634 thermosetting polymer Substances 0.000 abstract 1
- -1 Poly Phenylene Benzo Bisoxazole Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 235000019589 hardness Nutrition 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- ASDNIIDZSQLDMR-UHFFFAOYSA-N 2-[2-(1,3-benzoxazol-2-yl)phenyl]-1,3-benzoxazole Chemical compound C1=CC=C2OC(C=3C(C=4OC5=CC=CC=C5N=4)=CC=CC=3)=NC2=C1 ASDNIIDZSQLDMR-UHFFFAOYSA-N 0.000 description 1
- 239000005264 High molar mass liquid crystal Substances 0.000 description 1
- 241000191340 Morone chrysops x Morone saxatilis Species 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920002577 polybenzoxazole Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/442—Cut or abrasion resistant yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
- D02G3/182—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure
- D02G3/185—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure in the core
Definitions
- the present invention relates to a cut resistant wire, intended in particular for the production of protective clothing against mechanical assaults
- These personal protective equipment are the most often in the form of gloves, cuffs, aprons, or any part of clothing, and are generally knitted or more rarely woven.
- materials used special polymers such as Polyamides, Para-aramides, High molecular weight polyethylene, LCP (Liquid Crystal) fibers Polymer), Polybensimidizoasole, Polyester loaded with ceramic. These materials have in common the characteristic of being very crystalline and by therefore have a fairly high intrinsic hardness. Indeed, the hardness of the materials used is very important, and largely governs the slicing or shearing mechanisms to which they are exposed. As an indication, crystalline and semi-crystalline polymeric materials have hardnesses measured on the Mohs scale between 2 and 3 units.
- Glass or stainless steel filaments are poorly resistant to kink and break. The ends released, despite mounting of polymeric filaments intended to sheath them by wrapping operations, eventually pass through the layers of gimped polymer filaments, of which the effect is to prick the hands of operators, who generally do not wear plus protective equipment.
- glass filaments are used for their flame retardant properties (MO classification). These sun visors are placed inside buildings in front of the windows and must fill in addition to solar filtration, a aesthetic function.
- the glass filament generally named silionne is coextruded with a bulk flame retardant polymer resin and tinted to the desired color. These threads are then woven and heat sealed at the crossing of the wires to block the network of wires.
- the object of the invention is to provide a wire resistant to cutting allowing the realization of a protective equipment which offers a good security for users and which has good flexibility, promoting comfort.
- the wire which it relates comprising a core obtained by coextrusion of a glass multifilament E, R, C or S or more generally silione or basalt and a polymer sheath of the type thermoplastic, thermoset, natural elastomer, synthetic elastomer fluorinated or not, is characterized in that the fiberglass part represents maximum 60% by mass of the sheath + filament compound, and in that the core is assembled or twisted with yarns of fibers composed of synthetic fibers.
- the core and yarns of fibers composed of synthetic fibers are either assembled or twisted together in "S" or "Z" directions.
- the coextrusion part makes the core thread more flexible than if it were entirely made of glass.
- fiber yarns are absolutely blocked by the contact of the polymer constituting them on the polymer coextruded.
- the extruded polymer sheath creates a perfect seal for the axial component constituted by the glass filament.
- the polymers used can be polyvinyl chloride or polyurethane or any other chemically inert polymer.
- the fiber yarns are chosen from the following families: High molecular weight polyethylene, greater than 600,000 g / mole, Para-aramid with a module> 50Gpa, polyamide high tenacity and standard, High tenacity and standard polyester, Polymer liquid crystal (LCP), Poly Phenylene Benzo Bisoxazole (PBO), Polyester loaded with ceramic.
- the fiber yarns are made of identical materials.
- the fiber yarns are made, at least for some, of different materials.
- the fiber yarns further comprise fibers belonging to the vegetable or animal kingdom.
- the yarn consists of two yarns (B 1 ) of identical long or short fibers, Nm 28/1 (357 dTex) each composed of high molecular weight polyethylene fibers, mixed with polyamide 6.6 or 6 or 4.6 fibers in the proportion of 37% polyethylene and 63% polyamide fibers.
- a glass wire coextruded with a polymer sheath (950 dTex) A 1 constitutes the third component. This assembly is then twisted with a twist "S" or "Z" with a ratio between 0 and 200 turns / m.
- Hybrid wire title: 2 x 357 + 950 1664 dtex (Nm 6)
- the yarn consists of three yarns (B 2 ) of identical long or short fibers, Nm 50/1 (200 dtex) each composed of high molecular weight polyethylene fibers, mixed with polyamide 6.6 or 6 or 4.6 fibers, in the proportion of 37% polyethylene and 63% polyamide fibers.
