EP1326747A1 - Materiau pour emballage - Google Patents

Materiau pour emballage

Info

Publication number
EP1326747A1
EP1326747A1 EP01950187A EP01950187A EP1326747A1 EP 1326747 A1 EP1326747 A1 EP 1326747A1 EP 01950187 A EP01950187 A EP 01950187A EP 01950187 A EP01950187 A EP 01950187A EP 1326747 A1 EP1326747 A1 EP 1326747A1
Authority
EP
European Patent Office
Prior art keywords
layer
polycarbonate
amorphous polyester
coextruded
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01950187A
Other languages
German (de)
English (en)
Inventor
Karl Nideborn
David Roos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GPI Flexibles AB
Original Assignee
Amcor Flexibles Europe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amcor Flexibles Europe AS filed Critical Amcor Flexibles Europe AS
Publication of EP1326747A1 publication Critical patent/EP1326747A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters

Definitions

  • the present invention relates to a material for packing purposes, which material comprises a first layer, which is heat-resistant, and a second layer, which is heat-sealable, wherein said material comprising a coextruded laminate, and to a process for producing such a material.
  • the invention furthermore relates to a process for packing and to a process for thermoforming using a material in accordance with the present invention.
  • JP 07-186318 describes a coextruded laminate for packing purposes, which laminate consists of a heat-sealing layer and a layer for preventing crack formation, wherein the heat sealing layer consisting of polyester and the layer for preventing crack formation consisting, for example, of polycarbonate.
  • a "layer for preventing crack formation” is understood here as meaning a layer which exhibits a negligible stretching and which thereby prevents crack formation in a barrier layer which has been deposited on the layer. While it is true that the coextruded laminate in JP 07-186318 provides a combination which is suitable as far as recovery is concerned, JP 07- 186318 does not provide a coextruded laminate which exhibits heat resistance and heat sealability at the same time as the constituent components are thermoformable simultaneously.
  • the present invention relates to a material for packing purposes, which material comprises a coextruded laminate, wherein said material exhibiting heat resistance at the same time as heat sealability and also good optical properties in the form of high transparency and brightness.
  • the present invention furthermore relates to a material for packing purposes, which material comprises a coextruded laminate, wherein said material exhibiting heat resistance at the same time as heat sealability, and wherein the constituent components of the coextruded laminate being thermoformable simultaneously and providing process advantages in the form of improved heat transition in the coextruded laminate.
  • the present invention relates to a material for packing purposes, which material comprises a first layer, which is heat-resistant, and a second layer, which is heat-sealable, wherein said material comprising a coextruded laminate, which coextruded laminate comprises polycarbonate and amorphous polyester, wherein said polycarbonate having a melt flow index in the interval from 1.5 to 10.0 and said amorphous polyester having an intrinsic viscosity in the interval from 0.5 to 0.8.
  • Said material is expediently a flexible material in film or foil form which is useful in packing, for example in packing comprising the use of welding tools such as heated gripper jaws or other energy-transferring tools.
  • said material exhibits a first layer, which is heat-resistant, and a second layer, which is heat-sealable, wherein, when, for example, welding tools such as heated gripper jaws are used, said first layer remaining tack- free at the same time as said second layer is heat-sealed to an object.
  • a layer which is heat-resistant is defined here as being a layer which remains tack-free up to approx. 180°C
  • a layer which is heat-sealable is defined here as being a layer which has a Tg temperature (glass transition temperature) of about 85°C.
  • Said object is, for example, made of the same material as said second layer, for example amorphous polyester.
  • Said material comprises a coextruded laminate, wherein said laminate preferably being coextruded by means of single-slot coextrusion.
  • Said coextruded laminate furthermore comprises polycarbonate and amorphous polyester wherein said polycarbonate having a melt flow index in the interval from 1.5 to 10.0 and said amorphous polyester having an intrinsic viscosity in the interval from 0.5 to 0.8.
  • Said polycarbonate consists of thermoplastic, aromatic polymers of high molecular weight and comprises homopolycarbonates, copolycarbonates and mixtures thereof. Said polycarbonate furthermore has an average molecular weight of from about 8000 to more than 200,000.
  • Said polyester can be a polyester having a high molecular weight, wherein high molecular weight signifying a polyester which has an intrinsic viscosity (I.V.) of from about 0.5 to about 1.10, preferably to 0.8, which I.V. is measured in a solution which is 60/40, with respect to volume, of phenol/tetrachloroethane at 30°C.
  • Said polyester can alternatively be defined by a density which is about 1.361 grams per cubic centimetre or less.
  • Another embodiment relates to a material according to the present invention in which the thickness of said polycarbonate layer is in the interval from approx. 2 to 30 ⁇ , and the thickness of said amorphous polyester layer is in the interval 20-1000 ⁇ .
  • Yet another embodiment relates to a material according to the present invention in which said first layer consists of said polycarbonate and said second layer consists of said amorphous polyester.
  • Another embodiment relates to a material according to the present invention in which said material exhibits a third layer, which forms a gas and/or vapour barrier.