- a coextruded glass wire, with a polymer sheath (A 2 ) constitutes the fourth component.
- the yarn consists of three yarns (B 3 ) of identical long or short fibers, Nm 50/1 (200 dTex) each composed of para-aramid fibers.
- the fourth component is glass wire coextruded with a polymer sheath (A 3 ) 950 dTex. This assembly is then twisted with a twist "S" or "Z” with a ratio between 0 and 200 rpm.
- the yarn consists of three yarns (B 4 , C 4 , D 4 ) of non-identical long or short fibers, Nm 50/1 (200 dTex) composed of two yarns of long or short fibers, based on polyethylene fibers with high molecular weight, mixed with polyamide 6.6, 6 or 4.6 fibers, in the proportion of 37% polyethylene and 63% polyamide fibers.
- Nm 50/1 (200 dtex) composed of long or short fibers is added to the previous two.
- the material chosen for this thread is a polyamide 6, 6.6 or 4.6.
- a coextruded glass wire, with a polymer sheath (A 4 ) 950 dTex constitutes the fourth element of this set.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Artificial Filaments (AREA)
- Multicomponent Fibers (AREA)
Claims (6)
- Schnitttester Faden, umfassend eine Seele (A) erhalten durch Koextrudieren eines Multifilamentes aus Glas E, R, C oder S oder allgemeiner aus Silikon oder Basalt und eine Hülle aus Polymer von thermoplastischer. thermodurer, natürlicher elastomerer, fluorierter oder nichtfluorierter synthetischer elastomerer Art, dadurch gekennzeichnet, dass der Fiberanteil aus Glas maximal 60 Gew.-% der Verbindung aus Hülle + Filament darstellt, und dass die Seele (A) mit Garnen aus Fibem, die aus synthetischen Fibem (B, C, D) zusammengesetzt sind, zusammengefügt oder gezwirnt ist.
- Faden gemäß Anspruch 1, dadurch gekennzeichnet, dass die Seele (A) und die Game aus Fibem, die aus synthetischen Fibem (B, C, D) zusammengesetzt sind, im Gegenuhrzeigersinn oder Uhrzeigersinn entweder zusammengefügt oder gezwirnt sind.
- Faden gemäß einem der Ansprüche 1 und 2, dadurch gekennzeichnet, dass die Game aus Fibem, die aus synthetischen Fibern (B, C, D) zusammengesetzt sind, aus folgenden Familien ausgewählt sind: Polyethylen mit hohem Molekulargewicht größer als 600 000 g/Mol, Para-aramid mit einem Modul > 50 Gpa, Polyamid mit hoher Zähigkeit und Standard-Polyamid, Polyester mit hoher Zähigkeit und Standard-Polyester, Flüssigkristallpolymer (LCP) Polyphenylenbenzoblsoxazol (PBO), mit Keramik beladenes Polyester.
- Faden gemäß einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Garne aus Fibem außerdem Fibem umfassen, die dem Pflanzen- oder Tierreich zugehörig sind.
- Faden gemäß einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Game aus Fibem, die aus synthetischen Fibem (B, C, D) zusammengesetzt sind, aus identischen Materialien gebildet sind.