  • Said third layer, which forms a gas and/or vapour barrier can, for example, be ethyl vinyl alcohol or polyamide.
  • Yet another embodiment according to the present invention relates to a material in which said third layer is formed from a coextruded substance having gas and/or vapour barrier properties in said coextruded laminate.
  • Said coextruded substance having gas and/or vapour barrier properties is preferably ethyl vinyl alcohol.
  • Another embodiment according to the present invention relates to a material, wherein said material, from said first layer to said second layer, comprising a coextruded laminate consisting of polycarbonate, amorphous polyester, ethyl vinyl alcohol and amorphous polyester.
  • polyethylene can be laminated on if sealability to PE systems is desired.
  • polyethylene When polyethylene is laminated onto said material, it can expediently be laminated on in a layer having a thickness of from 20 to 60 ⁇ .
  • a process for producing material according to the present invention is also included, wherein said material being coextruded in a single-slot extruder.
  • the present invention also relates to a process for packing, wherein a material which has been described here being used for said process.
  • Another embodiment according to the present invention relates to a process for packing in which a material which has been described here is used, wherein it being possible for said polycarbonate to be thermoformed at the same time as the amorphous polyester which is included in said material.
  • Yet another embodiment according to the present invention relates to a process for packing in which a material which has been described here is used, in which process a layer of amorphous polyester in the coextruded laminate is heat-sealed, where appropriate after thermoforming together with the layer of polycarbonate, to compatible material, for example a packing trough.
  • the layer of polycarbonate which is heat-resistant, serves as a heat transition layer and a pressure-distributing layer.
  • the present invention furthermore relates to a process for thermoforming in which a material which has been described here is used, wherein said polycarbonate being thermoformed at the same time as the amorphous polyester which is included in said material.
  • the two components polycarbonate which has a melt flow index in the interval from 1.5 to 10.0 and amorphous polyester which has an intrinsic viscosity in the interval from 0.5 to 0.8, are melted separately. After that, the melted components are coextruded, at an extrusion temperature of 270°C, in a single-slot extruder using conventional methodology, wherein coextruded laminates being obtained which consist of a layer of polycarbonate and a layer of amorphous polyester.
  • the thickness of the polycarbonate layer is optionally in the interval from 2 to 30 ⁇ and the thickness of the amorphous polyester layer is in the interval from 20 to 1000 ⁇ .
  • the layer of polycarbonate remains tack-free towards currently available sealing jaws up to approx. 180°C and thereby exhibits the desired heat resistance.
  • the layer of amorphous polyester has a Tg temperature (glass transition temperature) of about 85°C and thereby exhibits the desired heat sealability. Furthermore, as a result of the choice of the melt flow index for said polycarbonate and the choice of the intrinsic viscosity for said amorphous polyester, the components which are included in the coextruded laminate exhibit the unique property of being thermoformable simultaneously.
  • polycarbonate which has a melt flow index in the interval from 1.5 to 10.0 and amorphous polyester which has an intrinsic viscosity in the interval from 0.5 to 0.8, ethyl vinyl alcohol is also used in this example, wherein all the components being melted separately.
  • the melted components are coextruded, at an extrusion temperature of approx. 240-270°C, in a single- slot extruder using conventional methology, wherein coextruded laminates consisting, in the following order, of a layer of polycarbonate, a layer of amorphous polyester, a layer of ethyl vinyl alcohol and an additional layer of amorphous polyester being obtained.
  • the thickness of the polycarbonate layer can optionally vary in the interval from 2 to 30 ⁇ , whereas the two amorphous polyester layers can optionally have a thickness of approx. 100 ⁇ , and the ethyl vinyl alcohol layer can have a thickness of approx. 2 ⁇ .
  • the layer of polycarbonate remains tack-free towards currently available sealing jaws up to approx. 180°C and exhibits the desired heat-resistance, and the layers of amorphous polyester have a Tg temperature (glass transition temperature) of about 85°C, wherein it in the present case being the second layer of amorphous polyester which exhibits heat sealability.
  • the layer of ethyl vinyl alcohol forms a gas and/or vapour barrier in the coextruded laminates.
  • the components which are included in the coextruded laminate exhibit the unique property of being thermoformable simultaneously.
  • polyethylene is also used in this present example, and the same conventional methodology as in Implementation Example 2 is employed for the coextruded laminate consisting, in the following order, of a layer of polycarbonate, a layer of amorphous polyester, a layer of ethyl vinyl alcohol and a second layer of amorphous polyester.
  • the layer of polyethylene is a layer which is applied using a conventional lamination technique.
  • the polyethylene layer has a thickness of approx. 40 ⁇ and the other layers have thicknesses, properties and functions in accordance with the corresponding layers in Implementation Example 2.
  • the polyethylene layer exhibits sealability to PE systems and can also provide a peel effect, i.e. packings which comprise a peel effect can be torn open.
  • the components which are included in the coextruded laminate exhibit the unique property of being thermoformable simultaneously.