- Faden gemäß einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die verschiedenen synthetischen Multifilamente (B, C, D) wenigstens aus gewissen verschiedenen Materialien gebildet sind.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0200264 | 2002-01-10 | ||
FR0200264A FR2834522B1 (fr) | 2002-01-10 | 2002-01-10 | Fil resistant a la coupure, destine notamment a la realisation de vetements de protection |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1327710A1 EP1327710A1 (de) | 2003-07-16 |
EP1327710B1 true EP1327710B1 (de) | 2004-07-28 |
Family
ID=8871229
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02356273A Expired - Lifetime EP1327710B1 (de) | 2002-01-10 | 2002-12-30 | Schnittfestes Garn insbesondere für die Herstellung von Schutzkleidung |
Country Status (10)
Country | Link |
---|---|
US (1) | US6880321B2 (de) |
EP (1) | EP1327710B1 (de) |
JP (1) | JP4542746B2 (de) |
AT (1) | ATE272139T1 (de) |
DE (1) | DE60200827T2 (de) |
DK (1) | DK1327710T3 (de) |
ES (1) | ES2225744T3 (de) |
FR (1) | FR2834522B1 (de) |
PT (1) | PT1327710E (de) |
TR (1) | TR200402273T4 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2828894B1 (fr) * | 2001-08-24 | 2004-01-02 | Schappe Sa | Fil resistant a la coupure, destine notamment a la realisation de vetements de protection |
ITLC20040006A1 (it) * | 2004-07-06 | 2004-10-06 | Paolo Cappellari | Tessuto elastico microforato costituito da una maglia a coste accoppiata e spalmata traspirante ad alta tenacit`. |
DE102005018477B4 (de) * | 2005-04-21 | 2008-01-17 | Institut Für Verbundwerkstoffe Gmbh | Garn mit mineralischen Fasern |
EP1780318B1 (de) * | 2005-08-01 | 2012-11-07 | SHOWA GLOVE Co. | Verbundfaser und damit hergestellte schnittresistente handschuhe |
KR100722409B1 (ko) | 2006-02-27 | 2007-05-28 | 주식회사 쎄코텍 | 현무암 코아사 제조방법, 제조장치 및 이를 이용하여제조된 현무암 코아사 |
FR2904009B1 (fr) * | 2006-07-21 | 2008-09-12 | Schappe Sa Sa | Fil destine a la confection d'une surface textile resistant a la coupure et a l'abrasion |
KR20080094159A (ko) * | 2007-04-19 | 2008-10-23 | 주식회사 쎄코텍 | 현무암사와 현무암 코아사의 기능성 코팅방법, 이 방법으로코팅된 현무암사와 현무암 코아사 및 이들로 제직된 제품 |
EP2112259A1 (de) * | 2008-04-22 | 2009-10-28 | DSM IP Assets B.V. | Abriebfestes Gewebe |
KR20110021915A (ko) * | 2008-06-24 | 2011-03-04 | 디에스엠 아이피 어셋츠 비.브이. | 내절단성 패브릭 |
US9896798B2 (en) * | 2012-07-17 | 2018-02-20 | Dsm Ip Assets B.V. | Abrasion resistant product |
US20140090349A1 (en) * | 2012-09-10 | 2014-04-03 | Angela Fisher | Composite yarn for cut resistant fabrics |
CN104068485A (zh) * | 2014-06-27 | 2014-10-01 | 江阴芗菲服饰有限公司 | 安全性高的儿童服装 |
CN104126942A (zh) * | 2014-07-28 | 2014-11-05 | 江苏云蝠服饰股份有限公司 | 安全性高的无静电污染儿童服装 |
MX365938B (es) * | 2015-08-28 | 2019-06-19 | Filspec Inc | Hilo compuesto con nucleo de vidrio. |
WO2017130545A1 (ja) * | 2016-01-25 | 2017-08-03 | 聡 備酒 | 強靱糸、耐切創性を備えた編織物及び手袋 |
US11598027B2 (en) | 2019-12-18 | 2023-03-07 | Patrick Yarn Mills, Inc. | Methods and systems for forming a composite yarn |
CN111088585B (zh) * | 2020-01-06 | 2021-12-28 | 常州科旭纺织有限公司 | 短纤包覆手套及其制造工艺 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1610495A1 (de) | 1967-09-28 | 1971-01-28 | Mueller Ernst Dietmar | Verfahren zum Herstellen eines Garnes,wobei ein Kernfaden aus Draht mit einem Vorgarn aus natuerlichen oder/und Synthetischen Textil-Stapelfasern zweimal umsponnen ist |
US3676287A (en) * | 1970-09-08 | 1972-07-11 | Owens Corning Fiberglass Corp | Glass fiber-reinforced elastomers |
JPS50112536A (de) * | 1974-02-20 | 1975-09-04 | ||
US3883898A (en) * | 1974-05-13 | 1975-05-20 | Sr Robert M Byrnes | Protective glove for use in meat processing plants |
US4004295A (en) * | 1975-12-30 | 1977-01-25 | Byrnes Sr Robert M | Protective glove constructed of flexible strands of metal wire and fiber yarn |
CA1133654A (en) | 1976-10-05 | 1982-10-19 | Robert M. Byrnes, Sr. | Protective gloves and the like and a yarn with flexible core wrapped with aramid fiber |
US4470251A (en) | 1978-03-30 | 1984-09-11 | Bettcher Industries, Inc. | Knittable yarn and safety apparel made therewith |
US4274448A (en) * | 1978-08-09 | 1981-06-23 | Scapa Dryers, Inc. | Dryer felt with encapsulated, bulky center yarns |
US4265972A (en) * | 1979-03-09 | 1981-05-05 | Bernard Rudner | Coated fibers and related process |
AU8277882A (en) * | 1982-03-31 | 1983-10-24 | Remora Textiles Ltd. | Flame resistant yarns & fabrics, & furnishings incorporating such fabrics |
FR2532553A1 (fr) * | 1982-09-02 | 1984-03-09 | Explosifs Prod Chim S | Cordage pour raquettes de tennis, et raquettes ainsi equipees |
DK153984A (da) | 1983-03-11 | 1984-09-12 | Bettcher Industries | Beskyttelsesbeklaedningsstykke, isaer handske |
US5136679A (en) * | 1985-07-23 | 1992-08-04 | U.S. Philips Corp. | Optical glass fibre having a synthetic resin coating and curable elastomer forming material |
US4777789A (en) * | 1986-10-03 | 1988-10-18 | Kolmes Nathaniel H | Wire wrapped yarn for protective garments |
US6826898B1 (en) * | 1985-10-17 | 2004-12-07 | Wells Lamont Industry Group | Knittable yarn and safety apparel |
JPS62172307A (ja) * | 1986-01-27 | 1987-07-29 | Mitsubishi Rayon Co Ltd | プラスチツク光伝送性繊維 |
US4774135A (en) * | 1986-05-16 | 1988-09-27 | Bgf Industries, Inc. | Process for coating yarn with hot melt thermoplastic |
JPS63270831A (ja) * | 1987-04-28 | 1988-11-08 | 東レ株式会社 | 可撓性糸状発熱体 |
US5177948B1 (en) * | 1989-06-13 | 1995-04-18 | Nathaniel H Kolmes | Yarn and glove |
JPH04163334A (ja) * | 1990-10-26 | 1992-06-08 | Toyobo Co Ltd | 熱可塑性樹脂被覆複合ガラス繊維ロービング |
EP0498216B1 (de) * | 1991-02-06 | 1995-11-08 | BETTCHER INDUSTRIES, INC. (a Delaware Corporation) | Verbessertes Garn und Schutzkleidung |
FR2674260B1 (fr) * | 1991-03-19 | 1994-01-14 | Vetrotex France | Dispositif de fabrication d'un fil composite forme de fibres de renforcement et de matiere organique thermoplastique. |
CA2108716C (en) * | 1992-10-29 | 2005-01-11 | Joseph Hummel | Knittable yarn and safety apparel |
US6132871A (en) * | 1992-11-25 | 2000-10-17 | Andrews; Mark A. | Composite yarn with thermoplastic liquid component |
US5845476A (en) * | 1997-06-04 | 1998-12-08 | Kolmes; Nathaniel H. | Composite yarn with fiberglass core |
JPH11172512A (ja) * | 1997-12-04 | 1999-06-29 | Kanebo Ltd | 編み手袋 |
JP2002069788A (ja) * | 2000-08-31 | 2002-03-08 | Toyobo Co Ltd | 耐切断性能に優れた繊維構造物 |
FR2828894B1 (fr) * | 2001-08-24 | 2004-01-02 | Schappe Sa | Fil resistant a la coupure, destine notamment a la realisation de vetements de protection |
-
2002
- 2002-01-10 FR FR0200264A patent/FR2834522B1/fr not_active Expired - Fee Related
- 2002-12-30 DE DE60200827T patent/DE60200827T2/de not_active Expired - Lifetime
- 2002-12-30 TR TR2004/02273T patent/TR200402273T4/xx unknown
- 2002-12-30 DK DK02356273T patent/DK1327710T3/da active
- 2002-12-30 EP EP02356273A patent/EP1327710B1/de not_active Expired - Lifetime
- 2002-12-30 ES ES02356273T patent/ES2225744T3/es not_active Expired - Lifetime
- 2002-12-30 AT AT02356273T patent/ATE272139T1/de active
- 2002-12-30 PT PT02356273T patent/PT1327710E/pt unknown
-
2003
- 2003-01-07 US US10/337,350 patent/US6880321B2/en not_active Expired - Fee Related
- 2003-01-10 JP JP2003004123A patent/JP4542746B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ES2225744T3 (es) | 2005-03-16 |
JP4542746B2 (ja) | 2010-09-15 |
PT1327710E (pt) | 2004-11-30 |
TR200402273T4 (tr) | 2004-12-21 |
DK1327710T3 (da) | 2004-11-29 |
DE60200827D1 (de) | 2004-09-02 |
US20030159422A1 (en) | 2003-08-28 |
US6880321B2 (en) | 2005-04-19 |
ATE272139T1 (de) | 2004-08-15 |
JP2003239152A (ja) | 2003-08-27 |
DE60200827T2 (de) | 2005-01-27 |
EP1327710A1 (de) | 2003-07-16 |
FR2834522B1 (fr) | 2005-05-13 |
FR2834522A1 (fr) | 2003-07-11 |
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