Landscapes

  • Laminated Bodies (AREA)
  • Wrappers (AREA)

Abstract

La présente invention concerne un matériau pour emballage. Ce matériau comprend une première couche résistante à la chaleur, une seconde couche thermoscellable, ainsi qu'un stratifié coextrudé renfermant un polycarbonate et un polyester amorphe, ledit polycarbonate présentant un indice de fluage compris entre 1,5 et 10,0 et ledit polyester présentant une viscosité intrinsèque comprise entre 0,5 et 0,8.
EP01950187A 2000-07-21 2001-07-16 Materiau pour emballage Withdrawn EP1326747A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE0002734 2000-07-21
SE0002734A SE523074C2 (sv) 2000-07-21 2000-07-21 Material för förpackninsändamål
PCT/SE2001/001630 WO2002007970A1 (fr) 2000-07-21 2001-07-16 Materiau pour emballage

Publications (1)

Publication Number Publication Date
EP1326747A1 true EP1326747A1 (fr) 2003-07-16

Family

ID=20280560

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01950187A Withdrawn EP1326747A1 (fr) 2000-07-21 2001-07-16 Materiau pour emballage

Country Status (5)

Country Link
EP (1) EP1326747A1 (fr)
AU (1) AU2001271212A1 (fr)
NO (1) NO330895B1 (fr)
SE (1) SE523074C2 (fr)
WO (1) WO2002007970A1 (fr)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH047150A (ja) * 1990-04-24 1992-01-10 Kanegafuchi Chem Ind Co Ltd 食品包装用積層材料、該材料からなる食品包装容器及び該容器の製造方法
EP0928683A2 (fr) * 1998-01-06 1999-07-14 HNA Holdings, Inc. Stratifié multicouche coprocessable pour la formation des articles à haute résistance, sans voile et transparents et son procédé de fabrication

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0219226Y2 (fr) * 1985-08-19 1990-05-28
JPH0435890Y2 (fr) * 1985-09-11 1992-08-25
EP0270374A3 (fr) * 1986-12-04 1989-05-10 Mitsui Petrochemical Industries, Ltd. Stratifié moulé en polyester et son utilisation
JPH07186318A (ja) 1993-12-27 1995-07-25 Dainippon Printing Co Ltd 蒸着フィルム

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH047150A (ja) * 1990-04-24 1992-01-10 Kanegafuchi Chem Ind Co Ltd 食品包装用積層材料、該材料からなる食品包装容器及び該容器の製造方法
EP0928683A2 (fr) * 1998-01-06 1999-07-14 HNA Holdings, Inc. Stratifié multicouche coprocessable pour la formation des articles à haute résistance, sans voile et transparents et son procédé de fabrication

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO0207970A1 *

Also Published As

Publication number Publication date
SE523074C2 (sv) 2004-03-23
SE0002734L (sv) 2002-01-22
NO20030278D0 (no) 2003-01-20
SE0002734D0 (sv) 2000-07-21
NO20030278L (no) 2003-02-20
NO330895B1 (no) 2011-08-08
AU2001271212A1 (en) 2002-02-05
WO2002007970B1 (fr) 2002-05-23
WO2002007970A1 (fr) 2002-01-31

Similar Documents

Publication Publication Date Title
EP0404803B1 (fr) Feuilles multicouche presentant une excellente adherence
CA1037370A (fr) Conditionnement des denrees alimentaires
US4585679A (en) Coextruded multilayer sheet and tough sleeve label made therefrom
US9656447B2 (en) Lidding structure based on aromatic polyester film, extrusion-coated with a sealable/peelable copolyester layer
WO2004094141A3 (fr) Films en polypropylene multicouches orientes, a partie centrale modifiee
KR960700890A (ko) 적층제, 적층 필름 및 성형품(laminate, laminated film and molding)
JPH0327938A (ja) 変性ヒートシール層を有する蓋素材用の非配向ポリエステルフィルム
KR20010015798A (ko) 자외선 차단성을 갖는 다층 할로중합체 폴리(알킬렌나프탈레이트) 필름
WO2001064435A1 (fr) Film polyolefinique thermoretractable
EP2237951A2 (fr) Films et feuilles à barrière contre les gaz
WO2010015402A1 (fr) Structures multicouches comprenant une séquence de microcouches
JP2008062493A (ja) オレフィン系シュリンクフィルム
CN110475722B (zh) 具有蒸煮冲击恢复性的膜
US9573348B2 (en) Lidding structure based on aromatic polyester film, coextruded with a sealable/peelable epdxy-containing thermoplastic polymer
AU705748B2 (en) Film/substrate composite material
WO2020136674A1 (fr) Stratifié recyclable
EP0291065A2 (fr) Films en polyester non orienté comme réserve de couvercle
JP2004066533A (ja) 熱収縮性ポリオレフィン系積層フィルム
EP1326747A1 (fr) Materiau pour emballage
JPH05200952A (ja) シール可能な多層プラスチックフィルム
WO2021177424A1 (fr) Film adhésif pour borne métallique ainsi que procédé de fabrication de celui-ci, borne métallique avec film adhésif pour borne métallique, dispositif de stockage électrique mettant en œuvre ce film adhésif pour borne métallique, et procédé de fabrication de dispositif de stockage électrique
JP2814496B2 (ja) ポリエステル複合フィルム
JP5023924B2 (ja) 電子レンジ調理用袋
KR20120125721A (ko) 차단성 및 열접착성이 우수한 다층필름
AU2008319934B2 (en) Multilayered laminate film

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20030117

AK Designated contracting states

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

17Q First examination report despatched

Effective date: 20061120

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: FLEXTRUS AB

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20150203